EP3289037B1 - Adhésifs sous forme d'émulsions d'acrylique - Google Patents

Adhésifs sous forme d'émulsions d'acrylique Download PDF

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EP3289037B1
EP3289037B1 EP16730539.0A EP16730539A EP3289037B1 EP 3289037 B1 EP3289037 B1 EP 3289037B1 EP 16730539 A EP16730539 A EP 16730539A EP 3289037 B1 EP3289037 B1 EP 3289037B1
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Prior art keywords
acrylate
emulsion
polymer
monomer
segment
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German (de)
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EP3289037A1 (fr
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Mark D. GOWER
Eric L. Bartholomew
Qiang Luo
Charles R. WILLIAMS JR.
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Avery Dennison Corp
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Avery Dennison Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature

Definitions

  • the present subject matter relates to acrylic based pressure sensitive adhesives prepared from emulsions which exhibit performance characteristics comparable to solvent-based pressure sensitive adhesives.
  • Acrylic adhesives provide a wide range of performance benefits. Such adhesives include acrylic polymers that are formed using solvent and solventless polymerization techniques. Although satisfactory in many respects, artisans have attempted to utilize acrylic polymers formed by emulsion polymerization, in adhesives. Emulsion polymerization offers several advantages including ability to form high molecular weight polymers at fast polymerization rates; the water phase present in emulsion polymerization is an excellent conductor of heat, and the viscosity of the reaction medium remains relatively stable and approximately that of water.
  • WO 93/18072 discloses a process for the formation of inherently tacky pressure-sensitive adhesive polymers by emulsion polymerization in the presence of a reactive surfactant, of an alkyl acrylate or vinyl ester monomer and a hard monomer, comprising forming the polymer in the presence of a reactive multifunctional monomer having a cyanurate or phosphate functionality.
  • the present subject matter provides an emulsion-based method of forming acrylate polymers (also referred to as precursor polymers).
  • the method disclosed herein is applicable not only to the preparation of RAFT acrylate oligomers but also to the preparation of controlled architecture acrylate (CAA) oligomers using other controlled radical polymerization agents (CRP agents)/processes, e.g. stable free radical mediated polymerization (SFRP), atomic transfer radical polymerization (ATRP), etc.
  • CRP agents controlled radical polymerization agents
  • SFRP stable free radical mediated polymerization
  • ATRP atomic transfer radical polymerization
  • the method comprises preparing a controlled architecture acrylate (CAA) oligomer, utilizing a CRP chain transfer agent such as a RAFT agent.
  • the method also comprises isolating the CAA oligomer.
  • the method additionally comprises preparing a monomer phase including (i) one or more acrylate monomers, (ii) the isolated CAA oligomer, and (iii) one or more acrylate co-stabilizers.
  • the method also comprises emulsifying the monomer phase using one or more copolymerizable surfactants to form a mini-emulsion.
  • the method further comprises preparing a seed latex from the mini-emulsion. And, the method also comprises growing the seed latex using emulsion polymerization to thereby form acrylate polymers.
  • the present subject matter provides various acrylate polymers formed by the noted methods.
  • CAA polymers comprising one or more copolymerizable surfactants.
  • the emulsion adhesive Upon incorporation of the polymers in an emulsion adhesive, the emulsion adhesive exhibits increased adhesion as compared to an emulsion adhesive including corresponding acrylate polymers prepared by a technique other than those used to develop CAA polymers and free of the one or more copolymerizable surfactants.
  • acrylic emulsion adhesives including CAA polymers.
  • the polymers include one or more copolymerizable surfactants.
  • the emulsion adhesives exhibit increased adhesion as compared to an emulsion adhesive including corresponding acrylate polymers prepared by a technique other than those used to develop CAA polymers and free of the one or more copolymerizable surfactants.
  • acrylic emulsion adhesives including CAA polymers, one or more copolymerizable surfactants and including one or more tackifiers.
  • the emulsion adhesives exhibit high adhesion, increased static shear and low delta opacity as compared to an emulsion adhesive including corresponding acrylate polymers containing tackifier and prepared by a technique other than those used to develop CAA polymers and free of the one or more copolymerizable surfactants.
  • the present subject matter provides acrylic emulsion adhesives which exhibit performance characteristics that are comparable, and in certain embodiments are superior, to solvent-based acrylic adhesives.
  • the present subject matter also provides emulsion-based methods of preparing the acrylic adhesives.
  • the present subject matter also provides various controlled architecture acrylate polymers comprising one or more copolymerizable surfactants.
  • the emulsion adhesive Upon incorporation of the polymers in an emulsion adhesive, the emulsion adhesive exhibits increased adhesion as compared to an emulsion-based adhesive (or "emulsion adhesive" as referred to herein) including corresponding acrylate polymers prepared by a technique other than controlled architecture polymerization and free of the one or more copolymerizable surfactants.
  • the present subject matter also provides various acrylic emulsion adhesives including controlled architecture acrylate polymers.
  • the polymers include one or more copolymerizable surfactants.
  • the emulsion adhesives exhibit increased adhesion as compared to emulsion-based adhesive including corresponding acrylate polymers prepared by a technique other than controlled architecture polymerization and free of the one or more copolymerizable surfactants.
  • emulsion pressure sensitive adhesives are prepared via controlled architecture polymerization, such as RAFT mediated controlled radical polymerization, and using reactive surfactant(s) to provide greatly enhanced adhesion performance.
  • the enhanced adhesion performance is demonstrated as significantly higher peel adhesion without sacrificing static shear, as compared with (i) similar polymers made using controlled architecture polymerization and conventional, non-reactive surfactants, (ii) similar polymers made using non-RAFT mediated/non-controlled polymerization using reactive surfactants, and/or (iii) similar polymers made using non-RAFT mediated/non-controlled polymerization and conventional, non-reactive surfactants.
  • the controlled architecture polymerization such as RAFT mediated controlled radical polymerization process, utilized in accordance with the present subject matter can deliver emulsion acrylate polymers with tightly controlled molecular weight (M w ) distribution and with functionality confined to polymer ends and/or functionality distributed across the polymer chain.
  • M w molecular weight
  • a wide array of functional groups can be incorporated in the acrylate polymers, and typically as end segments.
  • Representative examples include, without limitation, (meth)acrylate, hydroxy, siloxy, epoxy, cyano, isocyanate, amino, aryloxy, aryalkoxy, oxime, (meth)acryloxy, aceto, and reactive silanes such as alkoxy silanes, e.g., tetramethoxysilane, epoxyether and vinyl ether, alkoxymethylol, cyclic ethers, thiols, benzophenone, acetophenone, acyl phosphine, thioxanthone, and derivatives of benzophenone, acetophenone, acyl phosphine, and thioxanthone.
  • these groups may be added to one of more of the terminal ends of the polymer(s) via reaction with compounds containing these functionalities.
  • RAFT ARCHITECTURED shows a rheological response of a solvent polymer that is observed when Reversible Addition-Fragmentation chain Transfer (RAFT) is used to control molecular weight and place reactive groups on the polymer chain ends during polymer synthesis. This is typical of the response that is observed in many RAFT emulsion polymers of the present subject matter.
  • RAFT polymer (or like term) as used herein refers to a polymer formed using RAFT techniques or other controlled radical polymerization methodologies such as SFRP, ATRP, etc.
  • the curve designated as "RAFT RANDOM" is the tan delta response for polymers prepared by RAFT without structured chain formation.
  • the tan delta response i.e., the ratio of the viscous response to the elastic response, is much higher for the RAFT architectured polymer. It is the higher ratio of viscous to elastic response, particularly at higher temperatures, that delivers higher peel force outcomes for these adhesives.
  • the higher tan delta at the higher temperatures enables polymers to form better contact with adhered surfaces (also known as better wetting). In rheology, high temperature responses can be replicated by using slow deformation rates. Surface wetting is a slow rate process as polymers relax and flow to make intimate contact with surfaces.
  • the curve designated as "STANDARD HIGH MW RANDOM" is the tan delta response for a conventionally prepared adhesive with randomly placed reactive groups.
  • the low tan delta for that adhesive at high temperatures indicates it will also have a low tan delta at low deformation rates. This adhesive will not wet the adhered surface well, and thus will not establish intimate contact with the surface.
  • the adhesive must have cohesive strength. That is, the adhesive must have some internal strength to resist being pulled apart.
