EP3512902A1 - Film polymère contenant un copolyamide formé à partir au moins d'une diamine, d'un acide dicarboxylique et d'un acide dimère - Google Patents

Film polymère contenant un copolyamide formé à partir au moins d'une diamine, d'un acide dicarboxylique et d'un acide dimère

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Publication number
EP3512902A1
EP3512902A1 EP17764795.5A EP17764795A EP3512902A1 EP 3512902 A1 EP3512902 A1 EP 3512902A1 EP 17764795 A EP17764795 A EP 17764795A EP 3512902 A1 EP3512902 A1 EP 3512902A1
Authority
EP
European Patent Office
Prior art keywords
polymer film
copolyamide
component
acid
components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP17764795.5A
Other languages
German (de)
English (en)
Inventor
Rolf Minkwitz
Andreas Thomas HAEDLER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP3512902A1 publication Critical patent/EP3512902A1/fr
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/28—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/34—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids using polymerised unsaturated fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06—Polyamides derived from polyamines and polycarboxylic acids

Definitions

  • the present invention relates to a polymer film (P) containing at least one copolyamide.
  • the copolyamide is prepared by polymerizing a first monomer mixture (M1) and a second monomer mixture (M2).
  • the present invention relates to a process for producing the polymer film (P) and the use of the polymer film (P) for high temperature applications.
  • Polyamides are industrially of particular importance, since they are characterized by very good mechanical properties, in particular they have a high strength and toughness, good chemical resistance and high abrasion resistance. They are used for example for the production of fishing lines, climbing ropes and carpets. In addition, polyamides are used for the production of packaging films and packaging bags.
  • copolyamides which combine the positive properties of different polyamides are frequently used.
  • the prior art describes various copolyamides.
  • EP 0 352 562 describes films of copolyamides, wherein the copolyamides are prepared from ⁇ -caprolactam and preferably 1 to 10 parts by weight of a dimer acid and a diamine.
  • the copolyamides can then be used for the production of flat or blown films. Likewise, they are suitable for the production of composite films.
  • a disadvantage of the copolyamide films described in EP 0 352 562 is that they have a relatively low tear propagation resistance, a high modulus of elasticity and low penetration energy and, moreover, are poorly or even unusable even for high-temperature applications.
  • US 4,387,184 describes polyphase polyamide compositions. These polyphase polyamide compositions contain a polyamide matrix and a phase dispersed therein which also contains a polyamide. These polyphase polyamide compositions can be made into films.
  • a disadvantage of the films described in US Pat. No. 4,387,184 is that they have little or no transparency and that they have poor mechanical properties, in particular a high modulus of elasticity and thus high rigidity.
  • the object underlying the present invention was therefore to provide a polymer film (P) which contains a polyamide and which does not have the disadvantages of the polymer films described in the prior art or only to a reduced extent.
  • the polymer film (P) should also be as simple and inexpensive to produce.
  • a polymer film (P) containing at least one copolyamide prepared by polymerization of components (A) 15 to 95 wt .-% of a first monomer mixture (M1) containing the components
  • (A2) contains at least one first C 4 -C 12 -diamine
  • (B2) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B).
  • the polymer film (P) according to the invention has a high tear strength both in the direction of extrusion and perpendicular thereto. This is particularly advantageous when the polymer film (P) according to the invention is used as a packaging film.
  • the polymer film (P) according to the invention has a high transparency and a high low-temperature toughness.
  • the polymer film (P) according to the invention is less stiff than the polymer films described in the prior art which contain a polyamide or a copolyamide.
  • the polymer film (P) of the present invention has a low modulus of elasticity and a high puncture resistance in the dry state. The high puncture resistance is also particularly important when the polymer film (P) is used as a packaging film.
  • the polymer film (P) according to the invention is also suitable for use at relatively high temperatures, for example at temperatures in the range from 200 to 260 ° C., preferably in the range from 210 to 250 ° C.
  • relatively high temperatures for example at temperatures in the range from 200 to 260 ° C., preferably in the range from 210 to 250 ° C. The invention will be explained in more detail below.
  • the polymer film (P) contains at least one copolyamide.
  • At least one copolyamide is understood to mean both exactly one copolyamide and one mixture of two or more copolyamides.
  • the at least one copolyamide is described in more detail below.
  • the polymer film (P) has, for example, a thickness in the range from 0.1 ⁇ m to 1 mm, preferably a thickness in the range from 5 to 500 ⁇ m, and particularly preferably in the range from 20 to 100 ⁇ m.
  • the present invention therefore also relates to a polymer film (P) in which the polymer film (P) has a thickness in the range from 0.1 ⁇ m to 1 mm.
  • the polymer film (P) may contain, in addition to the at least one copolyamide, at least one further polymer (wP).
  • At least one further polymer (wP) means both exactly one further polymer (wP) and a mixture of two or more further polymers (wP) It goes without saying that the at least one further polymer (wP) is different from the at least one copolyamide.
  • the at least one further polymer (wP) is preferably selected from the group consisting of polyolefins, poly (ethylvinyl alcohols), poly (ethylvinylacetates), polyethylene terephthalates, polyvinylidene chlorides, maleic anhydride-grafted polyolefins, polyesters and ionomers.
  • the at least one further polymer (wP) is selected from the group consisting of polyolefins, poly (ethylvinyl alcohols), poly (ethylvinylacetates), polyethylene terephthalates,
  • the at least one other polymer (wP) is selected from the group consisting of polyolefins, maleic anhydride-grafted polyolefins, and ethylvinyl alcohols.
  • At least one further polymer (wP) selected from the group consisting of polyolefins it is preferred that polyolefins additionally grafted with maleic anhydride be used as at least one further polymer (wP). It is possible that a mixture of polyolefins and polyolefins grafted with maleic anhydride is used as the at least one further polymer (wP).
  • the polymer film (P) contains at least a first further layer of at least one further polymer (wP), wherein the at least one further polymer (wP) of the first another layer is selected from the group consisting of polyolefins grafted with maleic anhydride and the polymer film (P) comprises at least one second further layer of at least one further polymer (wP), wherein the at least one further polymer (wP) of the second further layer is selected from Group consisting of polyolefins.
  • the polymer film (P) then preferably contains the first further layer between the first layer containing the at least one copolyamide and the second further layer.
  • Polyolefins as such are known to those skilled in the art.
  • Preferred polyolefins are polypropylene (PP), low-density polyethylene (LDPE), linear-low-density polyethylene (LLDPE) and very-low-density polyethylene (VLDPE).
  • Linear low-density polyethylene (LLDPE) is a copolymer of ethylene and at least one C4-C8 ⁇ -olefin.
  • Linear-low-density polyethylene (LLDPE) is characterized by long polymer chains with short side chains. The length of the side chains in linear-low-density polyethylene (LLDPE) is usually shorter than in low-density polyethylene (LDPE) and in medium-density polyethylene (MDPE).
  • the melting point of linear-low-density polyethylene (LLDPE) is preferably in the range of 1 10 to 130 ° C, its density is in the range of 0.91 to 0.93 g / cm 3 .
  • VLDPE Very-low-density polyethylene
  • C 4 - Cs- ⁇ -olefin usually have a melting point in the range of 1 10 to 130 ° C and a density in the range of 0.86 to ⁇ 0.91 g / cm 3 .
  • the proportion of C 4 -C 8 ⁇ -olefins in VLDPE is generally higher than in LLDPE.
  • C4-C8- ⁇ -olefins are understood as meaning linear and branched, preferably linear, alkylenes having 4 to 8 carbon atoms which are unsaturated in the o position and thus have a C-C double bond in the ⁇ -position these are 1-butene, 1-pentene, 1-hexene, 1-heptane and 1-octene.1-butene, 1-hexene and 1-octene are preferred.
  • Preferred poly (ethylene vinyl acetates) are copolymers of ethylene with vinyl acetate.
  • ethylene ethylene vinyl acetates
  • Preferred poly (ethylene vinyl acetates) are copolymers of ethylene with vinyl acetate.
  • ethylene in the range of 82 to 99.9 wt.% Of ethylene and in the range of 0.1 to 18 wt.% Of vinyl acetate, preferably in the range of 88 to 99.9 wt.% Of ethylene and in the range of 0, 1 to 12 wt .-% vinyl acetate used for the preparation.
  • Preferred poly (ethylenevinyl alcohols) are obtainable by complete or partial saponification of the above-described poly (ethylenevinylacetates).
  • the poly (ethylene vinyl alcohols) contain in the range of 50 to 75 mole percent ethylene and in the range of 25 to 50 mole percent vinyl alcohol, based on the total amount of poly (ethylene vinyl alcohols).
