EP3497196B1 - Waschzusammensetzung - Google Patents
Waschzusammensetzung Download PDFInfo
- Publication number
- EP3497196B1 EP3497196B1 EP17743288.7A EP17743288A EP3497196B1 EP 3497196 B1 EP3497196 B1 EP 3497196B1 EP 17743288 A EP17743288 A EP 17743288A EP 3497196 B1 EP3497196 B1 EP 3497196B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- powder
- silicone
- powder composition
- cationic polymer
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 79
- 239000000843 powder Substances 0.000 claims description 73
- 229920001296 polysiloxane Polymers 0.000 claims description 44
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 36
- 229920006317 cationic polymer Polymers 0.000 claims description 35
- 125000002091 cationic group Chemical group 0.000 claims description 19
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 18
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 13
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 11
- 239000002775 capsule Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000004753 textile Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 229920006294 polydialkylsiloxane Polymers 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 239000002304 perfume Substances 0.000 description 35
- 239000004615 ingredient Substances 0.000 description 21
- 235000017550 sodium carbonate Nutrition 0.000 description 14
- 239000004484 Briquette Substances 0.000 description 10
- -1 polydimethylsiloxane Polymers 0.000 description 9
- 239000004744 fabric Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- 239000012876 carrier material Substances 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 235000010980 cellulose Nutrition 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000000969 carrier Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000282372 Panthera onca Species 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical group [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 244000303965 Cyamopsis psoralioides Species 0.000 description 1
- 229920004511 Dow Corning® 200 Fluid Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical group 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 238000000222 aromatherapy Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012669 compression test Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Chemical group 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- the present invention concerns a powder composition for use in laundry.
- the powder may be used to provide softening benefits.
- Silicones are known in the art to provide softening benefits for example WO 2006/005068 (The Procter & Gamble Company) discloses liquid laundry detergent compositions containing functionalised silicone materials as fabric care agents. WO 2015/078692 discloses that fabric softening silicones have been used to provide softness to fabrics from a laundry detergent composition.
- EP 1561803 discloses a need to improve the fabric-softening performance of a laundry detergent composition without unduly negatively affecting its fabric-cleaning performance.
- an auxiliary composition for use in the laundering or treatment of fabrics, comprising a co-particulate admix, the co-particulate ad-mix comprising: i) clay; and ii) a hydrophobic component that is a silicone; and iii) a cationic polymeric fabric-softening boosting component that is a cationic guar gum; ...
- co-particulate admix is obtained by a process comprising the steps of contracting the hydrophobic component with the clay and the charged polymeric fabric-softening boosting component to form a mixture, and then agglomerating the mixture in a high shear mixer and/or a low shear mixer to form a co-particulate admix.
- a powder composition for laundry comprising silicone, cationic polymer and carrier wherein the silicone composition and cationic polymer are loaded onto the carrier and the carrier is selected from sodium carbonate, sodium tripolyphosphate and mixtures thereof and wherein the ratio of silicone to cationic polymer is between 5:4 and 8:1 and the combined weight of silicone and cationic polymer is 15 to 35 w.t.% of the powder composition.
- the present invention relates to a powder composition.
- the powder composition may be used in a powder form or formed into a whole or part of a tablet or solid structure.
- the powder composition may be utilised as a laundry product on its own to provide softening benefits for example as an ancillary product.
- the powder composition may be integrated into another laundry product to provide an additional softening benefit e.g. added to a powdered laundry detergent, added to a unit dose capsule or incorporated into a tablet.
- the powder forms part of a unit dose capsule or tablet, preferably the powder is contained in a unit does capsule. More preferably the powder is contained in a unit dose capsule which further comprises a detergent composition. Preferably the detergent composition is in a separate compartment to the powder.
- the silicones suitable for the present invention are fabric softening silicones.
- Non-limiting examples of such silicones include: non-functionalised silicones such as polydimethylsiloxane (PDMS) or alkyl (or alkoxy) functional silicones, and functionalised silicones or copolymers with one or more different types of functional groups such as amino, phenyl, polyether, acrylate, siliconhydride, carboxy acid, quarternized nitrogen etc.
- the molecular weight of the softening silicone is preferably less than 150 000 g/mol, more preferably the molecular weight is less than 125 000 g/mol, most preferably the molecular weight is less than 105 00 g/mol.
- the molecular weight can be from 500 to 150 000 g/mol, more preferably the molecular weight 500 to 125 000 g/mol, most preferably the molecular weight is 500 to 105 00 g/mol.