  • This characteristic can be approximately measured using a static shear test.
  • an adhesive tape is applied to a test panel with a loop on one end to hang a weight. The panel is supported vertically and when the weight is suspended, the suspended weight creates a vertical shearing force on the adhesive layer.
  • a timer is used to measure the time period for the weight to pull the adhesive off the test panel. The longer the adhesive resists failure, the higher is its shear performance.
  • High shear is typically provided by a high molecular weight and/or a high degree of cross-linking.
  • Rheology tests reveal that the adhesives, in accordance with the present subject matter, have a relatively high modulus, particularly at higher temperatures, thus a relatively high modulus corresponding to lower rates of deformation (by the Time-Temperature-Superposition principle).
  • Figure 1 does not illustrate another characteristic of adhesives because the figure does not show the comparative moduli.
  • Figure 2 is a chart comparing RAFT emulsions in accordance with the present subject matter with those of similar composition made without RAFT control.
  • the curves for Samples 1 and 2 show the tan delta and modulus as a function of temperature for two particular RAFT polymers in accordance with the present subject matter.
  • the curves for Samples 3 and 4 are the conventionally prepared polymers.
  • RAFT polymers offer much higher tan delta at higher temperatures, i.e., above 25° C.
  • the modulus of the RAFT polymers is not detrimentally affected. An insignificant amount of modulus is given up in these examples to achieve much higher peel force.
  • the present subject matter adhesives retain high shear but enable much higher peel.
  • formulated adhesives such as a film grade adhesive S692N available from Avery Dennison, has a higher tan delta but a lower modulus.
  • controlled architecture acrylate polymers provide improved peel and with much improved static shear via the higher modulus, as is evident in the comparison, shown in Figure 3 .
  • polymers formed in accordance with the present subject matter methods have number average molecular weights (Mn) within a range of from about 500,000 to about 100,000 g/mol, in particular embodiments from about 250,000 to about 110,000 g/mol, and in still other embodiments from about 200,000 to about 125,000 g/mol.
  • Mn number average molecular weights
  • the polymers of the present subject matter have a molecular weight within a range of from about 170,000 to about 130,000 g/mol.
  • the present subject matter polymers may have molecular weights greater than about 500,000 and/or less than about 100,000 g/mol.
  • the polymers formed in accordance with the present subject matter methods have a polydispersity (PDI) of less than about 4.0, in certain embodiments less than 3.0, in still other embodiments less than 2.5, and in certain versions less than 2.0. Generally, the polydispersity is greater than about 1.15.
  • Tg glass transition temperatures
  • CAA controlled architecture acrylate
  • a polymer emulsion composition comprising: at least one acrylic copolymer including a surfactant copolymerized with the acrylic block copolymer, the surfactant being chemically bound to the polymer chain, the acrylic copolymer including at least one first segment of controlled size and position and at least one second segment of controlled size and position.
  • the first segment including a monomer having a functional group selected from the group consisting of a self reactive functional group, a reactive functional group, and combinations thereof, wherein the self reactive functional group is selected from the group consisting of silanes, anhydrides, epoxies, alkoxymethylol, and cyclic ethers, and wherein the reactive functional group is selected from the group consisting of acetoacetyl groups, acids, hydroxyls, amines, thiols, (meth)acrylates, benzophenone, acetophenone, acyl phosphine, thioxanthone, and derivatives of benzophenone, acetophenone, acyl phosphine, and thioxanthone.
  • the self reactive functional group is selected from the group consisting of silanes, anhydrides, epoxies, alkoxymethylol, and cyclic ethers
  • the reactive functional group is selected from the group consisting of acetoacet
  • the second segment does not contain a crosslinkable functional group, wherein the second segment is non-reactive with the functional group of the first segment.
  • the second segment may contain a functional group that is capable of undergoing crosslinking while remaining nonreactive with the functional groups of the first segment.
  • the functional groups of the first segment are capable of undergoing crosslinking reactions while remaining reactive with each other, and whereby the functional groups are in a non-terminal position in the copolymer.
  • the first segment and the second segment are molecularly miscible before cure.
  • the polymer emulsion composition described herein is a liquid polymer at room temperature. In other embodiments, the polymer emulsion composition described herein is a single phase polymer at room temperature. In certain other embodiments, the polymer emulsion composition described herein is a single phase liquid polymer at room temperature.
  • the second (non-reactive) segment of the acrylic polymer may be derived from acrylates, methacrylates, or mixtures thereof.
  • the acrylates include C 1 to about C 20 alkyl, aryl or cyclic acrylates such as methyl acrylate, ethyl acrylate, phenyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, n-hexyl acrylate, n-heptyl acrylate, n-octyl acrylate, n-nonyl acrylate, isobornyl acrylate, 2-propyl heptyl acrylate, isodecyl acrylate, isostearyl acrylate and the like.
  • the methacrylates include C 1 to about C 20 alkyl, aryl or cyclic methacrylates such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, phenyl methacrylate, isobornyl methacrylate, isooctyl methacrylate, and the like.
  • These compounds typically contain from about 4 to about 20 carbon atoms, and in one embodiment about 3 to about 10 carbon atoms.
  • the first segment of the acrylic polymer may be a copolymer derived from one or more of the monomers of the second (non-reactive) segment and at least one polymerizable comonomer having crosslinkable functionality.
  • the reactive segment comprises at least one monomer having the formula: where R is H or CH 3 and X represents or contains a functional group capable of crosslinking.
  • the crosslinkable functional group of the first segment of the acrylic polymer is not particularly restricted, but may include one or more crosslinkable silyl, hydroxyl, carboxyl, carbonyl, carbonate ester, isocyanato, epoxy, vinyl, amino, amide, imide, anhydride, mercapto, acid, acrylamide, acetoacetyl groups, alkoxymethylol, and cyclic ether groups.
  • the present subject matter provides a polymer emulsion composition
  • a polymer emulsion composition comprising: at least one acrylic copolymer including a surfactant copolymerized with the acrylic block copolymer, the surfactant being chemically bound to the polymer chain, the acrylic copolymer including at least one first segment of controlled size and position and at least one second segment of controlled size and position that includes at least one monomer having a reactive functional group.
  • the first segment including a monomer having a functional group selected from the group consisting of a self reactive functional group, a reactive functional group, and combinations thereof and whereby the first segment and the second segment are molecularly miscible before cure.
  • the reactive functionalities in the first segment and the second segment may be the same or different from one another.
  • the reactive functional group of the second segment is a self reactive functional group as in the first segment.
  • the self reactive functional group in the second segment may be the same or different than the self reactive functional group of the first segment.
  • the second segment may contain a functional group that is capable of undergoing crosslinking while remaining reactive with itself or with another second segment of a different polymer.
  • the second segment is free of a self reactive functional group.
  • the polymer emulsion composition described herein is a liquid polymer at room temperature.
  • the polymer emulsion composition described herein is a single phase polymer at room temperature.
  • the polymer emulsion composition described herein is a single phase liquid polymer at room temperature.
  • the first segment and the second segment are molecularly immiscible before cure.
  • the polymer emulsion composition described herein is a phase separated polymer at room temperature.
  • the polymer emulsion composition described herein is a phase separate liquid polymer at room temperature. As used herein, room temperature is about 15° to about 25°C.
  • reactive functional group refers to a functional group that is capable of reacting with another functional group.
  • self reactive functional group refers to a functional group that is capable of reacting with (i) an identical second self reactive functional group, (ii) with a different second self reactive functional group and/or (iii) with a reactive functional group. That is, the self reactive functional group may react with another identical self reactive functional group, with another self reactive functional group that is different, and/or with a reactive functional group.
  • Self reactive functional groups are capable of polymerizing with themselves.
  • the self reactive functional group may be selected from anhydrides, epoxies, alkoxymethylols, and cyclic ethers.
  • Non-limiting examples of reactive functional groups include acids, hydroxyls, amines, mercapto (thiols), benzophenone, acetophenone, acyl phosphine, thioxanthone, and derivatives of benzophenone, acetophenone, acyl phosphine, and thioxanthone.
  • a polymer emulsion composition comprising: at least one acrylic copolymer including a surfactant copolymerized with the acrylic block copolymer, the surfactant being chemically bound to the polymer chain, the acrylic copolymer including at least one first segment of controlled size and position and at least one second segment of controlled size and position that includes at least one monomer having a reactive functional group.
