ES2091072T3 - Catalizador estructurado, consistente en oxidos microporosos de silicio, aluminio y titanio. - Google Patents

Catalizador estructurado, consistente en oxidos microporosos de silicio, aluminio y titanio.

Info

Publication number
ES2091072T3
ES2091072T3 ES94110328T ES94110328T ES2091072T3 ES 2091072 T3 ES2091072 T3 ES 2091072T3 ES 94110328 T ES94110328 T ES 94110328T ES 94110328 T ES94110328 T ES 94110328T ES 2091072 T3 ES2091072 T3 ES 2091072T3
Authority
ES
Spain
Prior art keywords
titanium
silicon
aluminum
structured catalyst
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94110328T
Other languages
English (en)
Other versions
ES2091072T5 (es
Inventor
Georg Dr Thiele
Eckehart Dr Roland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25927603&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2091072(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Degussa GmbH filed Critical Degussa GmbH
Publication of ES2091072T3 publication Critical patent/ES2091072T3/es
Application granted granted Critical
Publication of ES2091072T5 publication Critical patent/ES2091072T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C249/04—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of oximes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/60—Synthesis on support
    • B01J2229/62—Synthesis on support in or on other molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN CATALIZADOR, COMPUESTO DE OXIDOS DE SILICIO, ALUMINIO Y TITANIO, CARACTERIZADO PORQUE LAS PARTICULAS DEL CATALIZADOR SON CONSTITUIDAS A PARTIR DE UN NUCLEO DE LA COMPOSICION (SIO2)X(AIO2)YMY CON X/Y = 10 Y M = H, NA, K, NH4, NR4, DONDE R = C 1 BIERTA DE LA COMPOSICION (SIO2)N(TIO2)M CON N/M = 12 TANTO EL NUCLEO COMO LA CUBIERTA POSEEN UNA ESTRUCTURA CRISTALINA DEL TIPO MFI O MEL. PUEDE SER ELABORADO DE TAL MODO, QUE EN UN CAMINO CONOCIDO SE ELABORA UN GEL DE SINTESIS PARA LA FABRICACION DE UN SILICALITO DE TITANIO, EN ESTE GEL DE SINTESIS SE INTRODUCE UN SILICATO DE ALUMINIO DEL TIPO DE ESTRUCTURA MFI O MEL Y EL GEL DE SINTESIS SE ELABORA DE FORMA CONOCIDA.
ES94110328T 1993-07-12 1994-07-02 Catalizador estructurado, consistente en oxidos microporosos de silicio, aluminio y titanio. Expired - Lifetime ES2091072T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4323255 1993-07-12
DE4419195A DE4419195A1 (de) 1993-07-12 1994-06-01 Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan

Publications (2)

Publication Number Publication Date
ES2091072T3 true ES2091072T3 (es) 1996-10-16
ES2091072T5 ES2091072T5 (es) 1999-12-16

Family

ID=25927603

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94110328T Expired - Lifetime ES2091072T5 (es) 1993-07-12 1994-07-02 Catalizador estructurado, consistente en oxidos microporosos de silicio, aluminio y titanio.

Country Status (8)

Country Link
US (3) US5525563A (es)
EP (1) EP0634212B2 (es)
JP (1) JP2872047B2 (es)
KR (1) KR970010334B1 (es)
AT (1) ATE139142T1 (es)
DE (2) DE4419195A1 (es)
ES (1) ES2091072T5 (es)
TW (1) TW409072B (es)