  • the polymer film (P) may contain the at least one further polymer (wP) as a blend (mixture) with the at least one copolyamide. Moreover, it is possible and preferred according to the invention for the polymer film (P) to contain at least one first layer which contains the at least one copolyamide and the polymer film (P) to contain at least one further layer which contains the at least one further polymer (wP) , In this embodiment, it is preferred that the at least one first layer containing the at least one copolyamide contains no further polymer (wP).
  • At least one first layer in the context of the present invention means both exactly one first layer and two or more first layers.
  • At least one further layer means both exactly one further layer and two or more further layers, two or more further layers are preferred, it is therefore preferred for the polymer film (P) to comprise at least one first layer, which contains at least one copolyamide, and the polymer film (P) also contains at least one further layer, the at least one further layer comprising at least one further polymer (wP) selected from the group consisting of polyolefins, poly (ethylenevinylalcohols), poly (ethylene vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides and maleic anhydride-grafted polyolefins.
  • polyolefins poly (ethylenevinylalcohols), poly (ethylene vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides and maleic anhydride-grafted polyolefins.
  • the present invention thus also provides a polymer film (P) in which the polymer film (P) contains at least one first layer containing the at least one copolyamide, and the polymer film (P) contains at least one further layer, wherein the at least one further Layer at least one further polymer (wP) selected from the group consisting of polyolefins, poly (ethylene vinyl alcohols), poly (ethylene vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides and maleic anhydride gegrafteten polyolefins containing.
  • the polymer film (P) contains at least one first layer containing the at least one copolyamide
  • the polymer film (P) contains at least one further layer
  • the at least one further Layer at least one further polymer (wP) selected from the group consisting of polyolefins, poly (ethylene vinyl alcohols), poly (ethylene vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides and maleic anhydride gegrafteten polyo
  • the polymer film (P) contains no further layer in addition to the at least one first layer, then the polymer film (P) is also referred to as monofilm. If the polymer film (P) is a monofilm, it may contain exactly one first layer and no further layer, and it is also possible that it contains two or more first layers and no further layer. If the polymer film (P) contains two or more first layers and is a monofilm, the two or more first layers all have the same composition.
  • the polymer film (P) contains at least one first layer which contains the at least one copolyamide, and at least one further layer which contains the at least one further polymer (wP), the polymer film (P) is also referred to as multilayer film.
  • the polymer film (P) then contains 1 to 11 first layers containing the at least one copolyamide and 1 to 13 further layers containing the at least one further polymer (wP).
  • the polymer film (P) contains 1 to 5 first layers containing the at least one copolyamide, and 1 to 1 1 further layers containing the at least one further polymer (wP). More preferably, the polymer film (P) contains 1 to 3 first layers containing the at least one copolyamide and 1 to 7 further layers containing the at least one further polymer (wP).
  • the at least one first layer consists of the at least one copolyamide. It is likewise preferred that the at least one further layer consists of the at least one further polymer (wP).
  • polymer film (P) thus encompasses both monofilms and multilayer films
  • the subject of the present invention is therefore also a polymer film (P), wherein the polymer film (P) is a monofilm or a multilayer film.
  • the polymer film (P) usually has a thickness in the range of 0.1 ⁇ to 1 mm, preferably in the range of 5 to 500 ⁇ and particularly preferably in the range of 10 to 100 ⁇ . If the polymer film (P) is a monofilm and if it contains exactly one first layer, the first layer has the same thickness as the polymer film (P), for example in the range of 0.1 ⁇ m to 1 mm, preferably in the range of 5 to 500 ⁇ and particularly preferably in the range of 10 to 100 ⁇ . If the polymer film (P) is monofilm and it contains two or more first layers, the thickness of each first layer is usually smaller than the thickness of the polymer film (P).
  • the at least one first layer containing the at least one copolyamide then has a thickness in the range of 0.1 to 100 ⁇ , preferably in the range of 0.5 to 50 ⁇ and particularly preferably in the range of 0.5 to 15 ⁇ on.
  • the thickness of the individual layers of the polymer film is (P), that is, the thickness of the at least one first layer containing the at least one copolyamide, and the thickness of the at least one further layer containing the contains at least one further polymer (wP), usually smaller than the thickness of the polymer film (P).
  • the sum of the thicknesses of the individual layers then generally corresponds to the thickness of the polymer film (P).
  • the at least one first layer containing the at least one copolyamide then has a thickness in the range from 0.1 to 100 ⁇ m, preferably in the range from 0.5 to 50 ⁇ m, and particularly preferably in the range from 0.5 to 15 ⁇ .
  • the at least one further layer which contains the at least one further polymer (wP) then has, for example, a thickness in the range from 0.1 to 100 ⁇ m, preferably in the range from 0.5 to 50 ⁇ m, and particularly preferably in the range from 0 , 5 to 15 ⁇ .
  • the polymer film (P) may contain at least one adhesion promoter. This embodiment is preferable when the polymer film (P) is a multilayer film. "At least one adhesion promoter" in the context of the present invention means both exactly one adhesion promoter and a mixture of two or more adhesion promoters.
  • the at least one adhesion promoter can be contained together with the at least one copolyamide in the at least one first layer. It is likewise possible for the at least one adhesion promoter to be present together with the at least one further polymer (wP) in the at least one further layer. Moreover, it is possible for the at least one adhesion promoter to be present as at least one additional layer in the polymer film (P). This embodiment is preferred.
  • the at least one adhesion promoter is contained as at least one additional layer in the polymer film (P), then this is at least one additional layer preferably between the at least one further layer, which is the at least one further Polymer (wP) contains, and the at least one first layer containing the at least one copolyamide arranged.
  • the at least one layer of the adhesion promoter has, for example, a thickness in the range from 0.1 to 100 ⁇ m, preferably in the range from 0.5 to 50 ⁇ m, and particularly preferably in the range from 0.5 to 15 ⁇ m.
  • adhesion promoters are known to those skilled in the art.
  • Preferred adhesion promoters are copolymers of ethylene with maleic anhydride or a copolymer of ethylene with vinyl acetate.
  • a copolymer of linear-low-density polyethylene (LLDPE) and maleic anhydride or a copolymer of ethylene and vinyl acetate is preferred, with> 18% by weight of vinyl acetate and ⁇ 82% by weight of ethylene being used for the preparation of the copolymer.
  • LLDPE linear-low-density polyethylene
  • These copolymers are commercially available, for example under the trade name Bynel 4105 from DuPont or Escorene FL00119 from Exxon.
  • Copolymers of ethylene with maleic anhydride and maleic anhydride grafted polymers or copolymers of ethylene are preferred as adhesion promoters.
  • the polymer film (P) may also contain additives.
  • additives are known to the person skilled in the art and are selected, for example, from the group consisting of stabilizers, dyes, antistatic agents, tackifiers, antiblocking agents, processing aids, antioxidants, light stabilizers, UV absorbers, lubricants and nucleating agents.
  • Suitable dyes are organic and inorganic pigments, such as, for example, sized titanium dioxide.
  • Suitable tackifiers are, for example, polyisobutylene (PIB) or ethylvinylacetate (EVA).
  • Suitable antiblocking agents are, for example, silica or calcium carbonate particles.
  • Suitable light stabilizers are, for example, so-called HALS (hindered amine light stabilizers).
  • HALS hinderedered amine light stabilizers
  • ethylenebisstearamide (EBS) wax can be used as a processing aid or lubricant.
  • Nucleating aids may be, for example, any types of organic or inorganic nucleating agents, e.g. Talk.
  • the additives may be contained both in the at least one first layer and in the at least one further layer. They can be contained in only one of these layers, as well as they are likely to be included in each of these layers. copolyamide
  • the polymer film (P) contains at least one copolyamide prepared by polymerizing the components (A) from 15 to 95% by weight of a first monomer mixture (M1) containing the components
  • (A1) at least one C4-Ci2 dicarboxylic acid and (A2) contains at least one first C 4 -C 12 -diamine,
  • component (A) and “first monomer mixture (M1)” are used synonymously in the context of the present invention and therefore have the same meaning.
  • the at least one copolyamide is prepared by polymerization of from 15 to 95% by weight of component (A) and from 5 to 85% by weight of component (B), preferably at least one copolyamide prepared by polymerization from 25 to 90% by weight % of component (A) and from 10 to 75% by weight of component (B), and particularly preferred is the at least one copolyamide prepared by polymerization of from 50 to 85% by weight of component (A) and from 15 to 50 wt .-% of component (B), wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B).
