EP3472290A1 - Konzentrierte isotrope flüssigwaschmittel enthaltend polymere - Google Patents
Konzentrierte isotrope flüssigwaschmittel enthaltend polymereInfo
- Publication number
- EP3472290A1 EP3472290A1 EP17730138.9A EP17730138A EP3472290A1 EP 3472290 A1 EP3472290 A1 EP 3472290A1 EP 17730138 A EP17730138 A EP 17730138A EP 3472290 A1 EP3472290 A1 EP 3472290A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- surfactant
- total
- alkyl
- agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 83
- 239000007788 liquid Substances 0.000 title claims abstract description 44
- 229920000642 polymer Polymers 0.000 title claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 claims abstract description 86
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims abstract description 17
- 239000003112 inhibitor Substances 0.000 claims abstract description 16
- 239000004753 textile Substances 0.000 claims abstract description 16
- 239000002689 soil Substances 0.000 claims abstract description 10
- -1 alkyl ether sulfates Chemical class 0.000 claims description 83
- 239000000203 mixture Substances 0.000 claims description 64
- 102000004190 Enzymes Human genes 0.000 claims description 36
- 108090000790 Enzymes Proteins 0.000 claims description 36
- 239000002736 nonionic surfactant Substances 0.000 claims description 28
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 150000002191 fatty alcohols Chemical class 0.000 claims description 26
- 239000003945 anionic surfactant Substances 0.000 claims description 22
- 239000002280 amphoteric surfactant Substances 0.000 claims description 11
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 11
- 239000000975 dye Substances 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000003752 hydrotrope Substances 0.000 claims description 8
- 239000002304 perfume Substances 0.000 claims description 5
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- 239000007844 bleaching agent Substances 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- WUTZOLDBWJNAMI-WCXIOVBPSA-N (2r,3s,4r,5r)-n-dodecyl-2,3,4,5,6-pentahydroxyhexanamide Chemical compound CCCCCCCCCCCCNC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WUTZOLDBWJNAMI-WCXIOVBPSA-N 0.000 claims description 3
- NLEBIOOXCVAHBD-QKMCSOCLSA-N dodecyl beta-D-maltoside Chemical compound O[C@@H]1[C@@H](O)[C@H](OCCCCCCCCCCCC)O[C@H](CO)[C@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 NLEBIOOXCVAHBD-QKMCSOCLSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 239000002216 antistatic agent Substances 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- WOQQAWHSKSSAGF-WXFJLFHKSA-N decyl beta-D-maltopyranoside Chemical group O[C@@H]1[C@@H](O)[C@H](OCCCCCCCCCC)O[C@H](CO)[C@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 WOQQAWHSKSSAGF-WXFJLFHKSA-N 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 230000002070 germicidal effect Effects 0.000 claims description 2
- 238000010409 ironing Methods 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 239000005871 repellent Substances 0.000 claims description 2
- 230000002940 repellent Effects 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 239000012748 slip agent Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 230000008961 swelling Effects 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims 3
- KTMBZDQOFPBYBL-FVCCEPFGSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxy-n-octylhexanamide Chemical group CCCCCCCCNC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO KTMBZDQOFPBYBL-FVCCEPFGSA-N 0.000 claims 1
- REISOHCMNXKYLD-APIJFGDWSA-N (2r,3s,4r,5r)-n-decyl-2,3,4,5,6-pentahydroxyhexanamide Chemical group CCCCCCCCCCNC(=O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO REISOHCMNXKYLD-APIJFGDWSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 230000000845 anti-microbial effect Effects 0.000 claims 1
- 239000007850 fluorescent dye Substances 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 239000003002 pH adjusting agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 15
- 239000006185 dispersion Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 54
- 229940088598 enzyme Drugs 0.000 description 35
- 235000000346 sugar Nutrition 0.000 description 31
- 235000014113 dietary fatty acids Nutrition 0.000 description 29
- 229930195729 fatty acid Natural products 0.000 description 29
- 239000000194 fatty acid Substances 0.000 description 29
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 27
- 108090001060 Lipase Proteins 0.000 description 17
- 102000004882 Lipase Human genes 0.000 description 17
- 239000004367 Lipase Substances 0.000 description 17
- 150000004665 fatty acids Chemical class 0.000 description 17
- 235000019421 lipase Nutrition 0.000 description 17
- 239000002253 acid Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 14
- 108091005804 Peptidases Proteins 0.000 description 12
- 102000035195 Peptidases Human genes 0.000 description 12
- 150000007513 acids Chemical class 0.000 description 12
- 239000004365 Protease Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 10
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 10
- 239000008103 glucose Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- 108010084185 Cellulases Proteins 0.000 description 8
- 102000005575 Cellulases Human genes 0.000 description 8
- 108090000637 alpha-Amylases Proteins 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 150000008163 sugars Chemical class 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 108010056079 Subtilisins Proteins 0.000 description 7
- 102000005158 Subtilisins Human genes 0.000 description 7
- 102000004139 alpha-Amylases Human genes 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 229930182470 glycoside Natural products 0.000 description 7
- 150000002338 glycosides Chemical class 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 229940024171 alpha-amylase Drugs 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 6
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- 108010059892 Cellulase Proteins 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000001814 pectin Substances 0.000 description 5
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- 239000002904 solvent Substances 0.000 description 5
- 150000005846 sugar alcohols Chemical class 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
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- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
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- 125000002947 alkylene group Chemical group 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 238000011161 development Methods 0.000 description 4
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- 150000002148 esters Chemical class 0.000 description 4
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Definitions
- the present application is directed to highly concentrated isotropic liquid detergents with surfactant contents of 30% by weight and more, which additionally contain organic, non-surfactant constituents and have optimized product stability, which is made possible by a specially adapted surfactant system. Also included are processes for washing textiles using the detergents described and their use.
- Liquid detergents are known in the art and have become increasingly popular with consumers in recent years as they offer a number of advantages over solid detergents. These include, among other things, the simpler dosage, addition and dissolution in the wash liquor. In addition, they are perceived as safer and less aggressive to the textiles and the environment. Especially for the washing of colored textiles, they have gained more and more popularity since their market launch.
- polymeric ingredients are increasingly used in modern liquid detergents. Often these are essentially nonionic or anionic polymers of different functionality. Important groups are so-called soil release polymers, dye transfer inhibitors (DTIs), anti-redeposition agents and polymeric dispersants.
- DTIs dye transfer inhibitors
- a particular challenge is to ensure a stable formulation of the polymers, since the compatibility of the polymeric ingredients of a liquid formulation decreases with increasing surfactant concentration. As a result, cloudiness occurs, Sedimentation or phase separations on. These not only affect the aesthetic appearance of the recipe but also adversely affect the washing performance.
- the present invention therefore relates to an isotropic liquid detergent having a total surfactant concentration of at least 30% by weight based on the total weight of the composition, preferably in the range of 30 to 70% by weight, more preferably 35 to 60% by weight. comprising, based on the total weight of the composition,
- D at least 1% by weight of at least one polymeric compound P selected from soil release polymers (SRP), dye transfer inhibitors (DTI), anti redeposition agents and dispersants, in particular an SRP and optionally a DTI.
- SRP soil release polymers
- DTI dye transfer inhibitors
- anti redeposition agents and dispersants in particular an SRP and optionally a DTI.
- the present invention relates to the use of a liquid detergent according to the invention for washing textiles.
- the present invention relates to a process for the cleaning of textiles, characterized in that in at least one process step, a liquid detergent according to the invention is used.
