ES2059039T5 - Procedimiento para la fabricacion de carbonato de dimetilo. - Google Patents

Procedimiento para la fabricacion de carbonato de dimetilo.

Info

Publication number
ES2059039T5
ES2059039T5 ES91201269T ES91201269T ES2059039T5 ES 2059039 T5 ES2059039 T5 ES 2059039T5 ES 91201269 T ES91201269 T ES 91201269T ES 91201269 T ES91201269 T ES 91201269T ES 2059039 T5 ES2059039 T5 ES 2059039T5
Authority
ES
Spain
Prior art keywords
dimethyl carbonate
water
mixture
methanol
carbon monoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91201269T
Other languages
English (en)
Other versions
ES2059039T3 (es
Inventor
Muzio Nicola Di
Carlo Fusi
Franco Rivetti
Giacomo Sasselli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enichem SpA
Original Assignee
Enichem SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11168341&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2059039(T5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Enichem SpA filed Critical Enichem SpA
Application granted granted Critical
Publication of ES2059039T3 publication Critical patent/ES2059039T3/es
Publication of ES2059039T5 publication Critical patent/ES2059039T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00Preparation of esters of carbonic or haloformic acids
    • C07C68/01Preparation of esters of carbonic or haloformic acids from carbon monoxide and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

EL CARBONATO DE DIMETILO SE PREPARA POR MEDIO DE UN PROCESO CONTINUO: * INTRODUCIENDO, EN UNA CAMARA DE REACCION, MONOXIDO DE CARBONO Y OXIGENO, PARA UNA MEZCLA DE REACCION LIQUIDA CON UN VOLUMEN Y UNA COMPOSICION EN GRAN MEDIDA CONSTANTES, CONTENIENDO METANOL, CARBONATO DE DIMETILO, AGUA, Y UN CATALIZADOR DE COBRE; * VAPORIZANDO DE LA MEZCLA DE REACCION UNA CORRIENTE DE METANOL, AGUA Y CARBONATO DE DIMETILO, QUE SE DESARROLLA JUNTO CON LA CORRIENTE GASEOSA QUE CONTIENE MONOXIDO DE CARBONO; Y * RECUPERANDO AGUA Y CARBONATO DE DIMETILO DE DICHA MEZCLA VAPORIZADA, EN CANTIDADES IGUALES, EN GRAN MEDIDA, A LAS RESPECTIVAS CANTIDADES DEL MISMO QUE SE FORMAN EN LA CAMARA DE REACCION Y RECICLANDO LOS DEMAS COMPONENTES. ESTE PROCESO, QUE SE CARACTERIZA FUNDAMENTALMENTE POR QUE EN LA MEZCLA DE REACCION LIQUIDA SE MANTIENEN UNA CONCENTRACION DE METANOL Y AGUA QUE SON RESPECTIVAMENTE IGUALES O SUPERIORES AL 30% POR PESO, Y IGUALES O INFERIORES AL 10% POR PESO, HACE POSIBLE OBTENER EL CARBONATO DE DIMETILO CON UNA PRODUCTIVIDAD MEJORADA.
ES91201269T 1990-06-04 1991-05-28 Procedimiento para la fabricacion de carbonato de dimetilo. Expired - Lifetime ES2059039T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT02053090A IT1248686B (it) 1990-06-04 1990-06-04 Procedimento per la produzione di dimetil carbonato

Publications (2)

Publication Number Publication Date
ES2059039T3 ES2059039T3 (es) 1994-11-01
ES2059039T5 true ES2059039T5 (es) 1997-10-01

Family

ID=11168341

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91201269T Expired - Lifetime ES2059039T5 (es) 1990-06-04 1991-05-28 Procedimiento para la fabricacion de carbonato de dimetilo.

Country Status (12)

