EP3533896B1 - Tôle en acier électrique à grains orientés et procédé de fabrication de celle-ci - Google Patents
Tôle en acier électrique à grains orientés et procédé de fabrication de celle-ci Download PDFInfo
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- EP3533896B1 EP3533896B1 EP17866141.9A EP17866141A EP3533896B1 EP 3533896 B1 EP3533896 B1 EP 3533896B1 EP 17866141 A EP17866141 A EP 17866141A EP 3533896 B1 EP3533896 B1 EP 3533896B1
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- grain
- steel sheet
- electrical steel
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- oriented electrical
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- 229910001224 Grain-oriented electrical steel Inorganic materials 0.000 title claims description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 22
- 238000000137 annealing Methods 0.000 claims description 43
- 238000001953 recrystallisation Methods 0.000 claims description 35
- 229910052727 yttrium Inorganic materials 0.000 claims description 32
- 229910052788 barium Inorganic materials 0.000 claims description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 238000005097 cold rolling Methods 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 6
- 230000003028 elevating effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 description 24
- 229910000831 Steel Inorganic materials 0.000 description 21
- 239000010959 steel Substances 0.000 description 21
- 238000005096 rolling process Methods 0.000 description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 239000003966 growth inhibitor Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000002244 precipitate Substances 0.000 description 13
- 229910000976 Electrical steel Inorganic materials 0.000 description 12
- 230000004907 flux Effects 0.000 description 10
- 239000011572 manganese Substances 0.000 description 9
- 238000005261 decarburization Methods 0.000 description 8
- 239000010960 cold rolled steel Substances 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 238000005204 segregation Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 230000033001 locomotion Effects 0.000 description 3
- 238000005121 nitriding Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000005381 magnetic domain Effects 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/005—Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
- C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
- C21D8/1272—Final recrystallisation annealing
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2202/00—Physical properties
- C22C2202/02—Magnetic
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/14766—Fe-Si based alloys
- H01F1/14775—Fe-Si based alloys in the form of sheets
Definitions
- the present invention is directed to a grain-oriented electrical steel sheet and a method of manufacturing the same. More specifically, the present invention relates to a grain-oriented electrical steel sheet containing B, Ba, and Y in a predetermined amount to be segregated in grain boundaries, and a method for manufacturing the same.
- the grain-oriented electrical steel sheet is a soft magnetic material having excellent magnetic properties in the rolling direction, composed of grains having a crystal orientation of ⁇ 110 ⁇ 001>, so-called Goss orientation.
- magnetic properties can be expressed by magnetic flux density and iron loss, and high magnetic flux density can be obtained by precisely aligning the orientation of the grains to the ⁇ 110 ⁇ 001> orientation.
- the electrical steel sheet having a high magnetic flux density not only makes it possible to reduce the size of the iron core material of the electric equipment, but also reduces the hysteresis loss, thereby making it possible to miniaturize the electric equipment and increase the efficiency at the same time.
- the iron loss is a power loss consumed as heat energy when an arbitrary alternating magnetic field is applied to the steel sheet, and varies greatly depending on the magnetic flux density and plate thickness of the steel sheet, the amount of impurities in the steel sheet, the specific resistance and the size of the secondary recrystallization grain. The higher the magnetic flux density and the specific resistance and the lower the plate thickness and the amount of impurities in the steel sheet, the lower the iron loss, thereby increasing the efficiency of the electrical equipment.
- a grain-oriented electrical steel sheet having excellent magnetic properties is required to strongly develop a Goss texture in a ⁇ 110 ⁇ ⁇ 001> orientation in the rolling direction of a steel sheet.
- grains in the Goss orientation should form an abnormal grain growth called the second recrystallization.
- This abnormal grain growth occurs when normal grain growth inhibits the movement of grain boundaries normally grown by precipitates, inclusions, or elements dissolved or segregated in the grain boundaries, unlike ordinary grain growth.
- precipitates and inclusions that inhibit grain growth are specifically referred to as a grain growth inhibitor.
- precipitates such as AlN and MnS[Se] are mainly used as a grain growth inhibitor.
