EP3497196B1 - Waschzusammensetzung - Google Patents

Waschzusammensetzung Download PDF

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Publication number
EP3497196B1
EP3497196B1 EP17743288.7A EP17743288A EP3497196B1 EP 3497196 B1 EP3497196 B1 EP 3497196B1 EP 17743288 A EP17743288 A EP 17743288A EP 3497196 B1 EP3497196 B1 EP 3497196B1
Authority
EP
European Patent Office
Prior art keywords
powder
silicone
powder composition
cationic polymer
cationic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP17743288.7A
Other languages
English (en)
French (fr)
Other versions
EP3497196A1 (de
Inventor
Amanda Jane Adams
Martin Charles Crossman
Philip Ronald Moore
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP3497196A1 publication Critical patent/EP3497196A1/de
Application granted granted Critical
Publication of EP3497196B1 publication Critical patent/EP3497196B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0082Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Definitions

  • the present invention concerns a powder composition for use in laundry.
  • the powder may be used to provide softening benefits.
  • Silicones are known in the art to provide softening benefits for example WO 2006/005068 (The Procter & Gamble Company) discloses liquid laundry detergent compositions containing functionalised silicone materials as fabric care agents. WO 2015/078692 discloses that fabric softening silicones have been used to provide softness to fabrics from a laundry detergent composition.
  • EP 1561803 discloses a need to improve the fabric-softening performance of a laundry detergent composition without unduly negatively affecting its fabric-cleaning performance.
  • an auxiliary composition for use in the laundering or treatment of fabrics, comprising a co-particulate admix, the co-particulate ad-mix comprising: i) clay; and ii) a hydrophobic component that is a silicone; and iii) a cationic polymeric fabric-softening boosting component that is a cationic guar gum; ...
  • co-particulate admix is obtained by a process comprising the steps of contracting the hydrophobic component with the clay and the charged polymeric fabric-softening boosting component to form a mixture, and then agglomerating the mixture in a high shear mixer and/or a low shear mixer to form a co-particulate admix.
  • a powder composition for laundry comprising silicone, cationic polymer and carrier wherein the silicone composition and cationic polymer are loaded onto the carrier and the carrier is selected from sodium carbonate, sodium tripolyphosphate and mixtures thereof and wherein the ratio of silicone to cationic polymer is between 5:4 and 8:1 and the combined weight of silicone and cationic polymer is 15 to 35 w.t.% of the powder composition.
  • the present invention relates to a powder composition.
  • the powder composition may be used in a powder form or formed into a whole or part of a tablet or solid structure.
  • the powder composition may be utilised as a laundry product on its own to provide softening benefits for example as an ancillary product.
  • the powder composition may be integrated into another laundry product to provide an additional softening benefit e.g. added to a powdered laundry detergent, added to a unit dose capsule or incorporated into a tablet.
  • the powder forms part of a unit dose capsule or tablet, preferably the powder is contained in a unit does capsule. More preferably the powder is contained in a unit dose capsule which further comprises a detergent composition. Preferably the detergent composition is in a separate compartment to the powder.
  • the silicones suitable for the present invention are fabric softening silicones.
  • Non-limiting examples of such silicones include: non-functionalised silicones such as polydimethylsiloxane (PDMS) or alkyl (or alkoxy) functional silicones, and functionalised silicones or copolymers with one or more different types of functional groups such as amino, phenyl, polyether, acrylate, siliconhydride, carboxy acid, quarternized nitrogen etc.
  • the molecular weight of the softening silicone is preferably less than 150 000 g/mol, more preferably the molecular weight is less than 125 000 g/mol, most preferably the molecular weight is less than 105 00 g/mol.
  • the molecular weight can be from 500 to 150 000 g/mol, more preferably the molecular weight 500 to 125 000 g/mol, most preferably the molecular weight is 500 to 105 00 g/mol.
  • the viscosity of the silicone is preferably 500 to 11 000 cP as measured at 25°C using a TA Instruments Discovery HR-2 rheometer. Viscosity is determined at a range of shear rates between 0.1 s-1 and 10s-1 and the largest value taken as the viscosity.
  • Preferred silicones are selected from polydialkylsiloxanes, anionic silicones and mixtures thereof.
  • the silicones are selected from polydialkylsiloxanes, amino functionalised silicones, carboxyl functionalised silicone and mixtures thereof.
  • Commercially available examples are Wacker SLM 441075, SFD209 (Ex Dow Corning) or X-22-3014E (ShinEtsu) DOW CORNING® 2-8566 AMINO FLUID and DOW CORNING® 200 FLUID.
  • the silicone may be in the form of an emulsion or a fluid. It is preferably a silicone fluid.
  • the cationic polymer may also be referred to as a deposition polymer, this aids the delivery of the silicone composition to the textile surface.
  • the cationic polymer may be naturally derived or synthetic.
  • suitable cationic polymers include: cationic guars, acrylate polymers, cationic starches, cationic amino resins, cationic urea resins, and cationic polysaccharides; preferably cationic celluloses.
  • the cationic polymer is selected from; cationic guars, cationic cellulose, and cationic acrylate polymers.
  • Cationic hydroxyethyl cellulose is a particularly preferred cationic cellulose.
  • a particularly preferred class of cationic polymer is cationic celloluse ethers.
  • ethers are commercially available under the tradename Ucare LR-400 (polyquaternium-10) or the Jaguar polymers such as Guar hydroxypropyl trimonium chloride, Jaguar C13 ex Rhodia.
  • the molecular weight of the cationic polymer is preferably greater than 50 000 g/mol, more preferably greater than 100 000 g/mol.
  • the molecular weight is preferably less than 5 000 000 g/mol.
  • the carrier material for the silicone composition and cationic polymer is selected from sodium carbonate, sodium tripolyphosphate and mixtures thereof. These are inorganic sodium salts.
  • Sodium carbonate may also be referred to as soda ash and is commercially available from Tata Chemicals Europe.
  • a light grade of sodium carbonate is preferred.
  • Sodium triphosphate is commercially available from Sigma-Aldrich.
  • the carrier material is sodium carbonate.
  • ingredients may be loaded onto the carrier material in addition to the silicone and cationic polymer. These may, for example be other laundry ingredients, benefit agents or materials providing an enhanced consumer experience.
  • Some particularly preferred optional ingredients include:
  • Free oil perfumes and fragrances may be added to the powder composition. These may be to scent the powder, to provide scent in the washing process or to provide scent to the textiles after the wash.
  • the powders of the present invention may comprise one or more perfumes if desired.
