EP3507243A1 - Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite - Google Patents

Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite

Info

Publication number
EP3507243A1
EP3507243A1 EP17778003.8A EP17778003A EP3507243A1 EP 3507243 A1 EP3507243 A1 EP 3507243A1 EP 17778003 A EP17778003 A EP 17778003A EP 3507243 A1 EP3507243 A1 EP 3507243A1
Authority
EP
European Patent Office
Prior art keywords
reaction mixture
ssz
synthesis
ppm
aluminosilicate zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17778003.8A
Other languages
German (de)
English (en)
Other versions
EP3507243B1 (fr
Inventor
Stacey Ian Zones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Publication of EP3507243A1 publication Critical patent/EP3507243A1/fr
Application granted granted Critical
Publication of EP3507243B1 publication Critical patent/EP3507243B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram

Definitions

  • This disclosure is directed to the synthesis of zeolite SSZ-26.
  • Zeolites SSZ-26 and SSZ-33 belong to a family of zeolites with three- dimensional intersecting 10- and 12-membered ring channels. These two zeolites can be characterized as members of a family of materials in which the two end-members are formed by the stacking of layers in an ABAB sequence ("polymorph A”) or an ABCABC sequence (“polymorph B").
  • polymorph A ABAB sequence
  • polymorph B ABCABC sequence
  • the framework formed by polymorph A is of orthorhombic symmetry while the framework formed by polymorph B is of monoclinic symmetry.
  • p fault probability
  • Fault probabilities of 0% and 100% represent the end-members polymorph B and polymorph A, respectively.
  • the aluminosilicate SSZ-26 and the borosilicate SSZ-33 are members of this family of materials and have fault probabilities of approximately 15% and 30%, respectively.
  • Zeolite CIT-1 (CON) corresponds to a pure or nearly pure polymorph B.
  • U.S. Patent No. 4,910,006 discloses zeolite SSZ-26 and its synthesis using hexamethyl[4.3.3.0]propellane-8,ll-diammonium cations as a structure directing agent.
  • U.S. Patent No. 7,648,694 discloses the synthesis of zeolites belonging to the SSZ-26/SSZ-33 family of zeolites using a structure directing agent selected from l,4-bis(A/-cyclohexylpyrrolidinium)butane dications, l,5-bis(/V- cyclohexylpyrrolidinium)pentane dications, l,5-bis(A/,/V- dimethylcyclohexylammonium)pentane dications, l,4-bis(/V- cyclohexylpiperidinium)butane dications, and l,4-bis(/V- cyclopentylpiperidinium)butane dications.
  • a structure directing agent selected from l,4-bis(A/-cyclohexylpyrrolidinium)butane dications, l,5-bis(/V- cyclohe
  • U.S. Patent No. 7,837,978 discloses the direct synthesis of aluminum- containing SSZ-26 using a structure directing agent comprising cis-N,N- diethyldecahydroquinolinium cations or a mixture of cis-N,N- diethyldecahydroquinolinium cations and frans-A/,A/-diethyldecahydroquinolinium cations.
  • aluminosilicate zeolite SSZ-26 by: (a) preparing a reaction mixture comprising: (1) a FAU framework type zeolite; (2) a source of Group 1 or Group 2 metal; (3) hydroxide ions; (4) a structure directing agent comprising l,4-bis(/V- cyclohexylpyrrolidinium)butane dications; and (5) water; and (b) subjecting the reaction mixture to crystallization condition sufficient to form crystals of
  • aluminosilicate zeolite SSZ-26 aluminosilicate zeolite SSZ-26.
  • FIG. 1 is a powder X-ray diffraction (XRD) pattern of the as-synthesized zeolite prepared in Example 1.
  • frame type is used in the sense described in the "Atlas of Zeolite Framework 7ypes,"Sixth Revised Edition, Elsevier (2007).
  • as-synthesized is employed herein to refer to a zeolite in its form after crystallization, prior to removal of the structure directing agent.
  • anhydrous is employed herein to refer to a zeolite substantially devoid of both physically adsorbed and chemically adsorbed water.
  • the term "substantially free" when used in relation to a specific component of a reaction mixture means that the reaction mixture can contain less than 0.5 wt. % (e.g., less than 0.1 wt. %, less than 0.05 wt. %, less than 0.01 wt. %, or no measurable quantity) of that component.
  • aluminosilicate zeolite SSZ-26 can be synthesized by: (a) preparing a reaction mixture comprising (1) a FAU framework type zeolite; (2) a source of Group 1 or Group 2 metal (M); (3) hydroxide ions; (4) a structure directing agent (Q) comprising l,4-bis(A/-cyclohexylpyrrolidinium)butane dications; and (5) water; and (b) subjecting the reaction mixture to crystallization condition sufficient to form crystals of aluminosilicate zeolite SSZ-26.
  • Suitable FAU framework type zeolites are available commercially from Zeolyst International (Conshohocken, PA) and Tosoh Corporation (Tokyo, Japan).
  • the reaction mixture may be substantially free of a non-zeolitic source of silicon oxide.
  • non-zeolitic sources of silicon oxide include colloidal silicas, fumed silicas, precipitated silicas, alkali metal silicates, and tetraalkyl orthosilicates.
  • the reaction mixture may be substantially free of a non-zeolitic source of aluminum oxide.
  • non-zeolitic sources of aluminum oxide include hydrated alumina, aluminum hydroxide, alkali metal aluminates, aluminum alkoxides, and water-soluble aluminum salts (e.g., aluminum nitrate).