- decarburization is carried out after one time of the strong cold-rolling.
- nitrogen is supplied to the inside of the steel sheet through a separate nitriding process using ammonia gas to produce secondary recrystallization by the Al-based nitride which exhibits a strong grain growth inhibiting effect.
- WO 2016/098917 A1 relates to a grain-oriented electrical steel sheet comprising 0.005-0.5 wt% of Ba, 0.005-0.5 wt% of Y, or 0.005-0.5% of Ba and Y, an area of grains of the electrical steel sheet having a grain size of 2 mm or less is 10 % or less with respect to 100 % of an area of total grains.
- EP 1 889 927 B1 relates to oriented magnetic steel plate used in transformers or other stationary induction apparatuses.
- an oriented magnetic steel plate with improved edge peeling resistance and 3X frequency watt loss characteristic W17/150 by adding a compound including one or more elements of Ce, La, Pr, Nd, Sc, and Y into an annealing separator having MgO as its main ingredient, and a method of production of the same.
- Ba and Y are excellent in the effect of inhibiting the growth of grains enough to form secondary recrystallization and are not affected by the atmosphere in the furnace during the high-temperature annealing process. However, they have a disadvantage in weakening the bonding strength of the grain boundaries. Therefore, there is a problem in that a large number of grain boundary cracks occur in the cold-rolling process in which the high pressure is required, so that the productivity decrease cannot be avoided.
- a grain-oriented electrical steel sheet and a method of manufacturing the same are provided.
- the grain-oriented electrical steel sheet according to an embodiment of the present invention is excellent in magnetic properties by stably forming Goss grain.
- AlN and MnS are not used as a grain growth inhibitor, it is not necessary to heat the slab at a high temperature of 1300°C or more.
- first, second, third, and the like are used to describe various portions, components, regions, layers and/or sections, but are not limited thereto. These terms are only used to distinguish one portion, component, region, layer or section from another portion, component, region, layer or section. Thus, a first portion, component, region, layer or section described below may be referred to as a second portion, component, region, layer or section without departing from the scope of the present invention.
- % means % by weight, and 1 ppm is 0.0001% by weight.
- precipitates such as AlN and MnS were used as the grain growth inhibitors. All the processes were strictly controlling the distribution of the precipitates and the process conditions were severely constrained by the conditions for removing precipitates remaining in the secondary recrystallized steel sheet.
- precipitates such as AlN and MnS are not used as a grain growth inhibitor.
- the present invention uses B and Ba or Y as a grain growth inhibitor, thus it is possible to increase the grain fraction of Goss and obtain an electrical steel sheet excellent in magnetic properties.
- the grain-oriented electrical steel sheet of the present invention includes by weight, Si: 1.0 to 7.0%, Mn: 0.01 to 0.5%, B: 0.001 to 0.1%, and Ba and Y individually or in a total amount of 0.005 to 0.5%, and the remainder including Fe and other unavoidable impurities.
- Barium (Ba) and yttrium (Y) act as a grain growth inhibitor, during secondary recrystallization annealing, to suppress the growth of grains in a orientation other than the Goss grains, thereby improving the magnetic properties of the electrical steel sheet.
- Ba and Y may be added individually or in combination.
- Ba and Y are included individually or in a total amount of 0.005 to 0.5% by weight. That is, when Ba or Y is added individually, the content of Ba or Y is 0.005 wt% to 0.5 wt%, respectively. When Ba and Y are simultaneously added, the sum of the contents (i.e., the total amount) of Ba and Y is 0.005 wt% to 0.5 wt%.
- the amount of Ba or Y or the total amount thereof is too small, it is difficult to exert a sufficient restraining force. If the amount of Ba or Y or the total amount thereof is too large, the brittleness of the steel sheet increases and cracks may occur during rolling.
- B Boron
- B is segregated at the grain boundaries to strengthen the grain boundary bonding force, thereby reducing generation of cracks and rolling times during rolling.
- it reacts with nitrogen in the steel to partially form BN precipitates.
