EP3752650B1 - Verfahren zum raffinieren von geschmolzenem metall unter verwendung eines konverters - Google Patents

Verfahren zum raffinieren von geschmolzenem metall unter verwendung eines konverters Download PDF

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Publication number
EP3752650B1
EP3752650B1 EP19704797.0A EP19704797A EP3752650B1 EP 3752650 B1 EP3752650 B1 EP 3752650B1 EP 19704797 A EP19704797 A EP 19704797A EP 3752650 B1 EP3752650 B1 EP 3752650B1
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EP
European Patent Office
Prior art keywords
converter
powdered material
side wall
slag
nozzle
Prior art date
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Application number
EP19704797.0A
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English (en)
French (fr)
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EP3752650A1 (de
Inventor
Sabrine KHADHRAOUI
Satyajit Das
Hans-Jürgen ODENTHAL
Fabian Krause
Andreas Kemminger
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SMS Group GmbH
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SMS Group GmbH
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28—Manufacture of steel in the converter
    • C21C5/30—Regulating or controlling the blowing
    • C21C5/32—Blowing from above
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52—Manufacture of steel in electric furnaces
    • C21C5/54—Processes yielding slags of special composition
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0087—Treatment of slags covering the steel bath, e.g. for separating slag from the molten metal
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04—Removing impurities by adding a treating agent
    • C21C7/064—Dephosphorising; Desulfurising
    • C21C7/0645—Agents used for dephosphorising or desulfurising
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/0025—Charging or loading melting furnaces with material in the solid state
    • F27D3/0026—Introducing additives into the melt
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/0033—Charging; Discharging; Manipulation of charge charging of particulate material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/18—Charging particulate material using a fluid carrier
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00—Charging; Discharging; Manipulation of charge
    • F27D3/18—Charging particulate material using a fluid carrier
    • F27D2003/185—Conveying particles in a conduct using a fluid

Definitions

  • the present invention relates to a method for refining molten metal using a converter, e.g. a converter steelmaking method for producing steel from molten iron.
  • a converter e.g. a converter steelmaking method for producing steel from molten iron.
  • the Linz-Donauwitz-process (also known as basic Oxygen steelmaking or Oxygen converter process) is a steel making process in which Oxygen is blown onto the surface of carbon-rich molten pig iron (iron bath) in a converter.
  • molten pig iron is introduced into a steelmaking converter, e.g. from a blast furnace, to form a bath of molten metal.
  • Suitable converters are known in the art, their design being e.g. based on a Bessemer converter.
  • the converter may be formed as a metallurgical vessel as for example disclosed in the patent specification of GB 1 276 029 .
  • a converter can be a metallurgical vessel, which can be held using e.g.
  • an encircling support ring having two trunnions defining a horizontal pivoting axis about which the converter can be rotated from a vertical orientation in which the steelmaking process is carried out into a tilted orientation for pouring or discharging the steel out of the converter.
  • Oxygen For refining the molten iron, Oxygen, usually high purity Oxygen, is blown at high pressure and at supersonic speed onto and into the surface of the iron bath usually through a water-cooled lance comprising one or more nozzles at its tip.
  • the Oxygen ignites carbon dissolved in the molten metal to form carbon monoxide and carbon dioxide thus lowering carbon content of the molten metal.
  • Fluxes, in particular dephosphorization agents, such as e.g. burnt lime are fed into the vessel to form slag and to absorb impurities (including phosphor) during the steelmaking process.
  • Magnesium oxide (MgO) containing agents may be added also for protecting an inner converter lining. Blowing the Oxygen onto and into the molten metal stirs the molten metal such that metal and fluxes may form an emulsion which facilitates the refining process.
  • a drawback which may be associated with a use of powdered lime is a possibly large loss of the lime as converter dust e.g. to gas cleaning plant systems. This may be less of a problem for lime powders of larger grain size or for bulk lime.
  • bulk lime can be dissolved less efficiently and it was found that bulk lime can in particular not be dissolved in a foamy slag.
  • a foamy slag may be advantageous for refining processes as an amount of metal droplets residing in the slag is at maximum during foaming (which results in a high decarburisation rate), only little dephosphorization appears possible when using bulk lime.
