EP4279461A1 - Profils de contrainte résistant à la fracture dans des lunettes - Google Patents
Profils de contrainte résistant à la fracture dans des lunettes Download PDFInfo
- Publication number
- EP4279461A1 EP4279461A1 EP23201195.7A EP23201195A EP4279461A1 EP 4279461 A1 EP4279461 A1 EP 4279461A1 EP 23201195 A EP23201195 A EP 23201195A EP 4279461 A1 EP4279461 A1 EP 4279461A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mpa
- equal
- glass
- less
- based article
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 629
- 239000000203 mixture Substances 0.000 claims description 151
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims description 83
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 claims description 83
- 239000000758 substrate Substances 0.000 claims description 77
- 238000005342 ion exchange Methods 0.000 claims description 70
- 238000007906 compression Methods 0.000 claims description 67
- 230000006835 compression Effects 0.000 claims description 67
- 238000000034 method Methods 0.000 claims description 58
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 56
- 210000003127 knee Anatomy 0.000 claims description 55
- 230000006870 function Effects 0.000 claims description 38
- 229910052744 lithium Inorganic materials 0.000 claims description 30
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 29
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 14
- 238000011282 treatment Methods 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 230000004083 survival effect Effects 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 101
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 40
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 36
- 150000002500 ions Chemical class 0.000 description 33
- 239000000047 product Substances 0.000 description 27
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 18
- 229910044991 metal oxide Inorganic materials 0.000 description 18
- 150000004706 metal oxides Chemical class 0.000 description 18
- 230000000717 retained effect Effects 0.000 description 16
- 208000010392 Bone Fractures Diseases 0.000 description 12
- 206010017076 Fracture Diseases 0.000 description 12
- 238000007654 immersion Methods 0.000 description 11
- 238000005259 measurement Methods 0.000 description 9
- 239000003513 alkali Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 7
- 238000003426 chemical strengthening reaction Methods 0.000 description 7
- 239000006059 cover glass Substances 0.000 description 7
- 239000006018 Li-aluminosilicate Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000005358 alkali aluminosilicate glass Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 5
- 229910001415 sodium ion Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 238000005452 bending Methods 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 238000003286 fusion draw glass process Methods 0.000 description 4
- 239000006060 molten glass Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000003283 slot draw process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 239000005407 aluminoborosilicate glass Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 238000003280 down draw process Methods 0.000 description 3
- 239000010438 granite Substances 0.000 description 3
- 238000007373 indentation Methods 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000002241 glass-ceramic Substances 0.000 description 2
- 238000001336 glow discharge atomic emission spectroscopy Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- -1 Na+ Chemical class 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 208000013201 Stress fracture Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000005345 chemically strengthened glass Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000006112 glass ceramic composition Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 206010021198 ichthyosis Diseases 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000005365 phosphate glass Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000006133 sodium aluminosilicate glass Substances 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
Definitions
- the present specification generally relates to stress profiles for fracture resistant stress profiles in glass articles. More specifically, the present specification is directed to stress profiles for glasses, which may be lithium-containing, that may be utilized in electronic devices.
- cover glasses which may become damaged upon impact with hard surfaces.
- the cover glasses function as display covers, and may incorporate touch functionality, such that use of the devices is negatively impacted when the cover glasses are damaged.
- cover glass when the associated portable device is dropped on a hard surface.
- One of the modes is flexure failure, which is caused by bending of the glass when the device is subjected to dynamic load from impact with the hard surface.
- the other mode is sharp contact failure, which is caused by introduction of damage to the glass surface. Impact of the glass with rough hard surfaces, such as asphalt, granite, etc., can result in sharp indentations in the glass surface. These indentations become failure sites in the glass surface from which cracks may develop and propagate.
- Glass-based articles herein exhibit high fracture resistance.
- the glass-based articles herein provide high fracture resistance after multiple drops.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ), wherein t is greater than or equal to 0.4 mm and less than or equal to 1.3 mm; a stress slope at DOC that is 1.5 MPa/micron or less; and a stress profile comprising: a depth of compression (DOC) that is greater than or equal to 0.15 t ; and an absolute value of stress integral in one compression zone that is in the range of from 4 MPa ⁇ mm to 20 MPa ⁇ mm.
- DOC depth of compression
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ), wherein t is greater than or equal to 0.4 mm and less than or equal to 1.3 mm; and a stress profile comprising: a depth of compression (DOC) that is greater than or equal to 0.15 t ; a stress slope at DOC that is 1.5 MPa/micron or less; and an absolute value of stress integral in one compression zone that is in the range of from 4 MPa ⁇ mm to 20 MPa ⁇ mm.
- DOC depth of compression
- the glass-based article of the preceding aspect comprising a peak compressive stress (CS) greater than or equal to 500 MPa.
- CS peak compressive stress
- the glass-based article of any preceding aspect comprising a compressive stress at a knee (CS k ) greater than or equal to 70 MPa.
- the glass-based article of any preceding aspect is provided, wherein the DOC is located at a depth of 95 microns or deeper.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass-based article to a depth of compression (DOC); wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 500 MPa, a thickness ( t ) of less than or equal to 0.73 mm, a compressive stress at a knee (CS k ) greater than or equal to 140 MPa, and a DOC/ t greater than 0.17.
- CS peak compressive stress
- the glass-based article of any preceding aspect is provided, wherein DOC/ t is greater than or equal to 0.18.
- the glass-based article of any preceding aspect is provided, wherein the peak CS is greater than or equal to 600 MPa.
- the glass-based article of any preceding aspect is provided, wherein the peak CS is greater than or equal to 720 MPa.
- the glass-based article of any preceding aspect is provided, wherein the peak CS is greater than or equal to 800 MPa.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass-based article to a depth of compression (DOC); wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 970 MPa, a compressive stress at a knee (CS k ) greater than or equal to 90 MPa, and a DOC/ t greater than or equal to 0.17.
- CS peak compressive stress
- CS k compressive stress at a knee
- DOC/ t greater than or equal to 0.17.
- the glass-based article of the preceding aspect is provided, wherein DOC/ t is greater than or equal to 0.18.
- the glass-based article of any of aspects (10) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 1020 MPa.
- the glass-based article of any of aspects (10) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 1060 MPa.
- the glass-based article of any of aspects (10) to the preceding aspect is provided, wherein a depth of layer of a spike (DOL sp ) is greater than or equal to 0.01 t .
- the glass-based article of any of aspects (10) to the preceding aspect wherein a depth of layer of a spike (DOL sp ) is greater than or equal to 7 ⁇ m.
- the glass-based article of any of aspects (10) to the preceding aspect wherein a depth of layer of a spike (DOL sp ) is greater than or equal to 7.8 ⁇ m.
- the glass-based article of any of aspects (10) to the preceding aspect is provided, wherein the CS k is greater than or equal to 100 MPa.
- the glass-based article of any of aspects (10) to the preceding aspect is provided, wherein the CS k is greater than or equal to 110 MPa.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC), wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 970 MPa, a compressive stress at a knee (CS k ) greater than or equal to 80 MPa, a DOC/t greater than or equal to 0.17, and a depth of layer of a spike (DOL sp ) greater than or equal to 0.012 t.
- CS peak compressive stress
- CS k compressive stress at a knee
- DOL sp depth of layer of a spike
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC), wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 970 MPa, a compressive stress at a knee (CS k ) greater than or equal to 50 MPa, a DOC/t greater than or equal to 0.17, and a depth of layer of a spike (DOL sp ) greater than or equal to 0.02 t .
- CS peak compressive stress
- CS k compressive stress at a knee
- DOL sp depth of layer of a spike
- the glass-based article of any of aspects (19) to the preceding aspect is provided, wherein the DOLsp is greater than or equal to 10 ⁇ m.
- the glass-based article of any of aspects (19) to the preceding aspect is provided, wherein the DOL sp is greater than or equal to 10.5 ⁇ m.
- the glass-based article of any of aspects (19) to the preceding aspect is provided, wherein the DOL sp is greater than or equal to 11 ⁇ m.
- the glass-based article of any of the preceding aspects is provided, wherein a peak central tension (PT) of the glass-based article is greater than or equal to 68 MPa.
- the glass-based article of any of the preceding aspects is provided, wherein a peak central tension (PT) of the glass-based article is greater than or equal to 70 MPa.
- the glass-based article of any of the preceding aspects is provided, wherein a peak central tension (PT) of the glass-based article is greater than or equal to 73 MPa.
- the glass-based article of any of the preceding aspects is provided, wherein t is less than or equal to 0.7 mm.
- the glass-based article of any of the preceding aspects is provided, wherein t is less than or equal to 0.65 mm.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC), wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 500 MPa, a depth of layer of a spike (DOL sp ) greater than or equal to 0.008 ⁇ t, a stress profile including a low slope region with an average absolute value of a slope less than or equal to 0.2 MPa/ ⁇ m, the low slope region is located in the compressive stress layer and extends for at least 10 ⁇ m, and the average compressive stress in the low slope region is greater than or equal to 80 MPa.
- CS peak compressive stress
- DOL sp depth of layer of a spike
- a stress profile including a low slope region with an average absolute value of a slope less than or equal to
- the glass-based article of the preceding aspect is provided, wherein the average compressive stress in the low slope region is greater than or equal to 90 MPa.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the average compressive stress in the low slope region is greater than or equal to 100 MPa.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the average absolute value of the slope in the low slope region is less than or equal to 0.25 MPa/ ⁇ m.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region starts at a depth greater than or equal to 0.01 t .
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region starts at a depth greater than or equal to 0.012 t .
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region starts at a depth greater than or equal to 0.015 t .
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region extends to a depth of less than or equal to 0.02 t .
- the glass-based article of any of aspects (29) to (34) is provided, wherein the low slope region extends to a depth of less than or equal to 0.15 t.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region extends to a depth of less than or equal to 0. 12t.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region extends to a depth of less than or equal to 0.1 t.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the low slope region extends to a depth of less than or equal to 0.09 t .
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 600 MPa.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 700 MPa.
- the glass-based article of any of aspects (29) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 750 MPa.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium; and a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC), wherein the glass-based article comprises a peak compressive stress (CS) greater than or equal to 500 MPa, a depth of layer of a spike (DOL sp ) greater than or equal to 0.008 t , a stress profile comprising a negative curvature region where a second derivative of stress as a function of depth is negative, the negative curvature region is located in the compressive stress layer, and a maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 0.003 MPa/ ⁇ m 2 .
- CS peak compressive stress
- DOL sp depth of layer of a spike
- a stress profile comprising a negative curvature region where a second derivative of stress as
- the glass-based article of aspect (44) is provided, wherein the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 0.005 MPa/ ⁇ m 2 .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 0.007 MPa/ ⁇ m 2 .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 0.009 MPa/ ⁇ m 2 .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the product of the thickness t and the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 19 GPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the product of the thickness t and the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 32 GPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the product of the thickness t and the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 45 GPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the product of the thickness t and the maximum absolute value of the second derivative in the negative curvature region is greater than or equal to 57 GPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.01 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.012 t.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.015 t .
- the glass-based article of any of aspects (44) to the preceding aspect wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.02 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.04 t .
- the glass-based article of any of aspects (44) to the preceding aspect wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.05 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.06 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth greater than or equal to 0.07 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth less than or equal to 0.2 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth less than or equal to 0.17 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth less than or equal to 0.14 t .
- the glass-based article of any of aspects (44) to the preceding aspect wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth less than or equal to 0.11 t .
- the glass-based article of any of aspects (44) to the preceding aspect wherein the maximum absolute value of the second derivative in the negative curvature region occurs at a depth less than or equal to 0.1 t .
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 600 MPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 700 MPa.
- the glass-based article of any of aspects (44) to the preceding aspect is provided, wherein the peak CS is greater than or equal to 750 MPa.
- the glass-based article of any of the preceding aspects is provided, wherein a ratio of the molar concentration of Li 2 O to the molar concentration of Na 2 O at the center of the glass-based article is less than or equal to 2.0.
- the glass-based article of any of the preceding aspects is provided, wherein a ratio of the molar concentration of Li 2 O to the molar concentration of Na 2 O at the center of the glass-based article is less than or equal to 1.9.