  • the sum of the weight percent of components (A) and (B) gives 100 wt .-%.
  • weight percentages of components (A) and (B) relate to the weight percentages of components (A) and (B) before the polymerization, that is, when components (A) and (B) are not yet together have reacted. During the polymerization, the weight ratio of the components (A) and (B) may change, if necessary.
  • the at least one copolyamide is prepared by polymerization of the components (A) and (B).
  • the polymerization of components (A) and (B) is known to those skilled in the art known.
  • the polymerization of components (A) and (B) is a condensation reaction.
  • components (A1) and (A2) contained in component (A) and, if appropriate, component (A3) described below react both with one another and with components (B1) and (B2) contained in component (B) ) and optionally with the component (B3) described below, which may also be present in component (B).
  • component (B1) and (B2) contained in component (B) and optionally also component (B3) described below react with each other and with components (A1) and (A2) contained in component (A) and optionally (A3).
  • amide bonds form between the individual components.
  • the optional components (A3) and (B3) are usually present during the polymerization at least partially open-chain, ie as an amino acid.
  • Suitable catalysts are all catalysts known to those skilled in the art, which catalyze the polymerization of components (A) and (B). Such catalysts are known in the art.
  • Preferred catalysts are phosphorus compounds such as sodium hypophosphite, phosphorous acid, triphenylphosphine or triphenyl phosphite.
  • the at least one copolyamide is formed which therefore contains building units derived from component (A) and building units derived from component (B).
  • Building units derived from component (A) contain building units derived from components (A1) and (A2) and optionally from component (A3), building blocks derived from component (B) Building units derived from the components (B1) and (B2), and optionally from the component (B3).
  • the copolyamide forms as a copolymer.
  • the copolymer may be a random copolymer, as well as it is possible that it is a block copolymer.
  • the copolyamide is a block copolymer.
  • the present invention therefore also provides a polymer film (P) in which the at least one copolyamide is a block copolymer.
  • blocks of units derived from component (B) and blocks of units derived from component (A) form. These alternate.
  • building units derived from component (A) alternate with building units derived from component (B). This alternation occurs statistically, for example, two units derived from component (B) may be followed by a unit derived from component (A), followed by another unit derived from component (B), to which then a structural unit follows, containing three units derived from component (A).
  • the preparation of the at least one copolyamide preferably comprises the following steps: a) polymerization of components (A) and (B) to obtain at least one first copolyamide, b) granulation of the at least one first copolyamide obtained in step a) to obtain at least one granulated copolyamide c) extraction of the at least one granulated copolyamide obtained in step b) with water to obtain at least one extracted copolyamide; d) drying of the at least one extracted copolyamide obtained in step c) at a temperature (Tr) to obtain the at least one copolyamide.
  • the present invention therefore also relates to a polymer film (P) in which the copolyamide is prepared in a process comprising the following steps: a) polymerization of the components (A) and (B) to obtain at least one first copolyamide, b) granulation of the c) extraction of the at least one granulated copolyamide obtained in step b) with water to obtain at least one extracted copolyamide, d) drying of the at least one extracted extract obtained in step c) Copolyamides at a temperature (Tr) to obtain the at least one copolyamide.
  • step a) can take place in all reactors known to those skilled in the art. Preference is given to stirred tank reactors. It is also possible to use adjuvants known to the person skilled in the art to improve the reaction process, for example defoamers such as polydimethylsiloxane (PDMS).
  • PDMS polydimethylsiloxane
  • step b) the at least one first copolyamide obtained in step a) can be granulated by all methods known to the person skilled in the art, for example by means of strand granulation or underwater granulation.
  • step c) can be carried out by all methods known to the person skilled in the art.
  • by-products formed during the polymerization of components (A) and (B) in step a) are usually extracted from the at least one granulated copolyamide.
  • step d) the at least one extracted copolyamide obtained in step c) is dried. Methods for drying are known in the art.
  • the at least one extracted copolyamide is dried at a temperature (Tr).
  • the temperature (Tr) is preferably above the at least one glass transition temperature (TG ⁇ C)) of the at least one copolyamide and below the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • the drying in step d) is usually carried out for a period in the range of 1 to 100 hours, preferably in the range of 2 to 50 hours and more preferably in the range of 3 to 40 hours.
  • step d the molecular weight of the at least one copolyamide is further increased.
  • the at least one copolyamide usually has at least one glass transition temperature (TG ⁇ O).
  • the at least one glass transition temperature (TG ⁇ O) is for example in the range of -10 to 70 ° C, preferably in the range of 10 to 65 ° C and particularly preferably in the range of 30 to 60 ° C, determined by means of ISO 1 1357-2: , 2014.
  • the present invention therefore also relates to a polymer film (P) in which the at least one copolyamide has at least one glass transition temperature (TG ⁇ C)) which is in the range from -10 to 70 ° C.
  • T ⁇ C glass transition temperature
  • the at least one copolyamide is a block copolymer in a preferred embodiment of the present invention
  • the at least one copolyamide usually has a first glass transition temperature (TG ⁇ OI) and a second glass transition temperature (TG ⁇ C) 2).
  • the first glass transition temperature (TG ⁇ C) I) of the at least one copolyamide is then for example in the range of 10 to 80 ° C, preferably in the range of 20 to 70 ° C and particularly preferably in the range of 30 to 60 ° C, determined according to ISO 1 1357-2: 2014.
  • the second glass transition temperature (TG ⁇ C) 2) of the at least one copolyamide is then for example in the range of -15 to 20 ° C, preferably in the range of -10 to 15 ° C and particularly preferably in the range of -5 to 10 ° C, determined according to ISO 1 1357-2: 2014.
  • the at least one glass transition temperature (TG ⁇ C)) and the first glass transition temperature (TG (OI) and the second glass transition temperature (TG ⁇ C) 2) of the at least one copolyamide are in accordance with ISO 1 1357-2: 2014 in the frame of the present invention respectively to the glass transition temperatures of the dry copolyamide.
  • dry means that the at least one copolyamide contains less than 1% by weight, preferably less than 0.5% by weight and more preferably less than 0.1% by weight, based on water More preferably, “dry” means that the at least one copolyamide contains no water, and most preferably that the at least one copolyamide contains no solvent.
  • the at least one copolyamide usually has a melting temperature (M (C)).
  • the melting temperature (TM ⁇ O) of the at least one copolyamide is, for example, in the range from 220 to 290 ° C., preferably in the range from 230 to 280 ° C. and particularly preferably in the range from 240 to 270 ° C., determined according to ISO 1 1357-3 : 2014.
  • the present invention therefore also relates to a polymer film (P) in which the at least one copolyamide has a melting temperature (TM ⁇ C)), wherein the melting temperature (TM ⁇ C)) in the range of 220 to 290 ° C.
  • the at least one copolyamide generally has a viscosity number (VZ (o) in the range from 120 to 300 ml / g, determined in a 0.5% strength by weight solution of the at least one copolyamide in 96% strength by weight sulfuric acid.
  • the viscosity number (VZ ⁇ o) of the at least one copolyamide is preferably in the range from 135 to 290 ml / g and particularly preferably in the range from 150 to 280 ml / g, determined in a 0.5% strength by weight solution of the at least one Copolyamides in 96 wt .-% sulfuric acid.
  • the present invention therefore also relates to a polymer film (P) in which the at least one copolyamide has a viscosity number (VZ ⁇ o) in the range from 120 to 300 ml / g, determined in a 0.5% by weight solution of the at least a copolyamide in 96% by weight sulfuric acid.
  • VZ ⁇ o viscosity number
  • component (A) is a first monomer mixture (M1).
  • the first monomer mixture (M1) contains the components (A1) at least one C4-C12 dicarboxylic acid and (A2) at least one first C4-C12 diamine.
  • a first monomer mixture (M1) is understood as meaning a mixture of two or more monomers, wherein at least the components (A1) and (A2) are contained in the first monomer mixture (M1).
  • component (A) and “at least one C4-C12 dicarboxylic acid” are used synonymously in the context of the present invention and therefore have the same meaning.
  • component (A2) and “at least one first C4-C12 diamine” are also used synonymously in the context of the present invention and therefore have the same meaning.
  • the first monomer mixture (M1) contains, for example, in the range from 45 to 55 mol% of component (A1) and in the range from 45 to 55 mol% of component (A2), in each case based on the sum of the mol% of the components ( A) and (B), preferably based on the total amount of the first monomer mixture (M1).
  • Component (A) preferably contains in the range from 47 to 53 mol% of component (A1) and in the range from 47 to 53 mol% of component (A2), in each case based on the sum of mol% of components (A1 ) and (A2), preferably based on the total amount of the component (A).
