EP4056723A1 - Tôle d'acier laminée à chaud et procédé de production correspondant - Google Patents

Tôle d'acier laminée à chaud et procédé de production correspondant Download PDF

Info

Publication number
EP4056723A1
EP4056723A1 EP20884487.8A EP20884487A EP4056723A1 EP 4056723 A1 EP4056723 A1 EP 4056723A1 EP 20884487 A EP20884487 A EP 20884487A EP 4056723 A1 EP4056723 A1 EP 4056723A1
Authority
EP
European Patent Office
Prior art keywords
less
hot
steel sheet
rolled steel
rolling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP20884487.8A
Other languages
German (de)
English (en)
Other versions
EP4056723A4 (fr
Inventor
Shohei Yabu
Kunio Hayashi
Koutarou Hayashi
Kazumasa TSUTSUI
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Publication of EP4056723A1 publication Critical patent/EP4056723A1/fr
Publication of EP4056723A4 publication Critical patent/EP4056723A4/fr
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B3/02Rolling special iron alloys, e.g. stainless steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/001Heat treatment of ferrous alloys containing Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/007Heat treatment of ferrous alloys containing Co
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/021Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/005Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/34Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/52Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium

Definitions

  • the present invention relates to a hot-rolled steel sheet and a method of manufacturing the same. Specifically, the present invention relates to a hot-rolled steel sheet having high strength and excellent ductility, hole expansibility, and toughness, and a method of manufacturing the same.
  • a steel sheet having both high strength and excellent formability is strongly desired.
  • a steel sheet having excellent ductility and hole expansibility particularly among the formability is desired.
  • a steel sheet applied to a vehicle body of a vehicle is also required to have excellent toughness in order to sufficiently absorb impact at the time of a collision.
  • Patent Document 1 discloses a high strength hot-rolled steel sheet which has excellent fatigue properties and stretch flangeability and in which when a bainite fraction is 80% or more, an average grain size r (nm) of a precipitation satisfies an expression of (r ⁇ 207/(27.4 ⁇ (V) + 23.5 ⁇ (Nb) + 31.4 ⁇ (Ti) + 17.6 ⁇ (Mo) + 25.5 ⁇ (Zr) + 23.5 ⁇ (W)), and the average grain size r and a precipitation fraction f satisfies an expression of (r/f ⁇ 12000).
  • Patent Document 2 discloses a hot-rolled steel sheet in which a steel structure at a position at a depth of 1/4 of a sheet thickness from a surface of the steel sheet contains, by area%, 60% or more of bainite, 5% or more and less than 30% of polygonal ferrite, less than 3% of residual austenite, and 10% or less of a remainder excluding the bainite, the residual austenite, and the polygonal ferrite, and a polygonal ferrite area ratio at a position at a depth of 100 ⁇ m from the surface of the steel sheet and a polygonal ferrite area ratio at a position at a depth of 1/4 of the sheet thickness satisfy an expression of (Vas > 1.5 Vaq, where Vas is an area ratio (%) of the polygonal ferrite at a position at a depth of 100 ⁇ m from the surface of the steel sheet, and Vaq is an area ratio of the polygonal ferrite at a position of a depth of 1/4 of the sheet thickness from the surface of the steel sheet).
  • Patent Documents 1 and 2 toughness is not considered.
  • the present inventors have found that it is necessary not only to improve ductility and hole expansibility but also to secure toughness, in order to achieve both weight reduction of a vehicle body and collision properties.
  • the present invention has been made in view of the above problems, and an object of the present invention is to provide a hot-rolled steel sheet having high strength and excellent ductility, hole expansibility, and toughness, and a method of manufacturing the same.
  • an object of the present invention is, preferably, to provide a hot-rolled steel sheet having excellent punching properties in addition to the above-mentioned properties and a method of manufacturing the same.
  • the gist of the present invention made based on the above findings is as follows.
  • the hot-rolled steel sheet according to the present embodiment includes, by mass%, C: 0.030% to 0.200%, Si: 0.05% to 2.50%, Mn: 1.00% to 4.00%, sol. Al: 0.001% to 2.000%, Ti: 0.030% to 0.200, P: 0.020% or less, S: 0.020% or less, N: 0.010% or less, and a remainder: Fe and impurities.
  • C 0.030% to 0.200%
  • Si 0.05% to 2.50%
  • Mn 1.00% to 4.00%
  • sol. Al: 0.001% to 2.000%
  • Ti: 0.030% to 0.200 P: 0.020% or less
  • S 0.020% or less
  • N 0.010% or less
  • a remainder Fe and impurities.
  • C is an element that promotes formation of bainite by improving a strength of a hot-rolled steel sheet and also improving hardenability.
  • a C content is set to 0.030% or more.
  • the C content is preferably 0.040% or more.
  • the C content is set to 0.200% or less.
  • the C content is preferably 0.180% or less.
  • Si is an element that contributes to solid solution strengthening and is an element that contributes to improving the strength of the hot-rolled steel sheet.
  • Si has an action of making steel soundness by deoxidation (suppressing an occurrence of a defect such as blow holes in the steel).
  • the Si content is set to 0.05% or more.
  • the Si content is preferably 0.50% or more and more preferably 1.00% or more.
  • Si is an element that promotes formation of a mixture (MA) of full hard martensite (hereinafter, when simply referred to as martensite, this martensite means fresh martensite) and residual austenite.
  • MA full hard martensite
  • this martensite means fresh martensite
  • residual austenite residual austenite
  • Mn dissolves in steel to contribute to an increase in the strength of the hot-rolled steel sheet, promotes the formation of bainite by improving the hardenability, and improves the hole expansibility of the hot-rolled steel sheet.
  • a Mn content is set to 1.00% or more.
  • the Mn content is preferably 1.30% or more.
  • the Mn content is set to 4.00% or less.
  • the Mn content is preferably 3.50% or less.
  • Al has an action of deoxidizing steel to make the steel soundness.