- the viscosity of the silicone is preferably 500 to 11 000 cP as measured at 25°C using a TA Instruments Discovery HR-2 rheometer. Viscosity is determined at a range of shear rates between 0.1 s-1 and 10s-1 and the largest value taken as the viscosity.
- Preferred silicones are selected from polydialkylsiloxanes, anionic silicones and mixtures thereof.
- the silicones are selected from polydialkylsiloxanes, amino functionalised silicones, carboxyl functionalised silicone and mixtures thereof.
- Commercially available examples are Wacker SLM 441075, SFD209 (Ex Dow Corning) or X-22-3014E (ShinEtsu) DOW CORNING® 2-8566 AMINO FLUID and DOW CORNING® 200 FLUID.
- the silicone may be in the form of an emulsion or a fluid. It is preferably a silicone fluid.
- the cationic polymer may also be referred to as a deposition polymer, this aids the delivery of the silicone composition to the textile surface.
- the cationic polymer may be naturally derived or synthetic.
- suitable cationic polymers include: cationic guars, acrylate polymers, cationic starches, cationic amino resins, cationic urea resins, and cationic polysaccharides; preferably cationic celluloses.
- the cationic polymer is selected from; cationic guars, cationic cellulose, and cationic acrylate polymers.
- Cationic hydroxyethyl cellulose is a particularly preferred cationic cellulose.
- a particularly preferred class of cationic polymer is cationic celloluse ethers.
- ethers are commercially available under the tradename Ucare LR-400 (polyquaternium-10) or the Jaguar polymers such as Guar hydroxypropyl trimonium chloride, Jaguar C13 ex Rhodia.
- the molecular weight of the cationic polymer is preferably greater than 50 000 g/mol, more preferably greater than 100 000 g/mol.
- the molecular weight is preferably less than 5 000 000 g/mol.
- the carrier material for the silicone composition and cationic polymer is selected from sodium carbonate, sodium tripolyphosphate and mixtures thereof. These are inorganic sodium salts.
- Sodium carbonate may also be referred to as soda ash and is commercially available from Tata Chemicals Europe.
- a light grade of sodium carbonate is preferred.
- Sodium triphosphate is commercially available from Sigma-Aldrich.
- the carrier material is sodium carbonate.
- ingredients may be loaded onto the carrier material in addition to the silicone and cationic polymer. These may, for example be other laundry ingredients, benefit agents or materials providing an enhanced consumer experience.
- Some particularly preferred optional ingredients include:
- Free oil perfumes and fragrances may be added to the powder composition. These may be to scent the powder, to provide scent in the washing process or to provide scent to the textiles after the wash.
- the powders of the present invention may comprise one or more perfumes if desired.
- the perfume is preferably present in an amount from 0.01 to 10 % by weight, more preferably from 0.05 to 5 % by weight, even more preferably from 0.1 to 4.0 %, most preferably from 0.15 to 4.0 % by weight, based on the total weight of the composition.
- Useful components of the perfume include materials of both natural and synthetic origin. They include single compounds and mixtures. Specific examples of such components may be found in the current literature, e.g., in Fenaroli's Handbook of Flavor Ingredients, 1975, CRC Press ; Synthetic Food Adjuncts, 1947 by M. B. Jacobs, edited by Van Nostrand ; or Perfume and Flavor Chemicals by S. Arctander 1969, Montclair, N.J. (USA ). These substances are well known to the person skilled in the art of perfuming, flavouring, and/or aromatizing consumer products.
- Particularly preferred perfume ingredients are blooming perfume ingredients and substantive perfume ingredients. Blooming perfume ingredients are defined by a boiling point less than 250°C and a LogP ogreater than 2.5. Substantive perfume ingredients are defined by a boiling point greater than 250°C and a LogP greater than 2.5. Preferably a perfume composition will comprise a mixture of blooming and substantive perfume ingredients. The perfume composition may comprise other perfume ingredients.
- perfume components it is commonplace for a plurality of perfume components to be present in a formulation.
- compositions for use in the present invention it is envisaged that there will be three or more, preferably four or more, more preferably five or more, most preferably six or more different perfume components.
- An upper limit of 300 perfume ingredients may be applied.
- Colour may optionally be provided to the powder by the addition of one or more colorants.
- the colorant comprises one or more dyes and/or pigments.
- the pigment/dye may be any colour. These may be substantive or non-substantive dyes/pigments. A preferred level is one where the colour is discernible to the consumer and aesthetically pleasing.
- the powder may be a plurality of colours.
