ES2092217T3 - Catalizador para la hidroisomerizacion de n-parafinas de cadena larga y procedimiento para su preparacion. - Google Patents

Catalizador para la hidroisomerizacion de n-parafinas de cadena larga y procedimiento para su preparacion.

Info

Publication number
ES2092217T3
ES2092217T3 ES93202253T ES93202253T ES2092217T3 ES 2092217 T3 ES2092217 T3 ES 2092217T3 ES 93202253 T ES93202253 T ES 93202253T ES 93202253 T ES93202253 T ES 93202253T ES 2092217 T3 ES2092217 T3 ES 2092217T3
Authority
ES
Spain
Prior art keywords
hydroisomerization
paraffins
catalyst
chain
procedure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93202253T
Other languages
English (en)
Inventor
Carlo Perego
Laura Zanibelli
Cristina Flego
Bianco Alberto Del
Giuseppe Bellussi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni Tecnologie SpA
Original Assignee
Eniricerche SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche SpA filed Critical Eniricerche SpA
Application granted granted Critical
Publication of ES2092217T3 publication Critical patent/ES2092217T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE PRESENTA UN CATALIZADOR PARA LA HIDROISOMERIZACION DE CERAS (PARAFINAS), QUE ESTA CONSTITUIDO POR UN PORTADOR DE NATURALEZA ACIDICA, DE GEL DE SILICE-ALUMINA AMORFO, CON UNA RELACION MOLAR DE SIO2:AL2O3 COMPRENDIDA EN LA BANDA DE ENTRE 30:1 Y 500:1, UN AREA DE SUPERFICIE COMPRENDIDA DENTRO DE LA BANDA DE ENTRE 500 Y 1000 M2/G, UNA POROSIDAD DE ENTRE 0.3 Y 0.6 ML/G, UN DIAMETRO MEDIO DE LOS POROS DE ENTRE 10 Y 30 ANGSTROM, Y UNO O MAS METALES QUE PERTENECEN AL GRUPO VIIIA.
ES93202253T 1992-07-31 1993-07-30 Catalizador para la hidroisomerizacion de n-parafinas de cadena larga y procedimiento para su preparacion. Expired - Lifetime ES2092217T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI921895A IT1256084B (it) 1992-07-31 1992-07-31 Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione

Publications (1)

Publication Number Publication Date
ES2092217T3 true ES2092217T3 (es) 1996-11-16

Family

ID=11363809

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93202253T Expired - Lifetime ES2092217T3 (es) 1992-07-31 1993-07-30 Catalizador para la hidroisomerizacion de n-parafinas de cadena larga y procedimiento para su preparacion.

Country Status (9)

Country Link
US (3) US5602292A (es)
EP (1) EP0582347B1 (es)
JP (1) JP4103053B2 (es)
AT (1) ATE142906T1 (es)
DE (1) DE69304840T2 (es)
DK (1) DK0582347T3 (es)
ES (1) ES2092217T3 (es)
GR (1) GR3021322T3 (es)
IT (1) IT1256084B (es)

