EP3381834A1 - Produit détergent - Google Patents

Produit détergent Download PDF

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Publication number
EP3381834A1
EP3381834A1 EP18159631.3A EP18159631A EP3381834A1 EP 3381834 A1 EP3381834 A1 EP 3381834A1 EP 18159631 A EP18159631 A EP 18159631A EP 3381834 A1 EP3381834 A1 EP 3381834A1
Authority
EP
European Patent Office
Prior art keywords
bag
chambers
bag chambers
chamber
detergent product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP18159631.3A
Other languages
German (de)
English (en)
Other versions
EP3381834B1 (fr
Inventor
Frank Meier
Katja Gerhards
Matthias Sunder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3381834A1 publication Critical patent/EP3381834A1/fr
Application granted granted Critical
Publication of EP3381834B1 publication Critical patent/EP3381834B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/045Multi-compartment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44FSPECIAL DESIGNS OR PICTURES
    • B44F9/00Designs imitating natural patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B65D81/3261Flexible containers having several compartments
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Definitions

  • the invention relates to a detergent product, in particular for textile treatment, more particularly for textile cleaning and / or for textile laundry, comprising a bag having a plurality of bag chambers, each enclosed by a water-soluble film, wherein the bag chambers interconnected by in a sealing plane water-soluble Films are formed and separated from each other by lying in the sealing plane sealing sections and wherein the bag chambers are each filled with a detergent formulation.
  • Water-soluble detergent products in the format of a one-time sachet for textile treatment are known. Such a sachet is for a one-time textile treatment application usually within a fabric washing machine.
  • the detergent product has a foil bag with one or more bag compartments.
  • a detergent composition is added, which contains detergent substances for textile treatment, in particular for the textile laundry.
  • the use of multiple bag chambers opens up the possibility of separate provision of different detergent formulations, which may chemically react with each other or mixed for other reasons are not storage stable.
  • the use of several, different detergent formulations within a washing process allows the release of a plurality of functionally different detergent and / or additional substances, such as bleach, fabric softener or fragrances.
  • the individual detergent formulations within the bag chambers may have the same or different consistency and are preferably of liquid consistency, for example liquid, gelatinous, pasty, waxy or of solid consistency, for example powdery, granular, free-flowing or solid-like.
  • the film bag can be formed from a plurality of water-soluble films, wherein the water-soluble film may preferably be PVA film (polyvinyl alcohol film).
  • the usable films are usually made of polyvinyl alcohol copolymers with appropriate additives such as plasticizers, water, surfactants, bittering agents, antioxidants, lubricants, release agents, or salts.
  • the film bag can be made of a water-soluble base film and a water-soluble cover film, which form the boundary walls of at least one bag chamber.
  • the base film can be thermoformed to form at least one bag chamber, for example in a plastically deforming manner. Subsequently, the base film and the cover film are sealed together or joined together in one or more sealing or connecting sections. The Sealing sections are then in a so-called sealing plane or joint plane of the two films.
  • Detergent products with multiple bag chambers are for example from DE 10 2014 102 567 A1 known.
  • the detergent product described in the aforementioned document may comprise a plurality of chambers which may be arranged in superimposed orientation, ie one positioned over the other.
  • the chambers are arranged side by side, that is, one positioned next to the other.
  • Chambers may also be arranged such that a first chamber is adjacent to a second chamber, but the first chamber at least partially surrounds the second chamber but does not completely surround the second chamber.
  • a chamber may be completely enclosed by another chamber.
  • the compartments may have different sizes and each contain a laundry, fabric care or dishwashing composition, including pretreatment or soaking compositions and other rinse compositions.
  • the composition may also be a detergent composition or a machine dishwashing composition.
  • the detergent composition may be used during the main wash or it may be used as a pretreatment or soaking composition.
  • a detergent product with a water-soluble bag having a plurality of juxtaposed bag chambers for example, from EP 2 617 659 B1 known.
  • Two separate chambers are each filled with a cleaning agent, wherein the film bag is made of a water-soluble base film and a water-soluble cover sheet, which are tightly interconnected in a sealing plane.
  • the bag chambers are separated from each other by sealing sections lying in the sealing plane.
  • the base film is deep drawn to form the bag chambers in a plastically deforming manner.
  • a first bag chamber has a first base surface and a second bag chamber has a second base surface.
