ES2059039T5 - Procedimiento para la fabricacion de carbonato de dimetilo. - Google Patents
Procedimiento para la fabricacion de carbonato de dimetilo.Info
- Publication number
- ES2059039T5 ES2059039T5 ES91201269T ES91201269T ES2059039T5 ES 2059039 T5 ES2059039 T5 ES 2059039T5 ES 91201269 T ES91201269 T ES 91201269T ES 91201269 T ES91201269 T ES 91201269T ES 2059039 T5 ES2059039 T5 ES 2059039T5
- Authority
- ES
- Spain
- Prior art keywords
- dimethyl carbonate
- water
- mixture
- methanol
- carbon monoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/01—Preparation of esters of carbonic or haloformic acids from carbon monoxide and oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
EL CARBONATO DE DIMETILO SE PREPARA POR MEDIO DE UN PROCESO CONTINUO: * INTRODUCIENDO, EN UNA CAMARA DE REACCION, MONOXIDO DE CARBONO Y OXIGENO, PARA UNA MEZCLA DE REACCION LIQUIDA CON UN VOLUMEN Y UNA COMPOSICION EN GRAN MEDIDA CONSTANTES, CONTENIENDO METANOL, CARBONATO DE DIMETILO, AGUA, Y UN CATALIZADOR DE COBRE; * VAPORIZANDO DE LA MEZCLA DE REACCION UNA CORRIENTE DE METANOL, AGUA Y CARBONATO DE DIMETILO, QUE SE DESARROLLA JUNTO CON LA CORRIENTE GASEOSA QUE CONTIENE MONOXIDO DE CARBONO; Y * RECUPERANDO AGUA Y CARBONATO DE DIMETILO DE DICHA MEZCLA VAPORIZADA, EN CANTIDADES IGUALES, EN GRAN MEDIDA, A LAS RESPECTIVAS CANTIDADES DEL MISMO QUE SE FORMAN EN LA CAMARA DE REACCION Y RECICLANDO LOS DEMAS COMPONENTES. ESTE PROCESO, QUE SE CARACTERIZA FUNDAMENTALMENTE POR QUE EN LA MEZCLA DE REACCION LIQUIDA SE MANTIENEN UNA CONCENTRACION DE METANOL Y AGUA QUE SON RESPECTIVAMENTE IGUALES O SUPERIORES AL 30% POR PESO, Y IGUALES O INFERIORES AL 10% POR PESO, HACE POSIBLE OBTENER EL CARBONATO DE DIMETILO CON UNA PRODUCTIVIDAD MEJORADA.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT02053090A IT1248686B (it) | 1990-06-04 | 1990-06-04 | Procedimento per la produzione di dimetil carbonato |
Publications (2)
Publication Number | Publication Date |
---|---|
ES2059039T3 ES2059039T3 (es) | 1994-11-01 |
ES2059039T5 true ES2059039T5 (es) | 1997-10-01 |
Family
ID=11168341
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91201269T Expired - Lifetime ES2059039T5 (es) | 1990-06-04 | 1991-05-28 | Procedimiento para la fabricacion de carbonato de dimetilo. |
Country Status (12)
Country | Link |
---|---|
US (1) | US5210269A (es) |
EP (1) | EP0460732B2 (es) |
JP (1) | JP3094241B2 (es) |
KR (1) | KR930010407B1 (es) |
AT (1) | ATE108432T1 (es) |
CA (1) | CA2043743C (es) |
DE (1) | DE69102826T3 (es) |
DK (1) | DK0460732T3 (es) |
ES (1) | ES2059039T5 (es) |
GR (1) | GR3024259T3 (es) |
IT (1) | IT1248686B (es) |
MX (1) | MX173385B (es) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1251853B (it) * | 1991-09-23 | 1995-05-26 | Enichem Sintesi | Procedimento per la produzione di carbonati alchilici |
US5183920A (en) * | 1992-01-13 | 1993-02-02 | The Dow Chemical Company | Integrated process for the production of dimethyl carbonate |
DE4203796A1 (de) * | 1992-02-10 | 1993-08-12 | Bayer Ag | Verfahren zur herstellung von dialkylcarbonaten |
KR940003917A (ko) * | 1992-08-20 | 1994-03-14 | 고지마 아끼로 | 반응 제어방법 |
