EP3239331A1 - Hochfester stahl mit hervorragender sprödbruchstablität und herstellungsverfahren dafür - Google Patents

Hochfester stahl mit hervorragender sprödbruchstablität und herstellungsverfahren dafür Download PDF

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Publication number
EP3239331A1
EP3239331A1 EP15873589.4A EP15873589A EP3239331A1 EP 3239331 A1 EP3239331 A1 EP 3239331A1 EP 15873589 A EP15873589 A EP 15873589A EP 3239331 A1 EP3239331 A1 EP 3239331A1
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Prior art keywords
steel
strength steel
brittle crack
central portion
crack arrestability
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EP15873589.4A
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English (en)
French (fr)
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EP3239331B1 (de
EP3239331A4 (de
Inventor
Hak-Cheol Lee
Sung-Ho Jang
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Posco Holdings Inc
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Posco Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/02Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of sheets
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/001Heat treatment of ferrous alloys containing Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/021Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/08Ferrous alloys, e.g. steel alloys containing nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/16Ferrous alloys, e.g. steel alloys containing copper
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2201/00Treatment for obtaining particular effects
    • C21D2201/05Grain orientation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling

Definitions

  • the present disclosure relates to a high-strength steel having excellent brittle crack arrestability and a method of manufacturing the same.
  • brittle crack arrestability referring to stability of a structure
  • a high-strength steel is applied to a major structure such as a ship, or the like
  • cases in which guaranteed levels of brittle crack arrestability are required have increased.
  • a low temperature transformation phase is generated in a central portion, a phenomenon in which brittle crack arrestability is significantly reduced occurs. Therefore, it may be difficult to improve brittle crack arrestability of an extremely thick high-strength steel.
  • An aspect of the present disclosure is to provide a high-strength steel having excellent brittle crack arrestability.
  • a high-strength steel having excellent brittle crack arrestability includes 0.05 wt% to 0.1 wt% of carbon (C), 0.9 wt% to 1.5 wt% of manganese (Mn), 0.8 wt% to 1.5 wt% of nickel (Ni), 0.005 wt% to 0.1 wt% of niobium (Nb), 0.005 wt% to 0.1 wt% of titanium (Ti), 0.1 wt% to 0.6 wt% of copper (Cu), 0.1 wt% to 0.4 wt% of silicon (Si), 100 ppm or less of phosphorous (P), 40 ppm or less of sulfur (S), and the remainder being iron (Fe) and other inevitably contained impurities, the high-strength steel having a microstructure including one structure selected from the group consisting of a single-phase structure of ferrite, a single-phase structure of bainite, a complex-
  • the contents of Cu and Ni may be set such that a Cu/Ni weight ratio may be 0.6 or less, in detail, 0.5 or less.
  • yield strength may be 390 MPa or more.
  • a method of manufacturing a high-strength steel having excellent brittle crack arrestability includes: reheating a slab at 950°C to 1100°C, the slab including 0.05 wt% to 0.1 wt % of carbon (C), 0.9 wt% to 1.5 wt% of manganese (Mn), 0.8 wt% to 1.
  • a crystal grain size of a central portion of the bar in a thickness direction before the finish rolling after the rough rolling may be 200 ⁇ m or less, preferably 150 ⁇ m or less, and more preferably 100 ⁇ m or less.
  • a reduction ratio during the finish rolling may be set such that a ratio of a slab thickness (mm)/a steel sheet thickness (mm) after finish rolling may be 3.5 or above, preferably 3.8 or above.
  • the cooling of the steel sheet may be performed at a cooling rate of a central portion of the steel sheet in a thickness direction of 2°C/s or more.
  • the cooling of the steel sheet may be performed at an average cooling rate from 3°C/s to 300°C/s.
  • a high-strength steel having high yield strength and excellent brittle crack arrestability may be obtained.
  • FIG. 1 is an image of a central portion of Inventive steel 1 in a thickness direction, captured with an optical microscope.
  • the inventors conducted research and experiments into improving yield strength and brittle crack arrestability of a thick steel having a thickness of 50 mm or more, and the present disclosure has been proposed based on the results thereof.
  • a steel composition, a structure, a texture, and manufacturing conditions of a steel are controlled, so yield strength and brittle crack arrestability of a steel having a thick thickness are further improved.
  • a main concept in the present disclosure is as follows.
  • a high-strength steel having excellent brittle crack arrestability includes 0.05 wt% to 0.1 wt% of C, 0.9 wt% to 1.5 wt% of Mn, 0.8 wt% to 1.5 wt% of Ni, 0.005 wt% to 0.1 wt% of Nb, 0.005 wt% to 0.1 wt% of Ti, 0.1 wt% to 0.6 wt% of Cu, 0.1 wt% to 0.4 wt% of Si, 100 ppm or less of P, 40 ppm or less of S, and the remainder being iron (Fe) and other inevitably contained impurities, and has a microstructure including one structure selected from the group consisting of a single-phase structure of ferrite, a single-phase structure of bainite, a complex-phase structure of ferrite and bainite, a complex-phase structure of ferrite and pearlite, and a complex-phase structure of ferrite
  • the content of C exceeds 0.10%, due to the generation of a large amount of martensite-austenite constituent (MA), high strength of ferrite itself, and generation of a large amount of a low temperature transformation phase, or the like, low temperature toughness may be reduced.
  • the content of C is preferably limited to 0.05% to 0.10%, more preferably limited to 0.061% to 0.091%, and most preferably limited to 0.065% to 0.085%.
  • Mn is a useful element for improving strength due to solid solution strengthening and for improving hardenability to allow a low temperature transformation phase to be generated.
  • Mn is preferably added in an amount of 0.9% or more.
  • Ni is an important element, allowing dislocation cross-slip to be easily performed at a low temperature to improve impact toughness, and improving hardenability to improve strength.
  • Ni is preferably added in an amount of 0.8% or more.
  • an upper limit of the content of Ni is preferably limited to 1.5%.
  • Nb is precipitated in the form of NbC or NbCN, thereby improving strength of a base material.
  • Cu is a main element in improving strength of a steel by improving hardenability and causing solid solution strengthening, and is a main element in increasing a yield strength due to generation of ⁇ (epsilon) Cu precipitate when tempering is applied.
  • Cu is preferably added in an amount of 0.1% or more.
  • an upper limit of the content of Cu is preferably limited to 0.6%.
  • iron (Fe) may be provided as a remainder thereof.
  • fraction of pearlite is preferably limited to 20% or less.
  • the grain size of a structure of a central portion of the steel is refined to be 30 ⁇ m or less, so strength is improved due to strengthening by grain refinement, while brittle crack arrestability is improved by significantly reducing the generation and propagation of cracks.
  • an area ratio of a (100) plane forming an angle within 15 degrees with respect to a plane perpendicular to a rolling direction is significantly reduced.
  • the steel has a thickness of 50 mm or more, preferably has a thickness of 50 mm to 100 mm, and more preferably has a thickness of 80 mm to 100 mm.
  • the slab, having been reheated, is rough rolled.
  • a total cumulative reduction ratio during rough rolling is preferably set to be 40% or more.
  • a microstructure, yield strength, an average grain size of a central portion measured in EBSD, an area ratio of a (100) plane forming an angle within 15 degrees with respect to a plane perpendicular to a rolling direction in a region of the high-strength steel in a range of 20% of an overall steel thickness based on a position equal to 1/2 of the steel thickness, a Kca value (a brittle crack arrestability coefficient) were investigated, and a result thereof is illustrated in Table 2.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
EP15873589.4A 2014-12-24 2015-12-21 Hochfester stahl mit hervorragender sprödbruchstablität und herstellungsverfahren dafür Active EP3239331B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20140189132 2014-12-24
PCT/KR2015/014054 WO2016105062A1 (ko) 2014-12-24 2015-12-21 취성균열전파 저항성이 우수한 고강도 강재 및 그 제조방법