  • the acrylic copolymer of the polymer emulsion composition may in certain embodiments also preferably comprise a third polymeric segment.
  • the third polymeric segment preferably includes a reactive functionality and/or a nonreactive segment. Additional aspects as described in conjunction with the previously described preferred embodiment acrylic copolymers are included in the examples described herein.
  • the term “molecularly miscible” means a compound or mixture of compounds that exhibit properties in the bulk state that can be observed and/or measured by one of ordinary skill in the art and are indicative of single phase behavior.
  • single phase behavior refers to behavior or physical properties that are uniform or substantially so.
  • the observation of a single Tg is indicative of polymer segment miscibility.
  • the single Tg is intermediate between those of the constituent polymer segments and varies monotonically between these values as the relative amounts of each segment changes.
  • phase separated compound In contrast to single phase behavior evidenced by a molecularly miscible compound or mixture of compounds, at a given temperature, a phase separated compound demonstrates multiple, independent sets of properties that are attributable to the different phases of matter present therein. Such sets of properties include, without limitation, T g , solubility parameters, refractive index, and physical state/phase of matter. Accordingly, the term "phase separated” is defined as two or more substances which are molecularly segregated due to one or more chemical and/or physical properties dependent upon, without limitation, polarity, molecular weight, relative amounts of the polymer segments, and T g (phase of matter).
  • end blocks or terminal blocks of the polymer refer to end segments of the polymer. These end blocks or terminal ends have a number average molecular weight (Mn) less than about 50,000 g/mol; in other embodiments, the molecular weight may be less than about 30,000 g/mol, while in still additional embodiments, the molecular weight of the end blocks may be less than about 10,000 g/mol. However, it will be appreciated that the present subject matter end blocks may have molecular weights greater than about 50,000.
  • a significant aspect of the process of the present subject matter is that insoluble polymers are synthesized within surfactant stabilized polymer particles dispersed within a continuous aqueous phase. Reactive monomers are replenished within growing polymer particles by diffusion through the aqueous phase. Monomer needs to be replenished within polymer particles because monomer is continually transformed into polymer by the free radical addition reactions taking place within the particles.
  • Figure 4 schematically illustrates the relatively large monomer droplets 10 and monomer M transporting from those droplets through the aqueous phase to the growing polymer particles 100. At this stage of particle formation, the monomer droplets 10 are relatively large and may have a diameter of about 1 micron. During this stage of particle formation, the reaction rate is typically accelerating. Figure 4 also shows small surfactant micelles 150 that provide surfactant 200 to keep droplets and particles stabilized during the process.
  • the majority of the various monomers used in the present subject matter are sparingly water soluble.
  • the monomers are introduced to the reaction mixture as pre-emulsified droplets, which typically are in the form of monomer droplets stabilized by surfactants at their surfaces as depicted in Figure 4 .
  • the monomers diffuse out of the monomer droplets and transport through the aqueous phase to the monomer depleted polymer particles. Concentration gradients drive the diffusion processes.
  • small polymer particles are desired, typically less than 500 nm in diameter. This ensures an overwhelming availability of polymer particle surface area available for diffusing monomers to penetrate.
  • a large available polymer particle surface area ensures that, when monomer enters the aqueous phase, it is quickly absorbed into polymer particles.
  • monomers are pre-emulsified to ensure that the monomer has plenty of opportunity to diffuse out of monomer droplets and into the aqueous phase.
  • a large surface area to volume ratio i.e., achieved through the use of small particles, provides that incentive for the monomers to enter the aqueous phase.
  • Monomer droplets are not as small as polymer particles. They are micron sized. This size provides enough driving force via concentration differences, i.e., monomer droplet vs aqueous phase, to supply monomer to polymer particles efficiently.
  • Emulsions are prepared to overcome the immiscibility of the monomers and water.
  • Monomers and polymers are typically only sparingly soluble in water.
  • the various species are able to exist as stable dispersions in water by mixing the two components, i.e., water and monomer or water and polymer, in the presence of surfactant.
  • the surfactants effectively chemically camouflage the droplet surfaces, "tricking" the aqueous phase into behaving as if the droplets are miscible in the continuous phase.
  • the surfactants have two ends that are chemically different.
  • the surfactants are located on or near the surface of monomer and polymer particle droplets. Their water-loving/charged ends point to the aqueous phase and their oil-loving/non-polar ends point toward the droplet monomer/polymer-rich interiors.
  • CRP agents controlled radical polymerization chain transfer agents
  • a mini-emulsion is used to create the initial set of polymer particles (known as the polymer seed latex).
  • the CRP agent (provided in the form of a pre-polymerized CAA oligomer molecule, as described in greater detail herein, is incorporated in this initial particle set, as a solution in monomer (i.e. CRP agent(s) dissolved in the monomer(s)). Placing the CRP agent within the initial seed particles offers the opportunity for the polymerization process to be CAA mediated from the outset. When the initial monomer is consumed, a semi-batch feed process is used to replenish the monomer.
  • the semi-batch feed process is one where monomer starved polymer particles are continuously replenished with monomer via a feed of emulsified monomer in water. Because the CRP agent is located within the polymerizing polymer particles, it continues to control the polymerization process of the present subject matter. As described in greater detail herein, one or more mini-emulsion co-stabilizer(s) can be used.
  • mini-emulsion allows the preparation of stable nano-sized droplets of monomer in aqueous dispersion. Since CRP agent (in the form of CAA oligomers) is predissolved in monomer, each mini-emulsion monomer droplet will contain a CRP agent(s). These nano-sized monomer droplets are efficiently converted to polymer particles via the use of thermal initiators.
  • the thermal initiator may be dissolved within the monomer mixture prior to forming the mini-emulsion or it may be added as an aqueous solution to the aqueous phase.
  • the nano-sized monomer droplets are converted to nano-sized polymer particles as they begin to polymerize via CRP agent mediation from the outset.
  • the overwhelmingly large polymer particle surface area provided by the nano-sized polymer particles of the present subject matter effectively absorb monomer from the water phase when it comes to time to replenish the monomer.
  • initial monomer droplets are needed which have diameters less than about 500 nm and in certain embodiments, less than 300 nm. Although diameters less than about 500 nm are used in many embodiments of the present subject matter, it is contemplated that in certain applications, larger particles could be used such as up to about 2,000 nm.
  • stable nano-sized monomer droplets are achieved, they can be readily converted to stable nano-sized polymer droplets by activating the thermal initiator to cause the polymerization reaction to occur. Ideally, all the monomer droplets are transformed to polymer particles.
  • a difference between standard monomer emulsion and a mini-emulsion process is the use of high energy mixing, i.e., high shear mixing and one or more co-stabilizer(s) to create mini-emulsion nano-dispersions.
  • High shear mixing provides the means to violently rip micron-sized monomer droplets apart. The micron-sized droplets can be reduced to nano-sized droplets using high shear mixing.
  • those monomer nano-droplets quickly "Ostwald ripen" back to micron sized particles.
  • Ostwald ripening is a process in which monomer diffuses from nano-sized droplets to micron sized and larger droplets. It is a thermodynamically driven process. There is a high energy cost in maintaining small droplets, where there is very large surface area to volume ratios. It is energetically favorable for the sparingly soluble monomers to exist as much larger particles.
  • the mini-emulsion co-stabilizer is an extremely water-insoluble material.
  • Co-stabilizers are hydrophobic and are soluble in hydrophobic acrylic monomers.
  • co-stabilizers are usually hexadecane or other small molecule, water insoluble solvents. They are used at levels of around 5% by weight based on monomer. They typically function as follows.
  • Osmotic pressure is a force relied upon by the present subject matter methods. Due to its very low water solubility, the co-stabilizer is compelled to remain inside the droplet. Ostwald ripening drives changes in droplet size but monomer diffusion out of the droplet will lead to higher co-stabilizer concentration inside the droplet. It is osmotic pressure that acts to prevent monomer from diffusing out of the particle and thereby driving the co-stabilizer concentration within droplets higher. The nano-dispersions thus formed are kinetically stable and their nano-size can remain unchanged for weeks.
  • the present subject matter methods utilize one or more copolymerizable co-stabilizer(s).
