MX166311B - Estabilizantes antioxidantes unidos al polimero - Google Patents
Estabilizantes antioxidantes unidos al polimeroInfo
- Publication number
- MX166311B MX166311B MX012323A MX1232388A MX166311B MX 166311 B MX166311 B MX 166311B MX 012323 A MX012323 A MX 012323A MX 1232388 A MX1232388 A MX 1232388A MX 166311 B MX166311 B MX 166311B
- Authority
- MX
- Mexico
- Prior art keywords
- polymer
- units
- stabilizers
- combinations
- class
- Prior art date
Links
- 239000003381 stabilizer Substances 0.000 title abstract 3
- 239000003963 antioxidant agent Substances 0.000 title abstract 2
- 230000003078 antioxidant effect Effects 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 3
- 125000006705 (C5-C7) cycloalkyl group Chemical group 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 150000003336 secondary aromatic amines Chemical class 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
La presente invención se refiere a un polímero con unidades recurrentes seleccionadas de las fórmulas: o ambas, en donde las unidades se presentan ya sea en la estructura del polímero, sobre las cadenas laterales injertadas, como unidades pendientes, o combinaciones de las mismas y en donde x es O o 1, R1 y R2 se seleccionan independientemente de hidrógeno, alquilo de 1 a 6 átomos de carbono, cicloalquilo de 5 a 7 átomos de carbono, fenilo, cloro o bromo, y cada -N-('G) es el residuo de un grupo estabilizante hidrazido substituído, seleccionado de a) fenoles impedidos, b) sulfuros de dialquilo, c) aminas aromáticas secundarias, y d) benzotiazoles o bencimidales, con la condición de que sólamente una clase del estabilizante antioxidante seleccionada de (a) a (d) se una al polímero, pero que se permitan combinaciones múltiples de estabilizantes dentro de la misma clase.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/084,537 US4857596A (en) | 1987-08-12 | 1987-08-12 | Polymer bound antioxidant stabilizers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX166311B true MX166311B (es) | 1992-12-29 |
Family
ID=22185589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX012323A MX166311B (es) | 1987-08-12 | 1988-07-19 | Estabilizantes antioxidantes unidos al polimero |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4857596A (es) |
| EP (1) | EP0306729B1 (es) |
| JP (1) | JPS6466209A (es) |
| BR (1) | BR8804073A (es) |
| CA (1) | CA1328326C (es) |
| DE (1) | DE3867976D1 (es) |
| ES (1) | ES2028210T3 (es) |
| MX (1) | MX166311B (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5043372A (en) * | 1989-12-22 | 1991-08-27 | Atochem North America, Inc. | N,N'-hydrocarbylenebis[N-hals-substituted amic acid hydrazides] and their derivatives |
| US5981065A (en) * | 1992-05-26 | 1999-11-09 | Union Carbide Chemicals & Plastics Technology Corporation | Telephone cables |
| CA2116167C (en) * | 1993-03-15 | 2007-05-15 | Myron W. Shaffer | One-component coating compositions containing oxime- or lactam-blocked polyisocyanates which have improved resistance to yellowing |
| US5510443A (en) * | 1993-03-15 | 1996-04-23 | Bayer Corporation | Process for preparing a coating with improved resistance to yellowing and the resulting coating |
| BR9712617A (pt) * | 1996-10-31 | 1999-10-26 | Ciba Sc Holding Ag | Polìmeros funcionalizados |
| JP3816697B2 (ja) * | 1999-07-07 | 2006-08-30 | 大日精化工業株式会社 | 重合体が結合した機能剤、その製造方法、それらの使用方法及びそれらを使用した物品 |
| US7595074B2 (en) * | 2002-04-05 | 2009-09-29 | University Of Massachusetts Lowell | Polymeric antioxidants |
| EP1492856A4 (en) * | 2002-04-05 | 2010-11-10 | Univ Massachusetts Lowell | POLYMER ANTIOXIDANTS |
| EP1727807B1 (en) * | 2003-12-25 | 2007-07-18 | Council of Scientific and Industrial Research | Antiozonant based functionalized benzotriazole uv absorbers and the process thereof |
| EP1846460A2 (en) * | 2004-01-21 | 2007-10-24 | University Of Massachusetts Lowell | Post-coupling synthetic approach for polymeric antioxidants |
| JP2008507613A (ja) * | 2004-07-23 | 2008-03-13 | ポルノクス コーポレーション | 抗酸化マクロモノマーおよび抗酸化ポリマー、ならびにその作製方法および使用方法 |