  • the perfume is preferably present in an amount from 0.01 to 10 % by weight, more preferably from 0.05 to 5 % by weight, even more preferably from 0.1 to 4.0 %, most preferably from 0.15 to 4.0 % by weight, based on the total weight of the composition.
  • Useful components of the perfume include materials of both natural and synthetic origin. They include single compounds and mixtures. Specific examples of such components may be found in the current literature, e.g., in Fenaroli's Handbook of Flavor Ingredients, 1975, CRC Press ; Synthetic Food Adjuncts, 1947 by M. B. Jacobs, edited by Van Nostrand ; or Perfume and Flavor Chemicals by S. Arctander 1969, Montclair, N.J. (USA ). These substances are well known to the person skilled in the art of perfuming, flavouring, and/or aromatizing consumer products.
  • Particularly preferred perfume ingredients are blooming perfume ingredients and substantive perfume ingredients. Blooming perfume ingredients are defined by a boiling point less than 250°C and a LogP ogreater than 2.5. Substantive perfume ingredients are defined by a boiling point greater than 250°C and a LogP greater than 2.5. Preferably a perfume composition will comprise a mixture of blooming and substantive perfume ingredients. The perfume composition may comprise other perfume ingredients.
  • perfume components it is commonplace for a plurality of perfume components to be present in a formulation.
  • compositions for use in the present invention it is envisaged that there will be three or more, preferably four or more, more preferably five or more, most preferably six or more different perfume components.
  • An upper limit of 300 perfume ingredients may be applied.
  • Colour may optionally be provided to the powder by the addition of one or more colorants.
  • the colorant comprises one or more dyes and/or pigments.
  • the pigment/dye may be any colour. These may be substantive or non-substantive dyes/pigments. A preferred level is one where the colour is discernible to the consumer and aesthetically pleasing.
  • the powder may be a plurality of colours.
  • the powder of the present invention may further comprise microcapsules encapsulating a benefit agent.
  • Suitable encapsulating material may comprise, but are not limited to; aminoplasts, proteins, polyurethanes, polyacrylates, polymethacrylates, polysaccharides, polyamides, polyolefins, gums, silicones, lipids, modified cellulose, polyphosphate, polystyrene, polyesters or combinations thereof.
  • Preferred benefit agents include perfumes, lubricants and any other oily materials. Particularly preferred benefit agents include, but are not limited to, the following:
  • perfume components include both odiferous materials and pro-fragrance materials.
  • perfume ingredients particularly preferred perfume ingredients are blooming perfume ingredients and substantive perfume ingredients. Blooming perfume ingredients are defined by a boiling point less than 250°C and a LogP ogreater than 2.5. Substantive perfume ingredients are defined by a boiling point greater than 250°C and a LogP greater than 2.5.
  • a perfume composition will comprise a mixture of blooming and substantive perfume ingredients. The perfume composition may comprise other perfume ingredients.
  • perfume components it is commonplace for a plurality of perfume components to be present in a formulation.
  • compositions for use in the present invention it is envisaged that there will be three or more, preferably four or more, more preferably five or more, most preferably six or more different perfume components.
  • An upper limit of 300 perfume ingredients may be applied.
  • the powder composition of the present invention preferably comprises 60 to 85 w.t. % sodium carbonate, sodium tripolyphosphate or mixtures thereof, more preferably 65 to 85 w.t. %, most preferably 65 to 80 w.t. %.
  • the powder composition of the present invention comprises a combined weight of silicone and cationic polymer 15 to 35 w.t. %.
  • the ratio of silicone to cationic polymer is between 5:4 and 8:1, more preferably between 5:4 and 6:1 and most preferably between 5:3 and 5:1.
  • a final laundry product comprising the powder of the present invention comprises 10 to 30 w.t. % silicone, more preferably, 15 to 25 w.t. % silicone.
  • the silicone, cationic polymer and carrier comprise at least 90 w.t. % of the powder composition. More preferably the silicone, cationic polymer and carrier comprise at least 95 w.t. % of the powder composition.
  • the powder of the present invention may in one embodiment be prepared by the following method:
  • the other laundry product my for example be a powder laundry detergent, a laundry tablet, or a laundry unit dose capsule.
  • the powder is used for softening benefits in other words as a softening booster for textiles.
  • the powder may be incorporated into another laundry product or may be for use as a separate, stand-alone product which can be added during the wash process for a softening boost.
  • the carrier material was added in to a Cutter C6 (ex. Sirman) mixer which was fitted with dough mix blades, and the mixer turned on.
  • the carboxysilicone 1 and cationic polymer 2 where mixed separately and slowly dripped into the mixer while the mixer was running. Mixing was continued for a short period to ensure thorough mixing.
  • the resulting powder was assessed visually. Dry powders which can flow more easily demonstrate higher loading capacity of the silicone, polymer mix. Damp and sticky powders demonstrate a lower loading capacity for the silicone, polymer mix.
  • the powder was loaded into a cylinder and the surface levelled. A 10 kg consolidation weight was placed slowly on top of the powder and allowed to remain in position for 2 minutes. The weight was then removed and the cylinder removed carefully from the powder to leave a free-standing briquette of powder. If the briquette remained standing, a 200g weight was placed on the top of the briquette. If after 10 seconds the briquette was still standing, a 250g weight was placed on top of the briquette. If after 10 seconds the briquette was still standing, a 100g weight was added. 100g weights continued to be added until the briquette collapsed.
  • the cohesiveness of a powder is classified by the weight (w.t.) as follows:
  • the visual assessment of the sodium carbonate and sodium tripolyphosphate carriers compared to the bentonite clay demonstrate that the two sodium carriers can carry more silicone and cationic polymer mix than the bentonite, while maintaining the properties of a flowing powder. Flowing powders are necessary for the processing and use of laundry products.
  • the UTC results demonstrate that the sodium carriers are have a good flow / have improved flow compared to the bentonite clay, which was cohesive and required significantly more weight to make the briquette collapse. If the carrier is a poor carrier and does not hold all of the silicone and cationic polymer mix, the powder sticks together and can support weights. However if the silicone and cationic polymer mix is carried well, the carrier is a free flowing powder which falls apart when weights are place on top.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Claims (15)