DE4339977A1 (de) * | 1993-11-24 | 1995-06-01 | Bayer Ag | Verfahren zur Aufarbeitung der flüssigen Reaktionsprodukte aus der Cu-katalysierten Dimethylcarbonatherstellung |
DE4403075A1 (de) * | 1994-02-02 | 1995-08-03 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von Diarylcarbonaten |
IT1269916B (it) * | 1994-03-25 | 1997-04-16 | Enichem Spa | Procedimento migliorato per la sintesi di dimetilcarbonato |
IT1269884B (it) * | 1994-06-03 | 1997-04-15 | Enichem Sintesi | Metodo per la rimozione dei contaminanti acidi e salini dalla fase condensata dell'effluente di reazione in un processo per la sintesi di dimetilcarbonato |
IT1269883B (it) | 1994-06-03 | 1997-04-15 | Enichem Sintesi | Metodo per la rimozione dei contaminanti acidi contenuti in una corrente vaporizzata composta da vapori organici e acqua |
DE19523390A1 (de) * | 1995-06-23 | 1997-01-09 | Bayer Ag | Verfahren zur Herstellung von Diarylcarbonaten |
US6280519B1 (en) * | 1998-05-05 | 2001-08-28 | Exxon Chemical Patents Inc. | Environmentally preferred fluids and fluid blends |
US6818049B1 (en) | 1998-05-05 | 2004-11-16 | Exxonmobil Chemical Patents Inc. | Environmentally preferred fluids and fluid blends |
US6294684B1 (en) | 1999-12-08 | 2001-09-25 | General Electric Company | Method and apparatus for the continuous production of diaryl carbonates |
JP3799968B2 (ja) | 2000-06-16 | 2006-07-19 | 東海ゴム工業株式会社 | 耐久性に優れた防振ゴムの製造方法 |
US6420589B1 (en) | 2000-12-14 | 2002-07-16 | General Electric Company | Process for the production of diaryl carbonates |
US6384262B1 (en) | 2000-12-14 | 2002-05-07 | General Electric Company | Process for the production of diaryl carbonates |
US6521777B2 (en) | 2000-12-14 | 2003-02-18 | General Electric Company | Process for the production of diaryl carbonates |
US6441215B1 (en) | 2001-06-06 | 2002-08-27 | General Electric Company | Method for reducing carbonate decomposition in reaction mixtures |
US7084292B2 (en) | 2001-06-22 | 2006-08-01 | Exxonmobil Chemical Patents Inc. | Integrated process for preparing dialkyl carbonates with a circulating catalyst |
US6774256B2 (en) | 2001-06-22 | 2004-08-10 | Exxonmobil Chemical Patents Inc. | Low corrosive integrated process for preparing dialkyl carbonates |
US7345187B2 (en) | 2001-08-14 | 2008-03-18 | General Electric Company | Method and apparatus for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates |
US6784277B2 (en) | 2001-08-14 | 2004-08-31 | General Electric Company | Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates |
US7514521B2 (en) | 2001-08-14 | 2009-04-07 | Sabic Innovative Plastics Ip B.V. | Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates |
US6903049B2 (en) * | 2002-02-25 | 2005-06-07 | General Electric Company | Method and catalyst composition for producing aromatic carbonates using activating solvents |
US6977308B2 (en) | 2002-06-25 | 2005-12-20 | General Electric Company | Method and apparatus for preparing a dialkyl carbonate |
US7718564B2 (en) * | 2005-06-24 | 2010-05-18 | Exxonmobil Research And Engineering Company | Partially decomposed catalyst and hydrocarbon oxidation processes using the same |