| EP1817393A2 (en) * | 2004-12-03 | 2007-08-15 | Polnox Corporation | Process for the synthesis of polyalkylphenol antioxidants |
| US20060128939A1 (en) * | 2004-12-03 | 2006-06-15 | Vijayendra Kumar | One pot process for making polymeric antioxidants |
| WO2006060802A1 (en) * | 2004-12-03 | 2006-06-08 | Polnox Corporation | Synthesis of sterically hindered phenol based macromolecular antioxidants |
| EP1828104A1 (en) | 2004-12-03 | 2007-09-05 | Polnox Corporation | Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers |
| EP1861484A2 (en) | 2005-02-22 | 2007-12-05 | Polnox Corporation | Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis , performances and applications |
| EP1866279A2 (en) * | 2005-03-25 | 2007-12-19 | Polnox Corporation | Alkylated and polymeric macromolecular antioxidants and methods of making and using the same |
| US20070106059A1 (en) * | 2005-10-27 | 2007-05-10 | Cholli Ashok L | Macromolecular antioxidants and polymeric macromolecular antioxidants |
| WO2007050991A1 (en) * | 2005-10-27 | 2007-05-03 | Polnox Corporation | Stabilized polyolefin compositions |
| US7705176B2 (en) * | 2005-10-27 | 2010-04-27 | Polnox Corporation | Macromolecular antioxidants based on sterically hindered phenols and phosphites |
| WO2007064843A1 (en) | 2005-12-02 | 2007-06-07 | Polnox Corporation | Lubricant oil compositions |
| WO2008005358A2 (en) | 2006-07-06 | 2008-01-10 | Polnox Corporation | Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same |
| US7767853B2 (en) | 2006-10-20 | 2010-08-03 | Polnox Corporation | Antioxidants and methods of making and using the same |
| US8557226B2 (en) * | 2009-01-16 | 2013-10-15 | Isp Investments Inc. | Performance-boosting UV-absorbing compounds |
| US9044623B2 (en) | 2009-01-27 | 2015-06-02 | Isp Investments Inc. | Polymer-bound UV absorbers in personal care compositions |
| WO2015077635A2 (en) | 2013-11-22 | 2015-05-28 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures methods of making and using the same |
| JP6424868B2 (ja) * | 2016-09-07 | 2018-11-21 | 信越化学工業株式会社 | シラン変性共重合体、その製造方法および密着向上剤 |
| WO2018160879A2 (en) | 2017-03-01 | 2018-09-07 | Polnox Corporation | Macromolecular corrosion (mcin) inhibitors: structures, methods of making and using the same |
| US10584234B1 (en) | 2017-06-28 | 2020-03-10 | Firestone Industrial Products Company, Llc | Antioxidant precursors for elastomeric compositions |
| EP4114871A4 (en) * | 2020-03-03 | 2024-05-22 | Advanced Polyolefin Technologies LLC | FUNCTIONAL POLYOLEFIN POLYMERS AND PRODUCTION THEREOF |
| WO2023034552A1 (en) * | 2021-09-03 | 2023-03-09 | Advanced Polyolefin Technologies Llc | Polyolefin polymer incorporating hindered phenol and manufacture thereof |
Family Cites Families (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA677494A (en) * | 1964-01-07 | O. Tawney Pliny | 2,6-di-t-butyl-4-(n-maleimidomethyl)-phenol | |
| NL88611C (es) * | 1951-09-10 | |||
| US2989517A (en) * | 1954-05-06 | 1961-06-20 | Dow Chemical Co | Polymerization method |
| US2971939A (en) * | 1959-01-30 | 1961-02-14 | Monsanto Chemicals | Process for preparing homogeneous copolymers of a vinylidene monomer and a maleic monomer and product thereof |
| US3336267A (en) * | 1960-06-02 | 1967-08-15 | Dow Chemical Co | Continuous preparation of thermoplastic copolymers and terpolymers of unsaturated cyclic anhydrides |
| JPS442719Y1 (es) * | 1964-08-07 | 1969-01-31 | ||
| GB1117515A (en) * | 1966-07-08 | 1968-06-19 | Ici Ltd | Maleic anhydride/alkyl vinyl ether copolymer |
| JPS4626859Y1 (es) * | 1966-12-30 | 1971-09-14 | ||
| US3488311A (en) * | 1967-01-19 | 1970-01-06 | Gulf Research Development Co | Ammonium hydroxide polymer solutions for floor polish compositions |
| JPS4424274Y1 (es) * | 1967-03-31 | 1969-10-14 | ||
| US3522992A (en) * | 1967-06-28 | 1970-08-04 | North American Rockwell | Geodetic survey system and digital phase-meter therefor |
| US3509110A (en) * | 1968-04-03 | 1970-04-28 | Koppers Co Inc | Vinyl aryl monomer-half ester copolymers by suspension polymerization |
