EP4065889B1 - Combustion du co dans un gaz d'échappement métallurgique secondaire, avec régulation de la valeur calorifique et régulation du débit volumique - Google Patents
Combustion du co dans un gaz d'échappement métallurgique secondaire, avec régulation de la valeur calorifique et régulation du débit volumique Download PDFInfo
- Publication number
- EP4065889B1 EP4065889B1 EP20812007.1A EP20812007A EP4065889B1 EP 4065889 B1 EP4065889 B1 EP 4065889B1 EP 20812007 A EP20812007 A EP 20812007A EP 4065889 B1 EP4065889 B1 EP 4065889B1
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- EP
- European Patent Office
- Prior art keywords
- gas
- waste gas
- afterburning
- exhaust gas
- volume flow
- Prior art date
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- 238000002485 combustion reaction Methods 0.000 title claims description 11
- 239000007789 gas Substances 0.000 claims description 126
- 238000000034 method Methods 0.000 claims description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 22
- 239000011261 inert gas Substances 0.000 claims description 21
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 16
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 16
- 238000010310 metallurgical process Methods 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000004868 gas analysis Methods 0.000 claims description 7
- 238000009489 vacuum treatment Methods 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 230000003750 conditioning effect Effects 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000002912 waste gas Substances 0.000 claims 33
- 239000000567 combustion gas Substances 0.000 claims 10
- 238000004458 analytical method Methods 0.000 claims 1
- 239000002737 fuel gas Substances 0.000 description 24
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 238000007872 degassing Methods 0.000 description 12
- 239000000155 melt Substances 0.000 description 8
- 239000003345 natural gas Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010923 batch production Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000161 steel melt Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/08—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases using flares, e.g. in stacks
- F23G7/085—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases using flares, e.g. in stacks in stacks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/08—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases using flares, e.g. in stacks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2204/00—Supplementary heating arrangements
- F23G2204/10—Supplementary heating arrangements using auxiliary fuel
- F23G2204/103—Supplementary heating arrangements using auxiliary fuel gaseous or liquid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2207/00—Control
- F23G2207/20—Waste supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2207/00—Control
- F23G2207/40—Supplementary heat supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/14—Gaseous waste or fumes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/14—Gaseous waste or fumes
- F23G2209/141—Explosive gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/55—Controlling; Monitoring or measuring
- F23G2900/55003—Sensing for exhaust gas properties, e.g. O2 content
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/55—Controlling; Monitoring or measuring
- F23G2900/55011—Detecting the properties of waste to be incinerated, e.g. heating value, density
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2900/00—Special features of, or arrangements for fuel supplies
- F23K2900/05004—Mixing two or more fluid fuels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23N—REGULATING OR CONTROLLING COMBUSTION
- F23N2221/00—Pretreatment or prehandling
- F23N2221/10—Analysing fuel properties, e.g. density, calorific
Definitions
- the invention relates to a method for the afterburning of exhaust gases containing carbon monoxide from metallurgical processes with discontinuous exhaust gas volumes, the composition and / or quantity of which changes during a period within which exhaust gas is produced.
- Such metallurgical processes can be, for example, secondary metallurgical processes in which a molten metal is degassed or decarburized.
- Flare gases In petrochemical and metallurgical processes it is generally known to burn exhaust gases with so-called flares. Flare gases often have different qualities. To ensure that the torch burns steadily, the gas must have a minimum combustible content. If this is not the case, natural gas may be added as fuel gas. Calorimeters are usually used to determine the calorific value of the flare gas. These include a measuring cell in which a measuring gas is burned. If the sample gas is successfully ignited, the amount of energy released during combustion or the calorific value of the gas is determined and, if necessary, natural gas is mixed into the flare gas.
- carbon-containing material is fed to a melt pool of metal and slag in a direct melting vessel, with hot gas from furnaces being fed into a gas space is supplied above the melt bath for the purpose of afterburning the reaction gases of the melt bath.
