EP3512903A1 - Film agricole contenant un copolyamide formé à partir d'une diamine, d'un acide dimère et d'un lactame - Google Patents

Film agricole contenant un copolyamide formé à partir d'une diamine, d'un acide dimère et d'un lactame

Info

Publication number
EP3512903A1
EP3512903A1 EP17767766.3A EP17767766A EP3512903A1 EP 3512903 A1 EP3512903 A1 EP 3512903A1 EP 17767766 A EP17767766 A EP 17767766A EP 3512903 A1 EP3512903 A1 EP 3512903A1
Authority
EP
European Patent Office
Prior art keywords
copolyamide
film
agricultural film
component
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP17767766.3A
Other languages
German (de)
English (en)
Inventor
Rolf Minkwitz
Frank Reil
Martina SCHOEMER
Johannes Klaus SPRAFKE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP3512903A1 publication Critical patent/EP3512903A1/fr
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
    • A01G9/14—Greenhouses
    • A01G9/1438—Covering materials therefor; Materials for protective coverings used for soil and plants, e.g. films, canopies, tunnels or cloches
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00—Protecting plants
    • A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256—Ground coverings
    • A01G13/0268—Mats or sheets, e.g. nets or fabrics
    • A01G13/0275—Films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/34—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids using polymerised unsaturated fatty acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/04—Polyamides derived from alpha-amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C08L77/08—Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/24—All layers being polymeric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582—Tearability
    • B32B2307/5825—Tear resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2410/00—Agriculture-related articles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/25—Greenhouse technology, e.g. cooling systems therefor

Definitions

  • the present invention relates to an agricultural film (AF) comprising at least one copolyamide, wherein the copolyamide is prepared by polymerization of at least one lactam and a monomer mixture (M). Moreover, the present invention relates to a process for the production of agricultural film (AF) and the use of agricultural film (AF) in the agricultural sector, for example as a mulch film, as a silage film, as a greenhouse film or as a silo film.
  • Agricultural films are used, for example, as a cover for greenhouses, as mulch films, as silage films and, for example, as packaging for trees.
  • Typical polymers from which the agricultural films are made are low density polyethylene (LDPE), ethylene vinyl acetate (EVA) and linear low density polyethylene (LLDPE).
  • LDPE low density polyethylene
  • EVA ethylene vinyl acetate
  • LLDPE linear low density polyethylene
  • PA 6 / 6.6 polyamide 6 / 6.6
  • Agricultural films should have good mechanical properties and be stable under the environmental conditions in which they are used. In particular, they must be able to withstand mechanical stresses as well as withstand temperature fluctuations, high solar radiation, moisture and agricultural chemicals such as pesticides and fertilizers.
  • DIN EN 14932: 2007-03 describes the requirements for thermoplastic stretch films for wrapping bales.
  • DIN EN 13206: 2001 describes the requirements for thermoplastic cover foils for use in agriculture and horticulture.
  • DIN EN 13207: 2001 describes the requirements for thermoplastic silage films.
  • Each of these DIN standards which are of particular relevance to agricultural films, places high demands, in particular, on the puncture resistance of the films used.
  • agricultural films should not have too high stiffness, for example, so that they can cling well to the seed.
  • the currently most widely used agricultural films made from LDPE often have a relatively low puncture resistance.
  • agricultural films made of PA 6 have a higher Puncture resistance as agricultural films made from LDPE, however, have a stiffness that is too high for most agricultural film applications.
  • the object underlying the present invention was thus to provide an agricultural film which does not have the disadvantages of the agricultural films described in the prior art or only to a reduced extent.
  • the agricultural film should also be as simple and inexpensive to produce.
  • (B2) contains at least one C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B).
  • the agricultural film (AF) according to the invention has a high tear strength both in the direction of extrusion and perpendicular thereto.
  • the agricultural film (AF) according to the invention has a higher puncture resistance, in particular than the agricultural films made of polyolefins such as LDPE and LLDPE which are frequently used in the prior art.
  • the agricultural film (AF) according to the invention has better acid resistance than the agricultural films of PA 6 and PA 6 / 6.6 described in the prior art.
  • the higher acid resistance is important, since precipitation in the form of acid rain often impinges on the agricultural film (AF) and also contain fertilizers and pesticides partially acidic ingredients or can form acids from their constituents.
  • the agricultural film (AF) according to the invention has a high transparency. It is also advantageous that the agricultural film (AF) according to the invention is less stiff than the agricultural films (AF) described in the prior art.
  • the agricultural film (AF) according to the invention also has a low modulus of elasticity and high puncture resistance in the dry and in the wet state. The invention will be explained in more detail below.
  • the agricultural film (AF) contains at least one copolyamide.
  • at least one copolyamide is understood to mean both exactly one copolyamide and one mixture of two or more copolyamides.
  • the agricultural film (AF) has, for example, a thickness in the range of 0.1 ⁇ m to 1 mm, preferably a thickness in the range of 5 to 500 ⁇ m, and particularly preferably in the range of 20 to 100 ⁇ m.
  • the present invention therefore also provides an agricultural film (AF) in which the agricultural film (AF) has a thickness in the range from 0.1 ⁇ m to 1 mm.
  • the agricultural film (AF) may contain, in addition to the at least one copolyamide, at least one further polymer (wP).
  • At least one further polymer (wP) in the context of the present invention means both exactly one further polymer (wP) and a mixture of two or more further polymers (wP).
  • At least one other polymer (wP) are all known in the art polymers. It goes without saying that the at least one further polymer (wP) is different from the at least one copolyamide.
  • the at least one further polymer (wP) is preferably selected from the group consisting of polyolefins, poly (ethylvinyl alcohols), poly (ethylvinylacetates), polyethylene terephthalates, polyvinylidene chlorides, maleic anhydride-grafted polyolefins, polyesters and ionomers.
  • the at least one further polymer (wP) is selected from the group consisting of polyolefins, poly (ethylene vinyl alcohols), poly (ethylene vinyl acetates), polyethylene terephthalates,
  • the at least one other polymer (wP) is selected from the group consisting of polyolefins, maleic anhydride-grafted polyolefins, and ethylvinyl alcohols.
  • the at least one further polymer (wP) is selected from the group consisting of polyolefins, it is preferred that polyolefins additionally grafted with maleic anhydride be used as at least one further polymer (wP). It is possible that a mixture of polyolefins and polyolefins grafted with maleic anhydride is used as the at least one further polymer (wP).
  • the Agrifilm (AF) is a multilayer film described below
  • the Agrarian Film (AF) at least one first further layer of at least one further polymer (wP), the at least one further polymer (wP) of the first further layer being selected from the group consisting of maleic anhydride-grafted polyolefins and the agricultural film (AF) at least one second further layer at least a further polymer (wP), wherein the at least one further polymer (wP) of the second further layer is selected from the group consisting of polyolefins.
  • the agricultural film (AF) then preferably contains the first further layer between the first layer containing the at least one copolyamide and the second further layer.
  • Polyolefins as such are known to those skilled in the art.
  • Preferred polyolefins are polypropylene (PP), low-density polyethylene (LDPE), linear-low-density polyethylene (LLDPE) and very-low-density polyethylene (VLDPE).
  • Linear low-density polyethylene is a copolymer of ethylene and at least one C4-C8 ⁇ -olefin.
  • Linear-low-density polyethylene (LLDPE) is characterized by long polymer chains with short side chains. The length of the side chains in linear-low-density polyethylene (LLDPE) is usually shorter than in low-density polyethylene (LDPE) and in medium-density polyethylene (MDPE).
  • the melting point of linear-low-density polyethylene (LLDPE) is preferably in the range of 1 10 to 130 ° C, its density is in the range of 0.91 to 0.93 g / cm 3 .
  • VLDPE Very-low-density polyethylene
  • C 4 - Cs- ⁇ -olefin usually have a melting point in the range of 1 10 to 130 ° C and a density in the range of 0.86 to ⁇ 0.91 g / cm 3 .
  • the proportion of C 4 -C 8 ⁇ -olefins in VLDPE is generally higher than in LLDPE.
  • C 4 -C 8 - ⁇ -olefin is understood as meaning linear and branched, preferably linear, alkylenes having 4 to 8 carbon atoms which are unsaturated in the a position, ie have a C-C double bond in the a position Examples of these are 1-butene, 1-pentene, 1-hexene, 1-heptane and 1-octene.1-butene, 1-hexene and 1-octene are preferred.
  • Preferred poly (ethylene vinyl acetates) are copolymers of ethylene with vinyl acetate.
  • ethylene ethylene vinyl acetates
  • Preferred poly (ethylene vinyl acetates) are copolymers of ethylene with vinyl acetate.
  • ethylene in the range of 82 to 99.9 wt.% Of ethylene and in the range of 0.1 to 18 wt.% Of vinyl acetate, preferably in the range of 88 to 99.9 wt.% Of ethylene and in the range of 0, 1 to 12 wt .-% vinyl acetate used for the preparation.
  • Preferred poly (ethylenevinyl alcohols) are obtainable by complete or partial saponification of the above-described poly (ethylenevinylacetates).
  • the poly (ethylene vinyl alcohols) contain in the range of 50 to 75 mole percent ethylene and in the range of 25 to 50 mole percent vinyl alcohol, based on the total amount of poly (ethylene vinyl alcohols).
  • the agricultural film (AF) may contain the at least one further polymer (wP) as a blend (blend) with the at least one copolyamide.