  • the component (A) particularly preferably contains in the range from 49 to 51 mol% of component (A1) and in the range from 49 to 51 mol% of component (A2), in each case based on the sum of the mol% of the components ( A1) and (A2), preferably based on the total amount of the component (A).
  • the present invention therefore also provides a polymer film (P) in which component (A) contains in the range of 45 to 55 mol% of component (A1) and in the range of 45 to 55 mol% of component (A2) , in each case based on the total amount of substance of component (A).
  • component (A1) The sum of the mol% of components (A1) and (A2) contained in component (A) usually gives 100 mol%.
  • the component (A) may additionally contain a component (A3), at least one lactam.
  • the present invention therefore also provides a polymer film (P) in which component (A) additionally contains a component (A3), at least one lactam.
  • component (A3) and “at least one lactam” are used synonymously in the context of the present invention and therefore have the same meaning.
  • the component (A) additionally contains the component (A3)
  • the component (A) be in the range of 35 to 49.95 mol% of the component (A1), in the range of 35 to 49.95 mol% of component (A2) and in the range of 0.1 to 25 mol% of component (A3), in each case based on the total amount of component (A).
  • the component (A) then particularly preferably contains in the range from 37 to 49.95 mol% of component (A1), in the range from 37 to 49.95 mol% of component (A2) and in the range from 0.1 to 20 mol% of component (A3), in each case based on the total amount of component (A).
  • component (A) then contains in the range of 40 to 49.95 mol% of component (A1), in the range of 40 to 49.95 mol% of component (A2) and in the range of 0.1 to 15 mol% of component (A3), in each case based on the total amount of component (A).
  • component (A) additionally contains component (A3), the molar percentages of components (A1), (A2) and (A3) usually add up to 100 mol%.
  • the first monomer mixture (M1) contains no component (A3), at least one lactam.
  • the first monomer mixture (M1) may also contain water.
  • component (A1) and (A2) and optionally the component (A3) of the component (A) can react with each other to give amides. This reaction is known to those skilled in the art. Therefore, component (A) may contain components (A1) and (A2) and optionally component (A3) in completely reacted form, in partially reacted form or in unreacted form. Component (A) preferably contains components (A1) and (A2) and optionally component (A3) in unreacted form.
  • “In unreacted form” in the context of the present invention means that component (A1) is present as the at least one C4-C12-dicarboxylic acid and component (A2) as the at least one first C4-C12-diamine and optionally the component If the components (A1) and (A2) and also, if appropriate, (A3) have reacted at least partially with one another, the components (A1) and (A2) and, if appropriate, (A3) are at least partially present as amide ,
  • component (A1) is at least one C 4 -C 12 -dicarboxylic acid.
  • at least one C 4 -C 12 dicarboxylic acid means both exactly one C 4 -C 12 dicarboxylic acid and one mixture of two or more C 4 -C 12 dicarboxylic acids
  • Invention understood aliphatic and / or aromatic compounds having 2 to 10 carbon atoms and two carboxy groups (-COOH groups). The aliphatic and / or aromatic compounds may be unsubstituted or additionally at least monosubstituted.
  • the aliphatic and / or aromatic compounds may carry one, two or more substituents which do not participate in the polymerization of components (A) and (B).
  • substituents are known to the person skilled in the art and are, for example, alkyl or cycloalkyl substituents.
  • the at least one C 4 -C 12 -dicarboxylic acid is preferably unsubstituted.
  • Suitable components (A1) are, for example, selected from the group consisting of butanedioic acid (succinic acid), pentanedioic acid (glutaric acid), hexanedioic acid (adipic acid), heptanedioic acid (pimelic acid), octanedioic acid (suberic acid, suberic acid), nonanedioic acid (azelaic acid), decanedioic acid (sebacic acid), Undecanedioic acid, dodecanedioic acid, terephthalic acid and isophthalic acid.
  • the component (A1) is preferably selected from the group consisting of pentanedioic acid (glurtaric acid), hexanedioic acid (adipic acid), decanedioic acid (sebacic acid), dodecanedioic acid, terephthalic acid and isophthalic acid.
  • the present invention therefore also provides a polymer film (P) in which component (A1) is selected from the group consisting of pentanedioic acid, hexanedioic acid, decanedioic acid, dodecanedioic acid, terephthalic acid and isophthalic acid.
  • the component (A2) is according to the invention at least one first C4-Ci2-diamine.
  • "At least one first C 4 -C 12 diamine” in the context of the present invention means both exactly one first C 4 -C 12 -diamine and a mixture of two or more first C 4 -C 12 diamines.
  • C 4 -C 12 -diamine is understood as meaning aliphatic and / or aromatic compounds having 4 to 12 carbon atoms and two amino groups (-IMH 2 groups)
  • the aliphatic and / or aromatic compounds may be unsubstituted or additionally at least monosubstituted
  • they may carry one, two or more substituents that do not participate in the polymerization of components (A) and (B).
  • substituents are, for example, alkyl or cycloalkyl substituents. These are known to those skilled in the art.
  • the at least one first C 4 -C 12 -diamine is unsubstituted.
  • Suitable components (A2) are, for example, selected from the group consisting of 1,4-diaminobutane (butane-1,4-diamine; tetramethylenediamine; putrescine), 1,5-diaminopentane (1, 5-pentamethylenediamine; pentane-1, 5 cadaverine), 1,6-diaminohexane (1,6-hexamethylenediamine, hexane-1,6-diamine), 1,7-diaminoheptane, 1,8-diaminoctane, 1,9-diaminononane, 1,10-diaminodecane ( 1, 10-decamethylenediamine), 1, 1 1 diaminoundecane (1,1,1-undecamethylenediamine) and 1,12-diaminododecane (1,12-dodecamethylenediamine).
  • 1,4-diaminobutane butane-1,4-d
  • component (A2) is selected from the group consisting of 1, 4-butanediamine, 1, 5-pentamethylenediamine, 1, 6-hexamethylenediamine, 1, 10-decamethylenediamine and 1, 12-dodecamethylenediamine.
  • the present invention therefore also relates to a polymer film (P) in which the component (A2) is selected from the group consisting of 1, 4-butanediamine, 1, 5-pentamethylenediamine, 1, 6-hexamethylenediamine, 1, 10-decamethylenediamine and 1, 12-dodecamethylenediamine.
  • the component (A2) is selected from the group consisting of 1, 4-butanediamine, 1, 5-pentamethylenediamine, 1, 6-hexamethylenediamine, 1, 10-decamethylenediamine and 1, 12-dodecamethylenediamine.
  • Component (A3) may additionally contain component (A3), at least one lactam.
  • At least one lactam means both exactly one lactam and a mixture of two or more lactams. Lactams are known to the skilled worker as such. Lactams having 4 to 12 carbon atoms are preferred according to the invention.
  • lactams are understood to mean cyclic amides which have in the ring preferably 4 to 12, particularly preferably 5 to 8, carbon atoms.
  • Suitable lactams are for example selected from the group consisting of
  • 6-aminohexanoic acid lactam (hexano-6-lactam: ⁇ -lactam; ⁇ -caprolactam),
  • the present invention therefore also provides a polymer film (P) in which component (A3) is selected from the group consisting of 3-aminopropanoic acid lactam, 4-aminobutanoic acid lactam, 5-aminopentanoic acid lactam, 6-aminohexanoic acid lactam, 7-aminoheptanoic acid lactam, 8-aminooctanoic acid lactam , 9-aminononanoic acid lactam, 10-aminodecanoic acid lactam, 1-amino undecanoic acid lactam and
  • the lactams may be unsubstituted or at least monosubstituted. In the event that at least monosubstituted lactams are used, they may carry on the nitrogen atom and / or on the carbon atoms of the ring one, two or more substituents independently selected from the group consisting of C 1 to C 10 alkyl, C 5 - to C6-cycloalkyl and C5- to Cio-aryl.
  • C 1 to C 10 -alkyl substituents examples include methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl and tert-butyl.
  • a suitable C5 to C6 cycloalkyl substituent is, for example, cyclohexyl.
  • Preferred C5 to Cio-aryl substituents are phenyl and anthranyl.
  • Unsubstituted lactams are preferably used, with ⁇ -lactam ( ⁇ -butyrolactam), ⁇ -lactam ( ⁇ -valerolactam) and ⁇ -lactam ( ⁇ -caprolactam) being preferred. Particularly preferred are ⁇ -lactam ( ⁇ -valerolactam) and ⁇ -lactam ( ⁇ -caprolactam), with ⁇ -caprolactam being particularly preferred.
