EP3925713B1 - Tôle d'acier dressée et revêtue, ainsi que son procédé de fabrication - Google Patents
Tôle d'acier dressée et revêtue, ainsi que son procédé de fabrication Download PDFInfo
- Publication number
- EP3925713B1 EP3925713B1 EP21178807.0A EP21178807A EP3925713B1 EP 3925713 B1 EP3925713 B1 EP 3925713B1 EP 21178807 A EP21178807 A EP 21178807A EP 3925713 B1 EP3925713 B1 EP 3925713B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel sheet
- skin
- coating
- surface structure
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 105
- 239000010959 steel Substances 0.000 title claims description 105
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000576 coating method Methods 0.000 claims description 76
- 239000011248 coating agent Substances 0.000 claims description 73
- 238000000151 deposition Methods 0.000 claims description 24
- 230000008021 deposition Effects 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 16
- 238000003618 dip coating Methods 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 239000012071 phase Substances 0.000 description 16
- 238000007740 vapor deposition Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 230000000875 corresponding effect Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052725 zinc Inorganic materials 0.000 description 7
- 239000011701 zinc Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000013461 design Methods 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/227—Surface roughening or texturing
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/261—After-treatment in a gas atmosphere, e.g. inert or reducing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
- C23C28/025—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B2001/228—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length skin pass rolling or temper rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/38—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
- B21B2001/383—Cladded or coated products
Definitions
- the invention relates to a steel sheet tempered with a deterministic surface structure and coated with a metallic coating, and a method for its manufacture.
- Steel sheets of the generic type tempered with a deterministic surface structure are known from the prior art, see for example the patent specification EP 2 892 663 B1 . Furthermore, tempered steel sheets of the generic type are also in the published disclosure documents DE 10 2019 214 155 A1 , DE 10 2019 214 155 A1 , DE 10 2019 214 136 A1 and DE 10 2019 215 580 A1 described by the applicant. From the disclosure document DE 10 2012 112 109 A1 , which forms the basis for the preamble of claims 1 and 5, respectively, a steel sheet textured with a pattern and coated with a PVD coating is also known.
- gas phase deposition for example in physical gas phase deposition
- a starting material is converted into the gas phase with the help of physical processes (laser, temperature, ion bombardment) and then brought to condense on a surface.
- physical processes laser, temperature, ion bombardment
- many materials and material combinations in the form of a wide variety of layer structures can be applied to a surface in an advantageous manner.
- zinc- and aluminum-based layers and high-melting layers are of particular interest, for example for hot forming.
- a disadvantage of these layers is the directional application, i.e. the material always comes from a fixed angle as long as the material is not rotated.
- Gas-phase deposition is economical for the steel industry when a high throughput can take place as quickly as possible, so that the material (steel sheet) is supplied in the form of strips or sheets and coated, so that the layers are applied in a direction-dependent manner.
- Skin-passing causes bulges, undercuts, steep flanks, fractures and/or roughening on the surface of the steel sheet. Since the skin-passing step is usually a necessary step before coating, in order to preferably set the mechanical parameters in the steel sheet and to ensure a sufficiently large surface for the coating as well as the downstream processes (oiling, etc.), irregular surfaces can be treated with Hard to avoid many peaks and undercuts, which in turn can have a negative impact on vapor deposition coating. It is therefore a major challenge to design dressed surfaces in such a way that optimal and homogeneous coating by gas phase deposition, especially independent of direction, is possible.
- the task is therefore to provide a steel sheet tempered with a deterministic surface structure, which allows an optimal and homogeneous coating by gas phase deposition.
- the provision of a defined surface structure on a skin-tempered steel sheet is essential for coating by vapor deposition and for applying a metallic coating that is as homogeneous as possible to the skin-tempered steel sheet.
