ES2054750T3 - Estabilizantes de uv unidos a polimeros. - Google Patents
Estabilizantes de uv unidos a polimeros.Info
- Publication number
- ES2054750T3 ES2054750T3 ES88113135T ES88113135T ES2054750T3 ES 2054750 T3 ES2054750 T3 ES 2054750T3 ES 88113135 T ES88113135 T ES 88113135T ES 88113135 T ES88113135 T ES 88113135T ES 2054750 T3 ES2054750 T3 ES 2054750T3
- Authority
- ES
- Spain
- Prior art keywords
- polymer
- stabilizers
- polymers
- linked
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 title abstract 10
- 239000012963 UV stabilizer Substances 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- -1 AMINO Chemical class 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 230000005012 migration Effects 0.000 abstract 1
- 238000013508 migration Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
LOS ESTABILIZADORES DE LUZ ULTRAVIOLETA ESTA QUIMICAMENTE LIGADAS AL ANHIDRIDOS CONTENIENDO POLIMEROS O COPOLIMEROS. LOS ESTABILIZADORES POLIMERICOS ESTAN PREPARADOS POR LA REACCION DE ABSORVENTES UV SUSTITUIDO POR HIDRACIDO O POR AMINO PRIMARIO CON ALFURO O TODOS LOS GRUPOS SUBSTITUIDOS DEL POLIMERO O DEL COPOLIMERO PARA FORMAR POLIMEROS CON UNIDADES PERIODICAS ELEGIDAS DE LAS FORMULAS, EN LAS CUALES LAS UNIDADES TIENEN LUGAR, POR EJEMPLO, EN LA PARTE PRINCIPAL DEL POLIMERO Y DONDE X ES 0 O 1, R1 Y R2 SON POR EJEMPLO HIDROGENO O FENIL Y G ES POR EJEMPLO (FORMULA) DONDE R3 Y R4 SON, POR EJEMPLO HIDROGENO O R3 O R4 ES UN GRUPO DE CONEXION X1 QUE ES POR EJEMPLO, UN ENLACE DIRECTO. LOS ESTABILIZADORES LIGADOS A POLIMEROS NO SE PIERDEN DEL SISTEMA DE POLIMEROS POR VOLATIZACION, MIGRACION O EXTRACCION, INCLUSO A ALTA TEMPERATURA. EL POLIMERO DE ESTA INVENCION PUEDE SER USADO COMO SON O COMO CONCENTRADOS PARA ESTABILIZAR OTROS SISTEMAS DE POLIMEROS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/084,608 US4868246A (en) | 1987-08-12 | 1987-08-12 | Polymer bound UV stabilizers |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2054750T3 true ES2054750T3 (es) | 1994-08-16 |
Family
ID=22186069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES88113135T Expired - Lifetime ES2054750T3 (es) | 1987-08-12 | 1988-08-12 | Estabilizantes de uv unidos a polimeros. |
Country Status (7)
Country | Link |
---|---|
US (2) | US4868246A (es) |
EP (1) | EP0303988B1 (es) |
JP (1) | JPS6466210A (es) |
BR (1) | BR8804066A (es) |
CA (1) | CA1336028C (es) |
DE (1) | DE3880926T2 (es) |
ES (1) | ES2054750T3 (es) |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3814567A1 (de) * | 1988-04-29 | 1989-11-09 | Du Pont Deutschland | Photopolymerisierbare zusammensetzungen mit carboxylgruppen enthaltenden bindemitteln |
US5037894A (en) * | 1988-11-07 | 1991-08-06 | Atochem North America, Inc. | Polymer bound flame retardants |
US5140070A (en) * | 1988-11-07 | 1992-08-18 | Elf Atochem North America, Inc | Compositions comprising polymer bond flame retardants |
US5220015A (en) * | 1988-11-07 | 1993-06-15 | Elf Atochem North America, Inc. | Flame retardants compounds |
US4975494A (en) * | 1988-11-23 | 1990-12-04 | Atochem Of North America, Inc. | Polymer bound light stabilizer coating resins |
EP0409840A4 (en) * | 1989-02-13 | 1991-09-04 | Atochem North America, Inc. | Benzotriazole and oxanilide uv absorber hydrazides |
GB2228488B (en) * | 1989-02-27 | 1992-03-25 | Du Pont Canada | Coextrudable adhesives |
US5981065A (en) * | 1992-05-26 | 1999-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Telephone cables |
GB9409466D0 (en) * | 1994-05-12 | 1994-06-29 | Ciba Geigy Ag | Textile treatment |
