EP3631318A1 - Heating device and method for production thereof - Google Patents
Heating device and method for production thereofInfo
- Publication number
- EP3631318A1 EP3631318A1 EP18728815.4A EP18728815A EP3631318A1 EP 3631318 A1 EP3631318 A1 EP 3631318A1 EP 18728815 A EP18728815 A EP 18728815A EP 3631318 A1 EP3631318 A1 EP 3631318A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer structure
- polymer
- heater
- fluid
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000010438 heat treatment Methods 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 87
- 239000012530 fluid Substances 0.000 claims abstract description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 17
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 238000001746 injection moulding Methods 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 claims description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 2
- 238000005266 casting Methods 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000004512 die casting Methods 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 229910021389 graphene Inorganic materials 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 238000000059 patterning Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 abstract description 3
- 238000005485 electric heating Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000012777 electrically insulating material Substances 0.000 description 3
- 229920002313 fluoropolymer Polymers 0.000 description 3
- 239000004811 fluoropolymer Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920002859 polyalkenylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920003245 polyoctenamer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H3/00—Air heaters
- F24H3/02—Air heaters with forced circulation
- F24H3/04—Air heaters with forced circulation the air being in direct contact with the heating medium, e.g. electric heating element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14639—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles for obtaining an insulating effect, e.g. for electrical components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H1/00—Heating, cooling or ventilating [HVAC] devices
- B60H1/22—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant
- B60H1/2215—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters
- B60H1/2218—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters controlling the operation of electric heaters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H1/00—Heating, cooling or ventilating [HVAC] devices
- B60H1/22—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant
- B60H1/2215—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters
- B60H1/2221—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters arrangements of electric heaters for heating an intermediate liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H1/00—Heating, cooling or ventilating [HVAC] devices
- B60H1/22—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant
- B60H1/2215—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters
- B60H1/2225—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant the heat being derived from electric heaters arrangements of electric heaters for heating air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/0072—Special adaptations
- F24H1/009—Special adaptations for vehicle systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/10—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium
- F24H1/101—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium using electric energy supply
- F24H1/102—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium using electric energy supply with resistance
- F24H1/103—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium using electric energy supply with resistance with bare resistances in direct contact with the fluid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/10—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium
- F24H1/12—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium in which the water is kept separate from the heating medium
- F24H1/121—Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium in which the water is kept separate from the heating medium using electric energy supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H3/00—Air heaters
- F24H3/02—Air heaters with forced circulation
- F24H3/04—Air heaters with forced circulation the air being in direct contact with the heating medium, e.g. electric heating element
- F24H3/0405—Air heaters with forced circulation the air being in direct contact with the heating medium, e.g. electric heating element using electric energy supply, e.g. the heating medium being a resistive element; Heating by direct contact, i.e. with resistive elements, electrodes and fins being bonded together without additional element in-between
- F24H3/0429—For vehicles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B1/00—Details of electric heating devices
- H05B1/02—Automatic switching arrangements specially adapted to apparatus ; Control of heating devices
- H05B1/0227—Applications
- H05B1/023—Industrial applications
- H05B1/0236—Industrial applications for vehicles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/02—Details
- H05B3/06—Heater elements structurally combined with coupling elements or holders
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/145—Carbon only, e.g. carbon black, graphite
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/146—Conductive polymers, e.g. polyethylene, thermoplastics
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/18—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor the conductor being embedded in an insulating material
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/26—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/28—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
- H05B3/286—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material the insulating material being an organic material, e.g. plastic
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/42—Heating elements having the shape of rods or tubes non-flexible
- H05B3/48—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
- H05B3/50—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material heating conductor arranged in metal tubes, the radiating surface having heat-conducting fins
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/54—Heating elements having the shape of rods or tubes flexible
- H05B3/56—Heating cables
- H05B3/565—Heating cables flat cables
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/78—Heating arrangements specially adapted for immersion heating
- H05B3/82—Fixedly-mounted immersion heaters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2307/00—Use of elements other than metals as reinforcement
- B29K2307/04—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0003—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular electrical or magnetic properties, e.g. piezoelectric
- B29K2995/0005—Conductive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/779—Heating equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H1/00—Heating, cooling or ventilating [HVAC] devices
- B60H1/00007—Combined heating, ventilating, or cooling devices
- B60H1/00021—Air flow details of HVAC devices
- B60H2001/00114—Heating or cooling details
- B60H2001/00128—Electric heaters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
- B60H1/00—Heating, cooling or ventilating [HVAC] devices
- B60H1/22—Heating, cooling or ventilating [HVAC] devices the heat being derived otherwise than from the propulsion plant
- B60H2001/2268—Constructional features
- B60H2001/2271—Heat exchangers, burners, ignition devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H1/00—Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
- F24H1/18—Water-storage heaters
- F24H1/20—Water-storage heaters with immersed heating elements, e.g. electric elements or furnace tubes
- F24H1/201—Water-storage heaters with immersed heating elements, e.g. electric elements or furnace tubes using electric energy supply
- F24H1/202—Water-storage heaters with immersed heating elements, e.g. electric elements or furnace tubes using electric energy supply with resistances
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
- F24H2250/00—Electrical heat generating means
- F24H2250/04—Positive or negative temperature coefficients, e.g. PTC, NTC
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/002—Heaters using a particular layout for the resistive material or resistive elements
- H05B2203/003—Heaters using a particular layout for the resistive material or resistive elements using serpentine layout
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/017—Manufacturing methods or apparatus for heaters
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/02—Heaters using heating elements having a positive temperature coefficient
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/021—Heaters specially adapted for heating liquids
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/022—Heaters specially adapted for heating gaseous material
- H05B2203/023—Heaters of the type used for electrically heating the air blown in a vehicle compartment by the vehicle heating system
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/022—Heaters specially adapted for heating gaseous material
- H05B2203/024—Heaters using beehive flow through structures
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2214/00—Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
- H05B2214/04—Heating means manufactured by using nanotechnology
Definitions
- the invention relates to a heater, in particular for a motor vehicle, and a method for producing the same.
- Electric heaters especially air heaters (especially those used in mobile applications) are often based on ceramic heating elements with a comparatively strong temperature-dependent electrical resistance, through which a self-regulation of the heat release is possible.
- These resistors are usually PTC ceramic elements (PTC for Positive Temperature Coefficient). These are usually connected to heat exchanger surfaces made of aluminum sheet and are also contacted electrically.
- a PTC element comprises a PTC resistor, ie a temperature-dependent resistor with a positive temperature coefficient, which conducts the electric current better at low temperatures than at high temperatures.
- Disadvantages of conventional heaters, in particular air heaters with ceramic PTC elements include u.a. an elaborate production by a comparatively complicated heat exchanger production and the installation of the ceramic elements, a usually necessary sorting of the ceramic elements due to manufacturing tolerances, a comparatively unfavorable power density in a heating element heat exchanger composite by a local heat generation, a relatively strong restriction a maximum heating power through a thickness of the PTC material (due to a limited heat dissipation from the ceramic) and a comparatively high risk of short circuit, in particular due to a low geometric
- the object is achieved by a method for producing an electric heater, preferably liquid or air heater, preferably for a vehicle, in particular for a motor vehicle, wherein at least one conductive polymer structure, wherein the polymer structure is a polymer component and a conductive component, in particular
- Carbon component is produced by prototyping, wherein
- Fluid channels are introduced for passing the fluid to be heated during the original manufacturing in the polymer structure.
- a central idea of the invention is to produce a (conductive) polymer structure for heating fluid (in particular water, preferably cooling water or air, preferably heating air for an interior, in particular a vehicle) in a heater, preferably liquid or air heater, wherein integrated openings for Passage of the fluid (fluid channels) are made or introduced during a primary molding.
- a heater preferably liquid or air heater, which allows efficient operation.
- the polymer structure has a plurality of fluid channels, e.g. B. more than 10 fluid channels, on.
- the polymer structure is as a one-piece, in particular
- the master molding may include casting, in particular injection molding and / or die casting, pressing, in particular extrusion and / or compression molding, and / or foaming.
- prototypes are to be understood as a production process in which an informal or deformable (eg liquid, pasty, pasty or plastically deformable) fabric a (solid) body is made (the
- the polymer structure is preferably dimensionally stable in itself, thus also retains its shape when other components of the heater are removed (or have not yet been added or integrated with other components, if they were not provided, which by producing a corresponding comparison object without the other components can be determined).
- a dimensionally stable design does not exclude in particular that the
- a tool for carrying out the primary shaping eg injection molding tool
- At least one electrical connection element such as, preferably, a metal wire, metal mesh, metal sheet and / or sheet metal strips, may be bonded to the polymer structure, preferably into the
- Embedded polymer structure Under a compound is in particular a cohesive (solid) connection to understand. Alternatively or additionally, a positive connection (eg by means of corresponding projections or recesses provided on the connection element) is provided.
- a positive connection eg by means of corresponding projections or recesses provided on the connection element.
- Mold in particular injection molding tool, arranged (or inserted into such).
- prototyping eg.
- an electric heater preferably liquid or air heater, in particular for a vehicle, preferably for a motor vehicle, more preferably produced by the above method, comprising at least one conductive
- Polymer structure wherein the polymer structure has a (possibly non-conductive)
- the electric fluid heater in particular liquid or air heater preferably has at least one electrical connection element, such as preferably a metal wire, metal mesh, metal sheet and / or sheet metal strips on.
- the polymer structure preferably has a grid, honeycomb or mesh structure.
- Cross-sections of the fluid channels in the polymer structure may be at least 5%, preferably at least 10%, more preferably at least 20% of a total cross-section of the polymer structure.
- Cross sections of the fluid channels in the polymer structure amount to at most 80% of an overall cross section of the polymer structure.
- the conductive component in particular carbon component may be present in particle form and / or as a carbon skeleton.
- the conductive component in particular carbon component may be formed or arranged so that it allows a flow of current, for. B. in particulate form (with the particles corresponding to touch or close together) and / or as a (carbon) scaffold.
- the conductive component may include metal particles and / or fibers.
- the carbon component may be present in the form of carbon black and / or graphite and / or graphene and / or carbon fiber fibers and / or carbon nanotubes and / or fullerenes.
- the polymer structure may comprise an electrically insulating polymer component.
- the polymer structure comprises at least 6, more preferably at least 10, even more preferably at least 40 fluid channels.
- a fluid heater in particular liquid or air heater of the type described above or prepared by the method of the type described above, wherein fluid flows through the fluid channels and is thereby heated.
- a fluid heater in particular liquid or air heater of the type described above or produced by the method described above for heating air, especially in a vehicle, preferably a motor vehicle, more preferably for a motor vehicle interior.
