EP4355847A1 - Composition en comprimé monodose - Google Patents

Composition en comprimé monodose

Info

Publication number
EP4355847A1
EP4355847A1 EP22731591.8A EP22731591A EP4355847A1 EP 4355847 A1 EP4355847 A1 EP 4355847A1 EP 22731591 A EP22731591 A EP 22731591A EP 4355847 A1 EP4355847 A1 EP 4355847A1
Authority
EP
European Patent Office
Prior art keywords
unit
tablet composition
dose tablet
water
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP22731591.8A
Other languages
German (de)
English (en)
Inventor
Girish Muralidharan
Rajeesh Kumar Ramachandran
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever Global IP Ltd
Unilever IP Holdings BV
Original Assignee
Unilever Global IP Ltd
Unilever IP Holdings BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Global IP Ltd, Unilever IP Holdings BV filed Critical Unilever Global IP Ltd
Publication of EP4355847A1 publication Critical patent/EP4355847A1/fr
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof

Definitions

  • the present invention relates to unit dose tablet compositions.
  • the invention further relates to a process for making such compositions, and methods of treating surfaces with such compositions.
  • Unit dose cleaning compositions such as detergent tablets are one of the most consumer preferred products, due to ease of handling, dosage and storage. Such compositions are used to clean surfaces, such as bathroom surfaces, kitchen surfaces as well as to clean laundry surfaces.
  • a low compression force improves dissolution but at the expense of tablet strength. This problem is compounded by the fact that conventional tablet compositions have relatively poor long-term storage-stability characteristics and, to compensate, have to be manufactured to a higher compression specification.
  • WO 2000/43488A1 discloses a detergent tablet for use in a washing machine, the tablet having one or more phases at least one of which is in the form of a compressed particulate solid comprising: a) a polymeric disintegrant having a particle size distribution such that at least 90 % by weight thereof has a particle size below about 0.3mm and at least 30 % by weight thereof has a particle size below about 0.2mm; and b) a water-soluble hydrated salt having a solubility in distilled water of at least about 25g/100g at 25 °C.
  • the detergent tablets of W00043488A1 still suffer from poor dissolvability when added to a bowl of water meaning that the detergent tablets do not meet consumer expectations, in particular in washing laundry.
  • GB 2 339575 A discloses cellulose disintegrant for detergent compositions.
  • DE 19843938 A1 discloses washing and cleaning agent shaped bodies which, as preparation components, contain substances selected from the group of alkali sulfates and/or alkaline-earth sulfates and/or alkaline-earth carbonates and/or alkaline-earth phosphates and/or alkaline-earth citrates. These shaped bodies are said to comprise advantageous properties with regard to application techniques if at least 60 weight percent of the designated alkali salts and/or alkaline-earth salts comprise particle sizes greater than 600 micrometers.
  • US 2002/155976 A1 discloses a tablet of compacted particulate detergent composition comprising non-soap surfactant and detergency builder, and; a) disintegration-promoting particles comprising water-insoluble disintegrant which can swell to at least twice its volume on contact with water, and a water-absorbent carrier which so swells to a lesser extent, and b) water-soluble polymeric binder solid at 25 degrees centigrade, and either c) comprising 2 to 30 percent wt.
  • water-soluble disintegration-promoting particles comprising at least 40 percent of materials selected from; compounds with water solubility at 20 degrees centigrade of at least 50 grams per 100 grams of water phase I sodium tripolyphosphate sodium tripolyphosphate that contains water of hydration in an amount which is at least 0.5 percent wt. of the sodium tripolyphosphate in the particles, or d) having a diametral fracture stress of at least 14 kPa.
  • the tablets are said to exhibit good disintegration properties.
  • US 2008/135062 A1 discloses a disinfecting tablet having rapid disintegration and low friability.
  • the disinfecting tablet comprises sodium dichloro isocyanurate dihydrate and at least one swellable disintegrating agent assisting with rapid disintegration of the tablet.
  • a disinfecting cleaning tool assembly and a method of cleaning.
  • US 4 013581 A discloses peroxygen bleaches, especially diperazelaic acid, are provided in tablet form useful for bleaching fabrics.
