ES2055361T3 - Nuevo catalizador a base de paladio y su empleo. - Google Patents

Nuevo catalizador a base de paladio y su empleo.

Info

Publication number
ES2055361T3
ES2055361T3 ES90401739T ES90401739T ES2055361T3 ES 2055361 T3 ES2055361 T3 ES 2055361T3 ES 90401739 T ES90401739 T ES 90401739T ES 90401739 T ES90401739 T ES 90401739T ES 2055361 T3 ES2055361 T3 ES 2055361T3
Authority
ES
Spain
Prior art keywords
palladium
catalyst based
suacia
new catalyst
sicau
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90401739T
Other languages
English (en)
Inventor
Denis Sinou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Sante SA
Original Assignee
Rhone Poulenc Sante SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Sante SA filed Critical Rhone Poulenc Sante SA
Application granted granted Critical
Publication of ES2055361T3 publication Critical patent/ES2055361T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023Preparation; Separation; Stabilisation; Use of additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4277C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
    • B01J2231/4283C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using N nucleophiles, e.g. Buchwald-Hartwig amination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48Ring-opening reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96Water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Cephalosporin Compounds (AREA)
  • Steroid Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)

Abstract

NUEVO SISTEMA CATALITICO CONSTITUIDO POR UNA DISOLUCION ACUOSA DE UN DERIVADO DE PALADIO Y DE UN LIGANDO HIDROSOLUBLE (TRI-METASULFOTRIFENILFOSFINA) ASOCIADO A UN NITRILO Y SU EMPLEO, EN PARTICULAR PARA LLEVAR A CABO REACCIONES DE SUSTITUCION ALILICA EN SISTEMA BIFASICO CON RECICLAJE FACIL DEL CATALIZADOR DESPUES DE DECANTACION.
ES90401739T 1989-06-22 1990-06-20 Nuevo catalizador a base de paladio y su empleo. Expired - Lifetime ES2055361T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8908318A FR2652514A1 (fr) 1989-06-22 1989-06-22 Nouveau catalyseur a base de palladium et son emploi.

Publications (1)

Publication Number Publication Date
ES2055361T3 true ES2055361T3 (es) 1994-08-16

Family

ID=9383018

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90401739T Expired - Lifetime ES2055361T3 (es) 1989-06-22 1990-06-20 Nuevo catalizador a base de paladio y su empleo.

Country Status (10)

Country Link
US (1) US5135900A (es)
EP (1) EP0407256B1 (es)
JP (1) JPH03232535A (es)
AT (1) ATE89495T1 (es)
CA (1) CA2019495A1 (es)
DE (1) DE69001649T2 (es)
DK (1) DK0407256T3 (es)
ES (1) ES2055361T3 (es)
FR (1) FR2652514A1 (es)
GR (1) GR3007916T3 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69128175T2 (de) * 1990-08-02 1998-05-20 Rhone Poulenc Chimie Allylierungsreagens und ein es verwendendes Herstellungsverfahren
US5366663A (en) * 1991-11-30 1994-11-22 Hoechst Ag Mixtures of liquid crystalline copolymers, polyether imides and compatibilizers and use thereof
IL105392A (en) * 1992-04-15 1998-02-22 Rhone Poulenc Chimie Reagent and catalytic process useful for cleaving a protected functional group
FR2690153A1 (fr) * 1992-04-15 1993-10-22 Rhone Poulenc Chimie Réactif et procédé catalytique utile pour cliver une fonction protégée.
FR2703688B1 (fr) * 1993-04-09 1995-05-19 Rhone Poulenc Chimie Réactif de désallylation, procédé de désallylation utilisant ledit réactif.
JP6928618B2 (ja) * 2016-05-10 2021-09-01 プロメガ コーポレイションPromega Corporation 生物学的環境において改善された性能を有するパラジウム触媒
CN112473748B (zh) * 2020-12-24 2021-09-17 北京交通大学 一种可控氧化的四三苯基膦钯催化剂及其制备方法和用途

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2366237A1 (fr) * 1976-07-27 1978-04-28 Rhone Poulenc Ind Procede de telomerisation de dienes
US4243829A (en) * 1976-10-04 1981-01-06 Charles U. Pittman, Jr. Production of 1,7-octadiene from butadiene
US4229606A (en) * 1978-12-13 1980-10-21 Shell Oil Company 1,7-Octadiene process
GB2074156B (en) * 1980-03-28 1984-02-29 Kuraray Co Preparation of n-octadienol
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins
US4362670A (en) * 1981-09-03 1982-12-07 The Dow Chemical Company Allylation of carbon compounds
FR2549840B1 (fr) * 1983-07-28 1986-03-21 Rhone Poulenc Sante Nouvelles phosphines chirales sulfonees, leur preparation et leur emploi en catalyse asymetrique
FR2596390B1 (fr) * 1986-03-27 1989-02-17 Rhone Poulenc Chimie Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique
DE3884254T2 (de) * 1987-04-16 1994-03-24 Kuraray Co Verfahren zur kontinuierlichen Herstellung von Octa-2,7-dien-1-ol.
FR2617163B1 (fr) * 1987-06-23 1992-04-30 Strasbourg I Universite Procede de preparation de la lactone ethylidene-2 heptene-6 olide-5, par telomerisation du butadiene et du dioxyde de carbone
GB8723602D0 (en) * 1987-10-08 1987-11-11 British Petroleum Co Plc Polyketones
JPH02240040A (ja) * 1989-03-13 1990-09-25 Nippon Zeon Co Ltd 3―ケト―1―アルコールの製造法

Also Published As

Publication number Publication date
ATE89495T1 (de) 1993-06-15
FR2652514A1 (fr) 1991-04-05
EP0407256A1 (fr) 1991-01-09
JPH03232535A (ja) 1991-10-16
EP0407256B1 (fr) 1993-05-19
GR3007916T3 (es) 1993-08-31
DK0407256T3 (da) 1993-06-14
DE69001649D1 (de) 1993-06-24
DE69001649T2 (de) 1993-10-07
US5135900A (en) 1992-08-04
CA2019495A1 (fr) 1990-12-22

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