| US3755354A (en) * | 1969-05-05 | 1973-08-28 | Gen Electric | Amide acid and imido-substituted organosilanes |
| US3560455A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 20 to 30 carbon atoms |
| US3560457A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 12 to 14 carbon atoms |
| US3560456A (en) * | 1969-05-26 | 1971-02-02 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having from 16 to 18 carbon atoms |
| US3553177A (en) * | 1969-05-26 | 1971-01-05 | Gulf Research Development Co | Process of forming copolymers of maleic anhydride and an aliphatic olefin having at least 30 carbon atoms |
| US3555001A (en) * | 1969-05-29 | 1971-01-12 | Monsanto Co | Process for the fractionation of plasma and serum using water-insoluble polyelectrolytes containing diloweralkylaminoloweralkylimide groups |
| US3658769A (en) * | 1969-06-23 | 1972-04-25 | Goodyear Tire & Rubber | Age resistant polymeric compositions containing amide segmeric units |
| US3767628A (en) * | 1969-06-23 | 1973-10-23 | Goodyear Tire & Rubber | Age resisters and age resistant polymeric compositions |
| US3657197A (en) * | 1970-05-07 | 1972-04-18 | Gaf Corp | Photosensitive propargyl polymer derivatives |
| US3723375A (en) * | 1970-11-24 | 1973-03-27 | Gaf Corp | Novel anhydride interpolymers |
| US4152319A (en) * | 1972-06-30 | 1979-05-01 | The Goodyear Tire & Rubber Company | Age resistors and age resistant polymeric compositions |
| US3998907A (en) * | 1972-08-29 | 1976-12-21 | Arco Polymers, Inc. | Rubber-modified dicarboxylic acid imide copolymers |
| US3919354A (en) * | 1972-09-08 | 1975-11-11 | Dow Chemical Co | Impact resistant polymers of a resinous copolymer of an alkenyl aromatic monomer and unsaturated dicarboxylic anhydride |
| CH579549A5 (es) * | 1973-01-18 | 1976-09-15 | Ciba Geigy Ag | |
| US4066616A (en) * | 1974-03-19 | 1978-01-03 | Ciba-Geigy Corporation | Hydroxyaryl hydantoins and their use as stabilizers |
| US4078091A (en) * | 1975-04-04 | 1978-03-07 | Dynapol | Polymeric N-substituted maleimide antioxidants |
| JPS51136782A (en) * | 1975-05-23 | 1976-11-26 | Mitsui Petrochem Ind Ltd | Process for introducing aromatics into olefinic copolymer |
| DE2534613A1 (de) * | 1975-08-02 | 1977-02-17 | Basf Ag | Bernsteinsaeurehydrazid-einheiten enthaltende copolymerisate |
| US4048263A (en) * | 1975-12-29 | 1977-09-13 | Monsanto Company | Rubber modified fire retardant polymer compositions |
| US4097551A (en) * | 1976-12-20 | 1978-06-27 | Arco Polymers, Inc. | Rubber modified dicarboxylic acid copolymer blends |
| US4197370A (en) * | 1976-12-27 | 1980-04-08 | General Electric Company | Foamable polyphenylene oxide composition with thermally unstable copolymer as foaming agent |
| US4341695A (en) * | 1977-12-27 | 1982-07-27 | Monsanto Company | Rubber modified terpolymers with improved heat distortion resistance |
| US4238572A (en) * | 1979-11-16 | 1980-12-09 | Monsanto Company | Foamable ABS polyblend composition |
| JPS56139541A (en) * | 1980-04-03 | 1981-10-31 | Japan Synthetic Rubber Co Ltd | Rubberlike polymer composition |
| DE3024525A1 (de) * | 1980-06-28 | 1982-02-04 | Chemische Werke Hüls AG, 4370 Marl | Kationische maleinsaeureanhydrid-homo- und copolymerisate sowie deren verwendung |
| US4381373A (en) * | 1980-12-11 | 1983-04-26 | Mitsubishi Monsanto Chemical Company | Heat resistant resin composition |
| US4358573A (en) * | 1981-05-29 | 1982-11-09 | S. C. Johnson & Son, Inc. | Waxy maleic anhydride alpha olefin terpolymers |
| CA1231500A (en) * | 1981-10-07 | 1988-01-12 | Richard M. Kopchik | Thermoplastic, non-crosslinked anhydride polymers, imide polymers, and process for preparation |
| US4486570A (en) * | 1982-01-25 | 1984-12-04 | Atlantic Richfield Company | Heat resistant high impact polymer compositions and method of making same |
| CA1227598A (en) * | 1982-01-25 | 1987-09-29 | Zenon Joffe | Method for making thermoplastics with bound stabilizers |
| US4452939A (en) * | 1983-02-28 | 1984-06-05 | The Goodyear Tire & Rubber Company | Process for the preparation of high molecular weight polymeric antidegradants |
