WO2006051422A1 - Capsuled adsorbent flavored filter - Google Patents
Capsuled adsorbent flavored filter Download PDFInfo
- Publication number
- WO2006051422A1 WO2006051422A1 PCT/IB2005/003644 IB2005003644W WO2006051422A1 WO 2006051422 A1 WO2006051422 A1 WO 2006051422A1 IB 2005003644 W IB2005003644 W IB 2005003644W WO 2006051422 A1 WO2006051422 A1 WO 2006051422A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- capsule
- cigarette
- filter
- adsorbent
- carbon particles
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0216—Applying additives to filter materials the additive being in the form of capsules, beads or the like
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0204—Preliminary operations before the filter rod forming process, e.g. crimping, blooming
- A24D3/0212—Applying additives to filter materials
- A24D3/0225—Applying additives to filter materials with solid additives, e.g. incorporation of a granular product
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/048—Tobacco smoke filters characterised by their shape or structure containing additives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/163—Carbon
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
- A24D3/166—Silicic acid or silicates
Definitions
- the present invention relates to a cigarette comprising a tobacco rod and an adjoining filter, and more particularly to a filter that includes a capsule packed with flavored adsorbent .
- Cigarettes with filters are old in the art, and filters that include adsorbents also are well known.
- adsorbents when used in cigarette filter constructions it is important that they be presented in a fully packed condition so as to avoid or substantially reduce channeling of mainstream tobacco smoke in and around the adsorbent.
- flavors have been added to mainstream tobacco smoke it is important to maintain such flavors as fresh as possible for extended shelf life of the cigarette.
- one of the objects of the present invention is a cigarette filter containing adsorbent particles in a fully packed condition so as to avoid channeling of mainstream tobacco smoke in and around the adsorbent particles .
- Another object of the present invention is a cigarette filter containing flavored adsorbent particles wherein the amount of flavor is precise.
- Still another object of the present invention is a cigarette filter containing fully packed flavored adsorbent particles within a capsule to preserve freshness of the flavored particles .
- a cigarette comprises a filter and an adjoining tobacco rod.
- the filter includes a capsule having a first end wall with a surrounding side wall secured thereto.
- Adsorbent spherical carbon particles are packed into the enclosure of the capsule, and flavorant is placed on the particles.
- a second end wall caps-off the side wall, and a plurality of perforations are located in the end walls of the capsule.
- mainstream tobacco passes into and through the capsule to thereby modify the characteristics of the smoke.
- the adsorbent spherical carbon particles comprise a combination of two different sizes.
- the filter has a plug-space-plug configuration with the capsule in the central space. The plugs on opposite ends of the capsule may each comprise cellulose acetate tow.
- Figure 1 is a side elevational view of a cigarette comprising a tobacco rod and a filter that includes a capsuled adsorbent and flavorant, according to the present invention, with portions of the filter broken away to show interior details;
- Figure 2 is a perspective view of the capsuled adsorbent and flavorant of the cigarette filter shown in Figure 1;
- Figure 3 is an end elevational view of the capsuled adsorbent and flavorant shown in Figures 1 and 2;
- Figure 4 is an elevational view of the capsuled adsorbent with flavorant being applied to the adsorbent within the capsule prior to capping the capsule, according to the present invention.
- Figure 1 illustrates a cigarette 10 comprising a tobacco rod 12 and a filter 14 adjoining the tobacco rod.
- Filter 14 has a plug-space-plug configuration and the central space provides a compartment for a capsule 16 containing a flavored adsorbent material, as explained more •fully below.
- Plugs 18 and 20 each of cellulose acetate tow are located on opposite ends of the capsule 16.
- Tipping paper 22 is wrapped around the filter 14 and joins the filter to the tobacco rod.
- Perforations 24 may be provided in the tipping paper for the introduction of air which dilutes the mainstream tobacco smoke following through the filter.
- Capsule 16 comprises an impervious surrounding side wall 24 and a first and second end wall 26, 28.
- Adsorbent spherical carbon particles 30, 32 are fully packed into the enclosure of the capsule, and a flavorant 34 is applied to the carbon particles.
- Both end walls 26 and 28 include a plurality of perforations 34 which enable mainstream smoke to pass through the capsule.
- the capsule 16 is produced by initially forming the surrounding side wall 24 with one end wall 26 attached thereto. Carbon particles 28, 30 each having a different size are fully packed into the capsule and a precise amount of flavorant 34 is delivered onto the particles by an applicator device 38. The opposite end of the surrounding side wall 24 is then capped-off by end wall 28.
- a capsule with fully packed particles is presented and such fully packed condition avoids channeling of mainstream tobacco smoke in and around the particles. Vibration may ⁇ be applied to obtain a fully packed capsule. Hence, the smoke is subjected to the fully effect of the adsorbent particles and the flavorant applied thereto. Moreover, the effectiveness of the encapsulated adsorbent particles 28, 30 is maintained over long periods thereby significantly increasing the shelf life of cigarette filters made in this manner. Overall the capsule 16 enables more exact filing of adsorbent particles 28, 30 and more control of flavor 34 per cigarette.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
- Socks And Pantyhose (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
Claims
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE602005023339T DE602005023339D1 (en) | 2004-11-10 | 2005-11-09 | FILTERS WITH CAPSULAR, ADDICTED SOCKS |
DK05808816.2T DK1827145T3 (en) | 2004-11-10 | 2005-11-09 | Filter with encapsulated flavoring adsorbent |
JP2007539655A JP5133694B2 (en) | 2004-11-10 | 2005-11-09 | Capsule type adsorbent aroma filter |
AT05808816T ATE479339T1 (en) | 2004-11-10 | 2005-11-09 | FILTER WITH ENCAPSULATED FLAVORED ADSORBENT |
EA200700478A EA010811B1 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
CN2005800318210A CN101022740B (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
MX2007005666A MX2007005666A (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter. |
EP05808816A EP1827145B1 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
AU2005303448A AU2005303448B2 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
PL05808816T PL1827145T3 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
SI200531112T SI1827145T1 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
BRPI0517309-4A BRPI0517309B1 (en) | 2004-11-10 | 2005-11-09 | Capsule for placing on a cigarette filter, cigarette and process of producing a Capsule for placing on a cigarette filter. |
HK08102364.6A HK1108329A1 (en) | 2004-11-10 | 2008-03-03 | Capsuled adsorbent flavored filter |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US62661304P | 2004-11-10 | 2004-11-10 | |
USUS60/626,613 | 2004-11-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006051422A1 true WO2006051422A1 (en) | 2006-05-18 |
Family
ID=35789084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2005/003644 WO2006051422A1 (en) | 2004-11-10 | 2005-11-09 | Capsuled adsorbent flavored filter |
Country Status (18)
Country | Link |
---|---|
US (1) | US20060112964A1 (en) |
JP (1) | JP5133694B2 (en) |
KR (1) | KR20070083531A (en) |
CN (1) | CN101022740B (en) |
AT (1) | ATE479339T1 (en) |
AU (1) | AU2005303448B2 (en) |
BR (1) | BRPI0517309B1 (en) |
DE (1) | DE602005023339D1 (en) |
DK (1) | DK1827145T3 (en) |
EA (1) | EA010811B1 (en) |
ES (1) | ES2351156T3 (en) |
HK (1) | HK1108329A1 (en) |
MX (1) | MX2007005666A (en) |
PT (1) | PT1827145E (en) |
RS (1) | RS51472B (en) |
UA (1) | UA91841C2 (en) |
WO (1) | WO2006051422A1 (en) |
ZA (1) | ZA200701426B (en) |
Cited By (21)
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WO2008081338A2 (en) * | 2006-12-29 | 2008-07-10 | Philip Morris Products S.A. | Sealed cigarette filter |
CN101444336A (en) * | 2008-11-13 | 2009-06-03 | 梁永林 | Cigarette detoxification holder capable of dispelling smoking addiction and stopping smoking |
CN101500441A (en) * | 2006-08-03 | 2009-08-05 | 菲利普莫里斯生产公司 | Smoking articles with enhanced delivery of additives incorporated into electrospun microfibers and nanofibers and related methods |
WO2009143338A2 (en) | 2008-05-21 | 2009-11-26 | R.J. Reynolds Tobacco Company | Apparatus and associated method for forming a filter component of a smoking article and smoking articles made therefrom |
WO2010098933A1 (en) | 2009-02-25 | 2010-09-02 | R.J. Reynolds Tobacco Company | Cigarette filter comprising a degradable fiber |
WO2011060008A1 (en) | 2009-11-11 | 2011-05-19 | R. J. Reynolds Tobacco Company | Filter element comprising smoke-altering material |
WO2011094171A1 (en) | 2010-01-27 | 2011-08-04 | R. J. Reynolds Tobacco Company | Apparatus and associated method for forming a filter component of a smoking article |
WO2011140430A1 (en) | 2010-05-07 | 2011-11-10 | R. J. Reynolds Tobacco Company | Filtered cigarette with modifiable sensory characteristics |
US8079369B2 (en) | 2008-05-21 | 2011-12-20 | R.J. Reynolds Tobacco Company | Method of forming a cigarette filter rod member |
WO2012016051A2 (en) | 2010-07-30 | 2012-02-02 | R. J. Reynolds Tobacco Company | Filter element comprising multifunctional fibrous smoke-altering material |
US8119555B2 (en) | 2008-11-20 | 2012-02-21 | R. J. Reynolds Tobacco Company | Carbonaceous material having modified pore structure |
US8186360B2 (en) | 2007-04-04 | 2012-05-29 | R.J. Reynolds Tobacco Company | Cigarette comprising dark air-cured tobacco |
WO2012076649A1 (en) * | 2010-12-10 | 2012-06-14 | Philip Morris Products S.A. | Smoking article having outer wrapper with cut-out portion |
US8375958B2 (en) | 2008-05-21 | 2013-02-19 | R.J. Reynolds Tobacco Company | Cigarette filter comprising a carbonaceous fiber |
WO2013043806A2 (en) | 2011-09-23 | 2013-03-28 | R. J. Reynolds Tobacco Company | Mixed fiber product for use in the manufacture of cigarette filter elements and related methods, systems, and apparatuses |
US8511319B2 (en) | 2008-11-20 | 2013-08-20 | R. J. Reynolds Tobacco Company | Adsorbent material impregnated with metal oxide component |
US8882647B2 (en) | 2005-09-23 | 2014-11-11 | R.J. Reynolds Tobacco Company | Equipment for insertion of objects into smoking articles |
EP2932860A4 (en) * | 2012-12-13 | 2016-07-20 | Japan Tobacco Inc | Cigarette |
US10076135B2 (en) | 2014-05-23 | 2018-09-18 | Greenbutts Llc | Biodegradable cigarette filter tow and method of manufacture |
US10609955B2 (en) | 2011-04-08 | 2020-04-07 | R.J. Reynolds Tobacco Company | Filtered cigarette comprising a tubular element in filter |
US11957163B2 (en) | 2011-04-08 | 2024-04-16 | R.J. Reynolds Tobacco Company | Multi-segment filter element including smoke-altering flavorant |
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US8739802B2 (en) * | 2006-10-02 | 2014-06-03 | R.J. Reynolds Tobacco Company | Filtered cigarette |
US7972254B2 (en) * | 2007-06-11 | 2011-07-05 | R.J. Reynolds Tobacco Company | Apparatus for inserting objects into a filter component of a smoking article, and associated method |
US8186359B2 (en) | 2008-02-01 | 2012-05-29 | R. J. Reynolds Tobacco Company | System for analyzing a filter element associated with a smoking article, and associated method |
US8308623B2 (en) * | 2008-10-28 | 2012-11-13 | R.J. Reynolds Tobacco Company | Apparatus for enhancing a filter component of a smoking article, and associated method |
ZA200901679B (en) | 2009-03-09 | 2015-08-26 | Tobacco Res And Development Institute (Pty) Ltd | Apparatus for introducing objects into filter rod material |
US8262550B2 (en) | 2009-03-19 | 2012-09-11 | R. J. Reynolds Tobacco Company | Apparatus for inserting objects into a filter component of a smoking article |
US8808153B2 (en) * | 2009-07-14 | 2014-08-19 | Aiger Group Ag | Apparatus for assembly of multi-segment rod-like articles |
US8440023B2 (en) * | 2009-10-09 | 2013-05-14 | Philip Morris Usa Inc. | Flavored packaging insert for smokeless tobacco |
US9131730B2 (en) | 2010-01-07 | 2015-09-15 | Aiger Group Ag | System and apparatus for registration of different objects in rod shaped articles |
US9049887B2 (en) | 2010-03-26 | 2015-06-09 | Philip Morris Usa Inc. | Apparatus and method for loading cavities of plug space plug filter rod |
US9010337B2 (en) * | 2010-03-26 | 2015-04-21 | Philip Morris Usa Inc. | Smoking article with flavor delivery system |
US8905243B2 (en) | 2010-08-11 | 2014-12-09 | R.J. Reynolds Tobacco Company | Apparatus for sorting objects, and associated method |
US8622882B2 (en) | 2010-09-27 | 2014-01-07 | Aiger Group Ag | Apparatus and method for insertion of capsules into filter tows |
US8475348B2 (en) | 2010-09-28 | 2013-07-02 | Aiger Group Ag | Apparatus and method for assembly of multi-segment rod-like articles |
ZA201008663B (en) | 2010-12-01 | 2014-08-27 | Tobacco Res And Dev Inst (Pty) Ltd | Feed mechanism |
EP2462822A1 (en) * | 2010-12-13 | 2012-06-13 | Philip Morris Products S.A. | Smoking article including flavour granules |
US8893725B2 (en) | 2011-01-28 | 2014-11-25 | R. J. Reynolds Tobacco Company | Polymeric materials derived from tobacco |
JP5719932B2 (en) * | 2011-07-15 | 2015-05-20 | 日本たばこ産業株式会社 | Perfume-carrying low adsorptive particles, cigarette filter, cigarette with filter, and method for producing perfume-carrying low adsorbent particles |
AT513412B1 (en) | 2012-09-17 | 2014-07-15 | Tannpapier Gmbh | Tipping paper |
ITBO20130129A1 (en) * | 2013-03-27 | 2014-09-28 | Gd Spa | SMOKE ITEM |
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US11388927B2 (en) | 2018-04-05 | 2022-07-19 | R.J. Reynolds Tobacco Company | Cigarette filter object insertion apparatus and associated method |
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US6814786B1 (en) * | 2003-04-02 | 2004-11-09 | Philip Morris Usa Inc. | Filters including segmented monolithic sorbent for gas-phase filtration |
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2005
- 2005-11-09 DE DE602005023339T patent/DE602005023339D1/en active Active
- 2005-11-09 ES ES05808816T patent/ES2351156T3/en active Active
- 2005-11-09 MX MX2007005666A patent/MX2007005666A/en active IP Right Grant
- 2005-11-09 US US11/270,115 patent/US20060112964A1/en not_active Abandoned
- 2005-11-09 AU AU2005303448A patent/AU2005303448B2/en not_active Ceased
- 2005-11-09 BR BRPI0517309-4A patent/BRPI0517309B1/en not_active IP Right Cessation
- 2005-11-09 DK DK05808816.2T patent/DK1827145T3/en active
- 2005-11-09 AT AT05808816T patent/ATE479339T1/en not_active IP Right Cessation
- 2005-11-09 UA UAA200706412A patent/UA91841C2/en unknown
- 2005-11-09 KR KR1020077004949A patent/KR20070083531A/en not_active Application Discontinuation
- 2005-11-09 CN CN2005800318210A patent/CN101022740B/en not_active Expired - Fee Related
- 2005-11-09 EA EA200700478A patent/EA010811B1/en not_active IP Right Cessation
- 2005-11-09 RS RSP-2010/0447A patent/RS51472B/en unknown
- 2005-11-09 WO PCT/IB2005/003644 patent/WO2006051422A1/en active Application Filing
- 2005-11-09 PT PT05808816T patent/PT1827145E/en unknown
- 2005-11-09 JP JP2007539655A patent/JP5133694B2/en not_active Expired - Fee Related
-
2007
- 2007-02-19 ZA ZA200701426A patent/ZA200701426B/en unknown
-
2008
- 2008-03-03 HK HK08102364.6A patent/HK1108329A1/en not_active IP Right Cessation
Patent Citations (6)
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GB795420A (en) * | 1956-06-20 | 1958-05-21 | Jose Mazar Barnett | Improvements in and relating to tobacco smoke filters |
US3251365A (en) * | 1963-03-04 | 1966-05-17 | Ii Charles H Keith | Tobacco smoke filter |
DE19527471A1 (en) * | 1995-07-28 | 1997-01-30 | Vauen Adolf Eckert Kg | Tobacco smoke filter for pipes and cigar and cigarette tips - in which the filter material (e.g. active carbon) carries or is mixed with a carrier of aromatic substances and vitamin(s) released during use |
DE19732579A1 (en) * | 1997-07-29 | 1999-02-18 | Schillik Ewald | Filter tip for cigarettes, cigars or pipes |
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US6814786B1 (en) * | 2003-04-02 | 2004-11-09 | Philip Morris Usa Inc. | Filters including segmented monolithic sorbent for gas-phase filtration |
Cited By (34)
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Also Published As
Publication number | Publication date |
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HK1108329A1 (en) | 2008-05-09 |
DE602005023339D1 (en) | 2010-10-14 |
CN101022740B (en) | 2012-06-13 |
BRPI0517309A (en) | 2008-10-07 |
AU2005303448A1 (en) | 2006-05-18 |
ATE479339T1 (en) | 2010-09-15 |
CN101022740A (en) | 2007-08-22 |
KR20070083531A (en) | 2007-08-24 |
ZA200701426B (en) | 2008-09-25 |
MX2007005666A (en) | 2007-07-09 |
DK1827145T3 (en) | 2010-12-06 |
EA200700478A1 (en) | 2007-08-31 |
EA010811B1 (en) | 2008-12-30 |
PT1827145E (en) | 2010-09-28 |
JP5133694B2 (en) | 2013-01-30 |
JP2008519583A (en) | 2008-06-12 |
US20060112964A1 (en) | 2006-06-01 |
RS51472B (en) | 2011-04-30 |
ES2351156T3 (en) | 2011-02-01 |
UA91841C2 (en) | 2010-09-10 |
BRPI0517309B1 (en) | 2013-05-21 |
AU2005303448B2 (en) | 2011-09-29 |
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