EP3292228B1 - Stahlflachprodukt und verfahren zu seiner herstellung - Google Patents
Stahlflachprodukt und verfahren zu seiner herstellung Download PDFInfo
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- EP3292228B1 EP3292228B1 EP16723293.3A EP16723293A EP3292228B1 EP 3292228 B1 EP3292228 B1 EP 3292228B1 EP 16723293 A EP16723293 A EP 16723293A EP 3292228 B1 EP3292228 B1 EP 3292228B1
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- steel
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- flat steel
- flat
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- 229910000831 Steel Inorganic materials 0.000 title claims description 204
- 239000010959 steel Substances 0.000 title claims description 204
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 238000001816 cooling Methods 0.000 claims description 50
- 229910052799 carbon Inorganic materials 0.000 claims description 49
- 238000010438 heat treatment Methods 0.000 claims description 44
- 229910052710 silicon Inorganic materials 0.000 claims description 42
- 229910052748 manganese Inorganic materials 0.000 claims description 37
- 229910000734 martensite Inorganic materials 0.000 claims description 33
- 229910052782 aluminium Inorganic materials 0.000 claims description 29
- 229910001566 austenite Inorganic materials 0.000 claims description 27
- 229910052804 chromium Inorganic materials 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims description 18
- 230000000717 retained effect Effects 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910052758 niobium Inorganic materials 0.000 claims description 12
- 229910001563 bainite Inorganic materials 0.000 claims description 11
- 229910052796 boron Inorganic materials 0.000 claims description 10
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 229910001568 polygonal ferrite Inorganic materials 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- 230000000171 quenching effect Effects 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims 2
- 238000005246 galvanizing Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 83
- 239000011572 manganese Substances 0.000 description 31
- 239000011651 chromium Substances 0.000 description 20
- 230000015572 biosynthetic process Effects 0.000 description 19
- 230000000694 effects Effects 0.000 description 17
- 238000000638 solvent extraction Methods 0.000 description 13
- 238000005275 alloying Methods 0.000 description 10
- 229910000859 α-Fe Inorganic materials 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 230000002349 favourable effect Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910052720 vanadium Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 238000001887 electron backscatter diffraction Methods 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 229910001562 pearlite Inorganic materials 0.000 description 4
- 230000008092 positive effect Effects 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- 238000000265 homogenisation Methods 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910001567 cementite Inorganic materials 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical group Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 238000004626 scanning electron microscopy Methods 0.000 description 2
- 238000010583 slow cooling Methods 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- -1 iron carbides Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
- C21D1/22—Martempering
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C—CHEMISTRY; METALLURGY
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
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- C—CHEMISTRY; METALLURGY
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/06—Zinc or cadmium or alloys based thereon
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
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- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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- C23C2/36—Elongated material
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F17/00—Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- a flat steel product which has a tensile strength R m of at least 1200 MPa and consists of a steel which, in addition to Fe and unavoidable impurities (in% by weight), C: 0.10-0.50%, Si: 0 , 1 - 2.5%, Mn: 1.0 - 3.5%, Al: up to 2.5%, P: up to 0.020%, S: up to 0.003%, N: up to 0.02% , and optionally one or more of the elements "Cr, Mo, V, Ti, Nb, B and Ca" in the following contents: Cr: 0.1-0.5%, Mo: 0.1-0.3%, V : 0.01-0.1%, Ti: 0.001-0.15%, Nb: 0.02-0.05%.
- Typical tensile strengths Rm of flat steel products according to the invention are 950-1300 MPa with a yield strength which is at least 800 MPa and can reach the respective tensile strength.
- the elongation A 50 of flat steel products according to the invention is typically 8-20%.
- a flat steel product according to the invention regularly achieves hole expansion ratios of at least 30% in the hole expansion test according to ISO 16630.
- the setting of a suitable ratio between the elements which influence the austenite formation and hardenability of the steel and the elements which suppress the carbide formation is of essential importance here.
- This ratio is set in an alloy according to the invention using the factor ⁇ in which the respective C, Mn, Cr, Al and Si content of the steel is incorporated.
- the factor ⁇ should not be less than 1.5. Too high a content of silicon or aluminum would have a negative effect on the coatability (silicon) or the castability (aluminum) of the steel. If the carbon, manganese or chromium content is insufficient, the required strength would not be achieved.
- the values for the factor ⁇ are at least 1.6.
- Al is added to the steel of a flat steel product according to the invention for deoxidation and for binding any nitrogen that may be present.
- Al can also be used to suppress cementite.
- the Al content of a steel intended for a flat steel product according to the invention is therefore limited to 0.01-1.5% by weight. If low austenitizing temperatures are to be guaranteed, it can be expedient to limit the Al content to a maximum of 0.44% by weight, in particular to 0.1% by weight.