- the resulting exhaust gas is used with fuel gas and oxygen-containing combustion air to heat the ovens, whereby the temperature of the gas space in the ovens is regulated by supplying the exhaust gas with fuel gas and combustion air depending on the oxygen content in the exhaust gas of the ovens, if the exhaust gas has a certain calorific value falls below.
- a method according to the preamble of claim 1 is, for example, from US 5,980,606 A known. Further state of the art is from the documents US 2019/242575 A1 and US 6,042,633 A known.
- the invention is therefore based on the object of providing a method for the afterburning of carbon monoxide-containing exhaust gases from metallurgical processes with discontinuous exhaust gas volumes and exhaust gas compositions, which enables safe afterburning of the exhaust gas with a lower environmental impact.
- One aspect of the invention relates to a method for the afterburning of carbon monoxide-containing exhaust gases from metallurgical processes with discontinuously occurring exhaust gas volumes, the composition of which changes during a period within which exhaust gas is produced, the method comprising conditioning the exhaust gas before the afterburning, such that At least one fuel gas and / or another additional gas is added in a controlled manner to the exhaust gas upstream of the afterburning, the regulation taking place depending on the composition of the exhaust gas and / or depending on the exhaust gas volume flow.
- the afterburning of the exhaust gas preferably takes place with an open flame in the area of the mouth of an exhaust gas duct into the atmosphere.
- the afterburning of the exhaust gas can take place in a combustion chamber provided for this purpose.
- the invention can be summarized in that, according to the invention, both the calorific value of the exhaust gas and the exhaust gas volume flow are regulated, so that on the one hand the most complete combustion possible is ensured and, on the other hand, it is ensured that the exhaust gas volume flow is adjusted in such a way that a flow velocity of the exhaust gas in the relevant Cross section sets that is smaller than a flame propagation speed of the exhaust gas, so that re-ignition of the exhaust gas into an exhaust gas duct is excluded.
- the exhaust gas composition and the exhaust gas volume flow are interrelated, especially if an inert gas is added as additional gas.
- Nitrogen is expediently added to the exhaust gas as additional gas in order to increase the exhaust gas volume flow. This reduces the calorific value of the exhaust gas, which means that the amount of fuel gas supplied, for example in the form of natural gas, may have to be increased.
- a calorific value of the exhaust gas is determined indirectly via the carbon monoxide content of the exhaust gas using at least one device for gas analysis becomes. For this purpose, results from a gas analysis that is required anyway can be used in secondary metallurgical processes.
- control takes place depending on the carbon monoxide content of the exhaust gas, with the control goal of the greatest possible conversion of carbon monoxide to carbon dioxide, so that essentially stoichiometric afterburning is guaranteed.
- control is carried out in such a way that the calorific value of the exhaust gas does not fall below ⁇ 2kWh/Nm 3 ( ⁇ 200 BTU/scf). It has surprisingly been found that with such a calorific value, an afterburning of carbon monoxide of over 97% is possible.
- the control can be carried out in such a way that the exhaust gas volume flow does not fall below a given minimum volume flow.
- the minimum volume flow of the exhaust gas is expediently determined as a function of the flow velocity of the exhaust gas in a given flow cross section so that the flow velocity is smaller than a flame propagation velocity of the exhaust gas during combustion.
- Typical flame propagation speeds are on the order of approximately 0.2 to 0.5 m/s.
- the afterburning is preferably carried out using at least one supporting gas torch arranged in or on a chimney.
- fuel gas and/or additional gas or inert gas is expediently carried out via separate feed lines with volume flow controllable valves, which are controlled, for example, by means of a software controller.
- a software controller can be implemented, for example, using a programmable logic controller.
