ES2085992T3 - Procedimiento de hidrogenacion catalitica en fase vapor de anhidrido maleico a la gamma-butirolactona con una conversion alta y una selectividad alta utilizando un catalizador activado. - Google Patents

Procedimiento de hidrogenacion catalitica en fase vapor de anhidrido maleico a la gamma-butirolactona con una conversion alta y una selectividad alta utilizando un catalizador activado.

Info

Publication number
ES2085992T3
ES2085992T3 ES91908530T ES91908530T ES2085992T3 ES 2085992 T3 ES2085992 T3 ES 2085992T3 ES 91908530 T ES91908530 T ES 91908530T ES 91908530 T ES91908530 T ES 91908530T ES 2085992 T3 ES2085992 T3 ES 2085992T3
Authority
ES
Spain
Prior art keywords
maleic anhydride
gamma
catalytic hydrogenation
weight
activated catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91908530T
Other languages
English (en)
Inventor
Paul D Taylor
Thomas Waldo De
Donald W Buchanan Jr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISP Investments LLC
Original Assignee
ISP Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ISP Investments LLC filed Critical ISP Investments LLC
Application granted granted Critical
Publication of ES2085992T3 publication Critical patent/ES2085992T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)

Abstract

LA HIDROGENACION CATALITICA EN FASE VAPOR DE ANHIDRIDO MALEICO A GAMMA DE 95 % O MAS Y UNA SELECTIVIDAD DE 80 % O MAS DURANTE UN PERIODO PROLONGADO DE PRODUCCION. EL PROCESO DEL INVENTO USA UN CATALIZADOR ACTIVADO PREPARADO REDUCIENDO UNA COMPOSICION CATALITICA QUE CONTIENE EN 30 PESO DE ZNO Y UN 8 CTIVANDO LA COMPOSICION CATALITICA REDUCIDA EN HIDROGENO A UNA TEMPERATURA DE ACTIVACION DE AL MENOS 400 ENTRE 400 DE HIDROGENACION SE LLEVA A CABO BAJO UNAS CONDICIONES DE PROCESO PREDETERMINADAS Y VENTAJOSAS, INCLUYENDO UNA RELACION MOLAR DEFINIDA DEL HIDROGENO AL ANHIDRIDO MALEICO EN LA CORRIENTE DE VAPOR REACTIVO, UNA PRESION SELECCIONADA DURANTE LA HIDROGENACION, UNA RELACION DE ALIMENTACION VELOCIDAD ESPACIAL VENTAJOSA, UN PERIODO DE CONTACTO PREDETERMINADO, Y UNA TEMPERATURA DE REACCION ADECUADA.
ES91908530T 1990-04-16 1991-04-08 Procedimiento de hidrogenacion catalitica en fase vapor de anhidrido maleico a la gamma-butirolactona con una conversion alta y una selectividad alta utilizando un catalizador activado. Expired - Lifetime ES2085992T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US52106590A 1990-04-16 1990-04-16
US07/656,388 US5347021A (en) 1990-04-16 1991-02-19 Process of vapor phase catalytic hydrogenation of maleic anhydride to gamma-butyrolactone in high conversion and high selectivity using an activated catalyst

Publications (1)

Publication Number Publication Date
ES2085992T3 true ES2085992T3 (es) 1996-06-16

Family

ID=27060363

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91908530T Expired - Lifetime ES2085992T3 (es) 1990-04-16 1991-04-08 Procedimiento de hidrogenacion catalitica en fase vapor de anhidrido maleico a la gamma-butirolactona con una conversion alta y una selectividad alta utilizando un catalizador activado.

Country Status (10)