- a vehicle comprising a fluid heater, in particular liquid or air heater of the type described above or produced by the method described above.
- the polymer structure is preferably a conductive structure with PTC behavior.
- Cross-sections of at least one or more or all of the fluid channels may be polygonal, in particular quadrangular, preferably rectangular (more preferably square) or oval, in particular elliptical, preferably (circular) circular.
- a cross section within a fluid channel may vary or be constant (over its length). Also cross sections of different fluid channels may differ or be the same.
- Short circuits may be provided on the entire heater or at least exposed areas of the polymer structure, a protective layer (paint or seal).
- Plastic component should be understood as an abbreviation for "electrically conductive”.
- the polymer structure may be formed as a polymer plate (with corresponding openings or fluid channels).
- Polymer component and conductive (carbon) component are preferably mixed together or intertwined.
- the polymer component can form a (skeletal) framework in which the conductive component is accommodated or vice versa.
- the polymer structure is at least
- Carbon component such as. B. the carbon particles.
- the carbon component is at least 50% by weight, more preferably at least 70% by weight of carbon.
- the polymer component is in particular in the form of an electrically insulating polymer component.
- the polymer component may be a first polymer subcomponent based on ethylene acetate (copolymer) and / or
- Ethylene acrylate (copolymer) and / or comprise a second polymer component based on polyolefin, in particular polyethylene and / or polypropylene, and / or polyester and / or polyamide and / or fluoropolymer.
- the term "subcomponent" is intended here in particular for Distinction between first and second polymer subcomponent can be used.
- the respective subcomponent can form either partially or completely the polymer component.
- the ethylene acrylate may be ethyl methyl acrylate or ethylene ethyl acrylate.
- Ethylene acetate may be ethylene vinyl acetate.
- the polyethylene may be high density polyethylene, medium density polyethylene, low density polyethylene.
- the fluoropolymer may be PFA (copolymer of tetrafluoroethylene and perfluoropropyl vinyl ester) MFA (copolymer of tetrafluoroethylene and perfluorovinyl ester), FEP (copolymer of tetrafluoroethylene and hexafluoropropylene), ETFE (copolymer of ethylene and tetrafluoroethylene) or PVDF (polyvinylidene fluoride) act.
- PFA copolymer of tetrafluoroethylene and perfluoropropyl vinyl ester
- MFA copolymer of tetrafluoroethylene and perfluorovinyl ester
- FEP copolymer of tetrafluoroethylene and hexafluoropropylene
- the first polymer subcomponent as in FIG. 1
- WO 2014/188190 AI (described as a first-electrically insulating material) may be formed.
- the second polymer subcomponent can likewise be formed as described in WO 2014/188190 A1 (as a second-electrically insulating material).
- the polymer structure or the polymer structures may be contacted by at least one metal structure, preferably a (in particular bent) metal sheet, preferably copper sheet, and / or metal strip and / or metal wire and / or metal grid (electrically).
- a metal structure preferably a (in particular bent) metal sheet, preferably copper sheet, and / or metal strip and / or metal wire and / or metal grid (electrically).
- the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding to the metal structure (or corresponding
- Electrodes On the substrate and / or the polymer coating,
- the polymer structure or the polymer structures and / or a corresponding substance to be formed (for example paste) for the production thereof may comprise (as in particular crystalline binder) at least one polymer, preferably based on at least one olefin; and / or at least one copolymer of at least one olefin and at least one monomer which can be copolymerized therewith, e.g. As ethylene / acrylic acid and / or
- polyacetylene or polyalkenylene such as.
- polyoctenamer polyoctenamer
- fluoropolymer such as.
- polyvinylidene fluoride and / or copolymers thereof As polyvinylidene fluoride and / or copolymers thereof.
- the polymer structure or one for producing the
- Binders (especially according to p. 4, 2nd paragraph and p. 5, 1st paragraph of
- the polymer structure is preferably a PTC resistor. Thereby, a self-regulation of the temperature can be made possible, which simplifies the control and in particular increases the safety during operation.
- Polymer body especially with regard to the fluid channels (openings) for the fluid to be heated, a high component surface can be realized, which allows a high heat output with little space due to a good convective heat transfer.
- metallic connecting elements of the electrical resistance in the transition into the polymer structure (or a polymer material of the
- Polymer structure are minimized and the risk of deterioration of the contact over the life can be reduced.
- the latter can be roughened (for example by sandblasting) and / or holes and / or undercuts can be introduced into the (respective) connection element.
- sandblasting for example by sandblasting
- holes and / or undercuts can be introduced into the (respective) connection element.
- Drahtgewebe-, knitted and / or -gewirke be provided as connecting elements.
- the polymer structure can not only fulfill the task of a heat conductor, but at the same time enable further functions as an (integral) component, in particular forming a frame or connecting surfaces for the heater.
- the fluid heater in particular liquid or air heater is preferably designed for operation in the low-voltage range (eg ⁇ 100 volts or ⁇ 60 volts).
- the heater can be designed for operation with alternating or direct current.
- a pulse width modulated supply is possible.
- An electrically insulating material is in particular a material to be understood, having at room temperature (25 ° C), an electrical conductivity of less than 10 "1 S 1 irr 1 (possibly less than 10" 8 S 1 m "1). Accordingly, is an electrical conductor or a material (or coating) to be understood with electrical conductivity, a material that is an electrical
- Fig. 1 is a schematic front view of an inventive
- FIG. 2 is a side view of the air heater of FIG. 1;
- FIG. 2 is a side view of the air heater of FIG. 1;
- Fig. 3 is a sectional view of the heater of FIG. 1;
- FIG. 4 shows a further sectional view of the air heater according to FIG. 1.
- Fig. 1 shows a schematic front view of an electric air heater according to the invention.
- the air heater has a polymer structure 10 as well
- the polymer structure 10 has a multiplicity of fluid channels 13 which here (optionally) have a rectangular cross-section.
- the fluid channels 13 are arranged in a plurality of rows and columns (regular) (which is not mandatory).
- connection elements 14, 14a for example, terminal strips or sheet metal strips
- the connection elements 14 a connect the connection elements 14 with the contacts 11, 12.
- the air flow is schematically sketched by the arrow 15 in FIGS. 2 and 4.
- the electrical connection elements 14 are connected to one another so that an electrical connection is ensured (via the electrical contacts 11, 12).
- the polymer structure 10 is a polymer structure based on polymer having a carbon content.
- the polymer structure has a PTC behavior.
- the electrical connection elements 14 are preferably made of metal.
- the electrical supply can be effected in particular via direct current. It should be noted at this point that all parts described above, taken alone and in any combination, especially in the
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Resistance Heating (AREA)
- Air-Conditioning For Vehicles (AREA)
- Surface Heating Bodies (AREA)
- Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
- Heat-Pump Type And Storage Water Heaters (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
The invention relates to a method for producing an electric heating device, in particular a fluid or air heating device, in particular for a motor vehicle. At least one conductive polymer structure (10) comprising a polymer component and a conductive component, in particular a carbon component, is produced by primary shaping. Fluid channels (13) for conducting the fluid which is to be heated during the primary shaping process are incorporated in the polymer structure.
Description
Heizgerät und Verfahren zur Herstellung desselben Heater and method of making the same
Beschreibung description
Die Erfindung betrifft ein Heizgerät, insbesondere für ein Kraftfahrzeug, sowie ein Verfahren zur Herstellung desselben. The invention relates to a heater, in particular for a motor vehicle, and a method for producing the same.
Elektrische Heizgeräte, insbesondere Luftheizgeräte (insbesondere solche, die in mobilen Anwendungen eingesetzt werden) basieren oftmals auf keramischen Heiz-Elementen mit einem vergleichsweise stark temperaturabhängigen elektrischen Widerstand, durch den eine Selbstregelung der Wärmeabgabe ermöglicht wird . Bei diesen Widerständen handelt es sich üblicherweise um keramische PTC-Elemente (PTC für Positive Temperature Coefficient). Diese sind in der Regel mit Wärmeübertrager-Flächen aus Aluminiumblech verbunden und werden darüber auch elektrisch kontaktiert. Ein PTC-Element umfasst einen PTC- Widerstand, also einen temperaturabhängigen Widerstand mit einen positiven Temperaturkoeffizienten, der bei tiefen Temperaturen den elektrischen Strom besser leitet als bei hohen Temperaturen. Electric heaters, especially air heaters (especially those used in mobile applications) are often based on ceramic heating elements with a comparatively strong temperature-dependent electrical resistance, through which a self-regulation of the heat release is possible. These resistors are usually PTC ceramic elements (PTC for Positive Temperature Coefficient). These are usually connected to heat exchanger surfaces made of aluminum sheet and are also contacted electrically. A PTC element comprises a PTC resistor, ie a temperature-dependent resistor with a positive temperature coefficient, which conducts the electric current better at low temperatures than at high temperatures.
Nachteile von herkömmlichen Heizgeräten, insbesondere Luftheizgeräten mit Keramik-PTC-Elementen sind u.a . eine aufwändige Herstellung durch eine vergleichsweise komplizierte Wärmeübertrager-Fertigung und der Einbau der Keramik-Elemente, eine üblicherweise notwendige Sortierung der Keramik- Elemente aufgrund von Fertigungstoleranzen, eine vergleichsweise ungünstige Leistungsdichte in einem Heizelement-Wärmeübertrager-Verbund durch eine lokale Wärmeerzeugung, eine vergleichsweise starke Einschränkung einer maximalen Heizleistung durch eine Dicke des PTC-Materials (aufgrund einer begrenzten Wärmeabfuhr aus der Keramik) sowie eine vergleichsweise hohe Kurzschlussgefahr, insbesondere aufgrund eines geringen geometrischen Disadvantages of conventional heaters, in particular air heaters with ceramic PTC elements include u.a. an elaborate production by a comparatively complicated heat exchanger production and the installation of the ceramic elements, a usually necessary sorting of the ceramic elements due to manufacturing tolerances, a comparatively unfavorable power density in a heating element heat exchanger composite by a local heat generation, a relatively strong restriction a maximum heating power through a thickness of the PTC material (due to a limited heat dissipation from the ceramic) and a comparatively high risk of short circuit, in particular due to a low geometric
Abstands von Bauteilen mit einem hohen Spannungspotential. Distance of components with a high voltage potential.
Es ist Aufgabe der Erfindung, ein Verfahren zur Herstellung eines Heizgerätes, insbesondere Luft- oder Flüssigkeitsheizgerätes vorzuschlagen, wobei eine effektive Aufheizung der Fluid ermöglicht wird . Weiterhin soll ein entsprechendes Luftheizgerät vorgeschlagen werden.