  • component (B) is a second monomer mixture (M2).
  • the second monomer mixture (M2) contains the components (B1), at least one C32-C4o dimer acid and (B2) at least one second C4-C12 diamine.
  • a second monomer mixture (M2) is understood as meaning a mixture of two or more monomers, wherein at least the components (B1) and (B2) are contained in the second monomer mixture (M2).
  • component (B1) and “at least one C32-C4o dimer acid” are used synonymously in the context of the present invention and therefore have the same meaning.
  • component (B2) and “at least one second C4-C12 diamine”. These terms are also used synonymously in the context of the present invention and therefore have the same meaning.
  • the second monomer mixture (M2) contains, for example, in the range from 45 to 55 mol% of component (B1) and in the range from 45 to 55 mol% of component (B2), in each case based on the sum of the molar percentages of components (B1) and (B2), preferably based on the total amount of material of the second monomer mixture (M2).
  • Component (B) preferably contains in the range from 47 to 53 mol% of component (B1) and in the range from 47 to 53 mol% of component (B2) in each case based on the sum of the molar percentages of components (B1) and ( B2), preferably based on the total amount of substance of component (B).
  • Component (B) particularly preferably contains in the range from 49 to 51 mol% of component (B1) and in the range from 49 to 51 mol% of component (B2), in each case based on the sum of the molar percentages of components (B1). and (B2), preferably based on the total amount of component (B).
  • the present invention therefore also provides a polymer film (P) in which component (B) contains in the range from 45 to 55 mol% of component (B1) and in the range from 45 to 55 mol% of component (B2) , in each case based on the total amount of substance of component (B).
  • component (B1) The sum of the mol% of components (B1) and (B2) contained in component (B) is usually 100 mol%.
  • the component (B) may additionally contain a component (B3), at least one lactam.
  • the present invention therefore also provides a polymer film (P) in which component (B) additionally contains a component (B3), at least one lactam.
  • component (B3) and “at least one lactam” are used synonymously in the context of the present invention and therefore have the same meaning.
  • component (B3) which is optionally contained in the second monomer mixture (M2)
  • the previously described embodiments and preferences for component (A3), which is optionally contained in the first monomer mixture (M1) apply accordingly.
  • the component (B3) optionally additionally present in the second monomer mixture (M2) may be identical or different from the one which may be present in the first monomer mixture (M1) contained component (A3).
  • the component (A3) optionally contained in the first monomer mixture (M1) and the component (B3) optionally present in the second monomer mixture (M2) are the same.
  • the component (B) additionally contains the component (B3) it is preferable that the component (B) be in the range of 35 to 49.95 mol% of the component (B1), in the range of 35 to 49.95 mol% of component (B2) and in the range of 0.1 to 25 mol% of component (B3), in each case based on the total amount of substance of component (B).
  • the component (B) then particularly preferably contains in the range from 37 to 49.95 mol% of component (B1), in the range from 37 to 49.95 mol% of component (B2) and in the range from 0.1 to 20 mol% of component (B3), in each case based on the total amount of substance of component (B). Most preferably, component (B) then contains in the range from 40 to 49.95 mol% of component (B1), in the range from 40 to 49.95 mol% of component (B2) and in the range of 0.1 to 15 mol% of component (B3), in each case based on the total amount of component (B). If component (B) additionally contains component (B3), the sum of the mole percent of components (B1), (B2) and (B3) usually gives 100 mole percent.
  • the second monomer mixture (M2) contains no component (B3), at least one lactam.
  • the second monomer mixture (M2) may also contain water.
  • component (B1) and (B2) and optionally (B3) of the component (B) may react with each other to give amides. This reaction is known to those skilled in the art. Therefore, component (B) may contain components (B1) and (B2) and optionally (B3) in fully reacted form, in partially reacted form or in unreacted form. Component (B) preferably contains the components (B1) and (B2) and optionally (B3) in unreacted form.
  • unreacted form means that component (B1) is present as the at least one C 32 -C 40 dimer acid and component (B2) is present as the at least one second C 4 -C 12 diamine and optionally the component If the components (B1) and (B2) and also, if appropriate, (B3) have reacted at least partially with one another, the components (B1) and (B2) and, if appropriate, (B3) are at least partially present as amide ,
  • the component (B2) contained in the second monomer mixture (M2), the at least one second C4-C12 diamine the previously described embodiments and preferences for the component (A2) contained in the first monomer mixture (M1) apply, which comprises at least one first C4 -Ci2-diamine, according to.
  • the present invention therefore also provides a process in which the component (B2) is selected from the group consisting of 1, 4-butanediamine, 1, 5-pentamethylenediamine, 1, 6-hexmethylenediamine, 1, 10-decamethylenediamine and 1, 12-dodecamethylenediamine.
  • the present invention therefore also provides a process in which component (A2) and component (B2) are each independently selected from the group consisting of 1, 4-butanediamine, 1, 5-pentamethylenediamine, 1, 6- Hexamethylenediamine, 1, 10-decamethylenediamine and 1, 12-dodecamethylenediamine.
  • the component (B2) may be the same as the component (A2) or may be different from it. Preferably, component (B2) is the same as component (A2).
  • the component (B1) is according to the invention at least one C32-C4o dimer acid.
  • At least one C32-C4o dimer acid in the context of the present invention means both exactly one C32-C4o dimer acid and one mixture of two or more C32-C40 dimer acids.
  • Dimer acids are also referred to as dimer fatty acids.
  • C32-C4o dimer acids are known to those skilled in the art and are usually prepared by dimerization of unsaturated fatty acids. This dimerization can be catalyzed by clays, for example.
  • Suitable unsaturated fatty acids for preparing the at least one C 32 -C 40 dimer acid are known to the person skilled in the art and are, for example, unsaturated C 16 -fatty acids, unsaturated C 18 -fatty acids and unsaturated C 20 -fatty acids.
  • the component (B1) is therefore preferably prepared starting from unsaturated fatty acids selected from the group consisting of unsaturated C 16 -fatty acids, unsaturated cis-fatty acids and unsaturated C 20 -fatty acids, the unsaturated C 18 -fatty acids being particularly preferred.
  • the present invention therefore also provides a polymer film (P) in which component (B1) is prepared starting from unsaturated fatty acids selected from the group consisting of unsaturated C 16 fatty acids, unsaturated cis fatty acids and unsaturated C 20 fatty acids.
  • a suitable unsaturated C 16 -fatty acid is, for example, palmitoleic acid ((9Z) -hexadeca-9-enoic acid).
  • Suitable unsaturated cis-fatty acids are, for example, selected from the group consisting of petroselinic acid ((6Z) -octadeca-6-enoic acid), oleic acid
  • Suitable unsaturated C2o-fatty acids are, for example, selected from the group consisting of gadoleic acid ((9Z) -eicosa-9-enoic acid), icosenoic acid ((11Z) -eicosa-1-enoic acid), arachidonic acid ((5Z, 8Z, 1 1Z, 14Z) -eicosa-5,8,11,14-tetraenoic acid) and timnodonic acid ((5Z, 8Z, 11Z, 14Z, 17Z) -eicosa-5,8,1,1,14,7-pentaenoic acid).
  • the component (B1) is particularly preferably at least one C36 dimer acid.
  • the at least one C36 dimer acid is preferably prepared starting from unsaturated cis fatty acids. More preferably, the C36 dimer acid is prepared from cis fatty acids selected from the group consisting of petroselinic acid ((6Z) -octadeca-6-enoic acid), oleic acid ((9Z) -octadeca-9-enoic acid), elaidic acid (9E Octadeca-9-enoic acid), vaccenic acid ((1 1 E) -octadeca-1-enoic acid) and linoleic acid ((9Z, 12Z) -octadeca-9,12-dienoic acid).
  • cis fatty acids selected from the group consisting of petroselinic acid ((6Z) -octadeca-6-enoic acid), oleic acid ((9Z) -octadeca-9-enoic acid), elaidic acid (9E Octa
  • trimer acids can form in the preparation of component (B1) from unsaturated fatty acids, and residues of unreacted unsaturated fatty acid can also be left over.
  • component (B1) preferably contains at most 0.5% by weight of unreacted unsaturated fatty acid and at most 0.5% by weight of trimer acid, especially preferably at most 0.2% by weight of unreacted unsaturated fatty acid and at most 0.2% by weight of trimer acid, in each case based on the total weight of component (B1).
  • Dimer acids are generally and in particular in the context of the present invention thus mixtures referred to, which are prepared by oligomerization of unsaturated fatty acids. They can be prepared, for example, by catalytic dimerization of vegetable, unsaturated fatty acids, using as starting materials in particular unsaturated C 16- to C 20 -fatty acids.