  • a nonlimiting example of such a stabilizer is heptadecyl acrylate, an acrylate with 17 carbons that is a sufficiently small molecule and is highly water insoluble. The small size contributes to its required mobility as a co-stabilizer.
  • This co-stabilizer is a reactive acrylate with a low glass transition temperature (Tg).
  • Tg glass transition temperature
  • heptadecyl acrylate readily copolymerizes with the monomers employed and its low glass transition temperature and hydrophobic nature makes it a useful component monomer for constructing polymers used in PSAs.
  • This co-stabilizer is also liquid at ambient temperature which makes it easy to handle at production scale. It will be understood that the present subject matter includes the use of other co-stabilizers.
  • surfactant-rich weak boundary layer conventional surfactants have been replaced with one or more copolymerizable surfactant(s).
  • polymerizable surfactants also known as reactive surfactants
  • the surfactants are able to continue to provide their particle stabilizing function when they combine with the polymer.
  • the polymer is flexible enough to allow the hydrophilic portion of the surfactant molecule to exist at the polymer particle surface where it orientates toward the aqueous phase.
  • the reactivity of the surfactant molecules is also a little less toward polymerization than the monomers.
  • the CRP agent is the RAFT agent dibenzyl trithiocarbonate (DBTTC). While possible, in these embodiments, a raw form of DBTTC is not used in the present subject matter mini-emulsion and emulsion polymerization processes to make CRP agent controlled PSA polymers. Instead, the CRP agent is converted into a small controlled architecture acrylate polymer or oligomer using solvent polymerization as one or more initial step(s) in the preparation of CAA polymer emulsions. This practice is followed because, even when using the mini-emulsion process, polymerization using RAFT agents in emulsion systems can be problematic.
  • DBTTC dibenzyl trithiocarbonate
  • CAA oligomers used in the present subject matter have ranged in size from a number average molecular weight (Mn) of about 500 to about 50,000 g/mol, in other embodiments from about 1,000 to about 25, 000 g/mol, and in certain embodiments from about 2,500 to about 10,000 g/mol.
  • Mn number average molecular weight
  • the present subject matter CAA oligomers may have molecular weights greater than about 50,000 and/or less than about 500 g/mol.
  • CRP agents not introduced as pre-formed oligomers include loss of CRP agent control when CRP agent fragments desorb from polymer particles or the super-swelling of polymer particles with monomer during early stage of polymerization, when the degree of polymerization is small and monomer solubility is high.
  • a RAFT emulsion adhesive preparation process 300 in accordance with the present subject matter comprises the following operations.
  • a RAFT acrylate oligomer is prepared typically via solvent polymerization, i.e., operation(s) 310.
  • the RAFT oligomer is isolated such as by solvent evaporation as shown by operation(s) 320.
  • a monomer phase including acrylate monomer, RAFT oligomer and a co-stabilizer such as a C17 acrylate is prepared, i.e., operation(s) 330.
  • Mini-emulsification of the monomer phase is then performed using copolymerizable surfactant and water, i.e., operation(s) 340.
  • a seed latex is then prepared such as by thermal initiation of the mini-emulsion, i.e., operation(s) 350.
  • the seed latex is then grown via an emulsion polymerization process, i.e., operation(s) 360.
  • a tackifier selected from the group consisting of a hydrocarbon resin, hydrogenated hydrocarbon resin, a fully hydrogenated hydrocarbon resin, a hydrogenated rosin ester, a fully hydrogenated rosin ester, and combinations thereof may be included in the monomer phase preparation step, i.e., operation(s) 330.
  • Mini-emulsification of the tackifier containing monomer phase is then performed using a copolymerizable surfactant(s) and water, i.e., operation(s) 340.
  • a seed latex is then prepared such as by thermal initiation of the mini-emulsion, i.e., operation(s) 350.
  • the seed latex is then grown via an emulsion polymerization process, i.e., operation(s) 360.
  • the tackifier(s) used in the present subject matter have a concentration range of about 2 to about 30% by weight of the total monomer(s), in other embodiments from about 2 to about 18% by weight of the total monomer(s), in certain embodiments from about 2 to about 15% by weight of the total monomer(s), from in still other embodiments from about 2 to about 12% by weight of the total monomer(s).
  • the present subject matter may have tackifier(s) having a concentration range greater than about 30% and/or less than about 2%.
  • the method disclosed herein is applicable not only to the preparation of RAFT acrylate oligomers but also to the preparation of controlled architecture acrylates (CAA) oligomers using other controlled radical polymerization agents (CRP agents)/processes, e.g. stable free radical mediated polymerization (SFRP), atomic transfer radical polymerization (ATRP), etc.
  • CRP agents controlled radical polymerization agents
  • SFRP stable free radical mediated polymerization
  • ATRP atomic transfer radical polymerization
  • the methods of the present subject matter include one or more operations 310 in Figure 5 of preparing RAFT acrylate oligomers. Typically, such preparations are performed by solvent polymerization using RAFT techniques. However, it is contemplated that the RAFT acrylate oligomers could be prepared by other polymerization techniques besides solvent polymerization.
  • a RAFT acrylate oligomer(s) is prepared by combining (i) one or more acrylate monomers, (ii) one or more RAFT agents, and optionally (iii) one or more comonomers which may be non-acrylates.
  • a wide array of acrylate monomers can be used to form the RAFT acrylate oligomers.
  • Nonlimiting examples of such acrylate monomers include acrylates, methacrylates, or mixtures thereof.
  • the acrylates include C1 to about C20 alkyl, aryl or cyclic acrylates such as methyl acrylate, ethyl acrylate, phenyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, n-hexyl acrylate, n-heptyl acrylate, n-octyl acrylate, n-nonyl acrylate, isobornyl acrylate, 2-propyl heptyl acrylate, isodecyl acrylate, isostearyl acrylate and the like.
  • the methacrylates include C1 to about C20 alkyl, aryl or cyclic methacrylates such as methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, phenyl methacrylate, acetoacetoxyethyl methacrylate, isobornyl methacrylate, isooctyl methacrylate, and the like. These compounds typically contain from about 4 to about 20 carbon atoms, and in one embodiment about 3 to about 10 carbon atoms.
  • RAFT agents can be used to form the RAFT acrylate oligomers.
  • Typical RAFT agents contain thiocarbonyl-thio groups, and include, for example, dithioesters, dithiocarbamates, trithiocarbonates and xanthenes.
  • useful RAFT agents include those described in The Chemistry of Radical Polymerization, Graeme Moad & David H. Solomon, 2nd rev. ed., 2006, Elsevier, p. 508-514 .
  • Nonlimiting and particular examples of such RAFT agents include the previously noted DBTTC.
  • a wide array of comonomers can optionally be used in forming the RAFT acrylate oligomers.
  • Nonlimiting examples of such comonomers include one or more crosslinkable silyl, hydroxyl, carboxyl, carbonyl, carbonate ester, isocyanato, epoxy, vinyl, amino, amide, imide, anhydride, mercapto, acid, acrylamide and acetoacetyl groups.
  • Hydroxy functional comonomers include, for example, hydroxy ethyl(meth)acrylate, hydroxy isopropyl(meth)acylate, hydroxy butyl(meth)acrylate and the like.
  • Epoxy functional monomers include, for example, glycidyl methacrylate and glycidal acrylate.
  • the acid containing comonomers include unsaturated carboxylic acids containing from 3 to about 20 carbon atoms.
  • the unsaturated carboxylic acids include, among others, acrylic acid, methacrylic acid, itaconic acid, beta carboxy ethyl acrylate, mono-2-acroyloxypropyl succinate, and the like.
  • Anhydride containing monomers include maleic anhydride, itaconic anhydride, citraconic anhydride and the like.
  • the acrylamides include acrylamide and its derivatives including the N-substituted alkyl and aryl derivatives thereof. These include N-methyl acrylamide, N,N-dimethyl acrylamide, t-octyl acrylamide and the like.
  • the methacrylamides include methacrylamide and its derivatives including the N-substituted alkyl and aryl derivatives thereof.
  • the vinyl esters include vinyl acetate, vinyl propionate, vinyl butyrate, vinyl valerate, vinyl versitate, vinyl isobutyrate and the like.
  • the vinyl ethers include vinyl ethers having 1 to about 8 carbon atoms including ethylvinyl ether, butylvinyl ether, 2-ethylhexylvinyl ether and the like.
