ES2098318T3 - Metodo para preparar composiciones de polimeros de olefinas. - Google Patents
Metodo para preparar composiciones de polimeros de olefinas.Info
- Publication number
- ES2098318T3 ES2098318T3 ES91301167T ES91301167T ES2098318T3 ES 2098318 T3 ES2098318 T3 ES 2098318T3 ES 91301167 T ES91301167 T ES 91301167T ES 91301167 T ES91301167 T ES 91301167T ES 2098318 T3 ES2098318 T3 ES 2098318T3
- Authority
- ES
- Spain
- Prior art keywords
- preparing
- polymer compositions
- olephine
- eta
- sub
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
LA PRESENTE INVENCION SUMINISTRA UN METODO PARA LA PREPARACION DE UN COMPUESTO DE POLIMERO DE ETILENO QUE TIENE UNA DENSIDAD DE 0.86-0.94 G/CM SUB 3 Y UNA VISCOSIDAD INTRINSECA [ETA] DE 1-6 DL/G, USANDO UN CATALIZADOR DE POLIMERIZACION DE OLEFINA QUE COMPRENDE UN COMPUESTO DE METAL DE TRANSICION QUE CONTIENE UN LIGANTE QUE TIENE UNA ESTRUCTURA DE CICLOALQUENIL Y UN COMPUESTO OXIDO DE ORGANO ALUMINIO. TAMBIEN SE SUMINISTRA EL METODO PARA LA PREPARACION DE UN COMPUESTO DE POLIMERO DE ETILENO QUE TENGA UNA DENSIDAD DE 0.87-0.93 G/CM SUB 3 Y UNA VISCOSIDAD INTRINSECA [ETA] DE 0.5-6 DL/G.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3209290A JP2781244B2 (ja) | 1990-02-13 | 1990-02-13 | エチレン系重合体組成物の製造方法 |
JP3209390A JP2781245B2 (ja) | 1990-02-13 | 1990-02-13 | エチレン系重合体組成物の製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2098318T3 true ES2098318T3 (es) | 1997-05-01 |
Family
ID=26370610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91301167T Expired - Lifetime ES2098318T3 (es) | 1990-02-13 | 1991-02-13 | Metodo para preparar composiciones de polimeros de olefinas. |
Country Status (13)
Country | Link |
---|---|
US (1) | US5605969A (es) |
EP (2) | EP0447035B1 (es) |
KR (2) | KR940010792B1 (es) |
CN (2) | CN1077901C (es) |
AT (2) | ATE147086T1 (es) |
CA (1) | CA2036196C (es) |
DE (2) | DE69123862T2 (es) |
DK (1) | DK0447035T3 (es) |
ES (1) | ES2098318T3 (es) |
GR (1) | GR3022413T3 (es) |
MY (1) | MY105398A (es) |
SG (1) | SG55752A1 (es) |
TW (1) | TW206240B (es) |
Families Citing this family (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2060019A1 (en) * | 1991-03-04 | 1992-09-05 | Phil Marvin Stricklen | Process for producing polyolefins having a bimodal molecular weight distribution |
US5677383A (en) * | 1991-10-15 | 1997-10-14 | The Dow Chemical Company | Fabricated articles made from ethylene polymer blends |
US6316549B1 (en) | 1991-10-15 | 2001-11-13 | The Dow Chemical Company | Ethylene polymer fiber made from ethylene polymer blends |
US5847053A (en) * | 1991-10-15 | 1998-12-08 | The Dow Chemical Company | Ethylene polymer film made from ethylene polymer blends |
US5475060A (en) * | 1993-02-18 | 1995-12-12 | Hoechst Ag | Cycloolefin block copolymers and a process for their preparation |
US5331057A (en) * | 1992-02-22 | 1994-07-19 | Hoechst Aktiengesellschaft | Cycloolefin block copolymers and a process for their preparation |
TW312695B (es) * | 1992-02-22 | 1997-08-11 | Hoechst Ag | |
BE1005795A3 (fr) * | 1992-05-13 | 1994-02-01 | Solvay | Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine. |