- At least one refers to 1, 2, 3, 4, 5, 6, 7, 8, 9 or more In the context of components of the compositions described herein, this indication does not refer to the absolute amount
- at least one anionic surfactant therefore means, for example, one or more different anionic surfactants, ie one or more different types of anionic surfactants.
- Isotropic as used herein with respect to the agents described refers to optically isotropic agents, that is, agents that appear homogeneous and monophasic when viewed with the naked eye.
- the detergents described herein may be detergents for textiles or natural fibers.
- Detergents in the context of the invention also include washing aids which are metered into the actual detergent during manual or automatic textile washing in order to achieve a further effect or to enhance an effect.
- laundry detergents within the scope of the invention also include textile pre-treatment and post-treatment agents, ie those agents with which the laundry item is brought into contact before the actual laundry, for example for dissolving stubborn soiling, and also agents which are in a downstream of the actual textile laundry step give the laundry further desirable properties such as comfortable grip, crease resistance or low static charge.
- the fabric softeners are calculated. In preferred embodiments, however, it is a textile detergent.
- the liquid detergents have a total surfactant content of 30 to 70% by weight, preferably 35-60% by weight.
- Total surfactant content refers to the sum of all compounds used having surfactant properties, ie, in particular, the sum of the amounts of the surfactants A, N and N 1. Any soaps present are also considered as falling under the term “anionic surfactants” and taken into account in the total surfactant content.
- the water-soluble metal, ammonium or alkanolammonium salts especially the sodium or potassium salts, the saturated and unsaturated higher fatty acids, the resin acids of the rosin (yellow rosin soaps) and the naphthenic acids, which may be solid or unsaturated semisolid mixtures are mainly used for washing and cleaning purposes.
- liquid detergents described herein contain no further surfactants beyond the surfactant mixture, i. the total surfactant content corresponds to the amount of surfactant mixture.
- Particularly suitable anionic surfactants A are those of the sulfonate type, preferably alkylbenzenesulfonates, olefin sulfonates, i. Mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as obtained for example from monoolefins having 12 to 18 carbon atoms with terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation into consideration.
- alkanesulfonates having 12 to 18 carbon atoms and the esters of ⁇ -sulfo fatty acids (ester sulfonates), for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
- Alkylbenzenesulfonates are preferably selected from linear or branched alkylbenzenesulfonates of the formula
- a particularly preferred representative is sodium dodecylbenzylsulfonate.
- Alk (en) ylsulfates are the salts of the sulfuric acid half-esters of fatty alcohols containing 12 to 18 carbon atoms, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the oxo alcohols having 10 to 20 carbon atoms and those half-esters of secondary alcohols these chain lengths are preferred.
- the alkyl sulfates having 12 to 16 carbon atoms and alkyl sulfates having 12 to 15 carbon atoms and alkyl sulfates having 14 and 15 carbon atoms are preferred.
- Secondary alkanesulfonates are also particularly suitable.
- "Secondary” as used herein refers to the well-known chemical meaning of this term, and indicates that the carbon atom to which the sulfonate group is covalently bonded continues to have two covalent bonds to two organic (alkyl) radicals, i.e., carbon atoms, and having a covalent bond to a hydrogen atom Together with the carbon atom to which they are attached, the two organic (alkylic) radicals form a linear or branched alkyl of 1 to 50 carbon atoms.
- secondary alkanesulfonate is one of the formula R CH (SO 3 X + ) R 2 , wherein each of R and R 2 is independently a linear or branched alkyl of 1 to 20 carbon atoms and having the carbon atom to which they are attached , form a linear or branched alkyl, preferably with 10 to 30 carbon atoms, preferably with 1 0 to 20 carbon atoms and X + is selected from the group Na + , K + , NH 4 + , Vi Zn 2+ , / 2 Mg 2+ , / 2 Ca 2+ , / 2 Mn 2+ and mixtures thereof, preferably Na + .
- Particularly preferred are secondary alkanesulfonates of the formula
- X + is further selected from the group Na +, K +, NH 4 + 1/2 Zn 2+ 1/2 mg 2+, 1/2 Ca 2+, 1/2 Mn 2+, and mixtures thereof, preferably Na +.
- anionic surfactants are those of the sulfate type and in particular the alkyl ether sulfates.
- Preferred alkyl ether sulfates are those of the following formula wherein R 3 is a linear or branched alkyl having 5 to 30 carbon atoms, preferably having 7 to 25 carbon atoms, and preferably having 10 to 19 carbon atoms.
- AO in the above formula is an ethylene oxide (EO) or propylene oxide (PO) group, preferably an ethylene oxide (EO) group, and n is an integer of 1 to 50, preferably 1 to 20, and preferably of 2 to 10 is.
- X + is any cation and is preferably selected from the group Na + , K + , NH 4 + , Mg 2+ , Y 2 Ca 2+ 2 Mn 2 and mixtures thereof, more preferably Na + .
- R 3 is a linear or branched, substituted or unsubstituted alkyl radical.
- R 3 is a linear or branched, preferably unsubstituted, alkyl radical having from 5 to 30 carbon atoms, preferably from 7 to 25 carbon atoms and especially from 10 to 19 carbon atoms.
- Preferred radicals R 3 are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl and mixtures thereof, with the even number of carbon atoms being preferred.
- Particularly preferred radicals R 3 are derived from fatty alcohols having 12 to 18 carbon atoms, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or oxo alcohols having 10 to 19 carbon atoms.
- AO is an ethylene oxide (EO) or propylene oxide (PO) moiety, preferably an ethylene oxide moiety.
- the index m is an integer from 1 to 50, preferably 2 to 20 and preferably 2 to 10. In particular, m is 3, 4, 5, 6 or 7.
- the composition according to the invention can comprise mixtures of nonionic surfactants which have different degrees of ethoxylation.
- the stated degree of ethoxylation represents a statistical average that may be an integer or a fractional number for a particular product.
- the degrees of alkoxylation indicated represent statistical means which, for a particular product, may be an integer or a fractional number.
- Preferred alkoxylates / ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
- Further suitable anionic surfactants are, for example, the bisalkylsulfosuccinates.
- anionic surfactants are the alkylbenzenesulfonates and the alkyl ether sulfates, and especially the combinations of both. It goes without saying that in each case several different representatives of the respective surfactant class can be used. Soaps are considered in the context of this invention to be anionic surfactants, i. the indicated amounts of anionic surfactants include any soaps present.
- any cation may be included to balance the negative charge of the sulfonate group.
- the cation is selected from the group Na + , K + , NhV, Zn 2+ , V Mg 2+ , V Ca 2+ , V Mn 2+ and mixtures thereof, more preferably Na + .
- the anionic surfactants A are preferably present in the compositions according to the invention in amounts of at least 20% by weight, based on the total weight of the composition. Preferred amount range are 20 to 65, more preferably 20 to 55 wt .-%. Most preferred are concentrations in the range of 25 to 35 weight percent. The amounts given are based on the total amount of anionic surfactants contained in the composition.
- nonionic surfactants N and when N1 is a nonionic surfactant also N1 can be selected from:
- Alkyl ethers especially fatty alcohol alkoxylates, such as fatty alcohol ethoxylates
- alkylene oxide s
- propylene oxide / ethylene oxide fatty acid alkanolamides and fatty amines
- the nonionic surfactants may comprise at least one alkyl ether.