- BN is excellent in high temperature stability and can act as an auxiliary inhibitor which suppresses grain growth together with Ba and Y described in the above.
- the content of B is 0.001 to 0.1% by weight. If B is included too little, it may be insufficient to alleviate the grain boundary brittleness due to Ba and Y. If B is included too much, grain boundary segregation of Ba and Y is suppressed, and a large number of inclusions are formed in the high-temperature annealing process, so that the magnetic properties may be deteriorated.
- the value of the Formula 1 When the value of the Formula 1 is less than 0.5, grain boundary segregation of Ba and Y is suppressed. Further, a large number of inclusions are formed in the high-temperature annealing process, so that the magnetic properties may be deteriorated. When the value of the Formula 1 is more than 3, it may be insufficient to alleviate the grain boundary brittleness due to Ba and Y.
- Silicon (Si) acts to lower the iron loss by increasing the specific resistance of the material. If the Si content in the slab and the electrical steel sheet is less than 1.0% by weight, the specific resistance may decrease and the iron loss property may be deteriorated. On the contrary, when the Si content exceeds 7% by weight in the grain-oriented electrical steel sheet, the Si content in the grain-oriented electrical steel sheet can be 7% by weight or less since the processing is difficult in manufacturing the transformer.
- Carbon (C) as an austenite stabilizing element, is added to the slab in an amount of 0.001 wt% or more to refine the coarse columnar structure that occurs during the performance process and to suppress the slab center segregation of S. It is also possible to accelerate work hardening of the steel sheet during cold-rolling, thereby promoting generation of secondary recrystallization nuclei in the ⁇ 110 ⁇ ⁇ 001> orientation in the steel sheet. However, if the content exceeds 0.1%, it may cause edge-cracks in hot-rolled steel. However, the decarburization annealing is performed during the production of the electrical steel sheet, and the C content in the final electrical steel sheet after decarburization annealing is 0.005 wt% or less. Preferably, it may be 0.003% by weight or less.
- the precipitates such as AlN and MnS
- the elements which are essentially used in normal grain-oriented electrical steel sheets, such as aluminum (Al), nitrogen (N), sulfur (S), are regulated within the range of impurities. That is, when Al, N, and S are inevitably further included, it further includes 0.005 wt% or less of Al, 0.0055 wt% or less of S, and 0.0055 wt% or less of N.
- AlN is not used as a grain growth inhibitor, aluminum (Al) content can be positively suppressed.
- Al may not be added to the grain-oriented electrical steel sheet or is controlled to 0.005 wt% or less.
- Al can be removed during the manufacturing process, Al can be contained in an amount of 0.01 wt% or less.
- nitrogen (N) forms precipitates such as AlN, (Al,Mn)N, (Al, Si,Mn)N, Si 3 N 4 , and BN, in the embodiment of the present invention, N may not be added or is controlled to 0.0055 wt% or less.
- the nitriding process can be omitted, so that the N content in the slab and the N content in the final electrical steel sheet can be substantially the same.
- the sulfur (S) is an element having a high dissolving temperature and a high segregation during hot-rolling, and thus, in one embodiment of the present invention, it may not be added or is controlled to 0.0055 wt% or less. Preferably, it may be 0.0035% by weight or less.
- MnS manganese
- Mn manganese
- Mn is a non-resistive element and has an effect of improving magnetic properties
- it may be further included as an optional component in slabs and electrical steel sheets.
- the content of Mn is 0.01 wt% or more. However, if it exceeds 0.5% by weight, phase transformation may occur after the secondary recrystallization, and the magnetic property may be deteriorated.
- additional elements when additional elements are further included, it is understood that it is added replacing iron (Fe) which is the remainder.
- unavoidable impurities components such as Ti, Mg, and Ca react with oxygen in the steel to form oxides, which may interfere with the magnetic migration of the final product as an inclusion and cause magnetic deterioration.
- components such as Ti, Mg, and Ca react with oxygen in the steel to form oxides, which may interfere with the magnetic migration of the final product as an inclusion and cause magnetic deterioration.
