EP3456212A1 - Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren, systeme sowie vorrichtungen - Google Patents

Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren, systeme sowie vorrichtungen Download PDF

Info

Publication number
EP3456212A1
EP3456212A1 EP18200346.7A EP18200346A EP3456212A1 EP 3456212 A1 EP3456212 A1 EP 3456212A1 EP 18200346 A EP18200346 A EP 18200346A EP 3456212 A1 EP3456212 A1 EP 3456212A1
Authority
EP
European Patent Office
Prior art keywords
fiber
fibers
filter element
characteristic
tow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP18200346.7A
Other languages
English (en)
French (fr)
Inventor
Andries D. Sebastian
Huamin Gan
Kenneth C. DELOACH
Richard L. SIZEMORE
Dean M. VICK
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RJ Reynolds Tobacco Co
Original Assignee
RJ Reynolds Tobacco Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RJ Reynolds Tobacco Co filed Critical RJ Reynolds Tobacco Co
Publication of EP3456212A1 publication Critical patent/EP3456212A1/de
Pending legal-status Critical Current

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02—Manufacture of tobacco smoke filters
    • A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02—Manufacture of tobacco smoke filters
    • A24D3/0229—Filter rod forming processes
    • A24D3/0233—Filter rod forming processes by means of a garniture
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
    • A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
    • A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
    • A24D3/065—Use of materials for tobacco smoke filters characterised by structural features of the fibers with sheath/core of bi-component type structure
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/30—Drawing through a die
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/08—Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams

Definitions

  • the present disclosure relates to products made or derived from tobacco or other smokable material that are intended for human consumption.
  • the disclosure relates to filter elements for smoking articles such as cigarettes, and related methods and apparatuses for producing filter elements.
  • Popular smoking articles such as cigarettes, may have a substantially cylindrical rod-shaped structure and may include a charge, roll or column of smokable material, such as shredded tobacco (e.g., in cut filler form), surrounded by a paper wrapper, thereby forming a so-called “smokable rod” or "tobacco rod.”
  • a cigarette has a cylindrical filter element aligned in an end-to-end relationship with the tobacco rod.
  • a filter element comprises plasticized cellulose acetate tow circumscribed by a paper material known as "plug wrap.”
  • the filter element is attached to one end of the tobacco rod using a circumscribing wrapping material known as “tipping material.” It also may be desirable to perforate the tipping material and plug wrap, in order to provide dilution of drawn mainstream smoke with ambient air.
  • tipping material a circumscribing wrapping material
  • a cigarette is employed by a smoker by lighting one end thereof and burning the tobacco rod. The smoker then receives mainstream smoke into his/her mouth by drawing on the opposite end (e.g., the filter end) of the cigarette.
  • Certain filter elements for cigarettes contain materials that alter the chemical composition or sensory characteristics of mainstream smoke.
  • adsorbent materials such as activated carbon or charcoal materials (collectively, carbonaceous materials) in particulate or granular form.
  • Granules of carbonaceous material can be incorporated into "dalmatian” types of filter regions using the general types of techniques used for traditional dalmatian filter manufacture. Techniques for production of dalmatian filters are known, and representative dalmatian filters have been provided commercially by Filtrona Greensboro Inc.
  • granules of carbonaceous material can be incorporated into "cavity” types of filter regions using the general types of techniques used for traditional "cavity” filter manufacture.
  • the currently available filter technology for incorporation of a particulate additive into a filter element may suffer from several drawbacks.
  • cavity filters that include a particulate additive in a free state such as activated carbon particles, may potentially result in contamination of mainstream smoke and may also suffer from channeling of smoke around the loose bed of particles in the cavity.
  • manufacturing methods for incorporating particulate additives in cavity filters may be challenging due to the potential for particulate dust clouds to form during the manufacturing process.
  • affixing a particulate adsorbent within a fibrous tow may involve use of a plasticizer or other adhesive material to adhere the particles within the fibrous mass, which may lead to deactivation of the adsorbent due to contamination of the surface of the particles by the plasticizer or adhesive.
  • a filter element in an embodiment, may comprise a mixed fiber product comprising a first fiber defining a first characteristic and a second fiber defining a second characteristic, wherein the first characteristic of the first fiber differs from the second characteristic of the second fiber and the first fiber is at least partially entangled with the second fiber by a texturing apparatus.
  • the filter element may further comprise a plug wrap.
  • the difference between the first characteristic and the second characteristic may relate to a difference in a finish of the first and second fiber, a difference in material composition of the first and second fiber, a difference in total denier or denier per filament of the first and second fiber, or a difference in size or shape of the first fiber and second fiber.
  • the first fiber and the second fiber may have a different material composition such that the first fiber and second fiber have different filtration properties or different levels of biodegradability.
  • the first fiber may define a cross-sectional area, finish, denier, and/or material composition that differs from the second fiber.
  • the first fiber may comprise at least one of cellulose ester and polyolefin.
  • the second fiber may be selected from a group consisting of cotton, regenerated cellulose, polylactic acid, polyhydroxyalkanoate, activated carbon fibers, catalytic fibers, cellulose ester, polyolefin, and ion-exchange fibers.
  • the first fiber may define a material composition that is the same as the second fiber. At least one of the first fiber and the second fiber may be biodegradable.
  • the filter element may further comprise a plasticizer.
  • a first portion of the mixed fiber product may define a first melting point that is less than a second melting point of a second portion of the mixed fiber product.
  • a cigarette comprising the above-described filter element in combination with a rod of smokable material and a tipping material that circumscribes at least a portion of the rod of smokable material and the filter element is also provided.
  • a cigarette in another embodiment, may comprise a rod of smokable material, a filter element comprising a mixed fiber product, the filter element being attached to an end of the rod of smokable material, and a tipping material that circumscribes at least a portion of the rod of smokable material and the filter element.
  • the mixed fiber product may comprise a first fiber defining a first characteristic and a second fiber defining a second characteristic, the first characteristic of the first fiber may differ from the second characteristic of the second fiber, and the first fiber may be at least partially entangled with the second fiber by a texturing apparatus.
  • the first fiber may define a cross-sectional area, finish, denier, and/or material composition that differs from the second fiber.
  • the first fiber may comprise at least one of cellulose ester and polyolefin.
  • the second fiber may be selected from a group consisting of cotton, regenerated cellulose, polylactic acid, polyhydroxyalkanoate, activated carbon fibers, catalytic fibers, cellulose ester, polyolefin, and ion-exchange fibers.
  • the first fiber may define a material composition that is the same as the second fiber. At least one of the first fiber and the second fiber may be biodegradable.
  • a first portion of the mixed fiber product may define a first melting point that is less than a second melting point of a second portion of the mixed fiber product.
  • a method for forming a cigarette filter element may comprise providing a first fiber defining a first characteristic, providing a second fiber defining a second characteristic wherein the first characteristic of the first fiber differs from the second characteristic of the second fiber, combining the first fiber and the second fiber in a texturing apparatus such that the first fiber is at least partially entangled with the second fiber to form a mixed fiber product, and at least partially enclosing the mixed fiber product in a plug wrap.
  • combining the first fiber and the second fiber in the texturing apparatus may comprise directing at least one flow of fluid at the first fiber and the second fiber.
  • Directing the flow of fluid at the first fiber and the second fiber may comprise directing a flow of air at the first fiber and the second fiber.
  • the first fiber may define a cross-sectional area, finish, denier, and/or material composition that differs from the second fiber.
  • the first fiber defines a finish that differs from the second fiber.
  • the first fiber may comprise at least one of cellulose ester and polyolefin.
  • the second fiber may be selected from the group consisting of cotton, regenerated cellulose, polylactic acid, polyhydroxyalkanoate, activated carbon fibers, catalytic fibers, cellulose ester, polyolefin, and ion-exchange fibers.
  • the first fiber may define a material composition that is the same as the second fiber.
  • the first fiber Prior to combining the first fiber and the second fiber in the texturing apparatus, the first fiber may define a tow and the second fiber may define a second tow, or the first fiber may define a tow and the second fiber may define a yarn.
  • the method may further comprise providing a first intermediate fiber, providing a second intermediate fiber, and combining the first intermediate fiber and the second intermediate fiber in an intermediate texturing apparatus such that the first intermediate fiber is at least partially entangled with the second intermediate fiber to form the first fiber.
  • the intermediate texturing apparatus may be the texturing apparatus. Additionally, combining the first fiber and the second fiber in the texturing apparatus may comprise false twisting the first fiber and the second fiber.
  • the method may also include applying a plasticizer to the mixed fiber product.
  • a first portion of the mixed fiber product may define a first melting point that is less than a second melting point of a second portion of the mixed fiber product.
  • the method may further comprise heating the mixed fiber product to a temperature that is greater than or equal to the first melting point and less than the second melting point.
  • the first fiber may define the first portion and the second fiber may define the second portion in one embodiment. In another embodiment the first fiber may define the first portion and at least part of the second portion.
  • the difference between the first characteristic and the second characteristic may relate to a difference in a finish of the first and second fiber, a difference in material composition of the first and second fiber, a difference in total denier or denier per filament of the first and second fiber, or a difference in size or shape of the first fiber and second fiber.
  • the first fiber and the second fiber may have a different material composition such that the first fiber and second fiber have different filtration properties or different levels of biodegradability.
  • the system may comprise a texturing apparatus configured to receive the first and second fibers and combine the first and second fibers into the mixed fiber product and a rod maker configured to receive and wrap the mixed fiber product with the plug wrap to form the filter element.
  • the system may also include a cigarette maker configured to receive the filter element, attach the filter element to a smokable rod, and wrap the filter element and the smokable rod with a tipping material.
  • a system configured for use in the manufacture of cigarettes.
  • the system may include a texturing apparatus configured to receive a first fiber defining a first characteristic and receive a second fiber defining a second characteristic, wherein the first characteristic of the first fiber differs from the second characteristic of the second fiber. Further, the texturing apparatus may be configured to combine the first fiber and the second fiber such that the first fiber is at least partially entangled with the second fiber and the first fiber and the second fiber form a mixed fiber product.
  • the system may also include a rod maker configured to receive and wrap the mixed fiber product with a plug wrap to form a filter element.
  • the texturing apparatus may be further configured to direct at least one flow of fluid at the first fiber and the second fiber in order to combine the first fiber and the second fiber.
  • the flow of fluid may comprise a flow of air.
  • the texturing apparatus may be further configured to receive the first fiber in the form of a tow and the second fiber in the form of a second tow and/or receive the first fiber in the form of a tow and the second fiber in the form of a yarn.
  • the texturing apparatus may also be configured to false twist the first fiber and the second fiber in order to combine the first fiber and the second fiber.
  • the system may additionally include a plasticizer apparatus configured to apply a plasticizer to the mixed fiber product.
  • the system may include a cigarette maker configured to receive the filter element, attach the filter element to a smokable rod, and wrap the filter element and the smokable rod with a tipping material.
  • the system may also include a heater configured to heat the mixed fiber product to a temperature that is greater than or equal to a first melting point of a first portion of the mixed fiber product and less than a second melting point of a second portion of the mixed fiber product.
  • a tow fiber refers to a substantially untwisted bundle of two or more substantially continuous filaments of a fiber.
  • the material composition of the fibers forming the tow fiber may vary depending on the desired characteristics of the filter element which is produced from the tow fiber.
  • the fibers forming the tow fiber may comprise cellulose acetate, which may be employed for taste and filtering characteristics associated therewith.
  • Tow fiber may be produced, in one example embodiment, by spinning a dope, which may comprise a solution of a polymer (e.g., cellulose acetate) and a solvent (e.g., acetone), into a plurality of filaments.
  • the filaments may be taken up, lubricated, and formed into a tow fiber by bundling the filaments.
  • the tow fiber may then be crimped in order to increase the volume of the tow fiber. Further, the tow fiber may be dried and bailed for shipment to a filter element manufacturer.
  • FIG. 1 illustrates an example embodiment of a system 100 configured to produce cigarettes or other smoking articles with operations performed by the system illustrated schematically.
  • the system 100 may receive as an input a tow fiber 108, which may be produced according to the above-described manufacturing process or various other manufacturing processes.
  • the tow fiber 108 may be subjected to tow opening at operation 110.
  • Tow opening refers to one or more processes whereby the tow fiber 108 is spread out.
  • the tow fiber 108 may be initially packaged in a bale or packing in another manner whereby each filament forming the tow fiber is substantially in continuous contact with those filaments adjacent thereto.
  • tow opening at operation 110 may be conducted by a pneumatic banding jet that flattens and spreads the tow fiber 108 and forms a spread tow 118.
  • a pneumatic banding jet that flattens and spreads the tow fiber 108 and forms a spread tow 118.
  • various other techniques may be employed in other embodiments to produce the spread tow 118.
  • the system 100 may be further configured to conduct crimp removal on the spread tow 118 at operation 120.
  • Crimp removal at operation 120 may involve stretching the spread tow fiber 118 to form a decrimped tow 128.
  • Crimp removal may be conducted by directing the spread tow 118 through one or more cooperating sets of rollers with circumferential grooves in some embodiments.
  • the decrimped tow 128 may be subjected to blooming at operation 130. Blooming may involve introducing further separation between the filaments defining the tow. Blooming at operation 130 may be conducted through a variety of techniques, such as tensioning and relaxing alternating sections of the tow using rollers. Alternatively or additionally, one or more pneumatic banding jets may be employed to bloom the tow.
  • the tow opening, crimp removal, and blooming operations 110, 120, 130 all refer to operations whereby the filaments defining the tow fiber 108 are at least partially separated from one another. Separating the filaments defining the tow fiber 108 in this manner ultimately produces a bloomed tow 138.
  • the term "bloomed tow,” as used herein refers to tow fibers that have been at least partially separated through one or more of tow opening, crimp removal, and blooming operations 110, 120, 130.
  • tow opening, crimp removal, and/or blooming operations 110, 120, 130 may occur substantially simultaneously and/or involve use of the same equipment.
  • tow opening at operation 110 and blooming at operation 130 may both occur via use of one or more pneumatic banding jets.
  • crimp removal at operation 120 and blooming at operation 130 may both occur via use of grooved rollers.
  • tow opening, crimp removal, and blooming operations 110, 120, 130 are illustrated and generally described above as being separate operations, it should be understood that there may be overlap between one or more of these operations, or one or more of these operations may be omitted.
  • the term "tow separation,” as used herein, may refer to one or more of tow opening, crimp removal and blooming operations 110, 120, 130, which results in bloomed tow 138, as defined above.
  • the system 100 may subject the bloomed tow 138 to plasticizer application at operation 140.
  • Plasticizer application may involve applying (e.g., via spraying or wick application) a plasticizer 142 to the bloomed tow 138 to produce a plasticized fiber product 148.
  • Plasticizer application at operation 140 may be conducted for the purpose of ultimately bonding the filaments of the tow to one another to produce a relatively firm and rigid structure configured to not soften or collapse during smoking.
  • the tow separation operations described above are configured to improve the penetration of the plasticizer 142 by creating gaps between the filaments defining the bloomed tow 138 through which the plasticizer may travel.
  • the plasticizer 142 which may in some embodiments comprise triacetin and/or carbowax, may be applied to the bloomed tow 138 in traditional amounts using known techniques.
  • the plasticizer 142 may comprise triacetin and carbowax in a 1:1 ratio by weight.
  • the total amount of plasticizer 142 may be generally about 4 to about 20 percent by weight, preferably about 6 to about 12 percent by weight of the filter material.
  • Other suitable materials or additives used in connection with the construction of the filter element will be readily apparent to those skilled in the art of cigarette filter design and manufacture. See, for example, US Patent No. 5,387,285 to Rivers , which is incorporated herein by reference.
  • the plasticized fiber product 148 may then be subjected to one or more rod making operations 150.
  • Rod making operations 150 may include shaping of the plasticized fiber product 148.
  • the plasticized fiber product 148 may be compressed or otherwise shaped to form a continuous cylindrical rod shape.
  • the rod making operations 150 may additionally include cutting the plasticized fiber product 148 into segments.
  • the plasticized fiber product 148 may be longitudinally subdivided into cylindrical shaped filter segments.
  • the length of the filter segments may be selected based on a desired length of the filter element for a single cigarette.
  • the filter segments may be cut to lengths which are equivalent to two times the length of the filter element for a single cigarette, and the filter segment may be cut in two at a later time.
  • the filter segment may connect two rods of tobacco, and the filter segment may be divided to form the filters for two cigarettes.
  • filter segments may range in length from about 80 mm to about 140 mm, and from about 16 mm to about 27 mm in circumference.
  • a typical filter segment having a 100 mm length and a 24.53 mm circumference may exhibit a pressure drop of from about 200 mm to about 400 mm of water as determined at an airflow rate of 17.5 cubic centimeters per second (cc/sec.) using an encapsulated pressure drop tester, sold commercially as Model No. FTS-300 by Filtrona Corporation, Richmond, Virginia.
  • Rod making at operation 150 may also include wrapping the plasticized fiber product 148 with a plug wrap 152 in some embodiments.
  • the plasticized fiber product 148 may be wrapped with the plug wrap 152 such that each end of the filter material remains exposed.
  • the plug wrap 152 can vary. See, for example, U.S. Pat. No. 4,174,719 to Martin .
  • the plug wrap 152 is a porous or non-porous paper material. Suitable plug wrap materials are commercially available.
  • Exemplary plug wrap papers ranging in porosity from about 1100 CORESTA units to about 26000 CORESTA units are available from Schweitzer-Maudit International as Porowrap 17-M1, 33-M1, 45-M1, 70-M9, 95-M9, 150-M4, 150-M9, 240M9S, 260-M4 and 260-M4T; and from Miquel-y-Costas as 22HP90 and 22HP150.
  • Non-porous plug wrap materials typically exhibit porosities of less than about 40 CORESTA units, and often less than about 20 CORESTA units.
  • Plug wrap paper can be coated, particularly on the surface that faces the plasticized fiber product 148, with a layer of a film-forming material.
  • a suitable polymeric film-forming agent e.g., ethylcellulose, ethylcellulose mixed with calcium carbonate, nitrocellulose, nitrocellulose mixed with calcium carbonate, or a so-called lip release coating composition of the type commonly employed for cigarette manufacture.
  • a plastic film e.g., a polypropylene film
  • a plug wrap material e.g., a polypropylene film
  • non-porous polypropylene materials that are available as ZNA-20 and ZNA-25 from Treofan Germany GmbH & Co. KG can be employed as plug wrap materials.
  • non-wrapped acetate filter segments may also be produced. Such segments are produced using the types of techniques generally set forth herein. However, rather than employing a plug wrap 152 that circumscribes the longitudinally extending periphery of the filter material, a somewhat rigid rod is provided, for example, by applying steam to the shaped plasticized fiber product 148. Techniques for commercially manufacturing non-wrapped acetate filter rods are possessed by Filtrona Corporation, Richmond, Virginia.
  • shaped, cut, and/or wrapped (or non-wrapped) filter elements 158 may be produced by the rod making operation(s) 150.
  • the system 100 may further conduct cigarette making operations 160.
  • the cigarette making operations 160 may include wrapping a supply of smokable material 162 with wrapping material 164 to form a smokable rod.
  • the smokable material 162 employed in manufacture of the smokable rod can vary.