- the glass-based article of any of the preceding aspects is provided, wherein a ratio of the molar concentration of Li 2 O to the molar concentration of Na 2 O at the center of the glass-based article is less than or equal to 1.8.
- the glass-based article of any of the preceding aspects is provided, wherein a ratio of the molar concentration of Li 2 O to the molar concentration of Na 2 O at the center of the glass-based article is less than or equal to 1.6.
- the glass-based article of any of the preceding aspects is provided, wherein a ratio of the molar concentration of Li 2 O to the molar concentration of Na 2 O at the center of the glass-based article is less than or equal to 1.4.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 12 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 11 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 10 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 9.5 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 9 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 8.5 mol%.
- the glass-based article of any of the preceding aspects is provided, wherein the Li 2 O concentration at the center of the glass-based article is less than or equal to 8 mol%.
- a fracture toughness of a glass comprising the central composition is greater than or equal to 0.7 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is greater than or equal to 0.75 MPa ⁇ sqrt(m).
- the glass-based article of any of the preceding aspects is provided, wherein a fracture toughness of a glass comprising the central composition is greater than or equal to 0.77 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is less than or equal to 1.3 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is less than or equal to 1.2 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is less than or equal to 1.1 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is less than or equal to 0.95 MPa ⁇ sqrt(m).
- a fracture toughness of a glass comprising the central composition is less than or equal to 0.9 MPa ⁇ sqrt(m).
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium and sodium, and a Li 2 O/Na 2 O molar ratio of greater than or equal to 0.65 and less than or equal to 1.2; and a fracture toughness corresponding to the central composition in the range of greater than or equal to 0.7 MPa ⁇ sqrt(m) to less than or equal to 1.3 MPa ⁇ sqrt(m).
- the glass-based article of aspect (88) comprising a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC) that is 0.17 t or more.
- DOC depth of compression
- the glass-based article of any of aspects (88) to the preceding aspect comprising a peak compressive stress (CS) in the range of greater than or equal to 500 MPa to 1200 MPa.
- CS peak compressive stress
- the glass-based article of any of aspects (88) to the preceding aspect comprising a compressive stress at a knee (CS k ) in the range of greater than or equal to 80 MPa to 160 MPa.
- the glass-based article of any of aspects (88) to the preceding aspect comprising a peak tension (PT) of greater than or equal to 68 MPa.
- the glass-based article of any of aspects (88) to the preceding aspect is provided, wherein a depth of layer of a spike (DOL sp ) is greater than 0.007 t .
- the glass-based article of any of aspects (88) to the preceding aspect comprising a stress profile comprising a negative curvature region, wherein a second derivative of stress as a function of depth is negative, the negative curvature region is located in a compressive stress layer, and a maximum absolute value of the second derivative in the negative curvature region being greater than or equal to 0.003 MPa/ ⁇ m 2 .
- the glass-based article of any of aspects (88) to the preceding aspect is provided, wherein a LiO 2 concentration of the central composition is less than or equal to 8.5 mol %.
- the glass-based article of any of aspects (88) to the preceding aspect is provided, wherein t is in the range of 0.5 mm to 0.8 mm.
- a glass-based article comprises: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ); a central composition at the center of the glass-based article comprising lithium and a Li 2 O/Na 2 O molar ratio of greater than or equal to 0.65 and less than or equal to 1.2; and a stress profile comprising a negative curvature region, wherein a second derivative of stress as a function of depth is negative, the negative curvature region is located in a compressive stress layer, and a maximum absolute value of the second derivative in the negative curvature region being greater than or equal to 0.003 MPa/ ⁇ m 2 .
- the glass-based article of aspect (97) comprising one or more of the following: a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC) that is 0.17Z or more; a peak compressive stress (CS) in the range of from 500 MPa to 1200 MPa; a compressive stress at a knee (CS k ) in the range of from 80 MPa to 160 MPa; a peak tension (PT) of greater than or equal to 68 MPa; a depth of layer of a spike (DOL sp ) is greater than or equal to 0.007t; a LiO 2 concentration of the central composition that is less than or equal to 8.5 mol %; and t in the range of from 0.5 mm to 0.8 mm.
- DOC depth of compression
- CS compressive stress in the range of from 500 MPa to 1200 MPa
- CS k compressive stress at a knee
- PT peak tension
- DOL sp depth of layer of a spike
- a consumer electronic product comprising: a housing comprising a front surface, a back surface, and side surfaces; electrical components provided at least partially within the housing, the electrical components comprising at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and a cover disposed over the display; wherein at least a portion of at least one of the housing and the cover comprises the glass-based article of one of the preceding claims.
- a method of increasing probability of survival after multiple drops of a glass-based article onto one or more hard surfaces comprises: exposing to an ion exchange treatment a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ) to form a glass-based article with a stress profile comprising a knee, the glass-based article comprising: a central composition at the at the center of the glass-based article comprising lithium and a Li 2 O/Na 2 O molar ratio of greater than or equal to 0.65 and less than or equal to 1.2; an alkali metal oxide comprising a non-zero concentration that varies from the first surface to a depth of layer (DOL) with respect to the alkali metal oxide; and a fracture toughness corresponding to the central composition in the range of greater than or equal to 0.7 MPa ⁇ sqrt(m) to less than or equal to 1.3 MPa ⁇ sqrt(m).
- DOL depth of layer
- the method of aspect (100) is provided, wherein the glass-based article comprising a compressive stress layer extending from a surface of the glass article to a depth of compression (DOC) that is 0.17 t or more.
- DOC depth of compression
- the method of any of aspects (100) to the preceding aspect is provided, wherein the glass-based article comprises a peak compressive stress (CS) in the range of greater than or equal to 500 MPa to 1200 MPa.
- CS peak compressive stress
- the method of any of aspects (100) to the preceding aspect is provided, wherein the glass-based article comprises a compressive stress at the knee (CS k ) in the range of greater than or equal to 80 MPa to 160 MPa.
- the method of any of aspects (100) to the preceding aspect is provided, wherein the glass-based article comprises a peak tension (PT) of greater than or equal to 68 MPa.
- PT peak tension
- the method of any of aspects (100) to the preceding aspect is provided, wherein the DOL of the glass-based article is greater than 0.007 t .
- the method of any of aspects (100) to the preceding aspect is provided, wherein the stress profile comprises a negative curvature region, wherein a second derivative of stress as a function of depth is negative, the negative curvature region is located in a compressive stress layer, and a maximum absolute value of the second derivative in the negative curvature region being greater than or equal to 0.003 MPa/ ⁇ m 2 .
- a LiO 2 concentration of the central composition is less than or equal to 8.5 mol %.
- the method of any of aspects (100) to the preceding aspect is provided, wherein the central composition comprises a Li 2 O/Na 2 O molar ratio less than or equal to 1.2.
- t is in the range of 0.5 mm to 0.8 mm.
- a glass-based article is provided.
- the glass-based article is made according to the method of any of aspects (100) to the preceding aspect.
- a stress profile for a lithium-containing glass-based article is provided that exhibits high fracture resistance.
- glass-based article and “glass-based substrates” are used to include any object made wholly or partly of glass, including glass-ceramics (including an amorphous phase and a crystalline phase).
- Laminated glass-based articles include laminates of glass and non-glass materials, laminates of glass and crystalline materials.
- Glass-based substrates according to one or more embodiments can be selected from soda-lime silicate glass, alkali-alumino silicate glass, alkali-containing borosilicate glass, alkali-containing aluminoborosilicate glass, and alkali-containing glass-ceramics.
- a “base composition” is a chemical make-up of a substrate prior to any ion exchange (IOX) treatment. That is, the base composition is undoped by any ions from IOX.
- a composition at the center of a glass-based article that has been IOX treated is typically the same as the base composition when IOX treatment conditions are such that ions supplied for IOX do not diffuse into the center of the substrate.
- a central composition at the center of the glass article comprises the base composition.
- a glass-based article that is “substantially free of MgO” is one in which MgO is not actively added or batched into the glass-based article, but may be present in very small amounts as a contaminant.
- the term “about” means that amounts, sizes, formulations, parameters, and other quantities and characteristics are not and need not be exact, but may be approximate and/or larger or smaller, as desired, reflecting tolerances, conversion factors, rounding off, measurement error and the like, and other factors known to those of skill in the art.
- the term “about” is used in describing a value or an end-point of a range, the disclosure should be understood to include the specific value or end-point referred to.
- compositions described herein are expressed in terms of mole percent (mol %) on an oxide basis.
- a "stress profile” is stress as a function of thickness across of a glass-based article.
- a compressive stress region extends from a first surface to a depth of compression (DOC) of the article, where the article is under compressive stress.
- a central tension region extends from the DOC to include the region where the article is under tensile stress.
- depth of compression refers to the depth at which the stress within the glass-based article changes from compressive to tensile stress.
- DOC depth of compression
- the stress crosses from a positive (compressive) stress to a negative (tensile) stress and thus exhibits a stress value of zero.
- compression is expressed as a negative ( ⁇ 0) stress and tension is expressed as a positive (> 0) stress.
- negative values of stress are tensile stress.
- CT central tension
- Central tension (CT) refers to tensile stress in a central region or a central tension region of the glass-based article.
- Maximum central tension (maximum CT or CT max ) occurs in the central tension region nominally at 0.5•t, where t is the article thickness, which allows for variation from exact center of the location of the maximum tensile stress.
- Peak tension (PT) refers to maximum tension measured, which may or may not be at the center of the article.
- a “knee” of a stress profile is a depth of an article where the slope of the stress profile transitions from steep to gradual.
- the knee may refer to a transition area over a span of depths where the slope is changing.
- a non-zero metal oxide concentration that varies from the first surface to a depth of layer (DOL) with respect to the metal oxide or that varies along at least a substantial portion of the article thickness ( t ) indicates that a stress has been generated in the article as a result of ion exchange.
- the variation in metal oxide concentration may be referred to herein as a metal oxide concentration gradient.
- the metal oxide that is non-zero in concentration and varies from the first surface to a DOL or along a portion of the thickness may be described as generating a stress in the glass-based article.
- the concentration gradient or variation of metal oxides is created by chemically strengthening a glass-based substrate in which a plurality of first metal ions in the glass-based substrate is exchanged with a plurality of second metal ions.
- depth of exchange As used herein, the terms “depth of exchange”, “depth of layer” (DOL), “chemical depth of layer”, and “depth of chemical layer” may be used interchangeably, describing in general the depth at which ion exchange facilitated by an ion exchange process (IOX) takes place for a particular ion.
- IOX ion exchange process
- DOL refers to the depth within a glass-based article (i.e., the distance from a surface of the glass-based article to its interior region) at which an ion of a metal oxide or alkali metal oxide (e.g., the metal ion or alkali metal ion) diffuses into the glass-based article where the concentration of the ion reaches a minimum value, as determined by Glow Discharge - Optical Emission Spectroscopy (GD-OES)).
- the DOL is given as the depth of exchange of the slowest-diffusing or largest ion introduced by an ion exchange (IOX) process.
- CT and CS are expressed herein in MegaPascals (MPa), thickness is express in millimeters and DOC and DOL are expressed in microns (micrometers, or ⁇ m).
- Compressive stress including surface/peak CS, CS max
- DOL sp are measured by surface stress meter (FSM) using commercially available instruments such as the FSM-6000, manufactured by Orihara Industrial Co., Ltd. (Japan).
- FSM surface stress meter
- Surface stress measurements rely upon the accurate measurement of the stress optical coefficient (SOC), which is related to the birefringence of the glass. SOC in turn is measured according to Procedure C (Glass Disc Method) described in ASTM standard C770-16, entitled “Standard Test Method for Measurement of Glass Stress-Optical Coefficient," the contents of which are incorporated herein by reference in their entirety.
- Compressive stress at the knee CS k may be measured by a method according to U.S. Ser. No. 16/015776, filed June 22, 2018 to the assignee, which is incorporated herein by reference.
- the maximum central tension (CT) or peak tension (PT) and stress retention values are measured using a scattered light polariscope (SCALP) technique known in the art.
- SCALP scattered light polariscope
- the Refracted near-field (RNF) method or SCALP may be used to measure the stress profile and the depth of compression (DOC).