  • a unit-dose tablet composition comprising: a) a swellable disintegrant selected from microcrystalline cellulose, sodium starch glycolate and mixtures thereof; b) a non-swellable disintegrant selected from polyvinyl pyrrolidone, calcium silicate, starch, magnesium stearate and mixtures thereof; c) a water-soluble salt having a solubility in distilled water of in the range of 0.5 g/100 ml_ to 75 g/100 mL at 25 °C; d) an effervescent; and e) a surfactant.
  • the present invention provides a process for preparing a unit dose tablet composition, comprising the steps of: a) providing a mix comprising: i) at least one surfactant; ii) a water-soluble salt having a solubility in distilled water in the range of 0.5 g/100 to 75 g/100 mL at 25 °C; iii) an effervescent; iv) a swellable disintegrant selected from microcrystalline cellulose, sodium starch glycolate and mixtures thereof; and, v) a non-swellable disintegrant, selected from polyvinyl pyrrolidone, calcium silicate, starch, magnesium stearate and mixtures thereof; b) compressing the mix to provide a unit dose tablet composition.
  • step b) is carried out at pressure in the range of 2.5 to 100 kgf/cm 2 .
  • the present invention provides a method of cleaning a surface comprising the step of dissolving a unit-dose tablet composition as defined herein in water to provide a solution of the cleaning composition, and contacting the surface with the cleaning composition, preferably wherein the surface is a hard surface, a soft surface or a laundry surface.
  • the present invention provides a use of a unit-dose tablet composition as defined herein for cleaning a surface, preferably wherein the surface is a hard surface, a soft surface or a laundry surface.
  • the unit dose tablet composition comprises a swellable disintegrant and a non-swellable disintegrant.
  • a swellable disintegrant is one which has a water absorption ratio (WAR) of greater than 1 and a non-water swellable disintegrant is one which has a water absorption ratio of less than 1.
  • Water Absorption Ratio is a measure as to how much water a material absorbs under controlled and defined conditions. The process described in ASTM D570 is used in this application.
  • the swellable disintegrant is selected from microcrystalline cellulose, sodium starch glycolate and mixtures thereof.
  • the swellable disintegrant comprises from 1 to 20% wt. of the unit dose tablet composition, more preferably from 2 to 18% wt. and most preferably from 5 to 15% wt.
  • the non-swellable disintegrant is selected from polyvinyl pyrrolidone, calcium silicate, starch, magnesium stearate and mixtures thereof.
  • the non-swellable disintegrant comprises from 1 to 10% wt. of the unit dose tablet composition, more preferably from 1.5 to 8% wt. and most preferably from 2 to 5% wt.
  • the water-soluble salt has a solubility of at least 0.5 g/100 ml_ at 25 °C, preferably at least 1 g/100 ml_, more preferably at least 5 g/100 ml_, and most preferably at least 10 g/100 ml_ at 25 °C.
  • the water-soluble salt has a solubility of at most 75 g/100 ml_, more preferably at most 70 g/100 ml_ at 25 °C, even more preferably at most 60 g/100 ml_.
  • the water-soluble salt has a solubility of in the range of 0.5 g/100 ml_ to 75 g/100 ml_ at 25 °C, preferably 1 g/100 ml_ to 70 g /100 ml_ at 25 °C, more preferably 5 g/100 mL to 65 g/100 ml_ at 25 °C, even more preferably 10 g/100 mL to 60 g/100 ml_.
  • the composition preferably comprises a water-soluble salt that is selected from anhydrous forms or hydrates of salts of mono or divalent alkali metals, preferably anhydrous forms or hydrates of salts of mono alkali metals, more preferably wherein the mono alkali metals is sodium or potassium.
  • the anhydrous forms or hydrates of salts of mono alkali metals is selected from the group consisting of sodium chloride, sodium sulphate, sodium hydrogen carbonate, potassium chloride, potassium sulphate, potassium hydrogen carbonate and mixtures thereof.
  • the unit-dose tablet composition preferably comprises 0.1 to 20 wt.% water soluble salt, preferably 1 to 15 wt.%, more preferably 5 to 10 wt.%.
  • the composition comprises an effervescent.
  • Suitable effervescents include organic acids such as citric acid, tartaric acid, fumaric acid, malic acid, adipic acid, succinic acid, and a carbonate salt.
  • Preferred carbonate salts include sodium carbonate, potassium carbonate, calcium carbonate, sodium bicarbonate, potassium bicarbonate, calcium carbonate, calcium bicarbonate and magnesium carbonate as well as mixtures thereof.
  • the level of effervescent is from 1 to 20% wt. of the composition, more preferably from 2 to 10% wt. of the composition.