  • the smokable material 162 can have the form of filler (e.g., such as tobacco cut filler).
  • filler e.g., such as tobacco cut filler
  • the terms "filler” or “cut filler” are meant to include tobacco materials and other smokable materials which have a form suitable for use in the manufacture of smokable rods.
  • filler can include smokable materials which are blended and are in a form ready for cigarette manufacturer.
  • the filler materials normally are employed in the form of strands or shreds as is common in conventional cigarette manufacture.
  • the cut filler material can be employed in the form of strands or shreds from sheet-like or "strip" materials which are cut into widths ranging from about 1/20 inch to about 1/60 inch, preferably from about 1/25 inch to about 1/35 inch.
  • strands or shreds have lengths which range from about 0.25 inch to about 3 inches.
  • suitable types of tobacco materials include flue-cured, Burley, Maryland or Oriental tobaccos, rare or specialty tobaccos, and blends thereof.
  • the tobacco material can be provided in the form of tobacco lamina; processed tobacco, processed tobacco stems such as cut-rolled or cut-puffed stems, reconstituted tobacco materials; or blends thereof.
  • the smokable material 162 or blend of smokable materials may consist essentially of tobacco filler material. Smokable materials 162 can also be cased and top dressed as is conventionally performed during various stages of cigarette manufacture.
  • the smokable rod has a length which ranges from about 35 mm to about 85 mm, preferably about 40 to about 70 mm; and a circumference of about 17 mm to about 27 mm, preferably about 22.5 mm to about 25 mm.
  • Short cigarette rods i.e., having lengths from about 35 to about 50 mm
  • the wrapping material 164 can vary, and typically is a cigarette wrapping material having a low air permeability value.
  • such wrapping materials 164 can have air permeabilities of less than about 5 CORESTA units.
  • Such wrapping materials 164 include a cellulosic base web (e.g., provided from wood pulp and/or flax fibers) and inorganic filler material (e.g., calcium carbonate and/or magnesium hydroxide particles).
  • a suitable wrapping material 164 is a cigarette paper consisting essentially of calcium carbonate and flax.
  • Particularly preferred wrapping materials 164 include an amount of a polymeric film forming agent sufficient to provide a desirably low air permeability.
  • Exemplary wrapping materials 164 are P-2540-80, P-2540-81, P-2540-82, P-2540-83, P-2540-84, and P-2831-102 available from Kimberly-Clark Corporation and TOD 03816, TOD 05504, TOD 05560 and TOD 05551 available from Ecusta Corporation.
  • the packing densities of the blend of smokable materials 162 contained within the wrapping materials 164 can vary. Typical packing densities for smokable rods may range from about 150 to about 300 mg/cm3. Normally, packing densities of the smokable rods range from about 200 to about 280 mg/cm3.
  • the cigarette making operations 160 may include attaching the filter element 158 to the smokable rod.
  • the filter element 158 and a portion of the smokable rod may be circumscribed by a tipping material 166 with an adhesive configured to bind to the filter element and the tobacco rod so as to couple the filter element to an end of the tobacco rod.
  • the tipping material 166 circumscribes the filter element 158 and an adjacent region of the smokable rod such that the tipping material extends about 3 mm to about 6 mm along the length of the smokable rod.
  • the tipping material 166 is a conventional paper tipping material.
  • the tipping material 166 can have a permeability which can vary.
  • the tipping material 166 can be essentially air impermeable, air permeable, or be treated (e.g., by mechanical or laser perforation techniques) so as to have a region of perforations, openings or vents thereby providing a means for providing air dilution to the cigarette.
  • the total surface area of the perforations and the positioning of the perforations along the periphery of the cigarette can be varied in order to control the performance characteristics of the cigarette.
  • cigarettes 168 may be produced in accordance with the above-described example embodiments, or under various other embodiments of systems and methods for producing cigarettes.
  • known manufacturing methods and apparatuses are conventionally configured to employ only a single filter tow as an input in the formation of the filter element.
  • FIG. 2 illustrates an example embodiment of a system 200 of operations configured to produce cigarettes or other smoking articles with operations performed by the system illustrated schematically.
  • the system 200 is configured to form a mixed fiber product from multiple fibers.
  • the mixed fiber may be employed in the formation of filter elements which may then be incorporated into cigarettes or other smoking articles.
  • the system 200 is illustrated as including sequential operations, the operations need not necessarily occur in the order shown. Further, the system may include fewer or a greater number of operations in some embodiments.
  • the system 200 may be configured to receive inputs of multiple fibers, which may be continuous in some embodiments.
  • the fibers may be processed by the system 200 to form filter elements.
  • a first fiber 208A and a second fiber 208B are received as inputs that are processed to form filter elements.
  • various other numbers of fibers may be employed in other embodiments, such as 2 to about 10 different fibers (e.g., 2, 3, 4, 5, 6, 7, 8, 9, or 10 different fibers).
  • the description appearing below generally describes specific numbers of fibers employed to form filter elements, it should be understood that this description is provided for exemplary purposes, and various other numbers of fibers may be employed in other embodiments.
  • the first fiber 208A may define one or more characteristics (referred to herein as the "first characteristic(s)") and the second fiber 208B may define one or more characteristics (referred to herein as the "second characteristic(s)").
  • first characteristic(s) the first characteristic
  • second characteristic(s) the second characteristic
  • One or more characteristics of the fibers 208A, 208B may be the same, or one or more of the characteristics may differ.
  • the fibers 208A, 208B may define various characteristics, as may be understood by one having skill in the art.
  • one characteristic is the form in which the fibers 208A, 208B are initially provided.
  • one or both of the fibers 208A, 208B may define a tow (i.e., a number of substantially parallel filaments).
  • one or both of the fibers 208A, 208B may define a yarn (i.e., a twisted bundle of filaments, which may or may not be continuous).
  • a yarn may be combined with a tow
  • a yarn may be combined with a yarn
  • a tow may be combined with a tow.
  • the material composition of the fibers 208A, 208B may also vary depending on the desired properties of the filter element which is produced from the fibers.
  • the two fibers 208A, 208B may include the same material composition, or different materials compositions.
  • one or both of the fibers 208A, 208B may comprise a cellulose ester (e.g., cellulose acetate) or polyolefin (e.g., polypropylene), or the like. While these material compositions are commonly used, one or both of the fibers 208A, 208B may alternatively or additionally define a different material composition than those described above. In this regard, certain material compositions may have properties that are desirable alone or in combination with fibers of differing material compositions.
  • the material compositions of the fibers 208A, 208B may be selected based on improved biodegradability, improved particulate filtration, and/or improved vapor absorption.
  • Vapor absorption refers to changing the chemical composition of mainstream smoke through physical or chemical sorption of gaseous components of mainstream smoke.
  • the fibers 208A, 208B can be characterized in certain embodiments as having different filtration properties or exhibiting different levels of biodegradability.
  • the overall level of biodegradability of the filter element can be adjusted to a desired level or the filtration efficiency with respect to specific solid or gaseous components of mainstream smoke can be adjusted as desired. Examples of combinations of fiber types exhibiting different filtration characteristics can be found, for example, in US Pat. Appl. No. 12/847,228 to Sebastian, filed July 30, 2010 .
  • At least one of the fibers 208A, 208B can be characterized as degradable.
  • One exemplary type of degradation is biodegradation.
  • biodegradable as used in reference to a degradable polymer refers to a polymer that degrades under aerobic and/or anaerobic conditions in the presence of bacteria, fungi, algae, and other microorganisms into carbon dioxide/methane, water and biomass, although materials containing heteroatoms can also yield other products such as ammonia or sulfur dioxide.
  • Biomass generally refers to the portion of the metabolized materials incorporated into the cellular structure of the organisms present or converted to humus fractions indistinguishable from material of biological origin.
  • Biodegradability can be measured, for example, by placing a sample in environmental conditions expected to lead to decomposition, such as placing a sample in water, a microbe-containing solution, a compost material, or soil.
  • the degree of degradation can be characterized by weight loss of the sample over a given period of exposure to the environmental conditions.
  • Exemplary rates of degradation for certain filter element embodiments of the invention include a weight loss of at least about 20% after burial in soil for 60 days or a weight loss of at least about 30% after 15 days of exposure to a typical municipal composter.
  • rates of biodegradation can vary widely depending on the type of degradable particles used, the remaining composition of the filter element, and the environmental conditions associated with the degradation test.
  • Additional examples of biodegradable materials include thermoplastic cellulose, available from Toray Industries, Inc. of Japan and described in US Pat. No. 6,984,631 to Aranishi et al.
  • thermoplastic polyesters such as Ecoflex® aliphatic-aromatic copolyester materials available from BASF Corporation or poly(ester urethane) polymers described in US Pat. No. 6,087,465 to Seppälä et al. , which is incorporated by reference herein in its entirety. Any of these biodegradable fibers can further include a cellulose acetate coating on the outer surface thereof.
  • Exemplary aliphatic polyesters advantageously used in the present invention have the structure -[C(O)-R-O] n -, wherein n is an integer representing the number of monomer units in the polymer chain and R is an aliphatic hydrocarbon, preferably a C1-C10 alkylene, more preferably a C1-C6 alkylene (e.g., methylene, ethylene, propylene, isopropylene, butylene, isobutylene, and the like), wherein the alkylene group can be a straight chain or branched.
  • R is an aliphatic hydrocarbon, preferably a C1-C10 alkylene, more preferably a C1-C6 alkylene (e.g., methylene, ethylene, propylene, isopropylene, butylene, isobutylene, and the like), wherein the alkylene group can be a straight chain or branched.
  • Exemplary aliphatic polyesters include polyglycolic acid (PGA), polylactic acid (PLA) (e.g., poly(L-lactic acid) or poly(DL-lactic acid)), polyhydroxyalkanoates (PHAs) such as polyhydroxypropionate, polyhydroxyvalerate, polyhydroxybutyrate, polyhydroxyhexanoate, and polyhydroxyoctanoate, polycaprolactone (PCL), polybutylene succinate adipate and copolymers thereof (e.g., polyhydroxybutyrate-co-hydroxyvalerate (PHBV)).
  • PGA polyglycolic acid
  • PLA polylactic acid
  • PHAs polyhydroxyalkanoates
  • PCL polycaprolactone
  • the fibers 208A, 208B can also be selected from carbon fibers, ion exchange fibers, and catalytic fibers.
  • Carbon fibers can be described as fibers obtained by the controlled pyrolysis of a precursor fiber.
  • Sources of carbon fibers include Toray Industries, Toho Tenax, Mitsubishi, Sumitomo Corporation, Hexcel Corp., Cytec Industries, Zoltek Companies, and SGL Group.
  • Exemplary commercially available carbon fibers include ACF-1603-15 and ACF-1603-20 available from American Kynol, Inc. Examples of starting materials, methods of preparing carbon-containing fibers, and types of carbon-containing fibers are disclosed in U.S. Patent Nos.
  • Ion exchange fibers are fibers capable of ion exchange with gas phase components of mainstream smoke from a smoking article. Such fibers are typically constructed by imbedding particles of an ion exchange material into the fiber structure or coating the fiber with an ion exchange resin. The amount of ion exchange material present in the fiber can vary, but is typically about 10 to about 50 percent by weight, based on the total weight of the ion exchange fiber, more often about 20 to about 40 percent by weight. Exemplary ion exchange fibers are described in US Patent Nos. 3,944,485 to Rembaum et al. and 6,706,361 to Economy et al , both of which are incorporated by reference herein. Ion exchange fibers are commercially available from Fiban of Belarus.
  • Catalytic fibers are fibers capable of catalyzing the reaction of one or more gas phase components of mainstream smoke, thereby reducing or eliminating the presence of the gas phase component in the smoke drawn through the filter element.
  • Exemplary catalytic fibers catalyze oxidation of one or more gaseous species present in mainstream smoke, such as carbon monoxide, nitrogen oxides, hydrogen cyanide, catechol, hydroquinone, or certain phenols.
  • the oxidation catalyst used in the invention is typically a catalytic metal compound (e.g., metal oxides such as iron oxides, copper oxide, zinc oxide, and cerium oxide) that oxidizes one or more gaseous species of mainstream smoke.
  • Exemplary catalytic metal compounds are described in US Pat. Nos.
  • Catalytic fibers can be constructed by, for example, imbedding particles of a catalytic material into the fiber structure or coating the fiber with a catalytic material, such as metal oxide particles.
  • the amount of catalytic material present in the fiber can vary, but is typically about 10 to about 50 percent by weight, based on the total weight of the ion exchange fiber, more often about 20 to about 40 percent by weight.
  • WO 1993/005868 also incorporated herein by reference, describes the use of catalytic fibers formed by coating a surface-treated hopcalite material, which is a material including both copper oxides and manganese oxides available from the North Carolina Center for Research located in Morrisville, North Carolina, onto a fibrous support.
  • cotton and/or regenerated cellulose having ion exchange groups introduced thereto may be employed, for example, as an ion-exchange fiber configured for vapor absorption.
  • polylactic acid and/or polyhydroxyalkanoate may be employed as one or more fibers for improved biodegradability.
  • Activated carbon fibers may also be employed for improved particle filtration and/or improved vapor absorption.
  • the fibers 208A, 208B may include any other fibers, which may be selected for improved biodegradability, improved particulate filtration, improved vapor absorption, and/or any other beneficial aspect associated with the fibers.
  • any other fibers which may be selected for improved biodegradability, improved particulate filtration, improved vapor absorption, and/or any other beneficial aspect associated with the fibers.
  • the first fiber 208A may comprise a cellulose ester such as cellulose acetate, or polyolefin
  • the second fiber 208B may comprise cotton, regenerated cellulose, polylactic acid, polyhydroxyalkanoate, activated carbon fibers, catalytic fibers, a cellulose ester such as cellulose acetate, polyolefin, and/or ion-exchange fibers.
  • cellulose acetate may be desirable (e.g., taste and filtration) while offering other functionality (e.g., improved biodegradability, improved particulate filtration, and/or improved vapor absorption).
  • the filaments defining the fibers 208A, 208B can vary in denier per filament (i.e., "dpf") and the total denier of the fibers 208A, 208B may also vary.
  • Denier per filament is a measurement of the weight per unit length of the individual filaments of the fibers 208A, 208B, and can be manipulated to achieve a desired pressure drop across the filter element produced from the fibers.
  • An exemplary dpf range for the filaments comprising the fibers 208A, 208B may be about 1.5 to about 8 where denier is expressed in units of grams / 9000 meters.
  • An exemplary range of total denier for the fibers 208A, 208B may be about 10,000 to about 50,000 (e.g., about 15,000 or about 40,000 total denier).
  • the denier per filament and/or the total denier may be the same or different for each of the fibers 208A, 208B.
  • Additional characteristics of the fibers 208A, 208B include the size and shape of the fibers and the filaments defining the fibers.
  • the sizes and shapes of the fibers 208A, 208B may be the same or different.
  • the fibers 208A, 208B may be provided in various overall cross-sectional shapes and/or the individual filaments defining the fibers may be provided in various cross-sectional shapes.
  • various overall sizes of the fibers 208A, 208B may be employed as well as various sizes of the individual filaments defining the fibers.
  • the first fiber 208A may define one or more cross-sectional areas that differ from, or are the same as, the cross-sectional areas of the second fiber 208B.
  • an overall cross-sectional area of the first fiber 208A may be the same as, or different from, the overall cross-sectional area of the second fiber 208B, and the cross-sectional areas of the individual filaments defining the first fiber may be the same as, or different from the cross-sectional areas of the individual filaments defining the second fiber.
  • Another characteristic of the fibers 208A, 208B is that of the finish applied thereto.
  • the same finish or a different finish may be applied to the fibers.
  • An additional characteristic of the fibers 208A, 208b that may be the same or different is that of the melting point thereof. Accordingly, one or more of the above-described characteristics and/or various other characteristics of the fibers 208A, 208B may be the same or different.
  • the fibers 208A, 208B may be subjected to texturing at operation 215.
  • Texturing refers to combining fibers in a texturing apparatus such that the fibers are at least partially entangled with one another. More particularly, texturing refers to applying mechanical force to fibers to entangle the fibers. For example, the mechanical force may be applied to the fibers through directing a fluid such as air at the fibers in order to entangle the fibers.
  • the texturing operation 215 at least partially entangles the first fiber 208A with the second fiber 208B to create a mixed fiber product 238.
  • the mixed fiber product 238 may define the characteristics of both of all of the fibers 208A, 208B that are combined to form the mixed fiber product.
  • FIG. 3 An example embodiment of a texturing apparatus 312, which may perform texturing operations is illustrated as part of a system for forming cigarettes 300 in FIG. 3 (with apparatuses forming the system illustrated schematically).
  • the texturing apparatus 312 is configured to receive four fibers 308A-D, although various other numbers of fibers may be employed in other embodiments.
  • the texturing apparatus 312 may receive the fibers 308A-D from a creel 314.
  • the creel 314 may include a plurality of bobbins 308A'-D', which respectively hold and supply the fibers 308A-D to the texturing apparatus 312.
  • the fibers 308A-D may be received in the form of a yarn, tow, individual filaments, or other form as may be understood.
  • the texturing apparatus 312 may be configured to receive the fibers 308A-D and combine the fibers such that the fibers are at least partially entangled with each other in order to form a mixed fiber product 338.
  • the texturing apparatus 312 may employ a variety of operations to entangle the fibers 308A-D.
  • texturing may involve applying mechanical force to the fibers 308A-D in order to entangle the fibers.
  • the texturing apparatus 312 may be configured to direct at least one flow of fluid at the fibers 308A-D in order to combine the fibers.
  • the flow of fluid may comprise a flow of air that is directed by one or more jets (e.g., nozzles) at the fibers 308A-D.
  • the texturing apparatus 312 may entangle the fibers 308A-D.
  • the texturing apparatus 312 may false twist the fibers 308A-D in order to combine the fibers. False twisting of the fibers 308A-D may involve twisting the fibers together, thermosetting the twisted fibers, and drawing (i.e., stretching) the fibers in one example embodiment.
  • An exemplary embodiment of a texturing apparatus suitable for use in the present invention is the AIRTEXTM jet texturing machine manufactured by TECHNISERVICE®, Inc. of Kennett Square, Pennsylvania.
  • the texturing apparatus 312 may be employed to produce a mixed fiber product 338 directly from the fibers 308A-D.
  • the total sum of the deniers of the fibers 308A-D received by the texturing apparatus 312 may be selected to be equal to a desired denier of the mixed fiber product 338.
  • the creel 314 may include enough bobbins 308A'-D' to accommodate fibers 308A-D defining a total denier equal to a desired denier of the mixed fiber product 338.
  • an intermediate texturing apparatus may be employed in the formation of the mixed fiber product 338.
  • intermediate fibers may be provided and then combined in an intermediate texturing apparatus such that the intermediate fibers are at least partially entangled with each other.
  • the intermediate fibers may be combined to form one of the fibers 308A-D that may then be combined to form the mixed fiber product.
  • the creel 314 may include fewer bobbins 308A'-D'.
