FR2187730A1 - Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts - Google Patents

Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts

Info

Publication number
FR2187730A1
FR2187730A1 FR7220209A FR7220209A FR2187730A1 FR 2187730 A1 FR2187730 A1 FR 2187730A1 FR 7220209 A FR7220209 A FR 7220209A FR 7220209 A FR7220209 A FR 7220209A FR 2187730 A1 FR2187730 A1 FR 2187730A1
Authority
FR
France
Prior art keywords
hydrocarbons
cpds
hydrogenation
catalysts
selective hydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7220209A
Other languages
French (fr)
Other versions
FR2187730B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7220209A priority Critical patent/FR2187730A1/en
Priority to DE2327230A priority patent/DE2327230A1/en
Priority to JP48062826A priority patent/JPS49132001A/ja
Publication of FR2187730A1 publication Critical patent/FR2187730A1/en
Application granted granted Critical
Publication of FR2187730B1 publication Critical patent/FR2187730B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C07C5/05—Partial hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Unsatd. hydrocarbons are selectively hydrogenated in presence of a catalyst contg. (A) an org. Ni deriv. and (B) a reducing agent, as in parent patent, using as (B) cpds. of formula AlR1R2R3 or LiR (where R1-3 are each H and for hydrocarbon gps. and R is a hydrocarbon gp.). Hydrogenation is carried out in presence of pyridine. (A) is pref. a carboxylate or acetyl-acetonate, and (B) is triethyl aluminium, or methyl or n-butyl lithium. The catalyst is pref. made by passing (B) into a mixt. of (A) and pyridine. The catalysts show high activity and selectivity for hydrogenation of acetylenic or olefinic hydrocarbons e.g. selective hydrogenation of cyclopentadiene to cyclopentene or cycloctadiene to cyclo-octene.
FR7220209A 1972-06-05 1972-06-05 Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts Granted FR2187730A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR7220209A FR2187730A1 (en) 1972-06-05 1972-06-05 Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts
DE2327230A DE2327230A1 (en) 1972-06-05 1973-05-29 NEW PROCESS FOR SELECTIVE HYDROGENATION AS WELL AS THE CATALYST USED IN IT
JP48062826A JPS49132001A (en) 1972-06-05 1973-06-04

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7220209A FR2187730A1 (en) 1972-06-05 1972-06-05 Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts

Publications (2)

Publication Number Publication Date
FR2187730A1 true FR2187730A1 (en) 1974-01-18
FR2187730B1 FR2187730B1 (en) 1974-07-26

Family

ID=9099726

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7220209A Granted FR2187730A1 (en) 1972-06-05 1972-06-05 Selective hydrogenation of hydrocarbons - using organonickel cpds with reducing agents as catalysts

Country Status (3)

Country Link
JP (1) JPS49132001A (en)
DE (1) DE2327230A1 (en)
FR (1) FR2187730A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2283111A1 (en) * 1974-08-29 1976-03-26 Goodyear Tire & Rubber SELECTIVE HYDROGENATION PROCESS OF CYCLOPENTADIENE
CN116174037A (en) * 2021-11-26 2023-05-30 沈阳化工研究院有限公司 Catalyst for selectively partially hydrogenating conjugated diene polymer and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4188348A (en) * 1978-08-11 1980-02-12 The Goodyear Tire & Rubber Company Hydrogenation of cyclopentadiene to form cyclopentene
DE10032303A1 (en) 2000-07-04 2002-01-17 Basf Ag Metallic hydrogenation catalysts
FR2841482B1 (en) * 2002-06-28 2006-12-29 Inst Francais Du Petrole METHOD FOR SELECTIVE HYDROGENATION OF POLYUNSATURATED COMPOUNDS TO MONOINSATURED COMPOUNDS USING A HOMOGENEOUS CATALYST

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3113986A (en) * 1962-01-08 1963-12-10 Hercules Powder Co Ltd Hydrogenation of unsaturated hydrocarbons
US3542898A (en) * 1969-08-22 1970-11-24 Sun Oil Co Process for hydrogenation of olefins

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2283111A1 (en) * 1974-08-29 1976-03-26 Goodyear Tire & Rubber SELECTIVE HYDROGENATION PROCESS OF CYCLOPENTADIENE
CN116174037A (en) * 2021-11-26 2023-05-30 沈阳化工研究院有限公司 Catalyst for selectively partially hydrogenating conjugated diene polymer and preparation method thereof

Also Published As

Publication number Publication date
FR2187730B1 (en) 1974-07-26
JPS49132001A (en) 1974-12-18
DE2327230A1 (en) 1974-01-10

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