EP3759417A1 - Projectile à charge active pyrotechnique - Google Patents
Projectile à charge active pyrotechniqueInfo
- Publication number
- EP3759417A1 EP3759417A1 EP19706999.0A EP19706999A EP3759417A1 EP 3759417 A1 EP3759417 A1 EP 3759417A1 EP 19706999 A EP19706999 A EP 19706999A EP 3759417 A1 EP3759417 A1 EP 3759417A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- projectile
- active mass
- pyrotechnic
- pyrotechnic active
- projectile body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002360 explosive Substances 0.000 title abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 8
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 8
- 230000035939 shock Effects 0.000 claims description 7
- 239000012634 fragment Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims 1
- 206010041662 Splinter Diseases 0.000 description 6
- 239000011149 active material Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000013467 fragmentation Methods 0.000 description 4
- 238000006062 fragmentation reaction Methods 0.000 description 4
- 230000001133 acceleration Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000001960 triggered effect Effects 0.000 description 2
- 241001674808 Biastes Species 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/367—Projectiles fragmenting upon impact without the use of explosives, the fragments creating a wounding or lethal effect
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/04—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect of armour-piercing type
- F42B12/06—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect of armour-piercing type with hard or heavy core; Kinetic energy penetrators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/44—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of incendiary type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B12/00—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
- F42B12/02—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
- F42B12/36—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
- F42B12/46—Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information for dispensing gases, vapours, powders or chemically-reactive substances
Definitions
- the invention is concerned with a pyrotechnic active charge or effective mass in a projectile, in particular in the middle caliber range.
- EP 1 316 774 B1 EP 1 000 311 B1 describe the so-called PELE effect, which is used in so-called PELE-T or PELE-pen projectiles. Furthermore, HE ammunitions are known which achieve splinter acceleration via a detonative conversion of secondary explosives.
- the lateral acceleration due to the PELE effect is essentially determined by the target speed.
- the splinter cone becomes smaller. In practice, this represents a weakening of the effectiveness of the projectile in the target.
- HE High Explosive
- blasting grenades The splinter acceleration when using HE (High Explosive) bullets or ammunition, such as blasting grenades, is known to be very good.
- explosives are used which increase the safety risk of such a bullet throughout its life cycle.
- separate detonator components are needed.
- Multi-Purpose (MP) ammunition has the same problem as HE ammunition, though it does not use classic detonating chains. However, the problem of undefined states, such as duds or implementations in the weapon in feeding problems.
- HE and MP projectiles generally contain secondary explosives that are initiated by a pyrotechnic set (MP) or a separate igniter (HE).
- EP 0 531 697 B1 discloses a multi-purpose projectile which has a jacket, a penetrator and at least one fire charge.
- the fire charge is in this case pressed over its entire cross section.
- the invention has the object to show a bullet, which overcomes the aforementioned disadvantages.
- the invention is based on the idea to show a projectile, which, without explosives and detonators, realizes a significant increase in the lateral fragmentation effect in relation to a PELE projectile.
- the aim is to combine a pyrotechnic active charge in combination with the proven PELE effect in an especially medium-caliber projectile
- Explosion-free projectiles are known from DE 10 2012 023 700 A1 and DE 10 2013 002 119 A1
- the explosive-free projectile according to DE 10 2012 023 700 A1 releases a fuel or a fuel mixture as an inflammable air-fuel mixture during the disassembly into the target. This mixture is spontaneously reacted by at least one explosive-free, spark-generating ignition mechanism triggered during the breakdown decomposition.
- These explosive-free projectiles serve to create an optical and thermal target signature.
- a non-detonation-capable pyrotechnic composition is incorporated as active compound.
- a metal powder / oxidizing agent is preferably provided.
- the shock wave splinters and simultaneously initiates the active mass, so that the expanding gases of pyrotechnics, the surrounding shell fragments of the projectile body laterally and from the Firing distance and thus accelerate independently of the impact speed.