  • the agricultural film (AF) contains at least one first layer which contains the at least one copolyamide, and the agricultural film (AF) contains at least one further layer which contains the at least one further polymer (wP) ,
  • the at least one first layer containing the at least one copolyamide contains no further polymer (wP).
  • At least one first layer means both exactly one first layer and two or more first layers.
  • At least one further layer means in the context of the present invention exactly one further layer as well as two or more further layers. Two or more further layers are preferred.
  • the agricultural film (AF) contains at least one first layer which contains the at least one copolyamide, and the agricultural film (AF) additionally contains at least one further layer, wherein the at least one further layer comprises at least one further polymer (wP). selected from the group consisting of polyolefins, poly (ethylene vinyl alcohols), poly (ethylene vinyl acetates), polyethylene terephthalates,
  • Polyvinylidenchloriden and gelled with maleic anhydride polyolefins contains.
  • the present invention thus also provides an agricultural film (AF) in which the agricultural film (AF) contains at least one first layer which contains the at least one copolyamide, and the agricultural film (AF) contains at least one further layer, wherein the at least one further layer Layer at least one further polymer (wP) selected from the group consisting of polyolefins, poly (ethylene vinyl alcohols), poly (ethylene vinyl acetates), polyethylene terephthalates, polyvinylidene chlorides and maleic anhydride gegrafteten polyolefins containing.
  • WP further polymer
  • the Agrifilm (AF) contains no further layer apart from the at least one first layer
  • the Agrifilm (AF) is also referred to as a monofilm. If the Agrifilm (AF) is a monofilm, it can contain exactly one first layer and no further layer, and it is also possible that it contains two or more first layers and no further layer. If the Agrifilm (AF) contains two or more first layers and is a monofilm, then the two or more first layers all have the same composition. If the agricultural film (AF) contains at least one first layer which contains the at least one copolyamide, and at least one further layer which contains the at least one further polymer (wP), the agricultural film (AF) is also referred to as multilayer film.
  • the agricultural film (AF) then contains 1 to 11 first layers containing the at least one copolyamide and 1 to 13 further layers containing the at least one further polymer (wP).
  • the agricultural film (AF) preferably contains 1 to 5 first layers containing the at least one copolyamide and 1 to 1 1 further layers containing the at least one further polymer (wP).
  • the agricultural film (AF) contains 1 to 3 first layers containing the at least one copolyamide, and 1 to 7 further layers containing the at least one further polymer (wP).
  • the at least one first layer consists of the at least one copolyamide. It is likewise preferred that the at least one further layer consists of the at least one further polymer (wP).
  • AF agricultural film
  • the subject of the present invention is therefore also an agricultural film (AF), the agricultural film (AF) being a monofilm or a multilayer film.
  • the agricultural film (AF) usually has a thickness in the range of 0.1 ⁇ to 1 mm, preferably in the range of 5 to 500 ⁇ and particularly preferably in the range of 10 to 100 ⁇ .
  • the first layer has the same thickness as the agricultural film (AF), that is, for example in the range of 0.1 ⁇ m to 1 mm, preferably in the range of 5 to 500 ⁇ and particularly preferably in the range of 10 to 100 ⁇ . If the agricultural film (AF) is monofilm and contains two or more first layers, the thickness of each first layer is usually smaller than the thickness of the agricultural film (AF). The sum of the thicknesses of the individual first layers then generally corresponds to the thickness of the agricultural film (AF).
  • the at least one first layer containing the at least one copolyamide then has a thickness in the range of 0.1 to 100 ⁇ , preferably in the range of 0.5 to 50 ⁇ and particularly preferably in the range of 0.5 to 15 ⁇ on.
  • the thickness of the individual layers of the agricultural film (AF) ie the thickness of the at least one first layer containing the at least one copolyamide, and the thickness of the at least one further layer, the contains at least one further polymer (wP), usually smaller than the thickness of the Agrarian Films (AF).
  • WP further polymer
  • the sum of the thicknesses of the individual layers then generally corresponds to the thickness of the agricultural film (AF).
  • the at least one first layer containing the at least one copolyamide then has a thickness in the range from 0.1 to 100 ⁇ m, preferably in the range from 0.5 to 50 ⁇ m, and particularly preferably in the range from 0.5 to 15 ⁇ .
  • the at least one further layer which contains the at least one further polymer (wP) then has, for example, a thickness in the range from 0.1 to 100 ⁇ m, preferably in the range from 0.5 to 50 ⁇ m, and particularly preferably in the range from 0 , 5 to 15 ⁇ .
  • the Agricultural Film (AF) may contain at least one bonding agent. This embodiment is preferred when the agricultural film (AF) is a multilayer film.
  • At least one adhesion promoter in the context of the present invention means both exactly one adhesion promoter and a mixture of two or more adhesion promoters.
  • the at least one adhesion promoter can be contained together with the at least one copolyamide in the at least one first layer. It is likewise possible for the at least one adhesion promoter to be present together with the at least one further polymer (wP) in the at least one further layer. Moreover, it is possible for the at least one adhesion promoter to be present as at least one additional layer in the agricultural film (AF). This embodiment is preferred.
  • the at least one adhesion promoter is present as at least one additional layer in the agricultural film (AF), then this at least one additional layer is preferably between the at least one further layer containing the at least one further polymer (wP) and the at least one first Layer containing the at least one copolyamide arranged.
  • the at least one layer of the adhesion promoter has, for example, a thickness of 0.1 to 100 ⁇ m, preferably in the range of 0.5 to 50 ⁇ m, and particularly preferably in the range of 0.5 to 15 ⁇ m.
  • adhesion promoters are known to those skilled in the art.
  • Preferred adhesion promoters are copolymers of ethylene with maleic anhydride or a copolymer of ethylene with vinyl acetate.
  • a copolymer of linear-low-density polyethylene (LLDPE) and maleic anhydride or a copolymer of ethylene and vinyl acetate is preferred, with> 18% by weight of vinyl acetate and ⁇ 82% by weight of ethylene being used for the preparation of the copolymer.
  • LLDPE linear-low-density polyethylene
  • These copolymers are commercially available, for example under the trade name Bynel 4105 from DuPont or Escorene FL001 19 from Exxon.
  • Copolymers of ethylene with maleic anhydride and maleic anhydride grafted polymers or copolymers of ethylene are preferred as adhesion promoters.
  • the agricultural film (AF) may also contain additives.
  • additives are known to the person skilled in the art and are selected, for example, from the group consisting of stabilizers, dyes, antistatic agents, tackifiers, anti-block, processing aids, antioxidants, light stabilizers, UV absorbers, lubricants and nucleating agents.
  • Suitable dyes are organic and inorganic pigments, such as, for example, sized titanium dioxide.
  • Suitable tackifiers are, for example, polyisobutylene (PIB) or ethylvinylacetate (EVA).
  • Suitable antiblocking agents are, for example, silica or calcium carbonate particles.
  • Suitable light stabilizers are, for example, so-called HALS (hindered amine light stabilizers).
  • HALS hinderedered amine light stabilizers
  • ethylenebisstearamide (EBS) wax can be used as a processing aid or lubricant.
  • Nucleating aids may be, for example, any types of organic or inorganic nucleating agents, e.g. Talk.
  • the additives may be contained both in the at least one first layer and in the at least one further layer. They can be contained in only one of these layers, as well as they are likely to be included in each of these layers.
  • the agricultural film (AF) according to the invention may be any type of agricultural film (AF) known to those skilled in the art.
  • the agricultural film (AF) is preferably a silage film, a mulch film, a greenhouse film and / or a silo film.
  • the present invention therefore also relates to an agricultural film (AF), wherein the agricultural film (AF) is selected from silage films, mulch films, greenhouse films and silo films.
  • Silage films are also known as silage films and are used to produce and store silage.
  • Silage is feed that has been preserved by fermentation, especially for livestock.
  • Silage films must in particular have a high air-tightness and a high mechanical stability, in particular a high puncture resistance. The high airtightness is necessary to ferment the feed and preserve it. The mechanical stability is particularly needed to achieve and maintain a high compression of the silage.
  • Mulch films are also referred to as mulch films and are cover sheets for agricultural soil, especially for beds and arable land.
  • mulch films serve to suppress the growth of weeds.
  • by the Covering the soil with the mulch film keeps the soil warm and at the same time dries less than without foil.
  • Greenhouse films are also referred to as greenhouse films. They separate the soil on which they stand from the environment and produce in the separated area a microclimate, which makes the growth of plants more efficient or even possible. Greenhouse films are distinguished between “Greenhouse Covers”, “Walk-In Tunnel Covers” and “Small Tunnel Covers.” Greenhouse films should be airtight, have high mechanical stability with high puncture and tear propagation resistance, and high UV resistance to extend the life of the films.
  • Silofilms are also referred to as silage films or silo bags. Silofilms are used for storage of crop or bulk material.
  • the crop stored in silo films is, for example, food and / or feed. These include plant seeds such as soybeans, cereals or corn, as well as potatoes, turnips and grains.
  • the crop stored in silo films is less densified and usually not decomposed, for example by fermentation. Therefore, the crop stored in the silo is preferably substantially undecomposed.
  • Substantially undecomposed in the context of the present invention means that at most 10% by weight, preferably at most 5% by weight and especially preferably at most 1% by weight of the crop is decomposed in the silo film, based on the total weight of the crop in the silo film.
  • the storage of the crop in the silo film can be done for example over weeks, months or even years.