- higher Al contents have a negative effect on castability in steel production. Al contents of at most 1.0% by weight, in particular at most 0.44% by weight, have proven to be favorable for ensuring particularly good castability.
- Chromium in contents of up to 1.0% by weight can optionally be used as an effective inhibitor of pearlite in the steel provided according to the invention and also contributes to strength. With contents of more than 1.0 wt.% Cr, there is a risk of pronounced grain boundary oxidation. To be able to use the positive effects of Cr are at least 0.05% by weight is required.
- the presence of Cr in the steel of a flat steel product according to the invention has a particularly favorable effect if at least 0.15% by weight of Cr is present, an optimal effect being achieved with contents of up to 0.8% by weight.
- the Ti content of the steel of a steel flat product according to the invention is limited to a maximum of 0.2% by weight and its Nb content to a maximum of 0.05% by weight, whereby the presence of micro-alloying elements has proven to be advantageous in order to avoid negative influences, when the sum of the contents of Nb and Ti does not exceed 0.2% by weight.
- the steels E, F and G therefore did not meet the requirements determined according to the invention by the factor ⁇ for the coordination of the alloying elements essential for austenite formation and hardenability.
- samples 1 - 7, 11, 12, 16 - 23, 28 - 31, 33 - 35, 39, 40, 43-60 for a holding period t Q of 10-60 s.
- Samples 1-7, 11, 12, 16, 17, 19-23, 28-31, 33-35, 39, 40, 43-48 were then heated to a treatment temperature T B at a heating rate ⁇ B1 over a heating time t BR heated, on which they have been held for an additional holding period t BI in some attempts.
- Sample 18 was cooled to the treatment temperature T B analogously. It was then cooled to room temperature at a cooling rate ⁇ B2 .
- Comparative examples A3 and C19 show that if the cooling speeds ⁇ Q are too low, the desired yield strength is not achieved, which is due to the fact that the formation of ferrite could not be prevented sufficiently.
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PCT/EP2015/059968 WO2016177420A1 (de) | 2015-05-06 | 2015-05-06 | Stahlflachprodukt und verfahren zu seiner herstellung |
PCT/EP2016/059960 WO2016177763A1 (de) | 2015-05-06 | 2016-05-04 | Stahlflachprodukt und verfahren zu seiner herstellung |
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US (1) | US20190119774A1 (ko) |
EP (1) | EP3292228B1 (ko) |
JP (1) | JP6788612B2 (ko) |
KR (1) | KR102594922B1 (ko) |
CN (1) | CN107580634A (ko) |
ES (1) | ES2820348T3 (ko) |
MX (1) | MX2017014090A (ko) |
WO (2) | WO2016177420A1 (ko) |
ZA (1) | ZA201707321B (ko) |
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CN110088326B (zh) * | 2016-12-14 | 2022-06-24 | 蒂森克虏伯钢铁欧洲股份公司 | 热轧扁钢产品及其生产方法 |
KR101917472B1 (ko) * | 2016-12-23 | 2018-11-09 | 주식회사 포스코 | 항복비가 낮고 균일연신율이 우수한 템퍼드 마르텐사이트 강 및 그 제조방법 |
WO2018142450A1 (ja) * | 2017-01-31 | 2018-08-09 | 新日鐵住金株式会社 | 鋼板 |
US11245153B2 (en) | 2017-05-18 | 2022-02-08 | Thyssenkrupp Ag | Battery housing |
PL3688203T3 (pl) * | 2017-09-28 | 2022-08-29 | Thyssenkrupp Steel Europe Ag | Płaski wyrób stalowy i sposób jego wytwarzania |
CN108359895A (zh) * | 2018-03-14 | 2018-08-03 | 河钢股份有限公司 | 一种抗拉强度950MPa级别的热成形钢及其热轧工艺 |
US20210189517A1 (en) * | 2018-05-22 | 2021-06-24 | Thyssenkrupp Steel Europe Ag | Sheet Metal Part Formed from a Steel Having a High Tensile Strength and Method for Manufacturing Said Sheet Metal Part |