- the inventors have found that it is advantageous if the surface structure is embossed into the steel sheet starting from a surface of the steel sheet, the surface structure having a flank area which runs from the surface to a valley area, the flank area being perpendicular to the Steel sheet is formed with an angle, and the steel sheet is coated with a metallic coating that according to the invention the angle is formed between 20 ° and 85 ° and the coating is applied by vapor deposition.
- a defined setting of the angle between the flank area and the perpendicular of the steel sheet can be used to influence a homogeneous deposition in a targeted manner, in particular by deliberate modeling of the flank area.
- the skin-pass roller is designed in such a way that flank areas that are as flat as possible and run out as slowly as possible and in particular no steep or vertical flank areas, in particular in all directions, are pressed onto the surface of the steel sheet. Accordingly, bulging and/or undercuts in the (negative) skin-pass impression are essentially avoided, so that the deposit can be distributed without obstacles on the surface and in the skin-pass impression.
- a deterministic surface structure is to be understood as meaning recurring surface structures which have a defined shape and/or design, cf. EP 2 892 663 B1 .
- this also includes surfaces with a (quasi) stochastic appearance, which, however, are applied using a deterministic texturing process and are therefore composed of deterministic form elements.
- Sheet steel is generally to be understood as meaning a flat steel product which can be provided in the form of sheet metal or in the form of blanks or in the form of strips.
- the metallic coating can be zinc or aluminum based.
- Base in this context means that more than 50% by weight of the coating consists of zinc or aluminum.
- the coating can also only consist of zinc together with unavoidable impurities or also only of aluminum together with unavoidable impurities.
- Other chemical elements such as magnesium, iron, silicon, manganese, nickel, chromium and/or zirconium can each be added individually or in combination in order to improve the properties of the coating.
- a zinc-aluminum combination (along with unavoidable impurities) with or without other chemical elements is also possible conceivable.
- high-melting coatings, especially those based on iron, can also be applied.
- Coating by chemical vapor deposition is conventional and well known to those skilled in the art.
- the surface structure has a flank area which runs from the surface to a valley area and is formed at an angle of between 30° and 85° to the vertical of the steel sheet.
- the angle can particularly preferably be between 35° and 85°.
- the valley and flank area (negative form) of the surface structure essentially corresponds to the surface (positive form) on a skin-pass roller, which forms or embosses the surface structure through a corresponding effect on the steel sheet.
- the flank area surrounding and forming the surface structure, together with the valley area integrally connected to the flank area defines a closed volume of the surface structure stamped into the steel sheet by skin-pass rolling.
- the closed volume the so-called empty volume, can contain a process medium to be applied, for example oil, for later processing using the forming process.
- the geometric design (size and depth) of a deterministic surface structure (negative shape) on a skin-pass steel sheet depends in particular on how the corresponding geometric structure (positive shape) is/is designed on a skin-pass roll.
- Laser texturing methods are preferably used in order to be able to set specific structures (positive shape) on the surface of a temper roll by removing material.
- the targeted control of the energy, the pulse duration and the selection of a suitable wavelength of a laser beam acting on the surface of the temper roll can have a positive influence on the design of the structure(s). With high or higher pulse duration, the interaction time of the laser beam and skin-pass roll surface increases and more material can be removed from the surface of the skin-pass roll.
- a pulse leaves an essentially circular crater on the surface of the skin-pass roller, which, if there are several craters, depicts the surface or area of the elevations on the steel sheet after the skin-pass process and thus the contact surface between the steel sheet and the skin-pass roller that gives the shape.
- a reduction in the pulse duration affects the formation of a crater, in particular the diameter of the crater can be reduced.
- By reducing the pulse duration in particular when using short or ultra-short pulse lasers, it is possible to set the geometric structure (positive shape) on the surface of a skin-pass roll in a targeted manner in order to texture a steel sheet surface in such a way that the flank area of the surface structure an angle of between 20° and 85° can be created for the tempered sheet steel.
- any gradients (angles) of the flank area can be set in a targeted manner.