US7622602B2 (en) | 2005-10-12 | 2009-11-24 | Sabic Innovative Plastics Ip B.V. | Method for preparing a dialkyl carbonate, and its use in the preparation of diaryl carbonates and polycarbonates |
TW200831458A (en) | 2007-01-17 | 2008-08-01 | China Petrochemical Dev Corp | The manufacturing method of dialkyl carbonate |
TW200846319A (en) | 2007-05-28 | 2008-12-01 | China Petrochemical Dev Corp | Method for preparing carbonate diester |
US9249082B2 (en) * | 2010-02-09 | 2016-02-02 | King Abdulaziz City for Science and Technology (KACST) | Synthesis of dimethyl carbonate from carbon dioxide and methanol |
CN102941114A (zh) * | 2012-11-08 | 2013-02-27 | 江南大学 | 用于氧化羰基合成碳酸二乙酯的复合分子筛催化剂及其制备方法 |
CN112439405B (zh) * | 2020-12-21 | 2022-03-11 | 中国科学院山西煤炭化学研究所 | 一种甲醇、二氧化碳和2-氰基吡啶制备碳酸二甲酯的催化剂及其制法和应用 |
CN116751124B (zh) * | 2023-08-17 | 2023-10-24 | 太原理工大学 | 一种甲醇氧化羰基化合成电子级碳酸二甲酯工艺 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA923139A (en) * | 1970-03-04 | 1973-03-20 | Snamprogetti S.P.A. | Process for the preparation of esters of the carbonic acid |
US4360477A (en) * | 1981-11-09 | 1982-11-23 | General Electric Company | Carbonylation of alkanols |
GB8321199D0 (en) * | 1983-08-05 | 1983-09-07 | Ici Plc | Carbonate production |
IT1227183B (it) * | 1988-10-19 | 1991-03-21 | Enichem Sintesi | Procedimento in continuo per la preparazione di di alchil carbonati |
DE3926709A1 (de) * | 1989-08-12 | 1991-02-14 | Basf Ag | Verfahren zur herstellung von dialkylcarbonaten |
-
1990
- 1990-06-04 IT IT02053090A patent/IT1248686B/it active IP Right Grant
-
1991
- 1991-05-28 EP EP91201269A patent/EP0460732B2/en not_active Expired - Lifetime
- 1991-05-28 DE DE69102826T patent/DE69102826T3/de not_active Expired - Lifetime
- 1991-05-28 ES ES91201269T patent/ES2059039T5/es not_active Expired - Lifetime
- 1991-05-28 AT AT91201269T patent/ATE108432T1/de not_active IP Right Cessation
- 1991-05-28 DK DK91201269.7T patent/DK0460732T3/da active
- 1991-06-03 MX MX026073A patent/MX173385B/es unknown
- 1991-06-03 KR KR1019910009138A patent/KR930010407B1/ko not_active IP Right Cessation
- 1991-06-03 CA CA002043743A patent/CA2043743C/en not_active Expired - Lifetime
- 1991-06-03 US US07/709,583 patent/US5210269A/en not_active Expired - Lifetime
- 1991-06-04 JP JP03159543A patent/JP3094241B2/ja not_active Expired - Lifetime
-
1997
- 1997-07-30 GR GR970401907T patent/GR3024259T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
CA2043743C (en) | 2001-10-23 |
KR930010407B1 (ko) | 1993-10-23 |
DK0460732T3 (da) | 1994-09-12 |
IT9020530A0 (es) | 1990-06-04 |
ES2059039T3 (es) | 1994-11-01 |
MX173385B (es) | 1994-02-24 |
IT9020530A1 (it) | 1991-12-04 |
EP0460732A1 (en) | 1991-12-11 |
DE69102826T3 (de) | 1998-08-27 |
JPH04270250A (ja) | 1992-09-25 |
DE69102826T2 (de) | 1995-02-23 |
ATE108432T1 (de) | 1994-07-15 |
IT1248686B (it) | 1995-01-26 |
US5210269A (en) | 1993-05-11 |
DE69102826D1 (de) | 1994-08-18 |
CA2043743A1 (en) | 1991-12-05 |
EP0460732B2 (en) | 1997-07-23 |
JP3094241B2 (ja) | 2000-10-03 |
GR3024259T3 (en) | 1997-10-31 |
KR920000675A (ko) | 1992-01-29 |
EP0460732B1 (en) | 1994-07-13 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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