  • the crop is stored in the silo film for a period in the range of 2 weeks to 2 years, preferably in the range of 4 weeks to 1, 5 years and more preferably in the range of 12 weeks to 1 year.
  • Silo films are preferably tubular and allow the storage of the crop in the field, for example, directly on the field.
  • Silo films usually have a hose diameter in the range of 1.5 to 10 m (meters), preferably in the range of 2 to 6 m and particularly preferably in the range of 2.5 to 3.5 m.
  • the length of inventive silofilaments is for example in the range of 2 to 250 m, preferably in the range of 5 to 200 m and particularly preferably in the range of 10 to 150 m.
  • Silo films must in particular have a high air-tightness, a high water-tightness and a high UV stability. In addition, high mechanical stabilities are advantageous.
  • the present invention therefore also relates to the use of the agricultural film (AF) according to the invention in the agricultural sector, for example as silage film, mulch film, greenhouse film or silo film. copolyamide
  • the agricultural film (AF) contains at least one copolyamide which is prepared by polymerization of the components
  • (B2) contains at least one C4-Ci2-diamine, wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B).
  • component (A) and “at least one lactam” are used synonymously in the context of the present invention and therefore have the same meaning.
  • the at least one lactam means both exactly one lactam and one mixture of two or more lactams, and exactly one lactam is preferred
  • the at least one copolyamide is prepared by polymerization from 5 to 99% by weight of the component (A) and 1 to 95% by weight of component (B)
  • the at least one copolyamide is prepared by polymerization from 40 to 90% by weight of component (A) and from 10 to 60% by weight of the component (B)
  • the at least one copolyamide is produced by polymerization of 60 to 80% by weight of component (A) and 20 to 40% by weight of component (B), the percentages by weight of components (A) being and (B) are each based on the sum of the weight percentages of components (A) and (B).
  • the sum of the weight percent of components (A) and (B) gives 100 wt .-%.
  • the weight percentages of components (A) and (B) relate to the weight percentages of components (A) and (B) before the polymerization, that is, when components (A) and (B) are not yet together have reacted.
  • the weight ratio of the components (A) and (B) may change, if necessary.
  • the copolyamide is prepared by polymerization of components (A) and (B).
  • the polymerization of components (A) and (B) is known to the person skilled in the art.
  • the polymerization of components (A) with (B) is a condensation reaction.
  • component (A) reacts with components (B1) and (B2) contained in component (B) and optionally with component (B3) described below, which may likewise be present in component (B).
  • component (A) during the polymerization is at least partially open-chain, ie as an amino acid.
  • Suitable catalysts are all catalysts known to those skilled in the art, which catalyze the polymerization of components (A) and (B). Such catalysts are known in the art.
  • Preferred catalysts are phosphorus compounds such as sodium hypophosphite, phosphorous acid, triphenylphosphine or triphenyl phosphite.
  • the copolyamide is formed, which thus obtains building units derived from component (A) and building units derived from component (B).
  • Building units derived from component (B) contain building blocks derived from components (B1) and (B2) and optionally from component (B3).
  • the copolyamide forms as a copolymer.
  • the copolymer may be a random copolymer, as well as it is possible that it is a block copolymer.
  • blocks of units derived from component (B) and blocks of units derived from component (A) form. These alternate.
  • building units derived from component (A) alternate with building units derived from component (B). This alternation occurs statistically, for example, two units derived from component (B) may be followed by a unit derived from component (A), followed by another unit derived from component (B), to which then a structural unit follows, containing three units derived from component (A).
  • the at least one copolyamide is a random copolymer.
  • the present invention therefore also relates to an agricultural film (AF) in which the at least one copolyamide is a random copolymer.
  • the preparation of the at least one copolyamide preferably comprises the following steps: a) polymerization of components (A) and (B) to obtain at least one first copolyamide, b) granulation of the at least one first copolyamide obtained in step a) to obtain at least one granulated copolyamide c) extraction of the at least one granulated copolyamide obtained in step b) with water to obtain at least one extracted copolyamide; d) drying of the at least one extracted copolyamide obtained in step c) at a temperature (Tr) to obtain the at least one copolyamide.
  • the present invention therefore also provides an agricultural film (AF) in which the copolyamide is prepared in a process comprising the following steps: a) polymerization of the components (A) and (B) to obtain at least one first copolyamide, b) granulation of the c) extraction of the at least one granulated copolyamide obtained in step b) with water to obtain at least one extracted copolyamide, d) drying of the at least one extracted extract obtained in step c) Copolyamides at a temperature (Tr) to obtain the at least one copolyamide.
  • the polymerization in step a) can take place in all reactors known to those skilled in the art. Preference is given to stirred tank reactors.
  • step b) the at least one first copolyamide obtained in step a) can be granulated by all methods known to the person skilled in the art, for example by means of strand granulation or underwater granulation.
  • the extraction in step c) can be carried out by all methods known to the person skilled in the art.
  • step c by-products formed during the polymerization of components (A) and (B) in step a) are usually extracted from the at least one granulated copolyamide.
  • step d) the at least one extracted copolyamide obtained in step c) is dried.
  • Methods for drying are known in the art.
  • the at least one extracted copolyamide is dried at a temperature (Tr).
  • the temperature (Tr) is preferably above the glass transition temperature (TG ⁇ C)) of the at least one copolyamide and below the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • the drying in step d) is usually carried out for a period in the range of 1 to 100 hours, preferably in the range of 2 to 50 hours and more preferably in the range of 3 to 40 hours.
  • step d the molecular weight of the at least one copolyamide is further increased.
  • the at least one copolyamide usually has a glass transition temperature (TG ⁇ C)).
  • the glass transition temperature (TG ⁇ C)) is for example in the range of 20 to 50 ° C, preferably in the range of 23 to 47 ° C and particularly preferably in the range of 25 to 45 ° C, determined according to ISO 1 1357-2: 2014.
  • the present invention therefore also provides an agricultural film (AF) in which the at least one copolyamide has a glass transition temperature (TG ⁇ C)), the glass transition temperature (TG ⁇ O) being in the range from 20 to 50 ° C.
  • AF agricultural film
  • the glass transition temperature (TG ⁇ C)) of the at least one copolyamide according to ISO 1 1357-2: 2014 in the context of the present invention refers to the glass transition temperature (TG ⁇ O) of the dry copolyamide.
  • dry means that the at least one copolyamide contains less than 1% by weight, preferably less than 0.5% by weight and more preferably less than 0.1% by weight, based on water the total weight of the at least one copolyamide. More preferably, “dry” means that the at least one Copolyamide contains no water, and most preferably that the at least one copolyamide contains no solvent.
  • the at least one copolyamide usually has a melting temperature (M (C)).
  • the melting temperature (TM ⁇ O) of the at least one copolyamide is, for example, in the range from 150 to 215 ° C., preferably in the range from 160 to 205 ° C. and particularly preferably in the range from 1 60 to 200 ° C., determined according to ISO 1157 -3: 2014.
  • the present invention therefore also relates to an agricultural film (AF) in which the at least one copolyamide has a melting temperature (TM ⁇ C)), wherein the melting temperature (TM ⁇ C)) in the range of 150 to 215 ° C.
  • TM ⁇ C melting temperature
  • the at least one copolyamide generally has a viscosity number (VZ (o) in the range of 150 to 300 ml / g, determined in a 0.5 wt .-% solution of at least one copolyamide in a mixture of phenol / o-dichlorobenzene in the weight ratio 1: 1.
  • VZ (o) viscosity number
  • the viscosity number (VZ ⁇ o) of the at least one copolyamide is preferably in the range from 1 60 to 290 ml / g and more preferably in the range from 170 to 280 ml / g, determined in a 0.5% by weight solution of the at least a copolyamide in a mixture of phenol / o-dichlorobenzene in the weight ratio 1: 1.
  • the present invention therefore also relates to an agricultural film (AF) in which the at least one copolyamide has a viscosity number (VZ ⁇ o) in the range from 150 to 300 ml / g, determined in a 0.5% by weight solution of the at least a copolyamide in a mixture of phenol / o-dichlorobenzene in the weight ratio 1: 1.
  • VZ ⁇ o viscosity number
  • Component (A) is at least one lactam.
  • Lactams are known to those skilled in the art. Lactams having 4 to 12 carbon atoms are preferred according to the invention.
  • lactams are understood to mean cyclic amides which have in the ring preferably 4 to 12, particularly preferably 5 to 8, carbon atoms.
  • Suitable lactams are for example selected from the group consisting of
  • 6-aminohexanoic acid lactam hexano-6-lactam: ⁇ -lactam; ⁇ -caprolactam
  • 7-aminoheptanoic acid lactam heptano-7-lactam; ⁇ -lactam; ⁇ -heptanolactam
  • the present invention therefore also provides an agricultural film (AF) in which component (A) is selected from the group consisting of 3-aminopropanoic acid lactam, 4-aminobutanoic acid lactam, 5-aminopentanoic acid lactam, 6-aminohexanoic acid lactam, 7-aminoheptanoic acid lactam, 8-aminooctanoic acid lactam , 9-aminononanoic acid lactam, 10-aminodecanoic acid lactam, 1-amino undecanoic acid lactam and
  • the lactams may be unsubstituted or at least monosubstituted. In the event that at least monosubstituted lactams are used, they may carry on the nitrogen atom and / or on the carbon atoms of the ring one, two or more substituents independently selected from the group consisting of C 1 to C 10 alkyl, C 5 - to C6-cycloalkyl and C5- to Cio-aryl.
