EP4292108A1 - Procédé de production d'aimant brut - Google Patents

Procédé de production d'aimant brut

Info

Publication number
EP4292108A1
EP4292108A1 EP21845004.7A EP21845004A EP4292108A1 EP 4292108 A1 EP4292108 A1 EP 4292108A1 EP 21845004 A EP21845004 A EP 21845004A EP 4292108 A1 EP4292108 A1 EP 4292108A1
Authority
EP
European Patent Office
Prior art keywords
raw
mold
magnetic field
starting material
produced
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP21845004.7A
Other languages
German (de)
English (en)
Inventor
Johannes MAURATH
Simone Schuster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mimplus Technologies & Co Kg GmbH
Original Assignee
Mimplus Technologies & Co Kg GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mimplus Technologies & Co Kg GmbH filed Critical Mimplus Technologies & Co Kg GmbH
Publication of EP4292108A1 publication Critical patent/EP4292108A1/fr
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/0551Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 in the form of particles, e.g. rapid quenched powders or ribbon flakes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/0536Alloys characterised by their composition containing rare earth metals sintered
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/0555Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 pressed, sintered or bonded together
    • H01F1/0557Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 pressed, sintered or bonded together sintered
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/057Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
    • H01F1/0571Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes
    • H01F1/0575Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together
    • H01F1/0577Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together sintered
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/06Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/08Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/086Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together sintered
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F41/00Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
    • H01F41/02Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
    • H01F41/0253Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
    • H01F41/0266Moulding; Pressing