Diese Aufgabe wird insbesondere durch ein Verfahren nach Anspruch 1 gelöst. It is an object of the invention to provide a method for producing a heater, in particular air or liquid heater, wherein an effective heating of the fluid is made possible. Furthermore, a corresponding air heater is to be proposed. This object is achieved in particular by a method according to claim 1.
Insbesondere wird die Aufgabe durch ein Verfahren zur Herstellung eines elektrischen Heizgerätes, vorzugsweise Flüssigkeits- oder Luftheizgerätes, vorzugsweise für ein Fahrzeug, insbesondere für ein Kraftfahrzeug, gelöst, wobei mindestens eine leitfähige Polymerstruktur, wobei die Polymerstruktur eine Polymerkomponente und eine leitfähige Komponente, insbesondere In particular, the object is achieved by a method for producing an electric heater, preferably liquid or air heater, preferably for a vehicle, in particular for a motor vehicle, wherein at least one conductive polymer structure, wherein the polymer structure is a polymer component and a conductive component, in particular
Kohlenstoffkomponente enthält, durch Urformen hergestellt wird, wobei Carbon component is produced by prototyping, wherein
Fluidkanäle (Öffnungen) zum Durchleiten des zu heizenden Fluids während der urformenden Fertigung in die Polymerstruktur eingebracht werden. Fluid channels (openings) are introduced for passing the fluid to be heated during the original manufacturing in the polymer structure.
Ein Kerngedanke der Erfindung liegt darin, eine (leitfähige) Polymerstruktur zum Aufheizen von Fluid (insbesondere Wasser, vorzugsweise Kühlwasser oder Luft, vorzugsweise Heizluft für einen Innenraum, insbesondere eines Fahrzeuges) in einem Heizgerät, vorzugsweise Flüssigkeits- oder Luftheizgerät herzustellen, wobei integrierte Öffnungen zum Durchleiten des Fluids (Fluidkanäle) während eines Urformens hergestellt bzw. eingebracht werden. Dadurch kann auf einfache und effiziente Art und Weise ein Heizgerät, vorzugsweise Flüssigkeits- oder Luftheizgerät realisiert werden, das einen effizienten Betrieb erlaubt. A central idea of the invention is to produce a (conductive) polymer structure for heating fluid (in particular water, preferably cooling water or air, preferably heating air for an interior, in particular a vehicle) in a heater, preferably liquid or air heater, wherein integrated openings for Passage of the fluid (fluid channels) are made or introduced during a primary molding. This can be realized in a simple and efficient manner, a heater, preferably liquid or air heater, which allows efficient operation.
Vorzugsweise weist die Polymerstruktur eine Vielzahl von Fluidkanälen, z. B. mehr als 10 Fluidkanälen, auf. Preferably, the polymer structure has a plurality of fluid channels, e.g. B. more than 10 fluid channels, on.
Vorzugsweise ist die Polymerstruktur als eine einstückige, insbesondere Preferably, the polymer structure is as a one-piece, in particular
monolithische, Struktur ausgebildet. monolithic, structure formed.
Es können vorzugsweise genau eine oder alternativ mehrere Polymerstrukturen vorgesehen sein. It may be preferable to provide exactly one or alternatively a plurality of polymer structures.
Das Urformen kann ein Gießen, insbesondere Spritzgießen und/oder Druckgießen, ein Pressen, insbesondere Extrudieren und/oder Pressformen, und/oder ein (Auf-) Schäumen umfassen. The master molding may include casting, in particular injection molding and / or die casting, pressing, in particular extrusion and / or compression molding, and / or foaming.
Grundsätzlich ist unter Urformen ein Fertigungsverfahren zu verstehen, bei dem aus einem formlosen bzw. verformbaren (z. B. flüssigen, pastösen, breiigen oder
plastisch verformbaren) Stoff ein (fester) Körper hergestellt wird (der In principle, prototypes are to be understood as a production process in which an informal or deformable (eg liquid, pasty, pasty or plastically deformable) fabric a (solid) body is made (the
insbesondere eine geometrisch definierte Form hat). in particular has a geometrically defined shape).
Eine Erstreckung der Polymerstruktur (in Strömungsrichtung) beträgt An extension of the polymer structure (in the flow direction) is
vorzugsweise mindestens 5 mm, weiter vorzugsweise mindestens 10 mm. preferably at least 5 mm, more preferably at least 10 mm.
Die Polymerstruktur ist vorzugsweise an sich formstabil, behält also auch ihre Form, wenn weitere Komponenten des Heizgerätes entfernt werden (bzw. noch nicht hinzugefügt worden sind bzw. bei integrierten weiteren Komponenten, wenn diese nicht vorgesehen wären, was durch Herstellung eines entsprechenden Vergleichsobjektes ohne die weiteren Komponenten festgestellt werden kann). Eine formstabile Ausführung schließt insbesondere nicht aus, dass die The polymer structure is preferably dimensionally stable in itself, thus also retains its shape when other components of the heater are removed (or have not yet been added or integrated with other components, if they were not provided, which by producing a corresponding comparison object without the other components can be determined). A dimensionally stable design does not exclude in particular that the
Polymerstruktur bei Einwirken äußerer Kräfte elastisch und/oder plastisch verformbar ist. Polymer structure when exposed to external forces elastically and / or plastically deformable.
Ein Werkzeug zum Durchführen des Urformens (z. B. Spritzwerkzeug) weist vorzugsweise entsprechend mit den Fluidkanälen korrespondierende A tool for carrying out the primary shaping (eg injection molding tool) preferably has corresponding corresponding to the fluid channels
Fertigungsstrukturen (z. B. entsprechende Vorsprünge) auf. Manufacturing structures (eg corresponding protrusions) on.
Während des Urformens kann mindestens ein elektrisches Anschlusselement, wie vorzugsweise ein Metalldraht, Metallgitter, Metallblech und/oder Metallblech- Streifen, mit der Polymerstruktur verbunden werden, vorzugsweise in die During the patterning, at least one electrical connection element, such as, preferably, a metal wire, metal mesh, metal sheet and / or sheet metal strips, may be bonded to the polymer structure, preferably into the
Polymerstruktur eingebettet werden. Unter einer Verbindung ist insbesondere eine stoffschlüssige (feste) Verbindung zu verstehen. Alternativ oder zusätzlich ist eine formschlüssige Verbindung (z. B. durch entsprechende Vorsprünge oder Ausnehmungen, die an dem Anschlusselement vorgesehen sind) vorgesehen. Unter einem Einbetten in die Polymerstruktur ist insbesondere zu verstehen, dass das mindestens eine elektrische Anschlusselement von mehr als nur einer Seite in Kontakt mit der Polymerstruktur ist bzw. dass mindestens 50 % des elektrischen Anschlusselementes von der Polymerstruktur bedeckt sind. Embedded polymer structure. Under a compound is in particular a cohesive (solid) connection to understand. Alternatively or additionally, a positive connection (eg by means of corresponding projections or recesses provided on the connection element) is provided. By embedding in the polymer structure is to be understood in particular that the at least one electrical connection element of more than one side is in contact with the polymer structure or that at least 50% of the electrical connection element are covered by the polymer structure.
Vorzugsweise wird mindestens ein (das mindestens eine) elektrische(s) Preferably, at least one (the at least one) electrical (s)
Anschlusselement vor dem Urformen, insbesondere Spritzgießen, in einem Connecting element before the primary molding, in particular injection molding, in one
Formwerkzeug, insbesondere Spritzgusswerkzeug, angeordnet (bzw. in ein solches eingelegt). Insbesondere können bereits vor dem Urformen (z. B. Mold, in particular injection molding tool, arranged (or inserted into such). In particular, even before the prototyping (eg.
Spritzgießen) in das Formwerkzeug (Spritzgießwerkzeug) Anschlussleitungen aus
Metallblech-Streifen und/oder Drähte und/oder Litzen und/oder eine Gewebe und/oder dergleichen eingelegt werden. Injection molding) into the mold (injection mold) connecting cables Sheet metal strips and / or wires and / or strands and / or a fabric and / or the like are inserted.
Die oben genannte Aufgabe wird weiterhin gelöst durch ein elektrisches Heizgerät, vorzugsweise Flüssigkeits- oder Luftheizgerät, insbesondere für ein Fahrzeug, vorzugsweise für ein Kraftfahrzeug, weiter vorzugsweise hergestellt nach dem obigen Verfahren, umfassend mindestens eine leitfähige The above object is further achieved by an electric heater, preferably liquid or air heater, in particular for a vehicle, preferably for a motor vehicle, more preferably produced by the above method, comprising at least one conductive
Polymerstruktur, wobei die Polymerstruktur eine (ggf. nicht-leitfähige) Polymer structure, wherein the polymer structure has a (possibly non-conductive)
Polymerkomponente und eine leitfähige (Füll-)Komponente, insbesondere Kohlenstoffkomponente, enthält, wobei die Polymerstruktur Fluidkanäle Polymer component and a conductive (filling) component, in particular carbon component, wherein the polymer structure fluid channels
(Öffnungen) zum Durchleiten der zu heizenden Fluid aufweist, wobei die Fluidkanäle durch Urformen während der Fertigung der Polymerstruktur eingebracht sind (was im fertigen Produkt insbesondere mittels einer (Openings) for passing the fluid to be heated, wherein the fluid channels are introduced by prototyping during the manufacture of the polymer structure (which in the finished product in particular by means of a
Untersuchung der Oberfläche von Fluidkanal-Wänden feststellbar ist). Investigation of the surface of fluid channel walls is detectable).
Das elektrische Fluidheizgerät, insbesondere Flüssigkeits- oder Luftheizgerät weist vorzugsweise mindestens ein elektrisches Anschlusselement, wie vorzugsweise einen Metalldraht, Metallgitter, Metallblech und/oder Metallblech- Streifen, auf. The electric fluid heater, in particular liquid or air heater preferably has at least one electrical connection element, such as preferably a metal wire, metal mesh, metal sheet and / or sheet metal strips on.
Die Polymerstruktur weist vorzugsweise eine Gitter-, Waben- oder Netzstruktur auf. The polymer structure preferably has a grid, honeycomb or mesh structure.
Querschnitte der Fluidkanäle in der Polymerstruktur können mindestens 5 %, vorzugsweise mindestens 10 %, weiter vorzugsweise mindestens 20 % eines Gesamt-Querschnittes der Polymerstruktur betragen. Weiterhin können Cross-sections of the fluid channels in the polymer structure may be at least 5%, preferably at least 10%, more preferably at least 20% of a total cross-section of the polymer structure. Furthermore you can
Querschnitte der Fluidkanäle in der Polymerstruktur höchstens 80 % eines Gesamt-Querschnittes der Polymerstruktur betragen. Cross sections of the fluid channels in the polymer structure amount to at most 80% of an overall cross section of the polymer structure.