  • C 1 to C 10 -alkyl substituents are methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl and tert-butyl.
  • a suitable C5 to C6 cycloalkyl substituent is, for example, cyclohexyl.
  • Preferred C5 to Cio-aryl substituents are phenyl and anthranyl.
  • Unsubstituted lactams are preferably used, with ⁇ -lactam ( ⁇ -butyrolactam), ⁇ -lactam ( ⁇ -valerolactam) and ⁇ -lactam ( ⁇ -caprolactam) being preferred. Particularly preferred are ⁇ -lactam ( ⁇ -valerolactam) and ⁇ -lactam ( ⁇ -caprolactam), with ⁇ -caprolactam being particularly preferred.
  • component (B) is a monomer mixture (M).
  • the monomer mixture (M) contains the components (B1), at least one C32-C4o dimer acid, and (B2) at least one C4-C12 diamine.
  • a monomer mixture (M) is understood as meaning a mixture of two or more monomers, where at least the components (B1) and (B2) are contained in the monomer mixture (M).
  • component (B1) and “at least one C32-C4o dimer acid” are used synonymously in the context of the present invention and therefore have the same meaning.
  • component (B2) and “at least one C4-C12 diamine”. These terms are also used synonymously in the context of the present invention and therefore have the same meaning.
  • the monomer mixture (M) contains, for example, in the range from 45 to 55 mol% of component (B1) and in the range from 45 to 55 mol% of component (B2) in each case based on the sum of the molar percentages of components (B1) and ( B2), preferably based on the total amount of substance of component (B).
  • Component (B) preferably contains in the range from 47 to 53 mol% of component (B1) and in the range from 47 to 53 mol% of component (B2) in each case based on the sum of the molar percentages of components (B1) and ( B2), preferably based on the total amount of substance of component (B).
  • Component (B) particularly preferably contains in the range from 49 to 51 mol% of component (B1) and in the range from 49 to 51 mol% of component (B2), in each case based on the sum of the molar percentages of components (B1). and (B2), preferably based on the total amount of component (B).
  • the present invention therefore also provides an agricultural film (AF) in which component (B) contains in the range from 45 to 55 mol% of component (B1) and in the range from 45 to 55 mol% of component (B2), in each case based on the total amount of component (B).
  • AF agricultural film
  • component (B1) The sum of the molar percentages of components (B1) and (B2) contained in component (B) is usually 100 mol%.
  • the component (B) may additionally contain a component (B3), at least one C 4 - C 20 diacid.
  • the present invention therefore also provides a polymer film (P) in which component (B) additionally contains a component (B3), at least one C 4 -C 20 diacid.
  • component (B3) and "at least one C 4 -C 20 diacid” are used synonymously in the context of the present invention and therefore have the same meaning. If component (B) additionally contains component (B3), it is preferred that component (B) be used in the range from 25 to 54.9 mol% of component (B1), in the range from 45 to 55 mol%. % of component (B2) and in the range of 0.1 to 25 mol% of component (B3), in each case based on the total amount of component (B).
  • the component (B) then particularly preferably contains in the range from 13 to 52.9 mol% of component (B1), in the range from 47 to 53 mol% of component (B2) and in the range from 0.1 to 13 mol% of component (B3), in each case based on the total amount of substance of component (B).
  • component (B) then contains in the range of 7 to 50.9 mol% of component (B1), in the range of 49 to 51 mol% of component (B2) and in the range of 0.1 to 7 mol% of component (B3), in each case based on the total amount of substance of component (B).
  • component (B) additionally contains component (B3)
  • the mole percentages of components (B1), (B2) and (B3) usually add up to 100 mole percent.
  • the monomer mixture (M) may also contain water.
  • component (B1) and (B2) and optionally (B3) of the component (B) may react with each other to give amides. This reaction is known to those skilled in the art. Therefore, component (B) may contain components (B1) and (B2) and optionally (B3) in fully reacted form, in partially reacted form or in unreacted form. Component (B) preferably contains the components (B1) and (B2) and optionally (B3) in unreacted form.
  • unreacted form means that component (B1) is present as the at least one C 32 -C 40 dimer acid and component (B2) is present as the at least one C 4 -C 12 diamine and optionally the component ( B3) as the at least one C4-C2o diacid.
  • the component (B1) is according to the invention at least one C32-C4o dimer acid.
  • At least one C32-C4o dimer acid in the context of the present invention means both exactly one C32-C4o dimer acid and one mixture of two or more C32-C40 dimer acids.
  • Dimer acids are also referred to as dimer fatty acids.
  • C32-C4o dimer acids are known to those skilled in the art and are usually prepared by dimerization of unsaturated fatty acids. This dimerization can be catalyzed by clays, for example.
  • Suitable unsaturated fatty acids for preparing the at least one C 32 -C 40 dimer acid are known to the person skilled in the art and, for example, unsaturated C 16 -fatty acids, unsaturated cie fatty acids and unsaturated C 20 fatty acids.
  • the component (B1) is therefore preferably prepared starting from unsaturated fatty acids selected from the group consisting of unsaturated C 16 -fatty acids, unsaturated cis-fatty acids and unsaturated C 20 fatty acids, the unsaturated cie fatty acids being particularly preferred.
  • the present invention therefore also provides an agricultural film (AF) in which component (B1) is prepared starting from unsaturated fatty acids selected from the group consisting of unsaturated C 16 -fatty acids, unsaturated cis-fatty acids and unsaturated C 20 fatty acids.
  • component (B1) is prepared starting from unsaturated fatty acids selected from the group consisting of unsaturated C 16 -fatty acids, unsaturated cis-fatty acids and unsaturated C 20 fatty acids.
  • a suitable unsaturated C 16 -fatty acid is, for example, palmitoleic acid ((9Z) -hexadeca-9-enoic acid).
  • Suitable unsaturated cis-fatty acids are, for example, selected from the group consisting of petroselinic acid ((6Z) -octadeca-6-enoic acid), oleic acid
  • Suitable unsaturated C2o-fatty acids are, for example, selected from the group consisting of gadoleic acid ((9Z) -eicosa-9-enoic acid), icosenoic acid ((11Z) -eicosa-1-enoic acid), arachidonic acid ((5Z, 8Z, 1 1Z, 14Z) -eicosa-5,8,11,14-tetraenoic acid) and timnodonic acid ((5Z, 8Z, 11Z, 14Z, 17Z) -eicosa-5,8,1,1,14,7-pentaenoic acid).
  • the component (B1) is particularly preferably at least one C36 dimer acid.
  • the at least one C36 dimer acid is preferably prepared starting from unsaturated cis fatty acids. More preferably, the C36 dimer acid is prepared starting from cis fatty acids selected from the group consisting of petroselinic acid ((6Z) octadeca-6- enoic acid), oleic acid ((9Z) -octadeca-9-enoic acid), elaidic acid ((9E) -octadeca-9-enoic acid), vaccenic acid ((1 1 E) -Octadeca-1-enoic acid) and linoleic acid ((9Z, 12Z) octadeca- 9,12-dienoic acid).
  • trimer acids can form in the preparation of component (B1) from unsaturated fatty acids, and residues of unreacted unsaturated fatty acid can also be left over.
  • trimer acids The formation of trimer acids is known to the person skilled in the art.
  • component (B1) preferably contains at most 0.5% by weight of unreacted unsaturated fatty acid and at most 0.5% by weight of trimer acid, more preferably at most 0.2% by weight of unreacted unsaturated fatty acid and at most 0.2 % By weight of trimer acid, in each case based on the total weight of component (B1).
  • Dimer acids are generally and in particular in the context of the present invention thus mixtures referred to, which are prepared by oligomerization of unsaturated fatty acids. They can be prepared, for example, by catalytic dimerization of vegetable, unsaturated fatty acids, using as starting materials in particular unsaturated C 16- to C 20 -fatty acids.
  • the linkage proceeds primarily according to the Diels-Alder type and, depending on the number and position of the double bonds of the fatty acids used to prepare the dimer acids, mixtures of predominantly dimeric products which are cycloaliphatic, linear-aliphatic, branched aliphatic and also between the carboxyl groups C6 have aromatic hydrocarbon groups.
  • the aliphatic radicals may be saturated or unsaturated and also the proportion of aromatic groups may vary.
  • the residues between the carboxylic acid groups then contain, for example, 32 to 40 carbon atoms.
  • fatty acids containing 18 carbon atoms are used for the preparation, so that the dimeric product thus has 36 carbon atoms.
  • the radicals linking the carboxyl groups of the dimer fatty acids have no unsaturated bonds and no aromatic hydrocarbon radicals.
  • Linolenic, linoleic and / or oleic acid are particularly preferably used.
  • mixtures are formed in the above-mentioned oligomerization, which contain mainly dimeric, but also trimeric molecules and monomeric molecules and other by-products. Usually, it is purified by distillation.
  • dimer acids generally contain at least 80% by weight. dimeric molecules, up to 19% by weight of trimeric molecules and at most 1% by weight of monomeric molecules and other by-products.
  • dimer acids which consist of at least 90% by weight, preferably at least 95% by weight, very particularly preferably at least 98% by weight, of dimeric fatty acid molecules.
  • the determination of the proportions of monomeric, dimeric and trimeric molecules and other by-products in the dimer acids can be carried out, for example, by means of gas chromatography (GC).
  • GC gas chromatography
  • the dimer acids are converted before the GC analysis via the boron trifluoride method to the corresponding methyl esters (see DIN EN ISO 5509) and then analyzed by GC.
