ES2054441T3 - Catalizador para producir anhidrido ftalico. - Google Patents

Catalizador para producir anhidrido ftalico.

Info

Publication number
ES2054441T3
ES2054441T3 ES91302270T ES91302270T ES2054441T3 ES 2054441 T3 ES2054441 T3 ES 2054441T3 ES 91302270 T ES91302270 T ES 91302270T ES 91302270 T ES91302270 T ES 91302270T ES 2054441 T3 ES2054441 T3 ES 2054441T3
Authority
ES
Spain
Prior art keywords
sub
parts
catalyst
phthalic anhydride
niobio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91302270T
Other languages
English (en)
Inventor
Kenji Ueda
Tatsuya Kawabata
Masaaki Okuno
Chisako Nishio
Shinya Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of ES2054441T3 publication Critical patent/ES2054441T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/682—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium, tantalum or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)

Abstract

LA INVENCION PRESENTA CATALIZADORES PARA PRODUCIR ANHIDRIDO FTALICO MEDIANTE LA OXIDACION CATALITICA DE LA FASE DE VAPOR DE ORTOXILENO Y/O NAFTALENO CON OXIGENO MOLECULAR O UN GAS QUE CONTENGA OXIGENO MOLECULAR. EL CATALIZADOR SE PREPARA SOPORTANDO UNA SUBSTANCIA CATALITICAMENTE ACTIVA QUE COMPRENDE ENTRE 1 Y 20 PARTES DE OXIDO DE VANADIO COMO V SUB 2 O SUB 3 ENTRE 99 Y 80 PARTES DE ANASTASO DEL TIPO DEL DIOXIDO DE TITANIO CON UN AREA DE SUPERFICIE ESPECIFICA DE ENTRE 10 Y 60 M (AL CUADRADO) /G TIO SUB 2 Y POR CADA 100 PARTES DE LA SUMA DE ESTOS DOS INGREDIENTES, ENTRE 0.05 Y 1.2 PARTES DE AL MENOS UN ELEMENTO SELECCIONADO ENTRE POTASIO, CESIO, RUBIDIO Y TALIO EN FORMA DE OXIDO, Y ENTRE 0.05 Y 2 PARTES DE PLATA, COMO AG SUB 2 O SOBRE UN PORTADOR INORGANICO RESISTENTE AL CALOR. EL CATALIZADOR PUEDE TAMBIEN CONTENER, POR CADA 100 PARTES DEL TOTAL DEL OXIDO DE VANADIO Y EL DIOXIDO DE TITANIO, ENTRE 0 Y 1 PARTE DE NIOBIO COMO NB SUB 2 O SUB 5, ENTRE 0 Y 1.2 PARTES DE FOSFORO COMO P SUB 2 O SUB3, Y ENTRE 0 Y 5 PARTES DE ANTIMONIO COMO SB SUB 2 O SUB 3 (POR SUPUESTO, QUE LOS CONTENIDOS DE NIOBIO, FOSFORO Y ANTIMONIO NO PUEDEN SER 0 AL MISMO TIEMPO).
ES91302270T 1990-03-16 1991-03-15 Catalizador para producir anhidrido ftalico. Expired - Lifetime ES2054441T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6397590 1990-03-16

Publications (1)

Publication Number Publication Date
ES2054441T3 true ES2054441T3 (es) 1994-08-01

Family

ID=13244794

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91302270T Expired - Lifetime ES2054441T3 (es) 1990-03-16 1991-03-15 Catalizador para producir anhidrido ftalico.

Country Status (10)