- the steel sheet can be coated with a further metallic coating, which is arranged below the metallic coating applied by vapor deposition, and can thus be applied directly to the steel sheet.
- the further metallic coating is applied by hot dip coating.
- the further metallic coating is a zinc-based coating.
- the further metallic coating can preferably contain additional elements such as aluminum with a content of up to 5% by weight and/or magnesium with a content of up to 5% by weight in the further metallic coating.
- Sheet steel with a zinc-based coating has very good cathodic protection against corrosion, which has been used in automobile construction for years.
- the coating additionally has magnesium with a content of at least 0.3% by weight, in particular at least 0.6% by weight, preferably at least 0.9% by weight.
- Aluminum can be present as an alternative or in addition to magnesium with a content of at least 0.3 wt coated sheet steel, so that the positive corrosion properties are retained.
- the thickness of the further metallic coating can be between 1 and 15 ⁇ m, in particular between 2 and 12 ⁇ m, preferably between 3 and 10 ⁇ m.
- melt-exchange coating the steel sheets are first coated with a corresponding further metallic coating and then fed to skin-passing. Skin-passing takes place after the steel sheet has been hot-dip coated.
- the steel sheet can be coated with a further metallic coating, which is arranged below the metallic coating applied by gas phase deposition, and can thus be applied directly to the steel sheet.
- the further metallic coating is applied by electrolytic coating.
- the thickness of the further metallic coating can be between 1 and 10 ⁇ m, in particular between 1.5 and 8 ⁇ m, preferably between 2 and 5 ⁇ m.
- the steel sheet can first be skin-passed and then electrolytically coated. Depending on the thickness of the additional metallic coating, the angle in the flank area can essentially be retained even after the electrolytic coating.
- first an electrolytic coating with subsequent skin-passing is conceivable.
- the further metallic coating can be applied subsequently to the metallic coating already applied by gas phase deposition, so that, for example, the metallic coating applied to the steel sheet by gas phase deposition can act as a quasi "adhesion promoter" or "interface” for further metallic coatings in order to in particular to upgrade steel sheet surfaces that are difficult to wet, for example hot-dip coatable, for the application of the further metallic coating. Poorly wettable steel sheets are, for example, high-alloy steel materials that are familiar to those skilled in the art.
- the further metallic coating, which is applied to the metallic coating by vapor deposition is preferably applied by hot dip coating.
- the further metallic coating can also be applied by electrolytic coating.
- the surface (positive shape) of the skin-pass roll forms a surface structure through the action of force on the surface of the steel sheet, which defines a valley and flank area (negative shape) and essentially corresponds to the surface (positive shape) of the skin-pass roll.
- the skin-pass roller to form a deterministic surface structure can be processed using suitable means, for example using a laser, see also EP 2 892 663 B1 .
- removal methods can also be used to adjust a surface on a skin-pass roller, for example machining processes with a geometrically defined or undefined cutting edge, chemical or electrochemical, optical or plasma-induced methods which are suitable for being able to implement a surface structure on a steel sheet to be skin-passed , which has an angle to the perpendicular of the surface of the steel sheet between 20 ° and 85 ° at least in the flank area.
- tempered steel sheets (1) with a deterministic surface structure (2) are shown in schematic partial sectional views.
- the steel sheets (1) which are provided in the form of sheets or preferably strips, are coated with a metallic coating (1.2), the metallic coating (1.2) being applied by vapor deposition in a suitable device.
- the example shown shows a schematic of a physical vapor deposition (4), with appropriate coating material such as zinc, aluminum and the like being converted into the vapor phase (4.1) and in the form of a metallic coating (1.2) on the surface (1.1) of the steel sheet (1) separates, in particular condenses.
- the difference between the statements in Figure 1a) and Figure 2a ) is that the sheet steel (1) in the version in Figure 2a ) with an angle ( ⁇ ) between 20° and 85° between flank area (2.3) and vertical (0) of the steel sheet (1) has been adjusted according to the invention.
