EP3621432A1 - Supports dégradables marins - Google Patents

Supports dégradables marins

Info

Publication number
EP3621432A1
EP3621432A1 EP18729534.0A EP18729534A EP3621432A1 EP 3621432 A1 EP3621432 A1 EP 3621432A1 EP 18729534 A EP18729534 A EP 18729534A EP 3621432 A1 EP3621432 A1 EP 3621432A1
Authority
EP
European Patent Office
Prior art keywords
marine
culture
rope
fibre
ropes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP18729534.0A
Other languages
German (de)
English (en)
Inventor
Marina Crnoja-Cosic
Robert Malinowsky
Thomas Richard Burrow
Berndt KÖLL
James Martin Taylor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lenzing AG
Original Assignee
Lenzing AG
Chemiefaser Lenzing AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lenzing AG, Chemiefaser Lenzing AG filed Critical Lenzing AG
Publication of EP3621432A1 publication Critical patent/EP3621432A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00—Culture of aquatic animals
    • A01K61/50—Culture of aquatic animals of shellfish
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00—Culture of aquatic animals
    • A01K61/50—Culture of aquatic animals of shellfish
    • A01K61/54—Culture of aquatic animals of shellfish of bivalves, e.g. oysters or mussels
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B5/00—Making ropes or cables from special materials or of particular form
    • D07B5/06—Making ropes or cables from special materials or of particular form from natural or artificial staple fibres
    • D—TEXTILES; PAPER
    • D07—ROPES; CABLES OTHER THAN ELECTRIC
    • D07B—ROPES OR CABLES IN GENERAL
    • D07B2501/00—Application field
    • D07B2501/20—Application field related to ropes or cables
    • D07B2501/2038—Agriculture, forestry and fishery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81—Aquaculture, e.g. of fish