  • a sol. Al content is less than 0.001%, an effect by the action cannot be obtained. Therefore, the sol. Al content is set to 0.001% or more.
  • the sol. Al content is preferably 0.010% or more.
  • the sol. Al content is set to 2.000% or less.
  • the sol. Al content is preferably 1.500% or less and more preferably 1.300% or less.
  • the sol. Al in the present embodiment means acid-soluble Al, and refers to solid solution Al present in steel in a solid solution state.
  • Ti precipitates as a carbide or a nitride in steel, and has an action of refining the microstructure by an austenite pinning effect and improving the strength of the hot-rolled steel sheet.
  • a Ti content is less than 0,030%, an effect by the action cannot be obtained. Therefore, the Ti content is set to 0.030% or more.
  • the Ti content is preferably 0.050% or more and more preferably 0.080% or more.
  • the Ti content is set to 0.200% or less.
  • the Ti content is preferably 0.170% or less, and more preferably 0.150% or less.
  • P is an element that dissolves in steel and contributes to an increase of the strength of the hot-rolled steel sheet.
  • P is also an element that segregates at a grain boundary, particularly at a prior austenite grain boundary, and promotes a grain boundary fracture due to a boundary segregation, thereby causing a decrease in the workability of the hot-rolled steel sheet.
  • a P content is preferably as low as possible, and containing of P is acceptable up to 0.020%. Therefore, the P content is set to 0.020% or less.
  • the P content is preferably 0.015% or less.
  • the P content is preferably set to 0%. However, when the P content is reduced to less than 0.0001%, the manufacturing costs increase. Therefore, the P content may be 0.0001% or more.
  • S is an element that adversely affects weldability and manufacturability during casting and hot rolling.
  • S combines with Mn to form coarse MnS. This MnS deteriorates the bendability and hole expansibility of the hot-rolled steel sheet, and promotes an initiation of a delayed fracture.
  • a S content is preferably as low as possible, and containing of S is acceptable up to 0.020%. Therefore, the S content is set to 0.020% or less.
  • the S content is preferably 0.015% or less.
  • the S content is preferably set to 0%. However, when the S content is reduced to less than 0.0001%, the manufacturing cost increases and it is economically disadvantageous. Therefore, the S content may be set to 0.0001% or more.
  • N is an element that forms a coarse nitride in steel. This nitride deteriorates the bendability and the hole expansibility of the hot-rolled steel sheet. Therefore, a N content is set to 0.010% or less. The N content is preferably 0.008% or less.
  • the N content When the N content is reduced to less than 0.0001%, a significant increase in manufacturing cost is caused. Therefore, the N content may be set to 0.0001% or more.
  • a remainder of the chemical composition of the hot-rolled steel sheet according to the present embodiment consists of Fe and impurities.
  • the impurities mean those mixed from ore as a raw material, scrap, manufacturing environment, and the like, and/or those allowed within a range that does not adversely affect the hot-rolled steel sheet according to the present embodiment.
  • the hot-rolled steel sheet according to the present embodiment may contain the following elements as an optional element in addition to a part of Fe.
  • a lower limit of a content thereof is 0%.
  • Nb is an element that forms a carbide during hot rolling and contributes to improvement in the strength of hot-rolled steel sheet by precipitation hardening.
  • a Nb content is preferably set to 0.005% or more.
  • the Nb content is set to 0.200% or less.
  • B is an element that segregates into the prior austenite grain boundary, suppresses the formation and growth of ferrite, and contributes to improvement in the strength and hole expansibility of the hot-rolled steel sheet.
  • a B content is preferably set to 0.001% or more.
  • the B content is set to 0.010% or less.
  • V 0% to 1.00%
  • V is an element that forms a carbonitride during hot rolling and contributes to improvement in the strength of hot-rolled steel sheet by precipitation hardening.
  • a V content is preferably set to 0.005% or more.
  • the V content is set to 1.00% or less.
  • Mo is an element that promotes the formation of bainite by improving the hardenability of steel and contributes to the improvement in the strength and the hole expansibility of the hot-rolled steel sheet.
  • a Mo content is preferably set to 0.005% or more.
  • the Mo content is set to 1.00% or less.
  • Cu is an element that has an effect for stably securing the strength of the hot-rolled steel sheet. Therefore, Cu may also be contained. However, even when containing Cu in an amount more than 1.00%, the effect of the action is likely to be saturated and may be economically disadvantageous in some cases. Therefore, the Cu content is set to 1.00% or less.
  • the Cu content is preferably 0.80% or less and more preferably 0.50% or less. In order to more reliably obtain the effect by the action, the Cu content is preferably 0.005% or more.
  • W is an element that is effective in improving the strength of the hot-rolled steel sheet by solid or precipitation.
  • a W content is set to 1.00% or less.
  • the W content is preferably 0.80% or less and more preferably 0.50% or less. In order to more reliably obtain the effect by the action, the W content is preferably 0.005% or more.
  • Cr is an element that is effective in improving the hardenability and improving the strength of the hot-rolled steel sheet.
  • a Cr content is set to 1.00% or less.
  • the Cr content is preferably 0.80% or less and more preferably 0.50% or less. In order to more reliably obtain the effect by the action, the Cr content is preferably 0.005% or more.
  • Ni is an element that is effective in improving the hardenability and improving the strength of the hot-rolled steel sheet.
  • a Ni content is set to 1.00% or less.
  • the Ni content is preferably 0.80% or less and more preferably 0.50% or less. In order to more reliably obtain the effect by the action, the Ni content is preferably 0.005% or more.
  • Co is an element that is effective in improving the strength of the hot-rolled steel sheet by solid solution strengthening.
  • a Co content is set to 1.00% or less.