- the nonionic surfactant agents described herein contain at least one fatty alcohol alkoxylate having the formula below
- R 4 is -O- (AO) m -H, wherein R 4 is a linear or branched alkyl radical, AO is an ethylene oxide (EO) or propylene oxide (PO) moiety and m is an integer from 1 to 50.
- R 4 is a linear or branched, substituted or unsubstituted alkyl radical.
- R is a linear or branched, preferably unsubstituted, alkyl radical having from 5 to 30 carbon atoms, preferably from 7 to 25 carbon atoms and especially from 10 to 19 carbon atoms.
- Preferred radicals R are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl and mixtures thereof, with the even number of carbon atoms being preferred.
- Particularly preferred radicals R 4 are derived from fatty alcohols (fatty alcohol alkoxylates) having 12 to 19 carbon atoms, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or oxo alcohols having 10 to 19 carbon atoms.
- AO is an ethylene oxide (EO) or propylene oxide (PO) moiety, preferably an ethylene oxide moiety.
- the index m is an integer from 1 to 50, preferably 2 to 20 and preferably 2 to 10. In particular, m is 3, 4, 5, 6 or 7.
- the composition according to the invention can comprise mixtures of nonionic surfactants which have different degrees of ethoxylation.
- Suitable alkyl (poly) glycosides are in particular those of the formula R 5 O- [G] P in which R 5 is a linear or branched alkyl having 4 to 26, preferably 8 to 20, more preferably 8 to 18, 8 to 10 or From 12 to 16 carbon atoms, G is a sugar residue having 5 or 6 carbon atoms and p is a number from 1 to 100, preferably 1 to 10.
- G stands for residues of sugars with 5 (pentoses) or 6 (hexoses) carbon atoms, whereby the sugars can be Ketosen or Aldosen.
- Preferred monosaccharides include, but are not limited to, glucose, galactose, fructose, mannose, or ribose, especially glucose.
- G may also be sugar derivatives, in particular sugar alcohols, sugar acids, amino sugars (glycosamines) or thiosugars.
- Sugar alcohols result from the corresponding monosaccharide by reduction of the aldehyde or ketone function, for example, glucose yields sorbitol (glucitol) and mannose mannitol.
- Sugar acids result from the corresponding monosaccharide by oxidation of the aldehyde function (aldonic acids) or a terminal hydroxyl function (uronic acids) or both (aldar acids), for example, glucose gives rise to gluconic acid, glucuronic acid or glucaric acid.
- Amino sugars are obtained by replacing a hydroxyl function with an amino function.
- a preferred example is glucosamine.
- Thiosugars result from the replacement of a hydroxyl function by a thiol function.
- An example is thioglucose.
- sugars and sugar derivatives are described as such, they appear as sugar residues in the alkyl (poly) glycosides of the formula given above and the R 5 group replaces a hydrogen atom in the corresponding sugar or sugar derivative.
- the degree of oligomerization p can be from 1 to 100, preferably from 1 to 10, where each G can independently stand for a simple sugar. When p is 2 or more, then the various units G are preferably linked together via glycosidic linkages. It may be preferred that the R 5 group is attached to a terminal sugar moiety, but it may also be attached to a non-terminal sugar moiety in a corresponding oligomer.
- the sugar residue is a disaccharide residue.
- one G may be glucose and the second G fructose to form sucrose ( ⁇ -glucopyranosyl- (1 -2) - ⁇ -D-fructofuranoside). It is preferred, however, that all G in a molecule be the same simple sugar, such as glucose.
- Suitable disaccharides are, without limitation, maltose (aD- Glucopyranosyl- (1-> 4) -cr-D-glucopyranose), isomaltose fa-D-glucopyranosyl- (1-> 6) -a-D-glucopyranose) and lactose (/ 3-D-galactopyranosyl- (1-> 4) -D-glucopyranose).
- the sugar residue is a trisaccharide residue.
- suitable trisaccharides include, but are not limited to, raffinose, panose, and especially maltotriose.
- the sugar residue is a tetrasaccharide residue, particularly preferred is maltotetraose.
- the units are preferably glucose units, especially those linked 1, 4-glycosidically.
- single, multiple or all sugar units may be replaced by the corresponding sugar derivatives defined above.
- aminoglycosides and thioglycosides in which the bond to the next unit via the nitrogen or the sulfur atom, are used.
- alkyl (poly) glycosides are derived from glucose and can be described by the formula:
- n 7 to 15, in particular 7 to 9 or 1 to 15, and p represents numbers of 1 to 100, preferably 1 to 10.
- the degree of oligomerization p in the formulas given above is preferably ⁇ 8, more preferably ⁇ 6, even more preferably ⁇ 4 and in particular ⁇ 2.
- Particularly preferred surfactants are those in which p is from 1.4 to 1.8.
- surfactants include, without limitation:
- Detergents according to the invention may contain, for example, Ce-IE, in particular Ce-io or Ci2-16-alkyl oligo (1, 4) glucoside.
- Suitable alkyl (poly) glycosides are available, for example, under the trade names Plantacare® or Plantaren® from BASF (BASF SE, DE) and include, among others, Plantacare® 220 UP (APG 220 UP) and Plantaren® 1200 UP NP (APG 600 UP) ,
- Sugar fatty acid esters may be compounds of the formula R 5 C (O) 0- [G] P where R 5 p and G may be as defined above for the alkyl polyglycosides. However, R 5 preferably contains 7 to 19, more preferably 7 to 17, 7 to 9 or 1 1 to 15 carbon atoms.
- R 5 preferably contains 7 to 19, more preferably 7 to 17, 7 to 9 or 1 1 to 15 carbon atoms.
- An example of such compounds is sucrose cocoate (INCI: sucrose-cocoate), ie the ester of sucrose with coconut oil-derived fatty acids.
- sorbitol esters which result from the use of the corresponding sugar alcohols instead of the sugars.
- examples of these are sorbitol esters. These may also satisfy the above-mentioned formula R 5 C (0) 0- [G] P , but G is a corresponding polyol, in particular a sugar alcohol.
- sorbitan fatty acid esters ie esters of 1, 4 sorbitan with 1-4, preferably 1 or 3 esterified fatty acid residues, in particular C12-18 fatty acids, especially those selected from laurate, palmitate, stearate and oleate. These may also be alkoxylated, in particular, ethoxylated, such as the polysorbates.
- fatty acid N-alkyl polyhydroxyamides in particular fatty acid N-alkylglucamides, ie amides of fatty acids with the sugars derived from sugars.
- fatty acid N-alkylglucamides ie amides of fatty acids with the sugars derived from sugars.
- such compounds are obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid ester or a fatty acid chloride.
- R 6 is a linear or branched, saturated or unsaturated alkyl group having 7 to 21 carbon atoms
- Z is a polyhydroxyhydrocarbyl group having at least three hydroxyl or alkoxy groups
- R 7 is C 1 -C 8 -Alkyl, a group of the formula - (CH 2 ) xNR 8 R 9 or R 0 O (CH 2 ) n -, where R 8 and R 9 is C 1 -C 4 -alkyl or C 2 -C 4 -hydroxyalkyl, R 0 is Ci C4 alkyl, n is a number from 2 to 4 and x is a number from 2 to 10.
- R 6 is C 7 -C 17 -alkyl, preferably linear and saturated
- R 7 is methyl
- Z is a residue of the formula -CH 2 - (CHOH) - (CHOH) - (CHOH) -CHOH) which is derived from glucose.
- CH20H is.