  • the foil bag has a third base surface, wherein the first base surface of the first bag chamber has a concave portion on its side facing the second bag chamber, and wherein the second base surface of the second bag chamber has a convex portion on its side facing the first bag chamber.
  • the convex portion of the second bag chamber extends into the concave portion of the first bag chamber.
  • the second base surface of the second bag chamber has laterally of its convex portion at least a concave portion adjacent to at least a convex portion of the first base surface.
  • Detergent products with geometrically simple side-by-side bag compartments usually have insufficient intrinsic dimensional stability of the film bag, with the result that such product designs are considered by users to be of inferior quality.
  • a low dimensional stiffness of the detergent product is accompanied by an insufficient machinability in the production and further processing of the products.
  • a large base area of the film bag and wide sealing sections between the bag chambers also make the (complete) dissolubility of the detergent product during a washing process questionable from the user's point of view.
  • the dissolution behavior of multi-chambered capsules i. the rate of dissolution and the degree of dissolution during a washing process, often not the high expectations of consumers of water-soluble detergent products.
  • the bag chambers of known multi-chamber capsules form surfaces for attacking parts of laundry items, such as buttons or applications, which causes the detergent product is hooked in the laundry and then transported with a laundry.
  • the geometry or shaping of the bag chambers also contributes to a non-optimal dissolution behavior of the known detergent products, with regions forming between adjacent bag chambers which flow around less well and are not sufficiently dissolved at the end of a washing process.
  • the product design of water-soluble multi-chamber capsules allows for designs that, from the users' point of view, are perceived as aesthetically pleasing in comparison to single-chamber capsules and as an indicator of an innovative product concept.
  • the film consumption for the production of multi-chamber capsules is 10 to 50% greater than the film consumption for the production of single-chamber systems with the same total amount of detergent contained in the bag chamber or the bag chambers.
  • the higher film consumption is due to detergent products having a plurality of superimposed chambers on the use of a third film layer for producing the chambers and detergent products with juxtaposed bag chambers on a non-optimized shaping of adjacent bag chambers with wide seal or sealing sections between the chambers.
  • the higher film consumption leads to higher production costs.
  • a high consumption of film is in contradiction to the steadily increasing environmental awareness of users and the desire for resource-saving production processes.
  • the present invention seeks to provide a generic detergent product, which has a high intrinsic dimensional stability and improved use especially in textile washing machines, including further especially an improved dissolution behavior during the washing process.
  • the detergent product of the invention should be characterized in particular by a high dissolution rate and a largely residue-free dissolution during a given washing process in a textile washing machine.
  • the detergent product should be easy to manufacture in a cost-effective and resource-saving manner with good machinability and satisfy the high demands of the users on an innovative product design.
  • a plurality of successive bag chambers of the number n with n ⁇ 3 proposed as a (finite) sequence of bag chambers with monotonically increasing size of lying in the sealing plane base surface and / or monotonically increasing size of the filling volume are.
  • the base area and / or fill volume of each successive bag chamber is greater than or equal to the base area and / or fill volume of the adjacent preceding bag chamber.
  • the first bag chamber may have the smallest base area and / or the smallest fill volume
  • a second bag chamber may have a larger base area and / or a larger fill volume.
  • a third subsequent bag chamber can, for example, again have the same base area and / or the same filling volume as the second bag chamber, or even a larger base area and / or a larger filling volume.
  • a fourth bag chamber of the sequence can then have, for example, a maximum base area and / or a maximum filling volume.
  • detergent product is to be understood broadly within the meaning of the invention and in particular also includes those products which are used for dishwashing in dishwashers application.
  • detergent preparation is therefore also to be understood broadly and includes, for example, machine dishwashing detergents and rinse aid.
  • the shape and the size of the base surfaces in the sealing plane are predetermined in the production of the bag chambers by plastic deformation of a base film in a thermoforming tool and connection with a cover sheet through the contour of the opening of the cavities of the thermoforming mold.
  • a product design is possible that is characterized by a high intrinsic stability.