Die leitfähige Komponente, insbesondere Kohlenstoffkomponente kann in Partikelform und/oder als Kohlenstoffgerüst vorliegen. The conductive component, in particular carbon component may be present in particle form and / or as a carbon skeleton.
Die leitfähige Komponente, insbesondere Kohlenstoffkomponente kann so ausgebildet bzw. angeordnet sein, dass sie einen Stromfluss erlaubt, z. B. in Partikelform (wobei sich die Partikel entsprechend berühren oder nahe beieinanderliegen) und/oder als (Kohlenstoff-)Gerüst. Die leitfähige Komponente
kann Metallpartikel und/oder -fasern umfassen. Die Kohlenstoffkomponente kann in Form von Ruß und/oder Graphit und/oder Graphen und/oder Kohlen Stoff fasern und/oder Kohlenstoff-Nanoröhren und/oder Fullerenen vorliegen. The conductive component, in particular carbon component may be formed or arranged so that it allows a flow of current, for. B. in particulate form (with the particles corresponding to touch or close together) and / or as a (carbon) scaffold. The conductive component may include metal particles and / or fibers. The carbon component may be present in the form of carbon black and / or graphite and / or graphene and / or carbon fiber fibers and / or carbon nanotubes and / or fullerenes.
Die Polymerstruktur kann eine elektrisch isolierende Polymerkomponente aufweisen. The polymer structure may comprise an electrically insulating polymer component.
Vorzugsweise umfasst die Polymerstruktur mindestens 6, weiter vorzugsweise mindestens 10, noch weiter vorzugsweise mindestens 40 Fluidkanäle. Preferably, the polymer structure comprises at least 6, more preferably at least 10, even more preferably at least 40 fluid channels.
Die oben genannte Aufgabe wird weiterhin gelöst durch ein Verfahren zum The above object is further achieved by a method for
Betreiben eines Fluidheizgerätes, insbesondere Flüssigkeits- oder Luftheizgerätes der oben beschriebenen Art oder hergestellt nach dem Verfahren der oben beschriebenen Art, wobei Fluid durch die Fluidkanäle strömt und dabei aufgeheizt wird. Operating a fluid heater, in particular liquid or air heater of the type described above or prepared by the method of the type described above, wherein fluid flows through the fluid channels and is thereby heated.
Die oben genannte Aufgabe wird weiterhin gelöst durch die Verwendung eines Fluidheizgerätes, insbesondere Flüssigkeits- oder Luftheizgerätes der oben beschriebenen Art oder hergestellt nach dem oben beschriebenen Verfahren zum Aufheizen von Luft, insbesondere in einem Fahrzeug, vorzugsweise Kraftfahrzeug, weiter vorzugsweise für einen Kraftfahrzeuginnenraum. The above object is further achieved by the use of a fluid heater, in particular liquid or air heater of the type described above or produced by the method described above for heating air, especially in a vehicle, preferably a motor vehicle, more preferably for a motor vehicle interior.
Die oben genannte Aufgabe wird weiterhin gelöst durch ein Fahrzeug umfassend ein Fluidheizgerät, insbesondere Flüssigkeits- oder Luftheizgerät der oben beschriebenen Art oder hergestellt nach dem oben beschriebenen Verfahren. The above object is further achieved by a vehicle comprising a fluid heater, in particular liquid or air heater of the type described above or produced by the method described above.
Die Polymerstruktur ist vorzugsweise eine leitfähige Struktur mit PTC-Verhalten. The polymer structure is preferably a conductive structure with PTC behavior.
Querschnitte mindestens eines oder mehrere oder aller Fluidkanäle können vieleckig, insbesondere viereckig, vorzugsweise rechteckig (weiter vorzugsweise quadratisch) oder oval, insbesondere elliptisch, vorzugsweise (kreis-)rund sein. Ein Querschnitt innerhalb eines Fluidkanals kann variieren oder konstant sein (über dessen Länge). Auch Querschnitte verschiedener Fluidkanäle können voneinander abweichen oder gleich sein.
Zum Schutz vor mechanischer Beschädigung, Feuchtigkeit und/oder Cross-sections of at least one or more or all of the fluid channels may be polygonal, in particular quadrangular, preferably rectangular (more preferably square) or oval, in particular elliptical, preferably (circular) circular. A cross section within a fluid channel may vary or be constant (over its length). Also cross sections of different fluid channels may differ or be the same. To protect against mechanical damage, moisture and / or
Kurzschlüssen kann eine Schutzschicht (Lackierung bzw. Versiegelung) auf dem gesamten Heizgerät oder zumindest freiliegenden Bereichen der Polymerstruktur vorgesehen sein. Short circuits may be provided on the entire heater or at least exposed areas of the polymer structure, a protective layer (paint or seal).
Der Begriff„leitfähig" hinsichtlich der Polymerstruktur (bzw. The term "conductive" with regard to the polymer structure (or
Kunststoffkomponente) soll als Abkürzung für„elektrisch leitfähig" verstanden werden. Plastic component) should be understood as an abbreviation for "electrically conductive".
Die Polymerstruktur kann als Polymerplatte (mit entsprechenden Öffnungen bzw. Fluidkanälen) ausgebildet sein. The polymer structure may be formed as a polymer plate (with corresponding openings or fluid channels).
Polymerkomponente und leitfähige (Kohlenstoff-)komponente sind vorzugsweise miteinander vermengt bzw. ineinander verflochten. Beispielsweise kann die Polymerkomponente ein (skelettartiges) Gerüst ausbilden, in dem die leitfähige Komponente aufgenommen ist oder umgekehrt. Polymer component and conductive (carbon) component are preferably mixed together or intertwined. For example, the polymer component can form a (skeletal) framework in which the conductive component is accommodated or vice versa.
Vorzugsweise besteht die Polymerstruktur zu mindestens Preferably, the polymer structure is at least
5 Gew.-%, vorzugsweise mindestens 10 Gew.-%, noch weiter vorzugsweise mindestens 15 Gew.-%, noch weiter vorzugsweise mindestens 20 Gew.-% und/oder weniger als 50 % aus Kohlenstoff (ggf. ohne Berücksichtigung eines Kohlenstoffanteils des Polymers als solchen) bzw. aus der 5 wt .-%, preferably at least 10 wt .-%, even more preferably at least 15 wt .-%, still more preferably at least 20 wt .-% and / or less than 50% of carbon (optionally without consideration of a carbon content of the Polymer as such) or from the
Kohlenstoffkomponente, wie z. B. den Kohlenstoffpartikeln. Carbon component, such as. B. the carbon particles.
Vorzugsweise besteht die Kohlenstoffkomponente zu mindestens 50 Gew.-%, weiter vorzugsweise mindestens 70 Gew.-% aus Kohlenstoff. Preferably, the carbon component is at least 50% by weight, more preferably at least 70% by weight of carbon.
Die Polymerkomponente ist insbesondere in Form einer elektrisch isolierenden Polymerkomponente ausgebildet. The polymer component is in particular in the form of an electrically insulating polymer component.
In Ausführungsformen kann die Polymerkomponente eine erste Polymer- Teilkomponente auf Basis von Ethylenacetat (-Copolymer) und/oder In embodiments, the polymer component may be a first polymer subcomponent based on ethylene acetate (copolymer) and / or
Ethylenacrylat (-Copolymer) aufweisen und/oder eine zweite Polymer- Teilkomponente auf Basis von Polyolefin, insbesondere Polyethylen und/oder Polypropylen, und/oder Polyester und/oder Polyamid und/oder Fluorpolymer umfassen. Der Begriff„Teilkomponente" soll hier insbesondere zur
Unterscheidung zwischen erster und zweiter Polymer-Teilkomponente verwendet werden. Die jeweilige Teilkomponente kann entweder teilweise oder auch vollständig die Polymerkomponente ausbilden. Bei dem Ethylenacrylat kann es sich um Ethyl-Methyl-Acrylat oder Ethylen-Ethyl-Acrylat handeln. Bei dem Ethylene acrylate (copolymer) and / or comprise a second polymer component based on polyolefin, in particular polyethylene and / or polypropylene, and / or polyester and / or polyamide and / or fluoropolymer. The term "subcomponent" is intended here in particular for Distinction between first and second polymer subcomponent can be used. The respective subcomponent can form either partially or completely the polymer component. The ethylene acrylate may be ethyl methyl acrylate or ethylene ethyl acrylate. In which
Ethylenacetat kann es sich um Ethylenvinylacetat handeln. Bei dem Polyethylen kann es sich um HD (High Density)-Polyethylen, MD (Medium Density)- Polyethylen, LD (Low Density)-Polyethylen, handeln. Bei dem Fluorpolymer kann es sich um PFA (Copolymer aus Tetrafluorethylen und Perfluorpropyl-Vinylester) MFA (Copolymer aus Tetrafluorethylen und Perfluorvinylester), FEP (Copolymer aus Tetrafluorethylen und Hexafluorpropylen), ETFE (Copolymer aus Ethylen und Tetrafluorethylen) oder PVDF (Polyvinyliden-Fluorid) handeln. Ethylene acetate may be ethylene vinyl acetate. The polyethylene may be high density polyethylene, medium density polyethylene, low density polyethylene. The fluoropolymer may be PFA (copolymer of tetrafluoroethylene and perfluoropropyl vinyl ester) MFA (copolymer of tetrafluoroethylene and perfluorovinyl ester), FEP (copolymer of tetrafluoroethylene and hexafluoropropylene), ETFE (copolymer of ethylene and tetrafluoroethylene) or PVDF (polyvinylidene fluoride) act.
In Ausführungsformen kann die erste Polymer-Teilkomponente, wie in In embodiments, the first polymer subcomponent, as in FIG
WO 2014/188190 AI (als first electrically insulating material) beschrieben, ausgebildet sein. Die zweite Polymer-Teilkomponente kann ebenfalls, wie in WO 2014/188190 AI (als second electrically insulating material) beschreiben, ausgebildet sein. WO 2014/188190 AI (described as a first-electrically insulating material) may be formed. The second polymer subcomponent can likewise be formed as described in WO 2014/188190 A1 (as a second-electrically insulating material).
Die Polymerstruktur bzw. die Polymerstrukturen können durch mindestens eine Metallstruktur, vorzugsweise ein (insbesondere gebogenes) Metallblech, vorzugsweise Kupferblech, und/oder Metallstreifen und/oder Metalldraht und/oder Metallgitter (elektrisch) kontaktiert sein (bzw. werden). The polymer structure or the polymer structures may be contacted by at least one metal structure, preferably a (in particular bent) metal sheet, preferably copper sheet, and / or metal strip and / or metal wire and / or metal grid (electrically).