- RNF Refracted near-field
- DOC depth of compression
- the maximum CT value provided by SCALP is utilized in the RNF method.
- the stress profile measured by RNF is force balanced and calibrated to the maximum CT value provided by a SCALP measurement.
- the RNF method is described in U.S. Patent No. 8,854,623 , entitled "Systems and methods for measuring a profile characteristic of a glass sample", which is incorporated herein by reference in its entirety.
- the RNF method includes placing the glass article adjacent to a reference block, generating a polarization-switched light beam that is switched between orthogonal polarizations at a rate of from 1 Hz to 50 Hz, measuring an amount of power in the polarization-switched light beam and generating a polarization-switched reference signal, wherein the measured amounts of power in each of the orthogonal polarizations are within 50% of each other.
- the method further includes transmitting the polarization-switched light beam through the glass sample and reference block for different depths into the glass sample, then relaying the transmitted polarization-switched light beam to a signal photodetector using a relay optical system, with the signal photodetector generating a polarization-switched detector signal.
- the method also includes dividing the detector signal by the reference signal to form a normalized detector signal and determining the profile characteristic of the glass sample from the normalized detector signal.
- Glass-based articles herein have stress profiles that are designed to increase probability of survival after multiple drops onto hard surfaces.
- High fracture toughness offers new higher levels of fracture resistance when combined with these advantageous stress profiles.
- the stress profiles include increased compressive stresses, for example, high peak compressive stress (CS) and high knee stress (CS k ), separately or in combination with other parameters.
- High depth of compression (DOC) and high spike depth of layer (DOL sp ), separately or in combination with other parameters, are also achieved.
- Peak tension (PT) of desired values are also obtained.
- the stress profiles may include a negative curvature region in a compressive stress layer, identified by having a negative second derivative, which contributes to the ability of the glass-based articles to survive multiple drops.
- Alkali aluminosilicate glasses have good ion exchangeability, and chemical strengthening processes have been used to achieve high strength and high toughness properties in alkali aluminosilicate glasses.
- Sodium aluminosilicate glasses are highly ion exchangeable glasses with high glass formability and quality.
- Lithium aluminosilicate glasses are highly ion exchangeable glasses with high glass quality. The substitution of Al 2 O 3 into the silicate glass network increases the interdiffusivity of monovalent cations during ion exchange.
- glasses with high strength, high toughness, and high indentation cracking resistance can be achieved.
- the stress profiles achieved through chemical strengthening may have a variety of shapes that increase the drop performance, strength, toughness, and other attributes of the glass articles.
- lithium aluminosilicate glasses with good physical properties, chemical durability, and ion exchangeability have drawn attention for use as cover glass.
- CT central tension
- DOC depth of compression
- CS high compressive stress
- the concentration of constituent components are given in mole percent (mol%) on an oxide basis, unless otherwise specified. It should be understood that any of the variously recited ranges of one component may be individually combined with any of the variously recited ranges for any other component.
- the glass has a first region under compressive stress (e.g., first and second compressive stress layers 120, 122 in FIG. 1 ) extending from the surface to a depth of compression (DOC) of the glass and a second region (e.g., central region 130 in FIG. 1 ) under a tensile stress or central tension (CT) extending from the DOC into the central or interior region of the glass.
- first and second compressive stress layers 120, 122 in FIG. 1 extending from the surface to a depth of compression (DOC) of the glass and a second region (e.g., central region 130 in FIG. 1 ) under a tensile stress or central tension (CT) extending from the DOC into the central or interior region of the glass.
- CT tensile stress or central tension
- the compressive stress (CS) has a maximum or peak value, which typically occurs at the surface of the glass(but such need not be the case as the peak may occur at a depth from the surface of the glass), and the CS varies with distance d from the surface according to a function.
- the first compressive stress layer 120 extends from first surface 110 to a depth di and a second compressive stress layer 122 extends from second surface 112 to a depth d 2 . Together, these segments define a compression or CS of glass 100 .
- an alkali metal oxide having a non-zero concentration that varies from one or both of first and second surfaces to a depth of layer (DOL) with respect to the metal oxide.
- a stress profile is generated due to the non-zero concentration of the metal oxide(s) that varies from the first surface.
- the non-zero concentration may vary along a portion of the article thickness.
- the concentration of the alkali metal oxide is non-zero and varies, both along a thickness range from about O• t to about 0.3• t .
- the concentration of the alkali metal oxide is non-zero and varies along a thickness range from about 0• t to about 0.35• t , from about 0• t to about 0.4• t , from about 0• t to about 0.45• t , from about 0• t to about 0.48• t , or from about 0• t to about 0.50• t .
- the variation in concentration may be continuous along the above-referenced thickness ranges.
- Variation in concentration may include a change in metal oxide concentration of about 0.2 mol % or more along a thickness segment of about 100 micrometers.
- the change in metal oxide concentration may be about 0.3 mol % or more, about 0.4 mol % or more, or about 0.5 mol % or more along a thickness segment of about 100 micrometers. This change may be measured by known methods in the art including microprobe.
- the variation in concentration may be continuous along thickness segments in the range from about 10 micrometers to about 30 micrometers.
- the concentration of the alkali metal oxide decreases from the first surface to a value between the first surface and the second surface and increases from the value to the second surface.
- the concentration of alkali metal oxide may include more than one metal oxide (e.g., a combination of Na 2 O and K 2 O).
- concentration of ions having a larger radius is greater than the concentration of ions having a smaller radius at shallow depths, while at deeper depths, the concentration of ions having a smaller radius is greater than the concentration of ions having larger radius.
- the alkali metal oxide concentration gradient extends through a substantial portion of the thickness t of the article.
- the concentration of the metal oxide may be about 0.5 mol% or greater (e.g., about 1 mol% or greater) along the entire thickness of the first and/or second section, and is greatest at a first surface and/or a second surface 0• t and decreases substantially constantly to a value between the first and second surfaces. At that value, the concentration of the metal oxide is the least along the entire thickness t ; however the concentration is also non-zero at that point. In other words, the non-zero concentration of that particular metal oxide extends along a substantial portion of the thickness t (as described herein) or the entire thickness t.
- the total concentration of the particular metal oxide in the glass-based article may be in the range from about 1 mol% to about 20 mol%.
- the concentration of the alkali metal oxide may be determined from a baseline amount of the metal oxide in the glass-based substrate ion exchanged to form the glass-based article.
- the glass-based article comprises a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), for example, greater than or equal to 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), for example less than or equal to 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween.
- the glass-based articles may possess one or a combination of the following features: a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200 MPa, including all values and subranges therebetween; a compressive stress at a knee (CS k ) that is greater than or equal to 80 MPa, 85 MPa, 90 MPa, 95 MPa, 100 MPa, 105 MPa, 110 MPa, 115 MPa, 120 MPa, 125 MPa, 130 MPa, 135 MPa, 140 MPa, 145 MPa, 150 MPa, 155 MPa, 160 MPa, including all values and subranges therebetween; a peak tension (PT) that is greater than or equal to 68 MPa, 69 MPa, 70 MPa
- the glass-based article comprises a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200 MPa, including all values and subranges therebetween.
- CS peak compressive stress
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a compressive stress at a knee (CS k ) that is greater than or equal to 80 MPa, 85 MPa, 90 MPa, 95 MPa, 100 MPa, 105 MPa, 110 MPa, 115 MPa, 120 MPa, 125 MPa, 130 MPa, 135 MPa, 140 MPa, 145 MPa, 150 MP
- the glass-based article comprises a compressive stress at a knee (CS k ) that is greater than or equal to 80 MPa, 85 MPa, 90 MPa, 95 MPa, 100 MPa, 105 MPa, 110 MPa, 115 MPa, 120 MPa, 125 MPa, 130 MPa, 135 MPa, 140 MPa, 145 MPa, 150 MPa, 155 MPa, 160 MPa, including all values and subranges therebetween.
- CS k compressive stress at a knee
- the glass-based article comprises a compressive stress at a knee (CS k ) that is greater than or equal to 50 MPa, 55 MPa, 60 MPa, 65 MPa, 70 MPa, 75 MPa, 80 MPa, 85 MPa, 90 MPa, 95 MPa, 100 MPa, 105 MPa, 110 MPa, 115 MPa, 120 MPa, 125 MPa, 130 MPa, 135 MPa, 140 MPa, 145 MPa, 150 MPa, 155 MPa, 160 MPa, including all values and subranges therebetween.
- CS k compressive stress at a knee
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1
- CS peak compressive stress
- the glass-based article comprises a peak tension (PT) that is greater than or equal to 68 MPa, 69 MPa, 70 MPa, 71 MPa, 72 MPa, or 73 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa, including all values and subranges therebetween.
- PT peak tension
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200 MPa
- CS peak compress
- the glass-based article comprises a depth of compression (DOC) that is greater than or equal to 0.13 t , 0.14 t , 0.15 t , 0.16 t , 0.17 t , 0.18 t , 0.19 t , 0.20 t , 0.21 t , 0.22 t , and/or less than or equal to 0.30 t , 0.29 t , 0.28 t , 0.27 t , 0.26 t , 0.25 t , 0.24 t , 0.23 t , including all values and subranges therebetween.
- DOC depth of compression
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200 MPa
- CS peak compress
- the glass-based article comprises a spike depth of layer (DOL sp ) that is greater than or equal to 0.007 t , 0.008 t , 0.009 t , or 0.01 t , including all values and subranges therebetween and/or at a depth from a surface of 7 microns or more, 7.8 microns or more, 8 microns or more, 8.5 microns or more, 9 microns or more, 9.5 microns or more, 10 microns or more, 10.5 microns or more, or 11 microns or more, including all values and subranges therebetween.
- DOL sp spike depth of layer
- the glass-based article comprises a spike depth of layer (DOL sp ) that is greater than or equal to 0.012 t , 0.014 t , 0.016 t , 0.018 t , or 0.02 t , including all values and subranges therebetween.
- DOL sp spike depth of layer
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or
- CS peak compressive stress
- the glass-based article comprises a stress profile comprising a negative curvature region wherein a second derivative of stress as a function of depth is negative, the negative curvature region is located in a compressive stress layer, and one or more of the following characteristics: a maximum absolute value of the second derivative in the negative curvature region being greater than or equal to 0.003 MPa/ ⁇ m 2 , 0.005 MPa/ ⁇ m 2 , 0.007 MPa/ ⁇ m 2 , or 0.009 MPa/ ⁇ m 2 ; and/or being located at depth that is greater than or equal to 0.01 t , 0.012 t , 0.015 t , 0.02 t , 0.04 t , 0.05 t , 0.06 t , 0.07 t , including all values and subranges therebetween; and/or being located at a depth of less than 0.2 t , 0.17 t , 0.14 t , 0.11 t , or 0.1 t , including all values
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa,
- CS peak compressive stress
- the glass-based article comprises a stress profile including a low slope region having one or more of the following characteristics: an average absolute value of a slope of less than or equal to 0.2 MPa/ ⁇ m; and/or the average compressive stress in the low slope region is greater than or equal to 80 MPa, 90 MPa, or 100 MPa, including all values and subranges therebetween.
- the low slope region is located in the compressive stress layer and extends for 10 ⁇ m or more.
- the low slope region starts at a depth that is greater than or equal to 0.01 t , 0.012 t , 0.015 t , 0.02 t , including all values and subranges therebetween; and/or being located at a depth of less than 0.2 t , 0.15 t , 0.12 t , 0.1 t , or 0.09 t including all values and subranges therebetween.
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200
- CS peak compressive stress
- the glass-based article comprises t in the range of 0.5 mm to 0.8 mm, and all values and subranges therebetween; and/or t may be 0.8 mm or less, 0.75 mm or less, 0.73 mm or less, 0.70 mm or less, 0.65 mm or less, 0.6 mm or less, 0.55 mm or less, 0.4 mm or less, 0.3 mm or less, or 0.2 mm or less.
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or 1200 MPa
- CS peak compress
- the glass-based article comprises a Li 2 O/Na 2 O molar ratio that is less than or equal to 2.0, 1.9, 1.8, 1.6, 1.4, 1.2 at the center of the glass-based article.