  • the Co content is preferably 0.80% or less and more preferably 0.50% or less. In order to more reliably obtain the effect by the action, the Co content is preferably 0.005% or more.
  • All of calcium (Ca), magnesium (Mg), a rare earth element (REM), and zirconium (Zr) are elements that contribute to inclusion control, especially fine dispersion of an inclusion, and has an action of enhancing the toughness of the hot-rolled steel sheet. Therefore, these elements may be contained. However, when each of the elements is contained in an amount of more than 0.010%, deterioration of surface properties may become apparent in some cases. Therefore, the amount of each of these elements is set to 0.010% or less. Each amount of these elements is preferably 0.005% or less and more preferably 0.003% or less. In order to obtain the effect by the action more reliably, each amount of the elements is preferably 0.0005% or more.
  • REM in the present embodiment refers to a total of 17 elements including Sc, Y, and lanthanoid, and the REM content refers to a total amount of these elements.
  • lanthanoid is industrially added in the form of misch metal.
  • the chemical composition of the hot-rolled steel sheet may be measured by a general analytical method.
  • the chemical composition may be measured using inductively coupled plasma-atomic emission spectroscopy (ICP-AES) or optical emission spectroscopic (OES).
  • ICP-AES inductively coupled plasma-atomic emission spectroscopy
  • OES optical emission spectroscopic
  • C and S may be measured by using a combustion-infrared absorption method
  • N may be measured by using the inert gas melting-thermal conductivity method.
  • a microstructure contains, by area%, bainite: 80.0% or more, ferrite: 10.0% or less, and a remainder in the microstructure: 10.0% or less, and a total density of a length L 7 of a grain boundary having a crystal orientation difference of 7° and a length L 68 of a grain boundary having a crystal orientation difference of 68° about a ⁇ 110> direction in the bainite is 0.35 to 0.60 ⁇ m/ ⁇ m 2 .
  • an average grain size of prior austenite grains is 10 to 30 ⁇ m, and a ratio ld/Sd between a long axis l d and a short axis S d of the prior austenite grains may be 2.0 or less.
  • the microstructure is defined at a depth of 1/4 of the sheet thickness from a surface and a center position in a sheet width direction in a cross section parallel to a rolling direction. The reason is that the microstructure at this position is a typical microstructure of a steel sheet.
  • Bainite 80.0% or more
  • Bainite means a lath-shaped bainitic ferrite and a structure having a Fe-based carbide between and/or inside the bainitic ferrite. Unlike polygonal ferrite, the bainitic ferrite has a lath shape and has a relatively high dislocation density inside, and therefore can be easily distinguished from other structures using SEM or TEM.
  • the area ratio of the bainite is set to 80.0% or more.
  • the area ratio of the bainite is preferably 85.0% or more and more preferably 90.0% or more. The higher the area ratio of the bainite, the more preferable.
  • a practical upper limit may be 97.5%.
  • the bainitic ferrite is not included in ferrite.
  • the area ratio of the ferrite is set to 10.0% or less.
  • the area ratio of the ferrite is preferably 5.0% or less. From the viewpoint of securing ductility, the area ratio of the ferrite may be 1.0% or more.
  • All of Cementite, pearlite, martensite, tempered martensite, and residual austenite are starting points of voids during distortion, and are structures that deteriorate the hole expansibility of the hot-rolled steel sheet.
  • the area ratio of the remainder in the microstructure is set to 10.0% or less. The area ratio thereof is preferably 5.0% or less.
  • the area ratio of the remainder in the microstructure may be 1.0% or more.
  • the total area ratio of the martensite and the tempered martensite in the remainder in the microstructure is preferably 5.0% or less.
  • the total area fraction thereof is more preferably 3.0% or less.
  • a test piece is taken from the hot-rolled steel sheet so that a microstructure at a depth of 1/4 of the sheet thickness from the surface and a center position in a sheet width direction in the cross section parallel to the rolling direction can be observed.
  • polishing After polishing the cross section of the test piece with silicon carbide paper of #600 to #1500, finishing is performed to a mirror surface using a diamond powder having a grain size of 1 to 6 ⁇ m using a diluted solution such as alcohol or a liquid dispersed in pure water. Next, polishing is performed with colloidal silica without containing an alkaline solution at a room temperature to remove a strain introduced into a surface layer of a sample.
  • a region with a length of 50 ⁇ m and between a depth of 1/8 of the sheet thickness from the surface to a depth of 3/8 of the sheet thickness from the surface is measured by electron backscatter diffraction at a measurement interval of 0.1 ⁇ m, so that a position at the depth of 1/4 of the sheet thickness from the surface is the center in a random position of the sample cross section in a longitudinal direction, to obtain crystal orientation information.
  • an EBSD analyzer configured of a thermal field emission scanning electron microscope (JSM-7001F manufactured by JEOL) and an EBSD detector (DVC5 type detector manufactured by TSL) is used.
  • the EBSD analyzer is set such that the degree of vacuum inside is 9.6 ⁇ 10 -5 Pa or less, an acceleration voltage is 15 kV, an irradiation current level is 13, and an electron beam irradiation level is 62.
  • the obtained crystal orientation information is used to calculate the area ratio of the residual austenite using a "Phase Map" function installed in the software "OIM Analysis (registered trademark)" attached to the EBSD analyzer. Those having a crystal structure of fcc are determined to be residual austenite.
  • those having a crystal structure of bcc are determined to be bainite, ferrite, and the "remainder in the microstructure (cementite, pearlite, martensite, and tempered martensite) other than residual austenite".
  • a region where the "Grain Orientation Spread” is 1° or less is extracted as ferrite, by using a "Grain Orientation Spread” function installed in the software "OIM Analysis (registered trademark)" attached to the EBSD analyzer, under the condition in which 15° grain boundary is defined as the grain boundary.