Alternativ oder zusätzlich kann die Metallstruktur (bzw. entsprechende Alternatively or additionally, the metal structure (or corresponding
Elektroden), z. B. auf das Substrat und/oder die Polymerbeschichtung, Electrodes), z. On the substrate and / or the polymer coating,
aufgedruckt werden (und/oder durch Aufdampfen, Abscheiden und7oder be printed (and / or by vapor deposition, deposition and 7or
Beschichten aufgebracht werden). Coating be applied).
Die Polymerstruktur bzw. die Polymerstrukturen und/oder ein entsprechender auszuformender Stoff (z. B. Paste) zu deren Herstellung kann/können (als insbesondere kristallines Bindemittel) mindestens ein Polymer umfassen, vorzugsweise basierend auf mindestens einem Olefin; und/oder mindestens einem Copolymer von mindestens einem Olefin und mindestens einem Monomer, das damit copolymerisiert werden kann, z. B. Ethylen/Acrylsäure und/oder The polymer structure or the polymer structures and / or a corresponding substance to be formed (for example paste) for the production thereof may comprise (as in particular crystalline binder) at least one polymer, preferably based on at least one olefin; and / or at least one copolymer of at least one olefin and at least one monomer which can be copolymerized therewith, e.g. As ethylene / acrylic acid and / or
Ethylen/Ethylacrylat und/oder Ethylen/Vinylacetat; und/oder mindestens einem Polyalkenamer (Polyacetylen bzw. Polyalkenylen), wie z. B. Polyoctenamer;
und/oder mindestens einem, insbesondere schmelzverformbaren, Fluorpolymer, wie z. B. Polyvinylidenfluorid und/oder Copolymere davon. Ethylene / ethyl acrylate and / or ethylene / vinyl acetate; and / or at least one polyalkenamer (polyacetylene or polyalkenylene), such as. For example, polyoctenamer; and / or at least one, in particular melt-deformable, fluoropolymer, such as. As polyvinylidene fluoride and / or copolymers thereof.
Im Allgemeinen kann die Polymerstruktur bzw. eine zur Herstellung der In general, the polymer structure or one for producing the
Polymerstruktur verwendeter Stoff (Paste), wie in DE 689 23 455 T2 beschrieben, ausgebildet sein. Dies gilt insbesondere auch für deren Herstellung und/oder konkrete Zusammensetzung . Beispielsweise gilt dies auch für mögliche Polymer structure used substance (paste), as described in DE 689 23 455 T2, be formed. This applies in particular also to their production and / or specific composition. For example, this also applies to possible
Bindemittel (insbesondere gemäß S. 4, 2. Absatz und S. 5, 1. Absatz der Binders (especially according to p. 4, 2nd paragraph and p. 5, 1st paragraph of
DE 689 23 455 T2) und/oder Lösungsmittel (insbesondere gemäß S. 5, 2. Absatz und S. 6 2. Absatz der DE 689 23 455 T2). DE 689 23 455 T2) and / or solvent (in particular according to page 5, 2nd paragraph and page 6 2nd paragraph of DE 689 23 455 T2).
Bei der Polymerstruktur handelt es sich vorzugsweise um einen PTC-Widerstand . Dadurch kann eine Selbstregelung der Temperatur ermöglicht werden, was die Steuerung vereinfacht und insbesondere die Sicherheit beim Betrieb erhöht. The polymer structure is preferably a PTC resistor. Thereby, a self-regulation of the temperature can be made possible, which simplifies the control and in particular increases the safety during operation.
Durch entsprechende Wahl der Geometrie der Polymerstruktur (des By appropriate choice of the geometry of the polymer structure (the
Polymerkörpers) speziell im Hinblick auf die Fluidkanäle (Öffnungen) für das zu erwärmende Fluid, kann eine hohe Bauteil-Oberfläche realisiert werden, die aufgrund eines guten konvektiven Wärmeübergangs eine hohe Heizleistung bei geringem Bauraum ermöglicht. Polymer body) especially with regard to the fluid channels (openings) for the fluid to be heated, a high component surface can be realized, which allows a high heat output with little space due to a good convective heat transfer.
Ebenso kann durch eine entsprechende Geometrie bzw. Oberfläche von Likewise, by a corresponding geometry or surface of
metallischen Anschlusselementen (Anschlussleitungen) der elektrische Widerstand beim Übergang in die Polymerstruktur (bzw. ein Polymermaterial der metallic connecting elements (connecting lines) of the electrical resistance in the transition into the polymer structure (or a polymer material of the
Polymerstruktur) minimiert werden und die Gefahr einer Verschlechterung des Kontakts über die Lebensdauer reduziert werden. Polymer structure) are minimized and the risk of deterioration of the contact over the life can be reduced.
Zur Verbesserung eines Kontakts zwischen Polymerstruktur und elektrischen Anschlusselementen können die letzteren (z. B. durch Sandstrahlen) aufgeraut werden und/oder es können Löcher und/oder Hinterschnitte in das (jeweilige) Anschlusselement eingebracht werden. Alternativ oder zusätzlich können To improve a contact between polymer structure and electrical connection elements, the latter can be roughened (for example by sandblasting) and / or holes and / or undercuts can be introduced into the (respective) connection element. Alternatively or additionally
Drahtgewebe-, -gestricke und/oder -gewirke als Anschlusselemente vorgesehen werden.
Die Polymerstruktur kann ggf. nicht nur die Aufgabe eines Heizleiters erfüllen, sondern als (integrales) Bauteil gleichzeitig weitere Funktionen ermöglichen, insbesondere einen Rahmen oder Anschlussflächen für das Heizgerät ausbilden. Drahtgewebe-, knitted and / or -gewirke be provided as connecting elements. If necessary, the polymer structure can not only fulfill the task of a heat conductor, but at the same time enable further functions as an (integral) component, in particular forming a frame or connecting surfaces for the heater.
Insgesamt kann eine einfache, kostengünstige Herstellung durch wenige (auf einfache Art und Weise automatisierbare) Prozessschritte und mit Overall, a simple, inexpensive production by a few (easily automated) process steps and with
kostengünstigen Materialien realisiert werden. Bei geringem Bauraum-Bedarf ist eine hohe Heizleistung möglich. Das zu erwärmende Fluid erfährt insbesondere einen nur vergleichsweise geringen Druckverlust. Weiterhin kann eine hohe Flexibilität hinsichtlich der Konstruktion, insbesondere bezüglich der cost-effective materials can be realized. With low installation space requirement, a high heating capacity is possible. In particular, the fluid to be heated undergoes only a comparatively small pressure loss. Furthermore, a high flexibility in terms of construction, in particular with respect to the
Abmessungen, Versorgungsspannungen und geometrischen Abmessungen, erzielt werden. Dimensions, supply voltages and geometric dimensions can be achieved.
Das Fluidheizgerät, insbesondere Flüssigkeits- oder Luftheizgerät ist vorzugsweise für einen Betrieb im Niedervoltbereich (z. B. < 100 Volt oder < 60 Volt) ausgelegt. The fluid heater, in particular liquid or air heater is preferably designed for operation in the low-voltage range (eg <100 volts or <60 volts).
Das Heizgerät kann für den Betrieb mit Wechsel- oder Gleichstrom ausgebildet sein. Eine pulsweitenmodulierte Versorgung ist möglich. The heater can be designed for operation with alternating or direct current. A pulse width modulated supply is possible.
Unter einem elektrisch isolierenden Material ist insbesondere ein Material zu verstehen, das bei Raumtemperatur (25 °C) eine elektrische Leitfähigkeit von weniger als 10"1 S 1 irr1 (ggf. weniger als 10"8 S 1 m"1) aufweist. Entsprechend ist unter einem elektrischen Leiter bzw. einem Material (oder Beschichtung) mit elektrischer Leitfähigkeit ein Material zu verstehen, das eine elektrische An electrically insulating material is in particular a material to be understood, having at room temperature (25 ° C), an electrical conductivity of less than 10 "1 S 1 irr 1 (possibly less than 10" 8 S 1 m "1). Accordingly, is an electrical conductor or a material (or coating) to be understood with electrical conductivity, a material that is an electrical
Leitfähigkeit von vorzugsweise mindestens 10 S 1 irr1, weiter vorzugsweise mindestens 103 S 1 irr1 (bei Raumtemperatur von insbesondere 25 °C) beträgt. Conductivity of preferably at least 10 S 1 irr 1 , more preferably at least 10 3 S 1 irr 1 (at room temperature, in particular 25 ° C).
Weitere Ausführungsformen ergeben sich aus den Unteransprüchen. Further embodiments emerge from the subclaims.
Nachfolgend wird die Erfindung anhand eines Ausführungsbeispiels beschrieben, das anhand der beigefügten Figuren näher erläutert wird. Hierbei zeigen : The invention will be described with reference to an embodiment which is explained in more detail with reference to the accompanying figures. Hereby show:
Fig. 1 eine schematische Frontansicht eines erfindungsgemäßen Fig. 1 is a schematic front view of an inventive
elektrischen Luftheizgerätes;
Fig. 2 eine Seitenansicht des Luftheizgerätes gemäß Fig. 1; electric air heater; FIG. 2 is a side view of the air heater of FIG. 1; FIG.
Fig. 3 eine Schnittdarstellung des Heizgerätes gemäß Fig. 1; und Fig. 3 is a sectional view of the heater of FIG. 1; and
Fig. 4 eine weitere Schnittansicht des Luftheizgerätes gemäß Fig. 1. 4 shows a further sectional view of the air heater according to FIG. 1.
In der nachfolgenden Beschreibung werden für gleiche und gleichwirkende Teile dieselben Bezugsziffern verwendet. In the following description, the same reference numerals are used for identical and equivalent parts.
Fig. 1 zeigt eine schematische Frontansicht eines erfindungsgemäßen elektrischen Luftheizgerätes. Das Luftheizgerät weist eine Polymerstruktur 10 sowie Fig. 1 shows a schematic front view of an electric air heater according to the invention. The air heater has a polymer structure 10 as well
elektrische Kontakte 11 und 12 auf. Die Polymerstruktur 10 weist eine Vielzahl von Fluidkanälen 13 auf, die hier (optional) einen rechteckförmigen Querschnitt aufweisen. Die Fluidkanäle 13 sind in mehreren Zeilen und Spalten (regelmäßig) angeordnet (was nicht zwingend ist). electrical contacts 11 and 12. The polymer structure 10 has a multiplicity of fluid channels 13 which here (optionally) have a rectangular cross-section. The fluid channels 13 are arranged in a plurality of rows and columns (regular) (which is not mandatory).