  • Suitable sources of Group 1 or Group 2 metal (M) cations include metal oxide, metal hydroxide, metal chloride, metal fluoride, metal sulfate, metal nitrate, and metal aluminate.
  • the metal cation is a Group 1 metal cation selected from sodium, potassium, and mixtures of sodium and potassium cations. Sodium cation is preferred.
  • Suitable sources of hydroxide ions include Group 1 or Group 2 metal hydroxides, such as sodium hydroxide. Hydroxide can also be present as a counter- ion of the structure directing agent.
  • the structure directing agent (Q) comprises l,4-bis(/V- cyclohexylpyrrolidinium)butane dications, represented by the following structure (1):
  • Suitable sources of Q are the hydroxides, chlorides, bromides, and/or other salts of the diquaternary ammonium compound.
  • the reaction mixture may contain seeds of a zeolitic material, such as SSZ-26 from a previous synthesis, desirably in an amount of from 0.01 to 10,000 ppm by weight (e.g., from 100 to 5000 ppm by weight) of the reaction mixture. Seeding can be advantageous in decreasing the time necessary for complete crystallization to occur. Seeding can lead to an increased purity of the obtained by promoting the nucleation and/or formation of SSZ-26 over any undesired phases.
  • the reaction mixture can be supplied by more than one source. Also, two or more reaction components can be provided by one source.
  • reaction mixture can be prepared either batch wise or
  • Crystal size, morphology and crystallization time of the zeolite herein can vary with the nature of the reaction mixture and the crystallization conditions.
  • Crystallization of SSZ-26 from the above reaction mixture can be carried out under either static, tumbled or stirred conditions in a suitable reactor vessel, such as for example polypropylene jars or Teflon-lined or stainless steel autoclaves, at a temperature of from 125°C to 200°C (e.g., from 130°C to 160°C) for a time sufficient for crystallization to occur at the temperature used (e.g., from 10 to 250 hours or from 15 to 100 hours).
  • the reaction mixture is usually reacted under autogenous pressure, or optionally in the presence of a gas such as nitrogen.
  • the solid product is separated from the reaction mixture by standard mechanical separation techniques such as centrifugation or filtration.
  • the recovered crystals are water-washed and then dried to obtain the as-synthesized SSZ-26 crystals.
  • the drying step is typically performed at a temperature of less than 200°C.
  • the recovered crystalline SSZ- 26 product contains within its pore structure at least a portion of the structure directing agent used in the synthesis.
  • the as-synthesized zeolite may be subjected to treatment to remove part, or all, of the organic structure directing agent used in its synthesis.
  • This is conveniently effected by thermal treatment (calcination) in which the as-synthesized material is heated at a temperature of at least about 370°C for at least 1 minute and generally not longer than 20 hours. While sub-atmospheric pressure can be employed for the thermal treatment, atmospheric pressure is desired for reasons of convenience.
  • the thermal treatment can be performed at a temperature up to 925°C.
  • the structure directing agent may be removed by photolysis techniques as described in U.S. Patent No. 6,960,327.
  • the original Group 1 and/or Group 2 metal cations (e.g., Na + ) in the as- synthesized material can be replaced in accordance with techniques well known in the art by ion exchange with other cations.
  • Preferred replacing cations include metal ions, hydrogen ions, hydrogen precursor (e.g., ammonium) ions, and combinations thereof.
  • Particularly preferred replacing cations are those which tailor catalytic activity for certain organic compound conversion reactions. These include hydrogen, rare earth metals and metals of Groups 2 to 15 of the Periodic Table.
  • aluminosilicate zeolite SSZ- 26 prepared by the method described herein has a chemical composition, in terms of molar ratios, as described in Table 2:
  • the as-synthesized form of aluminosilicate SSZ- 26 may have molar ratios different from the molar ratios of reactants of the reaction mixture used to prepare the as-synthesized form. This result may occur due to incomplete incorporation of 100% of the reactants of the reaction mixture into the crystals formed (from the reaction mixture).
  • aluminosilicate zeolite SSZ-26 is characterized by an X-ray diffraction pattern which, in the as-synthesized form of the zeolite, includes at least the peaks set forth in Table 3 and which, in the calcined form of the zeolite includes at least the peaks set forth in Table 4.
  • the powder XRD patterns provided are based on a relative intensity scale in which the strongest line in the XRD pattern is assigned a value of 100:
  • the powder XRD patterns provided are based on a relative intensity scale which the strongest line in the XRD pattern is assigned a value of 100:
  • the resulting product was analyzed by powder XRD.
  • the powder X-ray diffraction pattern is shown in FIG. 1 and indicates that the material is SSZ-26.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