- the Li 2 O/Na 2 O molar ratio is greater than or equal to 0.65 and less than or equal to 1.2; or greater than or equal to 0.70 and less than or equal to 1.1; or greater than or equal to 0.75 and less than or equal to 1.5; or greater than or equal to 0.75 and less than or equal to 1.25; or greater than or equal to 0.8 and less than or equal to 1.1, or greater than or equal to 0.85 and less than or equal to 1.05, or greater than or equal to 0.9 and less than or equal to 1.
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 11
- CS peak compressive stress
- the glass-based article comprises a Li 2 O molar concentration that is less than or equal to 12 mol %, 11 mol %, 10 mol %, 9.5 mol %, 9 mol %, 8.5 mol %, or 8 mol %, at the center of the glass-based article.
- the glass-based articles may possess one or a combination of the following features: a fracture toughness corresponding to the central composition of greater than or equal to 0.7 MPa ⁇ sqrt(m), 0.75 MPa ⁇ sqrt(m), or 0.77 MPa ⁇ sqrt(m); and/or a fracture toughness corresponding to the central composition of less than or equal to 1.3 MPa ⁇ sqrt(m), 1.2 MPa ⁇ sqrt(m), 1.1 MPa ⁇ sqrt(m), 0.95 MPa ⁇ sqrt(m), or 0.9 MPa ⁇ sqrt(m); and all values and subranges therebetween; a peak compressive stress (CS) that is greater than or equal to 500 MPa, 550 MPa, 600 MPa, 650 MPa, 700 MPa, 750 MPa, 800 MPa, 850 MPa, 900 MPa, 950 MPa, 1000 MPa, 1050 MPa, 1100 MPa, 1150 MPa, or
- CS peak compressive stress
- a stress profile in the Li-containing glass article has a high surface CS, a high knee stress CS k , and high depth of compression DOC.
- the DOC may be represented as a fraction of the thickness t of the glass article, such as greater than or equal to 0.15 t , or greater than or equal to 0.18 t .
- these properties are produced using a glass composition with a high fracture toughness (K IC ), such as a K IC greater than or equal to 0.77 MPa m 1/2 .
- Such stress profiles are particularly suited to smaller thicknesses, such as 0.7 mm and lower, where existing profiles had a CS k less than or equal to 110 MPa when combined with a CS over 800 MPa, a DOC above 0.18 t ., and a spike depth of layer DOL sp of 7.5 ⁇ m or more.
- the composition of the glass at the center of the glass article exhibits a Li 2 O/Na 2 O molar ratio less than or equal to 1.2.
- the composition at the center of the glass article approximates the composition of the glass before being ion exchanged, as substantially no or no ions exchange at the center of the glass article.
- the stress profile includes a CS k greater than or equal to 125 MPa simultaneously with high values of DOC/t, CS, and DOL sp .
- the stress profile may have a CS k greater than or equal to 140 MPa, such as greater than or equal to 150 MPa, greater than or equal to 160 MPa, or greater than or equal to 170 MPa.
- higher CS k values may provide a robust product even with slightly lower values for the magnitude of CS, DOL, and DOC/ t .
- the peak tension (PT) in the stress profile may be greater than or equal to 70 MPa, such as greater than or equal to 75 MPa, or greater than or equal to 80 MPa, or 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa.
- the PT in the stress profile is less than or equal to 90 MPa, such as less than or equal to 95 MPa, or less than or equal to 100 MPa.
- the PT less than or equal to 110 MPa t such as less than or equal to 100 MPa t , less than or equal to 95 MPa t , less than or equal to 90 MPa t , less than or equal to 80 MPa t , or less than or equal to 77 MPa t , where t is the thickness of the glass articles in mm.
- the stress profile in a Li-containing glass has a surface CS greater than or equal to 970 MPa, a CS k greater than or equal to 50 MPa, and a DOC greater than or equal to 150 ⁇ m and/or a DOC/ t greater than or equal to 0.18.
- the CS is greater than or equal to 1000 MPa, such as greater than or equal to 1030 MPa.
- the CS k is greater than or equal to 70 MPa, such as greater than or equal to 80 MPa, greater than or equal to 90 MPa, greater than or equal to 100 MPa, or greater than or equal to 110 MPa.
- the DOC/ t is greater than or equal to 0.19.
- the stress profile has a DOL sp from greater than or equal to 7 ⁇ m to less than or equal to 9.5 ⁇ m. In some embodiments, the DOL sp from greater than or equal to 9.5 ⁇ m to less than or equal to 14 ⁇ m. In some embodiments, peak tension PT of the stress profile is greater than or equal to 50 MPa, such as greater than or equal to 60 MPa, greater than or equal to 70 MPa, or greater than or equal to 76 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa.
- the PT is less than or equal to 90 MPa, such as less than or equal to 95 MPa, or less than or equal to 100 MPa. In some embodiments, the PT is less than or equal to 110 MPa t , such as less than or equal to 100 MPa t , less than or equal to 95 MPa t , less than or equal to 90 MPa t , less than or equal to 80 MPa t , or less than or equal to 77 MPa t , where t is the thickness of the glass articles in mm.
- a stress profile for a lithium-containing glass article has a peak CS greater than or equal to 400 MPa, a DOL sp from greater than or equal to 3.5 ⁇ m to less than or equal to 15 ⁇ m, a peak tension PT greater than or equal to 73 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa, a DOC/t greater than or equal to 0.18, a Li 2 O/Na 2 O molar concentration ratio at the center of the glass article less than or equal to 1.6, and where when a tension region of the stress profile is fitted with a power-law profile, the power p describing the profile is less than or equal to 2.0.
- the power p describing the profile is less than or equal to 2.05, such as less than or equal to 1.95, or less than or equal to 1.9.
- DOC/ t is greater than or equal to 0.19.
- the PT is less than or equal to 110 MPa t , such as less than or equal to 100 MPa t , less than or equal to 95 MPa t , less than or equal to 90 MPa t , less than or equal to 80 MPa t , or less than or equal to 77 MPa t , where t is the thickness of the glass articles in mm.
- the Li 2 O/Na 2 O molar concentration ratio at the center of the glass article is greater than or equal to 0.6, such as greater than or equal to 0.7, or greater than or equal to 0.8.
- the molar concentration of Li 2 O at the center of the glass article is less than or equal to 9.5 mol%, such as less than or equal to 9 mol%, less than or equal to 8.5 mol%, or less than or equal to 8.2 mol%.
- the molar concentration of Na 2 O at the center of the glass article is less than or equal to 10 mol%, such as less than or equal to 9.5 mol%, less than or equal to 9.0 mol%, or less than or equal to 8.5 mol%.
- the composition at the center of the glass article corresponds to the composition of the glass before ion exchange. These compositions allow a preferred ion diffusivity to be achieved, compatibility with a fusion forming process, and the ability to achieve a high DOC.
- a stress profile for a lithium-containing glass article has a peak CS greater than or equal to 400 MPa, a DOL sp from greater than or equal to 3.5 ⁇ m to less than or equal to 15 ⁇ m, a CS k greater than or equal to 65 MPa, a DOC greater than or equal to 150 ⁇ m and/or DOC/ t greater than or equal to 0.19, and a negative curvature region in the stress profile where the second derivative of the stress as a function of depth is negative, the negative curvature region is located in the compressive stress layer, a peak in the absolute value of the negative second derivative in the negative curvature region occurs at a depth from greater than or equal to 10 ⁇ m to less than or equal 0.18 t , and the peak in the absolute value of the negative second derivative in the negative curvature region is greater than or equal to 3000 MPa/mm 2 .
- the peak in the absolute value of the negative second derivative in the negative curvature region occurs at a depth greater than or equal to 20 ⁇ m, such as greater than or equal to 30 ⁇ m, or greater than or equal to 40 ⁇ m. In some embodiments, the peak in the absolute value of the negative second derivative in the negative curvature region is less than or equal to 50000 MPa/mm 2 . In some embodiments, the peak in the absolute value of the negative second derivative in the negative curvature region is greater than or equal to 4000 MPa/mm 2 , such as greater than or equal to 5000 MPa/mm 2 , greater than or equal to 6000 MPa/mm 2 , or greater than or equal to 8000 MPa/mm 2 .
- the peak in the absolute value of the negative second derivative in the negative curvature region is greater than or equal to 4500/t 2 MPa/mm 2 , such as greater than or equal to 5500/t 2 MPa/mm 2 , greater than or equal to 6600/t 2 MPa/mm 2 , greater than or equal to 8000/t 2 MPa/mm 2 , or greater than or equal to 12000/t 2 MPa/mm 2 .
- the peak CS is greater than or equal to 700 MPa, such as greater than or equal to 750 MPa.
- the CS k is greater than or equal to 65 MPa, such as greater than or equal to 75 MPa, or greater than or equal to 85 MPa.
- the DOC is greater than or equal to 160 ⁇ m. In some embodiments, the DOC/ t is greater than or equal to 0.20.
- the Li 2 O molar concentration at the center of the glass article is greater than or equal to 6.5 mol%. In some embodiments, the molar ratio of Li 2 O to Na 2 O at the center of the glass article is greater than or equal to 0.6, such as greater than or equal to 0.7. In some embodiments, the molar ratio of Li 2 O to Na 2 O at the center of the glass article is less than or equal to 1.2, such as less than or equal to 1.1, or less than or equal to 1.0.
- the peak tension PT is greater than or equal to 65 MPa, such as greater than or equal to 68 MPa, greater than or equal to 71 MPa, or greater than or equal to 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa.
- the PT is less than or equal to 100 MPa, such as less than or equal to 95 MPa, less than or equal to 90 MPa, less than or equal to 85 MPa, less than or equal to 82 MPa, or less than or equal to 80 MPa.
- a glass article has a planar portion having a thickness t , the portion of the glass article has a compressive stress layer on an outer surface extending to a depth of compression.
- the compressive stress layer extends to a depth of compression DOC of greater than or equal to 0.1 t , such as greater than or equal to 0.12 t , greater than or equal to 0.15 t , greater than or equal to 0.17 t , greater than or equal to 0.18 t , or greater than or equal to 0.19 t .
- the glass article has a relatively shallow region representing a near-surface "spike" of compressive stress with a maximum compressive stress CS max of greater than or equal to 950 MPa, such as greater than or equal to 980 MPa, greater than or equal to 1000 MPa, greater than or equal to 1040 MPa, or greater than or equal to 1070 MPa.
- the glass article has a "spike depth of layer" DOL sp from greater than or equal to 3 ⁇ m to less than or equal to 30 ⁇ m.
- the glass article has a knee stress CS k of the stress profile greater than or equal to 50 MPa, such as greater than or equal to 60 MPa, greater than or equal to 70 MPa, greater than or equal to 80 MPa, greater than or equal to 90 MPa, or greater than or equal to 100 MPa.
- the spike region is characterized as generally having substantially higher CS compared to the deeper portion of the compressive-stress layer.
- the knee stress CS k is defined as the value of compressive stress that the deeper portion of the CS profile extrapolates to at the depth DOL sp .
- the depth of the spike DOL sp is reported as measured by a surface-stress meter by known methods utilizing the number of fringes in a prism-coupling angular-coupling spectrum that correspond to guided optical modes in said CS-spike region.
- the measurement wavelength may be less than 590 nm to enable measuring at least 2 such fringes in one polarization state.
- the measurement wavelength may be 545 nm, or even 365 nm.
- DOL sp may be estimated accurately when the CS spike is the result of substantial enrichment of the near-surface layer in larger ions such as potassium (K) when compared to the smaller ions in the glass such as Na or Li.
- DOL sp may be considered to be the depth where the concentration of such larger ions has dropped to a level where its further decay with depth can be considered negligible (e.g., dropped 90% of the way from the maximum K concentration to the baseline level occurring in the next 20 ⁇ m of depth).
- a schematic representation of a stress profile including a knee stress is provided in FIG. 2 .
- the ratio DOC/t is less than or equal to 0.3, such as less than or equal to 0.28, less than or equal to 0.25, or less than or equal to 0.24.