Country Link
US (1) US5210269A (es)
EP (1) EP0460732B2 (es)
JP (1) JP3094241B2 (es)
KR (1) KR930010407B1 (es)
AT (1) ATE108432T1 (es)
CA (1) CA2043743C (es)
DE (1) DE69102826T3 (es)
DK (1) DK0460732T3 (es)
ES (1) ES2059039T5 (es)
GR (1) GR3024259T3 (es)
IT (1) IT1248686B (es)
MX (1) MX173385B (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1251853B (it) * 1991-09-23 1995-05-26 Enichem Sintesi Procedimento per la produzione di carbonati alchilici
US5183920A (en) * 1992-01-13 1993-02-02 The Dow Chemical Company Integrated process for the production of dimethyl carbonate
DE4203796A1 (de) * 1992-02-10 1993-08-12 Bayer Ag Verfahren zur herstellung von dialkylcarbonaten
KR940003917A (ko) * 1992-08-20 1994-03-14 고지마 아끼로 반응 제어방법
DE4339977A1 (de) * 1993-11-24 1995-06-01 Bayer Ag Verfahren zur Aufarbeitung der flüssigen Reaktionsprodukte aus der Cu-katalysierten Dimethylcarbonatherstellung
DE4403075A1 (de) * 1994-02-02 1995-08-03 Bayer Ag Verfahren zur kontinuierlichen Herstellung von Diarylcarbonaten
IT1269916B (it) * 1994-03-25 1997-04-16 Enichem Spa Procedimento migliorato per la sintesi di dimetilcarbonato
IT1269884B (it) * 1994-06-03 1997-04-15 Enichem Sintesi Metodo per la rimozione dei contaminanti acidi e salini dalla fase condensata dell'effluente di reazione in un processo per la sintesi di dimetilcarbonato
IT1269883B (it) 1994-06-03 1997-04-15 Enichem Sintesi Metodo per la rimozione dei contaminanti acidi contenuti in una corrente vaporizzata composta da vapori organici e acqua
DE19523390A1 (de) * 1995-06-23 1997-01-09 Bayer Ag Verfahren zur Herstellung von Diarylcarbonaten
US6280519B1 (en) * 1998-05-05 2001-08-28 Exxon Chemical Patents Inc. Environmentally preferred fluids and fluid blends
US6818049B1 (en) 1998-05-05 2004-11-16 Exxonmobil Chemical Patents Inc. Environmentally preferred fluids and fluid blends
US6294684B1 (en) 1999-12-08 2001-09-25 General Electric Company Method and apparatus for the continuous production of diaryl carbonates
JP3799968B2 (ja) 2000-06-16 2006-07-19 東海ゴム工業株式会社 耐久性に優れた防振ゴムの製造方法
US6420589B1 (en) 2000-12-14 2002-07-16 General Electric Company Process for the production of diaryl carbonates
US6384262B1 (en) 2000-12-14 2002-05-07 General Electric Company Process for the production of diaryl carbonates
US6521777B2 (en) 2000-12-14 2003-02-18 General Electric Company Process for the production of diaryl carbonates
US6441215B1 (en) 2001-06-06 2002-08-27 General Electric Company Method for reducing carbonate decomposition in reaction mixtures
US7084292B2 (en) 2001-06-22 2006-08-01 Exxonmobil Chemical Patents Inc. Integrated process for preparing dialkyl carbonates with a circulating catalyst
US6774256B2 (en) 2001-06-22 2004-08-10 Exxonmobil Chemical Patents Inc. Low corrosive integrated process for preparing dialkyl carbonates
US7345187B2 (en) 2001-08-14 2008-03-18 General Electric Company Method and apparatus for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
US6784277B2 (en) 2001-08-14 2004-08-31 General Electric Company Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
US7514521B2 (en) 2001-08-14 2009-04-07 Sabic Innovative Plastics Ip B.V. Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
US6903049B2 (en) * 2002-02-25 2005-06-07 General Electric Company Method and catalyst composition for producing aromatic carbonates using activating solvents
US6977308B2 (en) 2002-06-25 2005-12-20 General Electric Company Method and apparatus for preparing a dialkyl carbonate
US7718564B2 (en) * 2005-06-24 2010-05-18 Exxonmobil Research And Engineering Company Partially decomposed catalyst and hydrocarbon oxidation processes using the same
US7622602B2 (en) 2005-10-12 2009-11-24 Sabic Innovative Plastics Ip B.V. Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates
TW200831458A (en) 2007-01-17 2008-08-01 China Petrochemical Dev Corp The manufacturing method of dialkyl carbonate
TW200846319A (en) 2007-05-28 2008-12-01 China Petrochemical Dev Corp Method for preparing carbonate diester
US9249082B2 (en) * 2010-02-09 2016-02-02 King Abdulaziz City for Science and Technology (KACST) Synthesis of dimethyl carbonate from carbon dioxide and methanol
CN102941114A (zh) * 2012-11-08 2013-02-27 江南大学 用于氧化羰基合成碳酸二乙酯的复合分子筛催化剂及其制备方法
CN112439405B (zh) * 2020-12-21 2022-03-11 中国科学院山西煤炭化学研究所 一种甲醇、二氧化碳和2-氰基吡啶制备碳酸二甲酯的催化剂及其制法和应用
CN116751124B (zh) * 2023-08-17 2023-10-24 太原理工大学 一种甲醇氧化羰基化合成电子级碳酸二甲酯工艺