L'invention concerne également un procédé de synthèse de zéolite d'aluminosilicate SSZ-26 par transformation interzéolite.
EP17778003.8A 2016-09-01 2017-08-30 Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite Active EP3507243B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662382298P 2016-09-01 2016-09-01
PCT/US2017/049286 WO2018044981A1 (fr) 2016-09-01 2017-08-30 Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite

Publications (2)

Publication Number Publication Date
EP3507243A1 true EP3507243A1 (fr) 2019-07-10
EP3507243B1 EP3507243B1 (fr) 2020-05-13

Family

ID=60001994

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17778003.8A Active EP3507243B1 (fr) 2016-09-01 2017-08-30 Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite

Country Status (6)

Country Link
US (1) US10189717B2 (fr)
EP (1) EP3507243B1 (fr)
JP (1) JP7023871B2 (fr)
KR (1) KR102413862B1 (fr)
CN (1) CN109153577B (fr)
WO (1) WO2018044981A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10486145B2 (en) * 2015-10-12 2019-11-26 Umicore Ag & Co. Kg One-pot synthesis of copper containing small-pore zeolites
US10737946B1 (en) 2019-08-29 2020-08-11 Chevron U.S.A. Inc. Synthesis of aluminum-containing molecular sieves of SEW framework type
US10836644B1 (en) * 2019-10-02 2020-11-17 Chevron U.S.A. Inc. Small crystal SSZ-27, its synthesis and use
CN115916699B (zh) * 2020-08-03 2024-05-07 雪佛龙美国公司 沸石ssz-13的低压合成