In den Schnittansichten gemäß Fig. 3 und 4 sind elektrische Anschlusselemente 14, 14a (z. B. Anschlussleisten bzw. Blech-Streifen) vorgesehen, die in der Polymerstruktur 10 eingebettet sind (siehe auch Fig. 4). Die Anschlusselemente 14a verbinden die Anschlusselemente 14 mit den Kontakten 11, 12. 3 and 4, electrical connecting elements 14, 14a (for example, terminal strips or sheet metal strips) are provided which are embedded in the polymer structure 10 (see also FIG. 4). The connection elements 14 a connect the connection elements 14 with the contacts 11, 12.
Der Luftstrom ist durch den Pfeil 15 in Fig. 2 und 4 schematisch skizziert. The air flow is schematically sketched by the arrow 15 in FIGS. 2 and 4.
Wie weiter in Fig. 3 erkennbar, werden die elektrischen Anschlusselemente 14 (Anschlussleisten) miteinander verbunden, so dass ein elektrischer Anschluss gewährleistet ist (über die elektrischen Kontakte 11, 12). As can be seen further in FIG. 3, the electrical connection elements 14 (terminal strips) are connected to one another so that an electrical connection is ensured (via the electrical contacts 11, 12).
Bei der Polymerstruktur 10 handelt es sich um eine Polymerstruktur auf Basis von Polymer mit einem Kohlenstoffanteil. Die Polymerstruktur weist ein PTC-Verhalten auf. The polymer structure 10 is a polymer structure based on polymer having a carbon content. The polymer structure has a PTC behavior.
Die elektrischen Anschlusselemente 14 sind vorzugsweise aus Metall. Die elektrische Versorgung kann insbesondere über Gleichstrom erfolgen.
An dieser Stelle sei darauf hingewiesen, dass alle oben beschriebenen Teile für sich alleine gesehen und in jeder Kombination, insbesondere die in den The electrical connection elements 14 are preferably made of metal. The electrical supply can be effected in particular via direct current. It should be noted at this point that all parts described above, taken alone and in any combination, especially in the
Zeichnungen dargestellten Details, als erfindungswesentlich beansprucht werden. Abänderungen hiervon sind dem Fachmann geläufig. Drawings shown details are claimed as essential to the invention. Variations thereof are familiar to the person skilled in the art.
Bezugszeichenliste LIST OF REFERENCE NUMBERS
10 Polymerstruktur 10 polymer structure
11 elektrischer Kontakt 11 electrical contact
12 elektrischer Kontakt 12 electrical contact
13 Fluidkanal 13 fluid channel
14 elektrisches Anschlusselement 14 electrical connection element
15 Pfeil
15 arrow
Claims
1. Verfahren zur Herstellung eines elektrischen Heizgerätes, vorzugsweise 1. A method for producing an electric heater, preferably
Flüssigkeits- oder Luftheizgerätes, insbesondere für ein Kraftfahrzeug, wobei mindestens eine leitfähige Polymerstruktur (10), die eine Liquid or air heater, in particular for a motor vehicle, wherein at least one conductive polymer structure (10) having a
Polymerkomponente und eine leitfähige Komponente, insbesondere Polymer component and a conductive component, in particular
Kohlenstoffkomponente enthält, durch Urformen hergestellt wird, wobei Fluidkanäle (13) zum Durchleiten des zu heizenden Fluids während der urformenden Fertigung in die Polymerstruktur eingebracht werden. Carbon component is produced by prototyping, wherein fluid channels (13) are introduced for passing the fluid to be heated during the initial manufacturing in the polymer structure.
2. Verfahren nach Anspruch 1, 2. The method according to claim 1,
d a d u r c h g e ke n n z e i c h n et, dass d a d u r c h e n c i n e c e n s that
das Urformen umfasst: ein Gießen, insbesondere Spritzgießen und/oder Druckgießen, ein Pressen, insbesondere Extrudieren und/oder Pressformen, und/oder ein Schäumen. the primary molding comprises: casting, in particular injection molding and / or die casting, pressing, in particular extrusion and / or compression molding, and / or foaming.
3. Verfahren nach Anspruch 1 oder 2, 3. The method according to claim 1 or 2,
d a d u r c h g e ke n n z e i c h n et, dass d a d u r c h e n c i n e c e n s that
während des Urformens mindestens ein elektrisches Anschlusselement (14), wie vorzugsweise ein Metalldraht, (Metall-)Gitter, (Metall-)Leiste, at least one electrical connection element (14), such as preferably a metal wire, (metal) grid, (metal) strip, during the patterning,
Metallblech und/oder Metallblech-Streifen, mit der Polymerstruktur verbunden wird/werden, vorzugsweise in die Polymerstruktur eingebettet wird/werden. Metal sheet and / or sheet metal strip, is / are connected to the polymer structure, preferably embedded in the polymer structure / are.
4. Verfahren nach einem der vorhergehenden Ansprüche, 4. The method according to any one of the preceding claims,
d a d u r c h g e ke n n z e i c h n e t, dass d a d u r c h e n c i n e s that
mindestens ein/das mindestens eine elektrische(s) Anschlusselement (14) vor dem Urformen, insbesondere Spritzgießen in einem Formwerkzeug, insbesondere Spritzgusswerkzeug, angeordnet wird. at least one / the at least one electrical (s) connection element (14) prior to the primary molding, in particular injection molding in a mold, in particular injection molding tool, is arranged.
5. Verfahren nach einem der vorhergehenden Ansprüche, 5. The method according to any one of the preceding claims,
d a d u r c h g e ke n n z e i c h n e t, dass d a d u r c h e n c i n e s that
die Polymerstruktur (10) eine Gitter-, Waben- oder Netzstruktur ausbildet. the polymer structure (10) forms a grid, honeycomb or mesh structure.
6. Elektrisches Heizgerät, insbesondere Flüssigkeits- oder Luftheizgerät, 6. Electric heater, in particular liquid or air heater,
insbesondere für ein Kraftfahrzeug, vorzugsweise hergestellt nach einem der
vorhergehenden Ansprüche, umfassend mindestens eine leitfähige in particular for a motor vehicle, preferably manufactured according to one of preceding claims, comprising at least one conductive
Polymerstruktur (10), wobei die Polymerstruktur (10) eine Polymer structure (10), wherein the polymer structure (10) a
Polymerkomponente und eine Kohlenstoffkomponente enthält, wobei die Polymerstruktur Fluidkanäle (13) zum Durchleiten des zu heizenden Fluids aufweist, wobei die Fluidkanäle durch urformende Fertigung der Polymer component and a carbon component, wherein the polymer structure has fluid channels (13) for passing the fluid to be heated, wherein the fluid channels by forming the primitive
Polymerstruktur eingebracht sind. Polymer structure are introduced.
7. Heizgerät nach Anspruch 6, 7. Heater according to claim 6,
d a d u rch g e ke n n ze i c h n et, dass, d a d u rch e ke n ze i c h n et that,
mindestens ein elektrisches Anschlusselement (14), wie vorzugsweise ein Metalldraht, (Metall-)Gitter, (Metall-)Leiste, Metallblech und/oder at least one electrical connection element (14), such as preferably a metal wire, (metal) grid, (metal) strip, sheet metal and / or
Metallblech-Streifen, mit der Polymerstruktur verbunden, vorzugsweise in die Polymerstruktur eingebettet ist. Sheet metal strip bonded to the polymer structure, preferably embedded in the polymer structure.
8. Heizgerät nach Anspruch 6 oder 7, 8. Heater according to claim 6 or 7,
d a d u rch g e ke n n ze i c h n et, dass d a d u rch e ke n ze i c h n et that
die Polymerstruktur eine Gitter-, Waben- oder Netzstruktur umfasst. the polymer structure comprises a grid, honeycomb or mesh structure.
9. Heizgerät nach einem der vorhergehenden Ansprüche 6 bis 8, 9. Heater according to one of the preceding claims 6 to 8,
d a d u rch g e ke n n ze i c h n et, dass d a d u rch e ke n ze i c h n et that
Querschnitte der Fluidkanäle in der Polymerstruktur (10) mindestens 5 %, vorzugsweise mindestens 10 %, weiter vorzugsweise mindestens 20 % betragen und/oder höchstens 80 % eines Gesamt-Querschnittes der Polymerstruktur betragen. Cross sections of the fluid channels in the polymer structure (10) amount to at least 5%, preferably at least 10%, more preferably at least 20% and / or at most 80% of a total cross-section of the polymer structure.
10. Heizgerät nach einem der vorhergehenden Ansprüche 6 bis 9, 10. Heater according to one of the preceding claims 6 to 9,
d a d u rch g e ke n n ze i c h n et, dass d a d u rch e ke n ze i c h n et that
die Kohlenstoffkomponente in Partikelform und/oder als Kohlenstoffgerüst vorliegt und/oder the carbon component is present in particulate form and / or as a carbon skeleton and / or
in Form von Ruß und/oder Graphit und/oder Graphen und/oder in the form of carbon black and / or graphite and / or graphene and / or
Kohlen stoff fasern und/oder Kohlenstoff-Nanoröhren vorliegt. Carbon fiber and / or carbon nanotubes is present.
11. Heizgerät nach einem der vorhergehenden Ansprüche 6 bis 10, 11. Heating device according to one of the preceding claims 6 to 10,
d a d u rc h g e ke n n ze i c h n et, dass d a d u rc h e ke n ze i c h n et that
die Polymerstruktur (10) eine elektrische isolierende Polymerkomponente aufweist.
the polymer structure (10) comprises an electrical insulating polymer component.
12. Heizgerät nach einem der vorhergehenden Ansprüche 5 bis 11, 12. Heating device according to one of the preceding claims 5 to 11,
d a d u r c h g e ke n n z e i c h n e t, dass d a d u r c h e n c i n e s that
die Polymerstruktur (10) mindestens 6, vorzugsweise mindestens 10, weiter vorzugsweise mindestens 40 Fluidkanäle umfasst. the polymer structure (10) comprises at least 6, preferably at least 10, more preferably at least 40 fluid channels.
13. Verfahren zum Betreiben eines Heizgerätes nach einem der Ansprüche 6 bis 12 oder hergestellt nach einem der Ansprüche 1 bis 5, wobei Fluid, insbesondere eine Flüssigkeit oder Luft durch die Fluidkanäle (13) strömt und dabei aufgeheizt wird. 13. A method for operating a heater according to any one of claims 6 to 12 or prepared according to any one of claims 1 to 5, wherein fluid, in particular a liquid or air flows through the fluid channels (13) and is heated.
14. Verwendung eines Heizgerätes nach einem der Ansprüche 6 bis 12 oder hergestellt nach einem der Ansprüche 1 bis 5 zum Aufheizen eines Fluids, insbesondere einer Flüssigkeit, vorzugsweise Wasser oder von Luft, insbesondere in einem Kraftfahrzeug, vorzugsweise für einen 14. Use of a heater according to one of claims 6 to 12 or produced according to one of claims 1 to 5 for heating a fluid, in particular a liquid, preferably water or air, in particular in a motor vehicle, preferably for a
Kraftfahrzeug innenraum.