- Ci2-Ci 8 acyl-N-methylglucamide such as Ci2-acyl-N-methylglucamide.
- N-alkylglyconamides in particular N-alkylgluconamides, ie amides of alkylamines with the sugars derived from sugars.
- Exemplary compounds satisfy the formula R 6 NR 7 C (O) Z, wherein R 6 , R 7 and Z are as defined above, wherein R 7 can also be H and not Z alone, but the group C (O) Z may be in its entirety a radical derived from a sugar, such as glucose, such as -C (O) - (CHOH) - (CHOH) - (CHOH) -CHOH) - CH2OH ,
- suitable compounds are N-Cs-Os-alkyl-D-gluconamides, such as N-octyl, N-decyl and N-dodecyl-D-gluconamides and the corresponding N, N-dialkyl-D-gluconamides, in particular N-Cs-cis-alkyl-N-methyl-D-glucon
- fatty acid amidoalkoxylates of the formula R -CON (R 2 ) (R 13 ), where R is an alkyl group or alkenyl group having 7 to 21 carbon atoms, R 2 is hydrogen or a group - (AO) x H, R 3 is a group - (AO ) xH, A is a group of the formulas -C2H4-, -C3H6- or -C4H8- and x is a number from 1 to 20.
- alkoxylated fatty acid alkyl esters are suitable, especially those of the formula R 4 CO- (OCH 2 CHR 5 ) wOR 16 , in the R 4 CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R 5 is hydrogen or methyl and R 6 is linear or branched alkyl radicals having 1 to 4 carbon atoms and w is 1 to 20.
- hydroxy mixed ethers especially those of the formula
- R 7 is -O- (CH 2 -CH (R 8 ) -O) w- (CH 2 -CH (R 9 ) -O) x- (CH 2 -CH (R 20 ) -O) y - (CH 2 -CH ( R 2 ) -O) zR 22 where
- R 7 is H or, preferably, a linear or branched hydrocarbon radical having 2 to 26 carbon atoms
- each of R 8 , R 9 , R 20 and R 2 is independently selected from -H, -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 CH 3 , -CH (CH 3 ) 2, preferably -H or -CH 3 ;
- R 22 is selected from -CH 2 CH (OH) R 23 ;
- R 23 is a straight-chain or branched, saturated or mono- or polyunsaturated C 2-6 -alkyl or alkenyl radical
- w, x, y and z are values between 1 and 120, where x, y and / or z can also be 0.
- R 7 is a linear or branched hydrocarbon radical having from 2 to 26 carbon atoms
- R 8 is H
- R 22 is -CH 2 CH (OH) R 23
- surfactants examples include the C4-22 fatty alcohol (EO) io-8o-2-hydroxyalkyl ethers, in particular the C8-12 fatty alcohol (EO) 22-2-hydroxydecyl ethers and the C4-22 fatty alcohol (EO) 4-ol 8o-2-hydroxyalkyl ethers.
- surfactants are the C2-26 fatty alcohol (PO) i (EO) is-4o-2-hydroxyalkyl ethers, in particular the coco fatty alcohol (PO) i (EO) 22-2-hydroxydecyl ethers.
- R 8 can also be H and R 9 is -CH 3 , -CH 2 CH 3 , -CH 2 CH 2 -CH 3 , or -CH (CH 3) 2, but preferably -CH 3 .
- amine oxides can be used as alternative (zwitterionic / amphoteric) surfactants N1, for example.
- amine oxide in principle all amine oxides established for this purpose in the prior art are compounds which have the formula RR 2 R 3 NO, wherein each R, R 2 and R 3 independently of the others is an optionally substituted hydrocarbon chain having 1 to 30 carbon atoms , usable.
- Particularly preferred amine oxides are those wherein R is alkyl of 12 to 18 carbon atoms and R 2 and R 3 are each independently alkyl of 1 to 4 carbon atoms, especially alkyl dimethylamine oxides of 12 to 18 carbon atoms.
- Suitable amine oxides are N-cocoalkyl-N, N-dimethylamine oxide, N-tallowalkyl- ⁇ , ⁇ -dihydroxyethylamine oxide, myristyl / cetyldimethylamine oxide or lauryldimethylamine oxide.
- Betaines are preferably compounds of the formula (R iii ) (R iv ) (R v ) N + CH 2 COO " in which R i is an alkyl radical optionally interrupted by hetero atoms or heteroatom groups having 8 to 25, preferably 10 to 21 carbon atoms and R iv and R v are identical or different alkyl radicals having 1 to 3 carbon atoms, in particular compounds of the formula
- R 24 is -C (O) -NH- (CH 2 ) 3 -N + (CH 3 ) 2 -CH 2 -COO- wherein R 24 is a linear or branched hydrocarbon radical having 2 to 26, preferably 5 to 21 carbon atoms, preferably one straight-chain or branched, saturated or mono- or polyunsaturated C2-26-alkyl or alkenyl radical, preferably having 5 to 21 carbon atoms. Examples are C 10 -C 18 -alkyl-dimethylcarboxymethyl betaine and C 1 -C 7 -alkylamidopropyl-dimethylcarboxymethyl betaine.
- Sultaines are, for example, compounds of the formula
- R 24 is -C (O) -NH- (CH 2 ) 3 -N + (CH 3 ) 2 -CH 2 -CH (OH) -CH 2 -SO 3 wherein R 24 is as defined above.
- the nonionic surfactants N have an HLB value of ⁇ 12, in certain embodiments also ⁇ 1 1, ⁇ 10, ⁇ 9, ⁇ 8 or ⁇ 7.
- the HLB value is a measure of the balance between hydrophilic and hydrophobic moieties in a surfactant and is herein designated Griffin, in particular for all nonionic surfactants, unless otherwise specified (Griffin, WC: “Classification of surface active agents by HLB", J. Soc , 1949).
- the HLB value of each individual nonionic surfactant N is less than or equal to 12. Examples of such surfactants are low ethoxylated alkyl ethers, such as C12-18 alkyl ethers with ⁇ 7 EO.
- the agent contains at least one surfactant N1, which may also be a nonionic, but also an amphoteric or zwitterionic surfactant. Suitable nonionic, zwitterionic and amphoteric surfactants are described above.
- the additional surfactant N1, if it is a nonionic surfactant, has an HLB value> 12.
- the at least one surfactant N1 may also be a mixture of several surfactants. In such embodiments, each surfactant N1 has an HLB value of> 12.
- the difference between the HLB values of surfactant (s) N1 and surfactant (s) determined by the Griffin method is preferably at least 1, more preferably 2 or more, even more preferably 3 or more.
- the HLB value may also be measured by the increment method of Davies (JT Davies, A quantitative kinetic theory of emulsion type, I. Physical Chemistry of the Emulsifying Agent, Vol Proceedings of Second International Congress Surface Activity, 1957, p.426), and is then preferably> 5, more preferably> 6,> 7,> 8,> 9 or> 10. Again, however, the HLB value of Davies surfactant N1 must be greater than the HLB value of Davies surfactant (s).
- the HLB value of this surfactant is preferably> 5, preferably> 6,> 7,> 8,> 9 or> 10 and that according to the method of Davies HLB value of the surfactant / surfactants N by the Griffin method is ⁇ 12.
- the total concentration of surfactants N and N 1 (sum of N and N 1) is at least 7% by weight, preferably from 7 to 50% by weight, more preferably from 7-25% by weight, most preferably from 10 to 25% by weight. % based on the total weight of the agent.