  • OIM Analysis registered trademark
  • the area ratio of the extracted "remainder in the microstructure (cementite, pearlite, martensite, and tempered martensite) other than residual austenite" is calculated, and the area ratio of the above residual austenite is added to obtain the area ratio of the remainder in the microstructure (cementite, pearlite, martensite, tempered martensite, and residual austenite).
  • cementite, pearlite, martensite, and tempered martensite can be distinguished by the following method. First, in order to observe the same region as the EBSD measurement region by SEM, a Vickers indentation is imprinted in the vicinity of an observation position. Thereafter, a contamination on the surface layer is removed by polishing, leaving the structure of the observed section, and nital etching is performed. Next, the same visual field as the EBSD observed section is observed by SEM at a magnification of 3000 times.
  • a region having a substructure in the grain and where cementite precipitates with a plurality of variants is determined to be tempered martensite.
  • a region where the cementite precipitates in a lamellar shape is determined to be pearlite.
  • Spherical particles with high brightness and grain size (circle equivalent diameter) of 2 ⁇ m or less are determined to be cementite.
  • a region where the brightness is high and the substructure is not exposed by etching is determined as "martensite and residual austenite".
  • a method such as buffing using alumina particles having a particle diameter of 0.1 ⁇ m or less or Ar ion sputtering may be used.
  • the total density of L 7 and L 68 is set to 0.35 ⁇ m/ ⁇ m 2 or more.
  • the total density thereof is preferably 0.40 ⁇ m/ ⁇ m 2 or more.
  • the total density of L 7 and L 68 is set to 0.60 ⁇ m/ ⁇ m 2 or less.
  • the total density thereof is preferably 0.55 ⁇ m/ ⁇ m 2 or less.
  • the grain boundary having a crystal orientation difference of X° about the ⁇ 110> direction refers to a grain boundary having a crystallographic relationship in which the crystal orientations of the crystal grain A and the crystal grain B are the same by rotating one crystal grain B by X° about the ⁇ 110> axis, when two adjacent crystal grain A and crystal grain B are specified at a certain grain boundary.
  • an orientation difference of ⁇ 4° is allowed from the matching orientation relationship.
  • the length L 7 of a grain boundary and the length L 68 as above are measured by using the electron back scatter diffraction pattern-orientation image microscopy (EBSP-OIM) method.
  • EBSP-OIM electron back scatter diffraction pattern-orientation image microscopy
  • a crystal orientation of an irradiation point can be measured for a short time period in such manner that a highly inclined sample in a scanning electron microscope (SEM) is irradiated with electron beams, a Kikuchi pattern formed by back scattering is photographed by a high sensitive camera, and the photographed image is processed by a computer.
  • SEM scanning electron microscope
  • the EBSP-OIM method is performed using a device in which a scanning electron microscope and an EBSP analyzer are combined and an OIM Analysis (registered trademark) manufactured by AMETEK Inc.
  • the analyzable area of the EBSP-OIM method is a region that can be observed by the SEM.
  • the EBSP-OIM method makes it possible to analyze a region with a minimum resolution of 20 nm, which varies depending on the resolution of the SEM.
  • an analysis is performed in at least 5 visual fields of a region of 50 ⁇ m ⁇ 50 ⁇ m at a magnification of 1000 times and an average value of the lengths of the grain boundary having a crystal orientation difference of 7° about the ⁇ 110> direction in the bainite is calculated to obtain L 7 .
  • an average value of the lengths of the grain boundary having a crystal orientation difference of 68° about the ⁇ 110> direction in the bainite is calculated to obtain L 68 .
  • the orientation difference of ⁇ 4° is allowed.
  • the total density of the length L 7 of the grain boundary having the crystal orientation difference of 7° and the length L 68 of the grain boundary having the crystal orientation difference of 68° about the ⁇ 110> direction in the bainite is obtained.
  • a region exceeding I ⁇ /2 may be extracted as the bainite, as in the case of determining the area ratio of the bainite.
  • Average grain size of prior austenite grains 10 to 30 ⁇ m
  • the average grain size of the prior austenite grains is 10 to 30 ⁇ m, and the ratio l d /S d between the long axis l d and the short axis S d of the prior austenite grains may be 2.0 or less.
  • a test piece is taken from the hot-rolled steel sheet so that a microstructure at a depth of 1/4 of the sheet thickness from the surface and a center position in a sheet width direction in the cross section parallel to the rolling direction can be observed.
  • the prior austenite grain boundary is exposed by corroding the observed section with a saturated aqueous solution of picric acid.
  • a magnified photograph of a cross section parallel to the rolling direction that has been corroded, at a depth of 1/4 of the sheet thickness from the surface and at the center position in the sheet width direction is photographed with a scanning electron microscope (SEM) at a magnification of 1000 times and 5 or more visual fields.
  • SEM scanning electron microscope
  • the equivalent circle diameters (diameters) of at least 20 prior austenite grains having an equivalent circle diameter (diameter) of 2 ⁇ m or more, which are included in each SEM photograph, are determined by image processing, and an average value thereof is calculated to obtain the average grain size of the prior austenite grains.
  • the above measurement is performed by excluding these grains.
  • the long axis and the short axis of at least 20 prior austenite grains having an equivalent circle diameter (diameter) of 2 ⁇ m or more, which are included in each of the above SEM photographs, are measured.
  • the long axis l d and the short axis S d of the prior austenite grain are obtained.
  • the ratio l d /S d between the long axis l d and the short axis S d of the prior austenite grains is obtained.
  • the hot-rolled steel sheet according to the present embodiment has a tensile (maximum) strength of 780 MPa or more.
  • tensile strength is less than 780 MPa, an applicable component is limited, and the contribution of weight reduction of the vehicle body is small.