Definitions

  • the invention relates to a method for producing a raw magnet.
  • Permanent magnets from the rare earth group are used in a variety of technical applications and are characterized by a particularly high energy product.
  • Neodymium-iron-boron magnets in particular have an energy product of up to 400 kJ/m 3 .
  • Known methods for producing a permanent magnet include the production, in particular the pressing, of a raw form and the subsequent sintering of the raw form.
  • the disadvantage of this method is that only simple magnet shapes, in particular cylinders or cuboids, and/or simple magnetizations, in particular axial magnetization, can be implemented. A magnet shape and/or magnetization adapted to a special requirement is therefore not possible.
  • the invention is therefore based on the object of creating a method for producing a raw magnet, in particular for the production of a permanent magnet, in which the disadvantages mentioned, in particular with regard to the permanent magnet ultimately to be produced, are at least partially eliminated, preferably avoided.
  • the object is achieved in particular by creating a method for producing a raw magnet, a first raw mold being produced from a first magnetic starting material and a second raw mold being produced from a second magnetic starting material. Furthermore, an external magnetic field is applied to at least one raw mold selected from a group consisting of the first raw mold and the second raw mold during the production of the raw mold. Alternatively or additionally, an external magnetic field is applied to the at least one raw form after the production of the raw form. A third raw form is then produced from the first raw form and the second raw form by lying together. The third ingot is sintered to obtain the ingot magnet.
  • the method is advantageously suitable for producing permanent magnets, which are obtained after magnetizing the raw magnets, with a complex magnet shape and/or a complex magnetization.
  • the permanent magnet produced preferably has a magnet shape and/or magnetization which can be adapted to a specific requirement. Furthermore, little or no post-processing of the raw magnet is required. Furthermore, during the sintering of the third raw form, an integral connection between the first raw form and the second raw form is advantageously produced.
  • dipoles of the magnetic starting material are aligned in a parallel orientation by means of the externally applied magnetic field during production and/or after production of the at least one raw form.
  • the externally applied magnetic field is preferably generated by a switchable electromagnet and/or a permanent magnet.
  • the third raw mold is formed from a plurality of raw molds, in particular from a plurality of first raw molds and/or a plurality of second raw molds.
  • the at least one raw form in particular exactly one raw form, selected from a group consisting of the first raw form and the second raw form, is produced in the externally applied magnetic field.
  • the particles of the magnetic starting material from which the at least one raw mold is produced align themselves in accordance with the externally applied magnetic field while the at least one raw mold is being produced.
  • the magnetic starting material of the at least one raw form in particular of exactly one raw form, is preferably magnetically hard.
  • the external magnetic field is applied to the at least one raw form, in particular the precisely one raw form, only during the production of the at least one raw form, in particular the precisely one raw form.
  • the external magnetic field is not applied to the at least one raw form, in particular the precisely one raw form, after the production of the at least one raw form, in particular the precisely one raw form.
  • the external magnetic field is applied to the at least one raw mold, in particular to precisely one raw mold selected from a group consisting of the first raw mold and the second raw mold, after the production of the at least one raw mold, in particular the precisely one raw mold .
  • the external magnetic field is applied to the at least one raw form, in particular the precisely one raw form, only after the production of the at least one raw form, in particular the precisely one raw form.
  • the external magnetic field is not applied to the at least one raw form, in particular the precisely one raw form, during the production of the at least one raw form, in particular the precisely one raw form.
  • the external magnetic field is applied to the at least one raw form, in particular to exactly one raw form, selected from a group consisting of the first raw form and the second raw form, during and after the production of the raw form, in particular the precisely one raw form .
  • the first raw form and the second raw form are produced in the externally applied magnetic field.
  • the external magnetic field is applied to the first blank mold only during the manufacture of the first blank mold.
  • the external magnetic field is applied in particular to the second raw form only during the production of the second raw form.
  • the external magnetic field is not applied to the first rough shape after the first rough shape is manufactured.
  • the external magnetic field is not applied particularly to the second rough mold after the production of the second rough mold.
  • the external magnetic field is applied to the first raw form and the second raw form after the production of the first raw form and the second raw form.
  • the external magnetic field is applied to the first blank mold only after the first blank mold is manufactured.
  • the external magnetic field is applied to the second raw mold only after the production of the second raw mold.
  • the external magnetic field is not applied to the first rough shape during the manufacture of the first rough shape.
  • the external magnetic field is not applied particularly to the second rough shape during the production of the second rough shape.
  • the first raw mold is produced in the externally applied magnetic field.
  • the external magnetic field is applied to the second rough mold after the second rough mold is manufactured.
  • the external magnetic field is applied to the first blank mold only during the manufacture of the first blank mold.
  • the external magnetic field is not applied to the first rough shape after the first rough shape is manufactured.
  • the external magnetic field is applied to the second raw mold only after the production of the second raw mold.
  • the external magnetic field is not applied to the second rough shape during the production of the second rough shape.
  • the second raw mold is produced in the externally applied magnetic field.
  • the external magnetic field is applied to the first rough mold after the production of the first rough mold.
  • the external magnetic field is applied to the second blank mold only during the production of the second blank mold.
  • the external magnetic field is not applied to the second rough shape after the second rough shape is manufactured.
  • the external magnetic field is applied in particular to the first raw mold only after the production of the first raw mold.
  • the external magnetic field is not applied to the first rough shape during the manufacture of the first rough shape.
  • the external magnetic field is applied to the first raw form during and after the production of the first raw form.
  • the external magnetic field is applied to the second rough shape during and after the production of the second rough shape.
  • it is particularly preferable that the second raw mold is heated to the softening point while the external magnetic field is being applied.
  • the method is advantageously suitable for powdered magnetic starting materials which are formed on the basis of a newly melted alloy, in particular in the form of a cast block or in the form of melt-spun material.
  • the method is suitable for recycled magnetic material and/or for contaminated recycled magnetic material.