US5994431A (en) * | 1996-05-03 | 1999-11-30 | 3M Innovative Properties Company | Amide functional ultraviolet light absorbers for polyolefins |
US6100208A (en) * | 1996-10-31 | 2000-08-08 | Kimberly-Clark Worldwide, Inc. | Outdoor fabric |
WO1998018830A1 (en) * | 1996-10-31 | 1998-05-07 | Ciba Specialty Chemicals Holding Inc. | Functionalised polymers |
US5977219A (en) * | 1997-10-30 | 1999-11-02 | Ciba Specialty Chemicals Corporation | Benzotriazole UV absorbers having enhanced durability |
CH693032A5 (de) * | 1996-11-07 | 2003-01-31 | Ciba Sc Holding Ag | Benzotriazol-UV-Absorptionsmittel mit erhöhter Haltbarkeit. |
US6166218A (en) | 1996-11-07 | 2000-12-26 | Ciba Specialty Chemicals Corporation | Benzotriazole UV absorbers having enhanced durability |
JP3714574B2 (ja) * | 1997-03-26 | 2005-11-09 | ダイセル化学工業株式会社 | 紫外線吸収剤とその製造方法および合成樹脂組成物 |
US5990209A (en) * | 1997-04-25 | 1999-11-23 | Aristech Chemical Corporation | Copolymers of propylene with polymerizable hindered amine light stabilizers |
US6008302A (en) * | 1997-04-29 | 1999-12-28 | 3M Innovative Properties Company | Polyolefin bound ultraviolet light absorbers |
JP3448851B2 (ja) * | 1997-11-28 | 2003-09-22 | タキロン株式会社 | 添加剤含有樹脂成形品及びその製造方法 |
JP3816697B2 (ja) * | 1999-07-07 | 2006-08-30 | 大日精化工業株式会社 | 重合体が結合した機能剤、その製造方法、それらの使用方法及びそれらを使用した物品 |
US6514626B1 (en) | 2000-08-28 | 2003-02-04 | Pechiney Emballage Flexible Europe | Dienophile additives to polyvinylidene chloride copolymers |
DE10149077A1 (de) * | 2001-10-05 | 2003-04-24 | Tesa Ag | Verfahren zur Herstellung UV-vernetzbarer Acrylathaftklebemassen |
US7078464B2 (en) * | 2002-06-26 | 2006-07-18 | Sartomer Technology, Inc. | Acid salts of amine-functionalized SMA imide resins |
US6899866B2 (en) * | 2002-09-06 | 2005-05-31 | Cph Innovations Corporation | Photostabilization of a sunscreen composition with a combination of an α-cyano-β, β-diphenylacrylate compound and a dialkyl naphithalate |
US6919473B2 (en) * | 2002-09-17 | 2005-07-19 | Cph Innovations Corporation | Photostabilizers, UV absorbers, and methods of photostabilizing a sunscreen composition |
US7544350B2 (en) * | 2002-11-22 | 2009-06-09 | Hallstar Innovations Corp. | Method of decreasing the UV light degradation of polymers |
US7799317B2 (en) * | 2002-11-22 | 2010-09-21 | Hallstar Innovations Corp. | Photostabilizers, UV absorbers, and methods of photostabilizing compositions |
JP4163561B2 (ja) * | 2003-06-17 | 2008-10-08 | 富士フイルム株式会社 | 色素化合物 |
US7534420B2 (en) * | 2004-02-25 | 2009-05-19 | Hallstar Innovations Corp. | Compounds derived from polyanhydride resins with film-forming, UV-absorbing, and photostablizing properties, compositions containing same, and methods of using the same |
US7235587B2 (en) * | 2004-07-01 | 2007-06-26 | Cph Innovations Corporation | Diesters containing two crylene or fluorene moieties, sunscreen compositions containing the same, and methods of photostabilizing a sunscreen compositions containing the same |
US8158678B2 (en) * | 2005-04-07 | 2012-04-17 | Cph Innovations Corp. | Photoabsorbing, highly conjugated compounds of cyanoacrylic esters, sunscreen compositions and methods of use |
JP5324124B2 (ja) * | 2008-05-07 | 2013-10-23 | 大日精化工業株式会社 | 重合体結合機能剤マスターバッチ及びその製造方法 |
WO2010060698A2 (de) * | 2008-11-03 | 2010-06-03 | Basf Se | Pigmentzusammensetzungen |
US8557226B2 (en) | 2009-01-16 | 2013-10-15 | Isp Investments Inc. | Performance-boosting UV-absorbing compounds |
US9044623B2 (en) * | 2009-01-27 | 2015-06-02 | Isp Investments Inc. | Polymer-bound UV absorbers in personal care compositions |