- the glass article contains lithium, such that the concentration of Li 2 O at the center of the glass article is greater than 0.1 mol%. In some embodiments, the Li 2 O concentration at the center of the glass article is greater than or equal to 4 mol%, such as greater than or equal to 5 mol%, greater than or equal to 6 mol%, or greater than or equal to 7 mol%. In some embodiments, the Li 2 O concentration at the center of the glass article is less than or equal to 25 mol%, such as less than or equal to 20 mol %, less than or equal to 16 mol %, or less than or equal to 12 mol %. In some embodiments, a glass composition having the same composition as the center of the glass article has a fracture toughness (K IC ) that is greater than or equal to 0.77 MPa m .
- K IC fracture toughness
- a first ion exchange step may produce a stress profile characterized by a peak CS greater than or equal to 500 MPa, a CS k greater than or equal to 140 MPa, a DOL sp greater than or equal to 4 ⁇ m, a DOC/t ratio greater than or equal to 0.18, and a peak tension PT greater than or equal to 73 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa.
- the PT is less than or equal to 77 MPa t , such as less than or equal to 80 MPa t , less than or equal to 90 MPa t , less than or equal to 95 MPa t , less than or equal to 100 MPa t , or less than or equal to 110 MPa t , where the thickness t is measured in mm.
- the DOL sp is greater than or equal to 4 ⁇ m, such as greater than or equal to 5 ⁇ m, greater than or equal to 6 ⁇ m, or greater than or equal to 7 ⁇ m.
- the DOC/ t ratio is greater than or equal to 0.18, such as greater than or equal to 0.185, greater than or equal to 0.19, or greater than or equal to 0.195.
- the PT is greater than or equal to 73 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa, such as greater than or equal to 78 MPa, greater than or equal to 83 MPa, or greater than or equal to 88 MPa.
- a second ion exchange step may produce a stress profile having a CS greater than or equal to 700 MPa, a DOL sp greater than or equal to 3.5 ⁇ m, a CS k greater than or equal to 110 MPa, a DOC/ t greater than or equal to 0.18, and a PT greater than or equal to 73 MPa, 74 MPa, 75 MPa, 77 MPa, 79 MPa, 80 MPa, 82 MPa, 84 MPa, 86 MPa, or 88 MPa.
- the CS is greater than or equal to 800 MPa.
- the DOL sp is greater than or equal to 5 ⁇ m, such as greater than or equal to 6 ⁇ m, greater than or equal to 7 ⁇ m, or greater than or equal to 7.5 ⁇ m.
- the CS k is greater than or equal to 115 MPa, such as greater than or equal to 120 MPa.
- the DOC/ t is greater than or equal to 0.185, such as greater than or equal to 0.19.
- the PT is greater than or equal to 78 MPa, such as greater than or equal to 83 MPa.
- the PT may be less than or equal to 110 MPa t , such as less than or equal to 100 MPa t , less than or equal to 95 MPa t , less than or equal to 90 MPa t , less than or equal to 80 MPa t , or less than or equal to 77 MPa t . In some embodiments, these examples may also be non-frangible.
- glass-based articles comprise: a glass-based substrate comprising opposing first and second surfaces defining a substrate thickness ( t ), wherein t is greater than or equal to 0.4 mm and less than or equal to 1.3 mm; a stress slope at DOC that is 1.5 MPa/micron or less; and a stress profile comprising: a depth of compression (DOC) that is greater than or equal to 0.15 t ; and an absolute value of stress integral in one compression zone that is in the range of from 4 MPa ⁇ mm to 20 MPa ⁇ mm.
- DOC depth of compression
- the t being greater than or equal to 0.4 mm and less than or equal to 1.3 mm, the DOC that is greater than or equal to 0.15 t ; and the absolute value of stress integral in one compression zone that is in the range of from 4 MPa ⁇ mm to 20 MPa ⁇ mm may be combined with one or more of the following features:
- the glass articles with the stress profiles described herein offer the advantage of overall improvement in fracture resistance when considering several failure modes simultaneously - overstress from drops on smooth hard surfaces (such as those suppressed by using a surface compression spike with a high CS and a DOL 7 ⁇ m or more), deep damage (such as depths of greater than or equal to about 90 ⁇ m) introduction with failure from tension (such as those suppressed by having an increased DOC), and damage introduction to intermediate depths (such as depths of greater than or equal to about 30 ⁇ m to less than or equal to about 90 ⁇ m) combined with simultaneous or subsequent bending (such as those suppressed by having a high compressive stress at intermediate and larger depths, obtained in some cases by profiles with a high DOC and negative second derivative of the compressive stress as a function of depth, or by profiles with increased CS k and high DOC at the same time).
- the stress profiles described herein also allow fast chemical strengthening (ion exchange) due at least in part to the lithium content in the glass before being ion exchanged, and the sodium for lithium ion exchange allows for the fast increase of DOC.
- a further increase in the speed of sodium ion diffusion is achieved when the Li 2 O:Na 2 O molar ratio of the glass composition is from greater than or equal to 0.3 to less than or equal to 1.5, such as from greater than or equal to 0.65 to less than or equal to 1.2; or greater than 0.70 and less than 1.1; or greater than 0.75 and less than 1.5; or greater than 0.75 and less than 1.25; or greater than 0.8 and less than 1.1, or greater than 0.85 and less than 1.05, or greater than 0.9 and less than 1.
- the stress profiles disclosed herein may also be achieved with a lower cost of chemical strengthening (ion exchange).
- a stress profile having relatively high surface CS, DOL sp , CS k , and DOC at the same time, in a Li-containing glass having high fracture toughness, obtained through a single ion exchange step has an advantageously lower cost than a similar stress profile obtained through a 2-step ion exchange process.
- the stress profile of the glass-based article may include a spike region that includes an increased level of compressive stress.
- Such stress profiles are characterized by an increased DOL sp and increased surface CS, and may exhibit a reduced CS k .
- These stress profiles exhibit improved resistance to flaw formation due to the increased amount of compressive stress in the spike region, as illustrated by increased multi-orientation drop performance onto rough surfaces.
- the increased area of the spike region is believed to prevent the formation of flaws in the glass-based articles, and may be a particularly pronounced effect for three-dimensionally shape articles and articles with reduced thickness.
- the beneficial effect associated with the increased spike region area appears to be so significant that that amount of compressive stress present at deeper depths in the glass-based article may be reduced and maintain the desired performance.
- These "large spike area" profiles may be characterized by a DOL sp of at least 0.02t where t is the thickness of the glass-based article and/or at least 10 ⁇ m, in conjunction with a CS k of at least 80 MPa, a peak compressive stress of at least 970 MPa, and a ratio of the depth of compression to the thickness of the article of at least 0.17.
- DOL sp of at least 0.02t where t is the thickness of the glass-based article and/or at least 10 ⁇ m
- CS k of at least 80 MPa
- peak compressive stress of at least 970 MPa
- a ratio of the depth of compression to the thickness of the article of at least 0.17 may be further combined with any other stress profile attributes described herein.
- the articles may have a DOL sp of at most 0.04 t , a DOL sp of at most 0.036 t , a DOL sp of at most 0.032 t , a DOL sp of at most 0.03 t , or a DOL sp of at most 0.028 t .
- the articles may have a DOL sp of at most 20 ⁇ m, a DOL sp of at most 19 ⁇ m, a DOL sp of at most 18 ⁇ m, a DOL sp of at most 17 ⁇ m, a DOL sp of at most 16 ⁇ m, a DOL sp of at most 15 ⁇ m, or a DOL sp of at most 14 ⁇ m.
- the articles may have a CS k of greater than or equal to 50 MPa, greater than or equal to 55 MPa, greater than or equal to 60 MPa, greater than or equal to 65 MPa, greater than or equal to 70 MPa, greater than or equal to 75 MPa, greater than or equal to 80 MPa, greater than or equal to 85 MPa, greater than or equal to 90 MPa, greater than or equal to 95 MPa, greater than or equal to 100 MPa, or more.
- the articles may have a CS k of less than or equal to 150 MPa, less than or equal to 140 MPa, less than or equal to 130 MPa, less than or equal to 120 MPa, less than or equal to 115 MPa, or less.
- the CS k of the articles may be in a range formed from any combination of these minimum and maximum values.
- the stress profiles of the glass-based articles may be characterized by the trapezoidal area of the spike region.
- the stress profiles described herein may be characterized by a TA sp value of greater than or equal to 4000 MPa ⁇ ⁇ m, greater than or equal to 4400 MPa ⁇ ⁇ m, greater than or equal to 4700 MPa ⁇ ⁇ m, greater than or equal to 5000 MPa ⁇ ⁇ m, greater than or equal to 5300 MPa ⁇ ⁇ m, greater than or equal to 5500 MPa ⁇ ⁇ m, greater than or equal to 5700 MPa ⁇ ⁇ m, greater than or equal to 5800 MPa ⁇ ⁇ m, or any subranges formed from these values.
- the Kic fracture toughness is measured by the double cantilever beam (DCB) method.
- the K IC values were measured on glass-based substrates before being ion exchanged to form the glass-based articles.
- the DCB specimen geometry is shown in FIG. 3 with parameters being the crack length a , applied load P , cross-sectional dimensions w and 2h, and the thickness of the crack-guiding groove b.
- a hole was drilled on both ends with a diamond drill to provide a means of attaching the sample to a sample holder and to the load.
- a crack "guiding groove” was cut down the length of the sample on both flat faces using a wafer dicing saw with a diamond blade, leaving a "web” of material, approximately half the total plate thickness (dimension b in FIG. 1 ), with a height of 180 ⁇ m corresponding to the blade thickness.
- the high precision dimensional tolerances of the dicing saw allow for minimal sample-to-sample variation.
- a crack was first initiated at the tip of the web, and then the starter crack was carefully sub-critically grown until the ratio of dimensions a / h was greater than 1.5, as per equation (III) to accurately calculate stress intensity.
- the crack length, a was measured and recorded using a traveling microscope with 5 ⁇ m resolution.
- a drop of toluene was then placed into the crack groove and wicked along the length of groove by capillary forces, pinning the crack from moving until the fracture toughness is reached.
- the load was then increased until sample fracture occurred, and the critical stress intensity Kic calculated from the failure load and sample dimensions, with K P being equivalent to K IC due to the measurement method.
- Specific examples of glass-based substrates that may be used include but are not limited to an alkali-alumino silicate glass, an alkali-containing borosilicate glass, an alkali-alumino borosilicate glass, an alkali-containing lithium alumino silicate glass, or an alkali-containing phosphate glass.
- the glass-based substrates have base compositions that may be characterized as ion exchangeable.
- ion exchangeable means that a substrate comprising the composition is capable of exchanging cations located at or near the surface of the substrate with cations of the same valence that are either larger or smaller in size.
- glass-based substrates may include a lithium-containing aluminosilicate.
- the glass-based substrates may be formed from any composition capable of forming the stress profiles.
- the glass-based substrates may be formed from the glass compositions described in U.S. Provisional Application No. 62/591,953 titled “Glasses with Low Excess Modifier Content,” filed November 29, 2017 , the entirety of which is incorporated herein by reference.
- the glass articles may be formed from the glass compositions described in U.S. Provisional Application No. 62/591,958 titled “Ion-Exchangeable Mixed Alkali Aluminosilicate Glasses,” filed November 29, 2017 , the entirety of which is incorporated herein by reference.
- the glass-based substrates may be characterized by the manner in which it may be formed.
- the glass-based substrates may be characterized as float-formable (i.e., formed by a float process), down-drawable and, in particular, fusion-formable or slot-drawable (i.e., formed by a down draw process such as a fusion draw process or a slot draw process).
- Some embodiments of the glass-based substrates described herein may be formed by a down-draw process. Down-draw processes produce glass-based substrates having a uniform thickness that possess relatively pristine surfaces. Because the average flexural strength of the glass article is controlled by the amount and size of surface flaws, a pristine surface that has had minimal contact has a higher initial strength. In addition, down drawn glass articles have a very flat, smooth surface that can be used in its final application without costly grinding and polishing.
- the glass-based substrates may be described as fusion-formable (i.e., formable using a fusion draw process).
- the fusion process uses a drawing tank that has a channel for accepting molten glass raw material.
- the channel has weirs that are open at the top along the length of the channel on both sides of the channel.
