EP3797898B1 - Formflussmittel und verwendung davon - Google Patents

Formflussmittel und verwendung davon Download PDF

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Publication number
EP3797898B1
EP3797898B1 EP19199984.6A EP19199984A EP3797898B1 EP 3797898 B1 EP3797898 B1 EP 3797898B1 EP 19199984 A EP19199984 A EP 19199984A EP 3797898 B1 EP3797898 B1 EP 3797898B1
Authority
EP
European Patent Office
Prior art keywords
mould flux
mould
present
sio
flux
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP19199984.6A
Other languages
English (en)
French (fr)
Other versions
EP3797898A1 (de
Inventor
Bertil WALDÈN
Manas Paliwal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Alleima AB
Original Assignee
Sandvik Materials Technology AB
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Filing date
Publication date
Application filed by Sandvik Materials Technology AB filed Critical Sandvik Materials Technology AB
Priority to EP19199984.6A priority Critical patent/EP3797898B1/de
Publication of EP3797898A1 publication Critical patent/EP3797898A1/de
Application granted granted Critical
Publication of EP3797898B1 publication Critical patent/EP3797898B1/de
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/108Feeding additives, powders, or the like
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0037Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0075Treating in a ladle furnace, e.g. up-/reheating of molten steel within the ladle

Definitions

  • the present disclosure relates to a mould flux and to a method of manufacturing a nickel-base alloy.
  • KR2019009901 relates to a flux to be employed by casting of steels, said flux comprising SiO 2 37.6-39.6 wt%, CaO 27.2-29.2 wt %, MgO 2.6-3.6 wt%, Al 2 O 3 1-3 wt %, Na 2 O 15.1-16.1 wt%, K 2 O 0.16-0.18 wt%, Fe 2 O 3 0.56-0.83 wt%, Li 2 O 2.57-2.85 wt%.
  • the present disclosure therefore provides a mould flux having a composition of, in weight% SiO 2 15-25; CaO 15-35; Al 2 O 3 1-7; Na 2 O 18-30; K 2 O 15-25; Fe 2 O 3 0-5; C 0-4; TiO 2 0-2; MnO 0-2; MgO 0-2; Li 2 O 0-10; and wherein the melting point of the mould flux is less than or equal to 1300°C.
  • Mould fluxes are synthetic slags constituted by a complex mix of oxides, minerals and carbonaceous materials.
  • the main oxides are silica (SiO 2 ), calcium oxide (CaO), sodium oxide (Na 2 O), alumina (Al 2 O 3 ) and magnesium oxide (MgO).
  • the liquid slag formed by the flux constitutes a barrier to avoid steel re-oxidation by contact with air and the entrapment of other gases, such as nitrogen.
  • the fluxes can be added through the top of the mould on the liquid steel, manually or automatically.
  • the mould flux is provided as a powder having the above-mentioned or below-mentioned composition. The flux will then melt in contact with the molten alloy.
  • the present composition limits the CaO content in the mould powder compared to conventional mould fluxes.
  • Perovskite phase formation is assumed to be as follows: SiO 2 +Ti ⁇ TiO 2 +Si.
  • TiO 2 may together with CaO form Perovskite as a solution of Ca 2 Ti 2 O 5 and Ca 2 Ti 2 O 6 .
  • CaO in the flux contributes to the formation of Perovskite.
  • the mould flux according to the present disclosure suppresses the formation of a Perovskite phase compared to mould fluxes of prior art.
  • At least a part of Na 2 O, SiO 2 and Al 2 O 3 present in the mould flux are in the form of Sodium Feldspar (Na 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • at least 25%, or at least 40% of Na 2 O, SiO 2 and Al 2 O 3 present in the mould flux are in the form of Sodium Feldspar (Na 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • at least 50%, or at least 90% of the Na 2 O present in the mould flux is in the form of Sodium Feldspar, (Na 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • At least a part of K 2 O, SiO 2 and Al 2 O 3 present in the mould flux is present in the form of Potassium Feldspar (K 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • at least 25%, or at least 40% of K 2 O, SiO 2 and Al 2 O 3 present in the mould flux is present in the form of Potassium Feldspar (K 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • at least 50%, or at least 90%, of the K 2 O present in the mould flux is present in the form of Potassium Feldspar (K 0.33 Al 0.35 Si 1.13 O 2.95 ).
  • the content of Na 2 O in the mould flux is 18-25 weight%.
  • the content of K 2 O in the mould flux is 15-22 weight%.
  • the content of TiO 2 in the mould flux is >0.05 weight%.
  • the content of Li 2 O in the mould flux is >1.0 weight%.
  • the ratio of CaO and SiO 2 (CaO/SiO 2 )- is in the range of 3:4 to 4:3, such as 1:1. These oxides are important to control the viscosity and the melting point of the mould flux.
  • a CaO content greater than 35 weight% will promote the formation of Perovskite and CaO less than 15 % might induce high viscosity in the molten mould powder.
  • the content of SiO 2 should be controlled on the basis of CaO.
  • Na 2 O, K 2 O and Li 2 O will stabilize Ti in the melt and thereby as mentioned above will contribute to the prevention of Perovskite formation. This is best results are achieved when each of Na 2 O and K 2 O is present in an amount of 18-22 weight%, preferably around 20 weight%, in the mould mixture.
  • these alkali oxides promote the formation of Nepheline phase which is beneficial during casting. A very high content of these oxides will make the flux mould too fluid and a too low content would result in formation of Perovskite phase.
  • the objective of the present disclosure is also achieved by means of a method of moulding a piece of a Ni-base alloy wherein a mould flux as defined hereinabove or hereinafter is applied on a surface of the molten alloy during moulding thereof.
  • the Ni-base alloy comprises, in weight%: C ⁇ 0.05; Cr 17-23; Ni 35-63; Mo 2.5-9.5; Ti 0.3-3.0; Al 0-0.7; Si 0-0.5; Nb 0-4.5; Cu 0-3; Mn 0-0.1; S 0-0.003; P: 0-0.02; balance Fe.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Claims (14)