  • the Patent GB 2 011 477 A discloses a method for refining molten metal using a converter comprising at least one side wall nozzle mounted to a side wall of the converter. Further, a molten metal bath is formed inside of the converter and a mixture of an essential oxygen free carrier gas and a powdered material is blown onto and into a slag formed at least partially on the surface of the bath of molten metal using the at least one side wall nozzle.
  • a disadvantage of the disclosed method is that the powdered material is blown at the hot spot of the converter and thus increased the loss of the powder to the dedusting system.
  • a further object of the present invention is to avoid complex control mechanisms for introducing Oxygen and solid materials into a metallurgical converter.
  • a method for refining molten metal, preferably molten iron, e.g. molten pig iron, using a converter, e.g. a metallurgical furnace, for example for making steel from molten pig iron.
  • molten metal preferably molten iron, e.g. molten pig iron
  • a converter e.g. a metallurgical furnace
  • the converter is a top blown converter including at least one upper nozzle mounted to a top lance for blowing oxygen onto a bath of molten metal.
  • at least one upper nozzle is movably assigned to an upper wall of the converter.
  • the at least one upper nozzle is mounted movably in a vertical direction to the converter and is included in a, preferably water cooled, vertical lance.
  • the vertical lance itself can be mounted movably to the converter and can be movable through a corresponding opening formed in the upper wall of the converter.
  • the converter can for example also be a combined blown converter where oxygen may be partially blown into the molten bath via bottom tuyeres, while further oxygen is blown onto the bath of molten metal from above via a top lance.
  • the converter can be a combined blown converter including at least one bottom nozzle and at least one upper nozzle.
  • the converter further comprises at least one side wall nozzle mounted to a side wall of the converter lower in a vertical direction than a horizontal pivoting axis of the converter, when the converter is in an upright orientation and the method comprises a step of forming a bath of molten metal inside of the converter.
  • molten iron may be charged into the converter directly or after a suitable pretreatment stage from a blast furnace.
  • the method comprise blowing Oxygen gas onto a surface of the bath of molten metal using the at least one upper nozzle.
  • the method may comprise blowing Oxygen gas from at least one bottom nozzle or tuyere into the bath of molten metal from below.
  • the Oxygen gas may be high purity Oxygen and may be blown into the bath of molten metal at high pressure (e.g. in between 200 and 2000 kilopascal) at supersonic speeds. Reacting with Carbon included in the bath of molten metal to produce carbon oxides, blowing the Oxygen gas onto the bath surface provides the effect of removing carbon from the molten metal.
  • An iron refining or steelmaking process using the converter in accordance with the invention involves a formation of a slag on the surface of a bath of molten metal.
  • the slag may e.g. be formed using fluxes fed into the converter to absorb impurities during the process.
  • the converter being a top blown converter, the slag may e.g. be formed mainly aside of a hot spot zone where the Oxygen gas from the at least one upper nozzle impinges the surface of the bath of molten metal.
  • slag and molten metal may be mixed forming a slag/metal emulsion possibly on top of a slag layer.
  • the method further comprises blowing a mixture of a carrier gas and powdered material onto and downwardly into the slag (and/or the slag/metal emulsion) formed at least partially on the surface of the bath of molten metal using the at least one side wall nozzle.
  • the side wall nozzle is preferably mounted to a respective side wall of the converter such that the mixture of carrier gas and powdered material is injected mainly into the slag and/or into a slag/metal emulsion, preferably avoiding the hot spot zone in the case of a top blown or combined blown converter.
  • the slag being the reaction zone for the powdered material, e.g. a powdered agent, in particular for powdered lime, efficiency in using solid input materials in the converter can be thus increased.
  • a powdered material e.g. a powdered agent, in particular for powdered lime
  • the powdered material comprises a dephosphorization agent selected from a group including lime powder, Calcium Oxide (CaO), and 2CaO.SiO 2 powder may be injected directly into the reaction zone, that is the slag, which results in a high reactivity in particular in terms of efficient continuous dissolution of the agent and efficient dephosphorization of the molten metal.
