EP3458265B1 - Device for the surface treatment of a substrate having a metallic conveyor belt - Google Patents
Device for the surface treatment of a substrate having a metallic conveyor belt Download PDFInfo
- Publication number
- EP3458265B1 EP3458265B1 EP17716837.4A EP17716837A EP3458265B1 EP 3458265 B1 EP3458265 B1 EP 3458265B1 EP 17716837 A EP17716837 A EP 17716837A EP 3458265 B1 EP3458265 B1 EP 3458265B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- conveyor belt
- corona
- range
- substrate
- belt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000758 substrate Substances 0.000 title claims description 59
- 238000004381 surface treatment Methods 0.000 title claims description 6
- 239000011248 coating agent Substances 0.000 claims description 25
- 238000000576 coating method Methods 0.000 claims description 25
- 238000004049 embossing Methods 0.000 claims description 18
- 238000007639 printing Methods 0.000 claims description 18
- 238000007789 sealing Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 7
- 239000010935 stainless steel Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims 1
- 230000032258 transport Effects 0.000 description 36
- 239000010410 layer Substances 0.000 description 35
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 230000005684 electric field Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920002379 silicone rubber Polymers 0.000 description 4
- 239000004945 silicone rubber Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002346 layers by function Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/04—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
- B05D3/0493—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases using vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/14—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by electrical means
- B05D3/141—Plasma treatment
- B05D3/142—Pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F16/00—Transfer printing apparatus
- B41F16/0006—Transfer printing apparatus for printing from an inked or preprinted foil or band
- B41F16/002—Presses of the rotary type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F16/00—Transfer printing apparatus
- B41F16/0006—Transfer printing apparatus for printing from an inked or preprinted foil or band
- B41F16/002—Presses of the rotary type
- B41F16/0026—Presses of the rotary type with means for applying print under heat and pressure, e.g. using heat activable adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F19/00—Apparatus or machines for carrying out printing operations combined with other operations
- B41F19/02—Apparatus or machines for carrying out printing operations combined with other operations with embossing
- B41F19/06—Printing and embossing between a negative and a positive forme after inking and wiping the negative forme; Printing from an ink band treated with colour or "gold"
- B41F19/062—Presses of the rotary type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41F—PRINTING MACHINES OR PRESSES
- B41F23/00—Devices for treating the surfaces of sheets, webs, or other articles in connection with printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H20/00—Advancing webs
- B65H20/10—Advancing webs by a feed band against which web is held by fluid pressure, e.g. suction or air blast
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H5/00—Feeding articles separated from piles; Feeding articles to machines
- B65H5/02—Feeding articles separated from piles; Feeding articles to machines by belts or chains, e.g. between belts or chains
- B65H5/021—Feeding articles separated from piles; Feeding articles to machines by belts or chains, e.g. between belts or chains by belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H5/00—Feeding articles separated from piles; Feeding articles to machines
- B65H5/22—Feeding articles separated from piles; Feeding articles to machines by air-blast or suction device
- B65H5/222—Feeding articles separated from piles; Feeding articles to machines by air-blast or suction device by suction devices
- B65H5/224—Feeding articles separated from piles; Feeding articles to machines by air-blast or suction device by suction devices by suction belts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T19/00—Devices providing for corona discharge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2252/00—Sheets
- B05D2252/02—Sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2301/00—Handling processes for sheets or webs
- B65H2301/50—Auxiliary process performed during handling process
- B65H2301/51—Modifying a characteristic of handled material
- B65H2301/511—Processing surface of handled material upon transport or guiding thereof, e.g. cleaning
- B65H2301/5111—Printing; Marking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2404/00—Parts for transporting or guiding the handled material
- B65H2404/20—Belts
- B65H2404/26—Particular arrangement of belt, or belts
- B65H2404/264—Arrangement of side-by-side belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2404/00—Parts for transporting or guiding the handled material
- B65H2404/20—Belts
- B65H2404/27—Belts material used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2404/00—Parts for transporting or guiding the handled material
- B65H2404/20—Belts
- B65H2404/28—Other properties of belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2406/00—Means using fluid
- B65H2406/30—Suction means
- B65H2406/32—Suction belts
Definitions
- the invention relates to a device for the surface treatment of a substrate according to the preamble of the subject matter of claim 1.
- Devices for the surface treatment of a substrate are used, for example, to print the surfaces of sheet-like or web-shaped substrates or to coat them with a transfer layer of an embossing foil.
- the object of the present invention is to provide an improved device for the surface treatment of a substrate.
- a device for the surface treatment of a substrate comprising a transport device, a vacuum suction device, a corona device and a coating device, is proposed, it being provided that the transport device has a transport belt, that the transport belt is designed as a vacuum suction belt of the vacuum suction device, and that the transport belt as a counter electrode of the Corona device is formed.
- a sealing element with a circumferential sealing lip is arranged between the side of the conveyor belt facing away from the substrate and a suction head of the vacuum suction device, the suction head being arranged under the corona device.
- the device according to the invention has the advantage that the transport device has a transport belt that fulfills three functions, namely transporting the substrate, fixing the substrate in position by vacuum suction on the transport belt and providing an electrode for the corona device.
- the conveyor belt can in particular fulfill these three functions at the same time, so that a very advantageous synergy arises between these functions.
- the conveyor belt is mounted on two deflecting rollers which are spaced apart from one another, one of the deflecting rollers being designed as a drive roller.
- the conveyor belt can be designed as a revolving belt, which revolves in particular around the two deflecting rollers.
- the conveyor belt is mounted on a support device in the area of the coating device and / or the corona device.
- a support device in the area of the coating device and / or the corona device.
- Several support devices can be provided, which are arranged, for example, in the area of the coating device and the corona device.
- the support device can have a support roller or a plurality of support rollers which are arranged next to one another in the longitudinal extension of the conveyor belt.
- the support rollers can in particular rotate at the same speed as the conveyor belt on top of it moves, so that the lowest possible friction arises between the support rollers and the conveyor belt. This means that the support rollers have the same speed around their circumference as the conveyor belt on top.
- the conveyor belt can have a thickness in the range from 0.2 mm to 1 mm, preferably in the range from 0.3 mm to 0.5 mm.
- the conveyor belt is made of a material which has a degree of hardness in the range from 450 HV10 to 520 HV10, preferably in the range from 465 HV10 to 500 HV10.
- the conveyor belt is designed and / or supported in such a way that its maximum deflection under operational load is in the range from 1 ⁇ m to 10 ⁇ m.
- the surface of the conveyor belt facing the substrate is polished, i.e. has a roughness depth of less than 0.3 ⁇ m.
- the conveyor belt is made of stainless steel.
- the conveyor belt is made from copper or aluminum or titanium or from an alloy containing copper and / or aluminum and / or titanium, in particular from an alloy containing aluminum and / or titanium.
- the conveyor belt can be designed as a seamless belt.
- a seamless conveyor belt without joints offers the same conditions over its entire surface with regard to its property as a mechanical counter-bearing for the substrate.
- the conveyor belt can have several partial conveyor belts which are arranged adjacent to one another in the direction of transport, preferably with the smallest possible spacing between the partial conveyor belts.
- These partial conveyor belts can have the same or different properties, in particular with regard to material and / or hardness and / or thickness and / or flexural strength. The properties described above for the conveyor belt also apply to the partial conveyor belts.
- a first partial conveyor belt can be arranged in the area of the coating device and a second partial conveyor belt in the area of the corona device.
- a support element is arranged between adjacent partial conveyor belts which bridges the space between the adjacent partial conveyor belts without a gap.
- the conveyor belt is designed as a link belt made of plate-shaped links, with adjacent links being connected to one another by a swivel joint in such a way that they form a gap-free support surface in the extended state.
- the conveyor belt has transport recesses on the edge, and that the deflection rollers have corresponding toothed rims which engage in the transport recesses.
- the conveyor belt has through holes, in particular a multiplicity of through holes.
- the through holes can be designed as in particular circular bores and / or in particular elliptical elongated holes and / or slots and / or rhombuses.
- the through holes are arranged in a grid.