WO2019238741A1 (de) * | 2018-06-12 | 2019-12-19 | Thyssenkrupp Steel Europe Ag | Stahlflachprodukt und verfahren zu seiner herstellung |
CN109266956B (zh) * | 2018-09-14 | 2019-08-06 | 东北大学 | 一种汽车b柱加强板用钢及其制备方法 |
PL3856936T3 (pl) * | 2018-09-26 | 2023-01-02 | Thyssenkrupp Steel Europe Ag | Sposób wytwarzania powlekanego płaskiego wyrobu stalowego i powlekany płaski wyrób stalowy |
CN112752862B (zh) | 2018-09-28 | 2022-05-06 | Posco公司 | 具有高扩孔性的高强度冷轧钢板、高强度热浸镀锌钢板及它们的制造方法 |
KR102276741B1 (ko) * | 2018-09-28 | 2021-07-13 | 주식회사 포스코 | 구멍확장성이 높은 고강도 냉연강판, 고강도 용융아연도금강판 및 이들의 제조방법 |
EP3754037B1 (en) * | 2019-06-17 | 2022-03-02 | Tata Steel IJmuiden B.V. | Method of heat treating a high strength cold rolled steel strip |
MX2022008976A (es) * | 2020-01-22 | 2022-08-11 | Nippon Steel Corp | Hoja de acero y metodo de produccion de la misma. |
EP3872206B1 (de) * | 2020-02-28 | 2023-06-21 | ThyssenKrupp Steel Europe AG | Verfahren zur herstellung eines nachbehandelten, kaltgewalzten stahlflachprodukts und nachbehandeltes, kaltgewalztes stahlflachprodukt |
WO2021176249A1 (en) * | 2020-03-02 | 2021-09-10 | Arcelormittal | High strength cold rolled and galvannealed steel sheet and manufacturing process thereof |
CN114107794B (zh) * | 2020-08-31 | 2023-08-11 | 宝山钢铁股份有限公司 | 一种980MPa级超低碳马氏体加残奥型超高扩孔钢及其制造方法 |
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JPH0826401B2 (ja) * | 1990-12-29 | 1996-03-13 | 日本鋼管株式会社 | 加工性及び衝撃特性に優れた超高強度冷延鋼板の製造法 |
JPH06108152A (ja) * | 1992-09-30 | 1994-04-19 | Kobe Steel Ltd | 曲げ加工性に優れた高強度溶融亜鉛めっき鋼板の製造方法 |
JP2826058B2 (ja) * | 1993-12-29 | 1998-11-18 | 株式会社神戸製鋼所 | 水素脆化の発生しない超高強度薄鋼板及び製造方法 |
JP3849625B2 (ja) * | 1995-06-09 | 2006-11-22 | Jfeスチール株式会社 | 超高張力電縫鋼管の製造方法 |
JP3374659B2 (ja) * | 1995-06-09 | 2003-02-10 | 日本鋼管株式会社 | 超高張力電縫鋼管およびその製造方法 |
JP5365216B2 (ja) * | 2008-01-31 | 2013-12-11 | Jfeスチール株式会社 | 高強度鋼板とその製造方法 |
JP5402007B2 (ja) * | 2008-02-08 | 2014-01-29 | Jfeスチール株式会社 | 加工性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
JP5418047B2 (ja) | 2008-09-10 | 2014-02-19 | Jfeスチール株式会社 | 高強度鋼板およびその製造方法 |
KR20100034118A (ko) * | 2008-09-23 | 2010-04-01 | 포항공과대학교 산학협력단 | 마르텐사이트 조직을 가진 초고강도 용융아연도금 강판 및 그 제조 방법 |
JP5315956B2 (ja) * | 2008-11-28 | 2013-10-16 | Jfeスチール株式会社 | 成形性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
JP5342912B2 (ja) * | 2009-03-31 | 2013-11-13 | 株式会社神戸製鋼所 | 曲げ加工性に優れた高強度冷延鋼板 |
EP2524970A1 (de) | 2011-05-18 | 2012-11-21 | ThyssenKrupp Steel Europe AG | Hochfestes Stahlflachprodukt und Verfahren zu dessen Herstellung |
JP6047037B2 (ja) * | 2012-03-29 | 2016-12-21 | 株式会社神戸製鋼所 | 鋼板形状に優れた高強度冷延鋼板の製造方法 |
JP5906154B2 (ja) * | 2012-07-20 | 2016-04-20 | 株式会社神戸製鋼所 | 耐遅れ破壊性に優れた高強度鋼板およびその製造方法 |
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2015
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- 2016-05-04 ES ES16723293T patent/ES2820348T3/es active Active
- 2016-05-04 WO PCT/EP2016/059960 patent/WO2016177763A1/de active Application Filing
- 2016-05-04 EP EP16723293.3A patent/EP3292228B1/de active Active
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- 2016-05-04 US US15/571,379 patent/US20190119774A1/en not_active Abandoned
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EP3292228A1 (de) | 2018-03-14 |
KR102594922B1 (ko) | 2023-10-27 |
JP6788612B2 (ja) | 2020-11-25 |
US20190119774A1 (en) | 2019-04-25 |
CN107580634A (zh) | 2018-01-12 |
WO2016177763A1 (de) | 2016-11-10 |
MX2017014090A (es) | 2018-03-01 |
WO2016177420A1 (de) | 2016-11-10 |
ES2820348T3 (es) | 2021-04-20 |
KR20180003581A (ko) | 2018-01-09 |
ZA201707321B (en) | 2022-11-30 |
JP2018518593A (ja) | 2018-07-12 |
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