- the redox reaction is utilized, in which a sudden exothermic redox reaction occurs due to the chemical reaction of the pyrotechnic composition, in which gas is released, greatly expands due to temperature and thus causes the explosive force
- the pyrotechnic active mass can also create a lightning and bang effect on the target or acoustically improve the perception. In addition to the marking of the impact point of the opponent can be held down.
- the thus created Mer mixturegeunter fulfills the task of a tank performance, i.
- the projectile can penetrate an armor, form splinters and also pyrotechnic effects, such as fire, biast, lightning and / or bang effects in the target form.
- the pyrotechnic active mass is introduced into a projectile body of the projectile. It can be fixed in position by a disk, an epoxy resin or the like. Alternatively, the pyrotechnic active mass may be introduced into a projectile tip of the projectile.
- a second embodiment results when a core is introduced into the projectile. This can then fix the position pyrotechnic active mass.
- the material of the core may have a lower density than the projectile body, but this is not a condition.
- the pyrotechnic active mass may be located between a projectile body and a penetrator.
- the active material can be enclosed and sealed by a core, which preferably also consists of a metal or a plastic.
- the pyrotechnic active mass is attached annularly around the penetrator. The bullet body enveloping the pyrotechnic active mass forms the desired splinters after initiation of the active mass
- a projectile with a new active mass or active charge in a projectile body preferably in the middle caliber range.
- a shock wave is generated, which leads to splitting or fragmentation of at least the projectile body.
- the initiation of the pyrotechnic active mass is effected by the initiated shock wave, so that the pyrotechnic active material is reacted and the expanding gases of the pyrotechnic active mass additionally accelerate the surrounding shell fragments of the projectile body.
- the active material is not reacted detonatively, so they belong to a different class of substance than conventional explosives. Disposal of the ammunition is therefore less expensive.
- the handling safety of such ammunition increases.
- the lateral effect is increased compared to pure PELE bullets.
- a secondary rate is waived.
- the lateral effect of the PELE ammunition is increased and leads to a less severe decrease in long shooting distances.
- FIG. 1 shows a first variant of a projectile according to the invention
- Fig. 2 shows another variant of the projectile
- Fig. 3 shows a third variant of the projectile.
- a projectile 1 comprises a projectile body 2, which on the front side has a projectile nose 3, also called an ogive or hood, and has a projectile tail 4 on the rear side.
- a projectile body 2 In the projectile body 2 is introduced a pyrotechnic active mass 5. This can be fixed in position by a disc, an epoxy resin 16 or the like. Alternatively, the pyrotechnic active mass 5 can be integrated into the projectile nose 3.
- FIG. 2 An alternative is shown in FIG. 2.
- the pyrotechnic active mass 5 is incorporated between a core 6 and a projectile body 7 of a projectile 8.
- the core 6 is preferably made of a metal or a plastic.
- FIG. 3 shows a projectile 9 with a projectile body 10 and a penetrator 1 1.
- the projectile body 10 also has a projectile nose 3 on the front side and a projectile cusp 4 on the rear side.
- the penetrator 11 may in turn be fragile.
- the pyrotechnic active mass 5 is incorporated between the projectile body 10 and the penetrator 11. In the preferred embodiment, the pyrotechnic active mass 5 is preferably attached in a ring around the penetrator 11.
- the active mass 5 completely, but at least partially cover the penetrator 11.
- the active mass 5 is enclosed by a core 14 and thereby sealed.
- the core 14 sits at least partially on the penetrator 11.
- the core 14 has a bore 15 into which the penetrator 11 can protrude.
- This bore 15 is preferably matched to the outer geometry of the penetrator 11.
- the core 14 itself preferably consists of a metal or a plastic.
- the penetrator 11 can be fixed in position in the projectile 9 or in the projectile body 10. Alternatives of storage for fixing the penetrator 11 are also possible.
- Projectile body 2, 7, 10 and projectile nose 4 can be connected to each other via a screw.