- the molten glass overflows the weirs. Due to gravity, the molten glass flows down the outside surfaces of the drawing tank as two flowing glass films. These outside surfaces of the drawing tank extend down and inwardly so that they join at an edge below the drawing tank.
- the two flowing glass films join at this edge to fuse and form a single flowing glass article.
- the fusion draw method offers the advantage that, because the two glass films flowing over the channel fuse together, neither of the outside surfaces of the resulting glass article comes in contact with any part of the apparatus. Thus, the surface properties of the fusion drawn glass article are not affected by such contact.
- Some embodiments of the glass-based substrates described herein may be formed by a slot draw process.
- the slot draw process is distinct from the fusion draw method.
- the molten raw material glass is provided to a drawing tank.
- the bottom of the drawing tank has an open slot with a nozzle that extends the length of the slot.
- the molten glass flows through the slot/nozzle and is drawn downward as a continuous glass article and into an annealing region.
- the glass-based substrates described herein may exhibit an amorphous microstructure and may be substantially free of crystals or crystallites.
- the glass-base substrates articles exclude glass-ceramic materials in some embodiments.
- Chemical strengthening of glass substrates having base compositions is done by placing the ion-exchangeable glass substrates in a molten bath containing cations (e.g., K+, Na+, Ag+, etc) that diffuse into the glass while the smaller alkali ions (e.g., Na+, Li+) of the glass diffuse out into the molten bath.
- cations e.g., K+, Na+, Ag+, etc
- the smaller alkali ions e.g., Na+, Li+
- ion exchange processes they may independently be a thermal-diffusion process or an electro-diffusion process.
- ion exchange processes in which glass is immersed in multiple ion exchange baths, with washing and/or annealing steps between immersions, are described in U.S. Pat. No. 8,561,429, by Douglas C. Allan et al., issued on Oct. 22, 2013 , entitled “Glass with Compressive Surface for Consumer Applications,” and claiming priority from U.S. Provisional Patent Application No. 61/079,995, filed Jul. 11, 2008 , in which glass is strengthened by immersion in multiple, successive, ion exchange treatments in salt baths of different concentrations; and U.S. Pat. No.
- a composition at the surface of a glass article may be different than the composition of the as-formed glass article ( i . e ., the glass article before it undergoes an ion exchange process).
- the glass composition at or near the center of the depth of the glass article will, in embodiments, still have the composition of the as-formed glass article.
- the glass-based articles disclosed herein may be incorporated into another article such as an article with a display (or display articles) (e.g., consumer electronics, including mobile phones, tablets, computers, navigation systems, and the like), architectural articles, transportation articles (e.g., automobiles, trains, aircraft, sea craft, etc.), appliance articles, or any article that requires some transparency, scratch-resistance, abrasion resistance or a combination thereof.
- a display or display articles
- FIGS. 4A and 4B An exemplary article incorporating any of the glass articles disclosed herein is shown in FIGS. 4A and 4B . Specifically, FIGS.
- FIGS. 4A and 4B show a consumer electronic device 200 including a housing 202 having front 204, back 206, and side surfaces 208; electrical components (not shown) that are at least partially inside or entirely within the housing and including at least a controller, a memory, and a display 210 at or adjacent to the front surface of the housing; and a cover substrate 212 at or over the front surface of the housing such that it is over the display.
- the cover substrate 212 may include any of the glass articles disclosed herein.
- Glass sheets were formed having a lithium-alumino silicate glass composition according to Composition A or Composition B.
- Composition A as formed and analyzed included: 63.70 mol% SiO 2 , 0.39 mol% B 2 O 3 , 16.18 mol% Al 2 O 3 , 8.10 mol% Na 2 O, 0.53 mol% K 2 O, 8.04 mol% Li 2 O, 0.33 mol% MgO, 0.01 mol% TiO 2 , 0.02 mol% Fe 2 O 3 , 0.05 mol% SnO 2 , and 2.64 mol% P 2 O 5 .
- CS max peak compressive stress
- DOL sp depth of layer of spike
- CS k compressive stress at the knee
- DOC depth of compression
- PT peak tension
- CS max and DOL sp were measured by a surface stress meter (FSM).
- FSM surface stress meter
- CS k was measured by a method according to U.S. Ser. No. 16/015776, filed June 22, 2018 to the assignee, which is incorporated herein by reference.
- Stress profile and DOC were measured by a Refracted near-field (RNF) method.
- PT and stress retention were measured by a scattered light polariscope (SCALP) technique.
- the stress profiles and DOCs of Table 2 were used to calculate the following, which hare summarized in Table 3: absolute value of the slope at DOC (MPa/ ⁇ m), absolute value of the stress integral of the outer compression region (MPa*mm), absolute value of the stress integral of the tension zone (MPa*mm), percentage of the depth of compression with respect to thickness (DOC/t), and compressive stress integral with respect to thickness (CS integral/t) (MPa).
- Table 3 Example abs. value slope at DOC MPa/ ⁇ m abs. value stress integral outer compression region MPa*mm abs.
- FIG. 5 An exemplary stress profile for Example 2 is shown in FIG. 5 .
- the stress profile in FIG. 5 is the first half of a 0.5 mm thick chemically strengthened glass article.
- the stress profile of FIG. 5 was obtained by a two-step ion exchange process after a heat treatment of a glass sheet of Composition A at a temperature of 580°C for 15 minutes to form the glass sheet into a 3-dimensional shape (3D forming).
- the first step of the ion exchange process was immersion of the sample in a salt bath including approximately 38 wt% NaNO 3 and approximately 62 wt% KNO 3 390°C for 2 hours.
- the second step of the ion exchange process was immersion in a salt bath including approximately 1 wt% NaNO 3 and approximately 99 wt% KNO 3 at 370°C for 20 minutes.
- the resulting stress profile as shown in FIG. 5 , had a CS max of 1100 MPa, a knee stress CS k of 108 MPa, a DOL sp of 8.25 ⁇ m, and a DOC of 99 ⁇ m which represents 0.198 t .
- the stress profile after the first ion exchange step (Example 1) had a CS max of 581 MPa occurring at the surface, a DOL sp at 8.95 ⁇ m, a CS k in the range from greater than or equal to 170 MPa to less than or equal to 180 MPa, a DOC at 97 ⁇ m equating to 0.194 t , and a PT of 91.1 MPa.
- the stress integral over the tension region was 17.7 MPa*mm, and each of the two compressive stress regions had a depth integral of the stress that was about half of that by absolute value.
- the absolute value of the slope of the stress profile at the DOC was 1.15 MPa/micron.
- a glass sheet with the same thermal history and same first-step ion exchange as Example 1 was subjected to a second-step ion exchange in a bath including 6 wt% NaNO 3 and approximately 94 wt% KNO 3 at 380°C for 20 minutes in accordance with Example 4.
- the resulting stress profile after the second step had a peak CS of 877 MPa occurring on the surface, a DOL sp at 8.9 ⁇ m, a CS k at 159 MPa, a PT of 88.3 MPa, and a DOC at 98 ⁇ m equivalent to 0.196 t .
- a glass sheet with the same thermal history and same first-step ion exchange as Example 1 was subjected to a second-step ion exchange in a bath including 5 wt% NaNO 3 and approximately 95 wt% KNO 3 , with immersion at 380°C for 20 minutes in accordance with Example 3.
- the resulting stress profile included a CS max at the surface of 890 MPa, a DOL sp at 8.9 ⁇ m, and a CS k of 142 MPa.
- the peak tension PT and the DOC were about 88.8 MPa, and 98 ⁇ m, respectively.
- FIG. 6 An exemplary stress profile is shown in FIG. 6 .
- the stress profile in FIG. 6 was formed in a 0.6 mm thick sheet of glass (Composition A) with fusion-draw thermal history.
- the glass sheet was ion exchanged at 390°C for 2 hours in a bath including approximately 50 wt% NaNO 3 and 50 wt% KNO 3 in accordance with Example 10.
- the resulting stress profile exhibited a peak CS of 565 MPa at the surface, a DOL sp at 9.06 ⁇ m, a CS k in the range of from 185 to 190 MPa, a DOC at 115.2 ⁇ m, a DOC/ t of 0.192, and PT of 90 MPa.
- the integral under the entire tension zone was about 22.1 MPa*mm.
- the compression regions had a stress-depth integral of about 11.05 MPa*mm by absolute value.
- the absolute value of slope of the stress profile at the DOC was 1.06 MPa/ ⁇ m.
- FIG. 7 An exemplary stress profile is shown in FIG. 7 in accordance with Example 11.
- the stress profile in FIG. 7 was formed in a 0.6 mm thick sheet of glass (Composition A).
- the stress profile was obtained through a two-step ion exchange.
- the first ion exchange step was immersion in a bath at 390°C for 2 hours, the bath included approximately 50 wt% NaNO 3 and 50 wt% KNO 3 .
- the stress profile after the first ion exchange step was similar to the profile shown in FIG. 6 .
- the second ion exchange step was immersion in a bath at 380°C for 0.4 hours, the bath included approximately 6 wt% NaNO 3 and 94 wt% KNO 3 .
- the resulting stress profile had a surface CS of 903 MPa, a DOL sp at 8.36 ⁇ m, a DOC at 119 ⁇ m, a DOC/ t of 0.198, a CS k of 135 MPa, and a PT of 88.6 MPa.
- the absolute value of the slope of the stress profile at the DOC was 1.06 MPa/ ⁇ m.
- the absolute value of the stress integral over the tension region was 21.6 MPa*mm, while the absolute value of the stress integral for each of the two compression regions was 10.81 MPa*mm.
- FIG. 9 An exemplary stress profile is shown in FIG. 9 .
- the stress profile in FIG. 9 was produced in a 0.8 mm thick sheet of glass with Composition A.
- the glass sheet was subjected to a two-step ion exchange treatment as detailed for Example 21 in Table 1.
- the resulting stress profile, as shown in FIG. 9 had a peak CS of 839 MPa, a DOL sp of 8.7 ⁇ m, a DOC of 163 ⁇ m, a DOC/ t of 0.204, a PT of 83.4 MPa, and a CS k of 130 MPa.
- the stress profile slope at the DOC was 0.75 MPa/ ⁇ m, and the CS integral in the compression region was 13.48 MPa ⁇ mm.
- the CS integral normalized to the thickness was 16.85 MPa.
- FIG. 10 An exemplary stress profile is shown in FIG. 10 .
- the stress profile in FIG. 10 was produced in a 0.8 mm thick sheet of glass with Composition A.
- the glass sheet was subjected to an ion exchange treatment as detailed for Example 19 in Table 1.
- FIG. 10 also includes the stress profile for Example 21 and a stress profile produced in a glass sheet with Composition B.
- the three stress profiles shown in FIG. 10 are substantially identical within the spike region (approximately the first 10 ⁇ m).
- the stress profile of Example 19 features a peak CS of 848 MPa at the surface, a DOL sp of 8.3 ⁇ m, a PT of 78.6 MPa, and a DOC of 170 ⁇ m equal to 0.213 t .
- the stress profile of Example 19 matches the CS of the Composition B profile in the first 30 ⁇ m, but then at larger depths from 30 ⁇ m to 225 ⁇ m (from about 0.04 t to about 0.28 t ) is above the prior-art profile in terms of CS as a function of depth. The difference was greatest in the depth range from 80 ⁇ m to 120 ⁇ m.
- the stress profile of Example 19 had a peak negative second derivative of CS occurring at a depth of about 63 ⁇ m (0.08 t ) with an absolute value of 10 -2 MPa/ ⁇ m 2 .
- FIG. 11 An exemplary stress profile is shown in FIG. 11 .
- the stress profile in FIG. 11 was produced according to the details of Example 29 in Table 1.
- the resulting stress profile had a peak CS of 1137 MPa, a DOC of 159 ⁇ m, a DOC/ t of 0.199, a CS k of 169 MPa, a PT of 91 MPa, and a DOL sp of 7.7 ⁇ m.
- the stress profile also features a stress slope at the DOC of 0.75 MPa/ ⁇ m, a CS integral over the compressive region of 14.62 MPa ⁇ mm, which corresponds to 18.28 MPa when normalized to the thickness.