Motor vehicle interior.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102017111378 | 2017-05-24 | ||
DE102017111373 | 2017-05-24 | ||
DE102017115148 | 2017-07-06 | ||
DE102017121041.5A DE102017121041A1 (en) | 2017-05-24 | 2017-09-12 | Heater and method of making the same |
PCT/EP2018/063508 WO2018215541A1 (en) | 2017-05-24 | 2018-05-23 | Heating device and method for production thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
EP3631318A1 true EP3631318A1 (en) | 2020-04-08 |
Family
ID=64109087
Family Applications (10)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18727167.1A Withdrawn EP3631312A1 (en) | 2017-05-24 | 2018-05-08 | Air heating device |
EP18727168.9A Withdrawn EP3631313A1 (en) | 2017-05-24 | 2018-05-08 | Air heating device for a vehicle |
EP18728811.3A Withdrawn EP3631314A1 (en) | 2017-05-24 | 2018-05-23 | Heating conductor and heating device |
EP18728816.2A Withdrawn EP3630513A1 (en) | 2017-05-24 | 2018-05-23 | Electric heating device |
EP18728818.8A Withdrawn EP3631319A1 (en) | 2017-05-24 | 2018-05-23 | Liquid heating appliance, particularly water heating appliance |
EP18728814.7A Withdrawn EP3631317A1 (en) | 2017-05-24 | 2018-05-23 | Electric heating device, method for producing, operating and using said type of device |
EP18728813.9A Withdrawn EP3631316A1 (en) | 2017-05-24 | 2018-05-23 | Electric liquid-heating device, and use of same and of a heat conductor |
EP18728815.4A Withdrawn EP3631318A1 (en) | 2017-05-24 | 2018-05-23 | Heating device and method for production thereof |
EP18728812.1A Withdrawn EP3631315A1 (en) | 2017-05-24 | 2018-05-23 | Heating device and method for production thereof, method for the operation and use thereof |
EP18728826.1A Withdrawn EP3631320A1 (en) | 2017-05-24 | 2018-05-24 | Fluid heating device and method for the production thereof |
Family Applications Before (7)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18727167.1A Withdrawn EP3631312A1 (en) | 2017-05-24 | 2018-05-08 | Air heating device |
EP18727168.9A Withdrawn EP3631313A1 (en) | 2017-05-24 | 2018-05-08 | Air heating device for a vehicle |
EP18728811.3A Withdrawn EP3631314A1 (en) | 2017-05-24 | 2018-05-23 | Heating conductor and heating device |
EP18728816.2A Withdrawn EP3630513A1 (en) | 2017-05-24 | 2018-05-23 | Electric heating device |
EP18728818.8A Withdrawn EP3631319A1 (en) | 2017-05-24 | 2018-05-23 | Liquid heating appliance, particularly water heating appliance |
EP18728814.7A Withdrawn EP3631317A1 (en) | 2017-05-24 | 2018-05-23 | Electric heating device, method for producing, operating and using said type of device |
EP18728813.9A Withdrawn EP3631316A1 (en) | 2017-05-24 | 2018-05-23 | Electric liquid-heating device, and use of same and of a heat conductor |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP18728812.1A Withdrawn EP3631315A1 (en) | 2017-05-24 | 2018-05-23 | Heating device and method for production thereof, method for the operation and use thereof |
EP18728826.1A Withdrawn EP3631320A1 (en) | 2017-05-24 | 2018-05-24 | Fluid heating device and method for the production thereof |
Country Status (7)
Country | Link |
---|---|
US (9) | US20200224926A1 (en) |
EP (10) | EP3631312A1 (en) |
JP (4) | JP2020521291A (en) |
KR (3) | KR20190139282A (en) |
CN (9) | CN110678705A (en) |
DE (10) | DE102017121063A1 (en) |
WO (12) | WO2018215197A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102017121063A1 (en) * | 2017-05-24 | 2018-11-29 | Webasto SE | Heating conductor and heater |
US10969141B2 (en) * | 2018-03-13 | 2021-04-06 | Ngb Innovations Llc | Regulating temperature and reducing buildup in a water heating system |
DE102019202543A1 (en) * | 2019-02-26 | 2020-08-27 | Eberspächer Catem Gmbh & Co. Kg | PTC heating element and electrical heating device with such a PTC heating element |
DE102019113518A1 (en) | 2019-05-21 | 2020-11-26 | Dbk David + Baader Gmbh | Fluid heater and process for its manufacture |
CN110435385B (en) * | 2019-07-10 | 2024-05-10 | 芜湖汉特威电热科技有限公司 | Mixed heater warm air core for new energy automobile air conditioner |
EP4090705A4 (en) * | 2020-01-14 | 2023-10-18 | Evonik Specialty Chemicals (Shanghai) Co., Ltd. | Polymer composition comprising graphene |
DE102020113124A1 (en) * | 2020-05-14 | 2021-11-18 | Eberspächer catem Hermsdorf GmbH & Co. KG | PTC heating cell and process for its manufacture |
DE102020123131A1 (en) | 2020-09-04 | 2022-03-10 | Dbk David + Baader Gmbh | fluid heater |
DE102021103480A1 (en) * | 2021-02-15 | 2022-08-18 | Tdk Electronics Ag | PTC heating element, electric heating device and use of a PTC heating element |
KR102412198B1 (en) * | 2021-03-23 | 2022-06-23 | 엘에스자기장보일러 주식회사 | Heating apparatus for boiler |
Family Cites Families (101)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3163841A (en) * | 1962-01-02 | 1964-12-29 | Corning Glass Works | Electric resistance heater |
US3501619A (en) * | 1965-07-15 | 1970-03-17 | Texas Instruments Inc | Self-regulating thermal apparatus |
US3459924A (en) * | 1968-09-25 | 1969-08-05 | Dow Chemical Co | Electrical open cell heating element |
US3666924A (en) * | 1970-11-16 | 1972-05-30 | Westinghouse Electric Corp | Electric resistance convection heater |
US3965047A (en) * | 1971-07-20 | 1976-06-22 | Ernest K. Cleland | Electrical resistant fluid-permeable heat generating member and method of producing the same |
DE2305105B2 (en) * | 1973-02-02 | 1978-05-03 | Sigri Elektrographit Gmbh, 8901 Meitingen | Porous heating element |
JPS5221630Y2 (en) * | 1973-04-18 | 1977-05-18 | ||
DE2519623A1 (en) * | 1975-05-02 | 1976-11-11 | Peter Christian Dipl Kalischer | Continuous flow electrical water heater - has conducting plastic heating element which exhibits sudden change in resistance at specified temp. |
JPS5553100Y2 (en) * | 1975-11-07 | 1980-12-09 | ||
ES454025A1 (en) * | 1975-12-08 | 1977-11-16 | Raychem Corp | Expansible heater |
JPS60145594U (en) * | 1984-03-02 | 1985-09-27 | 東京コスモス電機株式会社 | Resistor element for planar heating element |
US4882466A (en) * | 1988-05-03 | 1989-11-21 | Raychem Corporation | Electrical devices comprising conductive polymers |
US5057673A (en) * | 1988-05-19 | 1991-10-15 | Fluorocarbon Company | Self-current-limiting devices and method of making same |
CN2036340U (en) * | 1988-06-25 | 1989-04-19 | 辽宁省日用电器研究所 | Heat exchanger with positive temp. coefficient thermalsensitive resistor as heating body |
US5093036A (en) * | 1988-09-20 | 1992-03-03 | Raychem Corporation | Conductive polymer composition |
CN2067056U (en) * | 1990-03-31 | 1990-12-05 | 中国科学院上海硅酸盐所 | Positive temp. coefficient thermal ceramic (ptc) heating device for heat gun |
US5245161A (en) * | 1990-08-31 | 1993-09-14 | Tokyo Kogyo Boyeki Shokai, Ltd. | Electric heater |
US5344591A (en) * | 1990-11-08 | 1994-09-06 | Smuckler Jack H | Self-regulating laminar heating device and method of forming same |
DE4213510C1 (en) * | 1992-04-24 | 1993-08-19 | Audi Ag, 8070 Ingolstadt, De | Electric heating arrangement in vehicle heating and ventilation system - is formed by grill located in air outlet and moulded in conductive polymer |
CN2230894Y (en) * | 1995-06-08 | 1996-07-10 | 尹继新 | Electric fluid heater |
JPH09184771A (en) * | 1995-12-28 | 1997-07-15 | Mikuni Corp | Sensor for detecting overheat of hot-water supply device |
JPH09213455A (en) * | 1996-02-05 | 1997-08-15 | Kyocera Corp | Power feeding structure of wafer holding device |
US6236302B1 (en) * | 1998-03-05 | 2001-05-22 | Bourns, Inc. | Multilayer conductive polymer device and method of manufacturing same |
US6194692B1 (en) * | 1998-10-02 | 2001-02-27 | Engelhard Corporation | Electric heating sheet and method of making the same |
US6299801B1 (en) * | 1998-11-02 | 2001-10-09 | Tdk Corporation | Organic positive temperature coefficient thermistor |
CN2362037Y (en) * | 1998-12-09 | 2000-02-02 | 杨广斌 | Liquid pipeline heater |
JP2000252044A (en) * | 1999-03-02 | 2000-09-14 | Hitachi Cable Ltd | Plane-like heater and its manufacture |
TW487742B (en) * | 1999-05-10 | 2002-05-21 | Matsushita Electric Ind Co Ltd | Electrode for PTC thermistor, manufacture thereof, and PTC thermistor |
JP2001035640A (en) * | 1999-07-16 | 2001-02-09 | Tokin Corp | Ptc element and its manufacture |
US6288372B1 (en) * | 1999-11-03 | 2001-09-11 | Tyco Electronics Corporation | Electric cable having braidless polymeric ground plane providing fault detection |
AU2001230551A1 (en) * | 2000-02-01 | 2001-08-14 | Ube Industries Ltd. | Conductive polymer composition and ptc element |
IT249474Y1 (en) * | 2000-02-17 | 2003-05-19 | Eltek Spa | ELECTRIC RADIATOR. |
KR100352892B1 (en) * | 2000-05-22 | 2002-09-16 | 주식회사 팍스텍 | Method for manufacturing thin film heating material and heating device thereof |