Definitions

  • This invention describes the use of man- made ce!lulosic fibres, in particular !yocefl and modal for the construction of ropes, nets and meshes for use as supports for the cultivation of marine cultures such as molluscs, particularly mussels and edible seaweed.
  • the key properties are that the supports are of sufficient strength to carry the weights of the growing cultures without breakage yet are marine biodegradable after use.
  • Synthetic fibres and plastics lost to the oceans account for 80% of all marine pollution and apart from the danger posed to marine life can enter the human food chain through being ingested by fish etc.
  • the marine biodegradability of the supports made from modal and iyocell remove this risk even if the supports are unintentionally lost.
  • the world mussel production is in excess of 2 million tonnes and is either by on-bottom or off-bottom culture.
  • the on-bottom culture system is also called the broadcast technique.
  • the off bottom culture system includes stake or pole method, rack, raft and long line. These systems are also called the hanging or suspended culture techniques and are particularly relevant to the invention.
  • Nylon and polypropylene are most commonly used for the rope material (12mm thick) and because they are not biodegradable can typically be used for 4 seasons. Synthetic ropes are durable and are of sufficient strength to hold the full weight of the fully grown mussels, but are not sustainable nor marine biodegradable, so pose a risk to sealife if lost.
  • Continuous filament yams are widely used in the textile industry to produce fabrics with a distinct character compared to fabrics produced from yarns made using staple fibre.
  • a continuous filament yam is one in which all of the fibres are continuous throughout any length of the yarn.
  • a continuous filament yam will commonly consist of 20 to 200 or more individual fibres which are ail parallel to each other and the axis of the yam when produced. The yam is produced by extruding a solution or melt of a polymer or a polymer derivative and then winding the yarn produced onto a bobbin or reel or by forming a cake by centrifugal winding.
  • Synthetic polymer continuous filament yarns are common.
  • nylon, polyester and polypropylene continuous filament yams are used in a wide variety of fabrics. They are produced by melt spinning a molten polymer through a spinneret with a number of holes corresponding to the number of fibres required in the yarn produced. After the molten polymer has started to solidify, the yarn may be drawn to orient the polymer molecules and improve the properties of the yarn.
  • rope suitable for use as a support and growth medium for marine organisms which comprises at least one man-made cellulosic yarn, preferably made from modal or lyoceii fibres, most preferably made from lyocell fibres.
  • the term "rope” includes the definition of a twine as well.
  • the term "fiber” for the purposes of the present invention shall include staple fibers as well as continuous filaments.
  • Viscose fibre is produced by extruding a solution of a cellulose derivative through very small spinneret holes and then precipitating by changing the pH and by converting the derivative back to cellulose.
  • Cellulose as wood pulp is usually used as the starting materia! although other sources of cellulose such as bamboo and cotton linters are also used.
  • the wood pulp is steeped in sodium hydroxide and then reacted with carbon disulphide to convert it to cellulose xanthate.
  • the xanthate is dissolved in a sodium hydroxide solution to yield a viscous, golden coloured liquid which is commonly called viscose.
  • the viscose is de-aerated and filtered. It is then extruded through precious metal spinnerets into a spinbath consisting of sulphuric acid, sodium sulphate and zinc sulphate.
  • the acid reacts with the sodium hydroxide in the viscose to cause precipitation of the cellulose xanthate.
  • the acid also reacts with the cellulose xanthate converting it back to cellulose.
  • the fibre While the newly formed fibre is still in a plastic state it is stretched to increase the orientation of the cellulose molecules with the axis of the fibre and encourage crystallisation.
  • the fibre may then be cut into lengths to form staple fibre or it may be kept as continuous filament or tow depending on the design of the spinning machine and the product required.
  • the fibre is washed to remove non-cellulose products of the reaction such as sodium sulphate and hydrogen sulphide, finished with lubricants and anti-stats to aid downstream processing and dried.
  • non-cellulose products of the reaction such as sodium sulphate and hydrogen sulphide
  • Modern viscose plants are designed to recover as much of the by-products of the process as possible. This is essential to avoid environmental pollution and to ensure the safety of the workforce and surrounding community. Better recovery and recycling of by-products can also give a positive economic benefit.
  • Viscose is not seen as appropriate for the invention as it has low wet strength and low wet modulus leading to high wet elongation.
  • Modal fibre is a high wet modulus fibre produced using a modified version of the viscose process.
  • An additive is mixed with the spinning solution which slows down the regeneration of the cellulose during spinning. Together with modified spinbath and viscose composition, the additive allows the fibre to be stretched to a much greater extent than normal viscose. This gives a fibre with a higher orientation which is stronger than viscose and has a modulus closer to that of cotton.
  • Modal fibre is often used in blend with cotton to give softer fabrics than would be made with cotton aione. It is used widely in knitted fabrics for lingerie and ladies apparel.
  • a pulp mill and the viscose and modal production are linked together so that undried wood pulp is fed directly to the viscose making stage.
  • the non-ceilulosic parts of the wood used in the pulp mill are incinerated and used to generate the power used by the pulp mill and most of the power for the viscose and modal process. Further chemicals are recovered before incineration such as acetic acid, xylitol or wood sugar and furfural.
  • Xyiitol is used as a low calorie sweetener.
  • the newest of the three main manmade cellulosic fibres is lyocell. It is produced by a solvent spinning process.
  • the solvent is an amine oxide, which is non-toxic.
  • a slurry of cellulose in a mixture of amine oxide and water is prepared. Water is removed from the slurry by evaporation and as the water content decreases, the cellulose dissolves in the amine oxide producing a solution which is a viscous liquid above 80°C.
  • the solution is extruded through spinneret holes into a water bath.
  • the solvent is diluted by the water and the cellulose precipitates to form a fibre. In the remainder of the process, the fibre is washed to remove any amine oxide solvent, cut into staple fibre, finished with a lubricant and anti-stat and then dried.
  • the amine oxide solvent is recycled in a closed loop in the factory. Recovery rates of greater than 99.5% are achieved. Recycling of the additive means that the effect of the process on the environment is very low. It is also essential for the economics of the process.
  • Lyocell is much stronger than viscose and is stronger than cotton in both the wet and the dry state, it is used in apparel, home furnishings, workwear and nonwovens. Over 90% of the world's lyocell production is produced by Lenzing Aktiengesellschaft, Lenzing, Austria, and branded TENCEL®.