- it is necessary to strongly suppress the unavoidable impurities. Therefore, when they are inevitably contained, they are controlled to 0.005% by weight or less for each component.
- the grain-oriented electrical steel sheet has 10 mm or more of an average particle diameter of grains having 2 mm or more of the particle diameter. If the average particle diameter of the grains having a particle diameter of 2 mm or more is less than 10 mm, the grains may not grow sufficiently and thus the magnetic properties may be deteriorated.
- the particle diameter of grains means the diameter length of the grains of the circular form.
- the grain-oriented electrical steel sheet according to an embodiment of the present invention is excellent in magnetic properties by stably forming Goss grain.
- the grain-oriented electrical steel sheet according to an embodiment of the present invention may have a magnetic flux density B 8 of 1.88T or more measured at a magnetic field of 800 A/m.
- the method for manufacturing a grain-oriented electrical steel sheet according to the present invention includes a step of heating the slab containing, by weight, Si: 1.0 to 7.0%, B: 0.001 to 0.1%, and Ba and Y individually or in a total amount of 0.005 to 0.5%, and the remainder including Fe and other unavoidable impurities; a step of hot-rolling the slab to produce a hot-rolled sheet; a step of cold-rolling the hot-rolled sheet to produce a cold-rolled sheet; a step of the primary recrystallization annealing the cold-rolled sheet; and a step of the second recrystallization annealing the cold-rolled sheet after the primary recrystallization annealing is completed.
- the slab is heated.
- the heating temperature of the slab is limited. If the slab is heated to a temperature of 1280°C or less, it may prevent the columnar structure of the slab from becoming coarse, thereby preventing cracks in the plate during the hot-rolling process. Thus, the heating temperature of the slab may be between 1000°C and 1280°C. In particular, in one embodiment of the present invention, since AlN and MnS are not used as a grain growth inhibitor, it is not necessary to heat the slab at a high temperature of 1300°C or more.
- the hot-rolling temperature is not limited, and in one embodiment, hot-rolling may be terminated at 950°C or lower. Thereafter, it is water-cooled and can be wound at 600°C or less.
- the hot-rolled sheet can be subject to a hot-rolled sheet annealing, if necessary.
- the hot-rolled steel sheet can be heated to a temperature of 900°C or more, cracked, and cooled to make the texture of the hot-rolled steel sheet uniform.
- the hot-rolled sheet is cold-rolled to produce a cold-rolled sheet.
- the cold-rolling can be carried out by a cold-rolling method using a reverse rolling mill or a tandem rolling mill through one cold-rolling, a plurality of cold-rolling, a plurality of cold-rolling including an intermediate annealing to produce a cold-rolled sheet having a thickness of 0.1 mm to 0.5 mm. Further, warm-rolling in which the temperature of the steel sheet is maintained at 100°C or higher during the cold-rolling can be performed.
- the final reduction roll through cold-rolling can be 80% or more.
- the grain boundary is segregated to strengthen the grain boundary's bonding force.
- cracking and rolling times can be reduced during rolling and the final reduction roll can be increased.
- the cold-rolled sheet is subject to the primary recrystallization annealing.
- the primary recrystallization occurs in which the core of the Goss grain nuclei is generated in the primary recrystallization annealing step.
- the decarburization of the cold-rolled sheet can be performed in the primary recrystallization annealing step. It is annealed at a temperature of 800°C to 900°C for decarburization. Further, the atmosphere is a mixed gas atmosphere of hydrogen and nitrogen. When the decarburization is completed, the carbon content in the cold-rolled steel sheet may be 0.005 wt% or less. In one embodiment of the present invention, since the AlN grain growth inhibitor is not used, the nitriding process can be omitted.
- the cold-rolled sheet having undergone the primary recrystallization annealing is subject to a secondary recrystallization annealing.
- secondary recrystallization annealing can be performed.
- the annealing separator is not particularly limited, and an annealing separator containing MgO as a main component can be used.
- the step of secondary recrystallization annealing includes a temperature elevating step and a soaking step.
- the temperature elevating step is a step of raising the temperature of the cold-rolled sheet, of which the primary recrystallization annealing is completed, to the temperature of the soaking step.