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EP3239331A1 true EP3239331A1 (de) 2017-11-01
EP3239331A4 EP3239331A4 (de) 2017-11-08
EP3239331B1 EP3239331B1 (de) 2020-10-28

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US (1) US20170327922A1 (de)
EP (1) EP3239331B1 (de)
JP (1) JP6788589B2 (de)
KR (1) KR101746999B1 (de)
CN (1) CN107109597B (de)
WO (1) WO2016105062A1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018024910A (ja) * 2016-08-09 2018-02-15 Jfeスチール株式会社 高強度厚鋼板およびその製造方法
EP3561112A4 (de) * 2016-12-22 2019-10-30 Posco Ultradickes stahlmaterial mit hervorragenden nrl-dwt-eigenschaften des oberflächenteils und verfahren zur herstellung davon

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10822671B2 (en) 2014-12-24 2020-11-03 Posco High-strength steel having superior brittle crack arrestability, and production method therefor
CN107109592A (zh) 2014-12-24 2017-08-29 Posco公司 耐脆性裂纹扩展性优异的高强度钢材及其制造方法
KR102209561B1 (ko) * 2018-11-30 2021-01-28 주식회사 포스코 취성균열전파 저항성이 우수한 극후물 강재 및 그 제조방법
KR102209547B1 (ko) * 2018-12-19 2021-01-28 주식회사 포스코 취성균열개시 저항성이 우수한 구조용 극후물 강재 및 그 제조방법

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KR20130134333A (ko) * 2012-05-30 2013-12-10 현대제철 주식회사 고강도 강판 및 그 제조 방법
KR20140098900A (ko) * 2013-01-31 2014-08-11 현대제철 주식회사 고강도 극후물 강판 및 그 제조 방법
US10822671B2 (en) * 2014-12-24 2020-11-03 Posco High-strength steel having superior brittle crack arrestability, and production method therefor
CN107109592A (zh) * 2014-12-24 2017-08-29 Posco公司 耐脆性裂纹扩展性优异的高强度钢材及其制造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018024910A (ja) * 2016-08-09 2018-02-15 Jfeスチール株式会社 高強度厚鋼板およびその製造方法
EP3561112A4 (de) * 2016-12-22 2019-10-30 Posco Ultradickes stahlmaterial mit hervorragenden nrl-dwt-eigenschaften des oberflächenteils und verfahren zur herstellung davon

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EP3239331B1 (de) 2020-10-28
WO2016105062A1 (ko) 2016-06-30
CN107109597A (zh) 2017-08-29
CN107109597B (zh) 2020-01-31
WO2016105062A8 (ko) 2016-11-24
EP3239331A4 (de) 2017-11-08
KR101746999B1 (ko) 2017-06-15
JP2018503744A (ja) 2018-02-08
US20170327922A1 (en) 2017-11-16
JP6788589B2 (ja) 2020-11-25
KR20160078926A (ko) 2016-07-05

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