  • 2CaO.SiO 2 powder may in a preferred embodiment have a grain or particle size equal to or smaller than 2 mm, preferably in between 20 to 50 ⁇ m. It turned out that 2CaO.SiO 2 powder can advantageously dissolve P 2 O 5 in solid form and thus increase the phosphorus capacity in slag which leads to high dephosphorization efficiency.
  • the use of such dephosphorization agents may allow that e.g. using high amounts of lump lime with large grain size can be avoided.
  • avoiding a use of lump lime has been found to be advantageous for a steelmaking process, as lump lime usually dissolves only slowly and undissolved parts may remain even after the end of the process.
  • the side wall nozzles may provide the following additional advantage. For example, when oxygen is blown through bottom tuyeres in case of a combined blown converter into the bath of molten metal, the produced slag amount is usually much lower than in the case of a top blown converter. This results in lower iron loss as compared with the case of a top blown converter, however, also to limited dissolution of solid lime und thus insufficient dephosphorization.
  • the method may preferably further comprise blowing a mixture of an essentially Oxygen free carrier gas and the powdered material into the bath of molten metal from below the bath of molten metal using the at least one bottom nozzle. Blowing a gas from below into the metal bath helps stirring the bath and thus facilitates the refining process. Providing additionally powdered material from below increases the total injection rate of said powdered material without introducing further load on the at least one side wall nozzle.
  • the carrier gas (preferably all gas from the at least one side wall nozzle) is essentially Oxygen (O) free.
  • the carrier gas does not comprise Oxygen up to a tolerable Oxygen pollution, e.g. a residue Oxygen concentration e.g. below 1%, e.g. below 0,1%, e.g. below 0,01% (by weight).
  • the carrier gas is an inert gas, preferably free of Oxygen.
  • the inert gas may e.g. be selected from the group of noble gases and is preferably Argon (Ar).
  • the carrier gas may comprise Nitrogen (N), being preferably free of Oxygen.
  • an oxygen-free carrier gas is advantageous as thereby, the overall system requires less complex control.
  • introducing Oxygen only (or mainly) via the at least one upper nozzle, mounted to a vertical lance prevents a necessity to synchronize oxygen blowing rates between the at least one upper nozzle and the at least one side wall nozzle.
  • a similar effect may be achieved by using the side wall nozzle in the cases of a combined blown converter.
  • the at least one side wall nozzle is mounted to the side wall at a height in a vertical direction, the height being lower than a horizontal pivoting axis of the converter, when the converter is in an upright orientation.
  • Blowing the mixture of the essentially Oxygen free carrier gas and the powdered material comprises blowing the mixture of the essentially Oxygen free carrier gas and the powdered material downwardly into the slag.
  • the at least one side wall nozzle is mounted to the converter side wall underneath the pivoting axis, defined e.g. by the trunnions about which the converter may be tilted.
  • the at least one side wall nozzle is thus mounted in close proximity to the slag and/or to the slag/metal emulsion.
  • the at least one side wall nozzle is not used for introducing oxygen into the converter, but to introduce the powdered material, e.g. the powdered dephosphorization agent, for example powdered iime, directly into the slag or slag/metal emulsion being carried by an essentially oxygen-free gas.
  • the at least one side wall nozzle By mounting the at least one side wall nozzle underneath the trunnions or a trunnion ring, the at least one side wall nozzle is located in close proximity to the reaction zone, i.e. the slag.
  • the powder can easily reach the reaction zone with minimal gas pressure such that only a reduced amount of carrier gas is necessary which is in particular advantageous if noble gasses such as Argon are used as carrier gas.
  • Noble gasses such as Argon are used as carrier gas.
  • Nitrogen Nitrogen
  • Blowing powdered material onto a slag and/or the metal bath surface from above conventionally resulted in undesirably large losses of the powdered material.
  • powdered and gaseous materials cannot be fully introduced into the slag/and or the metal bath but are blown into an inner volume of the converter above the metal bath and the slag.
  • gaseous and powdered materials are often extracted from the converter and fed to a gas cleaning plant (GCP) for separating the gaseous and powdered materials.
  • GCP gas cleaning plant
  • a mean diameter of particles forming the powdered material is smaller than 2 mm, preferably smaller than 1 mm, more preferably smaller than 0,1 mm. It was found that for example by injecting powdered lime or lime fines with grain size ⁇ 2 mm via at least one side wall nozzle located close to the slag, the typical losses to the GCP system known from using small grain sized lime are avoided or minimized.
  • the at least one side wall nozzle is arranged on the side wall of the converter underneath the trunnion ring, such that the blown mixture of carrier gas and powdered material is directed to impinge directly into the slag and/or the slag/metal emulsion.
  • a corresponding injection angle is set accordingly.
  • the blowing of the mixture of the essentially Oxygen free carrier gas and the powdered material comprises blowing the mixture of the essentially Oxygen free carrier gas and the powdered material into the slag downwardly at an injection angle with respect to the horizontal pivoting axis, the injection angle being in between 1° and 60°, preferably in between 10° and 50°, more preferably in between 15° and 35°. It was found that in particular within these angle ranges, beneficial results could be achieved in terms of use efficiency of the powdered material, e.g. the powdered dephosphorization agent.
  • Blowing the mixture of the essentially Oxygen free carrier gas and the powdered material comprises blowing the mixture of the essentially Oxygen free carrier gas and the powdered material along a main blowing direction of the at least one side wall nozzle into the slag, wherein said main blowing direction of the at least one side wall nozzle forms an angle in between 45° and 89° with a main blowing direction of the upper nozzle.
  • the powdered material can be suitably directed to areas aside of a hot spot zone in a case of a top blown converter in which zone oxygen from the upper nozzle impinges the metal bath surface into areas where slag and/or slag/metal emulsion is usually formed.
  • the essentially Oxygen free carrier gas is blown at subsonic speed onto and into the slag.
  • an inner diameter of the side wall nozzle is essentially constant along a length direction of the side wall nozzle.
  • the use of nozzles having e.g. converging and diverging inner profiles such as Laval nozzles is avoided. It was found that a use of nozzles with such inner profile are subject to larger wear of inner surfaces by grinding of particles transported through the nozzles. In the case of Laval nozzles, such grinding may be attributed to the fact that a carrier gas may reach supersonic velocities while velocities of powder particles usually remain subsonic. Nozzles with an essentially constant inner diameter are therefore advantageous as inner surfaces are subject to less wear.
  • the powdered material comprises converter dust.
  • converter dust is mainly iron oxide in form of Fe 2 O 3 and may also contain dephosphorization agents, such as CaO. It turned advantageously out that the converter dust, if introduced through the side wall nozzles can be used as a substitute for iron ore and thus as a cooling agent for the slag or as a slag former. It turned out that the cooling effect can be beneficial for dephosphorization.
  • converter dust may be converter dust recycled from the same converter or from a different converter.
  • the converter dust can be recycled without briquetting. This is advantageous as briquetting processes can be avoided and as corresponding costs can be avoided.
  • the use of the inventive side wall nozzles allow for an efficient recycling of powdered material lost to the inner volume of the converter above the bath of molten metal and the slag.
  • converter dust may be recycled from the converter.
  • the method comprises extracting a mixture of gaseous materials and converter dust from an inner converter volume during the refining of the molten metal. Thereafter, the converter dust is separated from the gaseous materials and the separated converter dust is again blown onto and into the slag via the at least one side wall nozzle.
  • the efficiency of the use of the powdered material is further increased as powdered material which escaped the reaction zone can be recycled from the converter dust and again injected into the reaction zone, i.e. into the slag and/or the slag/metal emulsion.
  • the powdered material comprises a slag forming material, preferably lime powder, preferably CaO powder. It was found that the use of the inventive side wall nozzles leads to a high efficiency of dephosphorization. Further materials such as iron ore can be used e.g. for cooling purposes.
  • the mixture of an essentially Oxygen free carrier gas and powdered material further comprises iron ore, e.g. iron ore powder. It was found that this material further has an advantageous cooling effect on the melt. Further, even though MgO-containing agents may have a negative effect on dephosphorization, this negative effect is overcompensated by the highly efficient dephosphorization enabled by the use of the side wall nozzles. Therefore, in a preferred embodiment, the mixture of an essentially Oxygen free carrier gas and powdered material further comprises dolomite powder, preferably MgO. The addition of dolomite powder helps to protect an inner converter lining.
  • the powdered material may comprise foaming or anti-foaming materials.
  • foaming or anti-foaming materials may have several advantages. For example, slag foaming increases the total reaction surface of the metallic droplets in the slag and thus the impurities removal rate. However, excessive foaming may lead to slopping (slag overrunning from the converter mouth). Thus, by appropriately providing foaming or anti-foaming materials, slag formation can be controlled.
  • the side wall nozzles can be used to either enhance or suppress the slag foaming by blowing foaming or anti-foaming agents in powdered form into or onto the slag. For example, fine powder coke was found to increase the foam height while grain coke (size 1 to 2 mm) suppresses the foaming.
  • the mixture of an essentially Oxygen free carrier gas and the powdered material may further comprise pulverized fuel materials including carbon and/or aluminum containing materials.
  • pulverized fuel materials including carbon and/or aluminum containing materials.
  • FIG. 1 shows a schematic illustration of a converter to be used in a method for refining molten metal.
  • Fig. 1 schematically illustrates a converter 100, in the shown only exemplary case a top blown converter, to be used in a method for refining molten metal, e.g. molten pig iron, for producing steel.
  • a refractory lining 110 forms an upper wall 111, a side wall 113 (the side wall essentially rotationally symmetric around a vertical axis 607) and a bottom wall 115.
  • Fig. 1 shows the converter 100 schematically during a refining process where a bath 501 of molten metal, e.g. molten iron, is formed inside the converter, a surface 503 of the bath 501 being partially covered by slag 401.
  • the slag 401 is formed least partially on the surface 503 of the bath 501, in the shown example around a hot spot zone 510 of the surface 503 which is impinged by an oxygen stream 301 from an upper nozzle 121 included in a vertical lance 120.
  • the vertical lance is mounted movable to the converter 100 along a vertical axis 607 which coincides with a main blowing direction 607 of the upper nozzle 121.
  • the vertical lance itself can be mounted movably to the converter 100 and can be movable through a corresponding opening formed in the upper wall of the converter 100.
  • a splashing mode of the vertical lance 120 can be enabled where the stream of oxygen from the upper nozzle 121 is used to generate metal droplets from the bath 501 of molten metal into to the slag 401.
  • a slag-metal interface can be increased to thereby increase the reactivity of the slag 401.
  • Fig. 1 further shows a trunnion ring 105 (cross sections of said ring at both sides of the converter 100) which embraces the converter 100.
  • the trunnion ring 105 has respective trunnions 106 which define a horizontal pivoting axis 601 around which the converter 100 can be tilted to pour the liquid steel after the refining process out of the converter 100.
  • the figure further illustrates side wall nozzles 150 which are mounted to the side wall 113 underneath a plane perpendicular to the vertical axis 607 and including the horizontal axis 601.
  • the side wall nozzles 150 are mounted lower than the trunnions 106 or the trunnion ring 105, when the converter 100 is in its upright, vertical orientation in which the steelmaking or iron refining process is carried out inside of the converter 100.
  • the figure illustrates the possibility of using a plurality of side wall nozzles (four side wall nozzles 150 are visible) which may be arranged in a ring-like fashion around the side wall 113 of the converter 100.
  • Providing the side wall nozzles 150 allows the possibility that maintenance of the powder injectors, i.e. according to the invention the side wall nozzles 150, can be done separately from the vertical lance 120, and therefore, a malfunction/breakdown of one of the side wall nozzles 150 would not affect the blowing profile and the plant operation.
  • the nozzles 150 are mounted to the side wall 113 at respective injection angles ( ⁇ 1 , ⁇ 2 shown in the figure) with respect to the horizontal pivoting axis 601 such that a mixture 303 of an essentially Oxygen free carrier gas, e.g. Argon and/or Nitrogen, and powdered material, e.g. powdered lime, is injected into the slag 401 while essentially avoiding the hot spot area 510.
  • an essentially Oxygen free carrier gas e.g. Argon and/or Nitrogen
  • powdered material e.g. powdered lime
  • the injection angle is chosen such that a main blowing direction 603, 605 of each side wall nozzle is essentially along an orientation of the slag 401 such that the mixture 303 is not blown into the metal bath 501 but such that most of the powdered material is injected into the volume of the slag 401 and or a slag/metal emulsion.
  • the side wall nozzles 150 it is possible to use the side wall nozzles 150 to generate metal droplets from the bath 501 of molten metal into to the slag 401 by blowing onto the metal bath surface (similar to a splashing mode of the vertical lance). In this way, a slag-metal interface can be increased increasing the reactivity. Using the side wall nozzles 150 in this way, it becomes possible to keep operating the vertical lance 120 and the upper nozzle 121 at a suitable vertical distance from the metal bath to reduce wear on the vertical lance 120 thereby increasing its possible lifetime.
  • the powdered material e.g. the powdered lime or CaO
  • the side wall nozzles being provided in close proximity to the slag underneath the trunnion ring 105.
  • GCP gas cleaning plant
  • powdered lime can be dissolved well in a foamy slag also when the iron oxide content in the slag is low. Losses of powdered material to the GCP system can also be efficiently avoided by blowing of the powdered material into the slag via the side wall nozzles placed in close proximity to the slag underneath the trunnion ring. Yet a further advantage achieved by blowing the mixture of carrier gas and powdered material through the side wall nozzles 150 is that a high iron content in the slag, which conventionally may be required to dissolve e.g. lime, is no longer necessary which reduces refractory and increases iron yield.
  • an efficient dephosphorization can be achieved leading to a high quality end product, e.g. a low P-content steel with a Phosphorous (P) content as low as 50 ppm.
  • the inventive method thus may allow also for refining of lower-priced raw materials with high phosphorus content.
  • the at least one side wall nozzle is provided below the trunnion ring (pivoting axis), so that the at least one side wall nozzle is situated in short distance to the slag yet a further advantage arises.
  • the powder can then easily reach the reaction zone with minimal gas pressure (and thus minimal total gas amount). In the case when Ar-gas is used, this would lead to costs reduction and in the case of nitrogen, to less N-pickup of the bath.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Analytical Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Claims (17)

  1. Verfahren zum Veredeln von geschmolzenem Metall unter Verwendung eines Konverters (100), der wenigstens eine Seitenwanddüse (150) umfasst, die an einer Seitenwand (113) des Konverters (100) in einer vertikalen Richtung tiefer als eine horizontale Schwenkachse (601) des Konverters (100), wenn sich der Konverter (100) in einer aufrechten Ausrichtung befindet, angebracht ist, wobei das Verfahren die folgenden Schritte umfasst:
    Bilden eines Bads (501) von geschmolzenem Metall in dem Konverter (100);
    Blasen eines Gemischs (303) eines im Wesentlichen sauerstofffreien Trägergases und eines pulverförmigen Materials auf und nach unten in eine Schlacke (401), die wenigstens zum Teil auf der Oberfläche (503) des Bads (501) von geschmolzenem Metall gebildet ist, unter Verwendung der wenigstens einen Seitenwanddüse (150) in einem Einspritzwinkel (α1, α2) bezogen auf die horizontale Schwenkachse (601), wobei der Einspritzwinkel zwischen 1° und 60° beträgt;
    dadurch gekennzeichnet, dass:
    der Konverter (100) ferner wenigstens eine obere Düse (121) umfasst, die beweglich einer oberen Wand (111) des Konverters (100) zugeordnet ist, und wobei das Verfahren ferner umfasst:
    Blasen von Sauerstoffgas (301) auf eine Oberfläche (503) des Bads (501) von geschmolzenem Metall unter Verwendung der wenigstens einen oberen Düse (121); und
    wobei das Gemisch (303) entlang einer Hauptblasrichtung (603, 605) der wenigstens einen Seitenwanddüse (150) in die Schlacke (401) geblasen wird, wobei die Hauptblasrichtung (603, 605) der wenigstens einen Seitenwanddüse (150) einen Winkel zwischen 45° und 89° mit einer Hauptblasrichtung (607) der oberen Düse (121) bildet.