  • tablets comprise high amounts of filler however, we have found that this level may be significantly reduced thanks to the discovery that the claimed combination of disintegrants improve disintegration without such high levels of fillers.
  • composition is also advantageous in that it requires less filler than typical tablet dose compositions.
  • the unit dose cleaning composition comprises no more than 15% filler, more preferably no more than 10% wt. and most preferably no more than 7% filler.
  • the composition comprises some filler though and this should be at least 5% wt. of the composition.
  • Fillers suitable for use in the composition include calcium carbonate, zeolite, clays such as bentonite, dolomite and combinations thereof.
  • the unit-dose tablet composition preferably has a diametral fracture stress (DFS) ratio of DFSair/DFSwater of at least 6, preferably at least 7, preferably at least 8 more preferably at least 9.
  • DFS diametral fracture stress
  • the unit-dose cleaning composition has a diametral fracture stress (DFS) ratio of DFSair/DFSwater in the range of 6 to 50, preferably 7 to 45.
  • DFS diametral fracture stress
  • the DFSair/DFSwater ratio can be measured using techniques known to the skilled person.
  • the DFS can be measured using a texture analyser, for example a CT3 Brookfield Texture Analyser.
  • the DFSair/DFSwater can be measured using a TA instrument, model TA-XT2i and the Texture Experte software (Texture Technologies Corp., Scarsdale, NY, USA/- Stable Micro Systems, Surrey, England, UK).
  • the instrument is calibrated with a 5 kg load cell and fitted with a stainless steel flat-bottomed cylindrical probe with 1 cm 2 surface area (Kobe probe).
  • the methodology consists in positioning the tablet to the flat surface of the probe.
  • the probe moves until a trigger force is detected at which point the TA is set to maintain a predetermined nominal force for a given period of time (60 sec).
  • the TA measures the penetration distance as the tablet is compressed while submerged in the medium (water).
  • a constant temperature of the medium of 18°C is maintained during the tests by means of a thermos stated double wall cell and a heating bath/circulator (Haake, Düsseldorf, Germany).
  • the unit-dose tablet composition comprises 1 to 80 wt.% surfactant system selected from anionic surfactants, cationic surfactants, non-ionic surfactants, amphoteric surfactants.
  • the unit dose tablet composition of the invention preferably comprises an anionic surfactant or a mixture of anionic surfactants.
  • Anionic surfactants are included in the composition for primary cleaning action by emulsifying the oil attached to the substrate. Any non-soap anionic surfactant known in the art for use in laundry detergents may be used herein. In general, these surfactants are described in well-known textbooks like "Surface Active Agents” Vol. 1, by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, Interscience 1958, and/or the current edition of "McCutcheon's Emulsifiers and Detergents” published by Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981.
  • a suitable class of anionic surfactants are water-soluble salts, particularly alkali metal (e.g., sodium or potassium), ammonium and alkylolammonium salts of organic sulphuric acid monoesters and sulphonic acids having in the molecular structure a branched or straight chain alkyl group and condensations products thereof containing 8 to 22 carbon atoms or an alkyl-aryl group containing 6 to 20 carbon atoms in the alkyl part.
  • alkali metal e.g., sodium or potassium
  • ammonium and alkylolammonium salts of organic sulphuric acid monoesters and sulphonic acids having in the molecular structure a branched or straight chain alkyl group and condensations products thereof containing 8 to 22 carbon atoms or an alkyl-aryl group containing 6 to 20 carbon atoms in the alkyl part.
  • Preferred anionic surfactants include higher alkyl aromatic sulphonates such as higher alkyl benzene sulphonates containing from 6 to 20 carbon atoms in the alkyl group in a straight or branched chain, particular examples of which are higher alkyl benzene sulphonates or of higher-alkyl toluene, xylene or phenol sulphonates, alkyl naphthalene sulphonates, diamyl naphthalene sulphonate, and dinonyl naphthalene sulphonate; alkyl sulphates containing 8 to 22 carbon atoms and alkyl ether sulphates containing from 1 to 10 ethylene oxide or propylene oxide, preferably 2 to 3 ethylene oxide units per molecule.
  • higher alkyl aromatic sulphonates such as higher alkyl benzene sulphonates containing from 6 to 20 carbon atoms in the alkyl group in a straight or