  • the basic characteristic of "dimer acids” is that their preparation comprises the oligomerization of unsaturated fatty acids, which is predominantly formed, ie preferably at least 80% by weight, more preferably at least 90% by weight. %, very particularly preferably at least 95% by weight and in particular at least 98% by weight of dimeric products
  • unsaturated fatty acids which is predominantly formed, ie preferably at least 80% by weight, more preferably at least 90% by weight. %, very particularly preferably at least 95% by weight and in particular at least 98% by weight of dimeric products
  • the dimer acids to be used can be obtained as commercial products. Examples include Radiacid 0970, Radiacid 0971, Radiacid 0972, Radiacid 0975, Radiacid 0976 and Radiacid 0977 from Oleon, Pripol 1006, Pripol 1009, Pripol 1012, and Pripol 1013 Croda, Empol 1008, Empol 1012, Empol 1061 and Empol 1062 from BASF SE and Unidyme 10 and Unidym Tl from Arizona Chemical.
  • the component (B1) has, for example, an acid number in the range from 185 to 200 mg KOH / g.
  • the component (B2) is according to the invention at least one C4-Ci2-diamine.
  • At least one C 4 -C 12 -diamine in the context of the present invention means both exactly one C 4 -C 12 -diamine and a mixture of two or more C 4 -C 12 diamines.
  • C 4 -C 12 -diamine is understood as meaning aliphatic and / or aromatic compounds having four to twelve carbon atoms and two amino groups (-NH 2 - groups)
  • the aliphatic and / or aromatic compounds may unsubstituted or additionally at least monosubstituted.
  • the aliphatic and / or aromatic compounds are additionally at least monosubstituted, they may carry one, two or more substituents which do not participate in the polymerization of components (A) and (B).
  • substituents are, for example, alkyl or cycloalkyl substituents. These are known to those skilled in the art.
  • the at least one C 4 -C 12 -diamine is preferably unsubstituted.
  • Suitable components (B2) are, for example, selected from the group consisting of 1,4-diaminobutane (butane-1,4-diamine, tetramethylenediamine, putrescine), 1,5-diaminopentane (pentamethylenediamine, pentane-1,5-diamine, cadaverine) , 1, 6-diaminohexane
  • Component (B2) is preferably selected from the group consisting of tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, decamethylenediamine and dodecamethylenediamine.
  • the present invention therefore also provides an agricultural film (AF) in which component (B2) is selected from the group consisting of tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, decamethylenediamine and dodecamethylenediamine.
  • component (B2) is selected from the group consisting of tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, decamethylenediamine and dodecamethylenediamine.
  • Component (B3) The component (B3) optionally contained in component (B) is at least one C4-C20 diacid according to the invention.
  • At least one C4-C2o-diacid means in the context of the present invention, both exactly one C 4 -C2o-diacid and a mixture of two or more C 4 -C2o-diacids.
  • C 4 -C 20 diacid is understood to mean aliphatic and / or aromatic compounds having two to eighteen carbon atoms and two carboxy groups (-COOH groups)
  • the aliphatic and / or aromatic compounds may be unsubstituted or additionally at least monosubstituted
  • they may carry one, two or more substituents which do not participate in the polymerization of the components (A) and (B)
  • substituents are, for example, alkyl
  • the at least one C 4 -C 20 diacid is preferably unsubstituted.
  • Suitable components (B3) are, for example, selected from the group consisting of butanedioic acid (succinic acid), pentanedioic acid (glutaric acid), hexanedioic acid (adipic acid), heptanedioic acid (pimelic acid), octanedioic acid (suberic acid, suberic acid), nonanedioic acid (azelaic acid), decanedioic acid (sebacic acid), Undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid and hexadecanedioic acid.
  • Bevozugt is the component (B3) selected from the group consisting of pentanedioic acid (glutaric acid), hexanedioic acid (adipic acid), decanedioic acid (sebacic acid), dodecanedioic acid.
  • Production of agricultural film (AF) is the component (B3) selected from the group consisting of pentanedioic acid (glutaric acid), hexanedioic acid (adipic acid), decanedioic acid (sebacic acid), dodecanedioic acid.
  • the agricultural film (AF) according to the invention is preferably produced in a process comprising the following steps. i) providing at least one copolyamide prepared by polymerization of the components
  • (B2) at least one C4-Ci2-diamine, wherein the sum of the weight percent of components (A) and (B) in each case based on the sum of the weight percent of components (A) and (B) in molten form in a first extruder , ii) extruding the at least one copolyamide in molten form provided in step i) from the first extruder through a die to obtain a
  • the present invention therefore also provides a process for producing an agricultural film (AF) according to the invention, comprising the steps i) providing at least one copolyamide prepared by polymerizing the components
  • (B2) contains at least one C 4 -C 12 -diamine, the percentages by weight of components (A) and (B) in each case being based on the sum of the percentages by weight of components (A) and (B), in molten form in a first extruder, ii) extruding the at least one copolyamide in molten form provided in step i) from the first extruder through a die to give a film of the at least one copolyamide in molten form; iii) cooling the film of at least one copolyamide obtained in step ii) into molten one Form, wherein the at least one copolyamide solidifies to give the agricultural film (AF).
  • step i) the at least one copolyamide is provided in molten form in a first extruder.
  • a first extruder means both exactly one first extruder and two or more first extruders. Usually as many first extruders are used as first layers which contain the at least one copolyamide in which agricultural film (AF) is contained should.
  • the agricultural film (AF) contains exactly one first layer which contains the at least one copolyamide, exactly one first extruder is used. If the agricultural film (AF) contains exactly two first layers containing the at least one copolyamide, exactly two first extruders are used. If the agricultural film (AF) contains exactly five first layers containing the at least one copolyamide, exactly five first extruders are used.
  • the at least one copolyamide which is provided in step i) the previously described embodiments and preferences for the at least one copolyamide contained in the agricultural film (AF) apply correspondingly.
  • the at least one copolyamide is provided in molten form.
  • “In molten form” in the context of the present invention means that the at least one copolyamide is provided at a temperature which is above the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • “In molten form” means that the at least a copolyamide has a temperature which is above the melting temperature (TM ⁇ C)) of the at least one copolyamide. If the at least one copolyamide is in molten form, the at least one copolyamide is free-flowing.
  • Flowable means that the at least one copolyamide can be promoted in the first extruder and that the at least one copolyamide can be extruded from the first extruder.
  • the at least one copolyamide in step i) is provided at a temperature in the range from 170 to 300 ° C., preferably in the range from 200 to 290 ° C. and particularly preferably in the range from 230 to 280 ° C., in each case with the proviso the temperature at which the at least one copolyamide is provided is above the melting temperature (TM ⁇ C)) of the at least one copolyamide.
  • the at least one copolyamide can be provided in molten form in the first extruder by all methods known to those skilled in the art.
  • the at least one copolyamide may be supplied in molten or solid form to the first extruder. If the at least one copolyamide is fed to the first extruder in solid form, it can be fed to the first extruder, for example, as granules and / or as a powder. The at least one copolyamide is then melted in the first extruder and thus provided in molten form in the first extruder. This embodiment is preferred.
  • the components (A) and (B) are polymerized directly in the first extruder and thus the at least one copolyamide in molten form is provided in the first extruder. Processes for this are known to the person skilled in the art.
  • step ii) the at least one copolyamide in molten form is extruded from the first extruder through a die to give a film of the at least one copolyamide in molten form.
  • a nozzle means both exactly one nozzle and two or more nozzles. According to the invention, exactly one nozzle is preferred.
  • Suitable nozzles are all nozzles known to those skilled in the art, which make it possible to extrude a film of the at least one copolyamide in molten form.
  • Such nozzles are, for example, annular nozzles or slot nozzles.
  • step ii) the at least one copolyamide in molten form from the first extruder with the at least one further polymer (wP) in molten form from the further extruder in the Nozzle, for example in the annular nozzle or in the slot nozzle, is brought together.
  • step ii) the at least one copolyamide in molten form from the first extruder with the at least one further polymer (wP) in molten form from the further extruder are combined in the nozzle in such a way that the film of the at least one obtained in step ii) Copolyamide and the at least one other polymer (wP), each in molten form, at least one first layer containing the at least one copolyamide in molten form, and at least one further layer containing the at least one further polymer (wP) in molten Contains form.
  • the thickness of the film of the at least one copolyamide in molten form is in the range of 0.1 ⁇ m to 1 mm, preferably in the range of 5 to 500 ⁇ m, and particularly preferably in the range of 20 to 100 ⁇ m.
  • the film of the at least one copolyamide in molten form may be, for example, a flat film or a tubular film.
  • a tubular film is usually obtained when an annular nozzle is used as a nozzle, a flat film is obtained when a slit nozzle is used as a nozzle.
  • step iii) the film of the at least one copolyamide obtained in step ii) is cooled in molten form. This solidifies the at least one copolyamide to give the agricultural film (AF).
  • the film of the at least one copolyamide in molten form may be cooled in molten form by air or water cooling or by contact with a cold surface.
  • the film of the at least one copolyamide in molten form is cooled in step iii), for example to a temperature below the melting temperature (TM ⁇ O) of the at least one copolyamide, to obtain the agricultural film (AF).
  • the film of the at least one copolyamide in molten form in step iii) is cooled to a temperature which is below the glass transition temperature (TG ⁇ C)) of the at least one copolyamide.