  • the vinyl amides include vinyl amides having 1 to about 8 carbon atoms including vinyl pyrrolidone, and the like.
  • the vinyl ketones include vinyl ketones having 1 to about 8 carbon atoms including ethylvinyl ketone, butylvinyl ketone, and the like.
  • the polymerizable silanes include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltripropoxysilane, vinylmethyldimethoxysilane, vinylmethyldiethoxy-silane, vinylmethyldipropoxysilane, ⁇ -methacryloxypropyl-trimethoxysilane, ⁇ -methacryloxypropyltriethoxysilane, ⁇ -methacryloxypropyl-tripropoxysilane, ⁇ -methacryloxydimethoxysilane, ⁇ -methacryloxypropyl-methyldimethoxysilane, ⁇ -methacryloxypropylmethyldiethoxysilane, ⁇ -methacryl-oxypropylmethyldipropoxysilane, ⁇ -methacryloxymethyl-dimethoxysilane, ⁇ -methacryloxymethyltrimethoxysilane, ⁇ -methacryloxymethyltrimethoxysilane, ⁇ -methacryloxymethyltrimethoxy
  • the comonomer may include at least one segment having the formula: where R3 is H or CH3 and R4 is a branched or unbranched, saturated alkyl group having 4 to 14 carbon atoms.
  • the RAFT acrylate oligomers typically have a number average molecular weight (Mn) in a range of from about 500 to about 50,000 g/mol, in other embodiments from about 1,000 to about 25,000 g/mol, and in certain embodiments from about 2,500 to about 10,000 g/mol. However, it will be appreciated that the present subject matter RAFT acrylate oligomers may have molecular weights greater than about 50,000 and/or less than about 500 g/mol.
  • the oligomers are isolated from the reaction system. This is shown as operation(s) 320 in Figure 5 .
  • the RAFT oligomers are isolated by removing solvent. Solvent removal can be performed by a variety of techniques such as by evaporation for example. In many applications evaporation of solvent is performed at reduced pressures to avoid heating the oligomers. However, heat can be used to evaporate solvent or other liquid(s) and thereby isolate the RAFT oligomers.
  • the methods of the present subject matter also include one or more operations of preparing a monomer phase, shown as 330 in Figure 5 .
  • the monomer phase includes (i) one or more acrylate monomers, (ii) the isolated RAFT acrylate oligomer, (iii) one or more acrylate co-stabilizers, optionally (iv) one or more other comonomers, optionally (v) one or more tackifiers, and optionally (vi) one or more oil soluble thermal initiators.
  • a tackifier is Foral AX-E, a fully hydrogenated rosin ester tackifier from Eastman or Regalite R1090, a hydrocarbon resin tackifier, also from Eastman.
  • the present subject matter includes the use of a variety of tackifiers such as tackifier(s) selected from the group consisting of a hydrocarbon resin, hydrogenated hydrocarbon resin, a fully hydrogenated hydrocarbon resin, a hydrogenated rosin ester, a fully hydrogenated rosin ester, and combinations thereof.
  • tackifier(s) selected from the group consisting of a hydrocarbon resin, hydrogenated hydrocarbon resin, a fully hydrogenated hydrocarbon resin, a hydrogenated rosin ester, a fully hydrogenated rosin ester, and combinations thereof.
  • An example of an oil soluble thermal initiator is Vazo 64 available from Dupont. Vazo 64 is 2,2'-azobisisobutyronitrile.
  • the present subject matter includes the use of a variety of oil soluble or water soluble thermal initiators such as persulfates.
  • a wide array of acrylate monomers can be used in this operation. Any of the previously noted monomers used in forming the RAFT acrylate oligomer can be used. The acrylate monomers used in this operation can also be different than those used in forming the RAFT acrylate oligomers.
  • the acrylate co-stabilizers are generally C6 to C20 acrylates. These stabilizers can include a C17 acrylate and in certain versions heptadecyl acrylate.
  • Nonlimiting examples of such comonomers include any of the previously noted comonomers used in forming the RAFT acrylate oligomer can be used.
  • the comonomers used can be different or the same as those used in forming the RAFT acrylate oligomers.
  • the monomer phase is emulsified using one or more copolymerizable surfactants to form a mini-emulsion, shown as operation(s) 340 in Figure 5 .
  • Emulsification can be performed using high speed blenders and emulsification equipment as known in the art.
  • An array of surfactants can be used in this operation so long as the one or more surfactants are copolymerizable.
  • copolymerizable surfactants include allyl or vinyl substituted alkyl phenolethoxylates and their sulfates, block copolymers of poly ethylene oxide, propylene oxide or butylene oxide with polymerizable end groups, allyl or vinyl substituted ethoxylated alcohols and their sulfates, maleate half esters of fatty alcohols, monoethanolamide ethoxylates of unsaturated fatty acids capable of undergoing autoxidative polymerization, allyl or vinyl polyalkylene glycol ethers, alkyl polyalkylene glycolether sulfates, functionalized monomer and surfactants, and combinations thereof.
  • the mini-emulsion which is prepared comprises the previously described monomer phase and the copolymerizable surfactant(s).
  • the particles in the mini-emulsion typically have particle sizes within a range of from 2,000 to 10 nm, particularly from 500 to 10 nm, and in certain embodiments from 300 to 10 nm. In many embodiments, at least about 90% of the particles in the mini-emulsion have a particle size within the noted range(s).
  • a seed latex is prepared, as shown as operation(s) 350 in Figure 5 .
  • the seed latex is formed by transforming the mini-emulsion monomer droplet dispersion into a dispersion of polymer particles via thermal initiation with a thermally activated, oil soluble initiator (previously dissolved within the monomer phase).
  • the mini-emulsion is heated in a stirred reactor to reaction temperature (approximately 75° C) and held until about at least 80% monomer to polymer conversion is achieved (measured gravimetrically). This typically takes 2 to 5 hours.
  • transformation of the mini-emulsion from nano-droplets of dispersed monomer to dispersed polymer could be achieved using a water soluble initiator such as sodium persulfate added to the aqueous phase and heating as noted above.
  • the seed step allows for the creation of stabilized polymer particles containing RAFT controller.
  • the seed polymer need only have a small molecular weight, for example 1000 g/mole or more.
  • the purpose of the seed preparation step is to prepare a surfactant stabilized polymer using RAFT controlled free-radical polymerization.
  • the polymer within the seed particles can be further polymerized (extended) to achieve the higher molecular weights required for good adhesive performance (usually at least two times the entanglement molecular weight (Me) of the polymer formed).
  • Seed polymer extension can be achieved by adding monomer emulsion and a low concentration of initiator via a conventional, semi-batch emulsion polymerization process. The introduced monomer will swell the polymer seed particles and the initiator will re-establish RAFT mediated free-radical polymerization within the monomer swollen particles. Concentration gradients will act to replenish monomer within the polymer particles as it is consumed.
  • the seed polymer latex can be polymerized to higher molecular weight immediately or it may be stored and processed at a later time.
  • the seed polymer particles can be used directly as a high performance PSA.
  • Monomer and RAFT oligomer ratios may be adjusted to enable high polymer Mn to be achieved during the seed stage. If the Mn formed is at least two times the Me of the formed polymer, the PSA will exhibit good PSA properties after cross-linking.
  • the seed latex can be prepared from the mini-emulsion by a thermal initiation process, as previously described.
  • the seed latex is grown, i.e., operation(s) 360 in Figure 5 , using pre-emulsion and initiator solution feeds according to a standard semi-batch emulsion polymerization approach.
  • the RAFT mediated free radical polymerization takes place slowly given the requisite low initiator concentrations to maintain controlled polymer growth.
  • Typical acrylate pre-emulsion compositions can be used with the exception that reactive surfactant must be the principal surfactant.
  • the monomer emulsion is fed into the reaction mixture along with a small amount of initiator.
  • Polymer dispersions with solids content of about 45 to about 63% with Mn in the order of 200,000 g/mole with PDI less than 4.0 can be prepared.
  • the ultimate solids/Mn balance will be determined, in part, by the ratio of RAFT agent to monomer in the initial seed preparation. High RAFT to monomer ratios will provide for lower ultimate Mn. Consideration should be given to the initial seed particle size to enable optimum solids and Mn distributions. Energy input during the dispersion step together with surfactant concentration, RAFT oligomer concentration and monomer choice are important parameters in controlling dispersion particle size.