  • Non-limiting examples of the anionic surfactants include any of the common anionic surfactants such as linear or modified, e. g. branched alkylbenzene sulphonates, alkylpoly(ethoxylates), sodium lauryl ether sulphates, methyl ester sulphonates, primary alkyl sulphates or mixtures thereof.
  • the common anionic surfactants such as linear or modified, e. g. branched alkylbenzene sulphonates, alkylpoly(ethoxylates), sodium lauryl ether sulphates, methyl ester sulphonates, primary alkyl sulphates or mixtures thereof.
  • the non-soap anionic surfactant is present in the detergent composition in a concentration of 5 to 60%, preferably not less than 10%, more preferably not less than 12%, still more preferably not less than 15% but typically not more than 40%, preferably not more than 35% or even not more than 30% by weight of the total composition.
  • Anionic surfactant of the present invention may be combined with another surfactant generally chosen from non-ionic, cationic, amphoteric or zwitterionic surfactants.
  • anionic surfactant In view of the anionic character of the anionic surfactant, cationic, amphoteric or zwitterionic surfactants when added are added at concentrations that do not hinder the performance of the composition.
  • Suitable non-ionic surfactants include water soluble aliphatic ethoxylated nonionic surfactants commercially known, including the primary aliphatic alcohol ethoxylates and secondary aliphatic alcohol ethoxylates.
  • non-ionic surfactants include, but are not limited to, the Neodol (trade mark, ex Shell) ethoxylates, which are higher aliphatic, primary alcohol containing about 9 to 15 carbon atoms, such as C9 to C11 alkanol condensed with 4 to 10 moles of ethylene oxide (Neodol 91-8 or Neodol 91-5), C12-13 alkanol condensed with 6.5 moles ethylene oxide (Neodol 23-6.5), C12-15 alkanol condensed with 12 moles ethylene oxide (Neodol 25-12), C14- 15 alkanol condensed with 13 moles ethylene oxide (Neodol 45-13), and the like.
  • Neodol trade mark, ex Shell
  • ethoxylates which are higher aliphatic, primary alcohol containing about 9 to 15 carbon atoms, such as C9 to C11 alkanol condensed with 4 to 10 moles of ethylene oxide (Neo
  • Such ethoxamers have an HLB (hydrophobic lipophilic balance) value of about 8 to 15 and give good O/W emulsification, whereas ethoxamers with HLB values below 7 contain less than 4 ethyleneoxide groups and tend to be poor emulsifiers and poor detergents.
  • HLB hydrophobic lipophilic balance
  • Suitable amphoteric surfactants include derivatives of aliphatic secondary and tertiary amines containing an alkyl group of 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilizing group, such as sodium 3-dodecylamino- propionate, sodium 3- dodecylaminopropane sulphonate and sodium N-2-hydroxydodecyl-N-methyltaurate.
  • Suitable cationic surfactants are quaternary ammonium salts according to the present invention are quaternary ammonium salts characterised in that the ammonium salt has the general formula: R1R2R3R4N+X- wherein R1 is a C12 to C18 alkyl group, each of R2, R3 and R4 independently is a C1 to C3 alkyl group and X is an inorganic anion.
  • R1 is preferably a C14 to C16 straight chain alkyl group, more preferably C16.
  • R2, R3 and R4 are preferably methyl groups.
  • the inorganic anion (X-) is preferably chosen from halide, sulphate, bisulphate or hydroxide.
  • a quaternary ammonium hydroxide is considered to be a quaternary ammonium salt. More preferably the anion is a halide ion or sulphate, most preferably a chloride or sulphate. Cetyl-trimethylammonium chloride is a specific example of a suitable compound and commercially abundantly available.
  • quaternary ammonium cationic surfactant is the class of benzalkonium halides, also known as alkyldimethylbenzylammonium halides.
  • the most common type being benzalkonium chloride, also known as alkyldimethylbenzylammonium chloride (or ADBAC).
  • Suitable zwitterionic surfactants include derivatives of aliphatic quaternary ammonium, sulphonium and phosphonium compounds having an aliphatic radical of from 8 to 18 carbon atoms and an aliphatic radical substituted by an anionic water-solubilising group, for instance 3- (N-N-dimethyl-N-hexadecylammonium) propane-1 -sulphonate betaine, 3-(dodecylmethyl sulphonium) propane-1 -sulphonate betaine and 3- (cetylmethylphosphonium) ethane sulphonate betaine.
  • anionic water-solubilising group for instance 3- (N-N-dimethyl-N-hexadecylammonium) propane-1 -sulphonate betaine, 3-(dodecylmethyl sulphonium) propane-1 -sulphonate betaine and 3- (cetylmethylphosphonium) ethane sulphonate betaine.