- the weight ratio of the surfactants N1 and N (N1: N) ⁇ 1 and the concentration of the surfactant N1 at least 2 wt .-% based on the total weight of the composition.
- the concentration of the surfactant N1 is 2-15% by weight, preferably 2-10% by weight, more preferably 2 to 8% by weight, most preferably 2 to 6% by weight.
- the amount of the surfactant N is preferably 5 to 20% by weight, preferably 5 to 15% by weight.
- the ratio of the total amount of N + N1 to total amount of anionic surfactants A is preferably 5: 1 to 1: 5, in particular 2: 1 to 1: 5, at a total surfactant content of 30% by weight, with a total surfactant content of 35% by weight.
- % preferably 5: 2 to 1: 6, in particular 4: 3 to 1: 6, with a total surfactant content of 40 wt.%, preferably 5: 3 to 1: 7, in particular 1: 1 to 1: 3, with a total surfactant content of 45% by weight, preferably 5: 4 to 1: 8, in particular 4: 5 to 2: 7, at a total surfactant content of 50% by weight, preferably 1: 1 to 1: 9, in particular 2: 3 to 1: 4 a total surfactant content of 55% by weight, preferably 5: 6 to 1:10, in particular 4: 7 to 2: 9, at a total surfactant content of 60% by weight, preferably 5: 7 to 1: 1 1, in particular 1: 2 to 1: 5, at a total surfactant content of 65 wt .-%, preferably 5: 8 to 1: 12, in particular 4: 9 to 2: 1 1, and at a total surfactant content of 70 wt .-%, preferably 5: 9 to 1: 13 , in particular 2: 5 to 1
- surfactants N in particular fatty alcohol alkoxylates, such as those described above, are used, in particular those having up to 7 EO, preferably 2-5 EO.
- Nonionic surfactants used in particular as surfactants N1 are, for example, alkyl polyglycosides, in particular n-decyl or n-dodecyl-.beta.-D maltoside, n-octyl, 2-ethylhexyl, n-decyl or n-dodecyl-.beta.-D Glucoside, n-octyl, 2-ethylhexyl, n-decyl or n-dodecyl-aD-glucoside, or in general Cs-16, in particular Ce-io or Ci2-i6-alkyl-oligo (1, 4) -glucosides as well as the above-described N-alkylgluconamides, in particular N-octyl, N-decyl and N-dodecyl-D-gluconamides and the corresponding N, N-dialkyl-D-glu
- compositions of the invention comprise as surfactant N alkyl ethers, in particular the fatty alcohol alkoxylates described above, and as surfactant N1 the alkyl polyglycosides or N-alkylgluconamides described above, in particular in weight ratios of 1: 1 to 5: 1, preferably 1: 1 to 3 :1.
- the amount of alkyl ether / fatty alcohol alkoxylate for example, 5 to 15 wt .-%, preferably 6 to 10 wt .-%, and / or the amount of alkyl (poly) glycoside, for example, 2 to 8 wt .-%, preferably 3 to 5 %
- the amount of alkyl ether / fatty alcohol alkoxylate for example, 5 to 15 wt .-%, preferably 6 to 10 wt .-%
- the amount of alkyl (poly) glycoside for example, 2 to 8 wt .-%, preferably 3 to 5 %
- the liquid detergent contains no other nonionic surfactants other than these two types of nonionic surfactants.
- the detergent may contain other nonionic surfactants, provided that the total content of nonionic surfactants in which the agent preferably does not exceed 20% by weight.
- the residual content of surfactants is preferably determined by anionic surfactants.
- the compositions do not contain any cationic surfactants and preferably also no amphoteric or zwitterionic surfactants.
- the surfactants described above are used in conventional amounts, the amount being selected so that the total surfactant content of the inventive compositions, as described above,> 30 wt .-%, for example 30 to 70 wt .-%, preferably 35-60 wt. -% is. In various embodiments, the total surfactant content is up to 45% by weight, while preferred amounts of surfactant may range from 32 to 38% by weight.
- the agents contain at least one anionic, preferably at least two anionic surfactants A and at least two nonionic surfactants N and N1, as defined above.
- the anionic surfactants are preferably alkylbenzenesulfonates, as described above, which are usually present in amounts of from 10 to 25% by weight, preferably from 12 to 20% by weight, particularly preferably from 14 to 18% by weight, in the compositions . Additionally or alternatively, the agents may also contain alkyl ether sulfates, usually in amounts of 2 to 10 wt .-%, in particular 3 to 8 wt .-%.
- nonionic surfactants are included in amounts of at least 7, preferably 7 to 25 percent by weight.
- Preferred amounts of surfactants N and N1 have been defined above.
- the detergent may contain at least one fatty acid soap. These are particularly advantageous for the cold washing performance.
- Preferred detergents are therefore characterized in that they contain, based on their weight, from 0.1 to 15% by weight, preferably from 0.2 to 12.5% by weight, more preferably from 0.5 to 3% by weight, of soap (n) included.
- soap (n) included Particularly preferred are soaps of fatty acids having 12 to 18 carbon atoms.
- the fatty acid soaps may be in the form of their sodium, potassium or magnesium or ammonium salts. Preferably, they are in the form of their sodium salts and / or ammonium salts.
- the polymeric compound P is present in an amount of at least 1% by weight, preferably 2% or more by weight, preferably 10% by weight, more preferably 5% by weight, based on the total weight of the agent this included.
- Compound P is a polymeric component selected from soil release polymers (SRPs), anti-redeposition agents, color transfer inhibitors (DTIs), polymeric dispersants, and combinations of the foregoing.
- oligoesters are obtainable as SRPs from preferably terephthalic acid, isophthalic acid, sulfoisophthalic acid and / or methyl esters thereof, aliphatic dicarboxylic acids (saturated and / or unsaturated), for example adipic acid, and / or their anhydrides, aliphatic substituted dicarboxylic acids, for example nonylsuccinic acid, alkylene glycols (ethylene, 1, 2-propylene, 1, 2-butylene glycol), polyethylene glycols, alkyl polyethylene glycols, Polyethylenglykolbenzoeklareester, Polyethylenglykolsulfobenzoeklareester and optionally alkanolamines used.
- SRPs terephthalic acid, isophthalic acid, sulfoisophthalic acid and / or methyl esters thereof, aliphatic dicarboxylic acids (saturated and / or unsaturated
- polymers based on terephthalate PEG as are commercially available, for example, under the trade name Texcare®.
- polymers based on polyethyleneimine, polyvinyl acetate and polyethylene glycol can also be used.
- Suitable soil release polymers are generally already well known in the art. In particular, therefore, all known in the art for this purpose polymers can be used.
- the composition of the invention may contain a dye transfer inhibitor.
- the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as vinylpyrrolidone and / or vinylimidazole.
- Suitable polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride and mixtures thereof.
- Particular preference is given to using polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) or copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) as color transfer inhibitor.
- polycarboxylates Particularly suitable as anti-redeposition agents are polycarboxylates.
- Suitable materials can be prepared by the polymerization or copolymerization of unsaturated carboxylic acid monomers such as acrylic acid, maleic acid (or anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid and methylmalonic acid.
- unsaturated carboxylic acid monomers such as acrylic acid, maleic acid (or anhydride), fumaric acid, itaconic acid, aconitic acid, mesaconic acid, citraconic acid and methylmalonic acid.