- the powder of the present invention may further comprise microcapsules encapsulating a benefit agent.
- Suitable encapsulating material may comprise, but are not limited to; aminoplasts, proteins, polyurethanes, polyacrylates, polymethacrylates, polysaccharides, polyamides, polyolefins, gums, silicones, lipids, modified cellulose, polyphosphate, polystyrene, polyesters or combinations thereof.
- Preferred benefit agents include perfumes, lubricants and any other oily materials. Particularly preferred benefit agents include, but are not limited to, the following:
- perfume components include both odiferous materials and pro-fragrance materials.
- perfume ingredients particularly preferred perfume ingredients are blooming perfume ingredients and substantive perfume ingredients. Blooming perfume ingredients are defined by a boiling point less than 250°C and a LogP ogreater than 2.5. Substantive perfume ingredients are defined by a boiling point greater than 250°C and a LogP greater than 2.5.
- a perfume composition will comprise a mixture of blooming and substantive perfume ingredients. The perfume composition may comprise other perfume ingredients.
- perfume components it is commonplace for a plurality of perfume components to be present in a formulation.
- compositions for use in the present invention it is envisaged that there will be three or more, preferably four or more, more preferably five or more, most preferably six or more different perfume components.
- An upper limit of 300 perfume ingredients may be applied.
- the powder composition of the present invention preferably comprises 60 to 85 w.t. % sodium carbonate, sodium tripolyphosphate or mixtures thereof, more preferably 65 to 85 w.t. %, most preferably 65 to 80 w.t. %.
- the powder composition of the present invention comprises a combined weight of silicone and cationic polymer 15 to 35 w.t. %.
- the ratio of silicone to cationic polymer is between 5:4 and 8:1, more preferably between 5:4 and 6:1 and most preferably between 5:3 and 5:1.
- a final laundry product comprising the powder of the present invention comprises 10 to 30 w.t. % silicone, more preferably, 15 to 25 w.t. % silicone.
- the silicone, cationic polymer and carrier comprise at least 90 w.t. % of the powder composition. More preferably the silicone, cationic polymer and carrier comprise at least 95 w.t. % of the powder composition.
- the powder of the present invention may in one embodiment be prepared by the following method:
- the other laundry product my for example be a powder laundry detergent, a laundry tablet, or a laundry unit dose capsule.
- the powder is used for softening benefits in other words as a softening booster for textiles.
- the powder may be incorporated into another laundry product or may be for use as a separate, stand-alone product which can be added during the wash process for a softening boost.
- the carrier material was added in to a Cutter C6 (ex. Sirman) mixer which was fitted with dough mix blades, and the mixer turned on.
- the carboxysilicone 1 and cationic polymer 2 where mixed separately and slowly dripped into the mixer while the mixer was running. Mixing was continued for a short period to ensure thorough mixing.
- the resulting powder was assessed visually. Dry powders which can flow more easily demonstrate higher loading capacity of the silicone, polymer mix. Damp and sticky powders demonstrate a lower loading capacity for the silicone, polymer mix.
- the powder was loaded into a cylinder and the surface levelled. A 10 kg consolidation weight was placed slowly on top of the powder and allowed to remain in position for 2 minutes. The weight was then removed and the cylinder removed carefully from the powder to leave a free-standing briquette of powder. If the briquette remained standing, a 200g weight was placed on the top of the briquette. If after 10 seconds the briquette was still standing, a 250g weight was placed on top of the briquette. If after 10 seconds the briquette was still standing, a 100g weight was added. 100g weights continued to be added until the briquette collapsed.
- the cohesiveness of a powder is classified by the weight (w.t.) as follows:
- the visual assessment of the sodium carbonate and sodium tripolyphosphate carriers compared to the bentonite clay demonstrate that the two sodium carriers can carry more silicone and cationic polymer mix than the bentonite, while maintaining the properties of a flowing powder. Flowing powders are necessary for the processing and use of laundry products.
- the UTC results demonstrate that the sodium carriers are have a good flow / have improved flow compared to the bentonite clay, which was cohesive and required significantly more weight to make the briquette collapse. If the carrier is a poor carrier and does not hold all of the silicone and cationic polymer mix, the powder sticks together and can support weights. However if the silicone and cationic polymer mix is carried well, the carrier is a free flowing powder which falls apart when weights are place on top.
