EP4017957B1 - Feste waschmittelzusammensetzung - Google Patents
Feste waschmittelzusammensetzung Download PDFInfo
- Publication number
- EP4017957B1 EP4017957B1 EP20758223.0A EP20758223A EP4017957B1 EP 4017957 B1 EP4017957 B1 EP 4017957B1 EP 20758223 A EP20758223 A EP 20758223A EP 4017957 B1 EP4017957 B1 EP 4017957B1
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- EP
- European Patent Office
- Prior art keywords
- acid
- solid
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- solid composition
- crystalline
- Prior art date
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- 239000008247 solid mixture Substances 0.000 title claims description 51
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- 239000000203 mixture Substances 0.000 claims description 44
- 150000007524 organic acids Chemical class 0.000 claims description 36
- 229910052797 bismuth Inorganic materials 0.000 claims description 35
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 35
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 34
- 229920000642 polymer Polymers 0.000 claims description 28
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 27
- 229910052725 zinc Inorganic materials 0.000 claims description 27
- 239000011701 zinc Substances 0.000 claims description 27
- 239000004094 surface-active agent Substances 0.000 claims description 24
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 12
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- 150000003839 salts Chemical class 0.000 claims description 12
- 238000002834 transmittance Methods 0.000 claims description 12
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- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 claims description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
- 235000011054 acetic acid Nutrition 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 4
- 235000013922 glutamic acid Nutrition 0.000 claims description 4
- 239000004220 glutamic acid Substances 0.000 claims description 4
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- 235000014655 lactic acid Nutrition 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000001361 adipic acid Substances 0.000 claims description 3
- 235000011037 adipic acid Nutrition 0.000 claims description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
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- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 claims 1
- 125000000291 glutamic acid group Chemical group N[C@@H](CCC(O)=O)C(=O)* 0.000 claims 1
- 239000000047 product Substances 0.000 description 92
- 239000004615 ingredient Substances 0.000 description 25
- 239000007844 bleaching agent Substances 0.000 description 24
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 23
- 239000002736 nonionic surfactant Substances 0.000 description 22
- -1 monosodium salt Chemical class 0.000 description 19
- 239000007864 aqueous solution Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 15
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- 239000000975 dye Substances 0.000 description 12
- 150000001298 alcohols Chemical class 0.000 description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
- 239000002304 perfume Substances 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 102000004190 Enzymes Human genes 0.000 description 9
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- 229910019142 PO4 Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 9
- 239000010452 phosphate Substances 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 9
- 150000004760 silicates Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 230000000007 visual effect Effects 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- 239000003086 colorant Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
- 239000003513 alkali Chemical group 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 230000009477 glass transition Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- KKMOSYLWYLMHAL-UHFFFAOYSA-N 2-bromo-6-nitroaniline Chemical compound NC1=C(Br)C=CC=C1[N+]([O-])=O KKMOSYLWYLMHAL-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 description 5
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- 239000011575 calcium Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 235000005985 organic acids Nutrition 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- 229940001593 sodium carbonate Drugs 0.000 description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 239000012190 activator Substances 0.000 description 4
- 238000000149 argon plasma sintering Methods 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 3
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 235000003704 aspartic acid Nutrition 0.000 description 3
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 3
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- 229910001424 calcium ion Inorganic materials 0.000 description 3
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- 229960001484 edetic acid Drugs 0.000 description 3
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- AURFNYPOUVLIAV-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]-2-hydroxyacetic acid Chemical compound OC(=O)C(O)N(CC(O)=O)CCN(CC(O)=O)CC(O)=O AURFNYPOUVLIAV-UHFFFAOYSA-N 0.000 description 2