  • the tensile strength is preferably 980 MPa or more.
  • An upper limit is not particularly limited, and may be 1800 MPa from the viewpoint of suppressing wearing of a die.
  • the hot-rolled steel sheet according to the present embodiment may have a total elongation of 14.0% or more.
  • An upper limit of the total elongation is not particularly limited, and may be 30.0% or less or 25.0% or less.
  • the tensile strength and the total elongation are measured according to JIS Z 2241: 2011 using a No. 5 test piece of JIS Z 2241: 2011.
  • a sampling position of the tensile test piece is set to the center position in the sheet width direction, and the direction perpendicular to the rolling direction may be the longitudinal direction.
  • the cross-head speed is set to 3 mm/min.
  • the hot-rolled steel sheet according to the present embodiment may have a hole expansion rate of 50% or more. It is not necessary to particularly limit an upper limit of the hole expansion rate, and the upper limit thereof may be 90% or less or 85% or less.
  • the hole expansion rate is obtained by performing a hole expanding test in accordance with JIS Z 2256: 2010.
  • the hot-rolled steel sheet according to the present embodiment may have an impact value of 60 J/cm 2 or more at -40°C. It is not necessary to particularly limit an upper limit of the impact value at -40°C, and the upper limit thereof may be 180 J/cm 2 or less or 175 J/cm 2 or less.
  • a sub-sized Charpy impact test piece is taken from a predetermined position of the hot-rolled steel sheet, and the impact value at -40°C is determined in accordance with a test method described in JIS Z 2242: 2005.
  • the sheet thickness of the hot-rolled steel sheet according to the present embodiment is not particularly limited and may be 0.6 to 8.0 mm.
  • the sheet thickness of the steel sheet When the sheet thickness of the steel sheet is less than 0.6 mm, it becomes difficult to secure the rolling completion temperature and the rolling force becomes excessive, which may make hot rolling difficult. Therefore, the sheet thickness of the steel sheet according to the present embodiment may be set to 0.6 mm or more.
  • the sheet thickness is preferably 1.2 mm or more or 1.4 mm or more.
  • the sheet thickness when the sheet thickness is more than 8.0 mm, it becomes difficult to refine the microstructure, particularly, the prior austenite grains, and it may become difficult to secure the microstructure described above from the viewpoint of the microstructural fraction. Therefore, the sheet thickness may be set to 8.0 mm or less.
  • the sheet thickness is preferably 6.0 mm or less.
  • the hot-rolled steel sheet according to the present embodiment having the above-described chemical composition and microstructure may be a surface-treated steel sheet provided with a plating layer on the surface for the purpose of improving corrosion resistance and the like.
  • the plating layer may be an electro plating layer or a hot-dip plating layer.
  • the electro plating layer include electrogalvanizing and electro Zn-Ni alloy plating.
  • the hot-dip plating layer include hot-dip galvanizing, hot-dip galvannealing, hot-dip aluminum plating, hot-dip Zn-Al alloy plating, hot-dip Zn-Al-Mg alloy plating, and hot-dip Zn-Al-Mg-Si alloy plating.
  • the plating adhesion amount is not particularly limited and may be the same as before. Further, it is also possible to further enhance the corrosion resistance by applying an appropriate chemical conversion treatment (for example, application and drying of a silicate-based chromium-free chemical conversion treatment liquid) after plating.
  • an appropriate chemical conversion treatment for example, application and drying of a silicate-based chromium-free chemical conversion treatment liquid
  • the preferred method of manufacturing the hot-rolled steel sheet according to the present embodiment includes the following steps.
  • the temperature of the slab and the temperature of the steel sheet in the present embodiment refer to the surface temperature of the slab and the surface temperature of the steel sheet.
  • a total rolling reduction in the rough rolling is set to 70% or more, and the finish rolling may be performed so that all rolling reductions of final three stages of the finish rolling are less than 25%.
  • the slab having the above-mentioned chemical composition is heated to a heating temperature of 1200°C or higher and retained for 1.0 hour. Since a coarse precipitate present at a slab stage causes cracking during rolling and a decrease in material properties, it is preferable to heat a steel material before the hot rolling to dissolve the coarse carbide. Therefore, the heating temperature is set to 1200°C or higher, and the retention time is set to 1.0 hour or longer. The preferred heating temperature is 1230°C or higher, and the preferred retention time is 3.0 hours or longer.
  • the heating temperature may be set to 1400°C or lower, and the retention time may be set to 20.0 hours or shorter.
  • the slab to be heated is preferably produced by continuous casting from the viewpoint of manufacturing cost, but may be produced by another casting method (for example, ingot-making method).
  • the rough rolling completion temperature is 1000°C or higher.
  • the rough rolling completion temperature is preferably 1050°C or higher.
  • the rough rolling completion temperature may be 1300°C or lower.
  • the total rolling reduction in the rough rolling is set to more than 65%.
  • the total rolling reduction in the rough rolling is preferably 68% or more, more preferably 70% or more, and even more preferably 80% or more.
  • An upper limit of the total rolling reduction in the rough rolling is not particularly limited, and may be set to 90% or less.
  • the total rolling reduction in the rough rolling is represented by (1-t r /t s ) ⁇ 100 (%) using the slab thickness: t s and the sheet thickness t r at the end of the rough rolling.
  • the average grain size and an aspect ratio of the prior austenite grains described above can be realized.
  • the finish rolling completion temperature is set to 860°C or higher.
  • the finish rolling completion temperature is preferably set to 900°C or higher.
  • the finish rolling completion temperature is set to 980° C or lower.
  • the finish rolling completion temperature is preferably 950° C or lower.