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DE69426907T2 (de) * 1993-08-11 2001-09-27 Mitsubishi Gas Chemical Co., Inc. Titanosilikate Katalysatorteilchen
FR2730722B1 (fr) * 1995-02-17 1997-04-30 Rhone Poulenc Chimie Zeolithe ti-beta a haute teneur en silice, son procede de preparation et son utilisation comme catalyseur d'oxydation
DE19545042A1 (de) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung
DE19624340A1 (de) * 1996-06-19 1998-01-08 Degussa Verfahren zur Herstellung von kristallinen mikro- und mesoporösen Metallsilicaten, verfahrensgemäß erhältliche Produkte und deren Verwendung
DE19723751A1 (de) * 1997-06-06 1998-12-10 Basf Ag Formkörper und Verfahren zu dessen Herstellung
DE19731627A1 (de) * 1997-07-23 1999-01-28 Degussa Granulate, enthaltend Titansilikalit-l
IL136124A0 (en) * 1997-11-14 2001-05-20 Du Pont Pharm Co Process for the selective oxidation of organic compounds
EP1044196A2 (en) * 1997-11-24 2000-10-18 E.I. Du Pont De Nemours And Company Process for the selective oxidation of organic compounds
AU1620299A (en) 1997-12-03 1999-06-16 Exxon Chemical Patents Inc. Catalyst comprising a zeolite partially coated with a second zeolite, its use for hydrocarbon conversion
GB9812235D0 (en) 1998-06-08 1998-08-05 Exxon Chemical Patents Inc Oxidation process
EP1129991A1 (de) * 2000-03-02 2001-09-05 Degussa AG Verfahren zur Herstellung eines titanhaltigen Zeolithen
EP1129992A1 (de) * 2000-03-02 2001-09-05 Degussa AG Verfahren zur Herstellung eines titanhaltigen Zeolithen
EP1138386A1 (de) * 2000-03-29 2001-10-04 Degussa AG Verfahren zur Herstellung eines Titansilicalitformkörpers
EP1138387A1 (de) 2000-03-29 2001-10-04 Degussa AG Verfahren zur Herstellung eines Titansilicalitformkörpers
DE10047435A1 (de) * 2000-09-26 2002-04-11 Degussa Verfahren zur Herstellung von Oximen
JP3747239B2 (ja) * 2001-02-28 2006-02-22 独立行政法人産業技術総合研究所 プロピレンオキシドの製造方法
ITMI20011363A1 (it) * 2001-06-28 2002-12-28 Enichem Spa Procedimento per l'attivazione di catalizzatori zeolitici contenenti titanio e loro impiego nelle reazioni di ossidazione
DE10142620A1 (de) 2001-08-31 2003-03-20 Degussa Ammoximation von Ketonen und Aufarbeitung durch Pervaporation/Dampfpermeation
DE10142621A1 (de) 2001-08-31 2003-03-20 Degussa Aufarbeitung der Ammoximationsprodukte von Ketonen durch Flüssig-Flüssig-Extraktion in einem ternären Lösemittelsystem
US20030091504A1 (en) * 2001-11-15 2003-05-15 Gary Pasquale Method for controlling synthesis conditions during molecular sieve synthesis using combinations of quaternary ammonium hydroxides and halides
US7408080B2 (en) * 2002-05-31 2008-08-05 China Petroleum & Chemical Corporation Process for ammoximation of carbonyl compounds
JP4837280B2 (ja) * 2004-12-28 2011-12-14 日揮触媒化成株式会社 コアセル型ゼオライト成型体
US8198479B2 (en) * 2005-02-17 2012-06-12 Monsanto Technology Llc Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts
WO2007098432A2 (en) * 2006-02-17 2007-08-30 Monsanto Technology Llc Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts
US8575055B2 (en) * 2010-03-30 2013-11-05 Uop Llc Surface-modified zeolites and methods for preparing the same
CN102441430B (zh) * 2010-10-11 2013-06-12 中国石油化工股份有限公司 一种催化剂及其制备方法和环氧化烯烃的方法
JP2012106967A (ja) * 2010-11-19 2012-06-07 Sumitomo Chemical Co Ltd 酸化オレフィンの製造方法
FR2987046B1 (fr) * 2012-02-17 2014-03-21 Rhodia Operations Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation
CN104549193B (zh) * 2015-01-08 2016-06-08 常州大学 一种低密度TiO2/SiO2复合微球及其制备方法
US10508032B2 (en) * 2015-03-20 2019-12-17 Northwestern University Catalysts and related methods for photocatalytic production of H2O2 and thermocatalytic reactant oxidation
CN105693551A (zh) * 2016-03-23 2016-06-22 华东师范大学 一种分子筛催化合成环己酮肟的方法
CN109593033B (zh) * 2017-09-30 2022-01-04 中国石油化工股份有限公司 一种环己酮氧化的方法
WO2020038222A1 (en) * 2018-08-24 2020-02-27 Rhodia Operations A microporous aluminotitanosilicate crystalline zeolite, method of preparation and applications thereof
CN111924854B (zh) * 2020-08-21 2023-03-10 华东师范大学 一种ecnu-29钛铝硅酸盐纳米片及其制备方法和应用
CN115155599B (zh) * 2022-04-11 2023-07-25 浙江氢邦科技有限公司 一种包覆Ni-In@SiO2-Al2O3的中空介孔纳米催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
JPH07148432A (ja) 1995-06-13
DE59400346D1 (de) 1996-07-18
JP2872047B2 (ja) 1999-03-17
EP0634212B1 (de) 1996-06-12
US5525563A (en) 1996-06-11
DE4419195A1 (de) 1995-01-19
ATE139142T1 (de) 1996-06-15
TW409072B (en) 2000-10-21
KR970010334B1 (ko) 1997-06-25
EP0634212A1 (de) 1995-01-18
EP0634212B2 (de) 1998-12-16
US5637715A (en) 1997-06-10
US5756778A (en) 1998-05-26
ES2091072T5 (es) 1999-12-16

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