- acrylate polymers and acrylic / maleic copolymers Particularly preferred are acrylate polymers and acrylic / maleic copolymers.
- Suitable SRPs, anti-redeposition agents and DTIs are also disclosed, for example, in International Patent Publication WO 2009/153184 A1 on pages 25-39 Headings "dye tranfer inhibitors", “anti redeposition agents” and “soil release polymers” The disclosure of this document with respect to said polymers is incorporated herein by reference in its entirety.
- the polymers contained in the agents comprise at least one SRP and optionally at least one DTI.
- the liquid detergents described herein further preferably contain at least one enzyme.
- the at least one enzyme may be any enzyme known in the art capable of exhibiting catalytic activity in a detergent or cleaning agent, and includes but is not limited to, for example, proteases, amylases, lipases, cellulases, hemicellulases, mannanases, pectin cleaving enzymes, tannases, xylanases, xanthanases, ⁇ -glucosidases, carrageenases, perhydrolases, oxidases, oxidoreductases and mixtures thereof.
- the at least one enzyme is selected from the group consisting of proteases, amylases, lipases, cellulases and mixtures thereof. These enzymes are, in principle, of natural origin, but starting from the natural molecules, improved variants are available for use in detergents or cleaners, which are preferably used accordingly.
- subtilisin type those of the subtilisin type are preferable.
- these are the subtilisins BPN 'and Carlsberg, the protease PB92, the subtilisins 147 and 309, the alkaline protease from Bacillus lentus, subtilisin DY and the enzymes thermitase, proteinase K and the subtilases, but not the subtilisins in the narrower sense Proteases TW3 and TW7.
- Subtilisin Carlsberg is available in a further developed form under the trade name Alcalase® from Novozymes A / S, Bagsvaerd, Denmark.
- subtilisins 147 and 309 are sold under the trade names Esperase®, and Savinase® by the company Novozymes. From the protease from Bacillus lentus DSM 5483 derived under the name BLAP® protease variants derived.
- proteases are, for example, those under the trade names Durazym®, Relase®, Everlase®, Nafizym®, Natalase®, Kannase® and Ovozyme® from Novozymes, which are available under the trade names, Purafect®, Purafect® OxP, Purafect® Prime, Excellase® and Properase® from Genencor, sold under the trade name Protoso D by Advanced Biochemicals Ltd., Thane, India, under the trade name Wuxi® by Wuxi Snyder Bioproducts Ltd., China, under the trade names Proleather ® and Protease P® from Amano Pharmaceuticals Ltd., Nagoya, Japan, and the enzyme available under the name Proteinase K-16 from Kao Corp., Tokyo, Japan.
- proteases from Bacillus gibsonii and Bacillus pumilus are also given to using the proteases from Bacillus gibsonii and Bacillus pumilus.
- amylases are the ⁇ -amylases from Bacillus licheniformis, from ⁇ . amyloliquefaciens or from ß. stearothermophilus and their improved for use in detergents or cleaners further developments.
- the enzyme from ß. licheniformis is available from Novozymes under the name Termamyl® and from Genencor under the name Purasta DST.
- this ⁇ -amylase is available from Novozymes under the trade name Duramyl® and Termamy Dultra, from Genencor under the name Purastar®OxAm and from Daiwa Seiko Inc., Tokyo, Japan, as Keistase®.
- the ⁇ -amylase of ⁇ . amyloliquefaciens is marketed by the company Novozymes under the name BAN®, and derived variants of the ⁇ -amylase from ⁇ . stearothermophilus under the names BSG® and Novamyl®, also from Novozymes.
- the ⁇ -amylase from Bacillus sp.
- a 7-7 (DSM 12368) and cyclodextrin glucanotransferase (CGTase) from ⁇ . agaradherens (DSM 9948).
- fusion products of all the molecules mentioned can be used.
- the further developments of the ⁇ -amylase from Aspergillus niger and A. oryzae available under the trade name Fungamyl® from the company Novozymes are suitable.
- Further advantageously usable commercial products are, for example, the amylase-LT® and Stainzyme® or Stainzyme ultra® or Stainzyme plus®, the latter also from the company Novozymes.
- variants of these enzymes obtainable by point mutations can be used according to the invention.
- lipases or cutinases which are contained in particular because of their triglyceride-cleaving activities, but also to generate in situ peracids from suitable precursors, are the lipases which are originally obtainable from Humicola lanuginosa (Thermomyces lanuginosus) or further developed, in particular those with the amino acid exchange D96L. They are sold for example by the company Novozymes under the trade names Lipolase®, Lipolase®Ultra, LipoPrime®, Lipozyme® and Lipex®.
- the cutinases can be used, which have been originally isolated from Fusarium solani pisi and Humicola insolens.
- Lipases which are likewise useful are sold by Amano under the names Lipase CE®, Lipase P®, Lipase B® or Lipase CES®, Lipase AKG®, Bacillus sp. Lipase®, Lipase AP®, Lipase M-AP® and Lipase AML®.
- Lipases or cutinases can be used, the initial enzymes were originally isolated from Pseudomonas mendocina and Fusarium solanii.
- Lipase® and Lipomax® are prepareds M 1 Lipase® and Lipomax®, which were originally sold by Gist-Brocades, and those sold by Meito Sangyo KK, Japan, under the name Lipase MY-30®, Lipase OF® and Lipase PL® To mention enzymes, also the product Lumafast® from Genencor.
- cellulases may be pure enzymes, enzyme preparations or in the form of Mixtures in which the individual components advantageously complement each other in terms of their various performance aspects, be present.
- These performance aspects include in particular the contributions of the cellulase to the primary washing performance of the composition (cleaning performance), to the secondary washing performance of the composition (anti-redeposition effect or graying inhibition), to softening (tissue effect) or to the exercise of a "stone-washed" effect.
- cleaning performance cleaning performance
- anti-redeposition effect or graying inhibition anti-redeposition effect or graying inhibition
- tissue effect tissue effect
- a useful fungal, endoglucanase (EC ) -rich cellulase preparation or its further developments is offered by the company Novozymes under the trade name Celluzyme®
- the products Endolase® and Carezyme® likewise available from the company Novozymes are based on the 50 kD-EG or the 43 kD-EG H.
- insolens DSM 1800 Other commercially available products of this company are Cellusoft®, Renozyme® and Celluclean.RTM .. Also usable are, for example, the 20 kD-EG from Melanocarpus, those from AB Enzymes, Finland, under the trade names Ecostone® and Biotouch® Other commercial products of AB Enzymes are Econa se® and Ecopulp®. Other suitable cellulases are from Bacillus sp. CBS 670.93 and CBS 669.93, those derived from Bacillus sp. CBS 670.93 from the company Genencor under the trade name Puradax® is available. Further commercial products of Genencor are "Genencor detergent cellulase L" and lndiAge®Neutra.
- variants of these enzymes obtainable by point mutations can be used according to the invention.
- Particularly preferred cellulases are Thielavia terrestris cellulase variants, cellulases from melanocarpus, in particular melanocarpus albomyces, cellulases of the EGIII type from Trichoderma reesei or variants obtainable therefrom.
- hemicellulases include, for example, mannanases, xanthan lyases, xanthanases, xyloglucanases, xylanases, pullulanases, pectin-splitting enzymes and ⁇ -glucanases.
- the ⁇ -glucanase obtained from Bacillus subtilis is available under the name Cereflo® from Novozymes.
- Hemicellulases which are particularly preferred according to the invention are mannanases which are sold, for example, under the trade names Mannaway® by the company Novozymes or Purabrite® by the company Genencor.