  • the film of the at least one copolyamide in molten form is cooled to a temperature in the range of 0 to 100 ° C, preferably in the range of 10 to 80 ° C and particularly preferably in the range of 15 to 50 ° C, wherein the temperature, on in which the film of the at least one copolyamide is cooled in molten form, below the melting temperature (TM ⁇ O), preferably below the glass transition temperature (TG ⁇ O) of the at least one copolyamide.
  • TM ⁇ O melting temperature
  • TG ⁇ O glass transition temperature
  • the present invention therefore also provides a process for producing an agricultural film (AF), in which in step iii) the film of the at least one copolyamide in molten form to a temperature below the melting temperature (TM ⁇ C)) of the at least one copolyamide is, is cooled.
  • a process for producing an agricultural film (AF) in which in step iii) the film of the at least one copolyamide in molten form to a temperature below the melting temperature (TM ⁇ C)) of the at least one copolyamide is, is cooled.
  • Steps ii) and iii) can be carried out successively or simultaneously.
  • a step i1) is preferably carried out in which at least one further polymer (wP) is provided in molten form in a further extruder.
  • the process for producing the agricultural film (AF) then comprises the following steps: i) providing at least one copolyamide prepared by polymerization of the components
  • step i1) Form from the further extruder through the nozzle to obtain a film of the at least one copolyamide and the at least one other polymer (wP), each in molten form, iii) cooling the obtained in step ii) film of the at least one copolyamide and the at least one other Polymers (wP), each in molten form, wherein the at least one copolyamide and / or the at least one further polymer (wP) solidifies to give the agricultural film (AF).
  • step i1) the at least one further polymer (wP) is provided in molten form in another extruder.
  • another extruder means both exactly one further extruder and two or more further extruders, two or more further extruders being preferred.
  • WP further polymer
  • 1 to 13 further extruders are used, preferably 1 to 1 1 further extruders and particularly preferably 1 to 7 further extruders.
  • the agricultural film (AF) contains exactly one further layer containing the at least one further polymer (wP), exactly one further extruder is used. If the agricultural film (AF) contains exactly two further layers containing the at least one further polymer (wP), exactly two further extruders are used. If the agricultural film (AF) contains exactly five further layers containing the at least one further polymer (wP), exactly five further extruders are used.
  • the previously described designs and preferences for the first extruder apply accordingly.
  • the at least one further polymer (wP) the previously described embodiments and preferences for the optionally present in the agricultural film (AF) contained at least one further polymer (wP) apply accordingly.
  • the at least one further polymer (wP) in step i1) is provided in molten form. "In molten form” means that the at least one further polymer (wP) is provided at a temperature above the melting temperature (TM ⁇ W P)) of the at least one other polymer (wP).
  • the at least one further polymer (wP) has a temperature which is above the melting temperature (TM ⁇ W P)) of the at least one further polymer (wP). If the at least one further polymer (wP) is present in molten form, then the at least one further polymer (wP) is free-flowing.
  • Flowable means that the at least one further polymer (wP) can be conveyed in the further extruder and that the at least one further polymer (wP) can be extruded from the other extruder.
  • the at least one further polymer (wP) is provided in step i1) at a temperature in the range of 120 to 350 ° C, preferably in the range of 130 to 300 ° C and more preferably in the range of 140 to 250 ° C, respectively with the proviso that the temperature at which the at least one further polymer (wP) is provided is above the melting temperature (TM ⁇ W P)) of the at least one further polymer (wP).
  • the at least one further polymer (wP) can be provided in molten form in the further extruder by all methods known to those skilled in the art.
  • the at least one further polymer (wP) can be supplied in molten or solid form to the other extruder. If the at least one further polymer (wP) is fed to the further extruder in solid form, then it can be fed to the further extruder, for example as granules and / or as a powder. The at least one further polymer (wP) is then melted in the further extruder and thus provided in molten form in the further extruder.
  • Step i1) is usually carried out simultaneously with step i).
  • step ii) of the at least one copolyamide and the at least one further polymer (wP), in each case in molten form, contains the at least one Copolyamide in at least one first layer and the at least one further polymer (wP) in at least one further layer.
  • the film obtained in step ii) contains as many first layers containing the at least one copolyamide in molten form as were first extruders used in step i) and as many further layers containing the at least one further polymer (wP) in contain molten form, as more extruders have been used in step i1).
  • step i1) when step i1) is performed, the agricultural film (AF) obtained in step iii) is a multilayer film.
  • the agricultural film (AF) is stretched.
  • the agricultural film (AF) can be stretched after step iii), it is also possible to use the agricultural film (AF) during step iii), ie during the cooling of the film of the at least one copolyamide and optionally of the at least one further polymer (wP) to stretch.
  • the subject matter of the present invention is therefore also a process in which additionally the following step is carried out: iv) stretching the agricultural film (AF) to obtain a stretched agricultural film (AF).
  • Steps iii) and iv) can be performed sequentially or simultaneously.
  • the polymer chains of the at least one copolyamide align and the crystallinity of the at least one copolyamide can increase.
  • the polymer chains of the optionally present in the agricultural film (AF) at least one other polymer (wP) aligned during stretching.
  • the crystallinity of the at least one further polymer (wP) can also increase.
  • the stretching can be carried out by all methods known to the person skilled in the art.
  • the agricultural film (AF) may be stretched by passing over at least one roller, preferably a roller system, or by stretching it to its width. If the Agrifilm (AF) is obtained as a tube, it is also possible that the Agrifilm (AF) is stretched by blowing air into the hose of the Agrifilm (AF) and thereby stretching the Agrifilm (AF). Of course, combinations of the methods are possible. If the agricultural film (AF) is guided over at least one roller, preferably via a roller system, then the agricultural film (AF) is stretched in the extrusion direction, ie in its length. Will the Agrarian film (AF), however, stretched in its width, it is stretched perpendicular to the extrusion direction.
  • the polymer chains of the at least one copolyamide and, if appropriate, of the at least one further polymer (wP) are oriented parallel to the direction in which they are drawn .
  • the resulting stretched agricultural film (AF) is then uniaxially oriented.
  • the obtained stretched agricultural film (AF) is uniaxially oriented when the agricultural film (AF) is stretched to stretch in width.
  • the polymer chains of the at least one copolyamide and optionally of the at least one further polymer (wP) are oriented parallel to the direction in which they are drawn.
  • Uniaxially oriented means that the polymer chains are oriented substantially in one direction.
  • the agricultural film (AF) is guided over a roller system for stretching and additionally stretched in its width, then the polymer chains of the at least one copolyamide and optionally of the at least one further polymer (wP) are oriented parallel to both directions to be drawn.
  • the resulting stretched agricultural film (AF) is then biaxially oriented.
  • Biaxially oriented means that the polymer chains are oriented substantially in two different directions, preferably perpendicular to each other.
  • the Agrifilm (AF) is obtained as a tube and the Agrifilm (AF) is stretched by blowing air into the Agrifilm (AF) tube, the resulting stretched Agrifilm (AF) is uniaxially oriented.
  • the agricultural film (AF) is obtained as a tube and the agricultural film (AF) is stretched by blowing air into the hose of the agricultural film (AF) and simultaneously passing it over rollers is also stretched, the resulting stretched agricultural film (AF) is biaxially oriented.
  • the agricultural film (AF) is usually stretched at a temperature which is above the glass transition temperature (TG ⁇ C)) of the at least one copolyamide and which is below the melting temperature (TM ⁇ C)) of the at least one copolyamide. If the agricultural film (AF) is a multilayer film, it is also preferred that the agricultural film (AF) be stretched at a temperature below the melting temperature (TM ⁇ W P)) of the at least one other polymer (wP), particularly preferably at a temperature below that Melting temperature of melting at the lowest temperature at least one other polymer (wP) is.
  • the agricultural film (AF) according to the invention can be produced, for example, in a casting process or in a blown process.
  • the present invention therefore also provides an agricultural film (AF), wherein the agricultural film (AF) is produced in a casting process or in a blown process.
  • the casting process and the blowing process are known to those skilled in the art.
  • the Agrifilm (AF) is stretched in these processes, so that a stretched Agricultural Film (AF) is obtained.
  • a casting process for making the agricultural film (AF) preferably comprises the following steps i-c) to iv-c): i-c) providing at least one copolyamide prepared by polymerizing the
  • (B2) contains at least one C 4 -C 12 -diamine, the percentages by weight of components (A) and (B) in each case being based on the sum of the percentages by weight of components (A) and (B), in molten form in a first extruder, ii-c) extruding the at least one copolyamide in molten form provided in step ic) from the first extruder through a die to give a film of the at least one copolyamide in molten form, iii-c) cooling the film obtained in step ii-c) the at least one copolyamide in molten form, the at least one copolyamide solidifying to give the agricultural film (AF), iv-c) stretching the agricultural film (AF) obtained in step iii-c) by passing the agricultural film (AF) over at least one roller, preferably via a roller system, to obtain a stretched agricultural film (AF).
  • the steps ic) to iii-c) of the casting process
  • the nozzle used in the casting process in step ii-c) is usually a slot die.
  • the film of the at least one copolyamide in molten form obtained in step ii-c) is therefore preferably a flat film, so that the agricultural film (AF) obtained in step iii-c) and the stretched agricultural film (AF) obtained in step iv-c) are preferably a flat sheet is.
  • steps iii-c) and iv-c) may be performed sequentially or simultaneously.
  • steps iii-c) and iv-c) are carried out simultaneously, more preferably, steps iii-c) and iv-c) are carried out simultaneously and directly after step ii-c).