- the well-known PEIE effect is triggered.
- a shock wave is introduced into the projectile body 2, 7, 10 and, if present, also into the core 6 (FIG. 2) or into the core 14 and the penetrator 14 (FIG. 3).
- the shock wave acts on the one hand on the jacket of the projectile body 2, 7, 10 fragment-forming (not shown in detail). Furthermore, the pyrotechnic composition 5 or the pyrotechnic active material 5 is simultaneously initiated by adiabatic compression by means of this shock wave. As a result, the reaction temperature or reaction threshold of the redox system, that is, the effective mass 5 (pyrotechnics), is exceeded. The active mass 5 reacts immediately. The now expanding gases of the pyrotechnic active mass 5 in turn accelerate the active mass 5 surrounded and formed by the Stoßwetie at impact coat fragments of the projectile body 2, 7, 10 in addition, laterally.
- the active mass 5 may also be a plurality of pyrotechnic sows which produce a fire effect at the target, a lightning and I or bang effect. It is advantageous that the forming splitter cone (opening angle of the cone) of the shell fragments of the projectile body 2, 7, 10 is constant, since this is independent of the firing distance (the impact velocity).
- the projectile body 2, 7, 10 may be circumferentially additionally provided with predetermined breaking points (not shown in detail). These can then support the fragmentation of the projectile 1, 8, 9. Also can be better defined by the predetermined breaking points, the shell fragments of the projectile body 2, 7, 10 in size.
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102018104333.3A DE102018104333A1 (de) | 2018-02-26 | 2018-02-26 | Geschoss mit pyrotechnischer Wirkladung |
PCT/EP2019/054464 WO2019162451A1 (fr) | 2018-02-26 | 2019-02-22 | Projectile à charge active pyrotechnique |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3759417A1 true EP3759417A1 (fr) | 2021-01-06 |
EP3759417B1 EP3759417B1 (fr) | 2023-12-06 |
Family
ID=65520307
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19706999.0A Active EP3759417B1 (fr) | 2018-02-26 | 2019-02-22 | Projectile à charge active pyrotechnique |
Country Status (16)
Country | Link |
---|---|
US (1) | US11307006B2 (fr) |
EP (1) | EP3759417B1 (fr) |
JP (1) | JP7021362B2 (fr) |
KR (1) | KR102448409B1 (fr) |
CN (1) | CN111919081B (fr) |
AU (1) | AU2019224532B2 (fr) |
BR (1) | BR112020017204A2 (fr) |
CA (1) | CA3091710C (fr) |
DE (1) | DE102018104333A1 (fr) |
FI (1) | FI3759417T3 (fr) |
PL (1) | PL3759417T3 (fr) |
RU (1) | RU2751328C1 (fr) |
SG (1) | SG11202008114QA (fr) |
UA (1) | UA126700C2 (fr) |
WO (1) | WO2019162451A1 (fr) |
ZA (1) | ZA202005180B (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2775320C1 (ru) * | 2022-01-25 | 2022-06-29 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") | Проникающий в преграду зонд |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20220039636A (ko) | 2020-09-21 | 2022-03-29 | 주식회사 엘지에너지솔루션 | 음극 및 이를 포함하는 리튬 이차전지 |
DE102022003489A1 (de) | 2022-09-22 | 2024-03-28 | Diehl Defence Gmbh & Co. Kg | PELE-Geschoss mit Reaktivmaterial |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