- the temperature of the soaking step is 900°C to 1250°C. If the temperature is less than 900°C, the Goss grains may not sufficiently grow and the magnetic properties may be deteriorated. When the temperature exceeds 1250°C, the grains may grow so large that the characteristics of the electrical steel sheet may be deteriorated.
- the temperature elevating step may be performed in a mixed gas atmosphere of hydrogen and nitrogen, and the soaking step may be performed in a hydrogen atmosphere.
- the stress relief annealing step can be omitted after the secondary recrystallization annealing is completed.
- high-temperature stress relief annealing to remove precipitates, such as AlN and MnS is required.
- the stress relief annealing process may not be necessary.
- the alloy component of the grain-oriented electrical steel sheet refers to a base steel sheet excluding a coating layer such as an insulating film.
- the slab was heated at a temperature of 1150°C for 90 minutes, and hot-rolled to obtain a hot-rolled sheet having a thickness of 2.6 mm.
- the hot-rolled sheet was heated to a temperature of 1050°C or higher, held at 910°C for 90 seconds, cooled with water, and pickled. And then, the sheet was cold-rolled to a thickness of 0.30 mm through a total of seven passes using a reverse mill. The reduction roll per pass was the same for each test condition.
- the cold-rolled steel sheet was heated in a furnace, and then held in a mixed gas atmosphere of 50 vol% of hydrogen and 50 vol% of nitrogen and annealing temperature of 850°C for 120 seconds to carry out the primary recrystallization annealing along with the decarburization was performed until carbon content reaches 0.002 wt.%. Thereafter, MgO was applied and then wound into a coil, followed by the secondary recrystallization annealing.
- the secondary recrystallization annealing was carried out in a mixed gas atmosphere of 25 vol% of nitrogen and 75 vol% of hydrogen to elevate the temperature to 1200°C. After reaching 1200°C, the sheet was held in 100 vol% of hydrogen gas atmosphere for 20 hours, followed by cooling in the furnace.
- FIG. 1 and FIG. 2 the photograph of the cold-rolled steel sheet in the manufacturing process of the inventive material of the Sample No. 2 and the photograph of the cold-rolled steel sheet in the manufacturing process of the comparative material of the Sample No. 1 were shown. It can be seen that the rolling cracks clearly appear in the case of the comparative material.
- the slab was heated at a temperature of 1150°C for 90 minutes, and hot-rolled to obtain a hot-rolled sheet having a thickness of 2.6 mm.
- the hot-rolled sheet was heated to a temperature of 1050°C or higher, held at 910°C for 90 seconds, cooled with water, and pickled. And then, the sheet was cold-rolled to a thickness of 0.30 mm through a total of seven passes using a reverse mill. The reduction roll per pass was the same for each test condition.
- the cold-rolled steel sheet was heated in a furnace, and then held in a mixed gas atmosphere of 50 vol% of hydrogen and 50 vol% of nitrogen and annealing temperature of 850°C for 120 seconds to carry out the primary recrystallization annealing along with the decarburization was performed until carbon content reaches 0.003 wt.%. Thereafter, MgO was applied and then wound into a coil, followed by the secondary recrystallization annealing.
- the secondary recrystallization annealing was carried out in a mixed gas atmosphere of 25 vol% of nitrogen and 75 vol% of hydrogen to elevate the temperature to 1200°C. After reaching 1200°C, the sheet was held in 100 vol% of hydrogen gas atmosphere for 20 hours, followed by cooling in the furnace.
- the magnetic flux density was measured at a magnetic field strength of 800 A/m using a single sheet measurement method.
- the particle diameter of the grains was calculated as the average value based on the area after removing the coating layer on the surface by immersing into a hydrochloric acid heated to 60°C for 5 minutes.
- the average particle diameter of the grains having 2 mm or more of particle diameter in the electrical steel sheet according to an embodiment of the present invention was found to be 10 mm or more, and the magnetic properties were excellent.