  • Monomer pre-emulsion and initiator feed times will approximately match the polymerization rate so as to avoid accumulating a large excess of unreacted monomer within the reactor at any given time.
  • Feed time and mass of feed monomer will depend on the initial Mn of the seed and the target Mn for the finished product. Typically, a seed polymer with Mn of approximately 25 Kg/mole grown to about 100 Kg/mol will require a pre-emulsion feed time of around 4 hours.
  • consideration must be paid to reducing residual monomer and reactive surfactant levels after feed completion.
  • the reactive surfactants in particular, are slow to incorporate and require the batch be held for additional time at elevated temperature after feed completion.
  • incorporation is aided by a shot of initiator after feed completion.
  • the RAFT mediated polymerization process also means that monomers are incorporated slowly. Extended period at elevated temperature and a shot or feed of peroxy initiator also aids achieving monomer conversions above 98%.
  • growing of the seed latex is performed by an emulsion polymerization process.
  • RAFT control and polymerizable surfactants to deliver high performance emulsion PSAs.
  • polymers After formation of the present subject matter polymers, a variety of post-formation operations can be undertaken such as but not limited to crosslinking, incorporation of fillers and additives, and curing.
  • the adhesive may be crosslinked during post curing of the adhesive to increase the cohesive strength of the pressure sensitive adhesive. This can be achieved via covalent crosslinking such as heat, actinic or electron beam radiation, or metal based ionic crosslinking between functional groups. Table 1 below lists the types of crosslinkers for the various functional groups of the segmented polymer.
  • the adhesives of the present subject matter may further comprise additives such as pigments, fillers, plasticizer, diluents, antioxidants, tackifiers and the like.
  • Pigment if desired, is provided in an amount sufficient to impart the desired color to the adhesive.
  • pigments include, without limitation, solid inorganic fillers such as carbon black, titanium dioxide and the like, and organic dyes. Additional inorganic fillers such as aluminum trihydrate, christobalite, glass fibers, kaolin, precipitated or fumed silica, copper, quartz, wollasonite, mica, magnesium hydroxide, silicates (e.g. feldspar), talc, nickel and calcium carbonate are also useful.
  • Metal oxides such as aluminum trihydrate and magnesium hydroxide are particularly useful as flame retardants.
  • tackifiers can be used to enhance the tack and peel of the adhesive. These include hydrocarbon resin tackifiers, rosins and rosin derivatives including rosinous materials that occur naturally in the oleoresin of pine trees, as well as derivatives thereof including rosin esters, modified rosins such as fractionated, hydrogenated, dehydrogenated, and polymerized rosins, modified rosin esters and the like.
  • Polymers were synthesized with target glass transition temperatures (Tg) of -20° C using predominantly n-butyl acrylate and t-butyl acrylate monomers. 0.6% by weight of methacrylic acid was included in each polymerization.
  • RAFT mediated polymerizations were conducted via mini-emulsion polymerization using a pre-made RAFT oligomer dissolved in the monomer phase together with a small amount of heptadecyl acrylate as a hydrophobe.
  • the RAFT oligomer was prepared in a solvent system.
  • the formulation was as provided in Table 2 as follows.
  • Table 2 - Representative Formulation for Forming RAFT Oligomer Reactor Charge % Total Lab Batch Ethyl Acetate 44.3373 520.00 Methacrylic Acid 4.3519 51.04 Butyl Acrylate 46.1961 541.80 DBTTC 100% 1.4657 17.19 Initiator Vazo-64 0.1107 1.298 Ethyl Acetate 3.5384 41.50 Reactor Charge Total 100.0000 1,172.83
  • the recipe stoichiometry set forth in Table 2 was designed to deliver a 10,000 g/mol polymer with 5 MAA molecules per polymer end.
  • the reaction was carried out at 80° C and when complete (i.e., conversion >98%), the solvent (ethyl acetate) was stripped from the polymer solution using rotary evaporation at 60 deg C.
  • the Mn of the isolated polymer was measured and found to be approximately 9,500 g/mole with a PDI of approximately 1.5.
  • the RAFT mediated polymerizations yielded polymers having a molecular weight of approximately 150,000 g/mol and low polydispersity (PDI) as shown in Table 3 as Polymer Samples 1 and 2.
  • PDI polydispersity
  • Each polymer dispersion was neutralized to a pH within a range of 8.5 to 9.5 using ammonia solution before adding CX100 aziridine cross-linker at equivalent stoichiometric weight based on available methacrylic acid.
  • Polymer latex films were prepared by drawing down the latexes containing crosslinker directly to 2 mil polyethylene terephthalate (PET) film.
  • PET polyethylene terephthalate
  • the wet adhesive films were dried and cured in a convection oven at 120° C for 5 minutes before laminating to silicone coated glassine release paper.
  • Adhesive coat weight of prepared laminates was measured by weighing a 100 mm x 100 mm section of adhesive coated PET. The weight of a 100 mm x 100 mm uncoated sample of PET was subtracted and the result multiplied by 100 to obtain a coat weight estimate in g/m 2 .
  • 180° peel adhesion after 24 hours dwell to stainless steel was measured by applying a 1 inch wide strip of test laminate to a stainless steel panel with a 5 pound roller with 1 pass in each direction. Samples were conditioned and tested at 23° C. After 24 hours dwell, the average peel force was measured over at least 20 mm of tests strip three times.
  • Static shear was measured by adhering a 1/2 inch by 1/2 inch area of a looped test strip to a stainless steel panel and rolling with a 5 pound roller with one pass in each direction. After allowing the test strips to dwell overnight, a 500 g test weight was hung via the loop formed in the test strip and the time to failure recorded.
  • DMA Dynamic Mechanical Analysis
  • Figures 6 and 7 illustrate that a combination of using RAFT polymerization with a polymerizable surfactant delivers high peel and high shear characteristics.
  • Figure 6 demonstrates that a peel force of approximately 5 pounds is achieved by combining the use of a RAFT process with a polymerizable surfactant as compared to a peel force of only about 1 pound for polymers using the same monomers via conventional polymerization, RAFT polymerization alone, and polymerizable surfactant alone.
  • Figure 7 illustrates the shear test results.
  • a significant performance benefit is the improved high temperature adhesion performance.
  • adhesives formed in accordance with the present subject matter will exhibit improved resistance to shear at higher temperatures, as typically measured by Shear Adhesion Failure Testing (SAFT).
  • SAFT Shear Adhesion Failure Testing
  • the adhesives of the present subject matter may exhibit improved resistance to water whitening when immersed in water.
  • a hot water resistance test was developed to simulate the effect of pasteurization and as a standard method to determine candidate adhesive polymer opacity.
  • Opacity is the ratio of the reflectance of a sample backed with a white background to that of a sample backed with a black background, multiplied by one hundred, and reported as percent opacity.
  • a pressure sensitive adhesive is coated to a thickness of 1 mil on a clear 2 mil biaxially oriented polypropylene (BOPP) facestock or backing, dried at 60°C in an oven for 10 min. and cooled. After cooling, the film facestock or backing is immersed in a beaker of hot water water (65°C) for 60 min.
  • BOPP biaxially oriented polypropylene
  • the PSA coated facestock is then immediately laminated to a clear 2 mil polyester film with a plastic squeegee and opacity of the resultant laminate determined using a spectrocolorimeter (Hunter Lab Colorvid 45/0). Percentage opacity for the immersed sample is compared to a sample that has not been immersed and the difference is recorded as Delta Opacity. An opacity increase of up to about 6% is regarded as good. An opacity increase of up to about 2.5 is regarded as excellent. An opacity increase above 10.0% is regarded as poor for applications requiring a non-water whitening PSA.
  • the present subject matter adhesives have a delta opacity of less than 10%, in other embodiments less than 6%, and in certain embodiments less than 2%,
  • Adhesives using polymers of the present subject matter were prepared and compared to two currently known adhesives.
  • Table 4 set forth below, present various properties of an emulsion adhesive of the present subject matter (designated as "Advanced Emulsion") with (i) a currently known high performance solvent acrylic adhesive and (ii) a currently known low cost solvent acrylic adhesive.