CN100409373C (en) * | 2001-04-06 | 2008-08-06 | 宝电通科技股份有限公司 | Composite structural material for thermosensitive resistor with positive temp coefficient and its preparing process |
US6957013B2 (en) * | 2001-06-08 | 2005-10-18 | Algas-Sdi International Llc | Fluid heater |
DE10201262B4 (en) * | 2002-01-15 | 2006-09-07 | Webasto Ag | resistance |
JP2003317906A (en) * | 2002-04-24 | 2003-11-07 | Sumitomo Electric Ind Ltd | Ceramic heater |
EP1407907B1 (en) * | 2002-10-07 | 2007-02-28 | Behr GmbH & Co. KG | Heat exchange device |
ITPN20020086A1 (en) * | 2002-11-07 | 2004-05-08 | Irca Spa | CONDUCT WITH PERFECTED ELECTRIC RESISTANCE E |
EP1432287B1 (en) * | 2002-12-19 | 2006-06-21 | Catem GmbH & Co.KG | Electrical heating device with housing |
JP2004273227A (en) * | 2003-03-07 | 2004-09-30 | Kawaguchi Gosei Kk | Planar heating element |
ATE385470T1 (en) * | 2003-03-13 | 2008-02-15 | Behr Gmbh & Co Kg | ELECTRIC HEATING DEVICE, PARTICULARLY FOR A MOTOR VEHICLE |
JP2005001447A (en) * | 2003-06-10 | 2005-01-06 | Denso Corp | Electric heater, heat exchanger for heating and vehicular air conditioner |
FR2859866B1 (en) * | 2003-09-11 | 2006-03-24 | Valeo Climatisation | HEAT RESISTIVE ELEMENT AND HEATING ASSEMBLY COMPRISING THIS ELEMENT |
DE502004005690D1 (en) * | 2003-10-31 | 2008-01-24 | Behr Gmbh & Co Kg | Electrically heatable plastic matrix |
DE102004020821A1 (en) * | 2004-04-28 | 2005-11-24 | BSH Bosch und Siemens Hausgeräte GmbH | Tubular electric heating element for warm water has winding between two parallel end sections and is bent in only one curved direction |
KR20060018174A (en) * | 2004-08-23 | 2006-02-28 | 한라공조주식회사 | Auxiliary heater |
CN2861852Y (en) * | 2005-09-24 | 2007-01-24 | 朱祥 | Heater for petroleum |
KR100749886B1 (en) * | 2006-02-03 | 2007-08-21 | (주) 나노텍 | Heating element using Carbon Nano tube |
EP1839920B1 (en) * | 2006-03-31 | 2013-02-13 | Behr GmbH & Co. KG | Electrical Heater for a vehicle air conditioning system |
EP1912028B1 (en) * | 2006-10-11 | 2016-03-30 | Mahle Behr France Rouffach S.A.S | Electric heating means, specially for an automobile |
EP1933597B1 (en) * | 2006-12-11 | 2014-02-26 | Behr GmbH & Co. KG | Electrical heater or supplementary heater, in particular for a heating or air conditioning assembly of a vehicle |
EP1933598B1 (en) * | 2006-12-11 | 2013-11-13 | Behr GmbH & Co. KG | Electrical heater or supplementary heater, in particular for a heating or air conditioning assembly of a vehicle |
EP2017546B1 (en) * | 2007-07-18 | 2016-04-13 | Eberspächer catem GmbH & Co. KG | Method for manufacturing an electrical heating device and electrical heating device |
KR100880773B1 (en) * | 2008-01-23 | 2009-02-02 | (주) 씨엠테크 | A heating unit for fluid |
EP2109347B1 (en) * | 2008-04-11 | 2015-03-11 | Behr GmbH & Co. KG | Electric device for heating, in particular a motor vehicle |
EP2131117B1 (en) * | 2008-06-04 | 2016-02-10 | Mahle Behr France Rouffach S.A.S | Motor vehicle air conditioning with PTC heating device |
CN201230379Y (en) * | 2008-07-16 | 2009-04-29 | 苏伟锋 | PTC heating element |
US8716633B2 (en) | 2009-10-13 | 2014-05-06 | Uniplatek Co., Ltd. | Method for manufacturing PTC device and system for preventing overheating of planar heaters using the same |
US20110110652A1 (en) * | 2009-11-09 | 2011-05-12 | Technical Analysis & Services International, Inc. (TASI) | Active air heater |
DE102009057749A1 (en) * | 2009-12-10 | 2011-06-16 | Dbk David + Baader Gmbh | Radiator element for heater, has multiple radiator profile segments with two parallel shanks, where middle part forming radiator surface extends between shanks |
CN201639793U (en) * | 2010-03-30 | 2010-11-17 | 东莞宏威数码机械有限公司 | Flat plate stack-up type heating device |
DE102010033092A1 (en) * | 2010-08-02 | 2012-02-02 | Osram Opto Semiconductors Gmbh | Optoelectronic light module and car headlights |
DE102010033309A1 (en) * | 2010-08-04 | 2012-02-09 | Ingo Schehr | Heat exchanger fins module, heat exchanger and electric heating module |
DE102010037132A1 (en) * | 2010-08-24 | 2012-03-01 | Webasto Ag | Electric vehicle heater |
EP2428747B1 (en) * | 2010-09-13 | 2015-04-08 | MAHLE Behr GmbH & Co. KG | Heat exchanger |
DE102011075383A1 (en) * | 2011-05-06 | 2012-11-08 | Evonik Degussa Gmbh | Temperable pipeline for offshore applications |
CN102833896A (en) * | 2011-06-15 | 2012-12-19 | 上海华族实业有限公司 | Electric heater based on Internet of Things for communication and fixed by compression joint |
DE102011077922B4 (en) * | 2011-06-21 | 2024-10-10 | Mahle International Gmbh | heat exchanger |
FR2981437B1 (en) * | 2011-10-14 | 2018-04-27 | Valeo Systemes Thermiques | ISOLATED HEATING MODULE FOR ADDITIONAL HEATING DEVICE |
DE102011054752B4 (en) * | 2011-10-24 | 2014-09-04 | Stego-Holding Gmbh | Cooling and holding body for heating elements, heater and method for producing a cooling and holding body |
CN202475806U (en) * | 2011-11-09 | 2012-10-03 | 芜湖华族实业有限公司 | Radiating fin clamping type ceramic PTC electric heater |
DE102011121451B4 (en) * | 2011-12-16 | 2023-02-02 | Audi Ag | Heating device for a motor vehicle and a motor vehicle with such a heating device and a method for producing such a heating device |
DE102011057108A1 (en) * | 2011-12-28 | 2013-07-04 | Webasto Ag | Electrical heating device for engine-driven road vehicle, has heating conductor electrically insulated opposite to substrate, and heat shield component extending over part of surface of conductor on side that is formed opposite to substrate |
DE112013001177T5 (en) * | 2012-02-28 | 2014-11-13 | Halla Visteon Climate Control Corp. | car heater |
CN202551366U (en) * | 2012-03-28 | 2012-11-21 | 熊欣 | PTC automobile liquid heater |
DE102012207301A1 (en) * | 2012-05-02 | 2013-11-07 | Webasto Ag | A heating device for a vehicle and method for cooling an electronic control device of the heating device |
KR20150013764A (en) * | 2012-05-14 | 2015-02-05 | 베르-헬라 테르모콘트롤 게엠베하 | Electrical vehicle heater, in particular for vehicles having a hybrid drive or having an electric drive |
CN202648155U (en) * | 2012-05-25 | 2013-01-02 | 比亚迪股份有限公司 | Shell of electric heating device, electric heating device and electric vehicle |
DE102012211173A1 (en) * | 2012-06-28 | 2014-01-16 | BSH Bosch und Siemens Hausgeräte GmbH | household appliance |
CN202764656U (en) * | 2012-09-11 | 2013-03-06 | 钡泰电子陶瓷股份有限公司 | Heater used in vehicle |
EP3524900B1 (en) * | 2013-01-29 | 2023-08-30 | Hanon Systems | Heater for motor vehicle |
WO2014188191A1 (en) | 2013-05-21 | 2014-11-27 | Heat Trace Limited | Electrical heater |
LU92270B1 (en) * | 2013-08-22 | 2015-02-23 | Iee Sarl | Foil heater eg for a heating panel |
DE102013021079B4 (en) * | 2013-12-18 | 2016-03-03 | Lisa Dräxlmaier GmbH | Heating device for a vehicle |
JP2016002998A (en) * | 2014-06-19 | 2016-01-12 | 現代自動車株式会社Hyundaimotor Company | Vehicle hybrid heater |
GB201413136D0 (en) * | 2014-07-24 | 2014-09-10 | Lmk Thermosafe Ltd | Conductive polymer composite |
CN204119542U (en) * | 2014-09-24 | 2015-01-21 | 上海荣威塑胶工业有限公司 | A kind of ptc heater |
CN204329292U (en) * | 2014-12-10 | 2015-05-13 | 王锦玲 | A kind of thick film heating device |
KR101664372B1 (en) * | 2015-01-08 | 2016-10-10 | 전병민 | Plane heater with waterproof and dampproof function |
FR3032084B1 (en) * | 2015-01-28 | 2017-02-10 | Commissariat Energie Atomique | HEATING DEVICE, PARTICULARLY SEMI-TRANSPARENT |
CN105313639B (en) * | 2015-07-16 | 2018-04-24 | 浙江吉利控股集团有限公司 | A kind of electric automobile air conditioner silica gel heating film heater |
CN110730519A (en) * | 2015-08-03 | 2020-01-24 | 深圳山源电器股份有限公司 | Heat dissipation base member and canned type PTC thermistor heater |
CN205208945U (en) * | 2015-11-06 | 2016-05-04 | 武汉商学院 | Spiral PTC fluid heater |
CN105509305B (en) * | 2015-12-28 | 2018-02-27 | 安徽农业大学 | A kind of PTC water heaters of air conditioning for automobiles heating |
CN106247611A (en) * | 2016-08-11 | 2016-12-21 | 安徽中科自动化股份有限公司 | A kind of water heater |
US20180124871A1 (en) * | 2016-10-31 | 2018-05-03 | Gentherm Gmbh | Carbon veil heater and method of making |
CN106595023A (en) * | 2016-12-16 | 2017-04-26 | 宁波勃兰特泵业科技有限公司 | Energy-saving environment-friendly type heater |
US20180267296A1 (en) * | 2017-03-20 | 2018-09-20 | Delphi Technologies, Inc. | Electrically conductive polymer film |
DE102017121063A1 (en) * | 2017-05-24 | 2018-11-29 | Webasto SE | Heating conductor and heater |
DE102019118092A1 (en) * | 2019-07-04 | 2021-01-07 | Carl Freudenberg Kg | Process for the production of a component shielded from electromagnetic radiation |
-
2017
- 2017-09-12 DE DE102017121063.6A patent/DE102017121063A1/en not_active Withdrawn
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