  • the total rolling reduction in the rough rolling and rolling reduction of final three stages of the finish rolling may be strictly controlled. Specifically, as described above, the total rolling reduction in the rough rolling may be set to 70% or more, and the rolling reduction in the final three stages of the finish rolling may be set to less than 25%.
  • all of the rolling reductions of the final three stages of the finish rolling may be set to less than 25%. All of the rolling reductions are 20% or less.
  • the rolling reduction can be represented by (1-h/h 0 ) ⁇ 100 (%) when the sheet thickness after rolling in one pass is h and the sheet thickness before rolling is ho.
  • cooling is performed to a temperature range of 570°C to 620°C at an average cooling rate of 20 °C/s or higher.
  • the average cooling rate is a value obtained by dividing the temperature difference between the start point and the end point of the set range by the elapsed time from the start point to the end point.
  • the average cooling rate is set to 20 °C/s or higher.
  • the average cooling rate is preferably 30 °C/s or higher, and more preferably 50 °C/s or higher. From the viewpoint of suppressing the increase in cooling equipment, the average cooling rate may be 200 °C/s or lower.
  • Cooling at the average cooling rate of 20 °C/s or higher is performed to a temperature range of 570°C to 620°C.
  • the cooling stop temperature is set to 620°C or lower.
  • the cooling stop temperature may be any temperature as long as it can be retained in a temperature range of 620°C or lower and 500°C to 580°C, and in order to retain in the temperature range of 500°C to 580°C for 2.0 hours or more, the cooling stop temperature is preferably set to 550°C or higher.
  • the cooling stop temperature is preferably set to 570°C or higher.
  • the cooling stop temperature is lower than 500°C and retention is performed in the temperature range of 500°C to 580°C by reheating, a desired amount of bainite cannot be obtained. Therefore, heating after the stop of cooling is not desirable.
  • the retention temperature is set to a temperature range of 500°C to 580°C, and the retention time is set to 2.0 to 12.0 hours.
  • a lower limit of the retention temperature is preferably 530°C.
  • An upper limit of the retention temperature is preferably 560°C.
  • a lower limit of the retention time is preferably 4.0 hours, and more preferably 6.0 hours.
  • An upper limit of the retention time is preferably 10.0 hours, and more preferably 8.0 hours.
  • the steel sheet temperature may be fluctuated or be constant in the temperature range of 500°C to 580°C.
  • the cooling stop temperature of cooling having an average cooling rate of 20 °C/s or higher is lower than 580°C, it is sufficient that the retention time of 2.0 to 12.0 hours can be secured in the temperature range of 500°C to 580°C.
  • cooling is performed to a room temperature.
  • any method may be used, and cooling may be performed by an appropriate method such as mist cooling or rapid cooling using a water cooling tank, in addition to air cooling.
  • the room temperature referred to here is a temperature range of 20°C to 30°C.
  • the microstructural fraction, the total density of L 7 and L 68 , the average grain size of the prior austenite grains, and the ratio ld/Sd between the long axis l d and the short axis S d of the prior austenite grains were determined.
  • the results obtained are shown in Tables 5 to 7.
  • the tensile strength (TS) and total elongation (El) were measured by using a test piece No 5 of JIS Z 2241: 2011, in accordance with JIS Z 2241: 2011.
  • a sampling position of the tensile test piece was set to the center position in the sheet width direction, and the direction perpendicular to the rolling direction was set to the longitudinal direction.
  • the cross-head speed was set to 3 mm/min.
  • TS tensile strength
  • El total elongation
  • the hole expansion rate ( ⁇ ) was evaluated by performing a hole expanding test in accordance with JIS Z 2256: 2010.
  • the toughness was evaluated by performing a Charpy impact test at -40°C and determining the impact value.
  • a sub-sized Charpy impact test piece was taken from a predetermined position of the hot-rolled steel sheet, and the impact value at -40°C was determined in accordance with a test method described in JIS Z 2242: 2005 to evaluate the toughness.
  • the toughness was determined excellent which was pass, and in a case where the impact value (vE -40 ) was less than 60 J/cm 2 , the toughness was determined poor which was fail.
  • the punching properties were evaluated by performing a punching test and observing the properties of the punched end surface.
  • a punched hole was prepared with a hole diameter of 10 mm, a clearance of 12.5%, and a punching speed of 80 mm/s.
  • a cross section of the punched hole perpendicular to the rolling direction was embedded in a resin, and the punched end surface was imaged with a scanning electron microscope.
  • "E (Excellent)" was noted in Tables 5 to 7 as having particularly good punching properties.
  • Invention Examples have high strength and excellent ductility, hole expansibility, and toughness.
  • Invention Examples in which the average grain size of the prior austenite grains is 10 to 30 ⁇ m, and the ratio l d /Sd between the long axis l d and the short axis S d of the prior austenite grains is 2.0 or less have particularly good punching properties.
  • Comparative Example is poor in any one or more of the strength, the ductility, the hole expansibility, and toughness.
  • the present invention it is possible to provide a hot-rolled steel sheet having high strength, and excellent ductility, hole expansibility, and toughness, and a method of manufacturing the same. According to the above preferred aspect according to the present invention, it is possible to provide a hot-rolled steel sheet having excellent punching properties in addition to the above-mentioned properties and a method of manufacturing the same.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)
EP20884487.8A 2019-11-06 2020-10-12 Tôle d'acier laminée à chaud et procédé de production correspondant Pending EP4056723A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019201427 2019-11-06
PCT/JP2020/038468 WO2021090642A1 (fr) 2019-11-06 2020-10-12 Tôle d'acier laminée à chaud et procédé de production correspondant