  • the texturing apparatus 312 may function as the intermediate texturing apparatus that forms the intermediate fibers and also as the texturing apparatus that forms the final mixed fiber product 338.
  • the texturing apparatus 312 may first combine the intermediate fibers to form one or more of the fibers 308A-D, and then the texturing apparatus may combine the fibers 308A-D to form the mixed fiber product 338.
  • one of the fibers 308A-D may be stored after formation from the intermediate fibers, and then once all of the fibers 308A-D are formed, they may be combined by the same texturing apparatus to form the mixed fiber product 338.
  • one or more separate intermediate texturing apparatuses may be employed to form the fibers 308A-D, or the creel 314 may be configured to supply fibers having a total denier equal to a desired denier of the mixed fiber product 338. Accordingly, the desired denier of the mixed fiber product 338 may be achieved in a variety of manners using one or more texturing apparatuses.
  • a mixed fiber product may be produced by a texturing apparatus as described above.
  • a mixed fiber product 238 resulting from the above-described texturing operations 215 may be subjected to plasticizer application at operation 240.
  • the plasticizer 242 may be applied to the mixed fiber product 238 by a traditional plasticizer apparatus as described above.
  • the system 200 illustrated in FIG. 2 may differ from existing embodiments of systems configured to manufacture cigarettes in that the separation operations (e.g., tow opening, crimp removal, and blooming) may not be necessary.
  • the texturing apparatus may combine the fibers 208A, 208B in the manner described above such that the fibers are entangled (so as to provide a substantially evenly mixed distribution of the fibers) and sufficiently separated such that the plasticizer 242 may penetrate the mixed fiber product 238.
  • embodiments of the system 200 employing texturing operations 215 performed by a texturing apparatus may provide benefits both in terms of allowing for combination of multiple fibers 208A, 208B, and in terms of reducing the number of operations required to produce the filter elements.
  • the operations performed after production of the mixed fiber product 238 may be substantially the same as those performed in traditional systems for producing smoking articles.
  • existing cigarette production equipment may be utilized.
  • the plasticized fiber product 248 may be subjected to one or more rod making operations 250 in which the plasticized fiber product is wrapped with a plug wrap 252.
  • the filter element 258 may be employed in one or more cigarette making operations 260.
  • smokable material 262 may be wrapped with wrapping material 264 to form a smokable rod, and the filter element 258 and the smokable rod may be coupled to the filter element via wrapping thereof with tipping material 266 to form cigarettes 268 or other smokable articles.
  • the above-described system 200 may employ a texturing apparatus to combine two or more fibers 208A, 208B while avoiding the need for separation operations (e.g., tow opening, crimp removal, and blooming) since the mixed fiber product 238 produced by the texturing apparatus may resemble bloomed tow.
  • the system for forming cigarettes 300 may also include other apparatuses and components that correspond with the operations discussed above in relation to FIG. 2 .
  • the mixed fiber product 338 exiting the texturing apparatus 312 may enter a plasticizer apparatus 340 in which plasticizer 342 is applied to the mixed fiber product.
  • the system 300 may further include a rod maker 350 that receives the plasticized fiber product 348 and wraps it with a plug wrap 352 to form a filter element 358.
  • the system 300 may include a cigarette maker 360 that attaches a smokable rod formed from smokable material 362 wrapped with wrapping material 364 to the filter element 358 with tipping material 366.
  • the system for forming cigarettes 300 may include various apparatuses that perform the operations described above with respect to FIG. 2 to form cigarettes 368.
  • the systems 200, 300 may include a heater 390 configured to conduct a heating operation 290.
  • the heating operation may be conducted on the mixed fiber product 238', 338' before or after it is formed into the filter element 258', 358'.
  • the systems 200, 300 may not include a plasticizer apparatus 340 or a corresponding plasticizer application operation 240.
  • the mixed fiber product 238', 338' may be directed to the rod maker 350 and subjected to rod making operations 250 and then heated without first being subjected to plasticizer application 240 by a plasticizer apparatus 340.
  • a first portion of the mixed fiber product 238', 338' may define a melting point (e.g., the "first melting point") that is less than a melting point of a second portion of the mixed fiber product 238', 338' (e.g., the "second melting point”).
  • the first portion with the first, lower melting point may comprise polyethylene, polypropylene, polylactic acid, ethylene vinyl acetate, or other material composition configured to have a lower melting point than the second portion.
  • the first melting point may be from about 100°C to about 150°C, and preferably about 120°C, with the second portion having a melting from about 160°C to about 260°C, and preferably about 170°C.
  • the melting point of the first portion may be configured to be from about 25°C to about 100°C less than the melting point of the second portion, and preferably about 50°C less than the melting point of the second portion, so as to enable melting the first portion without melting the second portion.
  • the first portion may comprise from about 5% to about 40%, and preferably about 25% of the total mass or volume of the mixed fiber product 238', 338'.
  • the first portion may be employed to bind the mixed fiber product 238', 338' together and/or bind the mixed fiber product to the plug wrap 252, 352.
  • the filter element 258', 358' may need to allow flow therethrough. Accordingly, the percentage of the mixed fiber product 238', 338'that is melted may be limited so as to allow for flow therethrough without unduly increasing the pressure drop associated therewith.
  • a first fiber may define the first portion with the first melting point
  • a second fiber may define the second portion with the second melting point. Accordingly, when the first fiber and the second fiber are entangled, formed into a mixed fiber product 238', 338', wrapped with a plug wrap 252, 352 to form a filter element 258', 358' and directed through the heater 390 and subjected to heating at operation 290, the first fiber may at least partially melt to bind the first fiber to the second fiber and/or to the plug wrap. As illustrated in FIGS. 2 and 3 , the heater 390 may conduct the heating operation 290 after the rod maker 350 conducts the rod making operation 250 in which the mixed fiber product 238', 338' is wrapped with the plug wrap 252, 352.
  • heating may be conducted prior to wrapping the mixed fiber product with a plug wrap.
  • the systems 200, 300 are illustrated as bypassing the plasticizer application operation 240 by the plasticizer apparatus 340, in some embodiments the plasticizer may also be applied to the mixed fiber product, in addition to conducting the heating operation 290 with the heater 390.
  • the fibers may define differing melting points.
  • one or more of the fibers may define both the first portion with the first melting point and at least part of the second portion with the second melting point.
  • FIG. 4 illustrates an embodiment in which a first fiber 208A defines a first section 208A' and a second section 208A", with one of the sections defining a lower melting point than the other section.
  • the first section 208A' may define the first melting point, which is lower than the melting point of the second section 208A".
  • the heater 390 may subject the mixed fiber product 238', 338' (e.g., embodied as the filter element 258', 358') to a heating operation 290 that heats the fibers to a temperature that is great than the first melting point of the first section 208A' of the first fiber 208A, but lower than the melting point of the second section 208A" of the first fiber.
  • a second fiber 208B may also have a melting point that is higher than the melting point of the first section 208A' of the first fiber 208A. Accordingly, the first section 208A' of the first fiber 208A may be melted without melting the second section 208A" of the first fiber or the second fiber 208B.
  • the first section 208A' of the first fiber 208A may define a sheath that surrounds a core defined by the second section 208A".
  • the heater 390 and the corresponding heating operation 290 may comprise a variety of configurations.
  • the heater 390 may comprise a conventional oven, an infrared heater, a microwave, or any other apparatus configured to impart heat to the fibers to melt a portion thereof.
  • the use of microwave heating may provide shorter melting times and more efficient heating through the application of microwave energy tuned to the most efficient absorption frequencies for the fiber (or the section of the fiber) that is configured to melt. Microwave energy heating is independent of the thermal conductivity of the material being heated.
  • the fiber (or the section of the fiber) that is configured to melt may be formulated with a polar additive, such as a salt material, to enhance the heating effect derived from the microwave energy.
  • a polar additive such as a salt material
  • Exemplary microwave heating systems are available from Lambda Technologies of Morrisville, NC. Microwave heating systems are also described in US Pat. Appl. Pub. No. 2007/0284034 to Fathi et al. , which is incorporated by reference herein.
  • variable frequency microwaves and/or other heaters may be employed to heat the filter fibers and produce a melted filter element 292, 392 in some embodiments.
  • FIG. 5 illustrates an example embodiment of a method for forming a cigarette filter element.
  • the method may include providing a first fiber defining a characteristic at operation 400, providing a second fiber defining a second characteristic at operation 402, combining the first fiber and the second fiber in a texturing apparatus such that the first fiber is at least partially entangled with the second fiber to form a mixed fiber product at operation 404, and at least partially enclosing the mixed fiber product in a plug wrap at operation 405.
  • the first characteristic of the first fiber may differ from the second characteristic of the second fiber, whereas in other embodiments the characteristics may be the same.
  • the method may further include providing a first intermediate fiber at operation 406, providing a second intermediate fiber at operation 408, and combining the first intermediate fiber and the second intermediate fiber in an intermediate texturing apparatus such that the first intermediate fiber is at least partially entangled with the second intermediate fiber to form the first fiber at operation 410.
  • the second fiber may be formed in the same manner or a similar manner.
  • combining the first fiber and the second fiber in a texturing apparatus at operation 404 may comprise false twisting the first fiber and the second fiber at operation 412. Additionally, combining the first fiber and the second fiber in a texturing apparatus at operation 404 may comprise directing at least one flow of fluid at the first fiber and the second fiber at operation 414. Also, directing the flow of fluid at the first fiber and the second fiber at operation 414 may comprise directing a flow of air at the first fiber and the second fiber at operation 416. For example, false twisting may employ directing an air jet at the fibers. The method may also include applying a plasticizer to the mixed fiber product to form a plasticized fiber product at operation 417.
  • a first portion of the mixed fiber product may define a first melting point that is less than a second melting point of a second portion of the mixed fiber product.
  • the method may also include heating the mixed fiber product to a temperature that is greater than or equal to the first melting point and less than the second melting point at operation 418.
  • Cigarette making operations 160, 260 described above may be conducted using a conventional automated cigarette rod making machine.
  • Exemplary cigarette rod making machines are of the type commercially available from Molins PLC or Hauni-Werke Korber & Co. KG.
  • cigarette rod making machines of the type known as MkX (commercially available from Molins PLC) or PROTOS (commercially available from Hauni-Werke Korber & Co. KG) can be employed.
  • a description of a PROTOS cigarette making machine is provided in US Patent No. 4,474,190 to Brand , at col. 5, line 48 through col. 8, line 3, which is incorporated herein by reference. Types of equipment suitable for the manufacture of cigarettes also are set forth in US Pat. Nos.
  • Filter elements produced in accordance with this disclosure may be incorporated within conventional cigarettes configured for combustion of a smokable material, and also within the types of cigarettes set forth in US Pat. Nos. 4,756,318 to Clearman et al. ; 4,714,082 to Banerjee et al. ; 4,771,795 to White et al. ; 4,793,365 to Sensabaugh et al. ; 4,989,619 to Clearman et al. ; 4,917,128 to Clearman et al. ; 4,961,438 to Korte ; 4,966,171 to Serrano et al. ; 4,969,476 to Bale et al.
  • filter elements produced in accordance with the description provided above may be incorporated within the types of cigarettes that have been commercially marketed under the brand names " Premier” and "Eclipse” by R. J. Reynolds Tobacco Company .
  • FIG. 6 illustrates an exploded view of a smoking article in the form of a cigarette 600 that may be produced by the apparatuses, systems, and methods disclosed herein.
  • the cigarette 600 includes a generally cylindrical rod 612 of a charge or roll of smokable filler material contained in a circumscribing wrapping material 616.
  • the rod 612 is conventionally referred to as a "tobacco rod.”
  • the ends of the tobacco rod 612 are open to expose the smokable filler material.
  • the cigarette 600 is shown as having one optional band 622 (e.g., a printed coating including a film-forming agent, such as starch, ethylcellulose, or sodium alginate) applied to the wrapping material 616, and that band circumscribes the cigarette rod 612 in a direction transverse to the longitudinal axis of the cigarette 600. That is, the band 622 provides a cross-directional region relative to the longitudinal axis of the cigarette 600.
  • the band 622 can be printed on the inner surface of the wrapping material 616 (i.e., facing the smokable filler material), or less preferably, on the outer surface of the wrapping material.
  • the cigarette can possess a wrapping material having one optional band, the cigarette also can possess wrapping material having further optional spaced bands numbering two, three, or more.
  • the plasticized and/or melted fiber product 626 may be produced by the apparatuses, systems, and methods disclosed herein.
  • the plasticized and/or melted fiber product 626 may comprise an embodiment of the above-described mixed fiber product comprising a first fiber defining a first characteristic and a second fiber defining a second characteristic to which a plasticizer has been applied and/or a portion of the mixed fiber product has been melted.
  • the plasticized and/or melted fiber product 626 may be produced by a texturing operation conducted by a texturing apparatus and plasticizer application operation performed by a plasticizer apparatus and/or a heating operation performed by a heater.
  • the plasticized and/or melted fiber product 626 may have a generally cylindrical shape, and the diameter thereof may be essentially equal to the diameter of the tobacco rod 612.
  • the plasticized and/or melted fiber product 626 is circumscribed along its outer circumference or longitudinal periphery by a layer of outer plug wrap 628 to form a filter element.
  • the filter element is positioned adjacent one end of the tobacco rod 612 such that the filter element and tobacco rod are axially aligned in an end-to-end relationship, preferably abutting one another. The ends of the filter element permit the passage of air and smoke therethrough.
  • a ventilated or air diluted smoking article can be provided with an optional air dilution means, such as a series of perforations 630, each of which extend through the tipping material 640 and plug wrap 628.
  • the optional perforations 630 can be made by various techniques known to those of ordinary skill in the art, such as laser perforation techniques. Alternatively, so-called off-line air dilution techniques can be used (e.g., through the use of porous paper plug wrap and pre-perforated tipping material). For cigarettes that are air diluted or ventilated, the amount or degree of air dilution or ventilation can vary.
  • the amount of air dilution for an air diluted cigarette is greater than about 10 percent, generally is greater than about 20 percent, often is greater than about 30 percent, and sometimes is greater than about 40 percent.
  • the upper level for air dilution for an air diluted cigarette is less than about 80 percent, and often is less than about 70 percent.
  • air dilution is the ratio (expressed as a percentage) of the volume of air drawn through the air dilution means to the total volume and air and smoke drawn through the cigarette and exiting the extreme mouth end portion of the cigarette.
  • the plasticized and/or melted fiber product 626 may be attached to the tobacco rod 612 using the tipping material 640 (e.g., essentially air impermeable tipping material), that circumscribes both the entire length of the filter element and an adjacent region of the tobacco rod 612.
  • the inner surface of the tipping material 640 is fixedly secured to the outer surface of the plug wrap 628 and the outer surface of the wrapping material 616 of the tobacco rod, using a suitable adhesive; and hence, the filter element and the tobacco rod are connected to one another to form the cigarette 600.
  • the automated cigarette making machines of the type set forth herein provide a formed continuous cigarette rod (or other smokable rod) that can be subdivided into formed smokable rods of desired lengths.
  • a method for forming a cigarette filter element comprising:
  • the method which is related to the first embodiment, wherein prior to combining the first fiber and the second fiber in the texturing apparatus, the first fiber defines a tow and the second fiber defines a second tow.
  • the method which is related to the first embodiment, wherein prior to combining the first fiber and the second fiber in the texturing apparatus, the first fiber defines a tow and the second fiber defines a yarn.
  • the method which is related to the first embodiment, further comprising:
  • combining the first fiber and the second fiber in the texturing apparatus comprises directing at least one flow of fluid at the first fiber and the second fiber.
  • directing the flow of fluid at the first fiber and the second fiber comprises directing a flow of air at the first fiber and the second fiber.
  • combining the first fiber and the second fiber in the texturing apparatus comprises false twisting the first fiber and the second fiber.
  • the method which is related to any one of the first to fourth embodiment, further comprising applying a plasticizer to the mixed fiber product.
  • a ninth embodiment it is provided the method, which is related to any one of the first to fourth embodiment, wherein a first portion of the mixed fiber product defines a first melting point that is less than a second melting point of a second portion of the mixed fiber product.
  • the method which is related to the ninth embodiment, further comprising heating the mixed fiber product to a temperature that is greater than or equal to the first melting point and less than the second melting point.
  • the method which is related to any one of the first to fourth embodiment, wherein the difference between the first characteristic and the second characteristic relates to a difference in a finish of the first and second fiber, a difference in material composition of the first and second fiber, a difference in total denier or denier per filament of the first and second fiber, or a difference in size or shape of the first fiber and second fiber.
  • the method which is related to any one of the first to fourth embodiment, wherein the first fiber and the second fiber have a different material composition such that the first fiber and second fiber have different filtration properties or different levels of biodegradability.
  • a system configured to perform the method, which is related to any one of the first to fourth embodiment, the system comprising a texturing apparatus configured to receive the first and second fibers and combine the first and second fibers into the mixed fiber product; and a rod maker configured to receive and wrap the mixed fiber product with the plug wrap to form the filter element.
  • the system which is related to the thirteenth embodiment, further comprising a cigarette maker configured to:
  • the system which is related to the thirteenth embodiment, further comprising a plasticizer apparatus configured to apply a plasticizer to the mixed fiber product.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Nonwoven Fabrics (AREA)
EP18200346.7A 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren, systeme sowie vorrichtungen Pending EP3456212A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/241,399 US10064429B2 (en) 2011-09-23 2011-09-23 Mixed fiber product for use in the manufacture of cigarette filter elements and related methods, systems, and apparatuses
EP12775086.7A EP2757910B1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren
PCT/US2012/056232 WO2013043806A2 (en) 2011-09-23 2012-09-20 Mixed fiber product for use in the manufacture of cigarette filter elements and related methods, systems, and apparatuses