- pectin-destroying enzymes in the context of the present invention are also counted enzymes with the designations pectinase, pectate lyase, pectin esterase, pectin methoxylase, pectin methoxylase, pectin methyl esterase, pectase, pectin methyl esterase, pectin esterase, pectin-pectin hydrolase, pectin-polymerase, endopolygalacturonase, pectolase, pectin hydrolase, pectin-polygalacturonase, Endo-polygalacturonase, poly-a-1, 4-galacturonide glycanohydrolase, endogalacturonase, endo-D-galacturonase, galacturan 1, 4-a-galacturonidase, exopolygalacturonase, poly (galacturonate) hydrolase, exo-
- suitable enzymes in this regard are, for example, under the names Gamanase®, Pektinex AR®, X-Pect® or Pectaway® from the company Novozymes, under the name Rohapect UF®, Rohapect TPL®, Rohapect PTE100®, Rohapect MPE®, Rohapect MA plus HC, Rohapect DA12L®, Rohapect 10L®, Rohapect B1 L® of the Company AB Enzymes and available under the name Pyrolase® from Diversa Corp., San Diego, CA, USA.
- oxidoreductases for example oxidases, oxygenases, catalases (which react as peroxidase at low H 2 O 2 concentrations), peroxidases, such as halo, chloro, bromo, lignin, glucose, can also be present in the detergents, in particular liquid detergents or manganese peroxidases, dioxygenases or laccases (phenol oxidases, polyphenol oxidases).
- Suitable commercial products are Denilite® 1 and 2 from Novozymes.
- the liquid detergents contain the at least one enzyme in amounts established in the prior art.
- the at least one enzyme in a total amount of 1 x 10 ⁇ 8 to 5 wt .-% based on active protein or in a total amount of 0.001 to 3 wt .-%, or 0.01 to 1, 5 wt. % or 0.05 to 1, 25 wt .-% contained.
- the amounts given are to be understood so that any enzyme contained can be contained in the stated amounts.
- the enzymes are preferably used as enzyme liquid formulation (s).
- the at least one enzyme present in a detergent or cleanser aids the cleaning performance of the agent on certain soils or stains.
- an agent according to the invention contains a plurality of enzymes, wherein the enzymes may belong to the same or different enzyme classes. Most preferably, the enzymes exhibit synergistic effects in their action against certain soils or stains, i.
- the enzymes contained in the composition support each other in their cleaning performance.
- the detergent may contain other ingredients that further improve the performance and / or aesthetic properties of the detergent.
- the detergent preferably additionally contains one or more substances from the group of builders / complexing agents, bleaching agents, electrolytes, perfumes, perfume carriers, fluorescers, dyes, hydrotropes, foam inhibitors, silicone oils, grayness inhibitors, anti-shrinkage agents, anti-crease agents, antimicrobial agents, germicides , Fungicides, Antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing auxiliaries, repellents and impregnating agents, swelling and anti-slip agents, softening components, pH adjusters and UV absorbers.
- a bleaching agent can serve all substances that destroy or absorb dyes by oxidation, reduction or adsorption and thereby discolor materials. These include, among others, hypohalite-containing bleach, hydrogen peroxide, perborate, percarbonate, peroxoacetic acid, diperoxoazelaic acid, diperoxododecanedioic acid, and oxidative enzyme systems.
- hypohalite-containing bleach hydrogen peroxide, perborate, percarbonate, peroxoacetic acid, diperoxoazelaic acid, diperoxododecanedioic acid, and oxidative enzyme systems.
- liquid detergents are typically free of non-enzymatic bleaches.
- Suitable builders which may be present in the detergent are, in particular, silicates, aluminum silicates (in particular zeolites), carbonates, phosphonates, organic di- and polycarboxylic acids or salts thereof and mixtures of these substances.
- Organic builders which may be present in the detergent are, for example, the polycarboxylic acids which can be used in the form of their sodium salts, polycarboxylic acids meaning those carboxylic acids which carry more than one acid function.
- these are citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, and mixtures of these.
- Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof.
- suitable and preferred are aminocarboxylic acids, in particular glutamic diacetic acid (GLDA) and methylglycine diacetic acid (MGDA).
- polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example, those having a molecular weight of 600 to 750,000 g / mol.
- Suitable polymers are in particular polyacrylates, which preferably have a molecular weight of from 1,000 to 15,000 g / mol. Because of their superior solubility, the short-chain polyacrylates, which have molecular weights of from 1,000 to 10,000 g / mol, and particularly preferably from 1,000 to 5,000 g / mol, may again be preferred from this group.
- copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid.
- copolymeric polycarboxylates which contain allyl sulfonic acids, such as allyloxybenzenesulfonic acid and methallylsulfonic acid, as a monomer.
- allyl sulfonic acids such as allyloxybenzenesulfonic acid and methallylsulfonic acid
- such sulfopolymers are particularly preferred.
- liquid detergents preference is given to using soluble builders, such as, for example, citric acid, or acrylic polymers having a molar mass of from 1,000 to 5,000 g / mol.
- soluble builders such as, for example, citric acid, or acrylic polymers having a molar mass of from 1,000 to 5,000 g / mol.
- citrate particularly preferred is citrate.
- the water-soluble organic builders described above may in various embodiments in amounts of 1 to 25 wt .-%, preferably 1, 5 to 20 wt .-%, more preferably 2 to 15 wt .-%, most preferably 2.5 to 10 wt .-%, based on the total weight of the agent.
- citrate is used in amounts of 2.5 to 5 wt .-%.
- the detergents may additionally contain phosphonates, such as HEDP (1-hydroxyethane-1, 1-diphosphonic acid) or DTPMP (diethylene triamine penta (methylene phosphonate) as builders and complexing agents.)
- phosphonates such as HEDP (1-hydroxyethane-1, 1-diphosphonic acid) or DTPMP (diethylene triamine penta (methylene phosphonate) as builders and complexing agents.
- the phosphonates are preferred in various embodiments in amounts up to 10% by weight to 5 wt .-%, particularly preferably 0.5 to 4 wt .-%, based on the total weight of the composition used.
- Preferred liquid detergents preferably contain water as the main solvent. It is preferred that the detergent more than 5 wt .-%, preferably more than 15 wt .-% and particularly preferably more than 25 wt .-%, each based on the total amount of detergent, water. Particularly preferred liquid detergents contain - based on their weight - 5 to 65 wt .-%, preferably 10 to 60 wt .-%, particularly preferably 25 to 55 wt .-% and in particular 30 to 50 wt .-% water.
- the liquid detergents may be low-water or water-free detergents, with water-based liquid detergents containing less than 20% by weight, preferably less than 15% by weight, more preferably less than 10% by weight and water most preferably less than 8% by weight, based in each case on the total liquid detergent.
- Anhydrous compositions contain less than 5% by weight, preferably less than 3% by weight, more preferably less than 2%, most preferably less than 1% by weight of water, based on the total weight of the composition.
- nonaqueous solvents may be added to the detergent.
- Suitable non-aqueous solvents include mono- or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range.
- the solvents are preferably selected from ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycol, propyldiglycol, butyldiglycol, hexyleneglycol, ethylene glycol methyl ether, ethylene glycol ethyl ether,
- Ethylene glycol propyl ether ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, Diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether,
- Propylene glycol propyl ether dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether, di-n-octyl ether and mixtures of these solvents. Particular preference is given to 1,2-propanediol and glycerol.