  • the linkage proceeds primarily according to the Diels-Alder type and, depending on the number and position of the double bonds of the fatty acids used to prepare the dimer acids, mixtures of predominantly dimeric products which are cycloaliphatic, linear-aliphatic, branched aliphatic and also between the carboxyl groups C6 have aromatic hydrocarbon groups.
  • the aliphatic radicals may be saturated or unsaturated and also the proportion of aromatic groups may vary.
  • the residues between the carboxylic acid groups then contain, for example, 32 to 40 carbon atoms.
  • fatty acids containing 18 carbon atoms are used for the preparation, so that the dimeric product thus has 36 carbon atoms.
  • the radicals linking the carboxyl groups of the dimer fatty acids have no unsaturated bonds and no aromatic hydrocarbon radicals.
  • Linolenic, linoleic and / or oleic acid are particularly preferably used.
  • mixtures are formed in the above-mentioned oligomerization, which contain mainly dimeric, but also trimeric molecules and monomeric molecules and other by-products. Usually, it is purified by distillation.
  • dimer acids generally contain at least 80% by weight of dimeric molecules, up to 19% by weight of trimeric molecules and at most 1% by weight of monomeric molecules and other by-products.
  • dimer acids which consist of at least 90% by weight, preferably at least 95% by weight, very particularly preferably at least 98% by weight, of dimeric fatty acid molecules.
  • the determination of the proportions of monomeric, dimeric and trimeric molecules and other by-products in the dimer acids can be carried out, for example, by means of gas chromatography (GC).
  • GC gas chromatography
  • the dimer acids are converted before the GC analysis via the boron trifluoride method to the corresponding methyl esters (see DIN EN ISO 5509) and then analyzed by GC.
  • the basic characteristic of "dimer acids" is that their preparation comprises the oligomerization of unsaturated fatty acids, which is predominantly formed, ie preferably at least 80% by weight, more preferably at least 90% by weight.
  • the dimer acids to be used can be obtained as commercial products. Examples include Radiacid 0970, Radiacid 0971, Radiacid 0972, Radiacid 0975, Radiacid 0976 and Radiacid 0977 from Oleon, Pripol 1006, Pripol 1009, Pripol 1012, and Pripol 1013 Croda, Empol 1008, Empol 1012, Empol 1061 and Empol 1062 from BASF SE and Unidyme 10 and Unidym Tl from Arizona Chemical.
  • the component (B1) has, for example, an acid number in the range from 190 to 200 mg KOH / g.
  • the polymer film (P) according to the invention is preferably produced in a process comprising the following steps. i) providing at least one copolyamide prepared by polymerizing the
  • (A2) contains at least one first C 4 -C 12 -diamine
  • (B2) contains at least one second C4-C12 diamine, wherein the weight percentages of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder, ii) extrusion of the at least one copolyamide provided in step i) in molten form from the first extruder through a die to obtain a film of the at least one polyamide in molten form, iii) cooling the film of the at least one copolyamide in molten form obtained in step ii), the at least one copolyamide solidifying to obtain the polymer film (P).
  • the present invention therefore also provides a process for the preparation of a polymer film (P) according to the invention, comprising the steps of i) providing at least one copolyamide prepared by polymerization of the components
  • (A2) contains at least one first C 4 -C 12 -diamine
  • step i) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder , ü) extruding the at least one copolyamide in molten form provided in step i) from the first extruder through a die to obtain a film of the at least one copolyamide in molten form, iii) cooling the film obtained in step ii) of the at least one copolyamide in molten form, wherein the at least one copolyamide is solidified to obtain the polymer film (P).
  • step i) the at least one copolyamide is provided in molten form in a first extruder.
  • a first extruder means both exactly one first extruder and two or more first extruders. Usually as many first extruders are used as first layers which contain the at least one copolyamide in which the polymer film (P) is contained should.
  • the polymer film (P) contains exactly one first layer which contains the at least one copolyamide, exactly one first extruder is used. If the polymer film (P) contains exactly two first layers containing the at least one copolyamide, exactly two first extruders are used. If the polymer film (P) contains exactly five first layers containing the at least one copolyamide, exactly five first extruders are used. For example, 1 to 1 1 first extruder used, preferably 1 to 5 first extruder and more preferably 1 to 3 first extruder.
  • step i) For the at least one copolyamide which is provided in step i), the above-described embodiments and preferences for the at least one copolyamide contained in the polymer film (P) apply correspondingly.
  • the at least one copolyamide is provided in molten form.
  • “In molten form” in the context of the present invention means that the at least one copolyamide is provided at a temperature which is above the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • “In molten form” means that the at least a copolyamide has a temperature which is above the melting temperature (TM ⁇ C)) of the at least one copolyamide. If the at least one copolyamide is in molten form, the at least one copolyamide is free-flowing.
  • the at least one copolyamide in step i) is at a temperature in the range 210 to 340 ° C, preferably in the range of 240 to 330 ° C, and more preferably in the range of 270 to 320 ° C, provided, respectively, provided that the temperature at which the at least one copolyamide is provided is above the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • the at least one copolyamide can be provided in molten form in the first extruder by all methods known to those skilled in the art.
  • the at least one copolyamide may be supplied in molten or solid form to the first extruder. If the at least one copolyamide is fed to the first extruder in solid form, it can be fed to the first extruder, for example, as granules and / or as a powder. The at least one copolyamide is then melted in the first extruder and thus provided in molten form in the first extruder. This embodiment is preferred.
  • the components (A) and (B) are polymerized directly in the first extruder and thus the at least one copolyamide in molten form is provided in the first extruder. Processes for this are known to the person skilled in the art.
  • step ii) the at least one copolyamide in molten form is extruded from the first extruder through a die to give a film of the at least one copolyamide in molten form.
  • a nozzle means both exactly one nozzle and two or more nozzles.According to the invention, exactly one nozzle is preferred.A nozzle is suitable for all nozzles known to those skilled in the art, which make it possible to produce a film of the at least one copolyamide in FIG Such nozzles are, for example, annular nozzles or slot nozzles.
  • Suitable annular nozzles and slot nozzles are known in the art as such.
  • step ii) the at least one copolyamide in molten form from the first extruder with the at least one further polymer (wP) in molten form from the further extruder in the Nozzle, for example in the annular nozzle or in the slot nozzle, is brought together.
  • step ii) the at least one copolyamide in molten form from the first extruder with the at least one further polymer (wP) in molten form from the further extruder are combined in the nozzle in such a way that the film of the at least one obtained in step ii) Copolyamide and the at least one other polymer (wP), each in molten form, at least one first layer containing the at least one Copolyamide contains in molten form, and at least one further layer containing the at least one further polymer (wP) in molten form.
  • the thickness of the film of the at least one copolyamide in molten form is in the range of 0.1 ⁇ m to 1 mm, preferably in the range of 5 to 500 ⁇ m, and particularly preferably in the range of 20 to 100 ⁇ m.
  • the film of the at least one copolyamide in molten form may be, for example, a flat film or a tubular film.
  • a tubular film is usually obtained when an annular nozzle is used as a nozzle, a flat film is obtained when a slit nozzle is used as a nozzle.
  • step iii) the film of the at least one copolyamide obtained in step ii) is cooled in molten form. As a result, the at least one copolyamide solidifies to obtain the polymer film (P).
  • the film of the at least one copolyamide in molten form all methods known to those skilled in the art are suitable.
  • the film of the at least one copolyamide may be cooled in molten form by air or water cooling or by contact with a cold surface.
  • the film of the at least one copolyamide in molten form is cooled in step iii), for example to a temperature below the melting temperature (TM ⁇ O) of the at least one copolyamide, to obtain the polymer film (P).
  • the film of the at least one copolyamide in molten form in step iii) is cooled to a temperature which is below the at least one glass transition temperature (TG ⁇ C)) of the at least one copolyamide.
  • the film of the at least one copolyamide in molten form in step iii) is cooled to a temperature in the range of 0 to 100 ° C, preferably in the range of 10 to 80 ° C and particularly preferably in the range of 15 to 70 ° C, wherein the temperature to which the film of the at least one copolyamide is cooled in molten form is below the melting temperature (TM ⁇ C)), preferably below the at least one glass transition temperature (TG ⁇ C)) of the at least one copolyamide.
  • TM ⁇ C melting temperature
  • TG ⁇ C glass transition temperature
  • the present invention therefore also provides a process for the preparation of a polymer film (P), in which in step iii) the film of the at least one copolyamide in molten form at a temperature below the melting temperature (TM ⁇ C)) of the at least one copolyamide is, is cooled.