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4910006A (en) * 1988-03-23 1990-03-20 Chevron Research Company Zeolite SSZ-26
US5007997A (en) 1988-03-23 1991-04-16 Chevron Research Company Zeolite SSZ-26
WO2003006370A1 (fr) * 2001-07-13 2003-01-23 Chevron U.S.A. Inc. Zeolithe ssz-58
US6960327B2 (en) 2003-01-30 2005-11-01 The Regents Of The University Of California Methods for removing organic compounds from nano-composite materials
ES2247921B1 (es) 2004-04-07 2007-06-16 Universidad Politecnica De Valencia Un material amorfo microporoso, procedimiento de preparacion y su uso en la conversion catalitica de compuestos organicos.
US7837978B2 (en) 2006-10-13 2010-11-23 Chevron U.S.A. Inc. Process for preparing aluminum-containing molecular sieve SSZ-26
US7648694B2 (en) 2008-10-10 2010-01-19 Chevron U.S.A. Inc. Method for preparing SSZ-26/33 zeolites using novel structure directing agents
JP5485369B2 (ja) * 2009-04-02 2014-05-07 シェブロン ユー．エス．エー． インコーポレイテッド 新規構造制御剤を使用してｃｈａ型モレキュラーシーブを調製する方法
US8198501B2 (en) 2009-11-30 2012-06-12 Chevron U.S.A. Inc. Zeolite catalyst for hydroisomerization of light paraffins to produce high octane gasoline
US8512674B1 (en) * 2012-03-01 2013-08-20 Chevron U.S.A. Inc. Preparation of molecular sieve SSZ-23
US8647601B2 (en) * 2012-06-08 2014-02-11 Chevron U.S.A. Inc. Method for making aluminosilicate zeolite SSZ-33
KR20150087302A (ko) 2012-11-25 2015-07-29 셰브런 유.에스.에이.인크. 콜로이드성 알루미노실리케이트를 이용한 cha-형 분자체를 제조하는 방법

Also Published As

Publication number Publication date
EP3507243B1 (fr) 2020-05-13
CN109153577B (zh) 2022-05-17
WO2018044981A1 (fr) 2018-03-08
JP2019529296A (ja) 2019-10-17
KR102413862B1 (ko) 2022-06-29
CN109153577A (zh) 2019-01-04
KR20190042084A (ko) 2019-04-23
JP7023871B2 (ja) 2022-02-22
US20180057365A1 (en) 2018-03-01
US10189717B2 (en) 2019-01-29

Similar Documents

Publication Publication Date Title
US9815705B2 (en) Synthesis of molecular sieve SSZ-98
EP3507243B1 (fr) Synthèse de zéolite d'aluminosilicate ssz-26 par transformation interzéolite
WO2016039826A1 (fr) Procédé de préparation de zéolite ssz-52 faisant appel à des agents d'orientation de la structure prédite par le calcul
WO2016039825A1 (fr) Procédé de préparation de zéolite ssz-52
US9890051B2 (en) Synthesis of zeolite SSZ-31
EP3224198B1 (fr) Procédé de préparation de tamis moléculaires en aluminosilicate présentant le type de squelette cha
WO2018071113A1 (fr) Synthèse d'un tamis moléculaire ssz-83
EP3634910B1 (fr) Synthèse de tamis moléculaires du type à structure sfe
EP3638623B1 (fr) Tamis moléculaire ssz-111, sa synthèse et son utilisation
US10214427B2 (en) Molecular sieve SSZ-109, its synthesis and use
US9908784B2 (en) Synthesis of molecular sieve SSZ-99
US10730757B1 (en) Method for preparing SSZ-26/33 zeolites
WO2022195463A1 (fr) Synthèse de zéolites ayant la structure de la ferriérite
US10239761B2 (en) Synthesis of zeolite SSZ-31
US10384949B1 (en) Synthesis of molecular sieve SSZ-43

Legal Events

Date Code Title Description
STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: UNKNOWN

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE INTERNATIONAL PUBLICATION HAS BEEN MADE

PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20181019

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAV Request for validation of the european patent (deleted)
DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20200210

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602017016778

Country of ref document: DE

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1270042

Country of ref document: AT

Kind code of ref document: T

Effective date: 20200615

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200914

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200913

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200814

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200813

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200813

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1270042

Country of ref document: AT

Kind code of ref document: T

Effective date: 20200513

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 602017016778

Country of ref document: DE

Representative=s name: HL KEMPNER PATENTANWAELTE, SOLICITORS (ENGLAND, DE

Ref country code: DE

Ref legal event code: R082

Ref document number: 602017016778

Country of ref document: DE

Representative=s name: HL KEMPNER PATENTANWALT, RECHTSANWALT, SOLICIT, DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602017016778

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

26N No opposition filed

Effective date: 20210216

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200831

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200830

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200831

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20200831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200831

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200830

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200513

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230522

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20240705

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240702

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240701

Year of fee payment: 8

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240702

Year of fee payment: 8