  1. Formflussmittel, das in Gewichts-% eine Zusammensetzung wie folgt aufweist: SiO2 15 - 25; CaO 15 - 35; Al2O3 1 - 7; Na2O 18 - 30; K2O 15 - 25; Fe2O3 0 - 5; C 0 - 4; TiO2 0 - 2; MnO 0-2; MgO 0-2; Li2O 0 -10;
    und wobei der Schmelzpunkt des Formflussmittels niedriger oder gleich 1300 °C ist.
  2. Formflussmittel nach Anspruch 1, wobei mindestens ein Teil von in dem Formflussmittel vorhandenen Na2O, SiO2 und Al2O3 in der Form von Natriumfeldspat, Na0,33Al0,35Si1,13O3,95, vorhanden ist.
  3. Formflussmittel nach Anspruch 1 oder 2, wobei mindestens ein Teil von in dem Formflussmittel vorhandenen K2O, SiO2 und Al2O3 in der Form von Kaliumfeldspat, K0,33Al0,35Si1,13O2,95, vorhanden ist.
  4. Formflussmittel nach einem der Ansprüche 1 - 3, wobei mindestens 50 % des in dem Formflussmittel vorhandenen Na2O in der Form von Natriumfeldspat, Na0,33Al0,35Si1,13O2,95, ist.
  5. Formflussmittel nach einem der Ansprüche 1 - 4, wobei mindestens 50 % des in dem Formflussmittel vorhandenen K2O in der Form von Kaliumfeldspat, K0,33Al0,35Si1,13O2,95, vorhanden ist.
  6. Formflussmittel nach einem der Ansprüche 1 - 5, wobei der Gehalt an Na2O in Gewichts-% 18 - 25 beträgt.
  7. Formflussmittel nach einem der Ansprüche 1 - 6, wobei der Gehalt an K2O in Gewichts-% 15 - 22 beträgt..
  8. Formflussmittel nach einem der Ansprüche 1 - 7, wobei der Gehalt an TiO2 > 0,05 Gewichts-% beträgt.
  9. Formflussmittel nach einem der Ansprüche 1 - 8, wobei der Gehalt an Li2O > 1,0 Gewichts-% beträgt.
  10. Formflussmittel nach einem der Ansprüche 1 - 9, wobei SiO2/(CaO+Al2O3) > 1.
  11. Formflussmittel nach einem der Ansprüche 1 - 10, wobei das Verhältnis zwischen CaO und SiO2 im Bereich von 3:4 - 4:3 liegt.
  12. Formflussmittel nach einem der Ansprüche 1-11, wobei das Formflussmittel ein Pulver ist, das eine Zusammensetzung nach einem der Ansprüche 1-11 aufweist.
  13. Verfahren zum Herstellen einer Nickelbasislegierung, wobei ein Formflussmittel nach einem der Ansprüche 1 - 12 auf eine Oberfläche der geschmolzenen Nickelbasislegierung während deren Formen angewendet wird.
  14. Verfahren nach Anspruch 13, wobei die Ni - Basislegierung in Gewichts-% Folgendes umfasst: C < 0,05; Cr 17 - 23; Ni 35 - 63; Mo 2,5 - 9,5; Ti 0,3 - 3,0; Al 0 - 0,7; Si 0 - 0,5; Nb 0-4,5; Cu 0 - 3; Mn 0-0,1; S 0 - 0,003; P: 0 - 0,02;
    Rest Fe.
EP19199984.6A 2019-09-26 2019-09-26 Formflussmittel und verwendung davon Active EP3797898B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP19199984.6A EP3797898B1 (de) 2019-09-26 2019-09-26 Formflussmittel und verwendung davon

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19199984.6A EP3797898B1 (de) 2019-09-26 2019-09-26 Formflussmittel und verwendung davon

Publications (2)

Publication Number Publication Date
EP3797898A1 EP3797898A1 (de) 2021-03-31
EP3797898B1 true EP3797898B1 (de) 2022-07-27

Family

ID=68072196

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19199984.6A Active EP3797898B1 (de) 2019-09-26 2019-09-26 Formflussmittel und verwendung davon

Country Status (1)

Country Link
EP (1) EP3797898B1 (de)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1016724A (en) * 1972-09-18 1977-09-06 Smc Corporation Flux for continuous casting of steel
JP2994718B2 (ja) * 1990-09-29 1999-12-27 株式会社神戸製鋼所 連続鋳造用フラックス
EP2035169B1 (de) * 2006-06-22 2017-03-15 Posco Giesspulver und dieses verwendendes stranggiessverfahren
JP5585347B2 (ja) * 2010-09-27 2014-09-10 品川リフラクトリーズ株式会社 鋼の連続鋳造用モールドパウダー
KR102073318B1 (ko) * 2015-11-05 2020-02-03 닛폰세이테츠 가부시키가이샤 연속 주조용 몰드 플럭스 및 연속 주조 방법
KR102033641B1 (ko) * 2018-02-13 2019-10-18 주식회사 포스코 몰드 플럭스 및 주조방법

Also Published As

Publication number Publication date
EP3797898A1 (de) 2021-03-31

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