- the invention further relates to a method for exhaust gas aftertreatment during vacuum treatment of liquid steel in a secondary metallurgy
- Process comprising the afterburning of the exhaust gas from the vacuum treatment of a metal melt by means of at least one torch in or on an exhaust gas duct of a vacuum pump, the method comprising conditioning of the exhaust gas before the afterburning, such that the exhaust gas upstream of the afterburning at least one fuel gas and / or a Additional gas is added in a controlled manner, the regulation taking place depending on the composition of the exhaust gas and depending on the exhaust gas volume flow.
- the vacuum treatment of liquid steel is usually a batch process in which the exhaust gas aftertreatment according to the invention is particularly useful and expedient.
- the exhaust gas aftertreatment according to the invention preferably takes place in secondary metallurgical processes such as VD, VD-OB, RH, RH-TOP, RH-OB, VacAOD VODC or VOD processes.
- the afterburning is carried out periodically only during the decarburization phase of the molten metal. If the CO proportion of the exhaust gas falls below a predetermined minimum value, which is significantly below the value that would justify an increase in the calorific value with fuel gas, afterburning preferably does not take place. This is due to the fact that during the degassing of a melt, which in itself already represents a discontinuous process, exhaust gas containing carbon monoxide is only produced for a certain period of time.
- the invention further relates to an afterburning device for afterburning exhaust gas during a vacuum treatment of liquid steel in a secondary metallurgical process, comprising at least one torch on an exhaust of an exhaust duct of a vacuum pump of a secondary metallurgical system, means for supplying fuel gas to the torch, and means for feeding an inert gas in the exhaust duct of the vacuum pump upstream of the flare, means for determining the exhaust gas volume flow and/or for measuring the exhaust gas velocity within the exhaust duct, means for analyzing the exhaust gas composition, means for metering the fuel gas and the inert gas and means for Control of the dosage of the fuel gas and/or the inert gas depending on the exhaust gas composition.
- Volume flow controllable valves can be provided as means for metering the fuel gas and the inert gas, which are each arranged in feed lines for fuel gas and for natural gas, which are connected to the exhaust gas duct.
- At least one control device is provided as a means for metering fuel gas and/or inert gas, the input variables of which are the exhaust gas composition, the exhaust gas volume flow, the amount of fuel gas supplied and the amount of inert gas supplied.
- control device comprises at least one programmable logic controller.
- control device can control a support burner of the torch in such a way that the torch is only operated when exhaust gas containing CO is produced.
- afterburning device 1 which comprises a torch 2 with a support burner 3, which is connected to the exhaust 4 of an exhaust duct 5 of a vacuum pump, not shown, of a metallurgical plant.
- the metallurgical system can, for example, include a casting ladle and devices for degassing the molten metal contained in the casting ladle.
- the degassing of the metal melt can be carried out, for example, using a partial degassing process, such as the Ruhrstahl-Heraeus process, in which a vacuum vessel is immersed in the melt for degassing, with vacuum pumps designed as steam jet pumps generating a negative pressure in the vacuum vessel for degassing the melt becomes.
- Multi-stage vacuum pumps which are connected to an exhaust gas duct 5, are usually used for this purpose.
- vacuum pump is predominantly used in the singular in the present application.
- this also includes an arrangement of vacuum pumps or a pump with a large number of pump stages.
- the support burner 3 of the torch 2 can be put into and out of operation or ignited and extinguished via a control device 6.
- the exhaust gas duct 5 is connected upstream of the flare 2 to an extinguishing line 7, a feed line 8 for fuel gas and a feed line 9 for nitrogen.
- Nitrogen can be supplied as an extinguishing agent from an extinguishing agent tank 10 to the exhaust gas duct 5 via the extinguishing line 7.
- a flow measuring device 11 for determining the exhaust gas volume flow is arranged in the exhaust gas duct 5 upstream of the mouth of the feed line 8 for fuel gas into the exhaust gas duct 5 and downstream of the mouth of the feed line 9 for nitrogen. Upstream of the mouth of the feed lines 9 in the A gas analysis device 12 is also provided in the exhaust gas duct, with which the exhaust gas composition is preferably continuously determined.