  • material obtained by recycling is preferably alloyed with at least one rare earth element, preferably in powder form, to improve its properties.
  • the first magnetic source material and/or the second magnetic source material is preferably in a pure form or in a hydrogenated form.
  • the US patent application US 2013/0263699 A1 and the German patent DE 198 43 883 CI describe a method, called hydrogen decrepitation (HD), for producing a hydrogenated form of the first magnetic starting material and/or the second magnetic starting material by means of a hydrogen-induced decay .
  • HD hydrogen decrepitation
  • a magnetic starting material is preferably comminuted mechanically, in particular by grinding, to a particle size of at least 1 ⁇ m and at most 200 ⁇ m in order to obtain a powdered magnetic starting material selected from the first magnetic starting material and the second magnetic starting material.
  • the first magnetic source material and the second magnetic source material are identical.
  • the first magnetic starting material and the second magnetic starting material are different, in particular the first magnetic starting material and the second magnetic starting material differ in at least one property selected from a group consisting of a particle size, a particle shape, a particle size distribution, and a chemical composition .
  • the raw magnet is preferably magnetized, a permanent magnet being obtained.
  • the method is then in particular a method for producing a permanent magnet.
  • a material is used as the first magnetic starting material and/or the second magnetic starting material which has particles of an R x T y B alloy.
  • a material which consists of particles of an R x T y B alloy is preferably used as the first magnetic starting material and/or the second magnetic starting material.
  • a material which has particles of an Nd x Le y B alloy or consists of particles of an Nd x Le y B alloy is preferably used as the first magnetic starting material and/or the second magnetic starting material.
  • the first magnetic raw material and/or the second magnetic raw material a material which comprises particles of an R x T y B alloy and particles of a rare earth-rich phase.
  • the first magnetic starting material and/or the second magnetic starting material preferably consists of a mixture of particles of an R x T y B alloy and particles of a rare earth-rich phase.
  • a material is preferably used as the first magnetic starting material and/or the second magnetic starting material which has particles of an Nd x Le y B alloy and particles of a neodymium-rich phase or consists of such particles.
  • the first magnetic starting material and/or the second magnetic starting material preferably has a mixture of particles of an Nd x Le y B alloy and particles of a neodymium-rich phase or consists of such a mixture.
  • R stands for a rare earth element, ie an element from the group of rare earths, T for at least one element selected from a group consisting of iron and cobalt, and B for the element boron.
  • the elements iron and cobalt substitute themselves partially or completely in such a way that either only iron or only cobalt or any iron-cobalt mixture is present.
  • the rare earth element is neodymium.
  • the R x T y B alloy additionally comprises a further element, preferably a metal, in particular a transition metal selected from a group consisting of aluminum, copper, zirconium, gallium, hafnium and niobium, preferably in traces.
  • the first magnetic starting material and/or the second magnetic starting material preferably has particles of an Nd 2 Fe 4 B alloy or consists of particles of an Nd 2 Fe 4 B alloy.
  • the rare earth-rich phase, in particular the neodymium-rich phase preferably has at least one rare earth element, in particular neodymium, or a chemical compound of this rare earth element, in particular neodymium.
  • the rare earth-rich phase, in particular the neodymium-rich phase preferably contains at least one further element of the R x T y B alloy, in particular the Nd x Fe y B alloy.
  • the at least one rare earth element, in particular neodymium is in a hydrogenated form.
  • the neodymium-rich phase has Ndtb and/or Ndfb. 7 or consists of Ndtb and/or Ndtb , 7 .
  • the rare earth-rich phase in particular the neodymium-rich phase, consists of at least one rare earth element, in particular neodymium, or of a chemical compound of this rare earth element, in particular neodymium .
  • the at least one rare earth element in particular neodymium, in a hydrogenated form, in particular Ndtb and/or Ndtb , 7 , is additionally added to the magnetic starting material.
  • the rare earth-rich phase preferably forms a phase in the structure of the raw magnet that is located at grain boundaries of the structure.
  • the rare earth-rich phase is enriched at the grain boundaries of the structure.
  • the rare earth-rich phase is inhomogeneously distributed in the structure.
  • a material is used as the first magnetic starting material and/or as the second magnetic starting material which comprises at least one compound selected from a group consisting of an aluminum-nickel-cobalt alloy, a samarium -Cobalt alloy, and a ferrite alloy.
  • a material which is composed of at least one compound selected from a group consisting of an aluminum-nickel-cobalt alloy, a samarium-cobalt alloy, and a ferrite alloy.
  • a samarium-cobalt alloy containing SmCo 5 preferably consisting of SmCos
  • a samarium-cobalt alloy containing SrmCon, iron, copper and zirconium preferably consisting of SrmCon, iron, copper and zirconium, is used as the first magnetic starting material and/or as the second magnetic starting material.
  • a material is used as the first magnetic starting material and/or as the second magnetic starting material which comprises an iron oxide, in particular FeiCE, and at least one metal oxide, in particular nickel oxide, zinc oxide, manganese oxide, cobalt oxide, copper oxide, magnesium oxide, cadmium oxide , barium oxide, or strontium oxide.
  • the material preferably consists of an iron oxide, in particular FeICE, and at least one metal oxide, in particular nickel oxide, zinc oxide, manganese oxide, cobalt oxide, copper oxide, magnesium oxide, cadmium oxide, barium oxide or strontium oxide.
  • the material is particularly preferably selected from a group consisting of a manganese-zinc ferrite, a nickel-zinc ferrite, a strontium ferrite, a barium ferrite, and a cobalt ferrite.
  • a first external magnetic field is applied to the first raw form during and/or after the production of the first raw form.
  • a second external magnetic field is applied to the second blank form during and/or after the production of the second blank form.
  • the first external magnetic field and the second external magnetic field preferably differ from one another, in particular the first external magnetic field and the second external magnetic field are not identical.
  • the first raw form is produced in the first externally applied magnetic field.
  • the second raw form is produced in the second externally applied magnetic field.
  • the first external magnetic field is applied to the first blank mold only during the production of the first blank mold. Specifically, the first external magnetic field is not applied to the first rough shape after the first rough shape is manufactured.
  • the second external magnetic field is applied in particular to the second blank mold only during the production of the second blank mold. Specifically, the second external magnetic field is not applied to the second rough shape after the second rough shape is manufactured.
  • the first external magnetic field is applied to the first raw form after the production of the first raw form.
  • the second external magnetic field is applied to the second rough mold after the second rough mold is manufactured.
  • the first external magnetic field is applied to the first blank mold only after the production of the first blank mold.
