ES2099017B1 - Fosfatos de dibutilo y monobutilo deuterados y procedimiento de elaboracion relacionado. - Google Patents
Fosfatos de dibutilo y monobutilo deuterados y procedimiento de elaboracion relacionado.Info
- Publication number
- ES2099017B1 ES2099017B1 ES09400702A ES9400702A ES2099017B1 ES 2099017 B1 ES2099017 B1 ES 2099017B1 ES 09400702 A ES09400702 A ES 09400702A ES 9400702 A ES9400702 A ES 9400702A ES 2099017 B1 ES2099017 B1 ES 2099017B1
- Authority
- ES
- Spain
- Prior art keywords
- dibutyl
- monobutyl
- manufacturing procedure
- deuterated
- related manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical class CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 title 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- YXHKONLOYHBTNS-UHFFFAOYSA-N Diazomethane Chemical compound C=[N+]=[N-] YXHKONLOYHBTNS-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 abstract 1
- 239000002360 explosive Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000011005 laboratory method Methods 0.000 abstract 1
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical compound O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 238000003672 processing method Methods 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/11—Esters of phosphoric acids with hydroxyalkyl compounds without further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
FOSFATOS DE DIBUTILO Y MONOBUTILO DEUTERADOS Y METODO DE ELABORACION RELACIONADO. UN PATRON INTERNO MEJORADO PARA SER UTILIZADO EN LA DETERMINACION DE LA CONCENTRACION DE PRODUCTOS DE DESCOMPOSICION DE FOSFATO DE TRIBUTILO EN UN DISOLVENTE UTILIZADO PARA EXTRACCION CON DISOLVENTES. EL PATRON INTERNO MEJORADO INCLUYE VARIANTES DEUTERADAS DE LOS PRODUCTOS DE DESCOMPOSICION QUE SE VAN A MEDIR, POR EJEMPLO, ACIDOS DIBUTIL- Y MONOBUTIL-FOSFORICO DEUTERADOS. LA UTILIZACION DE ACIDOS DIBUTIL- Y MONOBUTIL-FOSFORICO DEUTERADOS ELIMINA LA UTILIZACION DE DIAZOMETANO, QUE ES TOXICO Y EXPLOSIVO, PROPORCIONANDO ASI UNA TECNICA DE LABORATORIO MAS SEGURA PARA LOS ANALISIS RUTINARIOS NECESARIOS PARA CONTROLAR LA PRODUCCION DE PROCEDIMIENTOS DE EXTRACCION CON DISOLVENTES.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/058,180 US5302758A (en) | 1993-05-10 | 1993-05-10 | Deuterated dibutyl and monobutyl phosphates |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2099017A1 ES2099017A1 (es) | 1997-05-01 |
ES2099017B1 true ES2099017B1 (es) | 1997-12-16 |
Family
ID=22015194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES09400702A Expired - Lifetime ES2099017B1 (es) | 1993-05-10 | 1994-03-30 | Fosfatos de dibutilo y monobutilo deuterados y procedimiento de elaboracion relacionado. |
Country Status (3)
Country | Link |
---|---|
US (1) | US5302758A (es) |
JP (1) | JPH072881A (es) |
ES (1) | ES2099017B1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5401664A (en) * | 1993-06-10 | 1995-03-28 | General Electric Company | Analytical method for determining concentration of decomposition products in solvent used for solvent extraction |
JP2727289B2 (ja) * | 1993-09-29 | 1998-03-11 | 呉羽化学工業株式会社 | 3−デオキシグルコソン誘導体及びその定量法 |
KR20120093262A (ko) * | 2009-10-05 | 2012-08-22 | 다우 글로벌 테크놀로지스 엘엘씨 | 포스포릴 클로라이드 및 글리콜 또는 폴리글리콜의 모노알킬 에터로부터 포스페이트 에스터를 제조하는 방법 |
CN109307728B (zh) * | 2017-07-26 | 2020-11-03 | 华东理工大学 | 检测样品中氨基酸、有机酸或磷酸糖代谢产物的新型内标物 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5036014A (en) * | 1989-01-31 | 1991-07-30 | Elsohly Mahmoud A | Deuterated cannabinoids as standards for the analysis of tetrahydrocannabinol and its metabolites in biological fluids |
-
1993
- 1993-05-10 US US08/058,180 patent/US5302758A/en not_active Expired - Fee Related
-
1994
- 1994-03-30 ES ES09400702A patent/ES2099017B1/es not_active Expired - Lifetime
- 1994-05-09 JP JP6094635A patent/JPH072881A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ES2099017A1 (es) | 1997-05-01 |
JPH072881A (ja) | 1995-01-06 |
US5302758A (en) | 1994-04-12 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EC2A | Search report published |
Date of ref document: 19970501 Kind code of ref document: A1 Effective date: 19970501 |