  1. Pulverzusammensetzung für Wäsche, umfassend: Silicon, kationisches Polymer und Träger, wobei die Siliconzusammensetzung und das kationische Polymer auf den Träger geladen werden und der Träger unter Natriumcarbonat, Natriumtripolyphosphat und Mischungen davon ausgewählt ist und wobei das Verhältnis von Silicon zu kationischem Polymer zwischen 5:4 und 8:1 liegt und das kombinierte Gewicht von Silicon und kationischem Polymer 15 bis 35 Gew.-% der Pulverzusammensetzung beträgt.
  2. Pulver nach Anspruch 1, wobei das Silicon, das kationische Polymer und der Träger mindestens 90 Gew.-% der Pulverzusammensetzung umfassen.
  3. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Silicon unter Polydialkylsiloxanen, anionischen Siliconen und Mischungen davon ausgewählt ist.
  4. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Molekulargewicht des Silicons weniger als 150 000 g/mol beträgt.
  5. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das fertige Waschmittelprodukt, das das Pulver gemäß der vorliegenden Erfindung umfasst, 10 bis 30 Gew.-% Silicon umfasst.
  6. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Pulver 60 bis 85 Gew.-% Natriumcarbonat, Natriumtripolyphosphat oder Mischungen davon umfasst.
  7. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei der Träger Natriumcarbonat ist.
  8. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das kationische Polymer unter kationischen Guars, kationischer Cellulose und kationischen Acrylatpolymeren ausgewählt ist.
  9. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das kationische Polymer unter kationischen Guars und kationischen Cellulosepolymeren ausgewählt ist.
  10. Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Molekulargewicht des kationischen Polymers größer als 50 000 g/mol ist.
  11. Einheitsdosiskapsel, die die Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch enthält.
  12. Einheitsdosiskapsel nach Anspruch 11, die ferner eine Waschmittelzusammensetzung enthält.
  13. Einheitsdosiskapsel nach Anspruch 12, wobei die Waschmittelzusammensetzung zum Pulver in einer gesonderten Kammer einer Einheitsdosis vorliegt.
  14. Verfahren zur Herstellung der Pulverzusammensetzung nach irgendeinem der Ansprüche 1 bis 10, umfassend die Schritte:
    - Herstellen einer Vormischung von Silicon und kationischem Polymer
    - Zugeben der Vormischung zu dem Natriumcarbonat, Natriumtripolyphosphat und Mischungen davon
    - Mischen
    - optional Zugeben des Pulvers zu einem anderen Waschmittelprodukt.
  15. Verwendung der Pulverzusammensetzung nach irgendeinem der Ansprüche 1-10 zum Weichmachen von Textilien.
EP17743288.7A 2016-08-10 2017-07-13 Waschzusammensetzung Active EP3497196B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16183543 2016-08-10
PCT/EP2017/067792 WO2018028927A1 (en) 2016-08-10 2017-07-13 Laundry composition