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA923139A (en) * 1970-03-04 1973-03-20 Snamprogetti S.P.A. Process for the preparation of esters of the carbonic acid
US4360477A (en) * 1981-11-09 1982-11-23 General Electric Company Carbonylation of alkanols
GB8321199D0 (en) * 1983-08-05 1983-09-07 Ici Plc Carbonate production
IT1227183B (it) * 1988-10-19 1991-03-21 Enichem Sintesi Procedimento in continuo per la preparazione di di alchil carbonati
DE3926709A1 (de) * 1989-08-12 1991-02-14 Basf Ag Verfahren zur herstellung von dialkylcarbonaten

Also Published As

Publication number Publication date
CA2043743C (en) 2001-10-23
KR930010407B1 (ko) 1993-10-23
DK0460732T3 (da) 1994-09-12
IT9020530A0 (es) 1990-06-04
ES2059039T3 (es) 1994-11-01
MX173385B (es) 1994-02-24
IT9020530A1 (it) 1991-12-04
EP0460732A1 (en) 1991-12-11
DE69102826T3 (de) 1998-08-27
JPH04270250A (ja) 1992-09-25
DE69102826T2 (de) 1995-02-23
ATE108432T1 (de) 1994-07-15
IT1248686B (it) 1995-01-26
US5210269A (en) 1993-05-11
DE69102826D1 (de) 1994-08-18
CA2043743A1 (en) 1991-12-05
EP0460732B2 (en) 1997-07-23
JP3094241B2 (ja) 2000-10-03
GR3024259T3 (en) 1997-10-31
KR920000675A (ko) 1992-01-29
EP0460732B1 (en) 1994-07-13

Similar Documents

Publication Publication Date Title
ES2059039T5 (es) Procedimiento para la fabricacion de carbonato de dimetilo.
MX174018B (es) Composiciones generadoras de gas que contienen nitrotriazolona
ES2031973T3 (es) Produccion de hidrogeno y monoxido de carbono.
ES2064912T3 (es) Procedimiento para producir acido isoftalico de elevada pureza.
SE8008501L (sv) Sett att framstella dimetylkarbonat under anrikning av vete i bildad syntesgas
BR9801464A (pt) Processo para produzir hidrogênio gasoso
ES2061189T3 (es) Procedimiento para producir hidrogeno de alta pureza.
GB1464347A (en) Synthesis gas production by partial oxidation
ES2080997T3 (es) Proceso continuo para preparar carbonato de dimetilo.
MX169059B (es) Extraccion selectiva de argon de una corriente de recirculacion de oxido de etileno
ES454790A1 (es) Procedimiento para la preparacion de 4,4'-isopropilidon-bis (2,6-dibromofenol) puro.
SE8504439D0 (sv) Sett att framstella en ren, koloxid och vetgas innehallande gas
Reeves Jr et al. Photochemical equilibrium studies of carbon dioxide and their significance for the Venus atmosphere
AU576293B2 (en) Recovering sulphur from gas streams containing hydrogen sulphide
Moortgat et al. Photolysis of formaldehyde: relative quantum yields of H2 and CO in the wavelength range 270–360 nm
Asmus et al. Radical cation complexes in the oxidation of organic di-, tri-, and tetrathia compounds in hydrocarbon solutions
MX168358B (es) Procedimiento de oxidacion parcial
IT1247909B (it) Procedimento continuo integrato per la produzione di dimetil carbonato e metil ter-butil etere
Wampler The SO2 (3B1) photosensitized isomerization of cis‐and trans‐1, 2‐difluoroethylene
Ando et al. Novel adducts of sulfides and 4-substituted 1, 2, 4-triazoline-3, 5-diones (TAD) A similarity of TAD and singlet oxygen (1O2)
Perito et al. Magnetic field effects on the catalytic oxidation of 2, 6-di-tert-butylphenol by CoSMDPT: Deuterium and oxygen-17 magnetic isotope effects
GB1178515A (en) Generating Reducing Gas
GB1240081A (en) A process for scrubbing fuel and synthesis gases
US3189556A (en) Novel catalyst for the preparation of acetaldehyde from acetylene
GB1044764A (en) Improvements in and relating to the production of acetylene

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 460732

Country of ref document: ES