  • Table 4 Comparison of Adhesive Properties Property Advanced Emulsion High Performance Solvent Acrylic Low Cost Solvent Acrylic Solids (%) 58 31 39 Room Temp Static Shear (0.5 x 0.5 inch/1,000 g- minutes) >5,000 >5,000 2,580 SAFT Shear Failure Temp (° C) >200 >200 109 Delta Opacity (Water Immersion for 1 hour at 65° C) ⁇ 2 ⁇ 2 ⁇ 2 15 min.
  • the adhesive according to the present subject matter contained a significantly higher solids content, superior 24 hour peel to HDPE, and comparable static shear, SAFT, opacity after water immersion (tested using the above described hot water resistance test), and other peel and tack characteristics as the two known adhesives.
  • Tackified adhesives were synthesized with target glass transition temperatures (Tg) of -20° C using predominantly 2-ethylhexyl acrylate and methyl acrylate monomers and Regalite R1090, an hydrocarbon resin tackifier with 90 deg C softening point.
  • Regalite R1090 was included at a level of 8.1% based on total monomer phase components (including tackifier).
  • methacrylic acid was included in each polymerization.
  • RAFT mediated polymerizations were conducted via mini-emulsion polymerization using a pre-made RAFT oligomer dissolved in the monomer phase together with a small amount of heptadecyl acrylate as a hydrophobe.
  • the RAFT oligomer was prepared in a solvent system.
  • the formulation was as provided in Table 5 as follows.
  • Table 5 - Representative Formulation for Forming RAFT Oligomer Reactor Charge % Total Ethyl Acetate 15.62 Methacrylic acid 21.44 Butyl Acrylate 50.24 DBTTC 100% 3.63 Methanol 4.50 Initiator Vazo-64 0.22 Ethyl Acetate 4.36 Reactor Charge Total 100.00
  • the recipe stoichiometry set forth in Table 5 was designed to deliver a 5,000 g/mol polymer with 4 AAEM (acetoacetoxyethyl methacrylate) molecules per polymer end.
  • the reaction was carried out at 80° C and when complete (i.e., conversion >98%), the solvent (ethyl acetate and methanol) was stripped from the polymer solution using rotary evaporation at 60 deg C.
  • the Mn of the isolated polymer was measured and found to be approximately 5000 g/mole with a PDI of approximately 1.5.
  • the RAFT mediated polymerizations yielded polymers having molecular weights of approximately 40,000 and 60,000 g/mol, with low polydispersity (PDI).
  • PDI polydispersity
  • Each polymer dispersion was neutralized to a pH within a range of 7.5 to 9.5 using ammonia solution before adding Jeffamine T403 (trifunctional amine) cross-linker at equivalent stoichiometric weight based on available AAEM.
  • Figure 8 is a graph comparing peel testing to both polypropylene and low density polyethylene surfaces for adhesives prepared in accordance with the present subject matter and where both level and softening point of hydrocarbon tackifier was varied. The results show that low softening point resin (R1010) failed to improve peel to polypropylene and that the lower modulus provided by 2-EHA copolymer improves 15 minutes and 24hr peel.
  • Figure 9 is a graph comparing static shear and delta opacity testing for tackified, 2EHA based polymers with different molecular weights for adhesives prepared in accordance with the present subject matter.
  • the copolymers shown in Figure 9 differ only in Mn via RAFT concentration and cross-linker addition.
  • the copolymers include 2EHA, MAA, and MA. It was observed that the lower Mn provides tighter network and faster relaxation via lower entanglement number leading to higher peel to low surface energy (LSE) materials, high static shear, and low percent delta opacity. That is, the adhesive appears to have a good balance of rheology for improved LSE adhesion and static shear whilst sufficiently cross-linked to provide excellent water resistance (and/or aided by inter-particle mixing of polymer chains prior to crosslinking).
  • LSE low surface energy
  • Polymer latex films were prepared by drawing down the latexes containing crosslinker directly to 2 mil polyethylene terephthalate (PET) film.
  • PET polyethylene terephthalate
  • the wet adhesive films were dried and cured in a convection oven at 120° C for 5 minutes before laminating to silicone coated glassine release paper.
  • Adhesive coat weight of prepared laminates was measured by weighing a 100 mm x 100 mm section of adhesive coated PET. The weight of a 100 mm x 100 mm uncoated sample of PET was subtracted and the result multiplied by 100 to obtain a coat weight estimate in g/m 2 .
  • 180° peel adhesion after 15 minutes and 24 hours dwell to low density polyethylene test panels was measured by applying a 1 inch wide strip of test laminate to a stainless steel panel with a 5 pound roller with 1 pass in each direction. Samples were conditioned and tested at 23° C. After 15 minutes and 24 hours dwell, the average peel force was measured over at least 20 mm of tests strip three times.
  • Static shear was measured by adhering a 1/2 inch by 1/2 inch area of a looped test strip to a stainless steel panel and rolling with a 5 pound roller with one pass in each direction. After allowing the test strips to dwell overnight, a 1000 g test weight was hung via the loop formed in the test strip and the time to failure recorded.
  • DMA Dynamic Mechanical Analysis

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (15)

  1. Composition d'émulsion polymère, comprenant :
    un copolymère à blocs acrylique incluant un tensioactif copolymérisé avec le copolymère à blocs acrylique, le tensioactif étant chimiquement lié à la chaîne polymère ;
    le copolymère acrylique incluant un premier segment de poids moléculaire et position contrôlés et un second segment de poids moléculaire et position contrôlés ;
    le premier segment incluant un monomère ayant un groupe fonctionnel sélectionné parmi le groupe constitué d'un groupe fonctionnel auto-réactif, d'un groupe fonctionnel réactif et de combinaisons de ceux-ci, dans laquelle le groupe fonctionnel auto-réactif est sélectionné parmi le groupe constitué de silanes, d'anhydrides, d'époxys, d'alcoxy-méthylol et d'éthers cycliques, et dans laquelle le groupe fonctionnel réactif est sélectionné parmi le groupe constitué de groupes acétoacétyle, d'acides, d'hydroxyles, d'amines, de thiols, de (méth)acrylates, de benzophénone, d'acétophénone, d'acylphosphine, de thioxanthone, et de dérivés de benzophénone, d'acétophénone, d'acylphosphine, de thioxanthone.
  2. Composition selon la revendication 1, dans laquelle le premier segment et le second segment sont miscibles avant durcissement.
  3. Composition selon la revendication 1 ou 2, dans laquelle le tensioactif copolymérisable est sélectionné parmi le groupe constitué de phénoléthoxylates d'alkyle substitués par allyle ou vinyle et leurs sulfates ; de copolymères à blocs d'oxyde de polyéthylène, d'oxyde de propylène ou d'oxyde de butylène avec des groupes terminaux polymérisables ; d'alcools éthoxylés substitués par allyle ou vinyle et leurs sulfates ; de demi-esters de maléate d'alcools gras ; d'éthoxylates de monoéthanolamide d'acides gras insaturés capables de subir une polymérisation autoxydative ; d'éthers de polyalkylène glycol d'allyle ou de vinyle ; de sulfates de glycoléther d'alkylpolyalkylène ; de monomère fonctionnalisé et de tensioactifs ; et de combinaisons de ceux-ci.
  4. Composition selon l'une quelconque des revendications 1 à 3, dans laquelle le premier segment du polymère acrylique est un copolymère dérivé d'un ou plusieurs des monomères du second segment et d'au moins un comonomère polymérisable ayant une fonctionnalité réticulable.
  5. Composition selon l'une quelconque des revendications 1 à 4, dans laquelle le groupe fonctionnel auto-réactif est un époxy, et/ou dans laquelle le groupe fonctionnel réactif est un acide.
  6. Composition selon l'une quelconque des revendications 1 à 5, incluant en outre un tackifiant, dans laquelle le tackifiant est sélectionné parmi le groupe constitué d'une résine d'hydrocarbure, de résine d'hydrocarbure hydrogénée, d'une résine d'hydrocarbure entièrement hydrogénée, d'un ester de colophane hydrogéné, d'un ester de colophane entièrement hydrogéné et de combinaisons de ceux-ci.
  7. Adhésif sensible à la pression comprenant :
    la composition selon l'une quelconque des revendications 1 à 6 ; et
    un agent de réticulation.