DE102012022482A1 (de) | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerzusammensetzung mit verbesserter Langzeitstabilität, hieraus hergestellte Formteile sowie Verwendungszwecke |
DE102013005307A1 (de) | 2013-03-25 | 2014-09-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimiden als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffzusammensetzung und hieraus hergestelltem Formteil |
US9708465B2 (en) | 2013-05-29 | 2017-07-18 | Sabic Global Technologies B.V. | Color-stable thermoplastic composition |
CZ305144B6 (cs) | 2013-06-18 | 2015-05-20 | SYNPO, akciová společnost | Způsob přípravy stabilizovaného polyethylenu (PE) |
DE102014210214A1 (de) | 2014-05-28 | 2015-12-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Oxyimid-enthaltenden Copolymeren oder Polymeren als Flammschutzmittel, Stabilisatoren, Rheologiemodifikatoren für Kunststoffe, Initiatoren für Polymerisations- und Pfropfprozesse, Vernetzungs- oder Kopplungsmittel sowie solche Copolymere oder Polymere enthaltende Kunststoffformmassen |
DE102014211276A1 (de) | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Hydroxybenzotriazol-Derivaten und/oder Hydroxy-Indazol-Derivaten als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffformmasse |
WO2016085790A1 (en) | 2014-11-25 | 2016-06-02 | Sabic Global Technologies B.V. | Weatherable thermoplastic compositions, method of manufacture, and articles therefrom |
US10377876B2 (en) | 2014-11-25 | 2019-08-13 | Sabic Global Technologies B.V. | Thermoplastic compositions, method of manufacture, and articles therefrom |
AU2017350556B2 (en) * | 2016-10-26 | 2022-04-14 | Corning Incorporated | Flame retardant polyolefin-type resin and preparation method as well as optic fiber cable using the same |
US10584234B1 (en) | 2017-06-28 | 2020-03-10 | Firestone Industrial Products Company, Llc | Antioxidant precursors for elastomeric compositions |
Family Cites Families (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE513431A (es) * | 1951-09-10 | |||
US2989517A (en) * | 1954-05-06 | 1961-06-20 | Dow Chemical Co | Polymerization method |
US2849373A (en) * | 1955-03-31 | 1958-08-26 | American Oil Co | Preventing color formation in gasoline |
US2824084A (en) * | 1955-05-26 | 1958-02-18 | Eastman Kodak Co | Light-sensitive, unsaturated polymeric maleic and acrylic derivatives |
US2971939A (en) * | 1959-01-30 | 1961-02-14 | Monsanto Chemicals | Process for preparing homogeneous copolymers of a vinylidene monomer and a maleic monomer and product thereof |
US3159646A (en) * | 1960-01-13 | 1964-12-01 | American Cyanamid Co | Alkenoylamido and oxy phenylbenzotriazoles |
US3336267A (en) * | 1960-06-02 | 1967-08-15 | Dow Chemical Co | Continuous preparation of thermoplastic copolymers and terpolymers of unsaturated cyclic anhydrides |
US3214436A (en) * | 1960-12-19 | 1965-10-26 | American Cyanamid Co | Benzotriazole compounds |
US3213058A (en) * | 1960-12-19 | 1965-10-19 | American Cyanamid Co | Polymers reacted with benzotriazole uv absorbers |
NL279774A (es) * | 1961-06-16 | |||
NL126744C (es) * | 1961-06-16 | 1969-01-15 | ||
NL126588C (es) * | 1961-06-16 | |||
BE630550A (es) * | 1961-06-16 | |||
CH410968A (de) * | 1961-06-16 | 1966-04-15 | Geigy Ag J R | Verfahren zur Herstellung von substituierten 2-(2'-Hydroxyphenyl)-benztriazolverbindungen |
US3391110A (en) * | 1961-08-21 | 1968-07-02 | American Cyanamid Co | Polymerizable benzophenone uv absorber-condensation polymers |
US3385910A (en) * | 1964-04-15 | 1968-05-28 | Du Pont | Polymeric light stabilizers and compositions thereof |
US3272891A (en) * | 1964-10-14 | 1966-09-13 | American Cyanamid Co | Stabilizing polymers with alkenoylamido- and phenylbenzatriazoles |
US3483276A (en) * | 1964-12-04 | 1969-12-09 | Hercules Inc | Blends of modified and unmodified polypropylene |
CH501699A (de) * | 1965-12-08 | 1971-02-26 | Ciba Geigy Ag | Verwendung von symmetrischen Oxalsäure-diarylamiden als Ultraviolettschutzmittel für organische Materialien ausserhalb der Textilindustrie |
JPS4626860Y1 (es) * | 1966-03-04 | 1971-09-14 | ||
GB1117515A (en) * | 1966-07-08 | 1968-06-19 | Ici Ltd | Maleic anhydride/alkyl vinyl ether copolymer |
US3488311A (en) * | 1967-01-19 | 1970-01-06 | Gulf Research Development Co | Ammonium hydroxide polymer solutions for floor polish compositions |
US3598600A (en) * | 1967-10-09 | 1971-08-10 | Eastman Kodak Co | Photographic compositions and elements containing polymeric imidazoles |
US3509110A (en) * | 1968-04-03 | 1970-04-28 | Koppers Co Inc | Vinyl aryl monomer-half ester copolymers by suspension polymerization |
US3755354A (en) * | 1969-05-05 | 1973-08-28 | Gen Electric | Amide acid and imido-substituted organosilanes |
US3560455A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 20 to 30 carbon atoms |
US3560456A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 16 to 18 carbon atoms |
US3560457A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 12 to 14 carbon atoms |
US3553177A (en) * | 1969-05-26 | 1971-01-05 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having at least 30 carbon atoms |
US3555001A (en) * | 1969-05-29 | 1971-01-12 | Monsanto Co | Process for the fractionation of plasma and serum using water-insoluble polyelectrolytes containing diloweralkylaminoloweralkylimide groups |
US3657197A (en) * | 1970-05-07 | 1972-04-18 | Gaf Corp | Photosensitive propargyl polymer derivatives |
US3723375A (en) * | 1970-11-24 | 1973-03-27 | Gaf Corp | Novel anhydride interpolymers |
JPS4843658A (es) * | 1971-10-06 | 1973-06-23 | ||
US3998907A (en) * | 1972-08-29 | 1976-12-21 | Arco Polymers, Inc. | Rubber-modified dicarboxylic acid imide copolymers |
US3919354A (en) * | 1972-09-08 | 1975-11-11 | Dow Chemical Co | Impact resistant polymers of a resinous copolymer of an alkenyl aromatic monomer and unsaturated dicarboxylic anhydride |
US3884882A (en) * | 1973-01-10 | 1975-05-20 | Du Pont | Certain EPDM copolymer/maleic anhydride adducts and thermoplastic elastomers therefrom |
US4042773A (en) * | 1974-01-22 | 1977-08-16 | Pennwalt Corporation | Peroxide free radical initiators containing ultraviolet light stabilizing groups |
DE2534613A1 (de) * | 1975-08-02 | 1977-02-17 | Basf Ag | Bernsteinsaeurehydrazid-einheiten enthaltende copolymerisate |
US4048263A (en) * | 1975-12-29 | 1977-09-13 | Monsanto Company | Rubber modified fire retardant polymer compositions |
US4097551A (en) * | 1976-12-20 | 1978-06-27 | Arco Polymers, Inc. | Rubber modified dicarboxylic acid copolymer blends |
US4341695A (en) * | 1977-12-27 | 1982-07-27 | Monsanto Company | Rubber modified terpolymers with improved heat distortion resistance |
US4289686A (en) * | 1978-09-27 | 1981-09-15 | Ciba-Geigy Corporation | Tetra-alkyl piperidine derivatives as light stabilizers |
EP0031203B2 (en) * | 1979-12-10 | 1988-01-13 | Imperial Chemical Industries Plc | Process for preparing linear polyesters, and shaped articles obtained therefrom |