| US4522983A (en) * | 1983-03-09 | 1985-06-11 | Atlantic Richfield Company | Polymeric molding composition |
| JPS59221314A (ja) * | 1983-05-31 | 1984-12-12 | Kyowa Gas Chem Ind Co Ltd | メタクリル共重合体の製造方法 |
| JPS59221315A (ja) * | 1983-05-31 | 1984-12-12 | Kyowa Gas Chem Ind Co Ltd | メタクリル共重合体の製造方法 |
| EP0133164B1 (de) * | 1983-07-26 | 1988-12-14 | Ciba-Geigy Ag | Copolymerisierbare Verbindungen |
| US4481337A (en) * | 1983-09-19 | 1984-11-06 | The Goodyear Tire & Rubber Company | Process for the preparation of modified polymers |
| NL8403606A (nl) * | 1983-12-09 | 1985-07-01 | Ciba Geigy | Biocide polymeren, samenstellingen die deze polymeren bevatten, werkwijzen ter bereiding van deze polymeren alsmede de toepassing daarvan als algiciden. |
| US4694048A (en) * | 1986-04-21 | 1987-09-15 | Celanese Corporation | Thermoplastic polymers containing repeating hydrazide groups |
-
1987
- 1987-08-12 US US07/084,537 patent/US4857596A/en not_active Expired - Fee Related
-
1988
- 1988-06-07 CA CA000568862A patent/CA1328326C/en not_active Expired - Fee Related
- 1988-07-19 MX MX012323A patent/MX166311B/es unknown
- 1988-08-09 JP JP63197297A patent/JPS6466209A/ja active Pending
- 1988-08-11 BR BR8804073A patent/BR8804073A/pt active Search and Examination
- 1988-08-12 EP EP88113130A patent/EP0306729B1/en not_active Expired
- 1988-08-12 ES ES198888113130T patent/ES2028210T3/es not_active Expired - Lifetime
- 1988-08-12 DE DE8888113130T patent/DE3867976D1/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0306729A1 (en) | 1989-03-15 |
| DE3867976D1 (de) | 1992-03-05 |
| BR8804073A (pt) | 1989-03-07 |
| CA1328326C (en) | 1994-04-05 |
| EP0306729B1 (en) | 1992-01-22 |
| JPS6466209A (en) | 1989-03-13 |
| US4857596A (en) | 1989-08-15 |
| ES2028210T3 (es) | 1992-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX166311B (es) | Estabilizantes antioxidantes unidos al polimero | |
| MX166313B (es) | Fotoestabilizadores de amina impedida, ligados a polimeros | |
| ES2163573T3 (es) | Copolimeros de esteres de poliaminoacidos. | |
| ES2054750T3 (es) | Estabilizantes de uv unidos a polimeros. | |
| MX168740B (es) | Intermediarios de copolimeros de etileno alfaolefina, de bajo peso molecular | |
| ES2139926T3 (es) | Elastomeros termoestables. | |
| ES2054838T3 (es) | Poliesteramidas y polieteresteramidas - su procedimiento de fabricacion. | |
| ES2166374T3 (es) | Composiciones de derivados de polifenoles y su preparacion. | |
| ES2142379T3 (es) | Fosfitos ciclicos como estabilizadores de polimeros. | |
| ES2042660T3 (es) | Estabilizantes multifuncionales unidos a polimeros. | |
| ES2000379A6 (es) | Composiciones de moldeo termoplasticas de procesabilidad mejorada | |
| ES2099013B1 (es) | Nuevos compuestos de polimetilpiperidina con grupos de silano y su uso como estabilizantes para materiales organicos. | |
| ES2158077T3 (es) | Carboxanilidas oxidiacinicas artropodicidas. | |
| ES2045126T3 (es) | Agentes terapeuticos. | |
| ES2043725T3 (es) | Aminofenil-carbamatos substituidos. | |
| ES2054268T3 (es) | Aditivos polimericos. | |
| ES8801622A1 (es) | Un procedimiento para preparar derivados arilicos de dienamidas | |
| DE3750196D1 (de) | Verstärkte schlagzähe Styrolpolymere mit verbesserten physischen Eigenschaften. | |
| DE69128546D1 (de) | Ethylen-Penten-Copolymerzusammensetzungen | |
| TW358823B (en) | Molding materials comprising a polycarbonate blend and a siloxane network rubber | |
| ES2001228A6 (es) | Procedimiento para la obtencion de policarbonatos ramificados, solubles y de alto peso molecular | |
| ES2053518T3 (es) | Nuevos complejos de haluros de bismuto o antimonio con aminas, apropiadas como retardadores de combustion para polimeros y composiciones polimericas que los contienen. | |
| ES2122627T3 (es) | Derivados peptidicos que poseen una actividad inhibidora de metalopeptidasas. | |
| ES2078263T3 (es) | Compuestos de lacado para automoviles. | |
| ES2169816T3 (es) | Alcoholes lipidicos como nuevos medicamentos supresores de inmunidad y anti-viricos. |