- the supply of fuel gas and nitrogen as inert gas into the exhaust gas duct 5 is controlled according to the invention by means of a control device 21, the control scheme of which is shown below based on the illustration in Figure 2 is explained.
- the control device 21, which is in Figure 3 is shown in simplified form, controls valves 13, 14 provided in the feed lines 8, 9, each of which meter more or less fuel gas or inert gas or nitrogen into the exhaust gas duct 5.
- the control scheme shown includes two interdependent control circuits 15, 16, with a first control circuit 15 as a reference variable that regulates the calorific value of the exhaust gas determined based on the gas composition, and the in Figure 2
- the second control circuit 16 shown below regulates the exhaust gas volume flow as a reference variable.
- the calorific value of the exhaust gas is determined based on the measured values from the gas analysis device 12 via the CO proportion.
- the gas analysis device 12 supplies, among other things, the oxygen content and the carbon monoxide content of the exhaust gas.
- the CO content or carbon monoxide content of the exhaust gas determines its calorific value.
- the calorific value of the exhaust gas continues to depend on the nitrogen content of the exhaust gas.
- the exhaust gas volume flow must not fall below a certain minimum value in order to ensure sufficient gas velocity and thus prevent possible re-ignition in the exhaust gas duct.
- an appropriate amount of inert gas or nitrogen is supplied to the exhaust duct, which in turn has an impact on the calorific value of the exhaust gas.
- the calorific value of the exhaust gas should not fall below a specified minimum value, for example in the order of ⁇ 2kWh/Nm 3 (200 BTU/scf). This value corresponds to a stoichiometrically complete combustion of the CO
- the first control circuit 15 includes a first control device 17 for the fuel gas supply, which acts on the volume flow controllable valve 13 in the feed line 8 for fuel gas.
- the reference variable for the calorific value is determined using a calorific value calculator 18 specified, which uses the actual calorific value, the exhaust gas volume flow, the exhaust gas composition and the actual nitrogen volume flow from the second control circuit 16 as input variables.
- the second control circuit 16 includes a second control device 19 for nitrogen addition, which acts on the valve 14 that can control the volume flow.
- the second control circuit 16 further includes a volume flow computer 20, which uses the actually supplied nitrogen volume flow and the fuel gas volume flow as input variables.
- the volume flow calculator 20 specifies the reference variable for the minimum exhaust gas volume flow and, in parallel, supplies this value to the calorific value calculator 18.
- Figure 4 illustrates the exhaust gas composition and the amount of exhaust gas during a typical degassing process of a secondary metallurgical treatment of a steel melt, with the pressure prevailing during decarburization, the amount of exhaust gas, the amount of inert gas, the amount of natural gas and the CO proportion of the exhaust gas being plotted over time.
- the pressure drop (vacuum/thin solid line) at the beginning of the degassing process and the pressure increase at the end of the degassing process are easily recognizable. This is accompanied by an initially high and then decreasing CO formation.
- the dotted line illustrates the calorific value of the exhaust gas supported by the addition of natural gas (CH 4 ), whereas the bold solid curve illustrates the addition of nitrogen.
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Claims (15)
- Procédé de postcombustion de gaz d'échappement contenant du monoxyde de carbone provenant de processus métallurgiques avec des volumes de gaz d'échappement produits de manière discontinue, dont la composition et/ou la quantité varient pendant une période au cours de laquelle des gaz d'échappement sont produits, le procédé comprenant un conditionnement du gaz d'échappement avant la postcombustion, caractérisé en ce qu'au moins un gaz combustible et un gaz supplémentaire sont ajoutés de manière régulée aux gaz d'échappement en amont de la post-combustion, la régulation s'effectuant en fonction de la composition des gaz d'échappement et en fonction du débit volumique des gaz d'échappement, un gaz inerte, de préférence de l'azote, étant ajouté comme gaz supplémentaire.