- XMWLVXXYIYBETQ-UHFFFAOYSA-N 2-hydroxy-3-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NCC(O)CS(O)(=O)=O XMWLVXXYIYBETQ-UHFFFAOYSA-N 0.000 description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
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- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 2
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- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
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- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
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- 229910052739 hydrogen Inorganic materials 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
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- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
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- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
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- ZWVKLVQFUVAASH-ZPUQHVIOSA-N (e)-2-[[(e)-1,2-dicarboxyethenyl]amino]but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\N\C(C(O)=O)=C\C(O)=O ZWVKLVQFUVAASH-ZPUQHVIOSA-N 0.000 description 1
- ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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- 239000001102 lavandula vera Substances 0.000 description 1
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- 239000011572 manganese Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- 229910052751 metal Inorganic materials 0.000 description 1
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- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
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- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
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- 239000004223 monosodium glutamate Substances 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
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- 102000004169 proteins and genes Human genes 0.000 description 1
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- 239000000344 soap Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
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- MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical group [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
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- 239000008107 starch Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Claims (14)
- Feste Zusammensetzung, umfassend:a) 25 bis 88 Gew.-% Äquivalent freier Säure von nicht-kristallinem chiralem Aminopolycarboxylat; undb) 10 bis 60 Gew.-% Äquivalent freier Säure von nicht-kristalliner organischer Säure, die sich vom Aminopolycarboxylat unterscheidet; undc) 0,0005 bis 4 Gew.-% nicht-kristallines Wismut, nicht-kristallines Zink oder eine Kombination davon; undd) 0,7 bis 25 Gew.-% Wasser;wobei die organische Säure eine durchschnittliche molekulare Masse von höchstens 500 Dalton aufweist, wobei die molekulare Masse auf dem Äquivalent freier Säure basiert.
- Feste Zusammensetzung nach Anspruch 1, wobei die Gesamtmenge an Zink und Wismut 0,001 bis 3,5 Gew.-%, vorzugsweise 0,005 bis 3,0 Gew.-%, bevorzugter 0,01 bis 2,5 Gew.-% und noch bevorzugter 0,05 bis 1,0 Gew.-% beträgt.
- Feste Zusammensetzung nach Anspruch 1 oder Anspruch 2, wobei die Komponente c) aus Wismut besteht.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei die Menge des chiralen Aminopolycarboxylats 30 bis 70 Gew.-% und bevorzugter 35 bis 60 Gew.-%, bezogen auf das Äquivalent freier Säure, beträgt.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei die Menge der organischen Säure 15 bis 55 Gew.-%, vorzugsweise 25 bis 50 Gew.-% beträgt, wobei das Gewicht auf die Äquivalente freier Säure bezogen ist.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei das chirale Aminopolycarboxylat Glutaminsäure-N,N-diessigsäure (GLDA), Methylglycindiessigsäure (MGDA), Ethylendiamindibernsteinsäure (EDDS) oder eine Mischung davon ist und wobei das chirale Aminopolycarboxylat vorzugsweise Glutaminsäure-N,N-diessigsäure (GLDA), Methylglycindiessigsäure (MGDA) oder eine Mischung davon ist.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei die organische Säure umfasst Essigsäure, Zitronensäure, Adipinsäure, Bernsteinsäure, Glutarsäure, Äpfelsäure, Weinsäure, Maleinsäure, Fumarsäure, Zuckersäure, deren Salz, oder eine Mischung davon, wobei die organische Säure vorzugsweise Zitronensäure, Milchsäure, Essigsäure oder Mischungen davon umfasst und wobei die organische Säure bevorzugter Citronensäure umfasst.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei die Wassermenge 1,0 bis 20 Gew.-%, vorzugsweise 1,4 bis 15 Gew.-% und bevorzugter 1,5 bis 8 Gew.-% beträgt.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei a), b), c) und d) 60 bis 100 Gew.-%, vorzugsweise 70 bis 100 Gew.-%, bevorzugter 80 bis 100 Gew.-%, noch bevorzugter 90 bis 100 Gew.-% und sogar noch bevorzugter 95 bis 100 Gew.-% des Gesamtgewichts der festen Zusammensetzung bilden.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei der ph-Wert einer Lösung, hergestellt durch Lösen des Feststoffes in Wasser in einem 1:1-Gewichtsverhältnis, höchstens 10,0, vorzugsweise höchstens 9,0 und bevorzugter höchstens 8,0, gemessen bei 25 Grad Celsius, beträgt.