  • the first external magnetic field is not applied to the first rough shape during the manufacture of the first rough shape.
  • the second external magnetic field is applied in particular to the second raw mold only after the production of the second raw mold.
  • the second external magnetic field is not applied to the second rough shape during the production of the second rough shape.
  • the first raw form is produced in the first externally applied magnetic field.
  • the second external magnetic field is applied to the second rough mold after the second rough mold is manufactured.
  • the first external magnetic field is applied to the first blank mold only during the production of the first blank mold.
  • the first external magnetic field is not applied to the first rough shape after the first rough shape is manufactured.
  • the second external magnetic field is applied in particular to the second raw form only after the production of the second raw form.
  • the second external magnetic field is not applied to the second rough shape during the production of the second rough shape.
  • the first external magnetic field is applied to the first raw form after the production of the first raw form.
  • the second raw form is produced in the second externally applied magnetic field.
  • the first external magnetic field is applied to the first blank mold only after the first blank mold is manufactured.
  • the first external magnetic field is not applied to the first rough shape during the manufacture of the first rough shape.
  • the second external magnetic field is applied in particular to the second blank mold only during the production of the second blank mold. Specifically, the second external magnetic field is not applied to the second rough shape after the second rough shape is manufactured.
  • the first magnetic starting material is mixed with a first binder, with a first mixture of the first magnetic starting material and the first binder being obtained.
  • the second magnetic source material is mixed with a second binder to obtain a second mixture of the second magnetic source material and the second binder.
  • the first raw mold is produced from the first mixture and the second raw mold is produced from the second mixture.
  • the first binder and the second binder are at least partially, preferably completely, removed from the third preform.
  • the first binder and/or the second binder is/are at least partially, preferably completely, removed from the first raw mold and/or the second raw mold.
  • the first mixture has a volume fraction of at least 45% to at most 75% of the first magnetic starting material and a volume fraction of at least 25% to at most 55% of the first binder.
  • the second mixture has a volume fraction of at least 45% to at most 75% of the second magnetic starting material and a volume fraction of at least 25% to at most 45% of the second binder.
  • the first binder and/or second binder preferably has/have at least one organic binder component.
  • the first mixture and the second mixture are identical.
  • the first mixture and the second mixture are different, in particular the first mixture and the second mixture have different components and/or different weight proportions of the individual components.
  • the first raw form is preferably heated to a first softening point, in particular the first softening point of the first mixture, while the external magnetic field is applied.
  • the second raw form is heated to a second softening point, in particular the second softening point of the second mixture, while the external magnetic field is being applied.
  • the first binder and the second binder are at least partially removed from the third raw form by means of a solvent or a chemical process.
  • a remaining proportion of the first binder and the second binder is optionally removed from the third raw form by means of thermal decomposition, in particular directly before sintering.
  • a first main component of the first tie and a second main component of the second tie are identical.
  • a cohesive connection between the first raw mold and the second raw mold, in particular the first binder and the second binder, can thus be implemented during the production of the third raw mold by means of joining.
  • the first binder and the second binder are identical.
  • At least one raw form selected from the first raw form and the second raw form, by means of a method selected from a group consisting of injection molding, in particular metal powder injection molding, additive manufacturing, extrusion, cold pressing, dry pressing, and wet pressing.
  • the first blank is made by injection molding the first mixture comprising the first magnetic feedstock and the first binder.
  • the second blank is produced by injection molding the second mixture, which comprises the second magnetic starting material and the second binder.
  • At least one raw form is produced by means of cold pressing of a magnetic starting material.
  • the particles are mechanically interlocked, in particular under a pressure of up to 1 GPa.
  • no additional liquid component is added to the magnetic starting material.
  • at least one organic solvent preferably a volatile organic solvent, is added to the magnetic base material.
  • the volatile organic solvent is selected from a group consisting of an alcohol, an aliphatic, an acyclic alkane, a cyclic alkane, a ketone, an alkene, an aromatic, and a mixture of volatile organic substances that can serve as a solvent.
  • Ethanol or isopropanol is preferably used as the alcohol.
  • Cyclohexane is preferably used as the cyclic alkane.
  • Acetone is preferably used as the ketone.
  • Benzene, xylene and/or toluene is preferably used as the aromatic.
  • the mixture of volatile organic substances is preferably selected from a group consisting of petroleum, mineral spirits, and mineral spirits.
  • the organic solvent serves in particular as a binder in wet cold pressing.
  • the first raw form and/or the second raw form is preferably dried before sintering.
  • the first raw mold and the second raw mold are produced using the identical process.
  • the second raw mold is molded onto the first raw mold by means of injection molding, in particular of the second mixture.
  • the third raw form is produced.
  • At least one magnetic starting material selected from a group consisting of the first magnetic starting material and the second magnetic starting material, preferably has a hard magnetic material, in particular the at least one magnetic starting material consists of a hard magnetic material.
  • the hard magnetic material is an R x T y B alloy.
  • at least one magnetic starting material, selected from a group consisting of the first magnetic starting material and the second magnetic starting material has a soft magnetic or a paramagnetic material, in particular at most one magnetic starting material consists of a soft magnetic or paramagnetic material.
  • the first magnetic starting material preferably has a hard-magnetic material or consists of a hard-magnetic material
  • the second magnetic starting material has a soft-magnetic or paramagnetic material or consists of a soft-magnetic or paramagnetic material.
  • a soft-magnetic or paramagnetic material can advantageously be reworked in a simple manner after sintering, in particular by means of machining.
  • the first raw mold and the second raw mold are produced by means of injection molding, the first raw mold being overmoulded with the second mixture at least in regions.
  • the first mixture is injected into a first cavity of a tool.
  • the first raw mold is placed in a second cavity of the mold and overmoulded with the second mixture, the second raw mold, which at least partially surrounds, preferably encloses, the first raw mold being produced.
  • the first raw shape and the second raw shape together form the third raw shape.
  • the volume of the second blank reduces.
  • the second raw form therefore shrinks onto the first raw form during solidification, as a result of which a non-positive connection of the first raw form and the second raw form is obtained.