  • Step iii) For the polymer film (P) obtained in step iii), the embodiments and preferences described above for the polymer film (P) according to the invention apply correspondingly. Steps ii) and iii) can be carried out successively or simultaneously.
  • a step i1) is preferably carried out in which at least one further polymer (wP) is provided in molten form in a further extruder.
  • the process for producing the polymer film (P) then comprises the following steps: i) providing at least one copolyamide prepared by polymerizing the components
  • (A2) contains at least one first C4-Ci2 diamine
  • (B2) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder i1) providing at least one further polymer (wP) in molten form in another extruder, ii) extruding the at least one copolyamide in step i) in molten form from the first extruder through a die and extruding the one provided in step i 1) at least one further polymer (wP) in molten form from the further extruder through the die to give a film of the at least one copolyamide and the at least one other polymer (wP), each in molten form, iii) cooling the film obtained in step ii) the at least one copolyamide and the at least one further polymer (wP), each in molten form, wherein the at least one copolyamide and / or the mi At least
  • step i1) the at least one further polymer (wP) is provided in molten form in another extruder.
  • another extruder means both exactly one further extruder and two or more further extruders, two or more further extruders being preferred.
  • 1 to 13 further extruders are used, preferably 1 to 1 1 further extruders and particularly preferably 1 to 7 further extruders.
  • the polymer film (P) contains exactly one further layer which contains the at least one further polymer (wP), exactly one further extruder is used. If the polymer film (P) contains exactly two further layers containing the at least one further polymer (wP), exactly two further extruders are used. If the polymer film (P) contains exactly five further layers containing the at least one further polymer (wP), exactly five further extruders are used.
  • the above-described embodiments and preferences for the optionally in the polymer film (P) contained at least one further polymer (wP) apply accordingly.
  • the at least one further polymer (wP) in step i1) is provided in molten form.
  • “In molten form” means that the at least one further polymer (wP) is provided at a temperature above the melting temperature (TM ⁇ W P)) of the at least one other polymer (wP).
  • “In molten form” Thus, that the at least one further polymer (wP) has a temperature which is above the melting temperature (TM ⁇ W P)) of the at least one further polymer (wP). If the at least one further polymer (wP) is present in molten form, then the at least one further polymer (wP) is free-flowing.
  • Flowable means that the at least one further polymer (wP) can be conveyed in the further extruder and that the at least one further polymer (wP) can be extruded from the other extruder.
  • the at least one further polymer (wP) in step i1) at a temperature in the range of 120 to 350 ° C, preferably in the range of 130 to 300 ° C and particularly preferably in the range from 140 to 250 ° C, provided in each case on the condition that the temperature at which the at least one further polymer (wP) is provided above the melting temperature (TM ⁇ W P)) of the at least one further polymer (wP) is located.
  • the at least one further polymer (wP) can be provided in molten form in the further extruder by all methods known to those skilled in the art.
  • the at least one further polymer (wP) can be supplied in molten or solid form to the other extruder. If the at least one further polymer (wP) is fed to the further extruder in solid form, then it can be fed to the further extruder, for example as granules and / or as a powder. The at least one further polymer (wP) is then melted in the further extruder and thus provided in molten form in the further extruder.
  • Step i1) is usually carried out simultaneously with step i).
  • step i1) when the step i1) is carried out, the above-described embodiments and preferences for the steps i), ii) and iii) apply, if step i1) is not carried out.
  • the film obtained in step ii) of the at least one copolyamide and the at least one further polymer (wP), in each case in molten form, contains the at least one copolyamide in at least one first layer and the at least one further polymer (wP) in at least one further layer ,
  • the film obtained in step ii) contains as many first layers containing the at least one copolyamide in molten form as were first extruders used in step i) and as many further layers containing the at least one further polymer (wP) in contain molten form, as more extruders have been used in step i1).
  • step i1) when step i1) is performed, the polymer film (P) obtained in step iii) is a multilayer film.
  • the polymer film (P) is stretched.
  • the polymer film (P) can be stretched after step iii), it is also possible to remove the polymer film (P) during step iii), ie during the cooling of the film of the at least one copolyamide and optionally the at least one further polymer (wP) to stretch.
  • Steps iii) and iv) can be performed sequentially or simultaneously.
  • the polymer chains of the at least one copolyamide align and the crystallinity of the at least one copolyamide can be increased.
  • the polymer chains of the at least one further polymer (wP) optionally present in the polymer film (P) also align during stretching.
  • the crystallinity of the at least one further polymer (wP) can also increase.
  • the stretching can be carried out by all methods known to the person skilled in the art.
  • the polymer film (P) can be stretched by passing it over at least one roller, preferably a roller system, or by stretching it in its width.
  • the polymer film (P) is obtained as a tube, it is also possible that the polymer film (P) is stretched by blowing air into the tube of the polymer film (P) and thereby stretching the polymer film (P).
  • the polymer film (P) is guided over at least one roller, preferably via a roller system, then the polymer film (P) is stretched in the extrusion direction, ie in its length. If the polymer film (P), however, stretched in its width, it is stretched perpendicular to the extrusion direction.
  • the polymer film (P) is guided for stretching over at least one roller, preferably via a roller system, then the polymer chains of the at least one copolyamide and, if appropriate, of the at least one further polymer (wP) are oriented parallel to the direction in which they are drawn , The resulting stretched polymer film (vP) is then uniaxially oriented. Also, the obtained stretched polymer film (vP) is uniaxially oriented when the polymer film (P) is stretched to stretch in width. Even then, the polymer chains of the at least one copolyamide and optionally of the at least one further polymer (wP) are oriented parallel to the direction in which they are drawn.
  • Uniaxially oriented means that the polymer chains are oriented substantially in one direction.
  • the polymer film (P) is guided over a roller system for stretching and additionally stretched in its width, then the polymer chains of the at least one copolyamide and optionally of the at least one further polymer (wP) are oriented parallel to both directions to be drawn.
  • the resulting stretched polymer film (vP) is then biaxially oriented.
  • "Biaxially oriented" means that the polymer chains are oriented substantially in two different directions, preferably perpendicular to each other.
  • the polymer film (P) is obtained as a tube and the polymer film (P) is stretched by blowing air into the tube of the polymer film (P), the obtained stretched polymer film (vP) is uniaxially oriented.
  • the polymer film (P) is obtained as a tube and the polymer film (P) is stretched by blowing air into the tube of the polymer film (P) and simultaneously passing it over rollers is also stretched, the obtained stretched polymer film (vP) is biaxially oriented.
  • the polymer film (P) is usually stretched at a temperature which is above the at least one glass transition temperature (TG ⁇ C)) of the at least one copolyamide and which is below the melting temperature (TM ⁇ C)) of the at least one copolyamide. If the polymer film (P) is a multilayer film, it is further preferred that the polymer film (P) be stretched at a temperature lower than the melting temperature (TM ( W P)) of the at least one other polymer (wP), particularly preferably at a temperature which is below the melting temperature of the melting at least one further polymer (wP) at the lowest temperature.
  • the polymer film (P) of the present invention can be produced, for example, by a casting method, a blown method, a biaxially-oriented polyamide film method (BOPA method), or a multiblas method.
  • the subject of the present invention is therefore also a polymer film (P) which is produced in a casting process, in a blown process, in a biaxially-oriented polyamide film process or in a multiblas process.
  • the casting process, the blown process, the biaxially-oriented polyamide film process and the multi-glass process are known to those skilled in the art.
  • the polymer film (P) is stretched by these methods, so that a stretched polymer film (P) is obtained.
  • a casting process for producing the polymer film (P) preferably comprises the following steps i-c) to iv-c): i-c) providing at least one copolyamide prepared by polymerizing the components
  • (A2) contains at least one first C 4 -C 12 -diamine
  • (B2) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder , ii-c) extruding the at least one copolyamide provided in step ic) from the first extruder through a die to give a film of the at least one copolyamide in molten form, iii-c) cooling the one obtained in step ii-c) Film of the at least one copolyamide in molten form, wherein the at least one copolyamide solidifies to obtain the polymer film (P), iv-c) stretching the polymer film (P) obtained in step iii-c) by exposing the polymer film (P) over at least one Roll, preferably via a roller system, is performed to obtain a stretched polymer film (vP).
  • the nozzle used in the casting process in step ii-c) is usually a slot die.
  • the film of the at least one copolyamide in molten form obtained in step ii-c) is therefore preferably a flat film, so that the polymer film (P) obtained in step iii-c) and the stretched polymer film (vp) obtained in step iv-c) are preferably a flat sheet is.