JP3264332B2 (ja) * | 1992-05-26 | 2002-03-11 | 出光興産株式会社 | エチレン系重合体組成物の製造方法 |
JP3264333B2 (ja) * | 1992-05-28 | 2002-03-11 | 出光興産株式会社 | エチレン系重合体組成物の製造方法 |
US6774190B1 (en) | 1992-06-17 | 2004-08-10 | Mitsui Chemicals, Inc. | Ethylene copolymer composition |
EP0575123B2 (en) * | 1992-06-17 | 2008-02-13 | Mitsui Chemicals, Inc. | Ethylene copolymer composition |
JP3216734B2 (ja) * | 1992-08-14 | 2001-10-09 | 出光石油化学株式会社 | スチレン系重合体の製造方法 |
JPH06136195A (ja) * | 1992-09-08 | 1994-05-17 | Mitsui Petrochem Ind Ltd | エチレン系共重合体組成物 |
DE69333773T2 (de) | 1992-11-13 | 2006-04-06 | Cryovac, Inc. | Wärmeschrumpfbare, durch Single-site-Katalyse hergestellte Copolymere enthaltende Folien. |
CA2103401C (en) | 1992-11-19 | 2002-12-17 | Mamoru Takahashi | Ethylene copolymer composition |
CA2103380C (en) * | 1992-11-19 | 2002-07-02 | Mitsui Chemicals, Inc. | Ethylene/.alpha.-olefin copolymer composition, graft modified ethylene/.alpha.-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
CA2110654C (en) * | 1992-12-17 | 2006-03-21 | Albert Rossi | Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems |
US6448341B1 (en) | 1993-01-29 | 2002-09-10 | The Dow Chemical Company | Ethylene interpolymer blend compositions |
JP2986547B2 (ja) * | 1993-01-29 | 1999-12-06 | ザ・ダウ・ケミカル・カンパニー | エチレン共重合 |
IT1270253B (it) | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
US5773106A (en) * | 1994-10-21 | 1998-06-30 | The Dow Chemical Company | Polyolefin compositions exhibiting heat resistivity, low hexane-extractives and controlled modulus |
US5529965A (en) * | 1994-10-28 | 1996-06-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
US6506866B2 (en) | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
US5770318A (en) * | 1995-01-13 | 1998-06-23 | Norton Performance Plastics Corporation | Thermoplastic seal and wrapping film |
US5840808A (en) * | 1995-02-07 | 1998-11-24 | Mitsui Petrochemical Industries, Ltd. | Process for preparing olefin polymer |
US5869575A (en) * | 1995-08-02 | 1999-02-09 | The Dow Chemical Company | Ethylene interpolymerizations |
CA2188722A1 (en) * | 1995-10-26 | 1997-04-27 | George Norris Foster | Process for preparing an in situ polyethylene blend |
DE69715818T2 (de) * | 1996-01-22 | 2003-06-18 | The Dow Chemical Co., Midland | Polyolefinelastomerzusammensetzungen mit verbesserten eigenschaften |
NO301331B1 (no) * | 1996-03-05 | 1997-10-13 | Borealis As | Fremgangsmåte for skifting av katalysator ved suspensjonspolymerisasjon av olefiner |
JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
EP0816394B1 (en) * | 1996-06-26 | 2002-01-30 | BP Chemicals S.N.C. | Process for polymerising ethylene in the gas phase |
US5849823A (en) * | 1996-09-04 | 1998-12-15 | The Dow Chemical Company | Homogeneously branched ethylene α-olefin interpolymer compositions for use in gasket applications |
DE19652340A1 (de) * | 1996-12-17 | 1998-06-18 | Hoechst Ag | Verfahren zur Herstellung von Cycloolefincopolymers |
DE19652338A1 (de) * | 1996-12-17 | 1998-06-18 | Hoechst Ag | Verfahren zur Herstellung eines Cycloolefincopolymers |
EP0881237A1 (en) * | 1997-05-26 | 1998-12-02 | Fina Research S.A. | Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones |
EP0905145A1 (en) * | 1997-09-27 | 1999-03-31 | Fina Research S.A. | Production of polyethylene having improved crack resistance |
EP0905146B1 (en) * | 1997-09-27 | 2002-10-09 | ATOFINA Research | Production of polyethylene having improved crack and/or impact resistance |
FI990003A (fi) | 1999-01-04 | 2000-07-05 | Borealis Polymers Oy | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot |
SG97919A1 (en) * | 1999-08-31 | 2003-08-20 | Sumitomo Chemical Co | Ethylene-alpha-olefin copolymer and polyethylene composition |
US6455638B2 (en) | 2000-05-11 | 2002-09-24 | Dupont Dow Elastomers L.L.C. | Ethylene/α-olefin polymer blends comprising components with differing ethylene contents |
DE10217841B4 (de) * | 2001-04-23 | 2016-02-04 | Mitsui Chemicals, Inc. | Verfahren zur Herstellung einer Ethylenpolymer-Zusammensetzung, Teilchen aus Ethylenpolymer-Zusammensetzung und aus den Teilchen der Ethylenpolymer-Zusammensetzung erhaltene Folie |
US20080145402A1 (en) * | 2001-09-10 | 2008-06-19 | Abbott Cardiovascular Systems Inc. | Medical Devices Containing Rapamycin Analogs |
US7943700B2 (en) * | 2002-10-01 | 2011-05-17 | Exxonmobil Chemical Patents Inc. | Enhanced ESCR of HDPE resins |
US7396878B2 (en) * | 2002-10-01 | 2008-07-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions for injection molding |
US7396881B2 (en) * | 2002-10-01 | 2008-07-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions for rotational molding |
DE60331562D1 (es) * | 2002-10-01 | 2010-04-15 | Exxonmobil Chem Patents Inc | |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
CN101724110B (zh) * | 2002-10-15 | 2013-03-27 | 埃克森美孚化学专利公司 | 用于烯烃聚合的多催化剂体系和由其生产的聚合物 |
EP1496068A1 (en) * | 2003-07-09 | 2005-01-12 | Total Petrochemicals Research Feluy | Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones. |
US7488343B2 (en) * | 2003-09-16 | 2009-02-10 | Boston Scientific Scimed, Inc. | Medical devices |
KR100833561B1 (ko) * | 2004-08-16 | 2008-05-30 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌계 중합체 및 그 용도 |
US20060198869A1 (en) * | 2005-03-03 | 2006-09-07 | Icon Medical Corp. | Bioabsorable medical devices |
CN101490110B (zh) * | 2006-07-25 | 2011-04-20 | 三井化学株式会社 | 乙烯聚合物粒子、其制造方法以及使用其的成形物 |
EP2576690B1 (en) | 2010-05-28 | 2018-05-16 | Basell Polyolefine GmbH | Polyethylene composition |
CA2724943A1 (en) | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
EP2486913A1 (en) | 2011-02-14 | 2012-08-15 | Labtec GmbH | Rapidly disintegrating oral film formulation for Olanzapin |
EP3209722A2 (en) | 2014-10-21 | 2017-08-30 | Nova Chemicals (International) S.A. | Ethylene interpolymer product with dilution index |
CA2868640C (en) | 2014-10-21 | 2021-10-26 | Nova Chemicals Corporation | Solution polymerization process |
US10329412B2 (en) | 2017-02-16 | 2019-06-25 | Nova Chemicals (International) S.A. | Caps and closures |
WO2019198694A1 (ja) | 2018-04-11 | 2019-10-17 | 三井化学株式会社 | 4-メチル-1-ペンテン系重合体粒子および4-メチル-1-ペンテン系樹脂の製造方法 |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