  • a positive connection of the first raw form and the second raw form is obtained depending on the geometry of the first raw form and the second raw form.
  • This method can advantageously be carried out for a large number of raw forms.
  • the third raw form is produced by means of a method selected from a group consisting of material connection, in particular gluing, form-fit connection, force-fit connection and loose connection.
  • the third raw form is produced by means of a material connection.
  • the first binder and the second binder preferably have at least one identical binder component.
  • the at least one identical binder component is preferably a thermoplastic.
  • the at least one identical binder component is the first main component of the first binder and the second main component of the second binder.
  • At least one magnetic starting material selected from a group consisting of the first magnetic starting material and the second magnetic starting material is particularly preferably a hard magnetic material.
  • a first connecting surface of the first raw mold and a second connecting surface of the second raw mold are heated to a temperature of at least 35 °C to a maximum of 230 °C, preferably from at least 70 °C to a maximum of 200 °C, in particular by means of a hot plate or a laser, the first connection surface and the second connection surface being melted.
  • the first connecting surface and the second connecting surface are pressed together with a pressure of at least 0.001 MPa to a maximum of 10 MPa until the melted connecting surfaces have solidified again, with the first raw mold and the second raw mold being integrally bonded connected to each other to form the third raw form.
  • first connection surface and the second connection surface are connected to one another in a material connection by means of friction welding, the third raw form being produced.
  • the third raw form is produced by means of gluing.
  • the first raw form and the second raw form are particularly preferably connected by means of a physically and/or chemically curing adhesive.
  • a hot-melt adhesive that hardens physically is used.
  • At least one binder is preferably melted and used as an adhesive in order to join the first raw form and the second raw form to one another.
  • the hot-melt adhesive preferably has at least one magnetic starting material, in particular in powder form.
  • an adhesive which has at least one polymer dissolved in a solvent is used in order to join the first raw form and the second raw form to one another.
  • the solvent in the adhesive is evaporated, as a result of which an adhesive effect of the adhesive occurs.
  • an adhesive selected from a group consisting of a cyanoacrylate, an epoxy adhesive, and a phenolic resin is used to bond the first blank and the second blank together.
  • the third raw form is produced by means of form-fitting connection.
  • the first raw form and the second raw form can preferably be positively connected to one another via their respective geometries, in particular via a tongue and groove geometry, a screw thread geometry or a pin hole geometry.
  • at least one base magnetic material selected from a group consisting of the first base magnetic material and the second base magnetic material is a hard magnetic material.
  • a geometry that enables a form-fitting connection is formed during the production of the first raw mold and the second raw mold.
  • the geometry that enables the form-fitting connection is formed after the production of the first raw form and the second raw form, in particular by means of subsequent machining.
  • the geometry that enables the form-fitting connection is formed during the production of the first raw form and after the production of the second raw form, in particular by means of subsequent machining.
  • the third raw form is produced by means of a non-positive connection, in particular by means of a thread or a press fit.
  • at least one base magnetic material selected from a group consisting of the first base magnetic material and the second base magnetic material is a hard magnetic material.
  • the third raw mold is produced by loosely connecting the first raw mold and the second raw mold.
  • a non-positive and/or material connection is created for the raw magnet obtained.
  • at least one base magnetic material selected from a group consisting of the first base magnetic material and the second base magnetic material is a hard magnetic material.
  • the first blank has a recess in which the second blank is arranged.
  • the recess preferably has a greater extent than the second raw shape.
  • the first raw form has a first volume shrinkage of at least 15% to at most 20% during sintering.
  • the second raw form has a second volume shrinkage of at least 15% to at most 20% during sintering.
  • the second volumetric shrinkage is less than the first volumetric shrinkage.
  • the second raw mold is clamped in the recess of the first raw mold during sintering due to the second volumetric shrinkage, which is less than the first volumetric shrinkage of the first raw mold.
  • a first connecting surface of the first raw mold which corresponds to the surface of the recess
  • the second raw form which is arranged in the recess, cohesively with each other during sintering.
  • the first volumetric shrinkage and the second volumetric shrinkage different from the first volumetric shrinkage are achieved in that a first proportion of the first magnetic starting material is in the first mixture differs from a second portion of the second magnetic source material in the second mixture.
  • the first volume shrinkage and the second volume shrinkage, which differs from the first volume shrinkage are achieved in that a first raw form density, which obtained in particular in the dry-pressing at a first pressure, differs from a second bulk density obtained in particular in the dry-pressing at a second pressure different from the first pressure.
  • the first raw form and the second raw form are loosely layered in order to produce the third raw form, with a material connection of the first raw form and the second raw form being produced during sintering.
  • a metal foil in particular a stainless steel foil, is particularly preferably layered, in particular loosely layered, between the first raw mold and the second raw mold before sintering.
  • a ceramic foil is layered, in particular loosely layered, between the first raw mold and the second raw mold.
  • a plurality of first blanks and/or a plurality of second blanks are loosely stacked to produce the third blank.
  • the first binder and the second binder have at least one substance selected from a group consisting of polyoxymethylene, polypropylene, paraffin wax, polyethylene and polyamide.
  • polyoxymethylene, polypropylene, paraffin wax, polyethylene and polyamide are thermoplastics and are therefore suitable for forming an integral connection between the first raw form and the second raw form.
  • the at least one substance selected from a group consisting of polyoxymethylene, polypropylene, paraffin wax, polyethylene and polyamide facilitates alignment of the particles of the first magnetic starting material and the second magnetic starting material.
  • a separating layer is arranged, in particular inserted, between the first connecting surface of the first raw mold and the second connecting surface of the second raw mold.
  • a cohesive connection between the first raw mold and the second raw mold is prevented by means of the separating layer between the first raw mold and the second raw mold.
  • the separating layer in particular when loosely connecting, only one non-positive connection of the first raw mold and the second raw mold is formed.
  • the separating layer it is advantageously possible by means of the separating layer to separate the first raw form and the second raw form from one another with regard to at least one chemical and/or physical property of the raw forms and in particular of the permanent magnet.