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP12775086.7A Division-Into EP2757910B1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren
EP12775086.7A Division EP2757910B1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren

Publications (1)

Publication Number Publication Date
EP3456212A1 true EP3456212A1 (de) 2019-03-20

Family

ID=47045155

Family Applications (2)

Application Number Title Priority Date Filing Date
EP18200346.7A Pending EP3456212A1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren, systeme sowie vorrichtungen
EP12775086.7A Active EP2757910B1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP12775086.7A Active EP2757910B1 (de) 2011-09-23 2012-09-20 Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren

Country Status (8)

Country Link
US (1) US10064429B2 (de)
EP (2) EP3456212A1 (de)
JP (1) JP6240608B2 (de)
CN (2) CN103929986B (de)
DK (1) DK2757910T3 (de)
PL (1) PL2757910T3 (de)
TR (1) TR201901463T4 (de)
WO (1) WO2013043806A2 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201400990D0 (en) * 2014-01-21 2014-03-05 British American Tobacco Co Filter materials and filters made therefrom
CN104256891B (zh) * 2014-08-11 2017-12-01 浙江中烟工业有限责任公司 一种具有o型截面的降焦卷烟滤棒用混合单旦丝束及其制备方法和应用
US20160073686A1 (en) 2014-09-12 2016-03-17 R.J. Reynolds Tobacco Company Tobacco-derived filter element
GB201420733D0 (en) * 2014-11-21 2015-01-07 British American Tobacco Co Apparatus and method for filter manufacture
US10524500B2 (en) 2016-06-10 2020-01-07 R.J. Reynolds Tobacco Company Staple fiber blend for use in the manufacture of cigarette filter elements
MX2019012141A (es) * 2017-04-14 2019-12-09 Philip Morris Products Sa Componente de filtro.
KR101976325B1 (ko) * 2018-07-06 2019-05-07 주식회사 케이티앤지 연기 성분 저감 담배 필터, 담배, 그리고 그 제조 방법
BR112021001407A2 (pt) * 2018-08-03 2021-04-27 Philip Morris Products S.A. mecanismo de embalagem reconfigurável
GB201919104D0 (en) * 2019-12-20 2020-02-05 Nicoventures Trading Ltd An article for use in a non-combustible aerosol provision system

Citations (168)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB757283A (en) * 1953-10-07 1956-09-19 Lorillard Co P Improvements in tobacco smoke filters
US2881770A (en) 1954-05-27 1959-04-14 Eastman Kodak Co Fibrous tobacco smoke filters
US3101723A (en) 1960-11-15 1963-08-27 Philip Morris Inc Fibrous cigarette filter
US3236244A (en) 1961-09-19 1966-02-22 American Tobacco Co Tobacco smoke filter element
US3253396A (en) 1959-06-01 1966-05-31 Beaunit Corp Method and apparatus for making textured yarn and product
US3288147A (en) 1959-06-03 1966-11-29 Molins Machine Co Ltd Tobacco-manipulating machines
US3311519A (en) 1964-01-28 1967-03-28 Eastman Kodak Co Additive filter
US3313306A (en) 1965-10-22 1967-04-11 American Filtrona Corp Stable elongated elements and smoking means incorporating the same
US3319629A (en) 1965-05-20 1967-05-16 American Cyanamid Co Filter cigarette
US3328863A (en) 1966-04-29 1967-07-04 Owens Corning Fiberglass Corp Yarn texturizing jet
US3347247A (en) 1964-05-14 1967-10-17 Philip Morris Inc Tobacco smoke filter
US3349780A (en) 1964-11-04 1967-10-31 Eastman Kodak Co Acetate filter elements containing carbon
US3370595A (en) 1965-01-04 1968-02-27 Celanese Corp Smoke filters
US3381346A (en) 1967-06-20 1968-05-07 Owens Corning Fiberglass Corp Fluid nozzle for texturing yarns
US3413982A (en) 1965-08-04 1968-12-03 Eastman Kodak Co Tobacco smoke filter employing ethylene copolymer bonding material
US3424172A (en) 1965-05-14 1969-01-28 Georg Neurath Cigarette filters
US3551256A (en) 1963-11-21 1970-12-29 Celanese Corp Apparatus for making a multi-segmented filter
US3553953A (en) 1968-09-03 1971-01-12 Monsanto Co Bulked bonded yarn
US3602231A (en) 1969-12-12 1971-08-31 H 2 D Filter Corp The Means for audible detection of the activation of a filter for smoking devices
US3844200A (en) 1973-05-07 1974-10-29 Brown & Williamson Tobacco Continuous manufacture of a multiple filter rod having spaced pockets containing particulate material
US3904577A (en) 1971-08-12 1975-09-09 Rhone Poulenc Textile Textile articles for protective clothing
US3915176A (en) 1972-07-05 1975-10-28 Hauni Werke Koerber & Co Kg Apparatus for wrapping filler rods of tobacco or the like
GB1420655A (en) * 1972-09-27 1976-01-07 Rothmans Of Pall Mall Austrial Tobacco smoke filter
US3944485A (en) 1973-05-23 1976-03-16 California Institute Of Technology Ion-exchange hollow fibers
US3972335A (en) 1972-09-20 1976-08-03 Calgon Corporation Mentholated cigarette filter
US4016830A (en) 1975-07-16 1977-04-12 Brown & Williamson Tobacco Corporation Apparatus for dispensing spaced deposits of particulate material
US4068358A (en) 1975-06-18 1978-01-17 Berliner Maschinenbau-Ag Vormals L. Schwartzkopff Machine for air-jet texturizing of continuous synthetic filaments
US4125922A (en) 1977-09-22 1978-11-21 Techniservice Division, Textured Yarn Co. Inc. Jet tangler
US4174719A (en) 1977-06-29 1979-11-20 Olin Corporation Microperforated filter tip cigarette
US4182348A (en) 1977-09-06 1980-01-08 B.A.T. Cigaretten-Fabriken Gmbh Removal of nitric oxide and carbon monoxide from tobacco smoke
US4214508A (en) 1977-10-13 1980-07-29 Philip Morris Incorporated Method and apparatus for making cigarette filters of filamentary material
US4281671A (en) 1978-04-21 1981-08-04 American Filtrona Corporation Production of tobacco smoke filters
US4291713A (en) 1977-01-27 1981-09-29 Hauni-Werke Korber & Co. Kg Device for heating the seams of wrappers for rod-like fillers in cigarette making machines or the like
US4317460A (en) 1978-01-20 1982-03-02 Gallaher Limited Smoking products
US4338776A (en) 1977-11-08 1982-07-13 Barmag Barmer Maschinenfabrik Aktiengesellschaft Process for the production of a crimped continuous multifilament yarn
US4411640A (en) 1981-01-08 1983-10-25 Liggett Group Inc. Apparatus for the production of cigarette filter tips having multi-sectional construction
US4425107A (en) 1981-07-22 1984-01-10 Liggett Group Inc. Rotatable dispensing wheel
US4474190A (en) 1981-03-21 1984-10-02 Hauni-Werke Korber & Co. Kg Method and apparatus for regulating the operation of machines for the production of cigarettes or the like
US4559772A (en) 1982-02-13 1985-12-24 Hoechst Aktiengesellschaft False twist texturized yarn, and a process for its preparation
US4574816A (en) 1983-02-04 1986-03-11 Hauni-Werke Korber & Co. Kg Method and apparatus for forming a filler of fibrous material
US4714082A (en) 1984-09-14 1987-12-22 R. J. Reynolds Tobacco Company Smoking article
US4736754A (en) 1983-10-12 1988-04-12 Hauni-Werke Korber & Co. K.G. Method and apparatus for making rod-shaped smokers' products with soft cores
US4756318A (en) 1985-10-28 1988-07-12 R. J. Reynolds Tobacco Company Smoking article with tobacco jacket
US4771795A (en) 1986-05-15 1988-09-20 R. J. Reynolds Tobacco Company Smoking article with dual burn rate fuel element
US4781203A (en) 1985-05-15 1988-11-01 Hue Paul D Method and apparatus for making self-extinguishing cigarette
US4811745A (en) 1988-02-04 1989-03-14 Hercules Incorporated Method and device for control of by-products from cigarette smoke
US4844100A (en) 1986-09-13 1989-07-04 Korber Ag Method of and apparatus for making rod-shaped smokers' articles with dense ends
US4876078A (en) 1984-04-20 1989-10-24 Nikkiso Co., Ltd. Process for preparing carbon fibers in gas phase growth
US4878506A (en) 1987-07-31 1989-11-07 Korber Ag Method of and apparatus for treating accumulations of fibers of tobacco or other smokable material
US4917128A (en) 1985-10-28 1990-04-17 R. J. Reynolds Tobacco Co. Cigarette
US4925602A (en) 1988-08-10 1990-05-15 Filter Materials Limited Method for improving the crimping of polyolefin filter tow
US4947874A (en) 1988-09-08 1990-08-14 R. J. Reynolds Tobacco Company Smoking articles utilizing electrical energy
US4956330A (en) 1989-06-19 1990-09-11 Phillips Petroleum Company Catalyst composition for the oxidation of carbon monoxide
US4961438A (en) 1989-04-03 1990-10-09 Brown & Williamson Tobacco Corporation Smoking device
US4966171A (en) 1988-07-22 1990-10-30 Philip Morris Incorporated Smoking article
US4969476A (en) 1986-09-19 1990-11-13 Imperial Tobacco Limited Smoking article
US4989619A (en) 1985-08-26 1991-02-05 R. J. Reynolds Tobacco Company Smoking article with improved fuel element
US4991606A (en) 1988-07-22 1991-02-12 Philip Morris Incorporated Smoking article
US5012823A (en) 1984-08-03 1991-05-07 Philip Morris Incorporated Tobacco processing
US5020548A (en) 1985-08-26 1991-06-04 R. J. Reynolds Tobacco Company Smoking article with improved fuel element
US5027836A (en) 1984-12-21 1991-07-02 R. J. Reynolds Tobacco Company Insulated smoking article
US5033483A (en) 1985-10-28 1991-07-23 R. J. Reynolds Tobacco Company Smoking article with tobacco jacket
US5040551A (en) 1988-11-01 1991-08-20 Catalytica, Inc. Optimizing the oxidation of carbon monoxide
US5050621A (en) 1988-08-12 1991-09-24 British-American Tobacco Company Limited Smoking articles
US5052413A (en) 1987-02-27 1991-10-01 R. J. Reynolds Tobacco Company Method for making a smoking article and components for use therein
US5060665A (en) 1990-03-05 1991-10-29 Korber Ag Wrapping mechanism for rod making machines of the tobacco processing industry
US5065776A (en) 1990-08-29 1991-11-19 R. J. Reynolds Tobacco Company Cigarette with tobacco/glass fuel wrapper
US5076296A (en) 1988-07-22 1991-12-31 Philip Morris Incorporated Carbon heat source
US5076297A (en) 1986-03-14 1991-12-31 R. J. Reynolds Tobacco Company Method for preparing carbon fuel for smoking articles and product produced thereby
US5099861A (en) 1990-02-27 1992-03-31 R. J. Reynolds Tobacco Company Aerosol delivery article
US5105835A (en) 1989-01-25 1992-04-21 Imperial Tobacco, Ltd. Smoking articles
US5105837A (en) 1990-08-28 1992-04-21 R. J. Reynolds Tobacco Company Smoking article with improved wrapper
US5115820A (en) 1989-03-28 1992-05-26 B.A.T. Cigarettenfabriken Gmbh Smokable article
US5131416A (en) 1990-12-17 1992-07-21 R. J. Reynolds Tobacco Company Cigarette
US5148821A (en) 1990-08-17 1992-09-22 R. J. Reynolds Tobacco Company Processes for producing a smokable and/or combustible tobacco material
US5156169A (en) 1990-11-06 1992-10-20 R. J. Reynolds Tobacco Company Apparatus for making cigarettes
US5159940A (en) 1988-07-22 1992-11-03 Philip Morris Incorporated Smoking article
US5178167A (en) 1991-06-28 1993-01-12 R. J. Reynolds Tobacco Company Carbonaceous composition for fuel elements of smoking articles and method of modifying the burning characteristics thereof
US5183062A (en) 1990-02-27 1993-02-02 R. J. Reynolds Tobacco Company Cigarette
US5191906A (en) 1990-10-30 1993-03-09 Philip Morris Incorporated Process for making wrappers for smoking articles which modify the burn rate of the smoking article
WO1993005868A1 (en) 1991-09-27 1993-04-01 North Carolina Center For Scientific Research, Inc. Coated fibrous filter for catalytic cracking
US5211684A (en) 1989-01-10 1993-05-18 R. J. Reynolds Tobacco Company Catalyst containing smoking articles for reducing carbon monoxide
US5225277A (en) 1989-11-17 1993-07-06 Daicel Chemical Industries, Ltd. Acetate tow having high crimp modulus and manufacturing method thereof
US5230960A (en) 1990-01-12 1993-07-27 Gun Ei Chemical Industry Co., Ltd. Activated carbon fiber structure and process for producing the same
US5240016A (en) 1991-04-19 1993-08-31 Philip Morris Incorporated Thermally releasable gel-based flavor source for smoking articles
US5240014A (en) 1990-07-20 1993-08-31 Philip Morris Incorporated Catalytic conversion of carbon monoxide from carbonaceous heat sources
US5258340A (en) 1991-02-15 1993-11-02 Philip Morris Incorporated Mixed transition metal oxide catalysts for conversion of carbon monoxide and method for producing the catalysts
US5268158A (en) 1987-03-11 1993-12-07 Hercules Incorporated High modulus pan-based carbon fiber
US5271419A (en) 1989-09-29 1993-12-21 R. J. Reynolds Tobacco Company Cigarette
US5322495A (en) 1992-04-27 1994-06-21 Philip Morris Incorporated High speed vacuum assisted free flowing material inserter in filter rod manufacture
US5338605A (en) 1990-01-31 1994-08-16 Ketema, Inc. Hollow carbon fibers
US5345955A (en) 1992-09-17 1994-09-13 R. J. Reynolds Tobacco Company Composite fuel element for smoking articles
US5360023A (en) 1988-05-16 1994-11-01 R. J. Reynolds Tobacco Company Cigarette filter
US5387285A (en) 1992-06-02 1995-02-07 R. J. Reynolds Tobacco Company Apparatus for injecting a fluid into filter tow
US5396911A (en) 1990-08-15 1995-03-14 R. J. Reynolds Tobacco Company Substrate material for smoking articles
US5446005A (en) 1992-06-25 1995-08-29 Endo; Morinobu Pitch-based activated carbon fiber
US5482773A (en) 1991-07-01 1996-01-09 E. I. Du Pont De Nemours And Company Activated carbon-containing fibrids
US5536486A (en) 1989-03-15 1996-07-16 Petoca Ltd. Carbon fibers and non-woven fabrics
US5551451A (en) 1993-04-07 1996-09-03 R. J. Reynolds Tobacco Company Fuel element composition
US5595577A (en) 1993-06-02 1997-01-21 Bensalem; Azzedine Method for making a carbonaceous heat source containing metal oxide
US5622190A (en) 1990-08-24 1997-04-22 Philip Morris Incorporated Concentric smoking filter having cellulose acetate tow periphery and carbon-particle-loaded web filter core
US5727571A (en) 1992-03-25 1998-03-17 R.J. Reynolds Tobacco Co. Components for smoking articles and process for making same
US5819751A (en) 1992-09-17 1998-10-13 R. J. Reynolds Tobacco Company Cigarette and method of making same
US5839448A (en) * 1994-06-20 1998-11-24 Courtaulds Fibres (Holdings) Limited Absorbent articles
US5909736A (en) 1994-06-27 1999-06-08 Stavridis; Ioannis Removal of noxious oxidants and carcinogenic volatile nitrosocompounds from cigarette smoke using biological substances
US5970988A (en) 1992-05-27 1999-10-26 Eastman Kodak Company Environmentally non-persistant cellulose ester fibers
US6087465A (en) 1994-07-07 2000-07-11 Valtion Teknillinen Tutkimuskeskus Melt-processible poly (ester urethane) and a process for the preparation thereof
US6089857A (en) 1996-06-21 2000-07-18 Japan Tobacco, Inc. Heater for generating flavor and flavor generation appliance
US6095152A (en) 1994-09-07 2000-08-01 British-American Tobacco Company Limited Smoking article with non-combustible wrapper, combustible fuel source and aerosol generator
US20020014453A1 (en) 2000-02-07 2002-02-07 Lilly A. Clifton Filtering unsaturated hydrocarbons using intermetallic nano-clusters
US6360751B1 (en) 1999-12-01 2002-03-26 R. J. Reynolds Tobacco Company Asymmetrical trimmer disk apparatus
US20020167118A1 (en) 2001-03-23 2002-11-14 Romain Billiet Porous nanostructures and method of fabrication thereof
US20020172826A1 (en) 1998-11-06 2002-11-21 Tapesh Yadav Nanoscale catalyst compositions from complex and non-stoichiometric compositions
US20020194958A1 (en) 2001-06-08 2002-12-26 Chien-Liang Lee Process for preparing noble metal nanoparticles
US20030000538A1 (en) 2000-11-10 2003-01-02 Bereman Robert D. Method and product for removing carcinogens from tobacco smoke
US6503475B1 (en) 1998-05-15 2003-01-07 Advanced Nano Technologies Pty Ltd. Process for the production of ultrafine powders of metal oxides
US20030034085A1 (en) 2001-08-17 2003-02-20 Spiers Steven F. Apparatus and method for filling cavities with metered amounts of granular particles
US6537186B1 (en) 2000-07-05 2003-03-25 Baumgartner Papiers S.A. Process and apparatus for high-speed filling of composite cigarette filters
US6571802B1 (en) 1998-03-31 2003-06-03 Japan Tobacco Inc. Molded article of biodegradable cellulose acetate and filter plug for smoking article
US20030106562A1 (en) 2001-10-04 2003-06-12 Council Of Science And Industrial Research Activated charcoal filter for effectively reducing p-benzosemiquinone from the mainstream cigarette smoke
US20030136419A1 (en) 2002-01-24 2003-07-24 Hauni Maschinenbau Ag Garniture tongue of a garniture device
US20030145866A1 (en) 2002-02-07 2003-08-07 Hauni Maschinenbau Ag Process and device for conveying a wrapper strip in a machine of the tobacco processing industry
US20030200973A1 (en) 2002-04-12 2003-10-30 Lixin Xue Activated carbon fiber cigarette filter
US6647878B2 (en) 2000-02-11 2003-11-18 Hauni Mashinenbau Ag Apparatus for applying printed matter to webs of wrapping material for smokers' products
US6656412B2 (en) 2001-08-17 2003-12-02 Philip Morris Incorporated Compaction system for particles in particle filled cavities of an article
US6706361B1 (en) 2000-06-21 2004-03-16 Board Of Trustees Of University Of Illinois Polymeric ion exchange fibers
US20040129281A1 (en) 2001-06-27 2004-07-08 Hancock Lloyd Harmon Equipment and methods for manufacturing cigarettes
US6848449B2 (en) 2000-08-29 2005-02-01 Japan Tobacco Inc. Low fire-spreading smoking article and method of manufacturing the same
US20050039764A1 (en) 2002-12-20 2005-02-24 Barnes Vernon Brent Equipment and methods for manufacturing cigarettes
US20050066982A1 (en) 2003-09-30 2005-03-31 Clark Melissa Ann Filtered cigarette incorporating an adsorbent material
US20050076929A1 (en) 2003-10-09 2005-04-14 John Fitzgerald Materials, equipment and methods for manufacturing cigarettes
US6904917B2 (en) 2000-09-08 2005-06-14 Japan Tobacco, Inc. Method of manufacturing cigarette suppressing spread of burn and apparatus for manufacturing cigarette suppressing spread of burn
US20050274390A1 (en) 2004-06-15 2005-12-15 Banerjee Chandra K Ultra-fine particle catalysts for carbonaceous fuel elements
US6984631B2 (en) 2001-06-26 2006-01-10 Toray Industries, Inc. Thermoplastic cellulose derivative composition and fiber comprising the same
US20060025292A1 (en) 2004-07-29 2006-02-02 Brown & Williamson Tobacco Corporation Producing triple section filters using a dual rod filter maker
US7011096B2 (en) 2001-08-31 2006-03-14 Philip Morris Usa Inc. Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette
WO2006051422A1 (en) 2004-11-10 2006-05-18 Philip Morris Products S.A. Capsuled adsorbent flavored filter
WO2006064371A1 (en) 2004-12-15 2006-06-22 Philip Morris Products S.A. Cigarette with carbon on tow filter
US20060201524A1 (en) 2005-01-14 2006-09-14 Philip Morris Usa Inc. Cigarettes and cigarette filters including activated carbon for removing nitric oxide
US7115085B2 (en) 2003-09-12 2006-10-03 R.J. Reynolds Tobacco Company Method and apparatus for incorporating objects into cigarette filters
WO2006103404A1 (en) 2005-03-29 2006-10-05 British American Tobacco (Investments) Limited Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials
US20060231113A1 (en) 2005-04-13 2006-10-19 Philip Morris Usa Inc. Thermally insulative smoking article filter components
US7152609B2 (en) 2003-06-13 2006-12-26 Philip Morris Usa Inc. Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette
US7165553B2 (en) 2003-06-13 2007-01-23 Philip Morris Usa Inc. Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette
US20070056600A1 (en) 2005-09-14 2007-03-15 R. J. Reynolds Tobacco Company Filtered smoking article
US20070068540A1 (en) 2005-09-23 2007-03-29 Thomas Timothy F Equipment for insertion of objects into smoking articles
US7223376B2 (en) 2000-02-10 2007-05-29 Industrial Technology And Equipment Company Apparatus and method for making carbon fibers
US7228862B2 (en) 2002-04-08 2007-06-12 Philip Morris Usa Inc. Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette
US20070215168A1 (en) 2006-03-16 2007-09-20 Banerjee Chandra K Smoking article
US20070251658A1 (en) 2006-03-31 2007-11-01 Philip Morris Usa Inc. In situ formation of catalytic cigarette paper
US20070284034A1 (en) 2006-05-30 2007-12-13 Lambda Technologies, Inc. Resonating conductive traces and methods of using same for bonding components
US20080029118A1 (en) 2006-08-02 2008-02-07 R.J. Reynolds Tobacco Company Equipment and associated method for insertion of material into cigarette filters
US20080142028A1 (en) 2006-10-02 2008-06-19 R. J. Reynolds Tobacco Company Filtered Cigarette
US20080173320A1 (en) 2007-01-19 2008-07-24 R. J. Reynolds Tobacco Company Filtered Smoking Articles
US20080295853A1 (en) 2007-05-31 2008-12-04 R. J. Reynolds Tobacco Company Filtered Smoking Article
US20080302373A1 (en) 2007-06-11 2008-12-11 R.J. Reynolds Tobacco Company Apparatus for Inserting Objects into a Filter Component of a Smoking Article, and Associated Method
US7509961B2 (en) 2003-10-27 2009-03-31 Philip Morris Usa Inc. Cigarettes and cigarette components containing nanostructured fibril materials
US7549427B2 (en) 2004-07-20 2009-06-23 Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College Nanolayer catalysts useful in promoting oxidation, and their manufacture and use
US7560410B2 (en) 2004-10-25 2009-07-14 Philip Morris Usa Inc. Gold-ceria catalyst for oxidation of carbon monoxide
US7566681B2 (en) 2002-10-29 2009-07-28 National Research Council Of Canada Platinum based nano-size catalysts
US20090288672A1 (en) 2008-05-21 2009-11-26 R. J. Reynolds Tobacco Company Cigarette Filter Comprising a Carbonaceous Fiber
US20090288667A1 (en) 2008-05-21 2009-11-26 R. J. Reynolds Tobacco Company Apparatus for Forming a Filter Component of a Smoking Article, and Associated Method
US20090288669A1 (en) 2008-05-21 2009-11-26 R.J. Reynolds Tobacco Company Cigarette filter comprising a degradable fiber
US20100065075A1 (en) 2008-09-18 2010-03-18 R.J. Reynoldds Tobacco Company Method for Preparing Fuel Element For Smoking Article
US20100101589A1 (en) 2008-10-28 2010-04-29 John Larkin Nelson Apparatus for enhancing a filter component of a smoking article, and associated method
US20100125039A1 (en) 2008-11-20 2010-05-20 R. J. Reynolds Tobacco Company Carbonaceous Material Having Modified Pore Structure
US20100122708A1 (en) 2008-11-20 2010-05-20 R. J. Reynolds Tobacco Company Adsorbent Material Impregnated with Metal Oxide Component
US20110036366A1 (en) 2009-08-11 2011-02-17 R.J. Reynolds Tobacco Company Degradable filter element

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3039908A (en) 1953-07-13 1962-06-19 Hollingsworth & Vose Co Method of making a tobacco smoke filter
US2812767A (en) * 1955-05-17 1957-11-12 American Viscose Corp Absorbent element for filters and the like
US3224453A (en) 1959-06-12 1965-12-21 Celanese Corp Filter cigarettes
US3119396A (en) 1961-05-24 1964-01-28 Minnesota Mining & Mfg Tobacco smoke filter
US3111702A (en) * 1963-06-24 1963-11-26 United States Filter Corp Products formed from continuous filamentary tows
DE1757611A1 (de) 1968-05-24 1971-12-23 Lutravil Spinnvlies Verfahren zur Herstellung von Spinnvliesen und daraus hergestelle Filterstaebe
US3724199A (en) * 1970-04-20 1973-04-03 Monsanto Co Process for making continuous filament heather yarn
US3775958A (en) * 1970-06-01 1973-12-04 Celanese Corp Pneumatic false twisting interlacer
JPS5388400A (en) 1977-01-13 1978-08-03 Toho Rayon Co Ltd Cigarette filter
US4173504A (en) * 1977-01-19 1979-11-06 Chisso Corporation Method for producing tobacco filters
JPS54151199A (en) 1978-05-18 1979-11-28 Chisso Corp Production of cigarette filter
FR2462111B1 (fr) 1979-07-26 1988-08-12 Job Ets Bardou Job Pauilhac Procede pour la realisation d'une structure filtrante, notamment pour filtres a cigarettes et filtres obtenus
US4368688A (en) * 1980-06-20 1983-01-18 Hauni-Werke Korber & Co. Kg Apparatus for applying liquid plasticizer to filamentary filter material
US4468845A (en) 1982-03-19 1984-09-04 Eastman Kodak Company Jet and bustle tow blooming apparatus for a tow blooming process
US4549875A (en) 1983-06-02 1985-10-29 R. J. Reynolds Tobacco Co. Manufacture of tobacco smoke filters
GB8921659D0 (en) 1989-09-26 1989-11-08 Cigarette Components Ltd Particulate sorbent smoke filter
US5056200A (en) 1990-01-09 1991-10-15 Textured Yarn Company, Inc. Apparatus for making novel textured yarn
JP2965184B2 (ja) 1991-12-09 1999-10-18 三菱レイヨン株式会社 エアージェット
US5275859A (en) 1992-12-21 1994-01-04 Eastman Kodak Company Tobacco smoke filter
US5509430A (en) * 1993-12-14 1996-04-23 American Filtrona Corporation Bicomponent fibers and tobacco smoke filters formed therefrom
GB9404547D0 (en) 1994-03-09 1994-04-20 Courtaulds Fibres Holdings Ltd Fibre production process
CN1083020C (zh) 1995-02-14 2002-04-17 智索股份有限公司 可生物降解的纤维和非织造布
US5783505A (en) 1996-01-04 1998-07-21 The University Of Tennessee Research Corporation Compostable and biodegradable compositions of a blend of natural cellulosic and thermoplastic biodegradable fibers
DE19753195A1 (de) 1997-11-21 1999-05-27 Reemtsma H F & Ph Biologisch abbaubarer Filter für Cigaretten
DK1167589T3 (da) 1999-03-11 2007-10-29 Japan Tobacco Inc Bionedbrydelige artikler af celluloseacetat samt filter for tobaksrög
US6543106B1 (en) * 1999-10-25 2003-04-08 Celanese Acetate, Llc Apparatus, method and system for air opening of textile tow and opened textile tow web produced thereby
CN1422562A (zh) * 2001-12-07 2003-06-11 上海博迪纺织新材料有限公司 环保型降焦油香烟滤嘴
DE10200320A1 (de) * 2002-01-07 2003-07-17 Hauni Maschinenbau Ag Verfahren und Vorrichtung zur Herstellung eines Faserstranges der tabakverarbeitenden Industrie
DE10217410A1 (de) * 2002-04-18 2003-10-30 Hauni Maschinenbau Ag Zigarettenfilter und Verfahren zur Herstellung desselben
US6997190B2 (en) 2002-11-25 2006-02-14 R.J. Reynolds Tobacco Company Wrapping materials for smoking articles
DE50304210D1 (de) 2003-04-03 2006-08-24 Hauni Maschinenbau Ag Verfahren zur Aufbereitung endlicher Fasern und Aufbereitungseinrichtung für endliche Fasern zur Verwedung bei der Herstellung von Filtern
US7425289B2 (en) 2004-06-25 2008-09-16 Celanese Acetate Llc Process of making cellulose acetate tow
DE102005017478A1 (de) 2005-04-15 2006-10-19 Reemtsma Cigarettenfabriken Gmbh Tabakrauchfilter
US8186360B2 (en) 2007-04-04 2012-05-29 R.J. Reynolds Tobacco Company Cigarette comprising dark air-cured tobacco
DE102007029831A1 (de) 2007-06-28 2009-01-08 Reemtsma Cigarettenfabriken Gmbh Verfahren zum Herstellen von Tabakrauchfiltern
DE102007057396A1 (de) * 2007-11-27 2009-05-28 Hauni Maschinenbau Ag Vorrichtung zur Bearbeitung von mindestens zwei Filtertowsträngen
TW200936065A (en) 2008-01-23 2009-09-01 Filtrona Int Ltd Tobacco smoke filter
ES2420685T5 (es) * 2008-05-21 2017-02-10 R.J. Reynolds Tobacco Company Aparato y método asociado para formar un componente de filtro de un artículo para fumar y artículos para fumar fabricados a partir del mismo
US8262550B2 (en) 2009-03-19 2012-09-11 R. J. Reynolds Tobacco Company Apparatus for inserting objects into a filter component of a smoking article
US20120000479A1 (en) 2010-06-30 2012-01-05 Sebastian Andries D Biodegradable cigarette filter
US8720450B2 (en) 2010-07-30 2014-05-13 R.J. Reynolds Tobacco Company Filter element comprising multifunctional fibrous smoke-altering material
US8973588B2 (en) 2011-07-29 2015-03-10 R.J. Reynolds Tobacco Company Plasticizer composition for degradable polyester filter tow

Patent Citations (171)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB757283A (en) * 1953-10-07 1956-09-19 Lorillard Co P Improvements in tobacco smoke filters
US2881770A (en) 1954-05-27 1959-04-14 Eastman Kodak Co Fibrous tobacco smoke filters
US3253396A (en) 1959-06-01 1966-05-31 Beaunit Corp Method and apparatus for making textured yarn and product
US3288147A (en) 1959-06-03 1966-11-29 Molins Machine Co Ltd Tobacco-manipulating machines
US3101723A (en) 1960-11-15 1963-08-27 Philip Morris Inc Fibrous cigarette filter
US3236244A (en) 1961-09-19 1966-02-22 American Tobacco Co Tobacco smoke filter element
US3551256A (en) 1963-11-21 1970-12-29 Celanese Corp Apparatus for making a multi-segmented filter
US3311519A (en) 1964-01-28 1967-03-28 Eastman Kodak Co Additive filter
US3347247A (en) 1964-05-14 1967-10-17 Philip Morris Inc Tobacco smoke filter
US3349780A (en) 1964-11-04 1967-10-31 Eastman Kodak Co Acetate filter elements containing carbon
US3370595A (en) 1965-01-04 1968-02-27 Celanese Corp Smoke filters
US3424172A (en) 1965-05-14 1969-01-28 Georg Neurath Cigarette filters
US3319629A (en) 1965-05-20 1967-05-16 American Cyanamid Co Filter cigarette
US3413982A (en) 1965-08-04 1968-12-03 Eastman Kodak Co Tobacco smoke filter employing ethylene copolymer bonding material
US3313306A (en) 1965-10-22 1967-04-11 American Filtrona Corp Stable elongated elements and smoking means incorporating the same
US3328863A (en) 1966-04-29 1967-07-04 Owens Corning Fiberglass Corp Yarn texturizing jet
US3381346A (en) 1967-06-20 1968-05-07 Owens Corning Fiberglass Corp Fluid nozzle for texturing yarns
US3553953A (en) 1968-09-03 1971-01-12 Monsanto Co Bulked bonded yarn
US3602231A (en) 1969-12-12 1971-08-31 H 2 D Filter Corp The Means for audible detection of the activation of a filter for smoking devices
US3904577A (en) 1971-08-12 1975-09-09 Rhone Poulenc Textile Textile articles for protective clothing
US3915176A (en) 1972-07-05 1975-10-28 Hauni Werke Koerber & Co Kg Apparatus for wrapping filler rods of tobacco or the like
US3972335A (en) 1972-09-20 1976-08-03 Calgon Corporation Mentholated cigarette filter
GB1420655A (en) * 1972-09-27 1976-01-07 Rothmans Of Pall Mall Austrial Tobacco smoke filter
US3844200A (en) 1973-05-07 1974-10-29 Brown & Williamson Tobacco Continuous manufacture of a multiple filter rod having spaced pockets containing particulate material
US3944485A (en) 1973-05-23 1976-03-16 California Institute Of Technology Ion-exchange hollow fibers
US4068358A (en) 1975-06-18 1978-01-17 Berliner Maschinenbau-Ag Vormals L. Schwartzkopff Machine for air-jet texturizing of continuous synthetic filaments
US4016830A (en) 1975-07-16 1977-04-12 Brown & Williamson Tobacco Corporation Apparatus for dispensing spaced deposits of particulate material
US4291713A (en) 1977-01-27 1981-09-29 Hauni-Werke Korber & Co. Kg Device for heating the seams of wrappers for rod-like fillers in cigarette making machines or the like
US4174719A (en) 1977-06-29 1979-11-20 Olin Corporation Microperforated filter tip cigarette
US4182348A (en) 1977-09-06 1980-01-08 B.A.T. Cigaretten-Fabriken Gmbh Removal of nitric oxide and carbon monoxide from tobacco smoke
US4125922A (en) 1977-09-22 1978-11-21 Techniservice Division, Textured Yarn Co. Inc. Jet tangler
US4214508A (en) 1977-10-13 1980-07-29 Philip Morris Incorporated Method and apparatus for making cigarette filters of filamentary material
US4338776A (en) 1977-11-08 1982-07-13 Barmag Barmer Maschinenfabrik Aktiengesellschaft Process for the production of a crimped continuous multifilament yarn
US4317460A (en) 1978-01-20 1982-03-02 Gallaher Limited Smoking products
US4281671A (en) 1978-04-21 1981-08-04 American Filtrona Corporation Production of tobacco smoke filters
US4411640A (en) 1981-01-08 1983-10-25 Liggett Group Inc. Apparatus for the production of cigarette filter tips having multi-sectional construction
US4474190A (en) 1981-03-21 1984-10-02 Hauni-Werke Korber & Co. Kg Method and apparatus for regulating the operation of machines for the production of cigarettes or the like
US4425107A (en) 1981-07-22 1984-01-10 Liggett Group Inc. Rotatable dispensing wheel
US4559772A (en) 1982-02-13 1985-12-24 Hoechst Aktiengesellschaft False twist texturized yarn, and a process for its preparation
US4574816A (en) 1983-02-04 1986-03-11 Hauni-Werke Korber & Co. Kg Method and apparatus for forming a filler of fibrous material
US4736754A (en) 1983-10-12 1988-04-12 Hauni-Werke Korber & Co. K.G. Method and apparatus for making rod-shaped smokers' products with soft cores
US4876078A (en) 1984-04-20 1989-10-24 Nikkiso Co., Ltd. Process for preparing carbon fibers in gas phase growth
US5012823A (en) 1984-08-03 1991-05-07 Philip Morris Incorporated Tobacco processing
US4714082A (en) 1984-09-14 1987-12-22 R. J. Reynolds Tobacco Company Smoking article
US4793365A (en) 1984-09-14 1988-12-27 R. J. Reynolds Tobacco Company Smoking article
US5027836A (en) 1984-12-21 1991-07-02 R. J. Reynolds Tobacco Company Insulated smoking article
US4781203A (en) 1985-05-15 1988-11-01 Hue Paul D Method and apparatus for making self-extinguishing cigarette
US4989619A (en) 1985-08-26 1991-02-05 R. J. Reynolds Tobacco Company Smoking article with improved fuel element
US5020548A (en) 1985-08-26 1991-06-04 R. J. Reynolds Tobacco Company Smoking article with improved fuel element
US5033483A (en) 1985-10-28 1991-07-23 R. J. Reynolds Tobacco Company Smoking article with tobacco jacket
US4917128A (en) 1985-10-28 1990-04-17 R. J. Reynolds Tobacco Co. Cigarette
US4756318A (en) 1985-10-28 1988-07-12 R. J. Reynolds Tobacco Company Smoking article with tobacco jacket
US5076297A (en) 1986-03-14 1991-12-31 R. J. Reynolds Tobacco Company Method for preparing carbon fuel for smoking articles and product produced thereby
US4771795A (en) 1986-05-15 1988-09-20 R. J. Reynolds Tobacco Company Smoking article with dual burn rate fuel element
US4844100A (en) 1986-09-13 1989-07-04 Korber Ag Method of and apparatus for making rod-shaped smokers' articles with dense ends
US4969476A (en) 1986-09-19 1990-11-13 Imperial Tobacco Limited Smoking article
US5052413A (en) 1987-02-27 1991-10-01 R. J. Reynolds Tobacco Company Method for making a smoking article and components for use therein
US5268158A (en) 1987-03-11 1993-12-07 Hercules Incorporated High modulus pan-based carbon fiber
US4878506A (en) 1987-07-31 1989-11-07 Korber Ag Method of and apparatus for treating accumulations of fibers of tobacco or other smokable material
US4811745A (en) 1988-02-04 1989-03-14 Hercules Incorporated Method and device for control of by-products from cigarette smoke
US5360023A (en) 1988-05-16 1994-11-01 R. J. Reynolds Tobacco Company Cigarette filter
US5076296A (en) 1988-07-22 1991-12-31 Philip Morris Incorporated Carbon heat source
US5159940A (en) 1988-07-22 1992-11-03 Philip Morris Incorporated Smoking article
US4966171A (en) 1988-07-22 1990-10-30 Philip Morris Incorporated Smoking article
US4991606A (en) 1988-07-22 1991-02-12 Philip Morris Incorporated Smoking article
US4925602A (en) 1988-08-10 1990-05-15 Filter Materials Limited Method for improving the crimping of polyolefin filter tow
US5050621A (en) 1988-08-12 1991-09-24 British-American Tobacco Company Limited Smoking articles
US4947874A (en) 1988-09-08 1990-08-14 R. J. Reynolds Tobacco Company Smoking articles utilizing electrical energy
US5040551A (en) 1988-11-01 1991-08-20 Catalytica, Inc. Optimizing the oxidation of carbon monoxide
US5211684A (en) 1989-01-10 1993-05-18 R. J. Reynolds Tobacco Company Catalyst containing smoking articles for reducing carbon monoxide
US5105835A (en) 1989-01-25 1992-04-21 Imperial Tobacco, Ltd. Smoking articles
US5536486A (en) 1989-03-15 1996-07-16 Petoca Ltd. Carbon fibers and non-woven fabrics
US5115820A (en) 1989-03-28 1992-05-26 B.A.T. Cigarettenfabriken Gmbh Smokable article
US4961438A (en) 1989-04-03 1990-10-09 Brown & Williamson Tobacco Corporation Smoking device
US4956330A (en) 1989-06-19 1990-09-11 Phillips Petroleum Company Catalyst composition for the oxidation of carbon monoxide
US5271419A (en) 1989-09-29 1993-12-21 R. J. Reynolds Tobacco Company Cigarette
US5225277A (en) 1989-11-17 1993-07-06 Daicel Chemical Industries, Ltd. Acetate tow having high crimp modulus and manufacturing method thereof
US5230960A (en) 1990-01-12 1993-07-27 Gun Ei Chemical Industry Co., Ltd. Activated carbon fiber structure and process for producing the same
US5338605A (en) 1990-01-31 1994-08-16 Ketema, Inc. Hollow carbon fibers
US5099861A (en) 1990-02-27 1992-03-31 R. J. Reynolds Tobacco Company Aerosol delivery article
US5183062A (en) 1990-02-27 1993-02-02 R. J. Reynolds Tobacco Company Cigarette
US5060665A (en) 1990-03-05 1991-10-29 Korber Ag Wrapping mechanism for rod making machines of the tobacco processing industry
US5240014A (en) 1990-07-20 1993-08-31 Philip Morris Incorporated Catalytic conversion of carbon monoxide from carbonaceous heat sources
US5396911A (en) 1990-08-15 1995-03-14 R. J. Reynolds Tobacco Company Substrate material for smoking articles
US5148821A (en) 1990-08-17 1992-09-22 R. J. Reynolds Tobacco Company Processes for producing a smokable and/or combustible tobacco material
US5622190A (en) 1990-08-24 1997-04-22 Philip Morris Incorporated Concentric smoking filter having cellulose acetate tow periphery and carbon-particle-loaded web filter core
US5105837A (en) 1990-08-28 1992-04-21 R. J. Reynolds Tobacco Company Smoking article with improved wrapper
US5065776A (en) 1990-08-29 1991-11-19 R. J. Reynolds Tobacco Company Cigarette with tobacco/glass fuel wrapper
US5191906A (en) 1990-10-30 1993-03-09 Philip Morris Incorporated Process for making wrappers for smoking articles which modify the burn rate of the smoking article
US5156169A (en) 1990-11-06 1992-10-20 R. J. Reynolds Tobacco Company Apparatus for making cigarettes
US5131416A (en) 1990-12-17 1992-07-21 R. J. Reynolds Tobacco Company Cigarette
US5258340A (en) 1991-02-15 1993-11-02 Philip Morris Incorporated Mixed transition metal oxide catalysts for conversion of carbon monoxide and method for producing the catalysts
US5240016A (en) 1991-04-19 1993-08-31 Philip Morris Incorporated Thermally releasable gel-based flavor source for smoking articles
US5178167A (en) 1991-06-28 1993-01-12 R. J. Reynolds Tobacco Company Carbonaceous composition for fuel elements of smoking articles and method of modifying the burning characteristics thereof
US5482773A (en) 1991-07-01 1996-01-09 E. I. Du Pont De Nemours And Company Activated carbon-containing fibrids
WO1993005868A1 (en) 1991-09-27 1993-04-01 North Carolina Center For Scientific Research, Inc. Coated fibrous filter for catalytic cracking
US5727571A (en) 1992-03-25 1998-03-17 R.J. Reynolds Tobacco Co. Components for smoking articles and process for making same
US5322495A (en) 1992-04-27 1994-06-21 Philip Morris Incorporated High speed vacuum assisted free flowing material inserter in filter rod manufacture
US5970988A (en) 1992-05-27 1999-10-26 Eastman Kodak Company Environmentally non-persistant cellulose ester fibers
US5387285A (en) 1992-06-02 1995-02-07 R. J. Reynolds Tobacco Company Apparatus for injecting a fluid into filter tow
US5446005A (en) 1992-06-25 1995-08-29 Endo; Morinobu Pitch-based activated carbon fiber
US5345955A (en) 1992-09-17 1994-09-13 R. J. Reynolds Tobacco Company Composite fuel element for smoking articles
US5819751A (en) 1992-09-17 1998-10-13 R. J. Reynolds Tobacco Company Cigarette and method of making same
US5551451A (en) 1993-04-07 1996-09-03 R. J. Reynolds Tobacco Company Fuel element composition
US5595577A (en) 1993-06-02 1997-01-21 Bensalem; Azzedine Method for making a carbonaceous heat source containing metal oxide
US5839448A (en) * 1994-06-20 1998-11-24 Courtaulds Fibres (Holdings) Limited Absorbent articles
US5909736A (en) 1994-06-27 1999-06-08 Stavridis; Ioannis Removal of noxious oxidants and carcinogenic volatile nitrosocompounds from cigarette smoke using biological substances
US6087465A (en) 1994-07-07 2000-07-11 Valtion Teknillinen Tutkimuskeskus Melt-processible poly (ester urethane) and a process for the preparation thereof
US6095152A (en) 1994-09-07 2000-08-01 British-American Tobacco Company Limited Smoking article with non-combustible wrapper, combustible fuel source and aerosol generator
US6578584B1 (en) 1994-09-07 2003-06-17 British American Tobacco (Investments) Limited Smoking article with non-combustible wrapper, combustible fuel source and aerosol generator
US6089857A (en) 1996-06-21 2000-07-18 Japan Tobacco, Inc. Heater for generating flavor and flavor generation appliance
US6571802B1 (en) 1998-03-31 2003-06-03 Japan Tobacco Inc. Molded article of biodegradable cellulose acetate and filter plug for smoking article
US6503475B1 (en) 1998-05-15 2003-01-07 Advanced Nano Technologies Pty Ltd. Process for the production of ultrafine powders of metal oxides
US20020172826A1 (en) 1998-11-06 2002-11-21 Tapesh Yadav Nanoscale catalyst compositions from complex and non-stoichiometric compositions
US6360751B1 (en) 1999-12-01 2002-03-26 R. J. Reynolds Tobacco Company Asymmetrical trimmer disk apparatus
US20020014453A1 (en) 2000-02-07 2002-02-07 Lilly A. Clifton Filtering unsaturated hydrocarbons using intermetallic nano-clusters
US7223376B2 (en) 2000-02-10 2007-05-29 Industrial Technology And Equipment Company Apparatus and method for making carbon fibers
US6647878B2 (en) 2000-02-11 2003-11-18 Hauni Mashinenbau Ag Apparatus for applying printed matter to webs of wrapping material for smokers' products
US6706361B1 (en) 2000-06-21 2004-03-16 Board Of Trustees Of University Of Illinois Polymeric ion exchange fibers
US6537186B1 (en) 2000-07-05 2003-03-25 Baumgartner Papiers S.A. Process and apparatus for high-speed filling of composite cigarette filters
US6848449B2 (en) 2000-08-29 2005-02-01 Japan Tobacco Inc. Low fire-spreading smoking article and method of manufacturing the same
US6904917B2 (en) 2000-09-08 2005-06-14 Japan Tobacco, Inc. Method of manufacturing cigarette suppressing spread of burn and apparatus for manufacturing cigarette suppressing spread of burn
US20030000538A1 (en) 2000-11-10 2003-01-02 Bereman Robert D. Method and product for removing carcinogens from tobacco smoke
US20020167118A1 (en) 2001-03-23 2002-11-14 Romain Billiet Porous nanostructures and method of fabrication thereof
US20020194958A1 (en) 2001-06-08 2002-12-26 Chien-Liang Lee Process for preparing noble metal nanoparticles
US6984631B2 (en) 2001-06-26 2006-01-10 Toray Industries, Inc. Thermoplastic cellulose derivative composition and fiber comprising the same
US20040129281A1 (en) 2001-06-27 2004-07-08 Hancock Lloyd Harmon Equipment and methods for manufacturing cigarettes
US6656412B2 (en) 2001-08-17 2003-12-02 Philip Morris Incorporated Compaction system for particles in particle filled cavities of an article
US6837281B2 (en) 2001-08-17 2005-01-04 Philip Morris Incorporation Apparatus and method for filling cavities with metered amounts of granular particles
US20030034085A1 (en) 2001-08-17 2003-02-20 Spiers Steven F. Apparatus and method for filling cavities with metered amounts of granular particles
US7011096B2 (en) 2001-08-31 2006-03-14 Philip Morris Usa Inc. Oxidant/catalyst nanoparticles to reduce carbon monoxide in the mainstream smoke of a cigarette
US20030106562A1 (en) 2001-10-04 2003-06-12 Council Of Science And Industrial Research Activated charcoal filter for effectively reducing p-benzosemiquinone from the mainstream cigarette smoke
US20030136419A1 (en) 2002-01-24 2003-07-24 Hauni Maschinenbau Ag Garniture tongue of a garniture device
US20030145866A1 (en) 2002-02-07 2003-08-07 Hauni Maschinenbau Ag Process and device for conveying a wrapper strip in a machine of the tobacco processing industry
US7228862B2 (en) 2002-04-08 2007-06-12 Philip Morris Usa Inc. Use of oxyhydroxide compounds for reducing carbon monoxide in the mainstream smoke of a cigarette
US20030200973A1 (en) 2002-04-12 2003-10-30 Lixin Xue Activated carbon fiber cigarette filter
US7566681B2 (en) 2002-10-29 2009-07-28 National Research Council Of Canada Platinum based nano-size catalysts
US20050039764A1 (en) 2002-12-20 2005-02-24 Barnes Vernon Brent Equipment and methods for manufacturing cigarettes
US7165553B2 (en) 2003-06-13 2007-01-23 Philip Morris Usa Inc. Nanoscale catalyst particles/aluminosilicate to reduce carbon monoxide in the mainstream smoke of a cigarette
US7152609B2 (en) 2003-06-13 2006-12-26 Philip Morris Usa Inc. Catalyst to reduce carbon monoxide and nitric oxide from the mainstream smoke of a cigarette
US7115085B2 (en) 2003-09-12 2006-10-03 R.J. Reynolds Tobacco Company Method and apparatus for incorporating objects into cigarette filters
US20050066982A1 (en) 2003-09-30 2005-03-31 Clark Melissa Ann Filtered cigarette incorporating an adsorbent material
US20050076929A1 (en) 2003-10-09 2005-04-14 John Fitzgerald Materials, equipment and methods for manufacturing cigarettes
US7509961B2 (en) 2003-10-27 2009-03-31 Philip Morris Usa Inc. Cigarettes and cigarette components containing nanostructured fibril materials
US20050274390A1 (en) 2004-06-15 2005-12-15 Banerjee Chandra K Ultra-fine particle catalysts for carbonaceous fuel elements
US7549427B2 (en) 2004-07-20 2009-06-23 Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College Nanolayer catalysts useful in promoting oxidation, and their manufacture and use
US20060025292A1 (en) 2004-07-29 2006-02-02 Brown & Williamson Tobacco Corporation Producing triple section filters using a dual rod filter maker
US7560410B2 (en) 2004-10-25 2009-07-14 Philip Morris Usa Inc. Gold-ceria catalyst for oxidation of carbon monoxide
WO2006051422A1 (en) 2004-11-10 2006-05-18 Philip Morris Products S.A. Capsuled adsorbent flavored filter
WO2006064371A1 (en) 2004-12-15 2006-06-22 Philip Morris Products S.A. Cigarette with carbon on tow filter
US20060201524A1 (en) 2005-01-14 2006-09-14 Philip Morris Usa Inc. Cigarettes and cigarette filters including activated carbon for removing nitric oxide
WO2006103404A1 (en) 2005-03-29 2006-10-05 British American Tobacco (Investments) Limited Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials
US20060231113A1 (en) 2005-04-13 2006-10-19 Philip Morris Usa Inc. Thermally insulative smoking article filter components
US20070056600A1 (en) 2005-09-14 2007-03-15 R. J. Reynolds Tobacco Company Filtered smoking article
US20070068540A1 (en) 2005-09-23 2007-03-29 Thomas Timothy F Equipment for insertion of objects into smoking articles
US20070215168A1 (en) 2006-03-16 2007-09-20 Banerjee Chandra K Smoking article
US20070251658A1 (en) 2006-03-31 2007-11-01 Philip Morris Usa Inc. In situ formation of catalytic cigarette paper
US20070284034A1 (en) 2006-05-30 2007-12-13 Lambda Technologies, Inc. Resonating conductive traces and methods of using same for bonding components
US20080029118A1 (en) 2006-08-02 2008-02-07 R.J. Reynolds Tobacco Company Equipment and associated method for insertion of material into cigarette filters
US20080142028A1 (en) 2006-10-02 2008-06-19 R. J. Reynolds Tobacco Company Filtered Cigarette
US20080173320A1 (en) 2007-01-19 2008-07-24 R. J. Reynolds Tobacco Company Filtered Smoking Articles
US20080295853A1 (en) 2007-05-31 2008-12-04 R. J. Reynolds Tobacco Company Filtered Smoking Article
US20080302373A1 (en) 2007-06-11 2008-12-11 R.J. Reynolds Tobacco Company Apparatus for Inserting Objects into a Filter Component of a Smoking Article, and Associated Method
US20090288672A1 (en) 2008-05-21 2009-11-26 R. J. Reynolds Tobacco Company Cigarette Filter Comprising a Carbonaceous Fiber
US20090288667A1 (en) 2008-05-21 2009-11-26 R. J. Reynolds Tobacco Company Apparatus for Forming a Filter Component of a Smoking Article, and Associated Method
US20090288669A1 (en) 2008-05-21 2009-11-26 R.J. Reynolds Tobacco Company Cigarette filter comprising a degradable fiber
US20100065075A1 (en) 2008-09-18 2010-03-18 R.J. Reynoldds Tobacco Company Method for Preparing Fuel Element For Smoking Article
US20100101589A1 (en) 2008-10-28 2010-04-29 John Larkin Nelson Apparatus for enhancing a filter component of a smoking article, and associated method
US20100125039A1 (en) 2008-11-20 2010-05-20 R. J. Reynolds Tobacco Company Carbonaceous Material Having Modified Pore Structure
US20100122708A1 (en) 2008-11-20 2010-05-20 R. J. Reynolds Tobacco Company Adsorbent Material Impregnated with Metal Oxide Component
US20110036366A1 (en) 2009-08-11 2011-02-17 R.J. Reynolds Tobacco Company Degradable filter element

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Chemical and Biological Studies on New Cigarette Prototypes that Heat Instead of Burn Tobacco", R. J. REYNOLDS TOBACCO COMPANY MONOGRAPH (1988) AND INHALATION TOXICOLOGY, vol. 12, no. 5, 2000, pages 1 - 58

Also Published As

Publication number Publication date
CN103929986A (zh) 2014-07-16
DK2757910T3 (en) 2019-03-04
EP2757910B1 (de) 2018-11-28
US10064429B2 (en) 2018-09-04
WO2013043806A2 (en) 2013-03-28
JP6240608B2 (ja) 2017-11-29
JP2014526277A (ja) 2014-10-06
CN103929986B (zh) 2018-12-04
CN109527650A (zh) 2019-03-29
US20130074853A1 (en) 2013-03-28
TR201901463T4 (tr) 2019-02-21
PL2757910T3 (pl) 2019-06-28
WO2013043806A3 (en) 2013-06-06
EP2757910A2 (de) 2014-07-30

Similar Documents

Publication Publication Date Title
EP2757910B1 (de) Mischfase produkt zur verwendung bei der herstellung von zigarettenfilterelementen und zugehörige verfahren
JP7228622B2 (ja) 喫煙物品のフィルター要素のためのフィルター材料、ならびに関連システムおよび方法
JP6293751B2 (ja) シガレットのフィルター要素の製造で使用するための混合繊維スライバー
EP2713782B1 (de) Beschichtetes papierfilter
EP2403365B1 (de) Eine abbaubare faser enthaltender zigarettenfilter
US8973588B2 (en) Plasticizer composition for degradable polyester filter tow
JP2013532483A (ja) 多機能性繊維状煙改変材料を含むフィルター要素
US10524500B2 (en) Staple fiber blend for use in the manufacture of cigarette filter elements

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN PUBLISHED

AC Divisional application: reference to earlier application

Ref document number: 2757910

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

RIN1 Information on inventor provided before grant (corrected)

Inventor name: SIZEMORE, RICHARD L.

Inventor name: DELOACH, KENNETH C.

Inventor name: GAN, HUAMIN

Inventor name: SEBASTIAN, ANDRIES D.

Inventor name: VICK, DEAN M.

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20190919

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20200303

REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 40005872

Country of ref document: HK

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230505

P02 Opt-out of the competence of the unified patent court (upc) corrected

Effective date: 20230621