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
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Claims (15)
- Pulverzusammensetzung für Wäsche, umfassend: Silicon, kationisches Polymer und Träger, wobei die Siliconzusammensetzung und das kationische Polymer auf den Träger geladen werden und der Träger unter Natriumcarbonat, Natriumtripolyphosphat und Mischungen davon ausgewählt ist und wobei das Verhältnis von Silicon zu kationischem Polymer zwischen 5:4 und 8:1 liegt und das kombinierte Gewicht von Silicon und kationischem Polymer 15 bis 35 Gew.-% der Pulverzusammensetzung beträgt.
- Pulver nach Anspruch 1, wobei das Silicon, das kationische Polymer und der Träger mindestens 90 Gew.-% der Pulverzusammensetzung umfassen.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Silicon unter Polydialkylsiloxanen, anionischen Siliconen und Mischungen davon ausgewählt ist.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Molekulargewicht des Silicons weniger als 150 000 g/mol beträgt.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das fertige Waschmittelprodukt, das das Pulver gemäß der vorliegenden Erfindung umfasst, 10 bis 30 Gew.-% Silicon umfasst.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Pulver 60 bis 85 Gew.-% Natriumcarbonat, Natriumtripolyphosphat oder Mischungen davon umfasst.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei der Träger Natriumcarbonat ist.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das kationische Polymer unter kationischen Guars, kationischer Cellulose und kationischen Acrylatpolymeren ausgewählt ist.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das kationische Polymer unter kationischen Guars und kationischen Cellulosepolymeren ausgewählt ist.
- Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch, wobei das Molekulargewicht des kationischen Polymers größer als 50 000 g/mol ist.
- Einheitsdosiskapsel, die die Pulverzusammensetzung nach irgendeinem vorhergehenden Anspruch enthält.
- Einheitsdosiskapsel nach Anspruch 11, die ferner eine Waschmittelzusammensetzung enthält.
- Einheitsdosiskapsel nach Anspruch 12, wobei die Waschmittelzusammensetzung zum Pulver in einer gesonderten Kammer einer Einheitsdosis vorliegt.
- Verfahren zur Herstellung der Pulverzusammensetzung nach irgendeinem der Ansprüche 1 bis 10, umfassend die Schritte:- Herstellen einer Vormischung von Silicon und kationischem Polymer- Zugeben der Vormischung zu dem Natriumcarbonat, Natriumtripolyphosphat und Mischungen davon- Mischen- optional Zugeben des Pulvers zu einem anderen Waschmittelprodukt.
- Verwendung der Pulverzusammensetzung nach irgendeinem der Ansprüche 1-10 zum Weichmachen von Textilien.
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EP16183543 | 2016-08-10 | ||
PCT/EP2017/067792 WO2018028927A1 (en) | 2016-08-10 | 2017-07-13 | Laundry composition |
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EP (1) | EP3497196B1 (de) |
CN (1) | CN109563443B (de) |
AR (1) | AR109308A1 (de) |
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ATE393204T1 (de) | 2004-02-03 | 2008-05-15 | Procter & Gamble | Zusammensetzung zum waschen oder behandeln von wäsche |
DE602004024955D1 (de) * | 2004-02-03 | 2010-02-25 | Procter & Gamble | Zusammensetzung zur Wäschereinigung oder -behandlung, und ein Herstellungsverfahren für die Zusammensetzung |
US20060003913A1 (en) | 2004-06-30 | 2006-01-05 | The Procter & Gamble Company | Perfumed liquid laundry detergent compositions with functionalized silicone fabric care agents |
GB0518059D0 (en) * | 2005-09-06 | 2005-10-12 | Dow Corning | Delivery system for releasing active ingredients |
WO2009156233A1 (en) * | 2008-06-25 | 2009-12-30 | Unilever Plc | Laundry treatment compositions |
EP2145944B1 (de) * | 2008-07-14 | 2014-03-26 | The Procter & Gamble Company | Partikel zur Vermittlung der stoffweichenden Abgabe auf damit behandelten Stoffen und zur Bereitstellung einer gewünschten Schaumunterdrückung |
WO2012075611A1 (en) * | 2010-12-10 | 2012-06-14 | The Procter & Gamble Company | Laundry detergents |
WO2015078692A1 (en) | 2013-11-27 | 2015-06-04 | Unilever Plc | Laundry compositions |
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AR109308A1 (es) | 2018-11-21 |
WO2018028927A1 (en) | 2018-02-15 |
EP3497196A1 (de) | 2019-06-19 |
CN109563443B (zh) | 2021-01-26 |
CN109563443A (zh) | 2019-04-02 |
ZA201900610B (en) | 2020-05-27 |
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