  • the first connecting surface and the second connecting surface face one another and are separated from one another by the separating layer or are at least separated with regard to at least one property.
  • the separating layer is designed as at least one closed, ie in particular continuous, separating layer.
  • the separating layer is designed as a non-closed or partially open separating layer, in particular as a plurality of separating layer fragments present in certain regions.
  • the separating layer is formed in the form of particles on at least one connection surface selected from the first connection surface and the second connection surface.
  • a material is used as the separating layer, which has at least one compound selected from a group consisting of aluminum oxide, zirconium oxide, yttrium oxide and at least one oxide of the rare earths.
  • a material is preferably used as the separating layer, which consists of at least one compound selected from a group consisting of aluminum oxide, zirconium oxide, yttrium oxide and at least one oxide of the rare earths.
  • the third raw form is at least partially, preferably completely, debound.
  • the at least one binder component is preferably at least partially, preferably completely, removed from the third raw mold.
  • the third raw form is preferably partially debound by means of a solvent. Thermal debinding is then preferably carried out, in particular thermal debinding is carried out before sintering. Alternatively, the third raw form is completely debound by means of a solvent, in particular the third raw form is debound before sintering.
  • the third raw mold is sintered in an atmosphere that has at least one process gas selected from a group consisting of argon and helium.
  • the atmosphere in which the third raw form is sintered particularly preferably consists of at least one process gas selected from a group consisting of argon and helium.
  • the third blank is preferably sintered in a vacuum.
  • a Halbach array is produced as the raw magnet.
  • the first raw mold is produced by means of injection molding in the externally applied magnetic field having a magnetic field orientation.
  • the first rough shape is rotated such that a particle orientation in the first rough shape is orthogonal to the magnetic field orientation.
  • the second raw mold is then injection molded onto the rotated first raw mold in the externally applied magnetic field.
  • the first blank mold is not rotated until the first blank mold has solidified.
  • the external magnetic field is not applied to the first blank.
  • the second raw mold is preferably only injected onto the first raw mold when the first raw mold has solidified.
  • the method is carried out several times in succession, in particular four times in succession, in order to obtain a Halbach array which has a plurality of raw shapes, in particular five raw shapes.
  • the invention also includes a raw magnet, in particular a permanent magnet obtained after magnetization of the raw magnet, in particular a Halbach array, which is produced using a method according to the invention or using a method according to one or more of the embodiments described above.
  • the invention also includes a raw magnet, in particular a permanent magnet obtained after magnetization of the raw magnet, which has at least one separating layer arranged in an interior of the permanent magnet, preferably as an electrical resistance layer or as an electrically insulating layer.
  • the permanent magnet is produced in a method according to the invention or in a method according to one or more of the embodiments described above.
  • the permanent magnet has at least five separating layers, preferably at least ten separating layers, preferably at least 15 separating layers, particularly preferably 20 separating layers, in the interior of the permanent magnet, with one separating layer being arranged between two layers of the permanent magnet each formed from a raw form.
  • the invention also includes use of such a raw magnet, in particular such a permanent magnet, in a device selected from a group consisting of an electric motor, a loudspeaker, a microphone, a generator, a hard disk drive and a sensor.
  • the invention also includes a device selected from a group consisting of an electric motor, a loudspeaker, a microphone, a generator, a hard disk drive, and a sensor, the device having a permanent magnet which is activated by a method according to the invention or a method according to a or more of the embodiments described above is provided.
  • FIG. 1 shows a flowchart of a first exemplary embodiment of a method for producing a raw magnet
  • FIG. 2 shows a flow chart of a second exemplary embodiment of the method for producing the raw magnet
  • FIG. 3 shows a flow chart of a third exemplary embodiment of the method for producing the raw magnet
  • FIG. 4 shows a schematic representation of a first and second joining method for producing a third raw form
  • 5 shows a schematic representation of a third joining method for producing the third raw form as a Halbach array.
  • Figure 1 shows a flow chart of a first exemplary embodiment of a method for producing a raw magnet 4.
  • a first raw form is made from a first magnetic starting material 1.1
  • a second raw mold 2.2 is produced from a second magnetic starting material 1.2.
  • a material which is produced from particles of an R x T y B alloy and preferably particles of a phase rich in rare earths is particularly preferably used as the first magnetic starting material 1.1 and/or as the second magnetic starting material 1.2.
  • a material selected from a group consisting of an aluminum-nickel-cobalt alloy, a samarium-cobalt alloy and a ferrite alloy is used as the first magnetic starting material 1.1 and/or as the second magnetic starting material 1.2 .
  • At least one raw form 2 selected from a group consisting of the first raw form
  • an external magnetic field 21 is applied during and/or after the production of the raw form 2 according to step a) or b).
  • the first raw mold 2.1 is preferably produced in the externally applied magnetic field 21. Alternatively or additionally, the first raw mold 2.1 is made after the production of the first raw mold
  • the second raw form 2.2 is produced in the externally applied magnetic field 21.
  • the external magnetic field 21 is applied to the second raw form 2.2 after the production of the second raw form 2.2.
  • a first external magnetic field is particularly preferably applied to the first raw form 2.1 during and/or after the production of the first raw form 2.1.
  • a second external magnetic field is applied to the second raw form 2.2 during and/or after the production of the second raw form 2.2.
  • the first raw mold 2.1 is preferably produced in the first externally applied magnetic field and the second raw mold 2.2 is produced in the second externally applied magnetic field.
  • the first raw mold 2.1 is made after the production of the first raw mold
  • the first external magnetic field is applied and the second external magnetic field is applied to the second raw form 2.2 after the production of the second raw form 2.2.
  • the first raw form 2.1 is preferably produced in the first externally applied magnetic field and the second external magnetic field is applied to the second raw form 2.2 after the production of the second raw form 2.2.
  • the first external magnetic field and the second raw mold are applied to the first raw mold 2.1 after the production of the first raw mold 2.1
  • the first external magnetic field and the second external magnetic field preferably differ from one another, in particular the first external magnetic field and the second external magnetic field are not identical.
  • a first particle orientation is preferably achieved by means of the first magnetic field
  • an orientation of the first raw mold 2.1 and/or the second raw mold 2.2 is varied in the external magnetic field.