  • the at least one roll used in step iv-c), preferably the roll system, is cooled during step iv-c).
  • a blow molding process for the production of the agricultural film (AF) preferably comprises the following steps i-b) to iv-b): i-b) providing at least one copolyamide prepared by polymerizing the
  • At least one C4-Ci2-diamine wherein the weight percent of components (A) and (B) are each based on the sum of the weight percent of components (A) and (B), in molten form in a first extruder, ii) b) extruding the at least one copolyamide in molten form from the first extruder provided in step ib) through a die which is an annular die to obtain a tubular film of the at least one copolyamide in molten form; ii) b) cooling in step ii-b) obtained tube film of the at least one
  • Copolyamides in molten form wherein the at least one copolyamide solidifies to obtain the agricultural film (AF), iv-b) stretching the agricultural film (AF) obtained in step iii-b) by blowing air into the hose of the agricultural film (AF) and / or the hose is passed over a roller system to obtain a stretched agricultural film (AF).
  • the nozzle used in step ii-b) of the blowing process is preferably a stack dye, a helical distributor dye or a mixed form thereof. These nozzles are known in the art and described for example in "Blown Film Extrusion” by Kirk Cantor, 2nd Edition, Carl Hanser Verlag, Kunststoff 201 1.
  • Steps iii-b) and iv-b) can be carried out simultaneously or sequentially in the blowing process.
  • steps iii-b) and iv-b) are carried out simultaneously.
  • step iii-b) the tubular film of the at least one copolyamide obtained in step ii-b) is cooled in molten form and simultaneously being drawn by blowing air into the tubular film to obtain the stretched agricultural film (AF).
  • step i1) in which at least one further polymer (wP) is provided in a further extruder in molten form, can also be carried out and then according to step ii) the process for producing the agricultural film (AF) in step ii-c) and in step ii-b) a film of the at least one copolyamide and the at least one other polymer (wP) is obtained in each case in molten form and this according to step iii) of A process for producing the agricultural film (AF) in step iii-c) and in step iii-b) is cooled.
  • the previously described embodiments and preferences for the optionally performed step i1) of the method for producing the agricultural film (AF) apply accordingly.
  • the obtained stretched agricultural film (AF) can be wound up after its production, for example. Processes for this are known to the person skilled in the art. If the stretched Agrifilm (AF) is obtained as a hose, as in the case of blow molding, the tube can also be slit before winding. A slit film can then be wound on one or more rollers.
  • the viscosity number of copolyamides containing units derived from a C 32 -C 40 dimer acid was determined in a 0.5% strength by weight solution of phenol / o-dichlorobenzene in a weight ratio of 1: 1 at 25 ° C.
  • the viscosity number of copolyamides and polyamides containing no units derived from a C 32 -C 40 dimer acid was measured in a 0.5% by weight solution in 96% strength by weight sulfuric acid at 25 ° C. in accordance with EN ISO 307: 2007 + Amd 1: 2013 determined.
  • the glass transition temperatures and melting temperatures were determined according to ISO 1 1357-1: 2009, ISO 1 1357-2: 2013 and ISO 1 1357-3: 201 1. For this purpose, two heating runs were carried out and the glass transition and melting temperatures were determined on the basis of the second heating run.
  • the densities of the polyamides were determined by the gas pyknometer method according to EN ISO 1 183-3: 1999.
  • the copolyamide was hydrolyzed in dilute hydrochloric acid (20%).
  • the units derived from hexamethylenediamine are protonated, the chloride ion of the hydrochloric acid forming the counterion.
  • this chloride ion was then exchanged for a hydroxide ion with liberation of hexamethylenediamine.
  • the hexamethylenediamine concentration is then determined by titration with 0.1 molar hydrochloric acid, from which the content of polyamide 6.36 in the copolyamide can be determined.
  • the tear strength is determined according to Elmendorf, DIN ISO 6383-2: 2004 in the direction of extrusion (MD) and perpendicular thereto (TD).
  • the films were conditioned in standard climate for non-tropical countries according to DIN EN ISO 291: 2008.
  • the modulus of elasticity is determined according to ISO 527-3: 1995.
  • the impact strength of the monofilms was determined according to DIN ISO 7765-2: 1994 with 5 specimens at a relative humidity of 50% (50% LF), in the present case the puncture resistance is given.
  • the impact resistance of the multilayer films was determined in accordance with DIN ISO 7765-2: 1994 with 5 test specimens at a relative air humidity of 0% (0% LF), in which case the puncture work is stated.
  • the acid resistance of monofilms was determined in sulfuric acid.
  • monofilms were stretched in slide frames made of polypropylene, stored in sulfuric acid and tested after 24 h whether the monofilm is still intact.
  • a different concentration of sulfuric acid was used.
  • Monofilms prepared by a casting process were placed in 30% sulfuric acid
  • monofilms prepared by a blowing process were placed in 25% sulfuric acid.
  • acid resistance in the context of acid resistance "0"
  • the monofilament is still in tact after storage for 24 h in sulfuric acid
  • "X" indicates that the monofilm has dissolved.
  • P-1 polyamide 6 from BASF SE® sold under the brand name Ultramid B40L with a viscosity number of 250 ml / g, a glass transition temperature of 57 ° C, a melting temperature of 220 ° C and a density of 1, 153 g / ml.
  • P-2 polyamide 6 from BASF SE® sold under the brand name Ultramid B33L with a viscosity number of 195 ml / g, a glass transition temperature of 56 ° C, a melting temperature of 220 ° C and a density of 1.145 g / ml.
  • the copolyamide thus obtained was then discharged from the kettle, extruded and granulated. After extraction of the resulting granules of copolyamide for 4 times 6 hours with 95 ° C hot water, the copolyamide was dried at 90 to 140 ° C in a stream of nitrogen for 10 hours.
  • the viscosity number was 246 ml / g, the glass transition temperature at 49 ° C and the melting temperature at 21 1 ° C.
  • the proportion of polyamide 6.36 in the copolyamide based on the total weight of the copolyamide was 10.5% by weight, the density was 1.116 g / ml.
  • the resulting copolyamide was drained from the kettle, extruded and granulated.
  • the resulting granules of copolyamide were extracted with 95 ° C hot water for 4 times 6 hours and then at 90 to 140 ° C in a stream of nitrogen for 10 hours dried.
  • the copolyamide obtained had a viscosity number of 244 ml / g, a glass transition temperature of 44 ° C and a melting temperature of 203 ° C.
  • the proportion of polyamide 6:36 in the copolyamide based on the total weight of the copolyamide was 20.8 wt .-%, the density was 1, 095 g / ml.
  • a copolyamide of polyamide 6 and polyamide 6.36 prepared by the following procedure:
  • the resulting granules of the copolyamide were extracted with 95 ° C hot water for 4 times 6 hours and then dried at 90 to 140 ° C in a stream of nitrogen for 10 hours.
  • the copolyamide obtained had a viscosity number of 259 ml / g, a glass transition temperature of 38 ° C and a melting temperature of 188 ° C.
  • the proportion of polyamide 6:36 in the copolyamide based on the total weight of the copolyamide was 30.3 wt .-%, the density was 1, 076 g / ml.
  • a copolyamide of polyamide 6 and polyamide 6.36 prepared by the following procedure:
  • the resulting granules of the copolyamide were extracted with 95 ° C hot water for 4 times 6 hours and then dried at 90 to 140 ° C in a stream of nitrogen for 10 hours.
  • the copolyamide obtained had a viscosity number of 212 ml / g, a glass transition temperature of 38 ° C and a melting temperature of 187 ° C.
  • the proportion of polyamide 6:36 in the copolyamide based on the total weight of the copolyamide was 28.9 wt .-%, the density was 1, 076 g / ml.
  • WP-1 low density polyethylene from LyondellBasell® sold under the brand name Lupolen 2420 F with a MFR (melt flow rate) (190 ° C / 2.16 kg) of 0, 75 g / 10 min.
  • WP-2 low density polyethylene from LyondellBasell® sold under the brand name Lupolen 3020 K with a MFR (melt flow rate) (190 ° C / 2.16 kg) of 4 g / 10 min.
  • wP-3 anhydride-modified linear low density polyethylene from DuPont® sold under the brand name Bynel 4104 with a melt flow rate MFR (190 ° C / 2, 16 kg) of 1.1 g / 10 min.
  • wP-4 anhydride-modified linear low density polyethylene from DuPont® sold under the trade name Bynel 4105 with MFR (melt flow rate) (190 ° C / 2.16 kg) of 4 g / 10 minute wP-5 a poly (ethylvinyl alcohol) (EVOH) from Kuraray®, sold under the brand name EVAL F171 B with an MFR (melt flow rate, melt mass flow rate)
  • a 7-layer cast film plant from Collin® with a nozzle head width of 800 mm was used. So 7 extruders were used. Six of the extruders had a diameter of 30 mm (extruder B, C, D, E, F, G) and one extruder had a diameter of 45 mm (extruder A). Each of the 7 extruders was loaded with the same component. The melt of extruder A was in contact with the castroll, the melt of extruder G farthest from this. The order of the layers was A, B, C, D, E, F, G. The films produced had a thickness of 100 ⁇ and the layers had a layer thickness of 15/14/14/14/14/15 ⁇ .
  • Multilayer films with three different polymers were produced on the above-described 7-layer cast film line from Collin®.
  • the resulting multilayer films had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/14/15 ⁇ .