  8. Procédé à base d'émulsion de formation de polymères d'acrylate, le procédé comprenant :
    préparer une phase de monomère incluant (i) un ou plusieurs monomères d'acrylate, (ii) un oligomère d'acrylate à architecture contrôlée, et (iii) un ou plusieurs co-stabilisants d'acrylate, dans lequel l'oligomère d'acrylate à architecture contrôlée est préparé en combinant (i) un ou plusieurs monomères d'acrylate, (ii) un ou plusieurs agents pour polymérisation radicalaire contrôlée, et en option (iii) un ou plusieurs comonomères ;
    émulsifier la phase de monomère en utilisant un ou plusieurs tensioactifs copolymérisables pour former une mini-émulsion ; et
    préparer un latex d'ensemencement à partir de la mini-émulsion.
  9. Procédé selon la revendication 8, dans lequel le tensioactif copolymérisable est sélectionné parmi le groupe constitué de phénoléthoxylates d'alkyle substitués par allyle ou vinyle et leurs sulfates ; de copolymères à blocs d'oxyde de polyéthylène, d'oxyde de propylène ou d'oxyde de butylène avec des groupes terminaux polymérisables ; d'alcools éthoxylés substitués par allyle ou vinyle et leurs sulfates ; de demi-esters de maléate d'alcools gras ; d'éthoxylates de monoéthanolamide d'acides gras insaturés capables de subir une polymérisation autoxydative ; d'éthers de polyalkylène glycol d'allyle ou de vinyle ; de sulfates de glycoléther d'alkylpolyalkylène ; de monomère fonctionnalisé et de tensioactifs ; et de combinaisons de ceux-ci.
  10. Procédé selon la revendication 8 ou 9, dans lequel l'oligomère d'acrylate à architecture contrôlée est préparé par polymérisation en solvant, et/ou dans lequel l'agent pour polymérisation radicalaire contrôlée inclut du trithiocarbonate dibenzylique (DBTTC).
  11. Procédé selon l'une quelconque des revendications 8 à 10, comprenant en outre :
    faire pousser le latex d'ensemencement en utilisant une polymérisation en émulsion pour former de ce fait des polymères d'acrylate.
  12. Procédé selon l'une quelconque des revendications 8 à 11, dans lequel la préparation de la phase de monomère inclut un ou plusieurs tackifiants, dans lequel le tackifiant est sélectionné parmi le groupe constitué d'une résine d'hydrocarbure, de résine d'hydrocarbure hydrogénée, d'une résine d'hydrocarbure entièrement hydrogénée, d'un ester de colophane hydrogéné, d'un ester de colophane entièrement hydrogéné et de combinaisons de ceux-ci.
  13. Procédé selon l'une quelconque des revendications 8 à 12, dans lequel des monomères d'acrylate utilisés dans la préparation de la phase de monomère sont sélectionnés parmi le groupe constitué d' acrylates, de méthacrylates et de combinaisons de ceux-ci, et/ou dans lequel le co-stabilisant d'acrylate est un co-stabilisant d'acrylate en C6 à C20, de préférence l'acrylate d'heptadécyle.
  14. Procédé selon l'une quelconque des revendications 8 à 13, dans lequel préparer le latex d'ensemencement est réalisé par initiation thermique de la mini-émulsion.
  15. Polymères d'acrylate formés par les procédés selon l'une quelconque des revendications 8 à 14.
EP16730539.0A 2015-05-01 2016-05-02 Adhésifs sous forme d'émulsions d'acrylique Active EP3289037B1 (fr)

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Publication number Priority date Publication date Assignee Title
EP3739010B1 (fr) 2016-02-19 2024-09-04 Avery Dennison Corporation Procédés en deux étapes pour le traitement d'adhésifs et compositions associées
KR102182235B1 (ko) 2016-10-25 2020-11-24 애버리 데니슨 코포레이션 백본에 광개시제기를 갖는 블록 폴리머 및 접착제 조성물에서의 그것의 용도
US11505636B2 (en) * 2016-11-23 2022-11-22 Basf Se Binder compositions and methods of preparing and using the same
CN107955562A (zh) * 2017-12-06 2018-04-24 常德金德新材料科技股份有限公司 一种复合胶及其制备方法
CN111491967B (zh) * 2017-12-19 2023-05-02 艾利丹尼森公司 侧基官能团的聚合后官能化
CA3099249C (fr) 2018-05-03 2023-01-31 Eric L. Bartholomew Stratifies adhesifs et procede de fabrication de stratifies adhesifs
CN109337591B (zh) * 2018-09-17 2021-03-30 东莞市派乐玛新材料技术开发有限公司 一种低挥发性紫外光固化光学结构胶及其制备方法
JP2021127378A (ja) * 2020-02-13 2021-09-02 国立大学法人福井大学 接着構造体、接着構造体の製造方法、および異方性界面改質剤
KR102354796B1 (ko) * 2020-11-30 2022-01-24 한국화학연구원 점착제용 계면활성제 조성물 및 이를 포함하는 점착제
KR102338870B1 (ko) * 2020-11-30 2021-12-10 한국화학연구원 점착제용 계면활성제 조성물 및 이를 포함하는 점착제

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5264532A (en) 1989-08-14 1993-11-23 Avery Dennison Corporation Emulsion pressure-sensitive adhesives
US5990233A (en) * 1996-08-16 1999-11-23 National Starch And Chemical Investment Holding Corporation Rheology modifiers for use in aqueous compositions
EP2132243B1 (fr) 2007-04-05 2016-11-30 DSM IP Assets B.V. Émulsion polymère oligomère aqueuse à fonction cationique
JP5558660B2 (ja) 2007-05-11 2014-07-23 日東電工株式会社 両面接着性感圧接着シート
KR101750907B1 (ko) * 2008-03-20 2017-06-27 애버리 데니슨 코포레이션 작용기의 위치가 조절된 아크릴 중합체
JP5475959B2 (ja) * 2008-04-07 2014-04-16 日東電工株式会社 感圧接着シートおよびその製造方法
JP2009269956A (ja) * 2008-05-01 2009-11-19 Chuo Rika Kogyo Corp 水系エマルジョン型感圧接着剤
CN102076795B (zh) 2008-06-30 2015-05-13 帝斯曼知识产权资产管理有限公司 利用raft得到的嵌段共聚物对金属表面的粘附
JP2010084106A (ja) 2008-10-03 2010-04-15 Toray Fine Chemicals Co Ltd アクリルエマルジョンおよびその製造方法
ES2512440T3 (es) 2010-05-19 2014-10-24 Avery Dennison Corporation Arquitecturas ordenadas en polímeros acrílicos
CN103998481B (zh) 2011-10-14 2018-02-06 艾利丹尼森公司 可控构造聚合物
DE102011086502A1 (de) * 2011-11-16 2013-05-16 Tesa Se Verfahren zur Herstellung ungefärbter Polyacrylatklebemassen mit enger Molmassenverteilung
CN104203994A (zh) * 2012-02-03 2014-12-10 帝斯曼知识产权资产管理有限公司 聚合物、方法和组合物
US10717919B2 (en) * 2013-03-14 2020-07-21 Flotek Chemistry, Llc Methods and compositions for use in oil and/or gas wells
KR101687446B1 (ko) 2013-06-19 2016-12-16 주식회사 엘지화학 점착제 조성물
WO2015088478A1 (fr) * 2013-12-09 2015-06-18 Empire Technology Development Llc Procédés, systèmes de gravure du graphène et composites

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CN107709501B (zh) 2020-04-14
WO2016179076A8 (fr) 2017-11-23
US10287464B2 (en) 2019-05-14
KR20180002756A (ko) 2018-01-08
AU2016258589B2 (en) 2020-04-23
CN107709501A (zh) 2018-02-16
CA2984361A1 (fr) 2016-11-10
AU2016258589A1 (en) 2017-11-16
BR112017023451A2 (pt) 2018-07-31
JP7356789B2 (ja) 2023-10-05
JP2018522080A (ja) 2018-08-09
KR102591241B1 (ko) 2023-10-19
EP3289037A1 (fr) 2018-03-07
AU2020203583A1 (en) 2020-06-18
WO2016179076A1 (fr) 2016-11-10
US20160319169A1 (en) 2016-11-03
US11267999B2 (en) 2022-03-08
US20190161655A1 (en) 2019-05-30
AU2020203583B2 (en) 2021-06-24
CA2984361C (fr) 2023-09-26
CO2017011546A2 (es) 2018-03-28
MX2017014000A (es) 2018-02-21

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