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US2115047A (en) * | 1936-11-30 | 1938-04-26 | Stevenson Thomas | Tracer ammunition and to an igniter mixture for tracer compositions |
US3302570A (en) * | 1965-07-23 | 1967-02-07 | Walter G Finch | Armor piercing, fragmenting and incendiary projectile |
DE1278290B (de) * | 1966-01-25 | 1968-09-19 | Diehl Fa | Brandgeschoss |
DE2752946B2 (de) * | 1977-11-26 | 1979-11-15 | Diehl Gmbh & Co, 8500 Nuernberg | Verwendung einer Brandmasse für Brandgeschosse |
DE3240310A1 (de) * | 1981-11-02 | 1983-06-01 | Joseph 32548 Fort Walton Beach Fla. Jenus jun. | Panzerbrechendes brandgeschoss |
SE8206279L (sv) * | 1981-11-17 | 1983-05-18 | Rheinmetall Gmbh | Sammansatt material |
US4438700A (en) * | 1982-07-19 | 1984-03-27 | The United States Of America As Represented By The Secretary Of The Army | White smoke spotting composition for training ammunition |
DE3761109D1 (de) * | 1986-03-21 | 1990-01-11 | Oerlikon Buehrle Ag | Ein durch kinetische energie wirkendes treibspiegelgeschoss. |
US5728968A (en) * | 1989-08-24 | 1998-03-17 | Primex Technologies, Inc. | Armor penetrating projectile |
FR2673461B1 (fr) * | 1991-02-28 | 1993-05-07 | Giat Ind Sa | Projectile perforant et fragmentable. |
NO172865C (no) | 1991-08-01 | 1993-09-15 | Raufoss As | Flereffekt-prosjektil og fremgangsmaate ved dets fremstilling |
RU2082943C1 (ru) * | 1994-01-25 | 1997-06-27 | Владимир Алексеевич Одинцов | Осколочно-фугасный снаряд |
FR2722876B1 (fr) * | 1994-07-22 | 1996-09-13 | Manurhin Defense | Projectile explosif |
DE19700349C2 (de) | 1997-01-08 | 2002-02-07 | Futurtec Ag | Geschoß oder Gefechtskopf zur Bekämpfung gepanzerter Ziele |
US7603951B2 (en) * | 2004-03-15 | 2009-10-20 | Alliant Techsystems Inc. | Reactive material enhanced projectiles and related methods |
US20050199323A1 (en) * | 2004-03-15 | 2005-09-15 | Nielson Daniel B. | Reactive material enhanced munition compositions and projectiles containing same |
US6354222B1 (en) * | 2000-04-05 | 2002-03-12 | Raytheon Company | Projectile for the destruction of large explosive targets |
EP1167914A1 (fr) | 2000-06-19 | 2002-01-02 | SM Schweizerische Munitionsunternehmung AG | Projectile autopropulsé avec noyau perforant |
DK1316774T3 (da) | 2001-11-28 | 2006-10-09 | Rheinmetall Waffe Munition | Projektiler med höj penetrations- og lateralvirkning med integreret sönderdelingsindretning |
FR2867469A1 (fr) * | 2004-03-15 | 2005-09-16 | Alliant Techsystems Inc | Compositions reactives contenant un metal, et leur procede de production |
RU2407980C2 (ru) * | 2005-06-21 | 2010-12-27 | Геке Технологи Гмбх | Разрывной снаряд |
DE102005039901B4 (de) | 2005-08-24 | 2015-02-19 | Rwm Schweiz Ag | Geschoss, insbesondere für Mittelkalibermunition |
EP1780494A3 (fr) * | 2005-10-04 | 2008-02-27 | Alliant Techsystems Inc. | Projectiles améliorés par l'emploi de matériaux réactifs et procédés |
DE102006025330A1 (de) * | 2006-05-31 | 2007-12-06 | WEIHRAUCH, Günter | Geschoss, Wirkkörper oder Gefechtskopf zur Bekämpfung massiver, strukturierter und flächenhafter Ziele |
IL189612A (en) * | 2008-02-19 | 2012-10-31 | Rafael Advanced Defense Sys | Flammable arrowhead |