- the stress profile was obtained after a first ion exchange step at 390°C for 3.75 hours in a bath having a 75:25:0.3 ratio of NaNO 3 , KNO 3 , and LiNO 3 by weight.
- the second ion exchange step was a 20 minute immersion in a bath having about 0.5 wt% NaNO 3 and 99.5 wt% KNO 3 , without any addition of LiNO 3 .
- Stress profiles with a lower PT (80-86 MPa), a lower CS (950-1100 MPa), and a lower CS k (120-160 MPa) may be obtained with slight increases of LiNO 3 content (0.1%-0.2% by weight) or by extending the time of the second ion exchange step to 35 minutes or longer, or by slight decrease of NaNO 3 (from 0.5 wt% to 0.3-0.4 wt%) and an increase of LiNO 3 in the second step (from 0 to 0.1-0.2 wt%).
- the substitution of LiNO 3 for NaNO 3 can be used to reduce PT and CSk, while maintaining the peak CS around 1100 MPa.
- FIG. 12 An exemplary stress profile is shown in FIG. 12 .
- the stress profile in FIG. 12 was produced according to the details of Example 25 in Table 1.
- the resulting stress profile featured a combination of a peak CS of 1146 MPa, a DOL sp at 10.8 ⁇ m, a CS k of 133 MPa, a PT of 84.4 MPa, and a DOC of 158 ⁇ m equal to DOC/ t of 0.198.
- the CS integral over the compressive region was 13.5 MPa ⁇ mm, which normalized to the thickness equates to 16.9 MPa.
- the slope at the DOC was 0.67 MPa/ ⁇ m.
- the high DOL sp in combination with high CS helps to prevent high-stress fractures in designs that are prone to generate significant localized stress during a drop event. Additionally, the combination of high peak CS and high DOL sp with a relatively high CS k and DOC is particularly valuable for such circumstances.
- Example 30 Glass Article based on Composition B
- FIG. 8 An exemplary stress profile is shown in FIG. 8 .
- the stress profile in FIG. 8 was produced in a 0.6 mm thick sheet of glass with Composition B.
- the glass sheet was heat treated at a temperature of 580°C for 15 minutes to form the glass sheet into a 3-dimensional shape (3D forming).
- the glass sheet was then subjected to a two-step ion exchange treatment.
- the first step of the ion exchange process was immersion of the sample in a salt bath including approximately 38 wt% NaNO 3 and approximately 62 wt% KNO 3 at 380°C for 2 hours.
- the second step of the ion exchange process was immersion in a salt bath including approximately 1 wt% NaNO 3 and approximately 99 wt% KNO 3 at 370°C for 20 minutes.
- the resulting stress profile as shown in FIG. 8 , had a peak CS of 1125 MPa, a DOL sp of 9.1 ⁇ m, and a DOC of 113 ⁇ m, a PT of 70.4 MPa at approximately the mid-thickness of the glass article.
- the compressive stress in the depth region from 13 ⁇ m to 30 ⁇ m changes gradually from 76 MPa to 71 MPa, and changed only about 2 MPa in the range from 13 ⁇ m to 23 ⁇ m (correlating to an average slope of about 0.2 MPa/ ⁇ m).
- the stress profile in FIG. 5 for Composition A exhibited a stress value that was over 20 MPa greater in this region, despite having a lower glass article thickness.
- FIG. 13 provides stress profiles that were diffusion modeled using a two-dimensional (2D) plane strain ion exchange (IOX) model, which is based on finite difference modeling for a glass article of Composition B with an increased CS k (260 MPa) and a standard glass article of Composition B of lower CS k (150 MPa), both at a thickness of 0.8 mm.
- FIG. 13 shows compressive stress (MPa) versus depth (microns) of the article as-strengthened by simulated ion-exchange.
- Retained strength refers to the maximum bending stress that can be applied to the glass article in the presence of a crack of at a certain depth before the stress intensity factor at the crack tip reaches the fracture toughness of the material and the crack propagates catastrophically.
- the retained strength plots provide insight regarding the potential drop performance of a device.
- FIG. 14 provides a graph of retained strength (MPa) versus flaw length (microns) resulting after a simulated failure mode of simultaneous dropping onto a rough surface and introduction of sharp contact damage modeled by finite element fracture mechanic modeling.
- the higher CS k profile has a larger area under the curve, which indicates the higher CS k profile could handle more bending stress than the standard glass article for lengths of flaws and/or cracks of about 180 microns or less.
- the inflection point of the retained strength plot of FIG. 14 occurs for flaws that are approximately 20 microns beyond the depth of the inflection point in the compressive stress profile of FIG. 13 .
- the magnitude of increase in compression at the knee corresponds almost one-to-one to the increase in retained strength for flaws in the region of the approximately 30 microns.
- Higher knee stress corresponds to higher retained strength up to the crossover point of the plots ( ⁇ 180 microns). Without intending to be bound by theory, it is thought that the higher knee stress plot has lower strength for the longest flaws because of the more rapid increase in tension beyond the depth of compression. It is noted that failures are rarely observed for applied stresses in the region where the standard Composition B profile had increased retained strength over the high knee stress profile. The higher knee stress profile has higher strength, which decreases until the crossover point is reached.
- FIG. 15 The measured stress profiles of compressive stress (MPa) versus depth (microns) are shown in FIG. 15 , and the associated retained strength is shown in FIG. 16 generated in accordance with Example 31.
- Compositions A and B presented the same depth of compression (DOC) before which Composition A had higher compressive stress and after which Composition B had higher compressive stress.
- Composition A showed higher retained strength for flaw lengths up to about 180 microns.
- a review of Examples 31 and 32 indicates that for profiles having the same DOC, retained strength crossover is approximately constant independent of knee stress.
- FIG. 19 shows that for both thicknesses 0.6 mm and 0.6 mm, the differences in compressive stress (per FIGS. 15 and 17 ), even if not very large, indicate that a cumulative effect will result in improved performance of composition A in the field based on understanding of field failures.
- CS max peak compressive stress
- DOL sp depth of layer of spike
- CS k compressive stress at the knee
- DOC depth of compression
- PT peak tension
- Table 5 possible variation in CS values can be ⁇ 25 MPa and DOL variation can be about ⁇ 0.2 ⁇ m, due to precision limitations of the metrology.
- Table 5 Example CS max MPa DOL sp microns CS k MPa DOC ⁇ m PT MPa 35 859.2 8.3 136.0 166.4 84.2 36 800.0 8.3 150.6 160.1 84.1 37 700-750 8.3 150.6 160.1 84.1 38 875.9 9.0 133.5 109.8 90.5 39 859.2 8.3 136.0 166.4 84.2 40 874.3 8.8 139.4 140.3 84.1 41 908.9 8.5 146.3 118.5 88.6 42 43 908.9 8.5 146.3 118.5 88.6 44 908.9 8.5 146.3 118.5 88.6 45 908.9 8.5 146.3 118.5 88.6 46 883.9 9.0 135.6 98.4 89.3 47 887.1 9.1 120.6 100.4 87.3 48 887.1 9.1 120.6 100.4 87.3 49 875.9 9.0 13
- Example 58 The measured stress profiles of Examples 58 (dashed line) and 59 (solid line) are shown in FIG. 20 .
- the stress profile of Example 58 includes higher compressive stress between the DOL sp and the DOC when compared to Example 59. It was observed that Example 59 exhibited improved fracture resistance in multi-orientation drops onto rough granite than Example 58. This result indicates that the larger compressive stress area of the spike region in Example 59 contributes to increased multi-orientation rough surface drop performance.
- the area of the spike for Example 59 by the trapezoidal method of numerical integration was about 2925 MPa* ⁇ m to a depth of 4 ⁇ m, about 3269 MPa ⁇ ⁇ m to a depth of 5 ⁇ m, about 3555 MPa ⁇ ⁇ m to a depth of 6 ⁇ m, about 3747 MPa ⁇ ⁇ m to a depth of 7 ⁇ m, and about 3905 MPa ⁇ ⁇ m to a depth of 8 ⁇ m, while the area of the spike for Example 58 was between 4 ⁇ m and 10 ⁇ m lower at each of these depths.
- Example 58 generally had a spike area at least about 15% lower than Example 59 at equivalent depths, with a spike area at least 24% lower than Example 59 up to depths of 4 ⁇ m or 5 ⁇ m.
- Example 58 was characterized by a trapezoidal area of the spike (TA sp ), calculated as described above, of 3772 MPa ⁇ ⁇ m and Example 59 had a TA sp of 5803 MPa ⁇ ⁇ m.
- the alternative spike area measurement approach also indicates a correlation between spike area and multi-orientation drop performance. Additionally, the benefit associated with increased spike area is present even where the portions of the stress profile beyond the spike region exhibit decreased compressive stress values, as shown by comparing the stress profiles of Examples 58 and 59 in FIG. 20 .
- Example 59 exhibits a compressive stress integral of about 6073 MPa ⁇ ⁇ m, producing an average compressive stress in the compressive stress region of 69 MPa, as calculated by dividing the compressive stress integral by the DOC.
- the absolute value of the slope of the stress profile at the DOC for Example 59 was about 0.6 MPa/ ⁇ m, and the product of the absolute value of the stress slope at the DOC and the thickness was about 300 MPa for Example 59.
- Example 60 The stress profile for Examples 60 (dashed line), 61 (dashed dot line), and 62 (solid line) are shown in FIG. 21 from the surface to the mid-thickness of the articles.
- Example 60 As a general descriptor, if Example 60 is considered a baseline, Example 61 has an increased maximum compressive stress, and Example 62 exhibits an increased maximum compressive stress and DOL sp .
- Examples 60-62 all exhibited performance in multi-orientation drop testing on rough granite that was equivalent or better than Examples 58 and 59, with Example 62 demonstrating the best performance, with Example 60 exhibiting the least fracture resistance of Examples 60-62 in these tests.
- the absolute value of the slope of the stress profile at the DOC for Example 62 was between about 1.2 MPa/ ⁇ m and about 1.4 MPa/ ⁇ m, and the product of the absolute value of the stress slope at the DOC and the thickness was between about 600 MPa and about 700 MPa for Example 62.