  • the support for the growth of marine organisms can be produced from manmade cellulosic staple fibre which has been spun into a yarn by any conventional spinning method, it may also be produced using manmade celluiosic continuous filament yarn.
  • the fibers are staple fibers. Staple fibers are beneficial due to their many fiber ends, and also due to the fibrillation of the fiber surface; both properties allow a strong fixation of the marine organisms.
  • the thickness of such staple fiber yarns usually is measured as yarn number. While in principle a broad range of yarn thickness is suitable for the purposes of the present invention, a thickness of between Nm 5 and Nm 20 is preferred, in particular preferred are yarns with from Nm 6 to Nm 15. Nevertheless also continuous filaments are suitable for the invention; suitable filament yarns may consist of 20 to 200 or even more individual filaments per yam.
  • a rope or twine can be produced by twisting together a multitude of manmade celluiosic yarns constructed from staple fibres or continuous filament.
  • a rope may be produced by first twisting yarns together to produce an intermediate folded yam and then twisting together a number of intermediate folded yarns to produce a rope of the desired linear density.
  • a rope or twine may also be produced by braiding manmade celluiosic yarns together.
  • the rope of the invention further comprises a second celluiosic fibre such as cotton, modal or viscose fiber.
  • the rope of the invention further comprises a biodegradable polymeric fibre such as polytactic acid fibre suitable for use as a support and growth medium for the marine organisms.
  • the modal, viscose and biodegradable polymeric fibers can be used in the form of staple fibers or continuous filaments; the skilled in the art may choose the form most suitable for the individual application. Even bicomponent yarns consisting of or containing staple fibers and filaments of the above mentioned materials are possible and are within the scope of the present invention.
  • the rope according to the invention preferably consists of folded yams or folded and twisted yarns. It preferably shows a thickness of between 3 and 30 mm, more preferably between 3 and 20 mm.
  • Ropes or twines produced from manmade cellulosic fibres can be used as direct replacements for the synthetic or cellulosic ropes or twines currently used.
  • rope as described above as a support and growth medium for marine organisms in one out of the group containing the following culture methods: Bouchot culture, long line marine growing culture, raft marine growing culture, intertidal pole marine growing culture, stake marine growing culture, on-bottom marine growing culture or any combination of these culture methods.
  • the rope is used in the form of a mesh.
  • the term "mesh” for the purposes of this invention shall include nets as well.
  • Manmade cellulosic ropes and twines may be used in the Bouchot culture method as an alternative to coir ropes used to collect mussel spats and to support the growth of mussels.
  • Manmade cellulosic ropes and twines may be used in the stake culture method as an alternative to the polypropylene ropes between bamboo poles.
  • Manmade cellulosic ropes and twines may be used in the long line culture method for the horizontal ropes and for the droppers that support growing mussels and for the anchor ropes.
  • a mesh may be produced by knitting manmade cellulosic yarns.
  • a mesh of this type can be used in the raft culture method by anchoring the mesh to the sea bed.
  • Knitting on a circular knitting machine with manmade cellulosic yarns can be used to produce a sock like tube. Tubes produced in this way can be used in long line culture as a sock to support the mussel spats during their initial period of growth prior to attachment to the vertical ropes.
  • the important feature of the present invention is that the textile structure is made using manmade DCiuiosic fibres. This gives the advantage that any of the textile structure which is released into the environment due to accident, storm damage, negligence or any other cause will degrade in a reasonable time and not leave non-degradable residues.
  • the method of using manmade DCiuiosic textile structures in marine culture may be varied to suit the particular organism, the geography of the location, the methods normally used and personal preferences of the operator.
  • Mussel spats are collected on ropes made of coir. These spat bouchots are situated offshore and consist of parallel rows of poles with horizontal coir ropes for collecting seeds. When the seeds are a few months old, they are removed from the ropes, placed in mesh tubes and transferred to bouchots for growth. Ropes with spats attached are wound around large vertical poles (bouchots) in the intertidal zone. The mussels are harvested from each pole annually.
  • a variation on this is where two polypropylene ropes, 2 metres apart are tied to the bamboo poles in a zigzag manner.
  • the culture is based on the principle of transferring seeds from areas of great abundance where growth is poor to culture plots in lower density to obtain better growth.
  • the rope, twine or mesh is weighted at one end and lowered into the culture site.
  • a float is attached to the rope, twine or mesh at the opposite end to the weight
  • the rope, twine or mesh is retained for disposal at an appropriate place by composting.
  • the rope, twine or mesh can be used as a growing medium for marine animals such as mussels and other molluscs.
  • the rope, twine or mesh can be used as a growing medium for edible seaweed.
  • Lyoceil fibre of 1.7dtex and 38mm cut length was subjected to a marine biodegradation test according to ASTM D6691 (2009) "Standard Test Method in Determining Aerobic Biodegradation of Plastic materials in the Marine Environment by a Defined Microbial Consortium in Natural Seawater Innoculum (2009)"
  • test was carried out in triplicate, incubating at 30°C (+-2°C) for a total of 63 days duration.
  • Biodegradation is deemed to be valid if >70% of a reference material (natural cellulose powder - Avicel) is degraded at test end.
  • Modal fibre of 1.7dtex and 39mm cut length was subjected to a marine biodegradation test according to ASTM D6691 (2009) "Standard Test Method in Determining Aerobic Biodegradation of Plastic materials in the Marine Environment by a Defined Microbial Consortium in Natural Seawater Innoculum (2009)"
  • test was carried out in triplicate, incubating at 30°C (+-2°C) for a total of 28 days duration.
  • Biodegradation is deemed to be valid if >70% of a reference material (natural cellulose powder - Avicel) is degraded at test end.
  • a net was constructed from Nm 10 lyocell yam, made of lyocell staple fibers with single fiber titer 1,3 dtex,, combining into 3-strands (diameter 4mm) and knitting the nets out of that on a RL ⁇ warp kitting machine RS8 EL6M 50", 18E.
  • This net can be used as a growing medium for marine cultures.
  • a lyocell yarn was produced in Nm10. The yarn was then folded to produce Nm 10/7 to produce a twine of diameter 4 mm. That twine showed a breaking load of 0,2 kN.
  • This twine is suitable for subsequent use as a support structure in a marine environment.
  • a lyocell yam was produced Nm8 and folded to produce a twine in Nm8/7. This 8/7 twine was then twisted together as 3 strands to produce a lyocell rope of 16mm diameter.
  • This rope was now suitable for use as support rope for mussel growing using long line or raft culture production.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Artificial Filaments (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