  • the bending or bending of the bag chambers relative to each other in the manufacture, processing and application can be significantly reduced, so that the machinability is improved and the Detergent product according to the invention is perceived by users to be of particularly high quality.
  • the invention provided arrangement of the bag chambers in a particular order according to the size of their base surfaces and / or the size of their filling volumes an aesthetically pleasing product design, which contributes to a high user acceptance.
  • the bag chambers can be designed to optimize flow and arrange flow-optimized relative to each other, which leads to a uniform and intensive flow and overflow of the bag chambers associated with a fast and largely complete dissolution of the film material when used in a textile washing machine.
  • the product design can provide very narrow sealing portions between adjacent chambers, resulting in a reduction in the dimensions of the detergent product of the invention, and thus optimum utilization of the apparatus and machine capacities of those used to manufacture and transport the detergent products used apparatus and machinery.
  • the external appearance of the detergent products is upgraded.
  • the bag chamber can be formed by at least two, preferably only two, film layers sealed together in one or more sealing sections. Preferably, only juxtaposed and separate bag chambers are provided and no overlapping / overlapping bag chambers, so that the production of the film bag by only two film layers is possible. This leads to reduced manufacturing costs and a reduced production cost.
  • the film bag may be made of a water-soluble base film and a water-soluble cover film, which are sealed together in the sealing plane.
  • the base film can be thermoformed to form bag chambers in a plastically deforming manner.
  • the bag compartments are separated from each other by seal sections lying in the seal plane.
  • the sealing sections may in particular be non-rectilinear and thus ensure a desired high intrinsic dimensional stability of the detergent product.
  • the outer contour of the film bag in the sealing plane or its base surface may preferably be circular, triangular or quadrangular.
  • the shaping can be done for example by laser cutting or punching. Other outer contours of the foil bag are not excluded.
  • the bag chambers of the sequence lie in the circumferential direction of the film bag one behind the other.
  • the bag chambers may be arranged distributed over the circumference of the film bag around a central region of the film bag, so that the base surface and / or the filling volume of each subsequent in the circumferential direction of the film bag bag chamber sequence is greater than the base surface or the filling volume of the adjacent previous bag chamber or the base area or the filling volume of the adjacent preceding bag chamber corresponds. This is true until the largest bag chamber is reached, which then adjoins the smallest.
  • the arrangement of the bag chambers follows circumferentially the outer contour of the film bag in the sealing plane.
  • the bag chambers may be arranged, for example, on a substantially circular or polygonal path around a middle region of the film bag. But even a straight, spiral, zigzag, wave or step-shaped arrangement of bag chambers with monotonically increasing size of the base surface and / or monotonically increasing size of the filling volume is not excluded.
  • the number of successive bag chambers that form a sequence can be between three to nine bag chambers, preferably three or four bag chambers.
  • all bag chambers of the film bag form the sequence of bag chambers provided according to the invention.
  • a certain number of the bag chambers of the sequence may have the same size base areas and / or equal filling volumes.
  • an arrangement of at least three bag chambers as a result of bag chambers with strictly monotonically increasing size of the base surface and / or the filling volume is provided.
  • the base area and / or the filling volume of each subsequent bag chamber of the sequence are larger than the base area and / or the filling volume of the adjacent preceding bag chamber.
  • the invention may provide that the increase in the size of the base area and / or the increase in the size of the filling volume in the sequence of n bag chambers corresponds to the formation instruction of a sequence of numbers.
  • An "educational regulation” is to be understood as a mathematical function which unambiguously describes a mathematical relationship between the position or the arrangement of the respective bag chamber in the sequence of n bag chambers and the size of the base area or the volume of the respective bag chamber.
  • Another advantageous product design can provide that the increase in the size of the base area and / or the size of the filling volume from bag chamber to bag chamber correlates with the sequence of numbers of the primes or Fibonacci sequence or even this number sequences.
  • the volume of the second bag chamber may be three times the volume of the first bag chamber and the volume of the third bag chamber may be five times the volume of the first bag chamber.
  • the volume of the fourth bag chamber may correspond to seven times the volume of the first bag chamber.
  • the volume of each successive bag chamber in the sequence of n bag chambers may correspond to a non-constant multiple of the volume of the first bag chamber.