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Materials For Medical Uses (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862682672P | 2018-06-08 | 2018-06-08 | |
US201862699306P | 2018-07-17 | 2018-07-17 | |
EP19733342.0A EP3802451B1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
PCT/US2019/036009 WO2019236975A2 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19733342.0A Division EP3802451B1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
EP19733342.0A Division-Into EP3802451B1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
Publications (1)
Publication Number | Publication Date |
---|---|
EP4279461A1 true EP4279461A1 (fr) | 2023-11-22 |
Family
ID=67003749
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19733342.0A Active EP3802451B1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
EP23201195.7A Pending EP4279461A1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19733342.0A Active EP3802451B1 (fr) | 2018-06-08 | 2019-06-07 | Profils de contrainte résistant à la fracture dans des lunettes |
Country Status (7)
Country | Link |
---|---|
US (4) | US11339088B2 (fr) |
EP (2) | EP3802451B1 (fr) |
JP (1) | JP7492920B2 (fr) |
KR (1) | KR20210018929A (fr) |
CN (2) | CN112851142A (fr) |
TW (1) | TWI801598B (fr) |
WO (1) | WO2019236975A2 (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11130705B2 (en) | 2018-09-11 | 2021-09-28 | Corning Incorporated | Glass-based articles with improved fracture resistance |
CN112789253A (zh) * | 2018-09-28 | 2021-05-11 | 康宁股份有限公司 | 具有改进的应力分布的基于玻璃的制品 |
TW202043168A (zh) | 2019-03-29 | 2020-12-01 | 美商康寧公司 | 抗刮玻璃及製作方法 |
KR20210080654A (ko) * | 2019-12-20 | 2021-07-01 | 삼성디스플레이 주식회사 | 유리 제품 및 이를 포함하는 디스플레이 장치 |
KR20210081478A (ko) * | 2019-12-23 | 2021-07-02 | 삼성디스플레이 주식회사 | 유리 제품 및 그 제조 방법 |
KR20210109695A (ko) * | 2020-02-27 | 2021-09-07 | 삼성디스플레이 주식회사 | 유리 제품 및 그 제조 방법 |
KR20210127268A (ko) * | 2020-04-13 | 2021-10-22 | 삼성디스플레이 주식회사 | 유리 제품 및 이를 포함하는 디스플레이 장치 |
US11434167B2 (en) * | 2020-05-15 | 2022-09-06 | Corning Incorporated | Strengthened glass articles and methods of forming the same |
CN114180826A (zh) * | 2020-09-14 | 2022-03-15 | 肖特股份有限公司 | 低光损耗玻璃制品 |
KR20220088599A (ko) * | 2020-12-18 | 2022-06-28 | (주)유티아이 | 플렉시블 커버 윈도우의 제조방법 및 이에 의한 플렉시블 커버 윈도우 |
US20220396519A1 (en) * | 2021-06-11 | 2022-12-15 | Corning Incorporated | Glass compositions having improved mechanical durability and low characteristic temperatures |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8312739B2 (en) | 2008-07-29 | 2012-11-20 | Corning Incorporated | Dual stage ion exchange for chemical strengthening of glass |
US8561429B2 (en) | 2008-07-11 | 2013-10-22 | Corning Incorporated | Glass with compressive surface for consumer applications |
US8854623B2 (en) | 2012-10-25 | 2014-10-07 | Corning Incorporated | Systems and methods for measuring a profile characteristic of a glass sample |
US20170295657A1 (en) * | 2016-04-08 | 2017-10-12 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
US20170291849A1 (en) * | 2016-04-08 | 2017-10-12 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
US20170305786A1 (en) * | 2016-04-20 | 2017-10-26 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
JP2018065744A (ja) * | 2016-01-21 | 2018-04-26 | 旭硝子株式会社 | 化学強化ガラスおよび化学強化用ガラス |
Family Cites Families (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3995902B2 (ja) * | 2001-05-31 | 2007-10-24 | Hoya株式会社 | 情報記録媒体用ガラス基板及びそれを用いた磁気情報記録媒体 |
JP4726400B2 (ja) * | 2003-05-29 | 2011-07-20 | コニカミノルタオプト株式会社 | ガラス基板の製造方法 |
JP2009167086A (ja) * | 2007-12-18 | 2009-07-30 | Hoya Corp | 携帯端末用カバーガラス及びその製造方法、並びに携帯端末装置 |
EP2334613A1 (fr) * | 2008-08-21 | 2011-06-22 | Corning Inc. | Boîtiers/enceintes durables en verre destinés à des dispositifs électroniques |
US8439808B2 (en) | 2008-09-08 | 2013-05-14 | Brian H Hamilton | Bicycle trainer with variable resistance to pedaling |
TWM359148U (en) | 2009-01-05 | 2009-06-11 | Samya Technology Co Ltd | Universal battery charger |
BR112012019306A2 (pt) * | 2010-02-02 | 2018-05-08 | Apple Inc | vidro de reforço melhorado quimicamente de coberturas para dispositivos eletrônicos portáteis |
JP2012020921A (ja) * | 2010-06-18 | 2012-02-02 | Asahi Glass Co Ltd | ディスプレイ装置用のガラスおよびガラス板 |
US20120052271A1 (en) * | 2010-08-26 | 2012-03-01 | Sinue Gomez | Two-step method for strengthening glass |
US9434644B2 (en) | 2010-09-30 | 2016-09-06 | Avanstrate Inc. | Cover glass and method for producing cover glass |
US8883663B2 (en) * | 2010-11-30 | 2014-11-11 | Corning Incorporated | Fusion formed and ion exchanged glass-ceramics |
CN102531384B (zh) * | 2010-12-29 | 2019-02-22 | 安瀚视特股份有限公司 | 玻璃盖片及其制造方法 |
JP2012232882A (ja) * | 2011-04-18 | 2012-11-29 | Asahi Glass Co Ltd | 化学強化ガラスの製造方法および化学強化用ガラス |
JP5293908B1 (ja) * | 2011-12-16 | 2013-09-18 | 旭硝子株式会社 | ディスプレイ用カバーガラス、ディスプレイ用カバーガラスの製造方法 |
US9359251B2 (en) * | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
US9156725B2 (en) * | 2012-05-30 | 2015-10-13 | Corning Incorporated | Down-drawable chemically strengthened glass for information storage devices |
US9604871B2 (en) * | 2012-11-08 | 2017-03-28 | Corning Incorporated | Durable glass ceramic cover glass for electronic devices |
US11079309B2 (en) | 2013-07-26 | 2021-08-03 | Corning Incorporated | Strengthened glass articles having improved survivability |
JP6131154B2 (ja) * | 2013-09-11 | 2017-05-17 | Hoya株式会社 | 磁気記録媒体基板用ガラスおよび磁気記録媒体基板 |
US10442730B2 (en) * | 2013-11-25 | 2019-10-15 | Corning Incorporated | Method for achieving a stress profile in a glass |
WO2015080043A1 (fr) * | 2013-11-26 | 2015-06-04 | 旭硝子株式会社 | Élément en verre et procédé de production d'élément en verre |
US9517968B2 (en) | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
WO2015195419A2 (fr) | 2014-06-19 | 2015-12-23 | Corning Incorporated | Verre trempé présentant une grande profondeur de compression |
TW202311197A (zh) * | 2014-06-19 | 2023-03-16 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
CN105753314B (zh) * | 2014-10-08 | 2020-11-27 | 康宁股份有限公司 | 包含金属氧化物浓度梯度的玻璃和玻璃陶瓷 |
US10150698B2 (en) * | 2014-10-31 | 2018-12-11 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
DK3215471T3 (da) | 2014-11-04 | 2022-01-17 | Corning Inc | Dybe, ubrydelige belastningsprofiler og fremgangsmåde til fremstilling |
CN107108343B (zh) * | 2014-11-05 | 2020-10-02 | 康宁股份有限公司 | 具有非平面特征和不含碱金属的玻璃元件的玻璃制品 |
WO2016196748A1 (fr) * | 2015-06-04 | 2016-12-08 | Corning Incorporated | Procédés de caractérisation de verres chimiquement renforcés échangeurs d'ions contenant du lithium |
US11066323B2 (en) * | 2015-06-26 | 2021-07-20 | Corning Incorporated | Glass with high surface strength |
US11104602B2 (en) * | 2015-06-26 | 2021-08-31 | Corning Incorporated | Glass with high surface strength |
US9701569B2 (en) * | 2015-07-21 | 2017-07-11 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
TWI722069B (zh) * | 2015-12-08 | 2021-03-21 | 美商康寧公司 | S型應力輪廓及製造方法 |
DE202016008995U1 (de) * | 2015-12-11 | 2021-04-20 | Corning Incorporated | Durch Fusion bildbare glasbasierte Artikel mit einem Metalloxidkonzentrationsgradienten |
CN108463439B (zh) * | 2016-01-08 | 2022-07-22 | 康宁股份有限公司 | 具有固有抗损坏性的可化学强化锂铝硅酸盐玻璃 |
EP3402763A1 (fr) * | 2016-01-13 | 2018-11-21 | Corning Incorporated | Verre ultrafin, non frangible et procédés de fabrication |
CN105948536B (zh) | 2016-06-16 | 2019-02-26 | 深圳市东丽华科技有限公司 | 单一强化层玻璃及其制备方法 |
US10900850B2 (en) | 2017-07-28 | 2021-01-26 | Corning Incorporated | Methods of improving the measurement of knee stress in ion-exchanged chemically strengthened glasses containing lithium |
US10633279B2 (en) | 2017-11-29 | 2020-04-28 | Corning Incorporated | Glasses with low excess modifier content |
US10906834B2 (en) | 2017-11-29 | 2021-02-02 | Corning Incorporated | Ion-exchangeable mixed alkali aluminosilicate glasses |
CN112789253A (zh) * | 2018-09-28 | 2021-05-11 | 康宁股份有限公司 | 具有改进的应力分布的基于玻璃的制品 |
TW202043168A (zh) * | 2019-03-29 | 2020-12-01 | 美商康寧公司 | 抗刮玻璃及製作方法 |
-
2019
- 2019-06-07 WO PCT/US2019/036009 patent/WO2019236975A2/fr unknown
- 2019-06-07 EP EP19733342.0A patent/EP3802451B1/fr active Active
- 2019-06-07 JP JP2020568397A patent/JP7492920B2/ja active Active
- 2019-06-07 EP EP23201195.7A patent/EP4279461A1/fr active Pending
- 2019-06-07 CN CN202110257784.6A patent/CN112851142A/zh active Pending
- 2019-06-07 CN CN201980052645.0A patent/CN112566877A/zh active Pending
- 2019-06-07 US US16/434,750 patent/US11339088B2/en active Active
- 2019-06-07 KR KR1020217000576A patent/KR20210018929A/ko not_active Application Discontinuation
- 2019-06-10 TW TW108119901A patent/TWI801598B/zh active
-
2022
- 2022-05-12 US US17/742,461 patent/US11667566B2/en active Active
-
2023
- 2023-03-06 US US18/117,778 patent/US11912615B2/en active Active
-
2024
- 2024-01-12 US US18/411,608 patent/US20240150233A1/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8561429B2 (en) | 2008-07-11 | 2013-10-22 | Corning Incorporated | Glass with compressive surface for consumer applications |
US8312739B2 (en) | 2008-07-29 | 2012-11-20 | Corning Incorporated | Dual stage ion exchange for chemical strengthening of glass |
US8854623B2 (en) | 2012-10-25 | 2014-10-07 | Corning Incorporated | Systems and methods for measuring a profile characteristic of a glass sample |
JP2018065744A (ja) * | 2016-01-21 | 2018-04-26 | 旭硝子株式会社 | 化学強化ガラスおよび化学強化用ガラス |
US20170295657A1 (en) * | 2016-04-08 | 2017-10-12 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
US20170291849A1 (en) * | 2016-04-08 | 2017-10-12 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
US20170305786A1 (en) * | 2016-04-20 | 2017-10-26 | Corning Incorporated | Glass-based articles including a metal oxide concentration gradient |
Also Published As
Publication number | Publication date |
---|---|
US20220267202A1 (en) | 2022-08-25 |
WO2019236975A3 (fr) | 2020-03-19 |
US11912615B2 (en) | 2024-02-27 |
US11339088B2 (en) | 2022-05-24 |
KR20210018929A (ko) | 2021-02-18 |
JP7492920B2 (ja) | 2024-05-30 |
TW202000623A (zh) | 2020-01-01 |
US11667566B2 (en) | 2023-06-06 |
TWI801598B (zh) | 2023-05-11 |
EP3802451B1 (fr) | 2024-02-14 |
CN112566877A (zh) | 2021-03-26 |
JP2021527023A (ja) | 2021-10-11 |
CN112851142A (zh) | 2021-05-28 |
US20230202915A1 (en) | 2023-06-29 |
WO2019236975A2 (fr) | 2019-12-12 |
US20240150233A1 (en) | 2024-05-09 |
US20190375679A1 (en) | 2019-12-12 |
EP3802451A2 (fr) | 2021-04-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3802451B1 (fr) | Profils de contrainte résistant à la fracture dans des lunettes | |
US11639310B2 (en) | Glass-based articles with improved fracture resistance | |
EP3802449B1 (fr) | Verres présentant des performances améliorées de résistance à la chute | |
US20200223750A1 (en) | S-shaped stress profiles and methods of making | |
EP3717424B1 (fr) | Lunettes à faible teneur en modificateur en excédent | |
US11312657B2 (en) | Glass-based articles with improved stress profiles | |
US11472732B2 (en) | Glass-based articles with improved stress profiles | |
US11472733B2 (en) | Scratch resistant glass and method of making | |
US11787728B2 (en) | Scratch resistant glass and method of making | |
US20210155533A1 (en) | Glass-based articles with fracture resistant stress profiles | |
US20220324746A1 (en) | Fracture resistant glass-based articles | |
US20240166551A1 (en) | Lithium phosphoalumino silicate glasses with fast effective inter-diffusivity | |
US20240132394A1 (en) | Ion exchangeable glasses having high fracture toughness |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AC | Divisional application: reference to earlier application |
Ref document number: 3802451 Country of ref document: EP Kind code of ref document: P |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20240326 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |