Classifications

• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/12—Alloys based on aluminium with copper as the next major constituent
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/12—Alloys based on aluminium with copper as the next major constituent
  • C22C21/16—Alloys based on aluminium with copper as the next major constituent with magnesium
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0226—Hot rolling
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
  • C21D8/0236—Cold rolling
• • C—CHEMISTRY; METALLURGY
  • C21—METALLURGY OF IRON
  • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
  • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
  • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
  • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
  • C21D8/0273—Final recrystallisation annealing
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C21/00—Alloys based on aluminium
  • C22C21/12—Alloys based on aluminium with copper as the next major constituent
  • C22C21/14—Alloys based on aluminium with copper as the next major constituent with silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
  • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
  • C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
  • C22F1/057—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent

Definitions

• the present invention generally relates to manufacturing processes for aluminum-based 2XXX alloy sheets comprising lithium, in particular such improved processes that are particularly suited to the constraints of the aerospace industry.
• the processes according to the invention are especially suitable for the manufacture of fuselage sheets.
• Al-Cu-Li alloys are particularly interesting for manufacturing aluminum alloy rolled products, especially fuselage elements, because they offer compromises of properties generally higher than conventional alloys, especially in terms of the compromise between fatigue. , damage tolerance and mechanical resistance. This makes it possible in particular to reduce the thickness of the wrought products of Al-Cu-Li alloy, thus further maximizing the weight reduction they provide.
• the document EP 1 966 402 B2 discloses in particular fuselage plates with particularly advantageous properties, these sheets being produced using an alloy comprising in particular, in percentage by weight, Cu: 2.1 to 2.8; Li: 1.1 to 1.7; Ag: 0.1 to 0.8; Mg: 0.2 to 0.6; Mn: 0.2 to 0.6; Zr ⁇ 0.04; Fe and Si ⁇ 0.1 each; unavoidable impurities ⁇ 0.05 each and 0.15 in total; remains aluminum.
• such a product can not be subjected to an optimized manufacturing process in terms of duration of income without a deterioration of its properties, in particular of its compromise between mechanical resistance and toughness.
• the patent application WO2011 / 141647 describes an aluminum-based alloy comprising, in% by weight, 2.1 to 2.4% Cu, 1.3 to 1.6% Li, 0.1 to 0, Ag, 0.2 to 0.6% Mg, 0.05 to 0.15% Zr, 0.1 to 0.5% Mn, 0.01 to 0.12% Ti, optionally at minus one element selected from Cr, Se, and Hf, the amount of the element, if selected, being from 0.05 to 0.3% for Cr and for Se, 0.05 to 0.5% for Hf, an amount of Fe and Si less than or equal to 0.1 each, and unavoidable impurities at a content less than or equal to 0.05 each and 0.15 in total.
• the alloy allows the production of spun, rolled and / or forged products particularly suitable for the manufacture of aircraft wing-bottom elements.
• the temperature used for the income in the examples is 155 ° C.
• the patent application WO2013 / 054013 relates to the process for manufacturing a laminated product, in particular for the aerospace industry based on aluminum alloy with a composition of 2.1 to 3.9% by weight of Cu, 0.7 to 2.0% by weight of Li, 0.1 to 1.0% by weight of Mg, 0 to 0.6% by weight of Ag, 0 to 1% by weight of Zn, at most 0.20% by weight Fe + Si, at least one element selected from Zr, Mn, Cr, Se, Hf and Ti, the amount of said element, if selected, being 0.05 to 0.18% by weight for Zr, 0, 1 to 0.6% by weight for Mn, 0.05 to 0.3% by weight for Cr, 0.02 to 0.2% by weight for Se, 0.05 to 0.5% by weight for Hf and from 0.01 to 0.15% by weight for Ti, the other elements at most 0.05% by weight each and 0.15% by weight in total, the aluminum balance, in which, in particular, planing is carried out and / or a traction with a cumulative deformation of at least
• the patent application WO2010 / 055225 relates to a process for manufacturing a spun, rolled and / or forged product based on aluminum alloy in which: a bath of liquid metal is produced comprising 2.0 to 3.5% by weight of Cu, 1.4 to 1.8% by weight of Li, 0.1 to 0.5% by weight of Ag, 0.1 to 1.0% by weight of Mg, 0.05 to 0 , 18% by weight of Zr, 0.2 to 0.6% by weight of Mn and at least one element selected from Cr, Sc, Hf and Ti, the amount of the element, if chosen, being from 0.05 to 0.3% by weight for Cr and Sc, 0.05 to 0.5% by weight for Hf and 0.01 to 0.15% by weight for Ti, the balance being aluminum and unavoidable impurities; casting a raw form from the bath of liquid metal and homogenizing said raw form at a temperature of between 515 ° C and 525 ° C so the time equivalent to 520 ° C for homogenization is between 5 and 20 hours.
• the subject of the invention is a process for producing a wrought aluminum alloy product comprising the following steps:
• At. casting an alloy plate comprising, in percent by weight: Cu: 2.1 to 2.8; Li: 1.1 to 1.7; Mg: 0.2 to 0.9; Mn: 0.2 to 0.6; Ag ⁇ 0.1; Zr ⁇ 0.08; Ti 0.01 to 0.2; Fe and Si ⁇ 0.1 each; unavoidable impurities ⁇ 0.05 each and 0.15 in total; remains aluminum;
• tempered sheet metal by heating at a temperature of at least 160 ° C for a maximum of 30 hours.
• Another subject of the invention is a product that can be obtained by the process according to the invention, characterized in that among the phases containing lithium it does not contain the phase of but only the Tl phase.
• Figure 1 R curve in the TL direction (specimen CCT760) for an alloy sheet
• Figure 2 Tenacity K r6 o (TL) as a function of the elastic limit R p o, 2 (TL) for an alloy sheet AT
• Figure 3 R curve in the TL direction (specimen CCT760) for an alloy sheet B
• Figure 4 Tenacity Kq as a function of the temperature of the second income stage during a two-stage income applied to an alloy product 2A97 (According to Zhong et al, 2011)
• Figure 5 Kq toughness versus tempering temperature applied to an 8090 alloy product (according to Duncan and Martin, 1991)
• alloys are in accordance with the regulations of The Aluminum Association, known to those skilled in the art. The density depends on the composition and is determined by calculation rather than by a method of measuring weight. The values are calculated in accordance with the procedure of The Aluminum Association, which is described on pages 2-12 and 2-13 of "Aluminum Standards and Data". The definitions of the metallurgical states are given in the European standard EN 515 (1993).
• the static mechanical characteristics in tension in other words the tensile strength R m , the conventional yield stress at 0.2% elongation R P o, 2, and the elongation at break A%, are determined by a tensile test according to standard NF EN ISO 6892-1 / ASTM E8 - E8M-13, the sampling and the direction of the test being defined by the standard EN 485-1.
• a curve giving the effective stress intensity factor as a function of the effective crack extension, known as the R curve, is determined according to the standard E561-10 (2010).
• the critical stress intensity factor Kc in other words the intensity factor that makes the crack unstable, is calculated from the curve R.
• the stress intensity factor Kco is also calculated by assigning the length initial crack at the beginning of the monotonic load, at the critical load. These two values are calculated for a specimen of the required shape.
• Ka PP represents the Kco factor corresponding to the specimen that was used to perform the R curve test.
• K eff represents the Kc factor corresponding to the specimen that was used to perform the R aa curve test.
• (max) represents the crack extension of the last valid point of the curve R.
• the length of the curve R - namely the maximum crack extension of the curve - is a parameter in itself important, especially for the design fuselage.
• KrôQ represents the effective stress intensity factor for effective crack extension Aa eff of 60 mm.
• the method according to the invention comprises in particular a step of tempering the sheet metal by heating at a temperature of at least 160 ° C. for a maximum duration of 30 hours.
• the product of particular composition has a tenacity equal to or different from less than 8%, preferentially less than 5%, more preferably still less than 4% or even 2%, of that of the same product.
• the product of particular composition advantageously has a conventional limit of elasticity Rp0.2 (TL) equal to or different from less than 8%, preferably less than 5%, more preferably still less 4% or even 2%, of that of the same product manufactured according to a conventional process of the prior art, in particular a process identical to that of the invention with the exception of the income which would typically be an income by heating to about l52 ° C for about 48h.
• TL conventional limit of elasticity
• the method of manufacturing a wrought aluminum alloy product according to the invention firstly comprises a casting step of a particular alloy plate.
• the alloy comprises, in percentage by weight, Cu: 2.1 to 2.8; Li: 1.1 to 1.7; Mg: 0.2 to 0.9 ; Mn: 0.2 to 0.6; Ti 0.01 to 0.2; Ag ⁇ 0.1; Zr ⁇ 0.08; Fe and Si ⁇ 0.1 each; unavoidable impurities ⁇ 0.05 each and 0.15 in total; remains aluminum.
• the aluminum alloy plate comprises from 2.2 to 2.6% by weight of Cu, preferably from 2.3 to 2.5% by weight.
• the inventors have discovered that if the copper content is greater than 2.8% or even 2.6% or even 2.5% by weight, the toughness properties may in some cases fall rapidly, whereas, if the copper is less than 2.1% or even 2.2% or even 2.3% by weight, the mechanical strength may be too low.
• the aluminum alloy plate comprises from 1.1 to 1.7% by weight of lithium. Preferably, it comprises from 1.2 to 1.6% by weight of Li, or from 1.25 to 1.55% by weight. A lithium content greater than 1.7% or even 1.6% or even 1.55% by weight can cause thermal stability problems. A lithium content of less than 1.1% or even 1.2% or even 1.25% by weight can result in inadequate mechanical strength and lower density gain.
• the aluminum alloy plate comprises from 0.2 to 0.9% by weight of magnesium. According to one advantageous embodiment, the aluminum alloy plate comprises from 0.25 to 0.75% by weight of Mg.
• the aluminum alloy plate comprises from 0.01 to 0.2% by weight of titanium.
• the addition of titanium in various forms, Ti, TiB or TiC allows in particular to control the granular structure during the cast plate.
• the aluminum alloy plate comprises from 0.01 to 0.10% by weight of Ti.
• the plate further comprises less than 0.1% by weight of silver.
• the aluminum alloy plate comprises less than 0.05% by weight of Ag, preferably less than 0.04% by weight.
• the aluminum alloy plate comprises from 0.2 to 0.6% by weight of manganese. Preferably, it comprises from 0.25 to 0.45% by weight of Mn.
• the aluminum alloy plate comprises less than 0.08% by weight of zirconium. In a still more preferred embodiment, it comprises less than 0.05% by weight of Zr, preferably less than 0.04% by weight and, even more preferably, less than 0.03% or even 0.01% by weight. .
• a low zirconium content makes it possible to improve the toughness of the Al-Cu-Li-Ag-Mg-Mn alloys according to the invention; in particular, the length of the curve R is significantly increased.
• the use of manganese in place of zirconium to control the granular structure has several additional advantages such as obtaining a recrystallized structure and isotropic properties especially for a thickness of 0.8 to 12.7 mm.
• the recrystallization rate of the products according to the invention is greater than 80%, preferably greater than 90%.
• Iron and silicon generally affect toughness properties.
• the amount of iron should be limited to 0.1% by weight (preferably 0.05% by weight) and the amount of silicon should be limited to 0.1% by weight (preferably 0.05% by weight) ).
• the unavoidable impurities should be limited to 0.05% by weight each and 0.15% by weight in total.
• the manufacturing method according to the invention further comprises a step of homogenizing the casting plate at a temperature of 480 to 520 ° C. for 5 to 60 hours and, preferably, this step is carried out between 490 and 5 ° 10 °. C for 8 to 20 hours. Homogenization temperatures above 520 ° C tend to reduce the toughness performance in some cases.
• the homogenized plate is then hot-rolled and optionally cold-rolled into a sheet.
• the hot rolling is carried out at an initial temperature of 420 to 490 ° C, preferably 440 to 470 ° C.
• the hot rolling is preferably carried out to obtain a thickness of between about 4 and 12.7 mm.
• a cold rolling step may optionally be added, if necessary.
• the sheet obtained has a thickness of between 0.8 and 12.7 mm, and the invention is more advantageous for sheets of 1.6 to 9 mm thick, and even more advantageous. for sheets 2 to 7 mm thick.
• the rolled product is then dissolved, preferably by heat treatment at 470 to 520 ° C for 15 minutes to 4 hours, and then typically quenched with water at room temperature.
• the solution product is then subjected to a traction step in a controlled manner with a permanent deformation of 1 to 6%.
• traction in a controlled manner is carried out with a permanent deformation of between 2.5 and 5%.
• the inventors have discovered that the alloy product according to the invention can be manufactured using an optimized process, the income stage of said process being able to be carried out at particularly high temperatures, especially greater than 160.degree. ° C and even more so while the duration of the income can be, consequently, greatly reduced.
• this process optimization can be carried out without deterioration of the properties of the product, in particular without affecting the conventional yield limit compromise Rp0.2 (LT) - toughness Kapp (T-L).
• the quenched product is subjected to a tempering step by a particular heating at a temperature of at least 160 ° C for a maximum of 30 hours.
• the income can even be produced at a temperature of at least 162 ° C., preferably at least 165 ° C. and, more preferably, at least 170 ° C. for a maximum of 30 hours, advantageously 28 hours. even 25h or 20h.
• the tempering step is carried out at a temperature of at most 200 ° C. and preferably at most 190 ° C. and preferably at most 180 ° C.
• the income is carried out at a time equivalent h to 165 ° C between 15 and 35 hours, preferably between 20 and 30h.
• the equivalent time at 165 ° C. is defined by the formula:
• T in Kelvin
• T ref a reference temperature set at 428 K.
• h is expressed in hours.
• the present inventors have found that the products obtained by the process according to the invention contain, among the phases containing lithium, not the phase of (Af Li) but only the phase T1 (AhCuLi), which is particularly advantageous in this process. which concerns the thermal stability of the product obtained.
• the product of particular composition has a tenacity Kapp (TL) equal to or different from less than 8%, preferably less than 5%, more preferably less than 4 or even 2%, of that of the same manufactured product according to a conventional method of the prior art, in particular a process identical to that of the invention with the exception of the income which would typically be a revenue by heating to about 152 ° C for about 48 hours.
• TL tenacity Kapp
• the product of particular composition also advantageously has a conventional limit of elasticity Rp0.2 (LT) equal to or different from less than 8%, preferably less than 5%, more preferentially from less than 4 or even 2%, that of the same product manufactured according to a conventional process of the prior art, including a process identical to that of the invention with the exception of the income which would typically be a revenue by heating to about l52 ° C for about 48h.
• LT conventional limit of elasticity
• the method according to the invention makes it possible to obtain a product having at least one, advantageously at least two or even three or more of the following properties:
• the method according to the invention makes it possible to obtain a product having a very good thermal stability.
• the product obtained directly at the end of the process according to the invention that is to say at the end of the income by heating at a temperature of at least 160 ° C. for a maximum duration of 30 hours. and after a heat treatment of 1000h at 85 ° C, has a plane stress toughness, Kapp (TL), and / or an effective stress intensity factor for effective crack extension Aa eff of 60 mm, Kr60 (TL), which does not differ more than 7%, preferably not more than 5% and more preferably still not more than 4% or even 2%.
• the product according to the invention is a sheet and more preferably a thin sheet, more preferably still a thin fuselage sheet.
• the product according to the invention can therefore advantageously be used in an aircraft fuselage panel.
• the alloy A of composition shown in Table 1 is an alloy according to the invention.
• the process used to manufacture the alloy sheet A was as follows: a plate of thickness about 400 mm of alloy A was cast, homogenized at 508 ° C. for about 12 hours and then scalped. The plate was hot rolled to obtain a sheet having a thickness of 4 mm. It was dissolved at about 500 ° C and then quenched with cold water. The sheet was then fractionated with a permanent elongation of 3 to 4%. The following incomes were made on different samples of the sheet: 48h-l52 ° C, 40h-l55 ° C, 30h-l60 ° C and 25h-l65 ° C. For each of the income conditions, a portion of the sheets was subjected to a thermal stability test of 1000 h at 85 ° C.
• Samples were taken at full thickness to measure static mechanical tensile properties and toughness in the T-L direction.
• the specimens used for the tenacity measurement were CCT760 geometry specimens: 760mm (L) x 1250mm (TL).
• the alloy B of composition shown in Table 4 is a reference alloy, especially known from EP 1 966 402 B2.
• the method used for the manufacture of the alloy sheet B was as follows: a plate of thickness about 400 mm of alloy B was cast, homogenized at 500 ° C for about 12 hours and then scalped. The plate was hot rolled to obtain a sheet having a thickness of 5 mm. It was dissolved at about 500 ° C and then quenched with cold water. The sheet was then fractionated with a permanent elongation of 1 to 5%. The following incomes were made on different samples of the sheet: 48h-l52 ° C, and 25h-l65 ° C.
• Samples were taken at full thickness to measure tensile static mechanical characteristics and toughness in the T-L direction.
• the specimens used for the tenacity measurement were CCT760 geometry specimens: 760mm (L) x 1250mm (TL)
• the images were acquired either by the Slow Scan CCD camera (high quality digital images thanks to the wide dynamic range and linearity of response), or by the SIT camera ("large field" images at the TV speed), or on film shots (to record diffraction patterns).
• the acceleration voltage was 120 kV.

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• 2017
  • 2017-12-20 FR FR1762674A patent/FR3075078B1/fr active Active
• 2018
  • 2018-12-17 CN CN201880082024.2A patent/CN111492074A/zh active Pending
  • 2018-12-17 CA CA3085811A patent/CA3085811A1/fr active Pending
  • 2018-12-17 EP EP18833951.9A patent/EP3728667B1/de active Active
  • 2018-12-17 US US16/955,424 patent/US11732333B2/en active Active
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