- the grid can be regular or irregular or random.
- the grid is designed differently in areas.
- the through holes can have a diameter in the range from 0.2 mm to 5 mm, preferably in a range from 0.3 mm to 2 mm, or have an area corresponding to a circular hole of the aforementioned diameter, in particular if the through hole is not circular.
- the corona device has a housing which is open on its underside and in the lower end section of which an electrode is arranged.
- the electrode can, for example, be designed as an air-cooled ceramic electrode, have a cross section of 16 mm ⁇ 16 mm and a length that corresponds to the width of the conveyor belt.
- the corona device can be arranged with its longitudinal extent transverse to the transport direction of the conveyor belt and above the substrate.
- the electrode of the corona device forms the cathode and the conveyor belt as a counter electrode forms the anode of the corona device, a corona gap being formed between the cathode and the anode.
- the corona gap can, for example, be in the range from 1 mm to 2 mm.
- a high electrical voltage is applied to the electrode and the counter electrode, which is generated by a high-frequency generator with a frequency range of 10 kHz to 60 kHz and a field strength of 20 kV / cm to 30 kV / cm in the air gap.
- Field ionization forms ions that are accelerated in the electric field and adhere to the surface of the substrate.
- the polar portion of the surface tension of the substrate can be increased.
- the surface of the substrate is electrically charged and the surface energy of the substrate is increased.
- the surface tension of the substrate should be about 10 mN / m to 15 mN / m higher than the surface tension of the liquid.
- the surface tension of an ink can be between 20 mN / m to 25 mN / m and the surface tension of a film-shaped substrate to be printed can be between 30 mN / m to 35 mN / m.
- the surface tension of the substrate can be increased to approx. 40 mN / m to 45 mN / m, whereby this substrate can be printed.
- the coating device has an embossing device for transferring a onto a carrier layer Has transfer film, in particular a hot stamping film or cold stamping film arranged transfer layer on the substrate.
- An embossing roller of the embossing device can have a coating of an elastomer with a thickness in the range from 3 mm to 10 mm, preferably in the range from 5 mm to 10 mm, on its outer circumference.
- the elastomer is preferably silicone rubber.
- the silicone rubber preferably has a hardness in the range from 60 ° Shore A to 95 ° Shore A, preferably in the range from 70 ° Shore A to 90 ° Shore A.
- a support roller arranged in the area of the embossing device forms a counter-pressure roller for the embossing roller.
- the coating device can preferably be arranged downstream behind the corona device.
- the substrate can be coated by means of the corona device after the surface of the substrate has been treated.
- processing stations such as sorting stations, punching stations, blind embossing stations, folding stations or other processing stations for processing the substrate downstream of the corona device and preferably downstream of the at least one coating device.
- the transfer film has a transfer layer arranged on a carrier layer.
- the carrier layer can be made of PET or of polypropylene, polystyrene, PVC, PMMA, ABS, polyamide, for example.
- the hot stamping foil is arranged in such a way that the transfer layer faces the top side of the substrate to be stamped.
- the transfer layer can be coated with a heat-activated adhesive layer or be self-adhesive (cold adhesive).
- a separating layer which facilitates detachment of the transfer layer from the carrier layer, can be arranged between the transfer layer and the carrier layer.
- the transfer layer of the transfer film generally has several layers, in particular a release layer (for example made of wax or wax-containing compounds), a protective lacquer layer, a heat-activated adhesive layer.
- Decorative layers are, for example, colored (opaque or transparent or translucent) lacquer layers, metal layers or relief structures (haptically or optically refractive or optically diffractive).
- the substrate is preferably a flexible substrate, for example paper with a basis weight of 30 g / m 2 to 350 g / m 2 , preferably 80 g / m 2 to 350 g / m 2 or cardboard or plastic or a hybrid material made of several paper and Plastic layers or a laminate of several paper and / or plastic layers.
- Fig. 1 shows a device 1 for the surface coating of a substrate 2, comprising a transport device 3, a vacuum suction device 4, a corona device 5 and a coating device 6.
- the transport device 3 is designed as a revolving conveyor belt 31 which is mounted on two deflecting rollers 32 spaced apart from one another, one of the deflecting rollers 32 being designed as a drive roller 32a.
- the conveyor belt 31 is in the in Fig. 1
- the embodiment shown is designed as a seamless band made of stainless steel.
- the conveyor belt 31 revolves in a transport direction 31t.
- the substrate 2 is arranged in a transport section of the transport belt 31 on the transport belt 31 and is fixed on the transport belt 31 by negative pressure.
- the substrate 2 is moved in a transport direction 2t corresponding to the transport direction 31t of the transport belt 31, which corresponds to the transport direction 31 in the transport section.
- the support device 7 arranged below the corona device 5 is in the in Fig. 1
- the illustrated embodiment is formed from four support rollers 71 which are arranged next to one another in the longitudinal extension of the conveyor belt 31.
- the support rollers 71 can in particular rotate at the same speed as the overlying conveyor belt 31 moves, so that the lowest possible friction arises between the support rollers 71 and the conveyor belt 31. That is to say, the support rollers 71 have the same speed on their circumference as the conveyor belt 31 on top.
- the four support rollers 71 are mounted in a rigid or adjustable manner so that they can rotate.
- the support device 7 arranged below the coating device 6 has a support roller 71, the axis of rotation of which is likewise oriented transversely to the transport direction 31t of the transport belt 31.
- the maximum deflection of the conveyor belt 31 under operational load is in the range from 1 ⁇ m to 10 ⁇ m. With such a slight deflection, the conveyor belt can serve particularly advantageously as a mechanical counter-bearing for the substrate.
- the conveyor belt 31 has a thickness in the range from 0.2 mm to 1 mm, preferably in the range from 0.3 mm to 0.5 mm.
- the conveyor belt 31 is made of a material which has a degree of hardness in the range from 450 HV10 to 520 HV10, preferably in the range from 465 HV10 to 500 HV10.
- the conveyor belt 31 can be formed from a steel alloy, preferably from stainless steel. It can also be provided that the conveyor belt is made of copper, aluminum or titanium.
- the surface of the conveyor belt facing the substrate 2 is polished, i.e. it has a roughness depth of less than 0.3 ⁇ m.
- the conveyor belt 31 is designed as a vacuum suction belt 31v with through holes 31d (see Figures 4 to 8 ), by means of which a negative pressure can be formed on the upper side of the conveyor belt 31 which fixes the substrate 2 on the conveyor belt 31.
- the negative pressure is in the range from 10,000 Pascal to 100,000 Pascal (0.1 bar to 1 bar).
- the through holes 31 can be designed as in particular circular bores and / or in particular elliptical elongated holes and / or slots and / or rhombuses.
- a section of the conveyor belt 31 arranged above the sealing element 42 is connected to a suction head 41 of the vacuum suction device 4 in a gas-tight or approximately gas-tight manner.
- the sealing element 42 is designed as a circumferential sealing lip.
- a suction head 41 is provided according to the invention, wherein the
- Suction head 41 is arranged under the corona device 5.
- the vacuum suction device 4 is designed with a vacuum pump 43, the inlet of which is connected to the suction head 41.
- Fig. 4 and 8th show a first embodiment of the vacuum suction belt 31v.
- Through holes 31 d designed as bores with a circular cross section are arranged in a grid.
- the through holes 31d can have a diameter in the range from 0.2 mm to 5 mm, preferably in have a range of 0.3 mm to 2 mm or have a surface area corresponding to a circular hole of the aforementioned diameter.
- the through holes 31 d have a diameter of 1 mm.
- Fig. 5 shows a second embodiment in which the through holes 31d are designed as diamond-shaped elongated holes which are arranged in a grid.
- Fig. 6 shows a third embodiment, in which the through holes 31 are formed in areas with a different contour. In a central area, the through holes 31d are formed in a diamond shape. In the two edge regions, the through holes 31 are formed with a circular cross section. The grid is also designed differently in areas.
- Fig. 6 Fig. 13 shows a fourth embodiment in which the through holes 31d are randomly arranged.
- the grid can be formed regularly or irregularly or randomly.