  • the unit-dose tablet composition is preferably a shaped solid, preferably the unit dose shaped solid is a tablet, lozenge, block or cube.
  • the composition may be used in washing machines, dishwashers, in toilet bowls, cisterns, water tanks, washing up bowls, surface cleaning and personal care applications.
  • the present invention provides a process for preparing a unit dose tablet composition, comprising the steps of: a) providing a mix comprising: i) at least one surfactant; ii) adding a water-soluble salt having a solubility in distilled water in the range of 0.5 g/100 ml_ to 75 g/100 ml_ at 25 °C; iii) an effervescent; iv) a swellable disintegrant selected from microcrystalline cellulose, sodium starch glycolate and mixtures thereof; and, v) a non-swellable disintegrant, selected from polyvinyl pyrrolidone, calcium silicate, starch, magnesium stearate and mixtures thereof; b) compressing the mix to provide a unit dose tablet composition.
  • step b) is carried out at pressure in the range of 2.5 to 100 kgf/cm 2 , more preferably 5 to 30 kgf/cm 2 .
  • step i) also includes adding a builder and a filler.
  • the amounts and ingredients described above for the unit-dose tablet composition apply mutatis mutandis to the method of preparing the unit-dose tablet composition.
  • the present invention relates to a method of cleaning a surface comprising the step of dissolving a unit-dose tablet composition as defined herein in water to provide a solution of the cleaning composition and contacting a surface with the cleaning composition.
  • the method of cleaning a surface comprising the step of dissolving a unit-dose tablet composition as defined herein in water, to provide a solution of the cleaning composition, and contacting a surface with the cleaning solution of the cleaning composition, preferably wherein the surface is a hard surface, a soft surface or a laundry surface.
  • the surface to be cleaned is preferably selected from the group of hard, soft and laundry surfaces.
  • surface is a hard surface.
  • the hard surface is preferably selected from a bathroom, kitchen or floor surface.
  • the bathroom surface is selected from the group consisting of baths, toilet bowls, toilet cisterns, shower surfaces, floors and tiles.
  • the hard surface is a kitchen surface selected from the group of dishware, worktops, cooker tops, floors, ovens and sinks.
  • the floor surface may be any stone, linoleum, tile, wood, laminate floor.
  • the surface is a soft surface.
  • the soft surface is selected from the skin and/or scalp.
  • the unit dose composition is preferably dissolved in a container of water for washing the body, hair etc. In other words, the unit dose compositions may be used for personal care applications.
  • the surface is a laundry surface.
  • the laundry surface is preferably any fabric surface to be laundered.
  • a fabric surface is, for example, clothes, towels, linen, bedding etc.
  • the method of cleaning a surface comprises the step of dissolving a unit-dose cleaning composition as defined herein in water to provide a solution of the cleaning composition and contacting a surface with the cleaning composition wherein the surface is a laundry surface.
  • the unit-dose tablet composition is added to a container of water to be used in the cleaning of hard, soft and laundry surfaces.
  • the unit dose tablet composition is dosed in a bottle containing sufficient amount of water, thereby provides a cleaning composition in the bottle.
  • the bottle may be equipped with a spray trigger or foaming engine.
  • a consumer may dispense the cleaning composition directly on a surface as foam or spray.
  • the ratio of the composition to the water is in the range from 1 : 10 to 1 :200, more preferably from 1 : 10 to 1 : 150 and most preferably from 1:10 to 1:100 by wt.
  • the unit-dose tablet composition is added to a washing machine or a container of water to be used in laundering of fabrics.
  • the present invention relates to the use of a unit-dose tablet composition as defined herein for cleaning a surface, wherein the surface is a hard surface, a soft surface or a laundry surface.
  • Unit-dose tablet compositions were prepared according to Table 1. The water-soluble salt and disintegrant is post dosed to the remaining ingredients.
  • Example A contains both microcrystalline celluloses as swellable disintegrant and crosslinked polyvinyl pyrrolidone as non-swellable disintegrant thereby falling within the scope of the invention, whereas example B to E are comparatives.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Medicinal Preparation (AREA)