  • steps iii-c) and iv-c) may be performed sequentially or simultaneously.
  • steps iii-c) and iv-c) are carried out simultaneously, more preferably, steps iii-c) and iv-c) are carried out simultaneously and directly after step ii-c).
  • the at least one roll used in step iv-c), preferably the roll system is cooled during step iv-c).
  • a blowing method for producing the polymer film (P) preferably comprises the following steps i-b) to iv-b): i) providing at least one copolyamide prepared by polymerizing the
  • (A2) contains at least one first C 4 -C 12 -diamine
  • (B2) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder ii) b) extruding the at least one copolyamide in molten form from the first extruder provided in step ib) through a nozzle which is an annular die to obtain a tubular film of the at least one copolyamide in molten form; Step ii-b) obtained tube film of the at least one
  • Copolyamides in molten form wherein the at least one copolyamide solidifies to obtain the polymer film (P), iv-b) stretching the polymer film (P) obtained in step iii-b) by blowing air into the hose of the polymer film (P) Obtaining a stretched polymer film (vP).
  • the nozzle used in step ii-b) of the blowing process is preferably a stack dye, a helical distributor dye or a mixed form thereof.
  • Steps iii-b) and iv-b) can be carried out simultaneously or sequentially in the blowing process In the blowing process, steps iii-b) and iv-b) are carried out simultaneously.
  • a biaxially-oriented polyamide film process for producing the polymer film (P) preferably comprises the following steps i-o) to iv-o): i-o) providing at least one copolyamide prepared by polymerizing the
  • the at least one copolyamide solidifying to obtain the polymer film (P), iv-o) stretching the polymer film (P) obtained in step iii-o), by passing the polymer film (P) over at least one roller, preferably a roller system, and stretching it in width to obtain the stretched polymer film (vP).
  • the nozzle used in the biaxially-oriented polyamide film process in step ii-o) is usually a slot die.
  • the film of the at least one copolyamide in molten form obtained in step ii-o) is therefore preferably a flat film so that the polymer film (P) obtained in step iii-o) and the stretched polymer film (vP) obtained in step iv-o) is preferably one Flat film is.
  • steps iii-o) and iv-o) can be carried out successively or simultaneously, preferably steps iii-o) and iv-o) are carried out successively.
  • steps iii-o) and iv-o) are carried out successively and the polymer film (P) obtained in step iii-o) is heated before step iv-o).
  • the polymer film (P) before step iv-o) is heated to a temperature which is above the at least one glass transition temperature (TG ⁇ C)) of the at least one copolyamide contained in the polymer film (P) and below Melting temperature (TM ⁇ C)) of the polymer film (P) contained at least one copolyamide.
  • the polymer film (P) is then preferably stretched in step iv-o) at the temperature to which it is heated prior to step iv-o).
  • a multi-glass process for producing the polymer film (P) preferably comprises the following steps i-m) to iv-m): i-m) providing at least one copolyamide prepared by polymerizing the components
  • (A1) at least one C4-Ci2 dicarboxylic acid and (A2) contains at least one first C 4 -C 12 -diamine,
  • (B2) at least one second C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder ii-m) extruding the at least one copolyamide provided in step im) from the first extruder through a die which is an annular die to obtain a tubular film of the at least one copolyamide in molten form; iii-m) cooling the in Step ii-m) of the at least one copolyamide in molten form, the at least one copolyamide solidifying to obtain the polymer film (P), iv-m) stretching the polymer film (P) obtained in step iii-m) by adding air into blowing the tubing of the polymer film (P) and simultaneously passing the polymer film (P) over at least one roller, preferably a roller system, to obtain a stretched polymer film (vP).
  • the tubular film of the at least one copolyamide is cooled in molten form in step iii-m) in a water bath.
  • steps iii-m) and iv-m) can be carried out simultaneously or successively, preferably steps iii-m) and iv-m) are carried out successively. Particularly preferably, steps iii-m) and iv-m) are carried out successively and the polymer film (P) obtained in step iii-m) is heated before step iv-m).
  • the polymer film (P) it is preferable for the polymer film (P) to be heated to a temperature above the at least one glass transition temperature (TG ⁇ C)) of the polymer film (P) before step iv-m) is at least one copolyamide and below the melting temperature (TM ⁇ C)) of the polymer film (P) contained at least one copolyamide.
  • the polymer film (P) is then preferably stretched in step iv-m) at the temperature to which it is heated prior to step iv-m).
  • step i1) in which at least one further polymer (wP) in a further extruder in molten form and then according to step ii) of the process for producing the polymer film (P) in step ii-c), in step ii-b), in step ii-o) and in step ii-m) Film of the at least one copolyamide and of the at least one further polymer (wP), in each case in molten form, and this is obtained according to step iii) of the process for producing the polymer film (P) in step iii-c), in step iii-b) , in step iii-o) and in step iii-m) is cooled.
  • step i1) the previously described embodiments and preferences for the optionally performed step i1) of the method for producing the polymer film (P) apply accordingly.
  • step i1) is performed in the biaxially-oriented polyamide film method.
  • no further polymer (wP) is preferably provided in a further extruder.
  • the contained stretched polymer film (P) can be wound up after its production, for example. Processes for this are known to the person skilled in the art. If the stretched polymer film (vP) is contained as a tube, such as blow molding and the multi-glass process, the tube may also be slit prior to winding. A slit film can then be wound on one or more rollers. Use of the polymer film (P)
  • the polymer film (P) according to the invention can be used in all areas known to the person skilled in the art in which polymer films are used.
  • the polymer film (P) according to the invention is suitable for films with high service temperatures, which also have to be flexible. These include packaging films, such as fried films, also called oven bags, as well as technical films such as, for example, foils for casting, for example, for the casting of wind turbines.
  • the polymer film (P) according to the invention is therefore particularly suitable as a packaging film or as a technical film.
  • the present invention therefore also relates to the use of the polymer film (P) according to the invention as a technical film or as a packaging film.

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Abstract

La présente invention concerne un film polymère (P) contenant au moins un copolyamide. Ce copolyamide est préparé par polymérisation d'un premier mélange de monomères (M1) et d'un second mélange de monomères (M2). La présente invention concerne en outre un procédé de fabrication du film polymère (P) ainsi que l'utilisation du film polymère (P) pour des applications à haute température.
EP17764795.5A 2016-09-14 2017-09-05 Film polymère contenant un copolyamide formé à partir au moins d'une diamine, d'un acide dicarboxylique et d'un acide dimère Pending EP3512902A1 (fr)

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Application Number Priority Date Filing Date Title
EP16188757 2016-09-14
PCT/EP2017/072230 WO2018050488A1 (fr) 2016-09-14 2017-09-05 Film polymère contenant un copolyamide formé à partir au moins d'une diamine, d'un acide dicarboxylique et d'un acide dimère

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EP (1) EP3512902A1 (fr)
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WO2019147457A2 (fr) 2018-01-23 2019-08-01 Eastman Chemical Company Nouveaux polyestéramides, leurs procédés de préparation et compositions de polyestéramides
TWI846279B (zh) 2020-08-13 2024-06-21 美商阿散德性能材料營運公司 具有二聚酸和二聚胺的脂族和半芳族聚醯胺
CN112760739B (zh) * 2020-12-31 2021-10-29 扬州富威尔复合材料有限公司 一种汽车内饰用低熔点聚酯纤维及其制备方法
IL311403A (en) * 2021-09-17 2024-05-01 Basf Se Copolyamide and a polymer layer containing at least one lactam, dicarboxylic acid and 5,1-diamino-3-oxapentane
WO2023041368A1 (fr) * 2021-09-17 2023-03-23 Basf Se Copolyamide et film polymère contenant au moins une diamine, un acide dicarboxylique et un 1,5-diamino-3-oxapentane
EP4402195A1 (fr) * 2021-09-17 2024-07-24 Basf Se Enveloppe tubulaire (s) pour aliments, contenant au moins un copolyamide composé d'au moins un lactame, un acide dicarboxylique et du 1,5-diamino-3-oxapentane

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IL265346A (en) 2019-05-30
CN109937226A (zh) 2019-06-25
US12030991B2 (en) 2024-07-09
JP2019530764A (ja) 2019-10-24
KR20190055137A (ko) 2019-05-22
KR102407949B1 (ko) 2022-06-13
IL265346B1 (en) 2023-03-01
RU2019110996A (ru) 2020-10-15
IL265346B2 (en) 2023-07-01
JP7500196B2 (ja) 2024-06-17
US20190194392A1 (en) 2019-06-27

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