La présente invention concerne l'utilisation de fibres cellulosiques artificielles, en particulier de lyocell et modales pour la construction de cordes, de filets et de mailles pour une utilisation en tant que supports pour la culture de cultures marines telles que des mollusques, en particulier des moules et des algues comestibles. Les propriétés clés sont que les supports ont une résistance suffisante pour porter les poids des cultures en croissance sans rupture mais sont biodégradables dans la mer après utilisation.
EP18729534.0A 2017-05-09 2018-04-12 Supports dégradables marins Withdrawn EP3621432A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ATA191/2017A AT520161B1 (de) 2017-05-09 2017-05-09 Im Meer abbaubare Trägermaterialien
PCT/AT2018/000020 WO2018204940A1 (fr) 2017-05-09 2018-04-12 Supports dégradables marins

Publications (1)

Publication Number Publication Date
EP3621432A1 true EP3621432A1 (fr) 2020-03-18

Family

ID=62554898

Family Applications (1)

Application Number Title Priority Date Filing Date
EP18729534.0A Withdrawn EP3621432A1 (fr) 2017-05-09 2018-04-12 Supports dégradables marins

Country Status (3)

Country Link
EP (1) EP3621432A1 (fr)
AT (1) AT520161B1 (fr)
WO (1) WO2018204940A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102020132307A1 (de) 2020-12-04 2022-06-09 Cordenka Innovations GmbH Netz

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57125624A (en) * 1981-01-30 1982-08-05 Asahi Chemical Ind Artificial flow algae
FR2549695B1 (fr) * 1983-07-25 1985-12-13 Boussac Saint Freres Bsf Cordage pour le captage de naissains de mollusques marins et l'elevage de ces mollusques, ses procedes de fabrication et dispositif utilises
US6218321B1 (en) * 1994-12-22 2001-04-17 Biotec Biologische Naturverpackungen Gmbh Biodegradable fibers manufactured from thermoplastic starch and textile products and other articles manufactured from such fibers
JP2000154425A (ja) * 1998-11-19 2000-06-06 Unitika Ltd 生分解性モノフィラメントの製造法
FR2853330B1 (fr) * 2003-04-01 2005-08-26 Univ Bretagne Sud Procede et dispositif de fabrication de fils ou de ficelles biodegradables, fils ou ficelles obtenus par ce procede et applications correspondantes
WO2006012670A1 (fr) * 2004-08-06 2006-02-09 Tristano Pty Ltd Structure d'habitat pour animaux aquatiques
AU2005225144A1 (en) * 2004-10-27 2006-05-11 Kenneth Andrew Joines Improvements in or relating to mussel seeding
DE102006016538A1 (de) * 2006-04-07 2007-11-08 Garntec Gmbh Biologisch abbaubare Bindegarne
ES2372839B1 (es) * 2010-07-13 2012-06-28 Manuel González Corbacho Cuerda trenzada lastrada para captación y cultivo de mejillón.
WO2014210100A1 (fr) * 2013-06-28 2014-12-31 Barber James Patrick Appareil et procédé de restauration des courants et des récifs d'huîtres
CN103329827A (zh) * 2013-07-03 2013-10-02 青岛大学 一种养殖固着性贝类的装置与方法
JP2015092851A (ja) * 2013-11-12 2015-05-18 大和ハウス工業株式会社 薬剤供給装置およびこの薬剤供給装置を用いた植物栽培装置並びにこの薬剤供給装置の使用方法
CN105690883B (zh) * 2016-01-27 2017-10-20 滁州市金成米业有限公司 一种稻田虾养殖防渗漏复合布

Also Published As

Publication number Publication date
WO2018204940A1 (fr) 2018-11-15
AT520161A1 (de) 2019-01-15
AT520161B1 (de) 2020-02-15

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