US8485099B2 (en) * | 2008-07-10 | 2013-07-16 | Nammo Talley, Inc. | Mine defeat system and pyrotechnic dart for same |
JP2011047527A (ja) | 2009-08-25 | 2011-03-10 | Ihi Aerospace Co Ltd | 発煙弾 |
DE102009041366A1 (de) * | 2009-09-11 | 2011-05-26 | Diehl Bgt Defence Gmbh & Co. Kg | Flugkörper mit einem pyrotechnischen Satz |
RU96943U1 (ru) * | 2010-05-13 | 2010-08-20 | Федеральное государственное унитарное предприятие "Федеральный научно-производственный центр "Прибор" | Артиллерийский малокалиберный патрон |
FR2998659B1 (fr) * | 2012-11-23 | 2017-06-23 | Nexter Munitions | Projectile gyrostabilise projetant une charge utile |
DE102012023700A1 (de) | 2012-12-05 | 2014-06-05 | Rheinmetall Waffe Munition Gmbh | Munition mit explosivstofffreiem Geschoss zur Erzeugung einer multispektralen Zielsignatur |
DE102013002119A1 (de) | 2013-02-08 | 2014-08-28 | Rheinmetall Waffe Munition Gmbh | Explosivstofffreies Geschoss zur Erzeugung einer thermischen Signatur |
-
2018
- 2018-02-26 DE DE102018104333.3A patent/DE102018104333A1/de active Pending
-
2019
- 2019-02-22 US US16/975,470 patent/US11307006B2/en active Active
- 2019-02-22 FI FIEP19706999.0T patent/FI3759417T3/fi active
- 2019-02-22 KR KR1020207026315A patent/KR102448409B1/ko active IP Right Grant
- 2019-02-22 CN CN201980014938.XA patent/CN111919081B/zh active Active
- 2019-02-22 CA CA3091710A patent/CA3091710C/fr active Active
- 2019-02-22 BR BR112020017204-9A patent/BR112020017204A2/pt not_active Application Discontinuation
- 2019-02-22 PL PL19706999.0T patent/PL3759417T3/pl unknown
- 2019-02-22 WO PCT/EP2019/054464 patent/WO2019162451A1/fr active Application Filing
- 2019-02-22 SG SG11202008114QA patent/SG11202008114QA/en unknown
- 2019-02-22 EP EP19706999.0A patent/EP3759417B1/fr active Active
- 2019-02-22 RU RU2020128084A patent/RU2751328C1/ru active
- 2019-02-22 UA UAA202006155A patent/UA126700C2/uk unknown
- 2019-02-22 AU AU2019224532A patent/AU2019224532B2/en active Active
- 2019-02-22 JP JP2020544827A patent/JP7021362B2/ja active Active
-
2020
- 2020-08-20 ZA ZA2020/05180A patent/ZA202005180B/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2775320C1 (ru) * | 2022-01-25 | 2022-06-29 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") | Проникающий в преграду зонд |
Also Published As
Publication number | Publication date |
---|---|
FI3759417T3 (fi) | 2024-01-19 |
JP7021362B2 (ja) | 2022-02-16 |
PL3759417T3 (pl) | 2024-04-29 |
SG11202008114QA (en) | 2020-09-29 |
AU2019224532A1 (en) | 2020-09-10 |
CA3091710A1 (fr) | 2019-08-29 |
KR20200121830A (ko) | 2020-10-26 |
WO2019162451A1 (fr) | 2019-08-29 |
US11307006B2 (en) | 2022-04-19 |
CA3091710C (fr) | 2023-01-24 |
AU2019224532B2 (en) | 2022-05-19 |
BR112020017204A2 (pt) | 2020-12-22 |
JP2021515174A (ja) | 2021-06-17 |
EP3759417B1 (fr) | 2023-12-06 |
CN111919081B (zh) | 2023-01-24 |
KR102448409B1 (ko) | 2022-09-27 |
CN111919081A (zh) | 2020-11-10 |
DE102018104333A1 (de) | 2019-08-29 |
ZA202005180B (en) | 2021-09-29 |
UA126700C2 (uk) | 2023-01-11 |
US20210018305A1 (en) | 2021-01-21 |
RU2751328C1 (ru) | 2021-07-13 |
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