ES2086314T5 - Derivado de bisindenilo y un procedimiento para su obtencion. - Google Patents
Derivado de bisindenilo y un procedimiento para su obtencion.Info
- Publication number
- ES2086314T5 ES2086314T5 ES89123611T ES89123611T ES2086314T5 ES 2086314 T5 ES2086314 T5 ES 2086314T5 ES 89123611 T ES89123611 T ES 89123611T ES 89123611 T ES89123611 T ES 89123611T ES 2086314 T5 ES2086314 T5 ES 2086314T5
- Authority
- ES
- Spain
- Prior art keywords
- derivative
- procedure
- obtaining
- formula
- bisindenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000001455 metallic ions Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
EL INVENTO SE REFIERE A UN DERIVADO DE BISINDENILO DE FORMULA (I); TRATA DE UN PROCEDIMIENTO PARA LA OBTENCION DEL DERIVADO QUE CONSISTE EN TRATAR DE UN COMPUESTO DE FORMULA (II) CON UN EXCESO DE COMPUESTO DE FORMULA (III) O (IV); RESEÑA EL BUEN RENDIMIENTO DEL PROCESO DE PRODUCCION Y DESCRIBE LA APLICACION DEL DERIVADO COMO SUSTANCIA DE PARTIDA PARA LA PRODUCCION DE COMPONENTES CATALIZADORES CON IONES METALICOS. SIENDO: R6,R7 UN RESTO INDENILO SUSTITUIDO O NO SUSTITUIDO; M1 SI GE, Y HCL Y M2 METIL ALCALINO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3844282A DE3844282A1 (de) | 1988-12-30 | 1988-12-30 | Bisindenyl-derivat und verfahren zu seiner herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2086314T3 ES2086314T3 (es) | 1996-07-01 |
ES2086314T5 true ES2086314T5 (es) | 2001-01-01 |
Family
ID=6370497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES89123611T Expired - Lifetime ES2086314T5 (es) | 1988-12-30 | 1989-12-21 | Derivado de bisindenilo y un procedimiento para su obtencion. |
Country Status (8)
Country | Link |
---|---|
US (1) | US4985576A (es) |
EP (2) | EP0376154B2 (es) |
JP (1) | JP2825134B2 (es) |
AU (1) | AU615602B2 (es) |
CA (1) | CA2006905A1 (es) |
DE (2) | DE3844282A1 (es) |
ES (1) | ES2086314T5 (es) |
ZA (1) | ZA899945B (es) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5700896A (en) * | 1988-07-30 | 1997-12-23 | Hoechst Aktiengesellschaft | Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts |
DE59104869D1 (de) * | 1990-11-12 | 1995-04-13 | Hoechst Ag | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation. |
US5157136A (en) * | 1991-04-09 | 1992-10-20 | Regents Of The University Of California | Single-source metalloorganic precursors to produce ii/vi materials |
US5466766A (en) * | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
ATE162529T1 (de) * | 1992-06-13 | 1998-02-15 | Hoechst Ag | Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl |
JPH06271594A (ja) * | 1993-03-22 | 1994-09-27 | Mitsui Petrochem Ind Ltd | シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法 |
US5486585A (en) * | 1993-08-26 | 1996-01-23 | Exxon Chemical Patents Inc. | Amidosilyldiyl bridged catalysts and method of polymerization using said catalysts. |
DE4402192A1 (de) * | 1994-01-26 | 1995-07-27 | Witco Gmbh | Verfahren zur Herstellung von Biscyclopentadienyl-Verbindungen |
US5473020A (en) * | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
US5616765A (en) * | 1996-02-12 | 1997-04-01 | The United States Of America As Represented By The Secretary Of The Air Force | Method for the preparation of 4-hydroxy-and 4-trimethylsiloxybenzocyclobutene |
US6015868A (en) * | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