Country Link
US (1) US5169820A (es)
EP (1) EP0447267B1 (es)
KR (1) KR950008197B1 (es)
CN (1) CN1024092C (es)
AT (1) ATE106278T1 (es)
AU (1) AU641987B2 (es)
BR (1) BR9101046A (es)
DE (1) DE69102169T2 (es)
ES (1) ES2054441T3 (es)
RU (1) RU2047351C1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5235071A (en) * 1991-07-10 1993-08-10 Nippon Shokubai Co., Ltd. Catalyst for producing phthalic anhydride and process by using the same
DE59605306D1 (de) * 1995-03-15 2000-06-29 Basf Ag Verfahren zur herstellung von phosphordotierten silberkatalysatoren
US5736483A (en) * 1996-10-25 1998-04-07 Scientific Design Co., Inc. Niobium or tantalum promoted silver catalyst
DE19707943C2 (de) * 1997-02-27 1999-07-08 Basf Ag Verfahren zur Herstellung von Phthalsäureanhydrid und Katalysator hierfür
DE19851786A1 (de) 1998-11-10 2000-05-11 Basf Ag Silber- und Vanadiumoxid enthaltendes Multimetalloxid und dessen Verwendung
DE10022103A1 (de) * 2000-05-08 2001-11-15 Basf Ag Silber, Vanadium und ein oder mehrere Elemente der Phosphorgruppe enthaltendes Multimetalloxid und dessen Verwendung
ZA200200049B (en) * 2001-01-25 2002-07-16 Nippon Catalytic Chem Ind Fixed-bed shell-and-tube reactor and its usage.
US6657068B2 (en) 2002-03-22 2003-12-02 General Electric Company Liquid phase oxidation of halogenated ortho-xylenes
US6657067B2 (en) 2002-03-22 2003-12-02 General Electric Company Method for the manufacture of chlorophthalic anhydride
US6649773B2 (en) 2002-03-22 2003-11-18 General Electric Company Method for the manufacture of halophthalic acids and anhydrides
KR100549777B1 (ko) * 2002-03-28 2006-02-06 한국전력기술 주식회사 넓은 활성온도 대역을 갖는 질소산화물 및/또는 다이옥신제거용 삼산화 바나듐을 포함한 바나듐/티타니아계 촉매
DE10323461A1 (de) * 2003-05-23 2004-12-09 Basf Ag Herstellung von Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden mittels Vanadiumoxid, Titandioxid und Antimonoxid enthaltender Katalysatoren
DE10334132A1 (de) * 2003-07-25 2005-04-07 Basf Ag Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung
DE102004014918A1 (de) 2004-03-26 2005-10-13 Basf Ag Katalysator mit einer Silber-Vanadiumoxidphase und einer Promotorphase
US8097558B2 (en) * 2004-05-29 2012-01-17 Sud-Chemie Ag Catalyst and method for producing phthalic anhydride
US7541489B2 (en) 2004-06-30 2009-06-02 Sabic Innovative Plastics Ip B.V. Method of making halophthalic acids and halophthalic anhydrides
DE102008044890B4 (de) 2008-08-29 2023-09-14 Stesatec Gmbh Katalysator für die katalytische Gasphasenoxidation von aromatischen Kohlenwasserstoffen zu Aldehyden, Carbonsäuren und/oder Carbonsäureanhydriden, insbesondere zu Phthalsäureanhydrid, sowie Verfahren zur Herstellung eines solchen Katalysators
CN102039205B (zh) * 2009-10-21 2012-09-12 中国石油化工股份有限公司 整体式氮氧化物选择性还原催化剂及其制备方法
JP2011121048A (ja) * 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法
US9573119B2 (en) 2011-09-16 2017-02-21 Eastman Chemical Company Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8883672B2 (en) * 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US9029289B2 (en) 2012-07-16 2015-05-12 Basf Se Catalyst for preparing carboxylic acids and/or carboxylic anhydrides
WO2014013397A2 (de) * 2012-07-16 2014-01-23 Basf Se Katalysator zur herstellung von carbonsäuren und/oder carbonsäureanhydriden
EP3047904A1 (en) 2015-01-22 2016-07-27 Basf Se Catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1162348B (de) * 1961-04-28 1964-02-06 Basf Ag Verfahren zur Herstellung von Phthalsaeureanhydrid
DE1642921C3 (de) * 1965-05-18 1978-11-23 Basf Ag, 6700 Ludwigshafen Vanadium- und titanhaltiger Trägerkatalysator
GB1368626A (en) * 1970-08-26 1974-10-02 Rhone Progil Catalyst for the oxidation of ortho-xylene to phthalic anhydride
DE2260615A1 (de) * 1972-12-12 1974-06-20 Basf Ag Traegerkatalysator fuer die oxidation von o-xylol oder naphthalin zu phthalsaeureanhydrid
JPS5143732A (en) * 1974-10-11 1976-04-14 Nippon Catalytic Chem Ind Musuifutarusanno seizohoho
JPS603307B2 (ja) * 1978-11-29 1985-01-26 株式会社日本触媒 無水フタル酸の製造方法
DE2914683A1 (de) * 1979-04-11 1980-10-16 Basf Ag Vanadium- und titan- und/oder zirkonhaltiger traegerkatalysator
JPS591378B2 (ja) * 1979-12-03 1984-01-11 株式会社日本触媒 無水フタル酸製造用触媒
IT1193930B (it) * 1980-04-02 1988-08-31 Alusuisse Italia Spa Catalizzatore per la fabbricazione di anidride ftalica

Also Published As

Publication number Publication date
KR910016378A (ko) 1991-11-05
ATE106278T1 (de) 1994-06-15
CN1024092C (zh) 1994-03-30
DE69102169T2 (de) 1994-10-20
EP0447267A1 (en) 1991-09-18
KR950008197B1 (ko) 1995-07-26
RU2047351C1 (ru) 1995-11-10
EP0447267B1 (en) 1994-06-01
BR9101046A (pt) 1991-11-05
AU641987B2 (en) 1993-10-07
AU7273291A (en) 1991-09-19
DE69102169D1 (de) 1994-07-07
CN1054726A (zh) 1991-09-25
US5169820A (en) 1992-12-08

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