- the surface structure (2) is embossed into the steel sheet (1) starting from a surface (1.1) of the steel sheet (1), the surface structure (2) having a flank area (2.3) which, starting from the surface (1.1) to a Valley area (2.2) runs.
- the flank area (2.3) and the valley area (2.2) are replaced by the corresponding area (positive shape) on the not-shown Tempering roller set.
- the flank area (2.3) running around and forming the surface structure (2) defines, together with the valley area (2.2) integrally connected or connected to the flank area (2.3), a closed volume of the surface structure (2) embossed into the steel sheet (1) by skin-pass rolling.
- the angle ( ⁇ ) is deliberately formed between 20° and 85°.
- the angle ( ⁇ ) was set at approx. 50° and it is easy to see that there are no coating defects and that a tempered steel sheet (1) can be coated with a homogeneous metallic coating (1.2) by gas phase deposition, with an essentially flat transition between the valley area (2.2) and the surface (1.1) surrounding the valley areas (2.2) can be set essentially without undercuts and other disturbing obstacles, cf. Figure 2b ).
- direction-independent deposition can be favored by the targeted setting of the deterministic surface structure (2).
- (1.3) symbolically indicates a further metallic coating, which can be optionally applied, for example by hot-dip coating or by electrolytic coating before coating by gas-phase deposition, or alternatively can be optionally applied after coating by gas-phase deposition.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Claims (8)
- Tôle d'acier (1) dressée avec une structure de surface déterministe (2), la structure de surface (2) étant estampée dans la tôle d'acier (1) à partir d'une surface (1.1) de la tôle d'acier (1), la structure de surface (2) comportant une zone de flanc (2.3) qui s'étend de la surface (1.1) à une zone de vallée (2.2), la zone de flanc (2.3) formant un angle (α) par rapport à la perpendiculaire (O) de la tôle d'acier (1), et la tôle d'acier (1) étant revêtue d'un revêtement métallique (1.2), le revêtement (1.2) étant appliqué par dépôt en phase vapeur, caractérisé en ce que l'angle (α) est compris entre 20° et 85°.
- Tôle d'acier selon la revendication 1, l'angle (α) étant compris entre 30° et 85°.
- Tôle d'acier selon la revendication 1, l'angle (α) étant compris entre 35° et 85°.
- Tôle d'acier selon l'une des revendications précédentes, la tôle d'acier (1) étant revêtue d'un autre revêtement métallique (1.3) qui est disposé au-dessous du revêtement métallique (1.2) et la tôle d'acier (1) comprenant au moins deux revêtements métalliques (1.2, 1.3) qui sont appliqués à l'aide de différents procédés de revêtement.
- Procédé de fabrication d'une tôle d'acier (1) dressée avec une structure de surface déterministe (2) et revêtue d'un revêtement métallique (1.2), ledit procédé comprenant les étapes suivantes :- fournir une tôle d'acier (1),- dresser la tôle d'acier (1) avec un rouleau de dressage, la surface du rouleau de dressage, qui agit sur la surface (1.1) de la tôle d'acier (1.1), étant conçue avec une structure de surface déterministe de manière à ce que, après le dressage, la structure de surface (2) soit estampée dans la tôle d'acier (1) depuis une surface (1.1) de la tôle d'acier (1), la structure de surface (2) comportant une zone de flanc (2.3) qui s'étend de la surface (1.1) à une zone de vallée (2.2), la zone de flanc (2.3) formant un angle (α) par rapport à la perpendiculaire (O) à la tôle d'acier (1) et- revêtir ensuite la tôle d'acier dressée (1) d'un revêtement métallique (1.2) par dépôt en phase vapeur,caractérisé en ce que la tôle d'acier (1) est dressée avec un angle (α) compris entre 20° et 85° entre la zone de flanc (2.3) et la perpendiculaire (O) à la tôle d'acier (1).