Publications (2)

Publication Number Publication Date
EP3497196A1 EP3497196A1 (de) 2019-06-19
EP3497196B1 true EP3497196B1 (de) 2020-01-29

Family

ID=56618069

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17743288.7A Active EP3497196B1 (de) 2016-08-10 2017-07-13 Waschzusammensetzung

Country Status (5)

Country Link
EP (1) EP3497196B1 (de)
CN (1) CN109563443B (de)
AR (1) AR109308A1 (de)
WO (1) WO2018028927A1 (de)
ZA (1) ZA201900610B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021115724A1 (en) * 2019-12-11 2021-06-17 Unilever Ip Holdings B.V. Detergent composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE393204T1 (de) 2004-02-03 2008-05-15 Procter & Gamble Zusammensetzung zum waschen oder behandeln von wäsche
DE602004024955D1 (de) * 2004-02-03 2010-02-25 Procter & Gamble Zusammensetzung zur Wäschereinigung oder -behandlung, und ein Herstellungsverfahren für die Zusammensetzung
US20060003913A1 (en) 2004-06-30 2006-01-05 The Procter & Gamble Company Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents
GB0518059D0 (en) * 2005-09-06 2005-10-12 Dow Corning Delivery system for releasing active ingredients
WO2009156233A1 (en) * 2008-06-25 2009-12-30 Unilever Plc Laundry treatment compositions
EP2145944B1 (de) * 2008-07-14 2014-03-26 The Procter & Gamble Company Partikel zur Vermittlung der stoffweichenden Abgabe auf damit behandelten Stoffen und zur Bereitstellung einer gewünschten Schaumunterdrückung
WO2012075611A1 (en) * 2010-12-10 2012-06-14 The Procter & Gamble Company Laundry detergents
WO2015078692A1 (en) 2013-11-27 2015-06-04 Unilever Plc Laundry compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
BR112019002470A2 (pt) 2019-05-14
AR109308A1 (es) 2018-11-21
WO2018028927A1 (en) 2018-02-15
EP3497196A1 (de) 2019-06-19
CN109563443B (zh) 2021-01-26
CN109563443A (zh) 2019-04-02
ZA201900610B (en) 2020-05-27

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