Publications (2)

Publication Number Publication Date
EP4056723A1 true EP4056723A1 (fr) 2022-09-14
EP4056723A4 EP4056723A4 (fr) 2023-10-18

Family

ID=75849923

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20884487.8A Pending EP4056723A4 (fr) 2019-11-06 2020-10-12 Tôle d'acier laminée à chaud et procédé de production correspondant

Country Status (7)

Country Link
US (1) US20220259692A1 (fr)
EP (1) EP4056723A4 (fr)
JP (1) JP7243854B2 (fr)
KR (1) KR20220068250A (fr)
CN (1) CN114630917B (fr)
MX (1) MX2022004885A (fr)
WO (1) WO2021090642A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7440804B2 (ja) 2020-10-28 2024-02-29 日本製鉄株式会社 熱間圧延鋼板
JP7239071B1 (ja) * 2021-05-17 2023-03-14 Jfeスチール株式会社 高強度熱延鋼板及び高強度熱延鋼板の製造方法
EP4321645A1 (fr) * 2021-05-17 2024-02-14 JFE Steel Corporation Tôle en acier laminée à chaud hautement résistante et procédé de fabrication de tôle en acier laminé à chaud hautement résistante
WO2023095866A1 (fr) * 2021-11-26 2023-06-01 日本製鉄株式会社 Tôle d'acier laminée à chaud
CN115558863B (zh) * 2022-10-19 2023-04-07 鞍钢集团北京研究院有限公司 一种屈服强度≥750MPa的低屈强比海工钢及其生产工艺
KR20240082040A (ko) * 2022-12-01 2024-06-10 현대제철 주식회사 열연 강판, 차량용 부품 및 이를 제조하는 방법