- Feststoff nach irgendeinem vorhergehenden Anspruch, wobei der Feststoff sulfoniertes Polymer, Polycarboxylatpolymer oder eine Kombination davon in einer Gesamtmenge von 0,3 bis 50 Gew.-%, vorzugsweise von 5 bis 40 Gew.-%, bevorzugter von 10 bis 35 Gew.-% und sogar bevorzugter von 15 bis 25 Gew.-%, bezogen auf das Äquivalent freier Säure des Polymers, umfasst.
- Feste Zusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei die feste Zusammensetzung durchscheinend und vorzugsweise transparent ist, bewertet auf der Basis einer Weglänge von 0,5 cm durch den Feststoff, wobei die durchtretende Lichtmenge gemessen wird, wobei der Feststoff durchscheinend ist, wenn er eine maximale Lichtdurchlässigkeit von mindestens 5% im Wellenlängenbereich von 400 bis 700 nm aufweist, und wobei der Feststoff als transparent angesehen wird, wenn er eine maximale Lichtdurchlässigkeit von mindestens 20% im Wellenlängenbereich von 400 bis 700 nm aufweist.
- Feste Zusammensetzung nach Anspruch 12, wobei die feste Zusammensetzung einen metallischen Glanz und vorzugsweise einen grauen Glanz aufweist.
- Einheitsdosis-Detergenzprodukt, umfassend die feste Zusammensetzung nach irgendeinem vorhergehenden Anspruch in einer Menge von 1 bis 90 Gew.-%, vorzugsweise in einer Menge von 2 bis 85 Gew.-% und bevorzugter von 5 bis 70 Gew.-%, wobei das Einheitsdosis-Detergenzprodukt vorzugsweise ein Maschinengeschirrspülmittelprodukt ist, das 5 bis 60 Gew.-% Tensid enthält.
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| EP19192833 | 2019-08-21 | ||
| EP19192834 | 2019-08-21 | ||
| PCT/EP2020/073326 WO2021032834A1 (en) | 2019-08-21 | 2020-08-20 | Detergent solid composition |
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| EP4017957B1 true EP4017957B1 (de) | 2023-03-29 |
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| EP20756883.3A Active EP4017954B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20757347.8A Active EP4017955B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20758222.2A Active EP4017956B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20756882.5A Active EP4017953B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20756881.7A Active EP4017952B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20758223.0A Active EP4017957B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
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| EP20756883.3A Active EP4017954B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20757347.8A Active EP4017955B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20758222.2A Active EP4017956B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20756882.5A Active EP4017953B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
| EP20756881.7A Active EP4017952B1 (de) | 2019-08-21 | 2020-08-20 | Feste waschmittelzusammensetzung |
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| EP4017953A1 (de) | 2022-06-29 |
| WO2021032818A1 (en) | 2021-02-25 |
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| ES2944450T3 (es) | 2023-06-21 |
| EP4017957A1 (de) | 2022-06-29 |
| WO2021032834A1 (en) | 2021-02-25 |
| CN114286854A (zh) | 2022-04-05 |
| EP4017955B1 (de) | 2023-03-22 |
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| WO2021032817A1 (en) | 2021-02-25 |
| ES2943127T3 (es) | 2023-06-09 |
| EP4017954B1 (de) | 2023-04-05 |
| EP4017954A1 (de) | 2022-06-29 |
| CN114341330A (zh) | 2022-04-12 |
| EP4017956B1 (de) | 2023-03-15 |
| EP4017952B1 (de) | 2023-03-22 |
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| EP4017956A1 (de) | 2022-06-29 |
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| CN114341325A (zh) | 2022-04-12 |
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