- Procédé selon la revendication 1, caractérisé en ce qu'un pouvoir calorifique des gaz d'échappement est déterminé indirectement par la teneur en monoxyde de carbone des gaz d'échappement en utilisant un dispositif d'analyse de gaz (12).
- Procédé selon l'une des revendications 1 ou 2, caractérisé en ce que la régulation s'effectue en fonction de la teneur en monoxyde de carbone des gaz d'échappement, l'objectif de la régulation étant d'atteindre une conversion maximale du monoxyde de carbone en dioxyde de carbone.
- Procédé selon l'une des revendications 1 à 3, caractérisé en ce que la régulation est effectuée de telle manière que le pouvoir calorifique des gaz d'échappement ne descende pas en dessous de ≥ 2kWh/ Nm3 (≥ 200 BTU/scf).
- Procédé selon l'une des revendications 1 à 4, caractérisé en ce que la régulation est effectuée de telle manière que le débit volumique des gaz d'échappement ne soit pas inférieur à un débit volumique minimal donné.
- Procédé selon la revendication 5, caractérisé en ce que le débit volumique minimal des gaz d'échappement est déterminé en fonction de la vitesse d'écoulement des gaz d'échappement dans une section d'écoulement donnée de telle sorte que la vitesse d'écoulement soit supérieure à une vitesse de propagation de flamme des gaz d'échappement lors de la combustion.
- Procédé selon l'une des revendications 1 à 6, caractérisé en ce que la postcombustion est réalisée au moyen d'au moins une torche de gaz de soutien (2) disposée dans ou sur une cheminée.
- Procédé selon la revendication 7, caractérisé en ce que l'addition de gaz combustible et/ou de gaz inerte s'effectue par des conduites d'alimentation (8, 9) avec des vannes (13, 14) à débit réglable.
- Procédé de post-traitement de gaz d'échappement pendant un traitement sous vide d'acier liquide dans un processus métallurgique comprenant la postcombustion du gaz d'échappement provenant du traitement sous vide d'un métal en fusion au moyen d'au moins une torche (2) dans ou sur un canal d'échappement (5) d'une pompe à vide, le procédé comprenant un conditionnement de l'effluent gazeux avant la postcombustion, de telle sorte qu'au moins un gaz combustible et un gaz supplémentaire sont ajoutés de manière régulée à l'effluent gazeux en amont de la postcombustion, la régulation étant effectuée en fonction de la composition de l'effluent gazeux et en fonction du débit volumique de l'effluent gazeux.
- Procédé selon la revendication 9, caractérisé en ce que la postcombustion n'est effectuée périodiquement que pendant une phase de décarburation du métal en fusion.
- Dispositif de postcombustion pour la postcombustion de gaz d'échappement pendant un traitement sous vide d'acier liquide lors d'un processus métallurgique secondaire, comprenant au moins une torche (2) sur un échappement (4) d'un canal de gaz d'échappement (5) d'une pompe à vide d'une installation métallurgique secondaire, des moyens pour l'alimentation de la torche en gaz combustible, des moyens pour l'injection d'un gaz inerte dans le canal de gaz d'échappement de la pompe à vide en amont de la torche (2), des moyens pour déterminer le débit volumique des gaz d'échappement et/ou pour mesurer la vitesse des gaz d'échappement à l'intérieur du canal d'échappement (5), des moyens pour analyser la composition des gaz d'échappement, des moyens pour doser le gaz combustible et le gaz inerte, ainsi que des moyens pour régler le dosage du gaz combustible et/ou du gaz inerte en fonction de la composition des gaz d'échappement.
- Dispositif de postcombustion selon la revendication 11, caractérisé en ce que des vannes (13, 14) à débit réglable sont prévues comme moyens de dosage du gaz combustible et du débit volumique de gaz inerte, qui sont disposées respectivement dans des conduites d'alimentation (8, 9) pour le gaz combustible et pour le gaz inerte, qui sont raccordées au canal d'échappement (5).