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IT1256084B (it) * 1992-07-31 1995-11-27 Eniricerche Spa Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione
IT1276726B1 (it) * 1995-06-15 1997-11-03 Eniricerche Spa Gel di allumina mesoporoso e procedimento per la sua preparazione
EP1365005B1 (en) 1995-11-28 2005-10-19 Shell Internationale Researchmaatschappij B.V. Process for producing lubricating base oils
IT1284007B1 (it) * 1996-06-13 1998-05-08 Eniricerche Spa Procedimento per la preparazione di un materiale micro-meso poroso ad alta area superficiale con distribuzione controllata della
BR9807350A (pt) * 1997-02-13 2000-04-25 Engelhard Corp Processo e catalisador para hidrogenação, hidroisomerização e/ou hidrodessulfurização de uma carga de alimentação de hidrocarboneto contendo enxofre como contaminante, e, uso de um suporte ácido de sìlica-alumina.
US6296759B1 (en) * 1997-02-13 2001-10-02 Engelhard Corporation Process for hydrogenation, hydroisomerization and/or hydrodesulfurization of a sulfur containment containing feedstock
PH11998001775B1 (en) * 1997-07-21 2004-02-11 Procter & Gamble Improved alkyl aryl sulfonate surfactants
CA2297648C (en) 1997-07-21 2004-11-23 The Procter & Gamble Company Improved processes for making alkylbenzenesulfonate surfactants and products thereof
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AU8124498A (en) 1997-07-21 1999-02-16 Procter & Gamble Company, The Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
DE69814641T2 (de) 1997-07-21 2004-03-25 The Procter & Gamble Company, Cincinnati Verbessertes alkylarylsulfonattensid
CA2298618C (en) 1997-08-08 2007-04-03 The Procter & Gamble Company Improved processes for making surfactants via adsorptive separation and products thereof
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IT1295300B1 (it) * 1997-10-09 1999-05-04 Agip Petroli Procedimento per l'idroisomerizzazione di n-paraffine a catena lunga e catalizzatore adatto allo scopo
EP1022326A1 (en) 1999-01-20 2000-07-26 The Procter & Gamble Company Hard surface cleaning compositions comprising modified alkylbenzene sulfonates
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US6773578B1 (en) 2000-12-05 2004-08-10 Chevron U.S.A. Inc. Process for preparing lubes with high viscosity index values
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FR2846664B1 (fr) * 2002-10-30 2006-09-08 Inst Francais Du Petrole Procede flexible de production de bases huiles et de distillats moyens avec une etape de pretraitement convertissant suivie d'un deparaffinage catalytique
FR2846574B1 (fr) * 2002-10-30 2006-05-26 Inst Francais Du Petrole Catalyseur et procede d'hydrocraquage de charges hydrocarbonees
US7815789B2 (en) 2003-06-23 2010-10-19 Shell Oil Company Process to prepare a lubricating base oil
ITMI20040798A1 (it) 2004-04-23 2004-07-23 Eni Spa Processo e catalizzatori per l'apertura di anelli naftenici
US20050274646A1 (en) * 2004-06-14 2005-12-15 Conocophillips Company Catalyst for hydroprocessing of Fischer-Tropsch products
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JP5442254B2 (ja) 2005-07-01 2014-03-12 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ ブライトストックブレンドの製造方法
ITMI20051295A1 (it) * 2005-07-08 2007-01-09 Eni Spa Processo per migliorare le qualita' come carburante di miscele idrocarburiche idrotrattate
ITMI20062193A1 (it) * 2006-11-15 2008-05-16 Eni Spa Processo per produrre frazioni idrocarburiche da miscele di origine biologica
ITMI20070522A1 (it) 2007-03-16 2008-09-17 Eni Spa Composizione idrocarburica utile come carburante e combustibile contenente una componente petrolifera e una componente di origine biologica
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EP2075314A1 (en) 2007-12-11 2009-07-01 Shell Internationale Research Maatschappij B.V. Grease formulations
CA2709982C (en) 2007-12-21 2016-01-26 Uop Llc Production of aviation fuel from biorenewable feedstocks
CN102105219B (zh) * 2008-05-22 2013-07-31 陶氏环球技术有限责任公司 二氧化硅承载催化剂上的金属铂及其制备方法
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IT1392194B1 (it) 2008-12-12 2012-02-22 Eni Spa Processo per la produzione di idrocarburi, utili per autotrazione, da miscele di origine biologica
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Also Published As

Publication number Publication date
US5968344A (en) 1999-10-19
IT1256084B (it) 1995-11-27
US5602292A (en) 1997-02-11
GR3021322T3 (en) 1997-01-31
EP0582347A1 (en) 1994-02-09
ATE142906T1 (de) 1996-10-15
DE69304840D1 (de) 1996-10-24
JP4103053B2 (ja) 2008-06-18
DK0582347T3 (es) 1997-02-24
DE69304840T2 (de) 1997-03-20
US5767038A (en) 1998-06-16
EP0582347B1 (en) 1996-09-18
ITMI921895A0 (it) 1992-07-31
JPH06170226A (ja) 1994-06-21
ITMI921895A1 (it) 1994-01-31

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