- the corona device 5 has a housing 51 which is open on the underside and in which an electrode 52 is arranged.
- the electrode 52 is designed as an air-cooled ceramic electrode and is arranged above the substrate 2.
- the conveyor belt 31 forms a counter electrode 31e, which is in particular grounded.
- the illustrated embodiment has the electrode 52 a cross section of 16 mm x 16 mm and a length that corresponds to the width of the conveyor belt 31 (here: 350 mm).
- the corona device 5 can be arranged with its longitudinal extension transverse to the transport direction 31t of the transport belt 31.
- the electrode 52 is connected as a cathode.
- the counter electrode 31e is connected as an anode.
- the corona gap 5l is adjustable, in particular adjustable in height, and in FIG Fig. 1 illustrated embodiment 1 mm to 2 mm.
- the smallest possible corona gap 51 can be set, for example depending on the thickness and / or the material of the substrate 2, in order to be able to adapt the electric field surrounding and / or penetrating the substrate 2.
- a high electrical voltage is applied to the electrode 52 and the counter-electrode 31e, which is generated by a high-frequency generator 54 with a frequency range of 10 kHz to 60 kHz and forms a field strength of 20 kV / cm to 30 kV / cm in the air gap 5l. Ions are formed by field ionization, which are accelerated in the electric field and adhere to the surface of the substrate 2.
- the corona device 5 has a suction device 53 connected to the housing 51 in a gas-tight manner for suctioning off ozone.
- the ionization of the air in the air gap 5l creates ozone, which has to be sucked off or destroyed.
- the ozone-containing exhaust air is led through an exhaust hose and discharged outside of the production room.
- the ozone-containing exhaust air can be passed through an ozone destroyer, for example an activated carbon filter, before being discharged into the environment. In this way 99.5% of the ozone can be destroyed.
- the exhaust air hose can, for example, have a length of 12 to 15 m. A delivery rate of 4.9 m 3 / min has proven itself.
- the suction device 53 simultaneously forms a cooling device for the electrode 52.
- An embossing roller 67 of the embossing device 65 has on its outer circumference a coating made of an elastomer with a thickness in the range from 3 mm to 10 mm, preferably in the range from 5 mm to 10 mm.
- the elastomer is preferably silicone rubber. In the in Fig. 1 shown In the exemplary embodiment, the silicone rubber has a hardness of 80 ° Shore A.
- the support roller 71 arranged in the area of the embossing device 65 forms a counter-pressure roller for the embossing roller 67.
- the device 1 shown is like that in Fig. 2
- the device shown is designed, with the difference that the coating device 6 is designed as a printing device 61, comprising a printing roller 62 and an ink application device 63.
- Other printing devices can also be provided, for example a printing device based on the screen printing principle and / or based on the inkjet principle.
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Description
Die Erfindung betrifft eine Vorrichtung zur Oberflächenbehandlung eines Substrats nach dem Oberbegriff des Gegenstands des Anspruchs 1.The invention relates to a device for the surface treatment of a substrate according to the preamble of the subject matter of claim 1.
Vorrichtungen zur Oberflächenbehandlung eines Substrats werden beispielsweise eingesetzt, um die Oberflächen bogen- oder bahnförmiger Substrate zu bedrucken oder mit einer Übertragungsschicht einer Prägefolie zu beschichten.Devices for the surface treatment of a substrate are used, for example, to print the surfaces of sheet-like or web-shaped substrates or to coat them with a transfer layer of an embossing foil.
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Aufgabe der vorliegenden Erfindung ist es, eine verbesserte Vorrichtung zur Oberflächenbehandlung eines Substrats anzugeben.The object of the present invention is to provide an improved device for the surface treatment of a substrate.
Erfindungsgemäß wird diese Aufgabe mit dem Gegenstand des Anspruchs 1 gelöst. Es wird eine Vorrichtung zur Oberflächenbehandlung eines Substrats, aufweisend eine Transporteinrichtung, eine Vakuumansaugeinrichtung, eine Koronaeinrichtung und eine Beschichtungseinrichtung, vorgeschlagen, wobei vorgesehen ist, dass die Transporteinrichtung ein Transportband aufweist, dass das Transportband als ein Vakuumsaugband der Vakuumansaugeinrichtung ausgebildet ist, und dass das Transportband als eine Gegenelektrode der Koronaeinrichtung ausgebildet ist. Dabei ist zwischen der dem Substrat abgewandten Seite des Transportbandes und einem Ansaugkopf der Vakuumansaugeinrichtung ein Dichtelement mit einer umlaufenden Dichtlippe angeordnet, wobei der Ansaugkopf unter der Koronaeinrichtung angeordnet ist.According to the invention, this object is achieved with the subject matter of claim 1. A device for the surface treatment of a substrate, comprising a transport device, a vacuum suction device, a corona device and a coating device, is proposed, it being provided that the transport device has a transport belt, that the transport belt is designed as a vacuum suction belt of the vacuum suction device, and that the transport belt as a counter electrode of the Corona device is formed. A sealing element with a circumferential sealing lip is arranged between the side of the conveyor belt facing away from the substrate and a suction head of the vacuum suction device, the suction head being arranged under the corona device.
Die erfindungsgemäße Vorrichtung weist den Vorteil auf, dass die Transporteinrichtung ein Transportband aufweist, das drei Funktionen erfüllt, nämlich den Transport des Substrats, die Lagefixierung des Substrats durch Vakuumansaugung auf dem Transportband und die Bereitstellung einer Elektrode für die Koronaeinrichtung. Diese drei Funktionen kann das Transportband insbesondere gleichzeitig erfüllen, sodass eine sehr vorteilhafte Synergie zwischen diesen Funktionen entsteht.The device according to the invention has the advantage that the transport device has a transport belt that fulfills three functions, namely transporting the substrate, fixing the substrate in position by vacuum suction on the transport belt and providing an electrode for the corona device. The conveyor belt can in particular fulfill these three functions at the same time, so that a very advantageous synergy arises between these functions.
Es kann vorgesehen sein, dass das Transportband auf zwei voneinander beabstandeten Umlenkwalzen gelagert ist, wobei eine der Umlenkwalzen als eine Antriebswalze ausgebildet ist.It can be provided that the conveyor belt is mounted on two deflecting rollers which are spaced apart from one another, one of the deflecting rollers being designed as a drive roller.
Das Transportband kann als ein umlaufendes Band ausgebildet sein, welches insbesondere um die beiden Umlenkwalzen umläuft.The conveyor belt can be designed as a revolving belt, which revolves in particular around the two deflecting rollers.
Weiter kann vorgesehen sein, dass das Transportband im Bereich der Beschichtungseinrichtung und/oder der Koronaeinrichtung auf einer Auflageeinrichtung gelagert ist. Es können mehrere Auflageeinrichtungen vorgesehen sein, die beispielsweise im Bereich der Beschichtungseinrichtung und der Koronaeinrichtung angeordnet sind.It can further be provided that the conveyor belt is mounted on a support device in the area of the coating device and / or the corona device. Several support devices can be provided, which are arranged, for example, in the area of the coating device and the corona device.
Die Auflageeinrichtung kann eine Auflagewalze oder mehrere Auflagewalzen, die in Längserstreckung des Transportbandes nebeneinander angeordnet sind, aufweisen. Die Auflagewalzen können dabei insbesondere mit derselben Geschwindigkeit rotieren, wie sich das aufliegende Transportband bewegt, sodass eine möglichst geringe Reibung zwischen den Auflagewalzen und dem Transportband entsteht. D.h. die Auflagewalzen haben an ihrem Umfang dieselbe Geschwindigkeit wie das aufliegende Transportband.The support device can have a support roller or a plurality of support rollers which are arranged next to one another in the longitudinal extension of the conveyor belt. The support rollers can in particular rotate at the same speed as the conveyor belt on top of it moves, so that the lowest possible friction arises between the support rollers and the conveyor belt. This means that the support rollers have the same speed around their circumference as the conveyor belt on top.
Die Auflageeinrichtung kann alternativ oder zusätzlich einen insbesondere feststehenden Stützkörper, bevorzugt in Form einer Platte aufweisen.As an alternative or in addition, the support device can have an in particular stationary support body, preferably in the form of a plate.
Das Transportband kann eine Dicke im Bereich von 0,2 mm bis 1 mm aufweisen, bevorzugt im Bereich von 0,3 mm bis 0,5 mm aufweisen.The conveyor belt can have a thickness in the range from 0.2 mm to 1 mm, preferably in the range from 0.3 mm to 0.5 mm.
Es kann vorgesehen sein, dass das Transportband aus einem Material ausgebildet ist, das einen Härtegrad im Bereich von 450 HV10 bis 520 HV10, vorzugsweise im Bereich von 465 HV10 bis 500 HV10 aufweist.It can be provided that the conveyor belt is made of a material which has a degree of hardness in the range from 450 HV10 to 520 HV10, preferably in the range from 465 HV10 to 500 HV10.
In einer vorteilhaften Ausbildung kann vorgesehen sein, dass das Transportband so ausgebildet und/oder gelagert ist, dass seine maximale Durchbiegung bei betriebsmäßiger Belastung im Bereich von 1 µm bis 10 µm liegt.In an advantageous embodiment, it can be provided that the conveyor belt is designed and / or supported in such a way that its maximum deflection under operational load is in the range from 1 μm to 10 μm.
Weiter kann vorgesehen sein, dass die dem Substrat zugewandte Oberfläche des Transportbandes poliert ist, d.h. eine Rautiefe kleiner als 0,3 µm aufweist.It can also be provided that the surface of the conveyor belt facing the substrate is polished, i.e. has a roughness depth of less than 0.3 µm.
Das Transportband kann aus einer Stahllegierung ausgebildet sein.The conveyor belt can be made from a steel alloy.
In einer vorteilhaften Ausbildung kann vorgesehen sein, dass das Transportband aus Edelstahl ausgebildet ist.In an advantageous embodiment, it can be provided that the conveyor belt is made of stainless steel.
Alternativ kann vorgesehen sein, dass das Transportband aus Kupfer oder Aluminium oder Titan oder aus einer Legierung, die Kupfer und/oder Aluminium und/oder Titan, insbesondere aus einer Legierung, die Aluminium und/oder Titan enthält, ausgebildet ist.Alternatively, it can be provided that the conveyor belt is made from copper or aluminum or titanium or from an alloy containing copper and / or aluminum and / or titanium, in particular from an alloy containing aluminum and / or titanium.
Das Transportband kann als ein nahtloses Band ausgebildet sein. Ein nahtloses Transportband ohne Stoßstellen bietet über seine gesamte Oberfläche die gleichen Bedingungen hinsichtlich der Eigenschaft als mechanisches Gegenlager für das Substrat.The conveyor belt can be designed as a seamless belt. A seamless conveyor belt without joints offers the same conditions over its entire surface with regard to its property as a mechanical counter-bearing for the substrate.
Das Transportband kann mehrere Teiltransportbänder aufweisen, die in Transportrichtung aneinander anschließend angeordnet sind, bevorzugt mit möglichst geringem Abstand zwischen den Teiltransportbändern. Diese Teiltransportbänder können gleiche oder auch unterschiedliche Eigenschaften aufweisen, insbesondere bzgl. Material und/oder Härte und/oder Dicke und/oder Biegesteifigkeit. Die für das Transportband oben beschriebenen Eigenschaften gelten auch für die Teiltransportbänder.The conveyor belt can have several partial conveyor belts which are arranged adjacent to one another in the direction of transport, preferably with the smallest possible spacing between the partial conveyor belts. These partial conveyor belts can have the same or different properties, in particular with regard to material and / or hardness and / or thickness and / or flexural strength. The properties described above for the conveyor belt also apply to the partial conveyor belts.
Beispielsweise kann ein erstes Teiltransportband im Bereich der Beschichtungseinrichtung und ein zweites Teiltransportband im Bereich der Koronaeinrichtung angeordnet sein.For example, a first partial conveyor belt can be arranged in the area of the coating device and a second partial conveyor belt in the area of the corona device.
In einer vorteilhaften Ausbildung kann vorgesehen sein, dass zwischen benachbarten Teiltransportbändern ein Auflageelement angeordnet ist, das den Abstandsraum zwischen den benachbarten Teiltransportbändern spaltfrei überbrückt.In an advantageous embodiment it can be provided that a support element is arranged between adjacent partial conveyor belts which bridges the space between the adjacent partial conveyor belts without a gap.
Alternativ kann vorgesehen sein, dass das Transportband als ein Gliederband aus plattenförmigen Gliedern ausgebildet ist, wobei benachbarte Glieder durch ein Drehgelenk so miteinander verbunden sind, dass sie im gestreckten Zustand eine spaltfreie Auflagefläche bilden.Alternatively, it can be provided that the conveyor belt is designed as a link belt made of plate-shaped links, with adjacent links being connected to one another by a swivel joint in such a way that they form a gap-free support surface in the extended state.
Es kann vorgesehen sein, dass das Transportband randseitige Transportausnehmungen aufweist, und dass die Umlenkwalzen korrespondierende Zahnkränze aufweisen, die in die Transportausnehmungen eingreifen.It can be provided that the conveyor belt has transport recesses on the edge, and that the deflection rollers have corresponding toothed rims which engage in the transport recesses.
Weiter kann vorgesehen sein, dass das Transportband Durchgangslöcher, insbesondere eine Vielzahl an Durchgangslöchern aufweist.It can further be provided that the conveyor belt has through holes, in particular a multiplicity of through holes.
Die Durchgangslöcher können als insbesondere kreisförmige Bohrungen und/oder insbesondere ellipsenförmige Langlöcher und/oder Schlitze und/oder Rauten ausgebildet sein.The through holes can be designed as in particular circular bores and / or in particular elliptical elongated holes and / or slots and / or rhombuses.
Weiter kann vorgesehen sein, dass die Durchgangslöcher in einem Raster angeordnet sind.It can further be provided that the through holes are arranged in a grid.
Das Raster kann regelmäßig oder unregelmäßig oder zufällig ausgebildet sein.The grid can be regular or irregular or random.
Es kann auch vorgesehen sein, dass das Raster bereichsweise unterschiedlich ausgebildet ist.It can also be provided that the grid is designed differently in areas.
Die Durchgangslöcher können einen Durchmesser im Bereich von 0,2 mm bis 5 mm, bevorzugt in einem Bereich von 0,3 mm bis 2 mm aufweisen oder einen einem kreisförmigen Loch vorgenannten Durchmessers entsprechenden Flächeninhalt aufweisen, insbesondere wenn das Durchgangsloch nicht kreisförmig ausgebildet ist.The through holes can have a diameter in the range from 0.2 mm to 5 mm, preferably in a range from 0.3 mm to 2 mm, or have an area corresponding to a circular hole of the aforementioned diameter, in particular if the through hole is not circular.
Erfindungsgemäß ist vorgesehen, dass zwischen der dem Substrat abgewandten Seite des Transportbandes und einem Ansaugkopf der Vakuumansaugeinrichtung ein Dichtelement mit einer umlaufenden Dichtlippe angeordnet ist.According to the invention it is provided that a sealing element with a circumferential sealing lip is arranged between the side of the conveyor belt facing away from the substrate and a suction head of the vacuum suction device.
In einer vorteilhaften Ausbildung kann vorgesehen sein, dass der Unterdruck der Vakuumansaugvorrichtung im Bereich 10000 Pascal bis 100000 Pascal (0,1 bar bis 1 bar) insbesondere im Bereich von 10000 Pascal bis 75000 Pascal (0,1 bar bis 0,75 bar) liegt.In an advantageous embodiment, it can be provided that the negative pressure of the vacuum suction device is in the range from 10,000 Pascal to 100,000 Pascal (0.1 bar to 1 bar), in particular in the range from 10,000 Pascal to 75,000 Pascal (0.1 bar to 0.75 bar) .
Es kann vorgesehen sein, dass die Koronaeinrichtung ein an seiner Unterseite offenes Gehäuse aufweist, in dessen unteren Endabschnitt eine Elektrode angeordnet ist. Die Elektrode kann beispielsweise als eine luftgekühlte Keramik-Elektrode ausgebildet sein, einen Querschnitt von 16 mm x 16 mm und eine Länge, die der Breite des Transportbandes entspricht, aufweisen. Dabei kann die Koronaeinrichtung mit ihrer Längserstreckung quer zur Transportrichtung des Transportbandes und über dem Substrat angeordnet sein.It can be provided that the corona device has a housing which is open on its underside and in the lower end section of which an electrode is arranged. The electrode can, for example, be designed as an air-cooled ceramic electrode, have a cross section of 16 mm × 16 mm and a length that corresponds to the width of the conveyor belt. The corona device can be arranged with its longitudinal extent transverse to the transport direction of the conveyor belt and above the substrate.
Es kann vorgesehen sein, dass die Elektrode der Koronaeinrichtung die Kathode und das Transportband als Gegenelektrode die Anode der Koronaeinrichtung bilden, wobei zwischen der Kathode und der Anode ein Koronaspalt ausgebildet ist. Der Koronaspalt kann beispielsweise im Bereich von 1 mm bis 2 mm liegen.It can be provided that the electrode of the corona device forms the cathode and the conveyor belt as a counter electrode forms the anode of the corona device, a corona gap being formed between the cathode and the anode. The corona gap can, for example, be in the range from 1 mm to 2 mm.
An die Elektrode und die Gegenelektrode ist eine hohe elektrische Spannung angelegt, die durch einen Hochfrequenzgenerator mit einem Frequenzbereich von 10 kHz bis 60 kHz erzeugt wird und in dem Luftspalt eine Feldstärke von 20 kV/cm bis 30 kV/cm ausbildet. Durch Feldionisation werden Ionen gebildet, die im elektrischen Feld beschleunigt werden und sich an die Oberfläche des Substrats anheften.A high electrical voltage is applied to the electrode and the counter electrode, which is generated by a high-frequency generator with a frequency range of 10 kHz to 60 kHz and a field strength of 20 kV / cm to 30 kV / cm in the air gap. Field ionization forms ions that are accelerated in the electric field and adhere to the surface of the substrate.
Durch die Bildung polarer, funktionieller Gruppen kann der polare Anteil der Oberflächenspannung des Substrats angehoben werden. Die Oberfläche des Substrats wird elektrisch aufgeladen, die Oberflächenenergie des Substrats wird erhöht. Für eine gute Benetzung des Substrats mit einer Flüssigkeit, also z.B. eines UV-Klebers oder einer Drucktinte, sollte die Oberflächenspannung des Substrats ca.10 mN/m bis 15 mN/m höher liegen, als die Oberflächenspannung der Flüssigkeit. Beispielsweise kann die Oberflächenspannung einer Tinte zwischen 20 mN/m bis 25 mN/m und die Oberflächenspannung eines zu bedruckenden folienförmigen Substrats zwischen 30 mN/m bis 35 mN/m liegen. Mittels der Koronaeinrichtung kann die Oberflächenspannung des Substrats auf ca. 40 mN/m bis 45 mN/m angehoben werden, wodurch sich dieses Substrat bedrucken lässt.By forming polar, functional groups, the polar portion of the surface tension of the substrate can be increased. The surface of the substrate is electrically charged and the surface energy of the substrate is increased. For good wetting of the substrate with a liquid, e.g. a UV adhesive or a printing ink, the surface tension of the substrate should be about 10 mN / m to 15 mN / m higher than the surface tension of the liquid. For example, the surface tension of an ink can be between 20 mN / m to 25 mN / m and the surface tension of a film-shaped substrate to be printed can be between 30 mN / m to 35 mN / m. By means of the corona device, the surface tension of the substrate can be increased to approx. 40 mN / m to 45 mN / m, whereby this substrate can be printed.
Der Koronaspalt kann einstellbar ausgebildet sein. Beispielsweise kann die Elektrode der Koronaeinrichtung höheneinstellbar ausgebildet sein. Dadurch kann ein möglichst kleiner Koronaspalt einstellbar sein, beispielsweise abhängig von der Dicke und/oder vom Material des Substrats, um das das Substrat umschließende und/oder durchdringende elektrische Feld anpassen zu können.The corona gap can be designed to be adjustable. For example, the electrode of the corona device can be designed to be height-adjustable. As a result, the smallest possible corona gap can be set, for example depending on the thickness and / or the material of the substrate, in order to be able to adapt the electrical field surrounding and / or penetrating the substrate.
Die Koronaeinrichtung kann eine gasdicht mit dem Gehäuse verbundene Absaugvorrichtung zur Ozonabsaugung aufweisen. Durch die Ionisation der Luft in dem Koronaspalt entsteht Ozon, welches abgesaugt oder vernichtet werden muss. Die ozonhaltige Abluft wird über einen Abluftschlauch geführt und außerhalb des Fertigungsraumes abgeführt. Optional kann die ozonhaltige Abluft vor der Ableitung in die Umwelt durch einen Ozonvernichter geleitet werden, beispielsweise ein Aktivkohlefilter. Auf diese Weise können 99,5 % des Ozons vernichtet werden. Der Abbluftschlauch kann beispielsweise eine Länge von 12 m bis 15 m aufweisen. Eine Förderleistung von 4,9 m3/min hat sich bewährt. Die Absaugvorrichtung kann gleichzeitig eine Kühlvorrichtung für die Elektrode bilden.The corona device can have a suction device connected to the housing in a gas-tight manner for suctioning off ozone. The ionization of the air in the corona gap creates ozone, which has to be extracted or destroyed. The ozone-containing exhaust air is led through an exhaust hose and discharged outside of the production room. Optionally, the ozone-containing exhaust air can be passed through an ozone destroyer, for example an activated carbon filter, before being discharged into the environment. In this way 99.5% of the ozone can be destroyed. The exhaust air hose can, for example, have a length of 12 m to 15 m. A delivery rate of 4.9 m 3 / min has proven itself. The suction device can simultaneously form a cooling device for the electrode.
Es kann vorgesehen sein, dass die Beschichtungseinrichtung als eine Druckeinrichtung ausgebildet ist. Die Druckeinrichtung kann beispielsweise eine Druckwalze und eine Farbauftragsvorrichtung aufweisen und/oder nach dem Siebdruckprinzip und/oder nach dem Tintenstrahlprinzip arbeiten.It can be provided that the coating device is designed as a printing device. The printing device can, for example, have a printing roller and an ink application device and / or work according to the screen printing principle and / or according to the ink jet principle.
Es kann auch vorgesehen sein, dass die Beschichtungseinrichtung eine Prägevorrichtung zur Übertragung einer auf einer Trägerschicht einer Transferfolie, insbesondere einer Heißprägefolie oder Kaltprägefolie angeordneten Übertragungsschicht auf das Substrat aufweist.It can also be provided that the coating device has an embossing device for transferring a onto a carrier layer Has transfer film, in particular a hot stamping film or cold stamping film arranged transfer layer on the substrate.
Eine Prägewalze der Prägevorrichtung kann an ihrem Außenumfang eine Beschichtung aus einem Elastomer mit einer Dicke im Bereich von 3 mm bis 10 mm aufweisen, bevorzugt im Bereich von 5 mm bis 10 mm. Bei dem Elastomer handelt es sich vorzugsweise um Silikonkautschuk. Der Silikonkautschuk weist bevorzugt eine Härte im Bereich von 60° Shore A bis 95° Shore A, bevorzugt im Bereich von 70° Shore A bis 90° Shore A auf. Eine im Bereich der Prägevorrichtung angeordnete Auflagewalze bildet eine Gegendruckwalze für die Prägewalze.An embossing roller of the embossing device can have a coating of an elastomer with a thickness in the range from 3 mm to 10 mm, preferably in the range from 5 mm to 10 mm, on its outer circumference. The elastomer is preferably silicone rubber. The silicone rubber preferably has a hardness in the range from 60 ° Shore A to 95 ° Shore A, preferably in the range from 70 ° Shore A to 90 ° Shore A. A support roller arranged in the area of the embossing device forms a counter-pressure roller for the embossing roller.
Die Beschichtungseinrichtung kann bevorzugt stromabwärts hinter der Koronaeinrichtung angeordnet sein. Dadurch kann die Beschichtung des Substrats nach der Behandlung der Oberfläche des Substrats mittels der Koronaeinrichtung erfolgen.The coating device can preferably be arranged downstream behind the corona device. As a result, the substrate can be coated by means of the corona device after the surface of the substrate has been treated.
Stromabwärts nach der Koronaeinrichtung können auch mehrere Beschichtungsstationen stromabwärts hintereinander angeordnet sein, beispielsweise mehrere Druckeinrichtungen und/oder mehrere Prägevorrichtung und/oder eine Druckeinrichtung und eine Prägevorrichtung oder andere Kombinationen davon. Die Druckeinrichtungen können dabei jeweils nach dem gleichen Druckverfahren und/oder nach unterschiedlichen Druckverfahren arbeiten. Die Prägevorrichtungen können dabei jeweils nach dem gleichen Verfahren und/oder nach unterschiedlichen Verfahren arbeiten.Downstream of the corona device, a plurality of coating stations can also be arranged downstream one behind the other, for example a plurality of printing devices and / or a plurality of embossing devices and / or a printing device and an embossing device or other combinations thereof. The printing devices can each work according to the same printing process and / or according to different printing processes. The embossing devices can each work according to the same method and / or according to different methods.
Ebenso ist es möglich, stromabwärts nach der Koronaeinrichtung und bevorzugt nach der mindestens einen Beschichtungseinrichtung weitere Bearbeitungsstationen wie Sortierstationen, Stanzstationen, Blindprägestationen, Faltstationen oder andere Bearbeitungsstationen zur Bearbeitung des Substrats anzuordnen.It is also possible to arrange further processing stations such as sorting stations, punching stations, blind embossing stations, folding stations or other processing stations for processing the substrate downstream of the corona device and preferably downstream of the at least one coating device.
Die Transferfolie weist eine auf einer Trägerschicht angeordnete Übertragungsschicht auf. Die Trägerschicht kann z.B. aus PET oder aus Polypropylen, Polystyrol, PVC, PMMA, ABS, Polyamid sein. Die Heißprägefolie ist so angeordnet, dass die Übertragungsschicht der Oberseite des zu beprägenden Substrats zugewandt ist. Die Übertragungsschicht kann mit einer hitzeaktivierbaren Kleberschicht beschichtet sein oder selbstklebend (Kaltkleber) ausgebildet sein. Zwischen der Übertragungsschicht und der Trägerschicht kann eine Trennschicht angeordnet sein, die das Ablösen der Übertragungsschicht von der Trägerschicht erleichtert.The transfer film has a transfer layer arranged on a carrier layer. The carrier layer can be made of PET or of polypropylene, polystyrene, PVC, PMMA, ABS, polyamide, for example. The hot stamping foil is arranged in such a way that the transfer layer faces the top side of the substrate to be stamped. The transfer layer can be coated with a heat-activated adhesive layer or be self-adhesive (cold adhesive). A separating layer, which facilitates detachment of the transfer layer from the carrier layer, can be arranged between the transfer layer and the carrier layer.
Die Übertragungsschicht der Transferfolie weist im Allgemeinen mehrere Schichten auf, insbesondere eine Ablöseschicht (beispielsweise aus Wachs oder wachshaltigen Verbindungen), eine Schutzlackschicht, eine hitzeaktivierbare Kleberschicht. Zusätzlich können eine oder mehrere, flächig partiell oder vollflächig aufgebrachte, Dekorationsschichten und/oder Funktionsschichten enthalten sein. Dekorationsschichten sind zum Beispiel farbige (opak oder transparent oder transluzent) Lackschichten, Metallschichten oder Reliefstrukturen (haptisch oder optisch refraktiv oder optisch diffraktiv wirkend). Funktionsschichten sind beispielsweise elektrisch leitende Schichten (Metall, ITO (ITO = Indium Tin Oxide)), elektrisch halbleitende Schichten (z.B. Halbleiterpolymere) oder elektrisch nichtleitende Schichten (elektrisch isolierende Lackschichten) oder optisch mattierende oder anti-reflektierend wirkende Schichten (z.B. mit mikroskopischen Mattstrukturen) oder die Haftwirkung und/oder die Oberflächenspannung modifizierende Strukturen (Lotus-Effekt-Strukturen oder ähnliche). Zwischen den einzelnen Schichten können zusätzliche Hilfsschichten, insbesondere Haftvermittlerschichten vorhanden sein. Die einzelnen Schichten der Übertragungslage sind etwa zwischen 1 nm und 50 µm dick.The transfer layer of the transfer film generally has several layers, in particular a release layer (for example made of wax or wax-containing compounds), a protective lacquer layer, a heat-activated adhesive layer. In addition, one or more decorative layers and / or functional layers applied over the entire area can be included. Decorative layers are, for example, colored (opaque or transparent or translucent) lacquer layers, metal layers or relief structures (haptically or optically refractive or optically diffractive). Functional layers are, for example, electrically conductive layers (metal, ITO (ITO = Indium Tin Oxide)), electrically semiconducting layers (e.g. semiconductor polymers) or electrically non-conductive layers (electrically insulating lacquer layers) or optically matting or anti-reflective layers (eg with microscopic matt structures) or structures that modify the adhesive effect and / or the surface tension (lotus effect structures or similar). Additional auxiliary layers, in particular adhesion promoter layers, can be present between the individual layers. The individual layers of the transfer layer are approximately between 1 nm and 50 µm thick.
Das Substrat ist bevorzugt ein flexibles Substrat, beispielsweise Papier mit einem Flächengewicht von 30 g/m2 bis 350 g/m2, bevorzugt 80 g/m2 bis 350 g/m2 oder Karton oder Kunststoff oder ein Hybridmaterial aus mehreren Papier- und Kunststoffschichten oder ein Laminat aus mehreren Papier- und/oder Kunststoffschichten.The substrate is preferably a flexible substrate, for example paper with a basis weight of 30 g / m 2 to 350 g / m 2 , preferably 80 g / m 2 to 350 g / m 2 or cardboard or plastic or a hybrid material made of several paper and Plastic layers or a laminate of several paper and / or plastic layers.
Die Erfindung wird nun anhand von Ausführungsbeispielen näher erläutert. Es zeigen
- Fig. 1
- ein erstes Ausführungsbeispiel der erfindungsgemäßen Vorrichtung in schematischer Darstellung;
- Fig. 2
- ein zweites Ausführungsbeispiel der erfindungsgemäßen Vorrichtung in schematischer Darstellung;
- Fig. 3
- ein drittes Ausführungsbeispiel der erfindungsgemäßen Vorrichtung in schematischer Darstellung;
- Fig. 4
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Fig. 1 in schematischer Draufsicht; - Fig. 5
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Fig. 1 in schematischer Draufsicht; - Fig. 7
- ein viertes Ausführungsbeispiel des Transportbandes in
Fig. 1 in schematischer Draufsicht; - Fig. 8
- ein viertes Ausführungsbeispiel des Transportbandes in
Fig. 1 in der Draufsicht.
- Fig. 1
- a first embodiment of the device according to the invention in a schematic representation;
- Fig. 2
- a second embodiment of the device according to the invention in a schematic representation;
- Fig. 3
- a third embodiment of the device according to the invention in a schematic representation;
- Fig. 4
- a first embodiment of a conveyor belt in
Fig. 1 in a schematic plan view; - Fig. 5
- a second embodiment of the conveyor belt in
Fig. 1 in a schematic plan view; - Fig. 6
- a third embodiment of the conveyor belt in
Fig. 1 in a schematic plan view; - Fig. 7
- a fourth embodiment of the conveyor belt in
Fig. 1 in a schematic plan view; - Fig. 8
- a fourth embodiment of the conveyor belt in
Fig. 1 in top view.
Die Transporteinrichtung 3 ist als ein umlaufendes Transportband 31 ausgebildet, das auf zwei voneinander beabstandeten Umlenkwalzen 32 gelagert ist, wobei eine der Umlenkwalzen 32 als eine Antriebswalze 32a ausgebildet ist. Das Transportband 31 ist in der in
Es kann auch vorgesehen sein, dass das Transportband 31 als ein Gliederband aus plattenförmigen Gliedern ausgebildet ist, wobei benachbarte Glieder durch ein Drehgelenk so miteinander verbunden sind, dass sie im gestreckten Zustand eine spaltfreie Auflagefläche bilden. Vorteilhafterweise kann das Transportband 31 bei dieser in den Figuren nicht dargestellten Ausbildung randseitige Transportausnehmungen aufweisen, die mit korrespondierenden Zahnkränzen zusammenwirken, die mit den Umlenkwalzen 32 drehstarr verbunden sind.It can also be provided that the
Das Transportband 31 läuft in einer Transportrichtung 31t um. Das Substrat 2 ist in einem Transportabschnitt des Transportbandes 31 auf dem Transportband 31 angeordnet und ist durch Unterdruck auf dem Transportband 31 fixiert. Das Substrat 2 wird entsprechend der Transportrichtung 31t des Transportbandes 31 in einer Transportrichtung 2t bewegt, die der Transportrichtung 31 in dem Transportabschnitt entspricht.The
Das Transportband 31 ist im Bereich der Koronaeinrichtung 5 und im Bereich der Beschichtungseinrichtung 6 auf einer Auflageeinrichtung 7 gelagert. Die Beschichtungseinrichtung 6 ist stromabwärts hinter der Koronaeinrichtung 5 angeordnet.The
Die unter der Koronaeinrichtung 5 angeordnete Auflageeinrichtung 7 ist in dem in
Die unter der Beschichtungseinrichtung 6 angeordnete Auflageeinrichtung 7 weist eine Auflagewalze 71 auf, deren Drehachse ebenfalls quer zu der Transportrichtung 31t des Transportbandes 31 ausgerichtet ist.The support device 7 arranged below the
In dem in
Das Transportband 31 weist eine Dicke im Bereich von 0,2 mm bis 1 mm auf, bevorzugt im Bereich von 0,3 mm bis 0,5 mm.The
Das Transportband 31 ist aus einem Material ausgebildet, das einen Härtegrad im Bereich von 450 HV10 bis 520 HV10, vorzugsweise im Bereich von 465 HV10 bis 500 HV10 aufweist.The
Das Transportband 31 kann aus einer Stahllegierung ausgebildet sein, bevorzugt aus Edelstahl. Es kann auch vorgesehen sein, das Transportband aus Kupfer, Aluminium oder Titan ausgebildet ist.The
Die dem Substrat 2 zugewandte Oberfläche des Transportbandes ist poliert, d.h. sie weist eine Rautiefe kleiner als 0,3 µm auf.The surface of the conveyor belt facing the
Das Transportband 31 ist als ein Vakuumsaugband 31v mit Durchgangslöchern 31 d (siehe
Die Durchgangslöcher 31 können als insbesondere kreisförmige Bohrungen und/oder insbesondere ellipsenförmige Langlöcher und/oder Schlitze und/oder Rauten ausgebildet sein.The through holes 31 can be designed as in particular circular bores and / or in particular elliptical elongated holes and / or slots and / or rhombuses.
Über ein an der dem Substrat 2 abgewandten Seite des Transportbandes 31 angeordnetes Dichtelement 42 ist ein über dem Dichtelement 42 angeordneter Abschnitt des Transportbandes 31 mit einem Ansaugkopf 41 der Vakuumansaugeinrichtung 4 gasdicht oder annähernd gasdicht verbunden. Das Dichtelement 42 ist als eine umlaufende Dichtlippe ausgebildet. In dem in
Ansaugkopf 41 unter der Koronaeinrichtung 5 angeordnet ist. Die Vakuumansaugeinrichtung 4 ist mit einer Vakuumpumpe 43 ausgebildet, deren Eingang mit dem Ansaugkopf 41 verbunden ist.
Wie die vorbeschriebenen Ausführungsbeispiele zeigen, kann das Raster regelmäßig oder unregelmäßig oder zufällig ausgebildet sein.As the exemplary embodiments described above show, the grid can be formed regularly or irregularly or randomly.
Die Koronaeinrichtung 5 weist ein an der Unterseite offenes Gehäuse 51 auf, in dem eine Elektrode 52 angeordnet ist. Die Elektrode 52 ist als eine luftgekühlte Keramik-Elektrode ausgebildet und über dem Substrat 2 angeordnet. Das Transportband 31 bildet eine Gegenelektrode 31e, die insbesondere geerdet ist. In dem in
An die Elektrode 52 und die Gegenelektrode 31e ist eine hohe elektrische Spannung angelegt, die durch einen Hochfrequenzgenerator 54 mit einem Frequenzbereich von 10 kHz bis 60 kHz erzeugt wird und in dem Luftspalt 5l eine Feldstärke von 20 kV/cm bis 30 kV/cm ausbildet. Durch Feldionisation werden Ionen gebildet, die im elektrischen Feld beschleunigt werden und sich an die Oberfläche des Substrats 2 anheften.A high electrical voltage is applied to the
Durch die Bildung polarer, funktionieller Gruppen kann der polare Anteil der Oberflächenspannung des Substrats 2 angehoben werden. Die Oberfläche des Substrats 2 wird elektrisch aufgeladen, die Oberflächenenergie des Substrats 2 wird erhöht. Für eine gute Benetzung des Substrats 2 mit einer Flüssigkeit, also z.B. eines UV-Klebers oder einer Drucktinte, sollte die Oberflächenspannung des Substrats 2 ca. 10 mN/m bis 15 mN/m höher liegen, als die Oberflächenspannung der Flüssigkeit. Beispielsweise kann die Oberflächenspannung einer Tinte zwischen 20 mN/m bis 25 mN/m und die Oberflächenspannung eines zu bedruckenden folienförmigen Substrats 2 zwischen 30 mN/m bis 35 mN/m liegen. Mittels der Koronaeinrichtung 5 kann die Oberflächenspannung des Substrats 2 auf ca. 40 mN/m bis 45 mN/m angehoben werden, wodurch sich dieses Substrat 2 bedrucken lässt.By forming polar, functional groups, the polar portion of the surface tension of the
Die Koronaeinrichtung 5 weist eine gasdicht mit dem Gehäuse 51 verbundene Absaugvorrichtung 53 zur Ozonabsaugung auf. Durch die Ionisation der Luft in dem Luftspalt 5l entsteht Ozon, welches abgesaugt oder vernichtet werden muss. Die ozonhaltige Abluft wird über einen Abluftschlauch geführt und außerhalb des Fertigungsraumes abgeführt. Optional kann die ozonhaltige Abluft vor der Ableitung in die Umwelt durch einen Ozonvernichter geleitet werden, beispielsweise ein Aktivkohlefilter. Auf diese Weise können 99,5 % des Ozons vernichtet werden. Der Abbluftschlauch kann beispielsweise eine Länge von 12 bis 15 m aufweisen. Eine Förderleistung von 4,9 m3/min hat sich bewährt. Die Absaugvorrichtung 53 bildet gleichzeitig eine Kühlvorrichtung für die Elektrode 52.The
Die Beschichtungseinrichtung 6 ist als eine Prägevorrichtung 65 zur Übertragung einer auf einer Trägerschicht einer Transferfolie 66, insbesondere einer Heißprägefolie oder Kaltprägefolie angeordneten Übertragungsschicht auf das Substrat 2 ausgebildet.The
Eine Prägewalze 67 der Prägevorrichtung 65 weist an ihrem Außenumfang eine Beschichtung aus einem Elastomer mit einer Dicke im Bereich von 3 mm bis 10 mm auf, bevorzugt im Bereich von 5 mm bis 10 mm. Bei dem Elastomer handelt es sich vorzugsweise um Silikonkautschuk. In dem in
In dem in
Die in
- 11
- Vorrichtungcontraption
- 22
- SubstratSubstrate
- 2t2t
- TransportrichtungTransport direction
- 33
- TransporteinrichtungTransport device
- 3t3t
- TransportrichtungTransport direction
- 44th
- VakuumansaugeinrichtungVacuum suction device
- 55
- KoronaeinrichtungCorona device
- 5l5l
- LuftspaltAir gap
- 66th
- BeschichtungseinrichtungCoating device
- 77th
- AuflageeinrichtungSupport device
- 3131
- TransportbandConveyor belt
- 31 d31 d
- DurchgangslochThrough hole
- 31 e31 e
- GegenelektrodeCounter electrode
- 31t31t
- TransportrichtungTransport direction
- 31 v31 BC
- VakuumsaugbandVacuum suction belt
- 3232
- UmlenkwalzenGuide rollers
- 32a32a
- AntriebswalzeDrive roller
- 4141
- AnsaugkopfSuction head
- 4242
- DichtelementSealing element
- 4343
- VakuumpumpeVacuum pump
- 5151
- Gehäusecasing
- 5252
- Elektrodeelectrode
- 5353
- AbsaugvorrichtungSuction device
- 5454
- HochfrequenzgeneratorHigh frequency generator
- 6161
- DruckeinrichtungPrinting facility
- 6262
- DruckwalzePressure roller
- 6363
- FarbauftragseinrichtungPaint application device
- 6565
- PrägevorrichtungEmbossing device
- 6666
- TransferfolieTransfer film
- 6767
- PrägewalzeEmbossing roller
- 7171
- AuflagewalzePlaten
Claims (14)
- Device (1) for the surface treatment of a substrate (2), having a transport device (3), a vacuum suction device (4), a corona device (5) and a coating device (6),
wherein the transport device (3) has a conveyor belt (31), and the conveyor belt (31) is designed as a vacuum suction belt (31v) of the vacuum suction device (4),
characterised in that
the conveyor belt (31) is designed as a counter electrode (31e) of the corona device (5), wherein a sealing element (42) having a peripheral sealing lip is arranged between the side of the conveyor belt (31) facing away from the substrate (2) and a suction head (41) of the vacuum suction device (4), and the suction head (41) is arranged under the corona device (5). - Device according to claim 1,
characterised in that
the conveyor belt (31) is mounted on two spaced-apart deflection rollers (32), wherein one of the deflection rollers (32) is formed as a drive roller (32a). - Device according to claim 1 or 2,
characterised in that
the conveyor belt (31) is designed as a circulating belt. - Device according to one of the preceding claims,
characterised in that
the conveyor belt (31) is mounted on a support device (7) in the region of the corona device (5) and/or of the coating device (6), in particular wherein the support device (7) has a support roller (71) or several support rollers (71), which are arranged adjacent to one another in the longitudinal extension of the conveyor belt (31). - Device according to one of the preceding claims,
characterised in that
the conveyor belt (31) has a thickness in the range of from 0,2mm to 1mm, preferably in the range of from 0.3mm to 0.5mm, and/or is formed from a material that has a hardness in the range of from 450 HV10 to 520 HV10, preferably in the range of from 465 HV10 to 500 HV10, and/or is formed and/or mounted in such a way that its maximum deflection under operational load is in the range of from 1µm to 10µm. - Device according to one of the preceding claims,
characterised in that
the conveyor belt (31) is formed from a steel alloy, in particular wherein the conveyor belt (31) is formed from stainless steel. - Device according to one of the preceding claims,
characterised in that
the conveyor belt (31) is formed as a seamless belt. - Device according to one of claims 1 to 7,
characterised in that
the conveyor belt (31) has several partial conveyor belts, which are arranged following one another in the conveying direction (3 It), in particular wherein a support element is arranged between adjacent partial conveyor belts, which support element bridges the space between the adjacent partial conveyor belts without gaps, and/or the conveyor belt (31) is formed as a link belt made of plate-shaped links, wherein adjacent links are connected to one another by means of a swivel joint in such a way that they form a gap-free support surface in the extended state, in particular wherein the conveyor belt (31) has edge-sided conveying recesses, and the deflection rollers have corresponding gear rims that engage in the conveying recesses. - Device according to one of the preceding claims,
characterised in that
the conveyor belt (31) has through holes (31d), in particular wherein the through holes (31d) are formed as bores and/or elongated holes and/or slots and/or rhombuses, in particular preferably wherein the through holes (31d) are arranged in a grid, particularly preferably wherein the grid is formed regularly or irregularly or randomly and/or differently area by area. - Device according to claim 9,
characterised in that
the through holes (31d) have a diameter in the range of from 0.2mm to 5mm, preferably in a range of from 0.3mm to 2mm or have an area corresponding to a circular hole of the aforementioned diameter. - Device according to one of the preceding claims,
characterised in that
the negative pressure of the vacuum suction device is in the range of from 10000 Pascal to 100000 Pascal (0.1 bar to 1 bar), preferably in the range of from 10000 Pascal to 75000 Pascal (0.1 bar to 0.75 bar). - Device according to one of the preceding claims,
characterised in that
the corona device (5) has a housing (51) that is open on its underside, in the lower end section of which an electrode (52) is arranged, in particular wherein the electrode (52) of the corona device (5) forms the cathode and the conveyor belt (31) as a counter electrode forms the anode of the corona device (5), wherein a corona gap (51) is formed between the cathode and the anode, in particular preferably wherein the corona gap (51) is designed to be adjustable. - Device according to one of the preceding claims,
characterised in that
the coating device (6) is formed as a printing device (61). - Device according to one of claims 1 to 13,
characterised in that
the coating device (6) is formed as an embossing device (65) for transferring a transfer layer arranged on a carrier layer of a transfer film (66) to the substrate (2).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL17716837T PL3458265T3 (en) | 2016-05-17 | 2017-04-06 | Device for the surface treatment of a substrate having a metallic conveyor belt |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102016109044.1A DE102016109044B3 (en) | 2016-05-17 | 2016-05-17 | Device for surface treatment of a substrate |
PCT/EP2017/058291 WO2017198390A1 (en) | 2016-05-17 | 2017-04-06 | Device for the surface treatment of a substrate, comprising a metallic conveyor belt |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3458265A1 EP3458265A1 (en) | 2019-03-27 |
EP3458265B1 true EP3458265B1 (en) | 2021-08-11 |
Family
ID=58536961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP17716837.4A Active EP3458265B1 (en) | 2016-05-17 | 2017-04-06 | Device for the surface treatment of a substrate having a metallic conveyor belt |
Country Status (11)
Country | Link |
---|---|
US (1) | US11155427B2 (en) |
EP (1) | EP3458265B1 (en) |
JP (1) | JP6946347B2 (en) |
KR (1) | KR102304657B1 (en) |
CN (1) | CN109311310B (en) |
DE (1) | DE102016109044B3 (en) |
ES (1) | ES2886963T3 (en) |
HU (1) | HUE056316T2 (en) |
IL (1) | IL262861B (en) |
PL (1) | PL3458265T3 (en) |
WO (1) | WO2017198390A1 (en) |
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Also Published As
Publication number | Publication date |
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WO2017198390A1 (en) | 2017-11-23 |
IL262861A (en) | 2018-12-31 |
EP3458265A1 (en) | 2019-03-27 |
US11155427B2 (en) | 2021-10-26 |
JP6946347B2 (en) | 2021-10-06 |
US20190210823A1 (en) | 2019-07-11 |
KR20190008332A (en) | 2019-01-23 |
PL3458265T3 (en) | 2021-11-08 |
IL262861B (en) | 2022-07-01 |
CN109311310B (en) | 2021-09-21 |
CN109311310A (en) | 2019-02-05 |
JP2019517968A (en) | 2019-06-27 |
DE102016109044B3 (en) | 2017-07-06 |
HUE056316T2 (en) | 2022-02-28 |
ES2886963T3 (en) | 2021-12-21 |
KR102304657B1 (en) | 2021-09-27 |
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