US11028258B2 (en) * | 2019-08-19 | 2021-06-08 | Chevron Phillips Chemical Company Lp | Metallocene catalyst system for producing LLDPE copolymers with tear resistance and low haze |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5610506A (en) * | 1979-07-09 | 1981-02-03 | Mitsui Petrochem Ind Ltd | Production of ethylene polymer composition |
US4438238A (en) * | 1981-01-30 | 1984-03-20 | Sumitomo Chemical Company, Limited | Low density copolymer composition of two ethylene-α-olefin copolymers |
US4935474A (en) * | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
WO1988008432A1 (en) * | 1987-04-20 | 1988-11-03 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for polymerizing olefin |
US4939217A (en) * | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
HUT54722A (en) * | 1988-09-30 | 1991-03-28 | Exxon Chemical Patents Inc | Linear ethylene interpolymer mixtures |
US5382630A (en) * | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
-
1991
- 1991-02-02 TW TW080100852A patent/TW206240B/zh active
- 1991-02-05 MY MYPI91000176A patent/MY105398A/en unknown
- 1991-02-12 CA CA002036196A patent/CA2036196C/en not_active Expired - Fee Related
- 1991-02-13 AT AT91301167T patent/ATE147086T1/de not_active IP Right Cessation
- 1991-02-13 KR KR1019910002460A patent/KR940010792B1/ko not_active IP Right Cessation
- 1991-02-13 DE DE69123862T patent/DE69123862T2/de not_active Expired - Lifetime
- 1991-02-13 ES ES91301167T patent/ES2098318T3/es not_active Expired - Lifetime
- 1991-02-13 EP EP91301167A patent/EP0447035B1/en not_active Expired - Lifetime
- 1991-02-13 DK DK91301167.2T patent/DK0447035T3/da active
- 1991-02-13 SG SG1996005525A patent/SG55752A1/en unknown
- 1991-02-13 CN CN91101075A patent/CN1077901C/zh not_active Expired - Lifetime
- 1991-02-13 EP EP96109829A patent/EP0733653B1/en not_active Expired - Lifetime
- 1991-02-13 DE DE69130490T patent/DE69130490T2/de not_active Expired - Lifetime
- 1991-02-13 AT AT96109829T patent/ATE173278T1/de not_active IP Right Cessation
-
1993
- 1993-10-25 US US08/140,895 patent/US5605969A/en not_active Expired - Lifetime
-
1994
- 1994-06-20 KR KR1019940013907A patent/KR940010793B1/ko not_active IP Right Cessation
-
1997
- 1997-01-29 GR GR970400137T patent/GR3022413T3/el unknown
-
1999
- 1999-09-21 CN CN99120713A patent/CN1111174C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69123862D1 (de) | 1997-02-13 |
CN1054084A (zh) | 1991-08-28 |
CN1247874A (zh) | 2000-03-22 |
SG55752A1 (en) | 2000-11-21 |
TW206240B (es) | 1993-05-21 |
DK0447035T3 (da) | 1997-06-16 |
EP0447035A3 (en) | 1992-10-28 |
CN1111174C (zh) | 2003-06-11 |
EP0733653B1 (en) | 1998-11-11 |
US5605969A (en) | 1997-02-25 |
CN1077901C (zh) | 2002-01-16 |
KR940010792B1 (ko) | 1994-11-16 |
MY105398A (en) | 1994-09-30 |
KR940010793B1 (ko) | 1994-11-16 |
EP0733653A3 (en) | 1996-10-30 |
CA2036196A1 (en) | 1991-08-14 |
EP0447035A2 (en) | 1991-09-18 |
ATE147086T1 (de) | 1997-01-15 |
CA2036196C (en) | 1999-06-08 |
EP0733653A2 (en) | 1996-09-25 |
DE69130490T2 (de) | 1999-04-29 |
DE69123862T2 (de) | 1997-05-28 |
KR910015645A (ko) | 1991-09-30 |
GR3022413T3 (en) | 1997-04-30 |
DE69130490D1 (de) | 1998-12-17 |
ATE173278T1 (de) | 1998-11-15 |
EP0447035B1 (en) | 1997-01-02 |
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