  • At least two bag chambers of the series of n bag chambers, preferably all bag chambers, have base surfaces with a different shape.
  • the base surface of the bag chamber is axis asymmetric.
  • the base surface can then not be reflected on itself by a vertical axis reflection on a mirror axis passing through the base surface. Due to the axis asymmetry, flow conditions can be achieved at the bag chamber, which result in the application of the detergent product in a washing process to an improved and more uniform dissolution of the film material.
  • the width of the sealing sections between adjacent bag compartments can be reduced. It is a modern product design with unusual bag chamber shapes possible, which directs the user's view more on the bag chambers and their content. This contributes to a high consumer acceptance of the inventive detergent product.
  • a preferred embodiment of the invention provides drop-shaped, leaf-shaped or yin and yang-shaped base surfaces of the bag chambers.
  • a particularly preferred contour of the bag chamber in the sealing plane is characterized by a narrow convex end portion and a opposite in the longitudinal direction of the bag chamber wide convex end portion of the contour.
  • the contour may be characterized by a first circular shape with a smaller inner radius placed on the narrow end section and a second circular shape with a larger inner radius at the wider end section, where the ratio of the larger inner radius to the smaller inner radius is greater than 3: 1, preferably more 5: 1, more preferably more than 8: 1, or even more than 12: 1.
  • the inner radii are given by the cavities of the thermoforming mold.
  • the contour may be provided by a concave or straight inner portion facing the center of the film bag and a convex or straight outer portion facing the outer edge of the film bag, resulting in a teardrop-shaped, leaf-shaped or yin and yang-shaped one Base surface of the bag chamber may result.
  • An advantageous embodiment of the bag chamber contour in the sealing plane can provide that in each case a broader convex end portion of the contour of a first bag chamber adjoins or opposes a concave or straight inner portion and / or a narrow convex end portion of the contour of an adjacent second bag chamber.
  • the narrow convex end portion of the contour of the second bag chamber can also surround the wide convex end portion of the contour of the adjacent first bag chamber in sections from the outside.
  • the broad convex end portion of the contour of the first bag chamber may intersect a tangent which is laid on the wide convex end portion and on the narrow convex end portion of the contour of the adjacent second bag chamber. The wide convex end portion of the first bag chamber then extends into a concave portion of the contour of the second bag chamber.
  • the bag chambers can be arranged rotationally asymmetrically.
  • the base surfaces of the bag chambers are then not arranged around a common perpendicular to the sealing plane n-fold axis of rotation. This means that the arrangement of the bag chambers (with respect to the base surfaces) with a rotation about an axis of rotation by 360 ° / n (with n as the number of Each bag chamber) substantially different from the arrangement before the rotation of the film bag or the detergent product.
  • the base surfaces of the n bag chambers of the sequence can thus not coincide with itself by rotation of the film bag by a specific angle of 360 ° / n and no symmetry-equivalent or substantially congruent arrangements of the base surfaces result.
  • the non-rotationally asymmetric arrangement of the base surfaces can promote turbulent flow around the bag chambers when used in a textile washing machine, so that the dissolution time of the detergent product of the invention is reduced and the degree of dissolution at the end of a washing process is increased. Consumer acceptance of the use of the detergent products according to the invention is correspondingly high.
  • the transitions of the bag chambers in the circumferential direction of the film bag can be characterized by narrow sealing sections.
  • the sealing sections may have a maximum width of less than 5 mm, preferably less than 3 mm, more preferably only 2 mm or less, in particular in the radially outer regions between two adjacent bag chambers. Accordingly, the detergent product is less likely to get caught on laundry items. As a result, intensive contact between the film bag and the laundry drum and the laundry results during a washing process, which results in an improved dissolution behavior of the film bag. Incidentally, a higher intrinsic stability of the detergent product can be achieved in this way.
  • the product design can be designed in a modern and interesting way due to the unusual shape of the bag chambers, whereby the user hardly perceives narrow sealing sections between the bag chambers and the user's attention is directed to the bag chamber and its contents.
  • the outer portions of the contours of the bag chambers in the sealing plane may be at least substantially on a common circumferential line, which is a substantially circular , elliptical, superelliptic, square, rectangular or triangular.
  • a bisector of the base surface of a bag chamber in the sealing plane is left- or right-handed and if, preferably, a left - Is provided or right-handed arrangement of all bag chambers.
  • the base surfaces of all bag chambers may have outer contours and / or inner contours with at least sections of the same direction of curvature.
  • the area bisector of all Bag compartments of the film bag are then bent in a same direction, that is, either to the left or to the right, resulting in an aesthetically pleasing appearance of the detergent product of the present invention.
  • a rectified curvature of the bag compartments can contribute to the detergent product coming into intimate contact with the laundry parts in the washing drum and, as it were, "wandering" the laundry without getting caught on certain laundry items.
  • a shape of the base surface of the bag chamber lying in the sealing plane is advantageous for the width of the base surface transversely to the area bisecting from a narrow convex end portion of the contour of the bag chamber in the sealing plane first along the solicitn Halbierenden toward an opposite wide convex end portion of the contour increases steadily until a maximum value of the width is reached. Then then the width can decrease to the wide convex end portion again.
  • the cross-sectional area of the bag chamber perpendicular to the sealing plane starting from the narrow convex end portion of the contour may increase steadily along the area bisecting line until a maximum value is reached, and then decrease again until reaching the wide convex end portion.
  • the bag chamber can then have a helical structure both in the two-dimensional space in the sealing plane and in the three-dimensional space.
  • the cross-sectional area of the bag chamber may initially increase over a longer section of the area bisector until it reaches the maximum value and then fall off again after reaching the maximum value over a shorter section. The same can apply to the width of the base area.
  • the subsequent bag chamber may then follow with a similar cross-sectional profile, wherein the maximum cross-sectional area of a subsequently following bag chamber may be greater than the maximum cross-sectional area of a preceding bag chamber or may be the same size. If the contour of the bag chamber in the sealing plane has a narrow convex end portion and a wide convex end portion opposite to the narrow convex end portion, the maximum cross section or maximum width of the bag chamber may be in the region of the center of a circular arc set from the inside to the wide convex end portion lie.
  • At least one arranged in the central region of the film bag central chamber may be provided, wherein the bag chambers are then arranged around the central chamber.
  • the central chamber is separated from each bag chamber by a sealed portion, and the central chamber may be equidistant from each bag chamber.
  • the minimum width of the sealing portion between a bag chamber and the central chamber may be less than 5 mm, preferably less than 3 mm, more preferably less than 2 mm.
  • the central chamber can line up in the sequence of bag chambers with monotonically increasing size of the lying in the sealing plane base surfaces and / or monotonically increasing size of the filling volumes and form, for example, the first or last member of the sequence.
  • the central chamber and the bag chambers may form a (finite) sequence of chambers immediately behind one another with monotonically increasing size of the base surface of the chambers lying in the sealing plane and / or monotonically increasing size of the filling volumes of the chambers.
  • the total number of chambers (bag chambers, central chamber) of the film bag can be in the range between three and ten chambers, preferably in the range between three and five chambers.
  • the bag chambers may have a minimum distance to the contour line of the central chamber that varies along their contour lines but is preferably the same for all bag chambers.
  • the contour line of the central chamber can be adapted to the contour line of the adjacent bag chambers in order to realize narrowest possible sealing sections between the chambers.
  • the central chamber can have a circular base surface or polygonal base surface in the sealing plane, for example a square, triangular, star-shaped, propeller-shaped or fan-wheel-shaped base surface. Also, the base surface of the central chamber may have an asymmetrical shape.
  • FIGS. 1 to 14 show different embodiments of detergent products 1 for textile treatment in the format of disposable portion packs.
  • a sachet usually serves the one-time textile treatment application in a textile washing machine.
  • Each detergent product 1 has a foil bag 2 with four bag chambers 3 (FIG. FIGS. 1 to 7 ) or three bag chambers 3 ( FIGS. 8 to 14 ) on.
  • bag chambers 3 detergent compositions are added, which may contain detergent substances for textile treatment, especially textile laundry.
  • water-soluble PVA films with the type designation M8630 or M8720 from the film manufacturer Monosol can be used.
  • suitably designed water-soluble films of other film manufacturers such as Aicello, Nippon Gohsei or Mondi can be used.
  • the film bag 2 is formed from two water-soluble films, which can be designed as PVA films.
  • the water-soluble films enclose the bag chambers 3 by forming their boundary walls.
  • the films are connected to one another in the region of sealing sections 4 such that the bag chambers 3 are in each case completely closed by the sealing sections 4 and separated from one another.
  • a sealed film section is also provided between two adjacent bag chambers 3, which connects the bag chambers 3 to each other to achieve a single portion package.
  • the bag chambers 3 have different base surfaces A1 in the sealing plane or the connecting plane between the films ( FIGS. 2, 3 ; 9, 10 ), while the entire detergent product 1 or the foil bag 2 in the sealing plane has the base area A2.
  • the base area A1 of a bag chamber 3 is bounded by the contour line of the respective bag chamber 2 in the sealing plane.
  • the base area A2 of the (total) detergent product 1 is limited by its contour line of the sealing plane.
  • a substantially rectangular base surface A2 of the detergent product 1 is provided with rounded corner regions
  • the base surfaces A1 of the bag chambers 2 each have a teardrop or teardrop shape with a narrow convex end portion 5 of Contour line of the respective bag chamber 3 in the sealing plane (with a lower inner radius r1) and with a longer in the longitudinal direction of the bag chamber 3 wider convex end portion 6 (with a larger inner radius r2).
  • a concave or optionally also straight connecting section 7 and radially outwardly are provided radially inwardly.
  • FIGS. 1 to 14 show detergent products 1, ie in particular the geometric configuration (shape), the size and the arrangement of the bag chambers 3 relative to each other, explained in detail.
  • All embodiments shown have the common feature that an arrangement with three or more consecutive bag chambers 3 is provided, which is a series of bag chambers 3 with monotonically increasing size of lying in the sealing plane base surfaces A1 of the bag chambers 3 and monotonically increasing size of the filling volumes of the bag chambers 3 form.
  • FIGS. 1 to 7 shown embodiments four bag chambers 3 are provided, one behind the other in the circumferential direction (arrow 15) of the film bag 2 and form the sequence of bag chambers 3.
  • the in Fig. 2 Bag chamber 3 shown above the smallest base area A1 and the smallest filling volume and the in Fig. 2 Bag chamber 3 shown on the right has a mean size of the base area and a mean size of the filling volume.
  • the third bag chamber 3 shown below then has a maximum size of the base area A1 and a maximum size of the filling volume.
  • the fourth bag chamber 3 shown on the left corresponds essentially or identically to the size of the base area A1 and the size of the filling volume of the in Fig. 2
  • a sequence of bag chambers 3 with four followers is formed, wherein the bag chambers 3 are arranged one behind the other according to the size of the respective base surface and the size of the respective filling volume in the circumferential direction (arrow 12) of the film bag 2.
  • the circumferential direction follows the outer contour of the film bag 2 in the sealing plane.
  • the bag chambers 3 are arranged around a central sealing portion 4 of the film bag 2 around.
  • all the bag chambers 3 of the film bag 2 can also have a different sized base area A1 and / or a different filling volume.
  • the bag chambers 3 then form a sequence of bag chambers 3 with n followers, where n ⁇ 3, and wherein the base area and / or the fill volume of each successive bag chamber 3 of the sequence is greater than the base area A1 and / or the fill volume of an adjacent preceding bag chamber 3 or increases strictly monotonically.
  • the increase in the size of the base area A1 and / or the increase in the size of the filling volume of the bag chambers 3 in the sequence preferably corresponds to a mathematical training specification, namely a function that determines the relationship between the position of the respective bag chamber 3 in the sequence and Size of the base area A1 and the filling volume of the respective bag chamber 3 clearly describes.
  • the base surfaces A1 of the bag chambers 3 each have an axis-asymmetrical teardrop shape.
  • the arrangement of the base surfaces A1 on the foil bag 2 is rotationally asymmetrical.
  • bag chambers 3 with (possibly strictly) monotonically increasing size of the base surface and / or (possibly strictly) monotonically increasing size of the filling volume can reduce the risk that it is in a washing process to a hooking of laundry parts, such as buttons and / or applications, between adjacent bag chambers 3 comes. As a result, the detergent product 1 is moved more intensively during a washing process and washed around, which ensures good dissolution behavior.
  • the bag chambers 3 are arranged around a non-interrupted sealing section 4 provided in the middle region of the film bag 1.
  • the bag chambers 3 are in the circumferential direction (arrow 12) of the film bag. 2 arranged next to each other and do not overlap each other. All bag chambers 3 have a different filling volume and a different spatial form.
  • the base area A1 of each bag chamber 3 is axis-asymmetrical.
  • the base area A1 can each be formed drop-shaped.
  • the ratio of the larger inner radius r2 to the smaller inner radius r1 can be used for all Bag chambers 3 should be the same or change in the circumferential direction of the film bag 2.
  • the ratio may range between 3: 1 and 10: 1, for example according to Fig. 2 at about 5: 1.
  • the embodiment shown are larger and different for the bag chambers 3.
  • adjacent bag chambers 3 are arranged relative to each other such that the wider convex end portion 6 of the contour of a first bag chamber 3 is opposite to the concave connecting portion 7 of a second bag chamber 3 following in the circumferential direction.
  • the narrower convex end section 5 of the subsequent second bag chamber 3 is offset radially outward relative to the wider convex end section 6 of the first bag chamber 3 with respect to the area bisecting line 10 of the two base surfaces A1 of the adjacent bag chambers 3.
  • the starting point of the area bisector 10 of the base area A1 at the narrow end of a bag chamber 3 following in the circumferential direction of the film bag 2 is offset radially outward relative to the end point of the area bisector 10 of the base area A1 at the wide end of a preceding bag chamber 3.
  • the wider convex end portion 6 of the contour of a preceding bag chamber 3 in the sealing plane intersects a tangent 9 which is placed on the narrow convex end portion 5 and on the wide convex end portion 6 of the contour of a following bag chamber 3, thereby extending into a concave area the following bag chamber 3 inside.
  • the connecting portions 7, 8 of the contours of all the bag chambers 3 in the sealing plane have a same direction of curvature from the narrow convex end portion 5 to the wide convex end portion 6 of the respective bag chamber 3.
  • Fig. 2 follows therefrom in a plan view a right-handed arrangement of the base surfaces A1 of the bag chambers 3 in the direction of the narrow convex end portion 5 to the wide convex end portion 6 (or a corresponding left-handed arrangement in a view from below of the film bag 2 according to Fig. 3 ). It is understood that in a plan view, a left-handed arrangement of the base surfaces A1 of the bag chambers 3 may be provided.
  • the following bag chamber 3 then adjoins with the same or similar cross-sectional profile, wherein the maximum cross-sectional area of the following bag chamber 3 is greater than the maximum cross-sectional area of a preceding bag chamber 3. This applies to the in Fig. 2 above, right and bottom bag chambers 3.
  • the maximum cross-sectional area of the in Fig. 2 The bag chamber 3 shown on the left corresponds again essentially to the maximum cross-sectional area of the in Fig. 2 bottom of bag shown 3.
  • the geometry of the bag chamber 3 or of its envelope is thus both in the two-dimensional space in the sealing plane (in plan view of the base surfaces A1) and in the three-dimensional space (in a perspective view of the bag chambers 3) in the direction of curvature of the area bisector 10 by a helical structure characterized.
  • the maximum width of a base surface A1 or the maximum cross-sectional area of a bag chamber 3 can be achieved in each case in the region of the center of a circular arc placed from the inside on the broad convex end section 6 of the contour line of the bag chamber 3 in the sealing plane.
  • the convex outer connecting sections 8 of the contour lines of the bag chambers 3 of a film bag 2 in the case of the detergent products 1 shown are arranged on a common circumferential line 11 that runs around at least substantially four or more or eight.
  • Other shapes of the circumferential line 11 are not excluded, for example, the circumferential line may be circular. This too contributes to a compact construction.
  • the smallest distance between two bag chambers 2 following in the direction of the circumferential line 11 in the sealing plane may be preferably less than 5 mm, more preferably less than 3 mm, particularly preferably less than 2 mm. Due to the deformations occurring in the production of the film bag 2 by deep drawing and due to restoring forces of the film layers may adjacent Bag chambers 3 in the use state of the detergent product 1 even partially against each other.
  • FIGS. 8 to 14 shown detergent product 1 has three bag chambers.
  • the bag chambers 3 fit together in a ying and yang shape, so that the width of the sealing sections 4 between the bag chambers 3 becomes as small as possible. This achieves a high intrinsic dimensional stability. The perception of the narrow sealing portions between the bag chambers 3 is difficult.
  • the outer connecting portions 8 of the contour of the bag chambers 3 are formed as free-form curved sections.
  • the outer connecting portions 8 lie on a substantially quadrangular common circumferential line 11.
  • the circumferential line 11 extends substantially parallel to the outer contour of the foil bag 2.
  • all bag chambers 3 have differently shaped and differently sized base surfaces A1 and different filling volumes.
  • a central chamber may be provided in the middle region of the film bag 2, which forms a further chamber of the multi-chamber arrangement of the film bag 2.
  • the central chamber, together with the bag chambers 3, can form a (finite) series of immediately consecutive chambers with monotonically increasing size of the base surface A1 lying in the sealing plane and / or monotonically increasing size of the filling volume.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Detergent Compositions (AREA)
  • Bag Frames (AREA)
EP18159631.3A 2017-03-31 2018-03-02 Produit détergent Active EP3381834B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102017205547.2A DE102017205547A1 (de) 2017-03-31 2017-03-31 Waschmittelprodukt

