ATE89495T1 - Verfahren zur durchfuehrung von nucleophilen substitutionen. - Google Patents
Verfahren zur durchfuehrung von nucleophilen substitutionen.Info
- Publication number
- ATE89495T1 ATE89495T1 AT90401739T AT90401739T ATE89495T1 AT E89495 T1 ATE89495 T1 AT E89495T1 AT 90401739 T AT90401739 T AT 90401739T AT 90401739 T AT90401739 T AT 90401739T AT E89495 T1 ATE89495 T1 AT E89495T1
- Authority
- AT
- Austria
- Prior art keywords
- procedure
- nucleophilic substitutions
- performing nucleophilic
- catalyst
- sulphotriphenylphosphine
- Prior art date
Links
- 238000006467 substitution reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 230000000269 nucleophilic effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 150000002940 palladium Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
- B01J2231/4283—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using N nucleophiles, e.g. Buchwald-Hartwig amination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/48—Ring-opening reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Cephalosporin Compounds (AREA)
- Steroid Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8908318A FR2652514A1 (fr) | 1989-06-22 | 1989-06-22 | Nouveau catalyseur a base de palladium et son emploi. |
EP90401739A EP0407256B1 (de) | 1989-06-22 | 1990-06-20 | Verfahren zur Durchführung von nucleophilen Substitutionen |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE89495T1 true ATE89495T1 (de) | 1993-06-15 |
Family
ID=9383018
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT90401739T ATE89495T1 (de) | 1989-06-22 | 1990-06-20 | Verfahren zur durchfuehrung von nucleophilen substitutionen. |
Country Status (10)
Country | Link |
---|---|
US (1) | US5135900A (de) |
EP (1) | EP0407256B1 (de) |
JP (1) | JPH03232535A (de) |
AT (1) | ATE89495T1 (de) |
CA (1) | CA2019495A1 (de) |
DE (1) | DE69001649T2 (de) |
DK (1) | DK0407256T3 (de) |
ES (1) | ES2055361T3 (de) |
FR (1) | FR2652514A1 (de) |
GR (1) | GR3007916T3 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69128175T2 (de) * | 1990-08-02 | 1998-05-20 | Rhone Poulenc Chimie | Allylierungsreagens und ein es verwendendes Herstellungsverfahren |
US5366663A (en) * | 1991-11-30 | 1994-11-22 | Hoechst Ag | Mixtures of liquid crystalline copolymers, polyether imides and compatibilizers and use thereof |
IL105392A (en) * | 1992-04-15 | 1998-02-22 | Rhone Poulenc Chimie | Reagent and catalytic process useful for cleaving a protected functional group |
FR2690153A1 (fr) * | 1992-04-15 | 1993-10-22 | Rhone Poulenc Chimie | Réactif et procédé catalytique utile pour cliver une fonction protégée. |
FR2703688B1 (fr) * | 1993-04-09 | 1995-05-19 | Rhone Poulenc Chimie | Réactif de désallylation, procédé de désallylation utilisant ledit réactif. |
JP6928618B2 (ja) * | 2016-05-10 | 2021-09-01 | プロメガ コーポレイションPromega Corporation | 生物学的環境において改善された性能を有するパラジウム触媒 |
CN112473748B (zh) * | 2020-12-24 | 2021-09-17 | 北京交通大学 | 一种可控氧化的四三苯基膦钯催化剂及其制备方法和用途 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2366237A1 (fr) * | 1976-07-27 | 1978-04-28 | Rhone Poulenc Ind | Procede de telomerisation de dienes |
US4243829A (en) * | 1976-10-04 | 1981-01-06 | Charles U. Pittman, Jr. | Production of 1,7-octadiene from butadiene |
US4229606A (en) * | 1978-12-13 | 1980-10-21 | Shell Oil Company | 1,7-Octadiene process |
GB2074156B (en) * | 1980-03-28 | 1984-02-29 | Kuraray Co | Preparation of n-octadienol |
GB2085874B (en) * | 1980-09-04 | 1984-08-08 | Johnson Matthey Plc | Hydroformylation of olefins |
US4362670A (en) * | 1981-09-03 | 1982-12-07 | The Dow Chemical Company | Allylation of carbon compounds |
FR2549840B1 (fr) * | 1983-07-28 | 1986-03-21 | Rhone Poulenc Sante | Nouvelles phosphines chirales sulfonees, leur preparation et leur emploi en catalyse asymetrique |
FR2596390B1 (fr) * | 1986-03-27 | 1989-02-17 | Rhone Poulenc Chimie | Procede de (co)dimerisation catalytique d'un acrylate d'alkyle inferieur et composition catalytique |
DE3884254T2 (de) * | 1987-04-16 | 1994-03-24 | Kuraray Co | Verfahren zur kontinuierlichen Herstellung von Octa-2,7-dien-1-ol. |
FR2617163B1 (fr) * | 1987-06-23 | 1992-04-30 | Strasbourg I Universite | Procede de preparation de la lactone ethylidene-2 heptene-6 olide-5, par telomerisation du butadiene et du dioxyde de carbone |
GB8723602D0 (en) * | 1987-10-08 | 1987-11-11 | British Petroleum Co Plc | Polyketones |
JPH02240040A (ja) * | 1989-03-13 | 1990-09-25 | Nippon Zeon Co Ltd | 3―ケト―1―アルコールの製造法 |
-
1989
- 1989-06-22 FR FR8908318A patent/FR2652514A1/fr active Pending
-
1990
- 1990-06-20 ES ES90401739T patent/ES2055361T3/es not_active Expired - Lifetime
- 1990-06-20 DE DE90401739T patent/DE69001649T2/de not_active Expired - Fee Related
- 1990-06-20 AT AT90401739T patent/ATE89495T1/de active
- 1990-06-20 US US07/540,603 patent/US5135900A/en not_active Expired - Fee Related
- 1990-06-20 DK DK90401739.9T patent/DK0407256T3/da active
- 1990-06-20 EP EP90401739A patent/EP0407256B1/de not_active Expired - Lifetime
- 1990-06-21 CA CA002019495A patent/CA2019495A1/fr not_active Abandoned
- 1990-06-22 JP JP2162983A patent/JPH03232535A/ja active Pending
-
1993
- 1993-05-20 GR GR930400079T patent/GR3007916T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2055361T3 (es) | 1994-08-16 |
FR2652514A1 (fr) | 1991-04-05 |
EP0407256A1 (de) | 1991-01-09 |
JPH03232535A (ja) | 1991-10-16 |
EP0407256B1 (de) | 1993-05-19 |
GR3007916T3 (de) | 1993-08-31 |
DK0407256T3 (da) | 1993-06-14 |
DE69001649D1 (de) | 1993-06-24 |
DE69001649T2 (de) | 1993-10-07 |
US5135900A (en) | 1992-08-04 |
CA2019495A1 (fr) | 1990-12-22 |
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