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Claims (5)
- Tôle en acier magnétique à grains orientés comprenant, en poids, Si : 1,0 à 7,0 %, B : 0,001 à 0,1 %, et Ba et Y individuellement ou dans une quantité totale de 0,005 à 0,5 %, et le reste comprenant Fe et d'autres impuretés inévitables, et comprenant éventuellement C : 0,005 % ou moins à l'exclusion de 0 %, Al : 0,005 % ou moins à l'exclusion de 0 %, N : 0,0055 % ou moins à l'exclusion de 0 %, et S : 0,0055 % ou moins à l'exclusion de 0 %, et comprenant éventuellement Mn : 0,01 % à 0,5 %,
et satisfaisant la formule 1 suivante, et dans laquelle le diamètre moyen de particule des grains ayant un diamètre de particule de 2 mm ou plus est de 10 mm ou plus, - Tôle en acier magnétique à grains orientés selon la revendication 1, comprenant B et, Ba ou Y ségrégés dans les limites de grain.
- Procédé de fabrication d'une tôle en acier magnétique à grains orientés comprenant :une étape de chauffage de la bande comprenant, en poids, Si : 1,0 à 7,0 %, B : 0,001 à 0,1 %, et Ba et Y individuellement ou dans une quantité totale de 0,005 à 0,5 %, et le reste comprenant Fe et d'autres impuretés inévitables, et comprenant éventuellement C : 0,001 à 0,1 %, Al : 0,01 % ou moins à l'exclusion de 0 %, N : 0,0055 % ou moins à l'exclusion de 0 %, et S : 0,0055 % ou moins à l'exclusion de 0 %, et comprenant éventuellement Mn : 0,01 % à 0,5 % et satisfaisant la formule 1 suivante ;une étape de laminage à chaud de la bande pour produire une tôle laminée à chaud ;une étape de laminage à froid de la tôle laminée à chaud pour produire une tôle laminée à froid ;une étape du recuit avec recristallisation primaire de la tôle laminée à froid ; etune étape du second recuit avec recristallisation de la tôle laminée à froid après l'achèvement du recuit avec recristallisation primaire,dans lequel la recristallisation primaire est réalisée dans une plage de températures de 800 °C à 900 °C et dans une atmosphère de gaz mixte d'hydrogène et d'azote, etdans lequel la seconde étape de recuit avec recristallisation comprend une étape d'élévation de température et une étape de maintien en température, et la température de l'étape de maintien en température est de 900 à 1 250 °C,dans lequel, dans la seconde étape de recristallisation, l'étape d'élévation de température est réalisée dans une atmosphère de gaz mixte d'hydrogène et d'azote, et l'étape de maintien en température est réalisée dans une atmosphère d'hydrogène,dans la formule (1), [Ba], [Y], et [B] représentent les teneurs en % en poids, de Ba, Y et B, respectivement.
- Procédé de fabrication d'une tôle en acier magnétique à grains orientés selon la revendication 3,
dans lequel la bande est chauffée à 1 000 à 1 280 °C dans l'étape de chauffage de la bande. - Procédé de fabrication d'une tôle en acier magnétique à grains orientés selon la revendication 3,
dans lequel le rouleau de réduction final est de 80 % ou plus dans l'étape de laminage à froid de la tôle laminée à froid pour produire une tôle laminée à chaud.