US5900497A (en) * | 1996-12-20 | 1999-05-04 | Union Carbide Chemicals & Plsatics Technology Corporation | Process for preparing metallocene procatalysts |
AT405834B (de) | 1997-10-09 | 1999-11-25 | Borealis Ag | Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation |
US6417405B2 (en) | 1999-03-03 | 2002-07-09 | The Dow Chemical Company | Synthesis of cyclopentadiene or substituted cyclopentadiene compounds |
EP1159245A1 (en) | 1999-03-03 | 2001-12-05 | The Dow Chemical Company | Synthesis of 4-ketocyclopentene and cyclopentadiene compounds |
ATE336529T1 (de) | 2000-02-08 | 2006-09-15 | Exxonmobil Chem Patents Inc | Schlagzähe propylencopolymerisate |
AU2003283286A1 (en) * | 2002-10-25 | 2004-05-13 | Basell Polyolefine Gmbh | Racemoselective preparation of isolable ansa-metallocene biphenoxide complexes |
US7285608B2 (en) * | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3139448A (en) * | 1961-10-31 | 1964-06-30 | Ici Ltd | Chlorophenyl substituted di-and trisilaalkanes |
NL8102268A (nl) * | 1980-05-30 | 1981-12-16 | Tno | Germaniumverbindingen, werkwijze voor het bereiden daarvan, werkwijze voor het bereiden van een geneesmiddel met toepassing van een derglijke germaniumverbinding voor de behandeling van kanker, alsmede aldus verkregen gevormd geneesmiddel. |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
FR2599369B1 (fr) * | 1986-05-30 | 1989-03-31 | Europ Propulsion | Procede de preparation de disilylmethanes |
DE3784199D1 (de) * | 1986-08-01 | 1993-03-25 | Ciba Geigy Ag | Titanocene und deren verwendung. |
ES2082745T3 (es) * | 1987-04-03 | 1996-04-01 | Fina Technology | Sistemas cataliticos metalocenos para la polimerizacion de las olefinas presentando un puente de hidrocarburo de silicio. |
DE3742934A1 (de) * | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
DE3743321A1 (de) * | 1987-12-21 | 1989-06-29 | Hoechst Ag | 1-olefinpolymerwachs und verfahren zu seiner herstellung |
IL89525A0 (en) * | 1988-03-21 | 1989-09-10 | Exxon Chemical Patents Inc | Silicon-bridged transition metal compounds |
-
1988
- 1988-12-30 DE DE3844282A patent/DE3844282A1/de not_active Withdrawn
-
1989
- 1989-12-21 ES ES89123611T patent/ES2086314T5/es not_active Expired - Lifetime
- 1989-12-21 DE DE58909631T patent/DE58909631D1/de not_active Expired - Fee Related
- 1989-12-21 EP EP89123611A patent/EP0376154B2/de not_active Expired - Lifetime
- 1989-12-21 EP EP95113494A patent/EP0692486A3/de not_active Withdrawn
- 1989-12-27 JP JP1336754A patent/JP2825134B2/ja not_active Expired - Fee Related
- 1989-12-28 ZA ZA899945A patent/ZA899945B/xx unknown
- 1989-12-29 AU AU47333/89A patent/AU615602B2/en not_active Ceased
- 1989-12-29 US US07/458,348 patent/US4985576A/en not_active Expired - Fee Related
- 1989-12-29 CA CA002006905A patent/CA2006905A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CA2006905A1 (en) | 1990-06-30 |
DE58909631D1 (de) | 1996-05-02 |
EP0376154B1 (de) | 1996-03-27 |
ES2086314T3 (es) | 1996-07-01 |
AU615602B2 (en) | 1991-10-03 |
JP2825134B2 (ja) | 1998-11-18 |
AU4733389A (en) | 1990-07-05 |
EP0376154B2 (de) | 2000-09-27 |
EP0376154A2 (de) | 1990-07-04 |
JPH02221285A (ja) | 1990-09-04 |
US4985576A (en) | 1991-01-15 |
DE3844282A1 (de) | 1990-07-05 |
ZA899945B (en) | 1990-09-26 |
EP0376154A3 (de) | 1991-04-03 |
EP0692486A3 (de) | 2003-03-26 |
EP0692486A2 (de) | 1996-01-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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