  • At least one raw mold 2, selected from the first raw mold 2.1 and the second raw mold 2.2, is preferably formed, in particular in step a) and/or in step b), by means of a method selected from a group consisting of injection molding, additive manufacturing, extrusion, cold pressing, dry pressing, and wet pressing.
  • a step c) the first raw mold 2.1 and the second raw mold 2.2 are connected to one another by means of joining, with a third raw mold 3 being produced.
  • the third raw form 3 is preferably produced by means of a method selected from a group consisting of material connection, in particular gluing, form-fit connection, non-positive connection, and solid connection.
  • the third raw form 3 is sintered, the raw magnet 4 being obtained.
  • the third raw mold 3 is sintered in an atmosphere that has at least one Process gas selected from a group consisting of argon and helium.
  • the atmosphere particularly preferably consists of at least one process gas selected from a group consisting of argon and helium.
  • the third raw mold 3 is sintered in a vacuum.
  • Figure 2 shows a flowchart of a second embodiment of a method for producing the raw magnet 4.
  • the first magnetic starting material 1.1 is mixed with a first binder 5.1, a first mixture 6.1 of the first magnetic starting material 1.1 and the first binder 5.1 being obtained.
  • the first raw mold 2.1 is produced from the first mixture 6.1.
  • the second magnetic starting material 1.2 is mixed with a second binder 5.2, a second mixture 6.2 of the second magnetic starting material 1.2 and the second binder 5.2 being obtained.
  • the second raw mold 2.2 is produced from the second mixture 6.2.
  • step c) the first raw mold 2.1 and the second raw mold 2.2 are connected to one another by means of joining, with the third raw mold 3 being produced.
  • the first binder 5.1 and the second binder 5.2 are removed at least partially, preferably completely, from the third raw mold 3 before sintering and after the production of the third raw mold 3.
  • a first main component of the first binder 5.1 and a second main component of the second binder 5.2 are preferably identical.
  • the first binder 5.1 and the second binder 5.2 have at least one substance selected from a group consisting of polyoxymethylene, polypropylene, paraffin wax, polyethylene and polyamide.
  • Figure 3 shows a flowchart of a third embodiment of a method for producing the raw magnet 4.
  • the first raw mold 2.1 and the second raw mold 2.2 are preferably not produced separately from one another.
  • the first raw mold 2.1 is produced from the first mixture 6.1 by means of injection molding.
  • the first raw mold 2.1 is overmolded with the second mixture 6.2 by means of injection molding.
  • the second mixture 6.2 is injection molded onto the first raw mold 2.1.
  • the second raw mold 2.2 is thus produced, with the second mixture 6.2 being positively connected to the first raw mold 2.1 in a preferred embodiment.
  • the second raw mold 2.2 preferably solidifies and thus shrinks onto the first raw mold 2.1 and/or connects to the first raw mold 2.1, with the third raw mold 3 being produced.
  • the method step of joining accordingly includes the solidification of the second raw mold 2.2.
  • Figure 4 a shows a schematic representation of a first joining method for producing the third raw mold 3.
  • the first raw mold 2.1 and the second raw mold 2.2 are joined together to form the third raw mold 3 by means of positive connection.
  • the first raw form 2.1 is produced in a first externally applied magnetic field.
  • the first external magnetic field is applied to the first raw form 2.1 after the production of the first raw form 2.1. Therefore, the first raw form 2.1 has the first particle orientation
  • the second raw form 2.2 is produced in the first externally applied magnetic field. Alternatively or additionally, the first external magnetic field is applied to the second raw form 2.2 after the production of the second raw form 2.2.
  • the second raw mold 2.2 therefore has the second particle orientation 7.2, which differs from the first particle orientation 7.1.
  • the second raw form 2.2 is produced in a second externally applied magnetic field.
  • the second external magnetic field is applied to the second raw mold 2.2 after the production of the second raw mold 2.2. Therefore, the second raw form
  • the first external magnetic field and the second external magnetic field differ from each other, in particular the first external magnetic field and the second external magnetic field are not identical. Therefore, the first particle orientation 7.1 and the second particle orientation 7.2 differ from one another; in particular, the first particle orientation 7.1 and the second particle orientation 7.2 are not identical.
  • the first geometry 9.1 and the second geometry 9.2 have a tongue and groove connection 11.
  • Figure 4 b shows a schematic representation of a second joining method for producing the third raw mold 3.
  • the first raw mold 2.1 and the second raw mold 2.2 are joined together to form the third raw mold 3 by loose connection.
  • the first raw mold 2.1 has a recess 13 in which the second raw mold
  • the recess 13 of the first raw form 2.1 is particularly preferably larger than the second raw form 2.2.
  • the first raw form 2.1 and the second raw form 2.2 shrink. Since during sintering a first volume shrinkage of the first raw mold 2.1 is greater than a second volume shrinkage of the second raw mold 2.2, the first raw mold 2.1 shrinks onto the second raw mold 2.2 and a non-positive connection is formed between the first raw mold 2.1 and the second raw mold 2.2.
  • an integral connection between a first connecting surface 15.1 of the first raw mold 2.1 and a second connecting surface 15.2 of the second raw mold 2.2 is also produced during the sintering.
  • a separating layer 17 is inserted between the first connecting surface 15.1 of the first raw mold 2.1 and the second connecting surface 15.2 of the second raw mold 2.2. whereby an integral connection of the first raw mold 2.1 and the second raw mold 2.2, in particular the first connecting surface 15.1 of the first raw mold 2.1 and the second connecting surface 15.2 of the second raw mold 2.2, is prevented.
  • a material is preferably used as the separating layer 17 which has at least one compound selected from a group consisting of aluminum oxide, zirconium oxide, yttrium oxide and at least one rare earth oxide.
  • the separating layer 17 consists of at least one compound selected from a group consisting of aluminum oxide, zirconium oxide, yttrium oxide and at least one rare earth oxide.
  • FIG. 5 shows a schematic representation of a third joining method for producing the third raw mold 3 as a Haibach array.
  • the first raw mold 2.1 is produced in the externally applied magnetic field 21.
  • the external magnetic field 21 is applied to the first raw mold 2.1 after the production of the first raw mold 2.1, while the first raw mold 2.1 is preferably heated to a softening temperature.
  • the particles of the first magnetic starting material 1.1 are aligned in accordance with a magnetic field alignment 19 of the external magnetic field 21, and the first particle alignment 7.1 is produced in the first raw mold 2.1.
  • the first raw mold 2.1 is then rotated in such a way that the first particle alignment 7.1 in the first raw mold 2.1 is orthogonal to the magnetic field alignment 19.
  • the first raw mold 2.1 is preferably produced from the first mixture 6.1 by means of injection molding.
  • the second raw mold 2.2 is molded onto the turned first raw mold 2.1 by injection molding the second mixture 6.2 in the externally applied magnetic field 21, the third raw mold 3 being produced.
  • the particles of the second magnetic starting material 1.2 align themselves according to the external magnetic field 21, and the second particle alignment 7.2 is produced in the second raw mold 2.2.
  • a raw magnet 4 in the form of a Halbach array is obtained from the third raw form 3 by means of sintering.