  2. Verfahren gemäß Anspruch 1, wobei der Einspritzwinkel (α1, α2) zwischen 10° und 50°, vorzugsweise zwischen 15° und 35°, beträgt.
  3. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 2, wobei der Konverter (100) ferner wenigstens eine untere Düse umfasst, die an einer unteren Wand (115) des Konverters (100) angebracht ist, wobei das Verfahren ferner umfasst:
    Blasen eines Gemischs eines im Wesentlichen sauerstofffreien Trägergases und von pulverförmigem Material in das Bad (501) von geschmolzenem Metall von unterhalb des Bads (501) von geschmolzenem Metall unter Verwendung der wenigstens einen unteren Düse.
  4. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 3, wobei das Blasen des Gemischs (303) des im Wesentlichen sauerstofffreien Trägergases und des pulverförmiges Materials umfasst:
    Blasen des im Wesentlichen sauerstofffreien Trägergases mit Unterschallgeschwindigkeit auf und in die Schlacke (401).
  5. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 4, wobei ein Innendurchmesser der Seitenwanddüse (150) entlang einer Längsrichtung (603, 605) der Seitenwanddüse (150) im Wesentlichen konstant ist, wobei das Blasen des Gemischs (303) des im Wesentlichen sauerstofffreien Trägergases und des pulverförmiges Materials umfasst:
    Blasen des im Wesentlichen sauerstofffreien Trägergases mit Unterschallgeschwindigkeit auf und in die Schlacke (401).
  6. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 5, wobei das pulverförmige Material recycelten Konverterstaub umfasst.
  7. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 6, ferner umfassend:
    Extrahieren eines Gemischs von gasförmigen Materialien und Konverterstaub aus einem Konverter-Innenvolumen während des Veredelns des geschmolzenen Metalls,
    Abtrennen des pulverförmigen Materials von den gasförmigen Materialien; und
    Blasen des abgetrennten pulverförmigen Materials auf die Schlacke (401) über die wenigstens eine Seitenwanddüse (150).
  8. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 7, wobei das pulverförmige Material ein Dephosphorierungsmittel umfasst, vorzugsweise ausgewählt aus einer Gruppe umfassend Kalkpulver, CaO-Pulver und 2CaO.SiO2.
  9. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 8, wobei das pulverförmige Material Dolomitpulver, vorzugsweise MgO, umfasst.
  10. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 9, wobei das pulverförmige Material Eisenerz umfasst.
  11. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 10, wobei das pulverförmige Material ferner pulverförmige Brennstoffmaterialien, einschließlich kohlenstoff- und/oder aluminiumhaltiger Materialien, umfasst.
  12. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 11, wobei das pulverförmige Material schäumende oder Antischaummaterialien umfasst.
  13. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 12, wobei das Trägergas ein Inertgas ist.
  14. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 13, wobei das Trägergas Argon und/oder Stickstoff umfasst.
  15. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 14, wobei die wenigstens eine obere Düse (121) über eine wassergekühlte vertikale Lanze (120) in einer vertikalen Richtung an der oberen Wand (111) des Konverters (100) beweglich angebracht ist.
  16. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 15, wobei ein mittlerer Durchmesser von Partikeln, die das pulverförmige Material bilden, kleiner als 2 mm, vorzugsweise kleiner als 1 mm, bevorzugter kleiner als 0,1 mm, ist.
  17. Verfahren gemäß einem der vorstehenden Ansprüche 1 bis 16, wobei das geschmolzene Metall geschmolzenes Eisen umfasst.
EP19704797.0A 2018-02-16 2019-02-11 Verfahren zum raffinieren von geschmolzenem metall unter verwendung eines konverters Active EP3752650B1 (de)

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US4195985A (en) * 1977-12-10 1980-04-01 Eisenwerk-Gesellschaft Maximilianshutte Mbh. Method of improvement of the heat-balance in the refining of steel
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