- Procédé selon la revendication 5, la tôle d'acier (1) étant pourvue d'un autre revêtement métallique (1.3), l'autre revêtement métallique (1.3) étant appliqué par revêtement par immersion à chaud, et la tôle d'acier (1) fournie étant ensuite dressée.
- Procédé selon la revendication 5, la tôle d'acier (1) étant revêtue d'un autre revêtement métallique (1.3) après le dressage, l'autre revêtement métallique (1.3) étant appliqué par revêtement électrolytique, puis le revêtement métallique (1.2) étant revêtu par dépôt en phase vapeur.
- Procédé selon la revendication 5, la tôle d'acier (1) étant revêtue d'un autre revêtement métallique (1.3), l'autre revêtement métallique (1.3) étant appliqué après que le revêtement métallique (1.2) a été appliqué par dépôt en phase gazeuse.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102020207561.1A DE102020207561A1 (de) | 2020-06-18 | 2020-06-18 | Dressiertes und beschichtetes Stahlblech sowie Verfahren zu seiner Herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3925713A1 EP3925713A1 (fr) | 2021-12-22 |
EP3925713B1 true EP3925713B1 (fr) | 2023-02-22 |
Family
ID=76392165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP21178807.0A Active EP3925713B1 (fr) | 2020-06-18 | 2021-06-10 | Tôle d'acier dressée et revêtue, ainsi que son procédé de fabrication |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3925713B1 (fr) |
DE (1) | DE102020207561A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102021129934A1 (de) | 2021-11-17 | 2023-05-17 | Thyssenkrupp Steel Europe Ag | Verfahren zum Herstellen eines schmelztauchbeschichteten Stahlblechs und schmelztauchbeschichtetes Stahlblech |
DE102022113809A1 (de) | 2022-06-01 | 2023-12-07 | Thyssenkrupp Steel Europe Ag | Metallflachprodukt und Bauteil daraus |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019214133A1 (de) * | 2019-09-17 | 2021-03-18 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012017703A1 (de) | 2012-09-07 | 2014-03-13 | Daetwyler Graphics Ag | Flachprodukt aus Metallwerkstoff, insbesondere einem Stahlwerkstoff, Verwendung eines solchen Flachprodukts sowie Walze und Verfahren zur Herstellung solcher Flachprodukte |
DE102012112109B4 (de) | 2012-12-11 | 2016-03-24 | Thyssenkrupp Steel Europe Ag | Oberflächenveredeltes Stahlblech und Verfahren zu dessen Herstellung |
AT516956B1 (de) * | 2015-06-29 | 2016-10-15 | Andritz Ag Maschf | Vorrichtung und verfahren zur herstellung eines verzinkten stahlbandes |
EP3765649A1 (fr) * | 2018-03-16 | 2021-01-20 | Tata Steel Nederland Technology B.V. | Substrat métallique pourvu de textures de surface personnalisées et procédé d'application de telles textures sur des substrats métalliques |
DE102019214136A1 (de) | 2019-09-17 | 2021-03-18 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
DE102019214135A1 (de) | 2019-09-17 | 2021-03-18 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
DE102019215580A1 (de) | 2019-10-10 | 2021-04-15 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
-
2020
- 2020-06-18 DE DE102020207561.1A patent/DE102020207561A1/de active Pending
-
2021
- 2021-06-10 EP EP21178807.0A patent/EP3925713B1/fr active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019214133A1 (de) * | 2019-09-17 | 2021-03-18 | Thyssenkrupp Steel Europe Ag | Stahlblech mit einer deterministischen Oberflächenstruktur |
Also Published As
Publication number | Publication date |
---|---|
EP3925713A1 (fr) | 2021-12-22 |
DE102020207561A1 (de) | 2021-12-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3925713B1 (fr) | Tôle d'acier dressée et revêtue, ainsi que son procédé de fabrication | |
EP4182099B1 (fr) | Tôle d'acier laminée à écrouissage superficiel, rouleau d'écrouissage superficiel et procédé de production de tôle d'acier laminée à écrouissage superficiel | |
EP4038216B1 (fr) | Tôle d'acier pourvue d'une structure superficielle déterministe | |
EP4031301A1 (fr) | Tôle d'acier ayant une structure de surface déterministe | |