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
  • Hard Magnetic Materials (AREA)

Abstract

L'invention concerne un procédé de production d'un aimant brut (4), - une première forme brute (2.1) étant produite à partir d'un premier matériau de départ magnétique (1.1), - une seconde forme brute (2.2) est produite à partir d'un deuxième matériau de départ magnétique (1.2), - un champ magnétique externe (21) est appliqué à au moins une forme brute (2), choisie dans un groupe constitué par la première forme brute (2.1) et la deuxième forme brute (2.2) pendant et/ou après que la forme brute (2) est produite , - une troisième forme brute (3) est produite à partir de la première forme brute (2.1) et la deuxième forme brute (2.2) par assemblage desdites formes brutes l'une à l'autre, la troisième forme brute (3) est frittée, et l'aimant brut (4) est obtenu.
EP21845004.7A 2021-02-15 2021-12-22 Procédé de production d'aimant brut Pending EP4292108A1 (fr)

Applications Claiming Priority (2)

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DE102021201413.5A DE102021201413A1 (de) 2021-02-15 2021-02-15 Verfahren zur Herstellung eines Rohmagneten
PCT/EP2021/087411 WO2022171348A1 (fr) 2021-02-15 2021-12-22 Procédé de production d'aimant brut

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EP4292108A1 true EP4292108A1 (fr) 2023-12-20

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EP21844998.1A Pending EP4292107A1 (fr) 2021-02-15 2021-12-22 Procédé de production d'aimant brut

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EP (2) EP4292108A1 (fr)
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DE102022129227A1 (de) * 2022-11-04 2024-05-08 Mimplus Technologies Gmbh & Co. Kg Verfahren zur Herstellung eines Rohmagneten

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Publication number Priority date Publication date Assignee Title
JP2911017B2 (ja) 1993-12-10 1999-06-23 信越化学工業株式会社 ラジアル異方性希土類焼結磁石の製造方法
DE19843883C1 (de) 1998-09-24 1999-10-07 Vacuumschmelze Gmbh Verfahren zur Wiederverwendung von Dauermagneten
JP2001068317A (ja) * 1999-08-31 2001-03-16 Shin Etsu Chem Co Ltd Nd−Fe−B焼結磁石及びその製造方法
JP2004128302A (ja) 2002-10-04 2004-04-22 Hitachi Metals Ltd 希土類焼結磁石
JP2009225608A (ja) * 2008-03-18 2009-10-01 Nitto Denko Corp モータ用永久磁石及びモータ用永久磁石の製造方法
WO2011032201A1 (fr) 2009-09-21 2011-03-24 Soderberg Rod F Matière matrice contenant des particules magnétiques, destinée à être utilisée dans des véhicules hybrides et électriques
US9663843B2 (en) 2010-12-02 2017-05-30 The University Of Birmingham Magnet recycling
DE102011105324A1 (de) * 2011-06-03 2012-12-06 Minebea Co., Ltd. Spritzgusswerkzeug
US9147524B2 (en) 2011-08-30 2015-09-29 General Electric Company High resistivity magnetic materials
DE102012208362A1 (de) * 2012-05-18 2013-11-21 Siemens Aktiengesellschaft Verfahren zur Herstellung eines Permanentmagneten
CN106796835B (zh) * 2014-08-12 2019-05-21 Abb瑞士股份有限公司 具有不同磁性质的区域的磁体以及用于形成这种磁体的方法
US20190148994A1 (en) * 2014-11-07 2019-05-16 Ford Global Technologies, Llc Fixtures and methods for forming aligned magnetic cores

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WO2022171347A1 (fr) 2022-08-18
US20240127994A1 (en) 2024-04-18
EP4292107A1 (fr) 2023-12-20
WO2022171348A1 (fr) 2022-08-18
US20240145135A1 (en) 2024-05-02

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