Country Link
US (1) US5347021A (es)
EP (1) EP0593458B1 (es)
JP (1) JPH05505975A (es)
AT (1) ATE135938T1 (es)
AU (1) AU642250B2 (es)
CA (1) CA2080123A1 (es)
DE (1) DE69118404T2 (es)
DK (1) DK0593458T3 (es)
ES (1) ES2085992T3 (es)
WO (1) WO1991016132A1 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1273320B (it) * 1994-02-22 1997-07-08 Alusuisse Italia Spa Procedimento per la produzione di gamma-butirrolattone
US5637735A (en) * 1994-08-10 1997-06-10 China Petrochemical Corporation Process for the preparation of gamma-butyrolactone
TW341568B (en) * 1995-12-27 1998-10-01 Akzo Nobel Nv Process for manufacturing Gamma-butyrolactone and its use
ZA973971B (en) * 1996-05-15 1998-03-23 Kvaerner Process Tech Ltd A process for the production of at least one C4 compound selected from butane-1,4-diol, gamma-butyrolactone and tetrahydrofuran.
KR100464621B1 (ko) * 1996-12-30 2005-04-06 에스케이 주식회사 감마부티로락톤(r-Butyrolactone)의제조방법
JP4096128B2 (ja) * 1997-08-21 2008-06-04 大阪瓦斯株式会社 脱硫剤の製造方法および炭化水素の脱硫方法
GB9724195D0 (en) 1997-11-14 1998-01-14 Kvaerner Process Tech Ltd Process
IT1298096B1 (it) * 1998-01-09 1999-12-20 Lonza Spa Procedimento per la produzione di gamma-butirrolattone
IT1298535B1 (it) 1998-02-02 2000-01-12 Lonza Spa Procedimento per la produzione di gamma-butirrolattone
EP0962438B1 (en) 1998-03-23 2001-06-06 Basf Aktiengesellschaft Process for the preparation of 1,4-butanediol, butyrolactone and tetrahydrofuran.
DE10061558A1 (de) 2000-12-11 2002-06-13 Basf Ag Verfahren zur Hydrierung von Maleinsäureanhydrid und verwandten Verbindungen in einem Wirbelschichtreaktor
US6603021B2 (en) * 2001-06-18 2003-08-05 Battelle Memorial Institute Methods of making pyrrolidones
KR100457066B1 (ko) * 2002-04-22 2004-11-12 애경유화 주식회사 수소화 반응촉매 및 그의 제조방법, 및 이 촉매를이용하여 무수말레인산으로부터 감마-부티로락톤을제조하는 방법
DE10219224A1 (de) * 2002-04-30 2003-11-13 Basf Ag Verfahren zur Herstellung von gamma-Butyrolacton
DE10225927A1 (de) 2002-06-11 2003-12-24 Basf Ag Verfahren zur Herstellung von Butandiol durch kombinierte Gasphasen- und Flüssigphasensynthese
DE10225929A1 (de) 2002-06-11 2003-12-24 Basf Ag Zweistufiges Verfahren zur Herstellung von Butandiol mit Zwischenabtrennung von Bernsteinsäureanhydrid
DE10225926A1 (de) 2002-06-11 2003-12-24 Basf Ag Verfahren zur Herstellung von Butandiol
US7199250B2 (en) * 2002-12-20 2007-04-03 Battelle Memorial Institute Process for producing cyclic compounds
DE10357717A1 (de) * 2003-12-09 2005-07-14 Basf Ag Katalysatorextrudate auf Basis Kupferoxid und ihre Verwendung zur Hydrierung von Carbonylverbindungen
CN102781901B (zh) 2010-02-11 2016-08-03 梅塔玻利克斯公司 用于从经遗传修饰的聚羟基链烷酸酯生物质制备单体组分的方法
EP2742143A1 (en) 2011-08-10 2014-06-18 Metabolix, Inc. Post process purification for gamma-butyrolactone production
CN103044367B (zh) * 2011-10-17 2014-12-31 中国石油化工股份有限公司 一种γ-丁内酯的生产方法

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US2334100A (en) * 1940-10-19 1943-11-09 Universal Oil Prod Co Hydrogenation of ketones
US3388972A (en) * 1966-12-14 1968-06-18 Catalysts & Chemicals Inc Low temperature shift reaction catalysts and methods for their preparation
DE1668348A1 (de) * 1966-12-29 1972-03-30 Kao Corp Verfahren zur Herstellung von gamma-Butyrolacton
AU428299B2 (en) * 1968-04-08 1972-09-20 Catalysts And Chemicals Inc Activation of low temperature shift catalysts
US3614497A (en) * 1970-03-25 1971-10-19 Westinghouse Electric Corp Transposed conductor for dynamoelectric machines
SU596278A1 (ru) * 1976-05-03 1978-03-05 Предприятие П/Я Р-6603 Способ приготовлени катализатора дл конверсии окиси углерода
DE3005551A1 (de) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
NL8103173A (nl) * 1981-07-02 1983-02-01 Stamicarbon Werkwijze voor de bereiding van een 5-alkyl-butyrolacton.
GB2109263A (en) * 1981-10-20 1983-06-02 Ammonia Casale Sa A catalyst and processes for making and using the catalyst
US4477594A (en) * 1982-12-16 1984-10-16 Chem Systems, Inc. Process for the synthesis of aliphatic alcohol-containing mixtures
FR2558738B1 (fr) * 1984-01-27 1987-11-13 Inst Francais Du Petrole Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
US4801574A (en) * 1987-12-02 1989-01-31 Air Products And Chemicals, Inc. In-situ activation of CuO/ZnO/Al2 O3 catalysts in the liquid phase
CA1327812C (en) * 1987-12-23 1994-03-15 Thomas G. Attig Vapor-phase hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone

Also Published As

Publication number Publication date
ATE135938T1 (de) 1996-04-15
EP0593458A1 (en) 1994-04-27
EP0593458A4 (en) 1993-03-15
WO1991016132A1 (en) 1991-10-31
US5347021A (en) 1994-09-13
JPH05505975A (ja) 1993-09-02
AU7657691A (en) 1991-11-11
DE69118404D1 (de) 1996-05-02
AU642250B2 (en) 1993-10-14
CA2080123A1 (en) 1991-10-17
DE69118404T2 (de) 1996-09-19
DK0593458T3 (da) 1996-07-08
EP0593458B1 (en) 1996-03-27

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