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4955496B2 (ja) 2007-09-28 2012-06-20 株式会社神戸製鋼所 疲労特性及び伸びフランジ性に優れた高強度熱延鋼板
JP5029749B2 (ja) 2010-09-17 2012-09-19 Jfeスチール株式会社 曲げ加工性に優れた高強度熱延鋼板およびその製造方法
WO2013117953A1 (fr) * 2012-02-10 2013-08-15 Ascometal Procédé de fabrication d'une pièce d'acier et pièce d'acier ainsi obtenue
TWI463018B (zh) * 2012-04-06 2014-12-01 Nippon Steel & Sumitomo Metal Corp 具優異裂縫阻滯性之高強度厚鋼板
KR101910444B1 (ko) 2014-02-27 2018-10-22 제이에프이 스틸 가부시키가이샤 고강도 열연 강판 및 그의 제조 방법
JP6390274B2 (ja) 2014-08-29 2018-09-19 新日鐵住金株式会社 熱延鋼板
JP6252692B2 (ja) * 2015-07-27 2017-12-27 Jfeスチール株式会社 高強度熱延鋼板およびその製造方法
JP6911575B2 (ja) * 2016-06-30 2021-07-28 日本製鉄株式会社 脆性き裂伝播停止特性に優れた鋼板およびその製造方法
CN109642279B (zh) * 2016-08-05 2021-03-09 日本制铁株式会社 钢板及镀覆钢板
JP6857220B2 (ja) 2019-08-28 2021-04-14 キヤノン株式会社 通信装置、探索方法、及びプログラム

Also Published As

Publication number Publication date
US20220259692A1 (en) 2022-08-18
WO2021090642A1 (fr) 2021-05-14
KR20220068250A (ko) 2022-05-25
CN114630917B (zh) 2023-10-24
MX2022004885A (es) 2022-05-16
EP4056723A4 (fr) 2023-10-18
JP7243854B2 (ja) 2023-03-22
JPWO2021090642A1 (fr) 2021-05-14
CN114630917A (zh) 2022-06-14

Similar Documents

Publication Publication Date Title
KR102205432B1 (ko) 강판 및 도금 강판
EP4056723A1 (fr) Tôle d'acier laminée à chaud et procédé de production correspondant
EP2762582B1 (fr) Tole d'acier recuite par galvanisation et à haute résistance présentant une aptitude élevée au durcissement par cuisson, tole d'acier recuite par galvanisation, alliée et à haute résistance et procédé de fabrication correspondant
EP3263729B1 (fr) Tôle d'acier laminée à chaud
EP4039842B1 (fr) Tôle d'acier laminée à chaud
WO2011111758A1 (fr) Tôle d'acier à haute résistance laminée à chaud et son procédé de fabrication
JP6241274B2 (ja) 熱延鋼板の製造方法
EP3936628A1 (fr) Tôle d'acier laminée à chaud
US20220081748A1 (en) Hot-rolled steel sheet
EP4206343A1 (fr) Tôle d'acier laminée à chaud
EP4299781A1 (fr) Tôle d'acier et son procédé de fabrication
KR20240042470A (ko) 열간 압연 강판
US11970758B2 (en) Hot-rolled steel sheet
JP7440804B2 (ja) 熱間圧延鋼板
JP7348574B2 (ja) 熱延鋼板
EP4206344A1 (fr) Tôle d'acier laminée à chaud
EP4098761A1 (fr) Tôle d'acier laminée à chaud
EP4098762B1 (fr) Tôle d'acier laminée à chaud
WO2023063014A1 (fr) Tôle d'acier laminée à chaud
WO2022044492A1 (fr) Tôle d'acier laminée à chaud
WO2023063347A1 (fr) Tôle d'acier laminée à chaud
EP4130305A1 (fr) Tôle d'acier et son procédé de production

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20220323

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
A4 Supplementary search report drawn up and despatched

Effective date: 20230915

RIC1 Information provided on ipc code assigned before grant

Ipc: C22C 38/50 20060101ALI20230911BHEP

Ipc: C22C 38/28 20060101ALI20230911BHEP

Ipc: C21D 1/19 20060101ALI20230911BHEP

Ipc: B21B 37/74 20060101ALI20230911BHEP

Ipc: C22C 38/58 20060101ALI20230911BHEP

Ipc: C22C 38/00 20060101ALI20230911BHEP

Ipc: C21D 9/46 20060101ALI20230911BHEP

Ipc: C21D 8/02 20060101AFI20230911BHEP