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KR1020160139937A KR101884428B1 (ko) | 2016-10-26 | 2016-10-26 | 방향성 전기강판 및 이의 제조방법 |
PCT/KR2017/011849 WO2018080167A1 (fr) | 2016-10-26 | 2017-10-25 | Tôle en acier électrique à grains orientés et procédé de fabrication de celle-ci |
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EP3533896A1 EP3533896A1 (fr) | 2019-09-04 |
EP3533896A4 EP3533896A4 (fr) | 2019-10-16 |
EP3533896B1 true EP3533896B1 (fr) | 2021-03-31 |
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US (1) | US20190309387A1 (fr) |
EP (1) | EP3533896B1 (fr) |
JP (1) | JP6808830B2 (fr) |
KR (1) | KR101884428B1 (fr) |
CN (1) | CN109906284B (fr) |
WO (1) | WO2018080167A1 (fr) |
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KR102305718B1 (ko) * | 2019-12-18 | 2021-09-27 | 주식회사 포스코 | 방향성 전기강판 및 그 제조방법 |
KR102271299B1 (ko) * | 2019-12-19 | 2021-06-29 | 주식회사 포스코 | 이방향성 전기강판 및 그의 제조방법 |
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US6162306A (en) * | 1997-11-04 | 2000-12-19 | Kawasaki Steel Corporation | Electromagnetic steel sheet having excellent high-frequency magnetic properities and method |
EP2489753B1 (fr) * | 2002-12-05 | 2019-02-13 | JFE Steel Corporation | Feuille d'acier magnétique non orientée et son procédé de production |
JP4352691B2 (ja) * | 2002-12-05 | 2009-10-28 | Jfeスチール株式会社 | 打ち抜き性及び鉄損の優れた時効硬化性無方向性電磁鋼板、その製造方法及びそれを用いたローターの製造方法 |
DE20316160U1 (de) * | 2003-10-22 | 2004-01-15 | Turevsky, Boris | Verschleißfester Stahl |
JP2005264280A (ja) * | 2004-03-22 | 2005-09-29 | Jfe Steel Kk | 打ち抜き性及び耐被膜剥離性に優れた方向性電磁鋼板及びその製造方法 |
JP4716033B2 (ja) * | 2004-12-17 | 2011-07-06 | 日立金属株式会社 | カレントトランス用磁心、カレントトランス及び電力量計 |
JP5230194B2 (ja) * | 2005-05-23 | 2013-07-10 | 新日鐵住金株式会社 | 被膜密着性に優れる方向性電磁鋼板およびその製造方法 |
JP4962516B2 (ja) * | 2009-03-27 | 2012-06-27 | Jfeスチール株式会社 | 方向性電磁鋼板の製造方法 |
CN102002567B (zh) * | 2010-12-15 | 2012-07-11 | 北京科技大学 | 一种取向高硅钢薄板的制备方法 |
KR101482354B1 (ko) * | 2012-12-27 | 2015-01-13 | 주식회사 포스코 | 철손이 우수한 방향성 전기강판 및 그 제조방법 |
KR20150073511A (ko) * | 2013-12-23 | 2015-07-01 | 김종암 | 치마부용 보온덮개 및 이를 이용한 비닐하우스 |
KR20150073551A (ko) * | 2013-12-23 | 2015-07-01 | 주식회사 포스코 | 방향성 전기강판 및 그 제조방법 |
KR20150074925A (ko) * | 2013-12-24 | 2015-07-02 | 주식회사 포스코 | 방향성 전기강판 및 그 제조방법 |
KR101647655B1 (ko) * | 2014-12-15 | 2016-08-11 | 주식회사 포스코 | 방향성 전기강판 및 그 제조방법 |
JP6344263B2 (ja) * | 2015-02-25 | 2018-06-20 | Jfeスチール株式会社 | 方向性電磁鋼板の製造方法 |
CN104928452B (zh) * | 2015-05-15 | 2018-03-20 | 武汉钢铁有限公司 | 一种能防止取向硅钢二次再结晶退火边裂的涂料 |
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- 2017-10-25 CN CN201780066820.2A patent/CN109906284B/zh active Active
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- 2017-10-25 EP EP17866141.9A patent/EP3533896B1/fr active Active
- 2017-10-25 US US16/345,488 patent/US20190309387A1/en not_active Abandoned
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KR101884428B1 (ko) | 2018-08-01 |
CN109906284A (zh) | 2019-06-18 |
US20190309387A1 (en) | 2019-10-10 |
EP3533896A1 (fr) | 2019-09-04 |
EP3533896A4 (fr) | 2019-10-16 |
JP6808830B2 (ja) | 2021-01-06 |
JP2020509153A (ja) | 2020-03-26 |
CN109906284B (zh) | 2021-10-15 |
WO2018080167A1 (fr) | 2018-05-03 |
KR20180045504A (ko) | 2018-05-04 |
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