Abstract

L'invention concerne une composition nettoyante monodose comprenant : a) un délitant gonflant choisi parmi la cellulose microcristalline, le glycolate d'amidon sodique et des mélanges de ceux-ci ; b) un délitant non gonflant choisi parmi la polyvinylpyrrolidone, le silicate de calcium, l'amidon, le stéarate de magnésium et des mélanges de ceux-ci ; (c) un sel soluble dans l'eau ayant une solubilité dans l'eau distillée comprise dans la plage de 0,5 g/100 mb à 75 g/100 mb à 25 °C ; d) un agent tensioactif effervescent ; et e) un tensioactif.
EP22731591.8A 2021-06-15 2022-06-01 Composition en comprimé monodose Pending EP4355847A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP21179488 2021-06-15
PCT/EP2022/064898 WO2022263172A1 (fr) 2021-06-15 2022-06-01 Composition en comprimé monodose

Publications (1)

Publication Number Publication Date
EP4355847A1 true EP4355847A1 (fr) 2024-04-24

Family

ID=76483087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP22731591.8A Pending EP4355847A1 (fr) 2021-06-15 2022-06-01 Composition en comprimé monodose

Country Status (4)

Country Link
EP (1) EP4355847A1 (fr)
CN (1) CN117500907A (fr)
BR (1) BR112023025818A2 (fr)
WO (1) WO2022263172A1 (fr)

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4013581A (en) 1975-07-10 1977-03-22 The Procter & Gamble Company Bleach tablet composition
DK173111B1 (da) * 1996-04-03 2000-01-31 Cleantabs As Tøjvasketabletter
GB2339575A (en) 1998-07-15 2000-02-02 Procter & Gamble Cellulose disintegrant for detergent compositions
DE19843938A1 (de) 1998-09-24 2000-03-30 Henkel Kgaa Wasch- und Reinigungsmittelformkörper mit grobteiligen Aufbereitungskomponenten
EP1144585B1 (fr) 1999-01-23 2005-03-30 The Procter & Gamble Company Comprime detergent
WO2001012767A1 (fr) * 1999-08-12 2001-02-22 The Procter & Gamble Company Composant de desintegration et composition detergente contenant ce composant
ES2258442T3 (es) * 2000-06-09 2006-09-01 THE PROCTER & GAMBLE COMPANY Procedimiento para tratar tejidos con una pastilla detergente que comprende una resina de intercambio ionico.
GB2375543A (en) * 2001-05-18 2002-11-20 Reckitt Benckiser Inc Laundry additive compositions
ES2256291T3 (es) * 2000-09-20 2006-07-16 Reckitt Benckiser Inc. Mejoras en pastillas que contienen enzima.
WO2002042403A1 (fr) 2000-11-24 2002-05-30 Unilever N.V. Compositions de nettoyage
US20080135062A1 (en) 2006-12-12 2008-06-12 3M Innovative Properties Company Disinfecting tablet
ES2586461B1 (es) * 2015-03-12 2017-12-01 Lorena MARTÍ COMA Composición detergente en forma de pastilla efervescente

Also Published As

Publication number Publication date
WO2022263172A1 (fr) 2022-12-22
CN117500907A (zh) 2024-02-02
BR112023025818A2 (pt) 2024-02-27

Similar Documents

Publication Publication Date Title
EP2245128B1 (fr) Compositions et procédés de nettoyage universel dégraissants
US8785366B2 (en) Liquid cleaning compositions and methods
CA1120819A (fr) Comprime detersif
JPH05186800A (ja) 洗剤組成物
EP1625195B1 (fr) Detergent ayant une composition amelioree
KR20170134476A (ko) 발포정의 형태를 가지는 세제 조성물
JPH04253800A (ja) 洗剤組成物
CZ9903238A3 (cs) Čisticí prostředek
US20050288209A1 (en) Cleaning compositions in the form of a tablet or granule
PT1594944E (pt) Composições de limpeza em forma de pastilha
US20130338053A1 (en) Detergent Compositions
JP2014141641A (ja) 衣料用粉末洗剤組成物
CN106336958A (zh) 一种洗碗机清洁片及其制备方法
WO2022263332A1 (fr) Composition en comprimé monodose
EP4355847A1 (fr) Composition en comprimé monodose
KR100374936B1 (ko) 정제형 세탁세제 조성물
TWI491728B (zh) Liquid detergent composition
JP2023530130A (ja) 低減グリコール脂肪アルコールエトキシレート及び低減グリコールサルフェートエトキシル化界面活性剤
EP3541909B1 (fr) Composition aqueuse de nettoyage d'une surface dure
WO2013047102A1 (fr) Composition détergente en poudre pour les vêtements
WO2013047103A1 (fr) Composition détergente nettoyante en poudre pour les vêtements
WO2023202935A1 (fr) Composition de pastille
KR100346812B1 (ko) 정제형 세제 조성물
US20030032575A1 (en) Fragrance tablets
EP4352194A1 (fr) Composition de pastille

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20231127

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR