EP3436153A1 - Zweiphasige abschminkzusammensetzung - Google Patents

Zweiphasige abschminkzusammensetzung

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Publication number
EP3436153A1
EP3436153A1 EP17717487.7A EP17717487A EP3436153A1 EP 3436153 A1 EP3436153 A1 EP 3436153A1 EP 17717487 A EP17717487 A EP 17717487A EP 3436153 A1 EP3436153 A1 EP 3436153A1
Authority
EP
European Patent Office
Prior art keywords
composition
oil
composition according
buteth
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP17717487.7A
Other languages
English (en)
French (fr)
Inventor
Corinne DONDEYNE
Thibault SCHIRMANN
Véronique TROUILLET
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chanel Parfums Beaute SAS
Original Assignee
Chanel Parfums Beaute SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chanel Parfums Beaute SAS filed Critical Chanel Parfums Beaute SAS
Publication of EP3436153A1 publication Critical patent/EP3436153A1/de
Withdrawn legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/03Liquid compositions with two or more distinct layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/062Oil-in-water emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • A61K8/064Water-in-oil emulsions, e.g. Water-in-silicone emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55Phosphorus compounds
    • A61K8/553Phospholipids, e.g. lecithin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90Block copolymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

Definitions

  • the subject of the present invention is a cosmetic composition, in particular for topical application, consisting of two distinct phases, an aqueous phase and a water-in-oil (W / O) or oil-in-water (O / W) emulsion phase.
  • the composition comprising a specific emulsifier system, and said W / O emulsion comprising at least 20% by weight of the total weight of the oily phase composition.
  • the present invention also relates to the use of said composition in the cosmetic or dermatological field, and in particular for removing make-up, cleaning and / or care of the skin, eyes and / or integuments.
  • compositions consisting of two distinct phases, in particular an aqueous phase and a phase comprising oily compounds, said phases being distinct and not emulsified one in the other at rest, are generally referred to as "two-phase compositions ". They are distinguished from emulsions by the fact that at rest, the two phases are distinct, instead of being emulsified one in the other.
  • the use of these two-phase compositions requires prior agitation to form an emulsion, the latter must be of sufficient quality and stability to allow a uniform application of the two phases on the skin or the keratin material where it is applied. At rest, said phases must separate quickly and return to their initial state, this phenomenon being better known as "phase shift".
  • a rapid phase shift (or demixing) of the two phases after their use is one of the desired qualities of two-phase compositions. Indeed, obtaining a rapid phase shift is desirable for various reasons, in particular because a poor separation of the two phases is perceived as unsightly by users. However, it has proved difficult to find phase shift agents which make it possible to obtain a good phase shift without the formation of foam in the oily phase of the biphase during stirring. However, this formation of foam is prohibitive for the user. In addition, with conventional two-phase compositions, an emulsion is not necessarily formed after stirring the composition, which results in unsatisfactory makeup removal, and leaves a greasy residue on the skin or the keratin material.
  • the Applicant has developed a two-phase formulation having the desired qualities, that is to say, separating rapidly in two clear phases after use, without there being foaming in the oily phase. during agitation.
  • This formulation forms an ephemeral emulsion after stirring, and allows an effective makeup removal without leaving a greasy residue.
  • the present invention thus relates to a cosmetic composition consisting of an aqueous phase and a water-in-oil or oil-in-water emulsion, the composition comprising an emulsifying system comprising an inulin derivative, a lysophospholipid, a poloxamer, a polypropylene glycol buteth and a hydrogenated castor oil derivative, and the water-in-oil or oil-in-water emulsion comprising at least 20% by weight of the total composition weight of an oily phase.
  • an emulsifying system comprising an inulin derivative, a lysophospholipid, a poloxamer, a polypropylene glycol buteth and a hydrogenated castor oil derivative
  • water-in-oil or oil-in-water emulsion comprising at least 20% by weight of the total composition weight of an oily phase.
  • the cosmetic composition according to the invention consists of two distinct phases, an aqueous phase and a water-in-oil or oil-in-water emulsion phase, is easily emulsified by stirring and is easily extruded after stopping the stirring.
  • the composition according to the invention is preferably intended for topical application.
  • the composition according to the invention comprises a water-in-oil or oil-in-water emulsion and a distinct aqueous phase. These two phases are distinct, that is to say they are visible one above the other at rest, respectively. In addition, they are transparent at rest. Each of the phases may or may not be colored. After stirring, such a composition forms an oil-in-water emulsion ephemeral ready to use.
  • composition according to the invention comprises an oily phase, which is present in the water-in-oil or oil-in-water emulsion.
  • This oily phase is present in an amount of at least 20% by weight of the total weight of the composition.
  • the composition according to the invention also comprises a global aqueous phase, which corresponds to the totality of the aqueous phase present in the composition (ie the aqueous phase as such, as well as the aqueous phase of the water-in-oil emulsion or oil-in-water).
  • a global aqueous phase which corresponds to the totality of the aqueous phase present in the composition (ie the aqueous phase as such, as well as the aqueous phase of the water-in-oil emulsion or oil-in-water).
  • the overall aqueous phase: oily phase weight ratio is between 40: 60 and 80: 20. In fact, in these ratios, the tests carried out show stable compositions, especially at D + 2 at room temperature.
  • the water-in-oil or oil-in-water emulsion phase of the composition according to the invention comprises at least 20% by weight of the total weight of the oily phase composition.
  • the oily phase is present between 20% and 40%, preferably between 25% and 35% by weight of the total weight of the composition, preferably about 30% by weight.
  • composition according to the invention further comprises an emulsifying system comprising an inulin derivative, a lysophospholipid, a poloxamer, a polypropylene glycol buteth and a hydrogenated castor oil derivative.
  • an emulsifying system comprising an inulin derivative, a lysophospholipid, a poloxamer, a polypropylene glycol buteth and a hydrogenated castor oil derivative.
  • This specific emulsifying system is well tolerated, allows effective removal of makeup, increases hydration, prevents the formation of foam and stabilizes the resulting emulsion. In addition, it allows to prepare the composition according to the invention cold.
  • the poloxamer is all the more surprising that it avoids the formation of foam, which is not the case for other emulsifiers, as will be shown later comparative examples.
  • the presence of polypropylene glycol buteth and a hydrogenated castor oil derivative stabilizes the water-in-oil emulsion, and a good phase difference between this emulsion and the aqueous phase.
  • the emulsifying system is present in the composition according to the invention between 2% and 10%, preferably between 3% and 7% by weight of the total weight of composition.
  • the inulin derivative is a carbamoylated inulin with an alkyl (preferably lauryl) isocyanate, preferably said derivative is pinulin lauryl carbamate.
  • Inulin lauryl carbamate has the following formula (I):
  • Inulin lauryl carbamate at 25% by weight is especially marketed in the form of a mixture with glycerine at 75% by weight by Gova Group under the name Inutec SL1®.
  • Polypropylene glycol buteth is a polyoxypropylenated, polyoxyethylenated butyl alcohol ether having the following formula (II):
  • the hydrogenated castor oil derivative is an oxyethylenated hydrogenated castor oil, preferably comprising between 20 and 50 moles of ethylene oxide. More preferably, said derivative is PEG-30 hydrogenated castor oil or PEG-40 hydrogenated castor oil.
  • a mixture of PPG-26-buteth-26 and PEG-40 hydrogenated castor oil is used. More preferably, the mixture of PPG-26-buteth-26 of between 60% and 65% by weight is used, and PEG-40 hydrogenated castor oil of between 35% and 40% by weight, preferably marketed by Sensient Cosmetic Technologies. under the name Solubilizer LRI®.
  • the poloxamers are three-block nonionic copolymers, typically having a hydrophobic polypropylene glycol core block, and two hydrophilic outer blocks of polyethylene glycol. They correspond to the following formula (III):
  • x, y and z are integers, identical or different, between 1 and 50, preferably between 10 and 35.
  • the poloxamers are sold in particular under the names Pluronic (BASF) Kolliphor (BASF) and Synperonic ( Croda International).
  • the lysophospholipid designates a phospholipid having lost one or more acyl groups in particular by hydrolysis.
  • the lysophospholipid used in the composition of the invention is lysophosphatidylcholine, which has the formula: U ⁇
  • R is a fatty acid chain, especially comprising from 10 to 25 carbon atoms, preferably from 15 to 20.
  • the lysophospholipid used in the composition of the invention is preferably derived from soya beans.
  • it is INCI glycine soy (soybean) seed extract.
  • the mixture of glycerin at 80% by weight and glycine soybean (soybean) seed extract at 20% by weight marketed by Kemin under the name Lysofix Liquid® is used.
  • the amount of poloxamer is equal to the amount of lysophospholipid.
  • the emulsifier system comprises a ratio of inulin derivative: lysophospholipid: poloxamer: polypropylene glycol buteth: hydrogenated castor oil derivative of about (0.30 to 0.40): (0.90 to 1.10): (0.90 to 1.10) (0.80 to 0.90): (0.50 to 0.65), preferably about 0.36: 1: 1: 0.86: 0.57.
  • the composition further comprises gluconolactone and / or sodium benzoate. Such compounds are effective preservatives, and acceptable in cosmetics.
  • the composition comprises a mixture of gluconolactone, sodium benzoate and calcium gluconate.
  • a mixture is in particular marketed by Lonza under the name Geogard Ultra®.
  • gluconolactone and / or sodium benzoate, and optionally calcium gluconate are present in an amount of from 0.5% to 3% by weight.
  • the oily phase of the composition according to the invention may consist of one or more oils, which may be mineral, vegetable or synthetic oils.
  • the oily phase comprises one or more oils selected from hydrocarbon oils of mineral or synthetic origin and silicone oils. More particularly, the oily phase advantageously contains one or more volatile oils chosen from oils volatile hydrocarbons of mineral or synthetic origin and volatile silicone oils.
  • hydrocarbon-based oil means an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and not containing a silicon or fluorine atom; it may contain ester, ether, amine, amide groups.
  • iso-alkanes also called isoparaffins
  • Cs-C16 such as isododecane, isodecane, isohexadecane, such as iso-alkanes sold under the trade names Isopar by the company Exxon Chemical or the oils sold under the trade names Permethyl by the company Presperse, and mixtures thereof.
  • non-volatile hydrocarbon oils of mineral or synthetic origin mention may be made of liquid petroleum jelly, hydrogenated polyisobutene such as Parleam® oil, and mixtures thereof.
  • silicone oil is meant an oil containing at least one silicon atom, and in particular containing Si-O groups.
  • the silicone oil may be selected from non-volatile silicone oils, volatile silicone oils and mixtures thereof.
  • volatile silicone oils examples include cyclopolydimethylsiloxanes (INCI name: cyclomethicone), such as cyclopentasiloxane, cyclohexasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane; linear silicones such as heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl-disiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof.
  • cyclopolydimethylsiloxanes such as cyclopentasiloxane, cyclohexasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopent
  • Non-volatile silicone oils that may be mentioned include polydimethylsiloxanes (PDMS) and phenylated polymethylsiloxanes such as phenyltrimethicones, phenyldimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl-dimethicones, diphenylmethyldiphenyltrisiloxanes, 2-phenylethyltrimethylsiloxysilicates, and polymethylphenylsiloxanes. ; polysiloxanes modified with fatty acids, fatty alcohols or polyoxyalkylenes, and mixtures thereof. Mention may be made, for example, as vegetable or synthetic oils that can be used in the composition of the invention:
  • Hydrocarbon oils of plant origin such as liquid triglycerides of fatty acids containing from 4 to 10 carbon atoms, for instance triglycerides of heptanoic or octanoic acids or, for example, sunflower, corn or soybean oils, squash, grape seed, sesame, hazelnut, apricot kernel, macadamia, arara, coriander, castor oil, avocado, caprylic / capric acid triglycerides such as those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812N and 818 by Dynamit Nobel, jojoba oil or shea butter oil;
  • liquid triglycerides of fatty acids containing from 4 to 10 carbon atoms for instance triglycerides of heptanoic or octanoic acids or, for example, sunflower, corn or soybean oils, squash, grape seed, sesame, hazelnut, apricot kernel, macadamia, arara,
  • the oily phase comprises at least one volatile oil, preferably isohexadecane.
  • the oily phase comprises at least triglycerides of caprylic / capric acids, and / or mixtures of alcohol esters of coconut with caprylic and capric acid (coco-caprylate / caprate) and coconut alkanes.
  • the composition further comprises at least one antifoaming agent, preferably simethicone.
  • at least one antifoaming agent preferably simethicone.
  • simethicone is in particular marketed under the name Xiameter ACP-1500 Antifoam Compound®.
  • the composition may further comprise a salt, such as, for example, sodium chloride, which has no effect on the phase shift but which is used as an adjunct in an eye makeup removal composition so that the composition has a close osmotic pressure. from that of tears.
  • a salt such as, for example, sodium chloride
  • the amount of salt (s) may range, for example, from 0.01 to 5% by weight and preferably from 0.01 to 3% by weight and better still from 0.05 to 2% by weight relative to the total weight of the product.
  • the aqueous phase of the composition according to the invention comprises water and any water-soluble or water-dispersible additive.
  • the water used may be sterile demineralized water and / or floral water such as rose water, cornflower water, chamomile water or linden water, and / or or natural thermal or mineral water, such as: Vittel water, Vichy basin water, Uriage water, Roche Posay water, Bourboule water, water of Enghien-les-Bains, the water of Saint Gervais-les-Bains, the water of Néris-les-Bains, the water of Allevar-les-Bains, the water of Digne, the water of Maizines, Neyrac-les-Bains water, Lonsle-Saunier water, Les Eaux Bonnes, Rochefort water, Saint Christau water, Fumades water and Tercis water baths, Avène water.
  • floral water such as rose water, cornflower water, chamomile water or linden water
  • natural thermal or mineral water such as: Vittel water, Vichy basin water, Uriage water, Roche Posay water, Bourboule water, water of Enghien-les-
  • polyols such as glycerine and glycols such as hexylene glycol, polyethylene glycols and polypropylene glycol.
  • the polyols may be present in an amount ranging from 0.01 to 10% by weight, preferably from 0.05 to 8% by weight relative to the total weight of the composition.
  • the composition comprises at least one polyol, preferably glycerin.
  • composition according to the invention may also contain conventional cosmetic adjuvants or additives which will be in one or the other phase according to their hydrophilic or lipophilic nature, such as, for example, cosmetic active agents, perfumes, dyes, softening agents, buffers, humectants, UV filters (or sunscreens), a pH adjuster (for example citric acid or hydroxide). sodium), and mixtures thereof.
  • cosmetic adjuvants or additives which will be in one or the other phase according to their hydrophilic or lipophilic nature, such as, for example, cosmetic active agents, perfumes, dyes, softening agents, buffers, humectants, UV filters (or sunscreens), a pH adjuster (for example citric acid or hydroxide). sodium), and mixtures thereof.
  • the composition according to the invention has a pH of approximately 4.3 +/- 0.3.
  • the composition comprises gluconolactone and / or sodium benzoate, these compounds are effective at low pH.
  • a pH of about 4.3 +/- 0.3 maintains the effectiveness of the preservative, while ensuring skin tolerance.
  • softening agents mention may in particular be made of allantoin, bisabolol, plankton, and certain plant extracts such as rose extracts and melilot extracts.
  • active agents for example lactoperoxidase, lipase, protease, phospholipase, cellulases
  • avonoids such as isoflavones
  • moisturizing agents such as protein hydrolysates; sodium hyaluronate
  • procyannidol oligomers vitamins such as vitamin A (retinol), vitamin E (tocopherol), vitamin C (ascorbic acid), vitamin B5 (panthenol), vitamin B3 (niacinamide), derivatives of these vitamins (especially esters) and their mixtures; urea; caffeine; depigmenting agents such as kojic acid, hydroquinone and caffeic acid; salicylic acid and its derivatives; alpha-hydroxy acids such as lactic acid and glycolic acid and their derivatives; retinoids
  • enzymes for example lactoperoxidase, lipase, protease, phospholipase, cellulases
  • avonoids such as isoflavone
  • UV filters may be present in the composition according to the invention, especially when it is intended for sun protection. These filters may especially be organic filters, and they may be present in an amount of active material ranging from 0.01% to 20% by weight of active material, preferably from 0.1% to 15% by weight, and better still, 2 to 10% by weight relative to the total weight of the composition.
  • a sulfonic function such as sulphonated derivatives or sulphonated benzylidene camphor, benzophenone or phenylbenzimidazole, more particularly benzylidene camphor derivatives, such as benzene 1,4 [di (3-methylidene-campho-10-sulphonic
  • 4'-sulpho-3-benzylidenecamphoric acid (INCI name: Benzylidene Camphor Sulfonic Acid), manufactured under the name "MEXORYL SL" by the company CHIMEX, 2- [4- (camphomethylidene) phenyl] benzimidazole acid; sulfonic acid, phenylbenzimidazole sulfonic acid (INCI name: Phenylbenzimidazole Sulfonic Acid), sold under the name Eusolex 232 by the company Merck; para-aminobenzoic acid derivatives; salicylic derivatives such as ethyl hexyl salicylate sold under the trade name NEO HELIOPAN OS by Haarmann and Reimer; derivatives of dibenzoylmethane such as Butyl Methoxydibenzoylmethane sold in particular under the trade name PARSOL 1789 by Hoffmann La Roche; cinnamic derivatives such as ethylhexy
  • compositions described above can be packaged, in known manner, into a single-compartment bottle. The user must then shake the bottle before pouring the contents on a cotton. It is also possible that the two phases of the composition are introduced into two independent compartments of the same bottle, a system being provided for their mixing at the time of dispensing.
  • the composition according to the invention can be used for any topical application; in particular, it may constitute a cosmetic or dermatological composition. It can in particular be used for the care, cleaning and / or removal of make-up of the skin, eyes and / or integuments.
  • the present invention also relates to a cosmetic process for removing make-up, cleaning and / or care of the skin, eyes and / or integuments, comprising the application to the skin, eyes and / or integuments, of a cosmetic composition as defined above.
  • the composition constitutes a composition for removing make-up from the eyes.
  • the present invention also relates to a method for preparing a composition as defined above, comprising the following steps:
  • compositions according to the invention could comprise two steps directly.
  • the following example of compositions according to the invention is given by way of illustration and without limitation. Quantities are given in% by weight unless otherwise stated.
  • Example 1 Choice of emulsifying system a) In the following examples, the following raw materials are used:
  • poloxamer 184 Synperonic® PE L64;
  • caprylic / capric acid triglycerides Miglyol 812N.
  • formulations 1 to 7 are prepared, and the foam obtained after stirring is evaluated.
  • Formulations 5 and 6 comprise 3 emulsifiers according to the invention, while formulations 1 to 4 and 7 are comparative.
  • Caprylic / capric Lysofix 3.5% aerated foam and triglycerides: 10% Inutec SL1: 3% fades faster
  • Formulations 8 to 17 of the following table are prepared.
  • the initial formulation is formula 5 of the preceding table. Only the formulation 13 is according to the invention.
  • foam foam foam foam plus foam immediate foam aqueous foam important
  • the 13 (13 *) formulation is the only formulation according to the invention, the others are comparative.
  • the formulation 13 which comprises a polypropylene glycol buteth and a hydrogenated castor oil derivative, and which is a formulation according to the invention, has little foam and an aqueous phase having a good appearance. This is the only formulation tested that does not include a lot of foam, and is stable.
  • compositions 18 to 28 The stability of the following compositions 18 to 28 is evaluated.
  • Triglycerides 10% Synperonic PE Pentylene Glycol 2.25%
  • Triglycerides 10% Synperonic PE Methylparaben 0.25% compliant
  • composition comprising the surfactant system and a preservative according to the invention is stable.
  • composition according to the invention is prepared with the following ingredients (the percentages are by weight of the total composition):

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Molecular Biology (AREA)
  • Biophysics (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
EP17717487.7A 2016-04-01 2017-03-31 Zweiphasige abschminkzusammensetzung Withdrawn EP3436153A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1652853A FR3049459B1 (fr) 2016-04-01 2016-04-01 Composition de demaquillage biphase
PCT/FR2017/050741 WO2017191382A1 (fr) 2016-04-01 2017-03-31 Composition de demaquillage biphase

Publications (1)

Publication Number Publication Date
EP3436153A1 true EP3436153A1 (de) 2019-02-06

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EP17717487.7A Withdrawn EP3436153A1 (de) 2016-04-01 2017-03-31 Zweiphasige abschminkzusammensetzung

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FR3082428B1 (fr) * 2018-06-19 2020-12-11 La Phoceenne De Cosmetique Sa Composition biphase et son utilisation en non rincee pour demeler tous types de cheveux
EP3817717A1 (de) 2018-07-03 2021-05-12 The Procter & Gamble Company Verfahren zur behandlung einer hautkrankheit
CN114173749A (zh) 2019-06-28 2022-03-11 宝洁公司 水溶性个人清洁产品和用途
CN114144156A (zh) 2019-07-31 2022-03-04 宝洁公司 包括包含天然或改性淀粉的纤维元件的水溶性个人清洁产品、用途、方法和套盒
EP3895683A1 (de) 2020-04-14 2021-10-20 Chanel Parfums Beauté Kosmetische multiphasen-zusammensetzung, die mindestens zwei nicht mischbare ölige phasen umfasst
US10959933B1 (en) 2020-06-01 2021-03-30 The Procter & Gamble Company Low pH skin care composition and methods of using the same
CN115843238A (zh) 2020-06-01 2023-03-24 宝洁公司 改善维生素b3化合物渗透到皮肤中的方法
CN112451394B (zh) * 2020-12-02 2022-11-18 广东柏俐臣生物科技有限公司 一种温和的卸妆液
FR3122091B1 (fr) * 2021-04-22 2023-12-29 Naos Inst Of Life Science Composition cosmetique biphasique ecobiologique a separation de phases retardee
WO2023039780A1 (en) 2021-09-16 2023-03-23 Beiersdorf Ag Bi-PHASE MAKE-UP REMOVER

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FR3015235B1 (fr) * 2013-12-19 2016-01-15 Oreal Composition biphase comprenant un derive d'acide cucurbique

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FR3049459B1 (fr) 2018-03-23
WO2017191382A1 (fr) 2017-11-09
US20190083369A1 (en) 2019-03-21
KR20180123685A (ko) 2018-11-19
FR3049459A1 (fr) 2017-10-06
JP2019510065A (ja) 2019-04-11
US10537502B2 (en) 2020-01-21

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