- Dispositif de postcombustion selon l'une des revendications 11 ou 12, caractérisée en ce qu'il est prévu comme moyen de dosage du gaz combustible et/ou du gaz inerte au moins un dispositif de régulation (21) dont les grandeurs d'entrée sont la composition des gaz d'échappement, le débit volumique des gaz d'échappement, la quantité de gaz combustible fournie et la quantité de gaz inerte fournie.
- Dispositif de postcombustion selon la revendication 13, caractérisé en ce que le dispositif de régulation comprend au moins un automate programmable.
- Dispositif de postcombustion selon l'une des revendications 13 ou 14, caractérisé en ce que le dispositif de régulation commande un brûleur d'appui (3) de la torche (2).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102019132181 | 2019-11-27 | ||
PCT/EP2020/083023 WO2021105045A1 (fr) | 2019-11-27 | 2020-11-23 | Combustion du co dans un gaz d'échappement métallurgique secondaire, avec régulation de la valeur calorifique et régulation du débit volumique |
Publications (2)
Publication Number | Publication Date |
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EP4065889A1 EP4065889A1 (fr) | 2022-10-05 |
EP4065889B1 true EP4065889B1 (fr) | 2024-02-28 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP20812007.1A Active EP4065889B1 (fr) | 2019-11-27 | 2020-11-23 | Combustion du co dans un gaz d'échappement métallurgique secondaire, avec régulation de la valeur calorifique et régulation du débit volumique |
Country Status (5)
Country | Link |
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US (1) | US20220412554A1 (fr) |
EP (1) | EP4065889B1 (fr) |
DE (1) | DE102020214667A1 (fr) |
ES (1) | ES2984528T3 (fr) |
WO (1) | WO2021105045A1 (fr) |
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Publication number | Priority date | Publication date | Assignee | Title |
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CA2005415C (fr) * | 1989-01-10 | 1994-03-01 | Willie H. Best | Bruleur a gaz a rendement eleve |
DE19518900C1 (de) * | 1995-05-26 | 1996-08-08 | Technometal Ges Fuer Metalltec | Verfahren zur Nachverbrennung von bei der Vakuumbehandlung von Stahl entstehenden Reaktionsgasen |
US5980606A (en) * | 1996-03-22 | 1999-11-09 | Steel Technology Corporation | Method for reducing sulfuric content in the offgas of an iron smelting process |
US10041672B2 (en) * | 2013-12-17 | 2018-08-07 | Schlumberger Technology Corporation | Real-time burner efficiency control and monitoring |
WO2016123666A1 (fr) | 2015-02-03 | 2016-08-11 | Technological Resources Pty. Limited | Traitement de dégagement gazeux à faible valeur calorifique |
JP6965167B2 (ja) * | 2018-01-12 | 2021-11-10 | 三菱パワー株式会社 | ガスタービンコジェネレーションシステム及びその運転切換方法 |
US11047573B2 (en) * | 2018-02-05 | 2021-06-29 | Chevron Phillips Chemical Company Lp | Flare monitoring and control method and apparatus |
-
2020
- 2020-11-23 ES ES20812007T patent/ES2984528T3/es active Active
- 2020-11-23 WO PCT/EP2020/083023 patent/WO2021105045A1/fr unknown
- 2020-11-23 US US17/779,868 patent/US20220412554A1/en active Pending
- 2020-11-23 EP EP20812007.1A patent/EP4065889B1/fr active Active
- 2020-11-23 DE DE102020214667.5A patent/DE102020214667A1/de active Pending
Also Published As
Publication number | Publication date |
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ES2984528T3 (es) | 2024-10-29 |
DE102020214667A1 (de) | 2021-05-27 |
WO2021105045A1 (fr) | 2021-06-03 |
EP4065889A1 (fr) | 2022-10-05 |
US20220412554A1 (en) | 2022-12-29 |
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