- the detergent may contain such an alcohol, in particular 1,2-propanediol and / or glycerol, very particularly preferably 1,2-propanediol, in amounts of between 0.5 and 15% by weight, based on the total detergent contains.
- hydrotropes may be used in addition to the surfactant systems described herein.
- the term "hydrotrope" as used in the context of the present invention refers to additives or solvents which cause the water solubility of poorly soluble (hydrophobic) organic compounds to increase, whereby a second component (ie the hydrotrope) is added to the sparingly soluble substance
- hydrotropes have hydrophilic and hydrophobic structural units (such as surfactants) but without the tendency to form aggregates in water (as opposed to surfactants) .
- these hydrotropes have no micelle-forming activity or are critical Micelle Formulation Concentration (CMC) is greater than 10 -4 mol / L, preferably greater than 10 -3 mol / L, and more preferably 10 -2 mol / L.
- the "critical micelle concentration” is in line with the general understanding in the art Concentration of the corresponding substance over which this begins Mizel and any other molecule added to the system is converted into the micelles.
- the hydrotropes employed typically have a molecular weight ⁇ 10,000 g / mol, preferably ⁇ 2,500 g / mol, more preferably ⁇ 1,000 g / mol, and most preferably ⁇ 500 g / mol.
- They may be selected, for example, from short chain mono-, di-, tri-, tetra- or penta-alkylbenzenesulfonates, especially C1-6 alkylbenzenesulfonates wherein the alkyl groups may be linear or branched, including but not limited to cumene sulfonate, toluenesulfonate and / or xylenesulfonate and butyl glycol, propylene glycol, 3-methoxy-3-methyl-1-butanol, 2,2-dimethyl-4-hydroxymethyl-1,2-dioxolane, propylene carbonate, butyl lactate, 2-isobutyl-2-methyl-1,3-dioxolane -4-methanol or mixtures thereof.
- the hydrotropic compounds are preferably used in a range of 0, 1 to 5 wt .-%, more preferably from 1 to 2 wt .-%, based on the total weight of the detergent.
- the detergents described herein in particular the described low-water to anhydrous liquid detergents, can be filled into a water-soluble casing and thus be part of a water-soluble packaging. If the detergent is packaged in a water-soluble wrapper, it is preferred that the level of water be less than 20% Wt .-%, preferably less than 15 or 10 wt .-% based on the total detergent.
- a water-soluble packaging contains, in addition to the detergent, a water-soluble coating.
- the water-soluble coating is preferably formed by a water-soluble film material.
- Such water soluble packages can be made by either vertical fill seal (VFFS) or thermoforming methods.
- VFFS vertical fill seal
- the thermoforming process generally includes forming a first layer of water-soluble sheet material to form protrusions for receiving a composition therein, filling the composition into the protrusions, covering the composition-filled protrusions with a second layer of water-soluble sheet material, and sealing the first and second layers at least around the bulges.
- the water-soluble coating is preferably formed from a water-soluble film material selected from the group consisting of polymers or polymer blends.
- the wrapper may be formed of one or two or more layers of the water-soluble film material.
- the water-soluble film material of the first layer and the further layers, if present, may be the same or different.
- the water-soluble package comprising the detergent and the water-soluble wrapper may have one or more chambers.
- the liquid detergent may be contained in one or more chambers, if any, of the water-soluble coating.
- the amount of liquid detergent preferably corresponds to the full or half dose needed for a wash.
- the water-soluble coating contains polyvinyl alcohol or a polyvinyl alcohol copolymer.
- Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 g / mol, preferably 20,000 to 500,000 g / mol, more preferably 30,000 to 100,000 g / mol and especially from 40,000 to 80,000 g / mol.
- a suitable for the preparation of the water-soluble envelope sheet material may additionally polymers selected from the group comprising acrylic acid-containing polymers, polyacrylamides, Oxazoline polymers, polystyrenesulfonates, polyurethanes, polyesters, polyethers, polylactic acid, and / or mixtures of the above polymers.
- Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
- Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.
- polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
- Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
- Suitable water-soluble films for use in the casings of the water-soluble packaging according to the invention are films sold by the company MonoSol LLC, for example under the designation M8630, C8400 or M8900.
- Other suitable films include films named Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.
- the water-soluble packages may have a substantially dimensionally stable spherical and pillow-shaped configuration with a circular, elliptical, square or rectangular basic shape.
- the water soluble package may include one or more chambers for storing one or more agents. If the water-soluble packaging has two or more chambers, at least one chamber contains a liquid detergent. The other chambers may each contain a solid or a liquid detergent.
- Another object of the invention is a process for the cleaning of textiles, which is characterized in that in at least one process step, an inventive composition is used and the use of a liquid detergent according to the invention for washing textiles.
- Methods for cleaning textiles are generally distinguished by the fact that various cleaning-active substances are applied to the items to be cleaned and washed off after the contact time, or that the items to be cleaned are otherwise treated with a detergent or a solution or dilution of this product. All conceivable washing methods can be used in at least one of Process steps are enriched by the use of a detergent according to the invention and then constitute embodiments of the present invention. All facts, objects and embodiments described for means according to the invention are also applicable to this subject of the invention. Therefore, reference is made at this point expressly to the disclosure in the appropriate place with the statement that this disclosure also applies to the above inventive methods and uses.
- Glucopon 215 CSUP C8-10 alkyl (poly) glucoside; DP 1, 5; active substance 62-65% by weight
- Glucopon 600 CSUP C12-14 alkyl (poly) glucoside; DP 1, 4; active substance 50-53% by weight
- the formulations E1 and E2 according to the invention were stable after 12 weeks of storage at room temperature.
- Reference recipe V2 serves as a reference and contains neither polymer (SRP) nor glucopone.
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Abstract
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DE102016210743.7A DE102016210743A1 (de) | 2016-06-16 | 2016-06-16 | Konzentrierte Flüssigwaschmittel enthaltend Polymere |
DE102017209213.0A DE102017209213A1 (de) | 2017-05-31 | 2017-05-31 | Konzentrierte isotrope Flüssigwaschmittel enthaltend Polymere |
PCT/EP2017/064518 WO2017216216A1 (de) | 2016-06-16 | 2017-06-14 | Konzentrierte isotrope flüssigwaschmittel enthaltend polymere |
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CA1049367A (en) * | 1974-06-25 | 1979-02-27 | The Procter And Gamble Company | Liquid detergent compositions having soil release properties |
DE10153183A1 (de) * | 2001-10-27 | 2003-05-15 | Henkel Kgaa | Betainesterhaltige Mittel |
DE102005015328A1 (de) * | 2005-04-01 | 2006-10-05 | Henkel Kgaa | Klares Wasch- und Reinigungsmittel mit Fließgrenze |
US20080015135A1 (en) | 2006-05-05 | 2008-01-17 | De Buzzaccarini Francesco | Compact fluid laundry detergent composition |
CA2728378A1 (en) | 2008-06-16 | 2009-12-23 | Unilever Plc | A method of laundering fabrics using a pourable liquid detergent composition with a minority of soap |
EP2295531B1 (de) | 2009-09-14 | 2017-02-22 | The Procter & Gamble Company | Flüssigwaschmittelzusammensetzung |
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ES2564700T3 (es) * | 2011-12-20 | 2016-03-28 | Unilever N.V. | Detergente de lavado de ropa líquido acuoso isotrópico, que comprende secuestrante |
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