  • the extruders of the Castfolienstrom were applied in accordance with the structure of the multilayer films shown in Table 2 with the components.
  • % By weight of component (B) given in Table 2 is understood as meaning the% by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Table 2 also shows the properties of the multilayer film produced. Table 2:
  • Multilayer films with five different polymers were produced on the above-described 7-layer cast film line from Collin®.
  • the resulting multilayer films had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/14/15 ⁇ .
  • the extruders of the Castfolienstrom were applied according to the structure of the multilayer films specified in Table 3 with the components.
  • the percentages by weight of component (B) given in Table 3 are understood as meaning the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Table 3 also shows the properties of the multilayer film produced.
  • Monofilms were produced on a 7-layer blown film line from Collin® with a die head diameter of 180 mm.
  • 6 had a diameter of 30 mm (extruder B, C, D, E, F, G) and a diameter of 45 mm (extruder A).
  • the melt of extruder was inside the bladder, the melt of extruder G was outside.
  • the monofilms produced had a thickness of 100 ⁇ m and the layers had a layer thickness of 15/14/14/14/14 / 14/15 ⁇ in the monofilms. All extruders were loaded with the same component.
  • the films were slit before winding.
  • component (B) The components used and the properties of the monomaterial films are given in Table 4.
  • the percentages by weight of component (B) given in Table 4 are understood as meaning the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Component (B) [wt%] - - - 10.5 20.8 30.3
  • Pendulum pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum)
  • Pendulum pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum) pendulum)
  • Modulus of elasticity [MPa] 635 41 1 188 536 412 329
  • Multilayer films with three different materials were produced on a 7-layer blown film line from Collin® with a die head diameter of 180 mm. Of the 7 extruders, 6 had a diameter of 30 mm and a diameter of 45 mm. The resulting multilayer films had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/15 ⁇ .
  • the extruders of the blown film line were charged with the components according to the structure of the multilayer films given in Table 5.
  • Table 5 also shows the properties of the multilayer films produced.
  • the percentages by weight of component (B) given in Table 5 are understood to mean the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Multilayer films with five different polymers were produced on a 7-layer blown film line from Collin® with a die head diameter of 180 mm. Of the 7 extruders, 6 had a diameter of 30 mm and a diameter of 45 mm. The resulting multilayer films had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/15 ⁇ .
  • the extruders of the blown film line were charged with the components according to the structure of the multilayer films given in Table 6. Table 6 also shows the properties of the multilayer films produced.
  • the percentages by weight of component (B) given in Table 6 are understood to mean the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Monofilms were produced on a 7-layer blown film line from Collin® with a die head diameter of 180 mm. Of the 7 extruders, 6 had a diameter of 30 mm and a diameter of 45 mm. The Monomaterialfilme produced had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/14/15 ⁇ . All extruders were loaded with the same component.
  • component (B) The components used and the properties of the monofilaments are given in Table 7.
  • the percentages by weight of component (B) given in Table 7 are understood to mean the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • Component (B) [wt%] - - 28.9
  • Multilayer films were produced on a 7-layer blown film line from Collin® with a die head diameter of 180 mm. Of the 7 extruders, 6 had a diameter of 30 mm and a diameter of 45 mm. The Monomaterialfilme produced had a thickness of 100 ⁇ and the layers have a layer thickness of 15/14/14/14/14/14/15 ⁇ . All extruders were loaded with the same component.
  • component (B) The components used and the properties of the monomaterial films are given in Table 8.
  • the percentages by weight of component (B) given in Table 8 are understood as meaning the percent by weight of units derived from component (B) (polyamide 6.36 units) in the copolyamide, based on the total weight of the copolyamide.
  • copolyamide according to the invention can significantly increase the tear strength of the agricultural films (AF) both along the direction of extrusion and perpendicular to it.
  • the modulus of elasticity and puncture resistance of the agricultural films (AF) according to the invention are also in an acceptable range for practical use, so that the agricultural films (AF) according to the invention have altogether advantageous properties, in particular for use in the agricultural sector.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental Sciences (AREA)
  • Materials Engineering (AREA)
  • Soil Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Protection Of Plants (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyamides (AREA)
  • Laminated Bodies (AREA)

Abstract

La présente invention concerne un film agricole (AF) contenant au moins un copolyamide, ledit copolyamide étant préparé par polymérisation d'au moins un lactame et d'un mélange de monomères (M). L'invention concerne en outre un procédé de production du film agricole (AF) ainsi que l'utilisation du film agricole (AF) comme film de paillage, film d'ensilage, film de serre ou film pour silo.
EP17767766.3A 2016-09-14 2017-09-05 Film agricole contenant un copolyamide formé à partir d'une diamine, d'un acide dimère et d'un lactame Pending EP3512903A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16188745 2016-09-14
PCT/EP2017/072223 WO2018050485A1 (fr) 2016-09-14 2017-09-05 Film agricole contenant un copolyamide formé à partir d'une diamine, d'un acide dimère et d'un lactame

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EP3512903A1 true EP3512903A1 (fr) 2019-07-24

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US (1) US11696533B2 (fr)
EP (1) EP3512903A1 (fr)
JP (1) JP7073347B2 (fr)
KR (1) KR102407948B1 (fr)
CN (1) CN109863191B (fr)
AR (1) AR109640A1 (fr)
AU (1) AU2017326285B2 (fr)
BR (1) BR112019004925B8 (fr)
CL (1) CL2019000666A1 (fr)
IL (1) IL265341B2 (fr)
RU (1) RU2754821C2 (fr)
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WO (1) WO2018050485A1 (fr)

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EP3668926B8 (fr) 2017-08-15 2022-03-30 Basf Se Article moulé par injection comprenant des silicates à surface modifiée
DE202019000670U1 (de) 2019-02-12 2019-03-04 Agrophil Gmbh Abdeckmaterial für Biomassen
EP4251677A1 (fr) * 2020-11-24 2023-10-04 Basf Se Procédé pour la préparation de copolyamides en continu à partir de lactames, de diamines et d'acides dimères
CA3205056A1 (fr) * 2020-12-14 2022-06-23 Lubrizol Adavanced Materials, Inc Polymeres et copolymeres de polyamide n-alkyles telecheliques

Family Cites Families (15)

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Publication number Priority date Publication date Assignee Title
BE792796A (fr) 1971-12-16 1973-03-30 Du Pont Interpolymeres de polyamide condenses a l'etat fondu solubles ala temperature ambiante
JPS5114997A (ja) * 1974-07-30 1976-02-05 Showa Denko Kk Kyojugohoriamidojushino seizohoho
FR2407227A1 (fr) * 1977-10-28 1979-05-25 Rhone Poulenc Ind Procede d'obtention de copolyamides souples ayant des proprietes mecaniques ameliorees
DE3825411A1 (de) * 1988-07-27 1990-02-08 Bayer Ag Verfahren zur herstellung von polyamidfolien
JPH0641514B2 (ja) * 1988-08-17 1994-06-01 三菱化成株式会社 ブロックコポリアミドの製造法
JPH0568708A (ja) * 1991-08-09 1993-03-23 Terumo Corp 抗血栓性材料
EP0761715B1 (fr) * 1995-08-17 2003-11-05 Solar Dew Copolyétheramide et film perméable à la vapeur d'eau préparé à partir de celle-ci
DE10120453A1 (de) * 2001-04-26 2002-10-31 Bayer Ag Polyamid-Formmassen zur Herstellung besonders transparenter Folien
US7001979B2 (en) 2002-06-14 2006-02-21 H.B. Fuller Licensing & Financing Inc. Polyamide and composition and article including same
BR0318549A (pt) 2003-10-17 2006-10-10 Invatec Srl balões para sondas
AU2008335400A1 (en) * 2007-12-05 2009-06-18 The Regents Of The University Of California Devices and methods for suppression of tinnitus
DE102009052948B4 (de) 2009-11-12 2013-05-29 Rkw Se Silageabdeckung
US20130225786A1 (en) * 2010-09-06 2013-08-29 Institut National Des Sciences Appliquees De Lyon Copolyamides
ES2623227T3 (es) 2012-12-20 2017-07-10 Dsm Ip Assets B.V. Procedimiento para producir película soplada multicapa y película obtenida por el proceso
AU2017326287B2 (en) * 2016-09-14 2021-12-09 Basf Se Polymer film comprising a co-polyamide of a diamine, a dimer acid and a lactam

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AU2017326285B2 (en) 2021-08-26
JP7073347B2 (ja) 2022-05-23
US20190269075A1 (en) 2019-09-05
RU2019110956A (ru) 2020-10-15
BR112019004925A2 (pt) 2021-03-30
CN109863191B (zh) 2022-05-31
CN109863191A (zh) 2019-06-07
AU2017326285A1 (en) 2019-05-02
AR109640A1 (es) 2019-01-09
BR112019004925B1 (pt) 2023-02-14
CL2019000666A1 (es) 2019-05-17
RU2019110956A3 (fr) 2020-12-23
KR20190052057A (ko) 2019-05-15
BR112019004925B8 (pt) 2023-03-14
KR102407948B1 (ko) 2022-06-13
US11696533B2 (en) 2023-07-11
UA128519C2 (uk) 2024-08-07
IL265341B2 (en) 2023-07-01
RU2754821C2 (ru) 2021-09-07
JP2019529640A (ja) 2019-10-17
IL265341A (en) 2019-05-30
WO2018050485A1 (fr) 2018-03-22

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