Publications (2)

Publication Number Publication Date
EP3381834A1 true EP3381834A1 (fr) 2018-10-03
EP3381834B1 EP3381834B1 (fr) 2023-07-19

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ID=61563181

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EP18159631.3A Active EP3381834B1 (fr) 2017-03-31 2018-03-02 Produit détergent

Country Status (6)

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US (1) US20180282673A1 (fr)
EP (1) EP3381834B1 (fr)
KR (1) KR102485530B1 (fr)
CN (1) CN108688999A (fr)
AU (1) AU2018202254B2 (fr)
DE (1) DE102017205547A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3786272A1 (fr) 2019-09-02 2021-03-03 BlueSun Consumer Brands, S.L. Composition de détergent à lessive liquide à dose unitaire
CN114808387A (zh) * 2022-05-21 2022-07-29 栗亚妮 一种具有均匀释放功能的洗衣液凝珠

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU201713661S (en) * 2017-01-12 2017-08-15 Henkel Ag & Co Kgaa Chamber pouches
JP1618537S (fr) * 2017-11-07 2018-11-19
AU201812847S (en) * 2017-12-20 2018-06-18 Henkel Ag & Co Kgaa Pouches for detergent
JP1661185S (fr) * 2019-06-13 2020-06-08
USD937096S1 (en) * 2019-06-25 2021-11-30 Whealthfields (Hong Kong) Limited Laundry detergent capsule
CN110316473B (zh) * 2019-07-16 2024-05-28 威莱(广州)日用品有限公司 一种多腔室凝珠及其制作方法
USD953881S1 (en) 2019-08-05 2022-06-07 Henkel Ag & Co. Kgaa Multi-chamber pouch
USD939764S1 (en) 2019-08-07 2021-12-28 Henkel Ag & Co. Kgaa Detergent pouch
USD937097S1 (en) * 2019-10-14 2021-11-30 Whealthfields (Hong Kong) Limited Laundry detergent capsule
PL3828255T3 (pl) * 2019-11-29 2024-03-25 Henkel Ag & Co. Kgaa Wielokomorowy produkt stanowiący środek piorący o dużym kontraście między komorami
USD942680S1 (en) * 2020-03-03 2022-02-01 Korex Canada Company Multi-compartment detergent unit dose
US20230313085A1 (en) 2020-07-03 2023-10-05 Conopco, lnc., d/b/a UNILEVER Unit dose capsule
EP4176035A1 (fr) 2020-07-03 2023-05-10 Unilever IP Holdings B.V. Capsule à dose unitaire
AU2021299894B2 (en) * 2020-07-03 2024-01-04 Unilever Global Ip Limited A unit dose capsule

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1375637A1 (fr) * 2002-06-17 2004-01-02 Unilever N.V. Compositions détergentes
WO2014170882A1 (fr) * 2013-04-19 2014-10-23 Rideau Machinery, Inc Fabrication de poches solubles dans l'eau
EP2927307A1 (fr) * 2014-03-31 2015-10-07 The Procter & Gamble Company Article de dose unitaire de lessive
WO2015179584A1 (fr) * 2014-05-21 2015-11-26 The Procter & Gamble Company Procédés et systèmes de distribution d'une composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6329734Y2 (fr) * 1984-11-24 1988-08-09
PL2617659T5 (pl) 2012-01-19 2021-08-23 Lakma Strefa Sp.Z O O. Wyrób ze środkiem czyszczącym
CA2841024C (fr) 2014-01-30 2017-03-07 The Procter & Gamble Company Article de type doses unitaires
TWI689547B (zh) * 2014-10-13 2020-04-01 美商摩諾索公司 具有塑化劑摻合物的水溶性聚乙烯醇膜、相關方法及相關物品

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1375637A1 (fr) * 2002-06-17 2004-01-02 Unilever N.V. Compositions détergentes
WO2014170882A1 (fr) * 2013-04-19 2014-10-23 Rideau Machinery, Inc Fabrication de poches solubles dans l'eau
EP2927307A1 (fr) * 2014-03-31 2015-10-07 The Procter & Gamble Company Article de dose unitaire de lessive
WO2015179584A1 (fr) * 2014-05-21 2015-11-26 The Procter & Gamble Company Procédés et systèmes de distribution d'une composition

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3786272A1 (fr) 2019-09-02 2021-03-03 BlueSun Consumer Brands, S.L. Composition de détergent à lessive liquide à dose unitaire
CN114808387A (zh) * 2022-05-21 2022-07-29 栗亚妮 一种具有均匀释放功能的洗衣液凝珠
CN114808387B (zh) * 2022-05-21 2023-09-01 佳宜(广州)生物技术有限公司 一种具有均匀释放功能的洗衣液凝珠

Also Published As

Publication number Publication date
DE102017205547A1 (de) 2018-10-04
US20180282673A1 (en) 2018-10-04
KR102485530B1 (ko) 2023-01-05
CN108688999A (zh) 2018-10-23
AU2018202254A1 (en) 2018-10-18
KR20180111621A (ko) 2018-10-11
AU2018202254B2 (en) 2023-09-21
EP3381834B1 (fr) 2023-07-19

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