EP1041173A1 (fr) | Bloc-cylindres en métal léger, méthode pour sa fabrication et dispositif pour la mise en oeuvre de cette méthode | |
EP4076777B1 (fr) | Feuille de métal présentant une structure de surface déterministe et procédé de production d'un composant de métal en feuille formé et revêtu | |
EP4041467B1 (fr) | Tôle d'acier à structure de surface déterministe et procédé de fabrication d'une telle tôle d'acier | |
DE102012021089B4 (de) | Bauteil mit einer aufgerauten Oberfläche | |
WO2021052809A1 (fr) | Tôle d'acier à structure de surface déterministe | |
WO2021144192A1 (fr) | Procédé de fabrication d'une tôle d'acier traitée en surface et conditionnée en surface | |
WO2021052818A1 (fr) | Tôle d'acier à structure de surface déterministe | |
WO2012052353A1 (fr) | Bande lithographique destinée à la rugosification électrochimique, ainsi que son procédé de fabrication | |
EP2944706B1 (fr) | Procédé de fabrication d'un composant en acier moulé par déformation à chaud à partir d'une tôle d'acier présentant un revêtement métallique | |
EP3056591A1 (fr) | Procede de fabrication d'un produit a partir d'un materiau de bande enroule | |
EP4035788B1 (fr) | Procédé de texturation d'un cylindre de dressage | |
WO2017144407A1 (fr) | Cylindre, en particulier cylindre de travail de dressage et produit plat dressé | |
DE102020107653A1 (de) | Verfahren zum Erzeugen einer Phosphatierschicht und mit einer Phosphatierschicht versehenes Stahlflachprodukt | |
WO2023006449A1 (fr) | Tôle métallique pourvue d'une structure superficielle déterministe | |
DE102019213464B4 (de) | Verfahren zum Herstellen eines Reibbremskörpers für eine Reibbremse eines Kraftfahrzeugs | |
WO2023020875A1 (fr) | Procédé de fabrication d'un cylindre de dressage texturé par laser, procédé de dressage d'une tôle d'acier et tôle d'acier dressée de manière correspondante | |
DE102021130855A1 (de) | Verfahren zum Herstellen eines Prägewerkzeugs für eine Heiß-Kalt-Laminierpresse | |
DE10049579B4 (de) | Verfahren zur Herstellung einer dekorativen Oberfläche | |
DE102021125889A1 (de) | Verfahren zum Dressieren eines Stahlblechs, dressiertes Stahlblech und daraus hergestelltes Bauteil | |
WO2024002507A1 (fr) | Procédé de conditionnement des surfaces de tôles d'acier galvanisé traitées thermiquement | |
DE102022114930A1 (de) | Dressiertes, schmelztauchbeschichtetes Stahlblech |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
B565 | Issuance of search results under rule 164(2) epc |
Effective date: 20211115 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 20220114 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20221005 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: JUNGE, FABIAN Inventor name: CETINKAYA, BURAK WILLIAM |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502021000451 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1549175 Country of ref document: AT Kind code of ref document: T Effective date: 20230315 Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG9D |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230526 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230622 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230522 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230628 Year of fee payment: 3 Ref country code: DE Payment date: 20230620 Year of fee payment: 3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230622 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230523 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20230620 Year of fee payment: 3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502021000451 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
26N | No opposition filed |
Effective date: 20231123 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230610 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230610 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230610 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20230610 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20230222 |