US4381373A (en) * | 1980-12-11 | 1983-04-26 | Mitsubishi Monsanto Chemical Company | Heat resistant resin composition |
US4358573A (en) * | 1981-05-29 | 1982-11-09 | S. C. Johnson & Son, Inc. | Waxy maleic anhydride alpha olefin terpolymers |
CA1231500A (en) * | 1981-10-07 | 1988-01-12 | Richard M. Kopchik | Thermoplastic, non-crosslinked anhydride polymers, imide polymers, and process for preparation |
EP0080431B1 (de) * | 1981-10-16 | 1986-09-24 | Ciba-Geigy Ag | Synergistisches Gemisch von niedermolekularen und hochmolekularen Polyalkylpiperidinen |
GB2114574B (en) * | 1981-12-11 | 1985-07-03 | Denki Kagaku Kogyo Kk | Iminated graft copolymer and blends containing it |
CA1227598A (en) * | 1982-01-25 | 1987-09-29 | Zenon Joffe | Method for making thermoplastics with bound stabilizers |
US4486570A (en) * | 1982-01-25 | 1984-12-04 | Atlantic Richfield Company | Heat resistant high impact polymer compositions and method of making same |
DD208470A3 (de) * | 1982-04-20 | 1984-05-02 | Klaus Ruehlmann | Verfahren zur herstellung von polymeren kv-stabilisatoren |
DD208471A3 (de) * | 1982-04-20 | 1984-05-02 | Klaus Ruehlmann | Verfahren zur herstellung von lichtgeschuetzten polymeren |
US4522983A (en) * | 1983-03-09 | 1985-06-11 | Atlantic Richfield Company | Polymeric molding composition |
JPS59221315A (ja) * | 1983-05-31 | 1984-12-12 | Kyowa Gas Chem Ind Co Ltd | メタクリル共重合体の製造方法 |
JPS59221314A (ja) * | 1983-05-31 | 1984-12-12 | Kyowa Gas Chem Ind Co Ltd | メタクリル共重合体の製造方法 |
US4522992A (en) * | 1983-06-28 | 1985-06-11 | S. C. Johnson & Son, Inc. | Aromatic monovinyl alkenyl alphaolefin anhydride terpolymers |
EP0133164B1 (de) * | 1983-07-26 | 1988-12-14 | Ciba-Geigy Ag | Copolymerisierbare Verbindungen |
JPS6084378A (ja) * | 1983-10-14 | 1985-05-13 | Showa Denko Kk | 紫外線吸収剤 |
NL8403606A (nl) * | 1983-12-09 | 1985-07-01 | Ciba Geigy | Biocide polymeren, samenstellingen die deze polymeren bevatten, werkwijzen ter bereiding van deze polymeren alsmede de toepassing daarvan als algiciden. |
US4694048A (en) * | 1986-04-21 | 1987-09-15 | Celanese Corporation | Thermoplastic polymers containing repeating hydrazide groups |
US4980420A (en) * | 1987-08-12 | 1990-12-25 | Atochem North America, Inc. | Benzotriazole and oxanilide UV absorber hydrazides |
DE3888952D1 (de) * | 1987-12-28 | 1994-05-11 | Ciba Geigy | Neue 2-(2-Hydroxyphenyl)-benztriazol-derivate. |
-
1987
- 1987-08-12 US US07/084,608 patent/US4868246A/en not_active Expired - Fee Related
-
1988
- 1988-04-19 CA CA000564522A patent/CA1336028C/en not_active Expired - Fee Related
- 1988-08-11 BR BR8804066A patent/BR8804066A/pt active Search and Examination
- 1988-08-11 JP JP63199053A patent/JPS6466210A/ja active Pending
- 1988-08-12 ES ES88113135T patent/ES2054750T3/es not_active Expired - Lifetime
- 1988-08-12 DE DE88113135T patent/DE3880926T2/de not_active Expired - Fee Related
- 1988-08-12 EP EP88113135A patent/EP0303988B1/en not_active Expired - Lifetime
-
1993
- 1993-05-18 US US08/063,483 patent/US5319090A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA1336028C (en) | 1995-06-20 |
EP0303988B1 (en) | 1993-05-12 |
BR8804066A (pt) | 1989-03-07 |
US5319090A (en) | 1994-06-07 |
US4868246A (en) | 1989-09-19 |
DE3880926D1 (de) | 1993-06-17 |
JPS6466210A (en) | 1989-03-13 |
EP0303988A3 (en) | 1989-03-08 |
DE3880926T2 (de) | 1993-12-16 |
EP0303988A2 (en) | 1989-02-22 |
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Legal Events
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FG2A | Definitive protection |
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