Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
  • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
  • B32B17/10082—Properties of the bulk of a glass sheet
  • B32B17/1011—Properties of the bulk of a glass sheet having predetermined tint or excitation purity
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
  • B32B17/10183—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer being not continuous, e.g. in edge regions
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
  • B32B17/10348—Specific parts of the laminated safety glass or glazing being colored or tinted comprising an obscuration band
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10431—Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
  • B32B17/10467—Variable transmission
  • B32B17/10495—Variable transmission optoelectronic, i.e. optical valve
  • B32B17/10504—Liquid crystal layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/10165—Functional features of the laminated safety glass or glazing
  • B32B17/10431—Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
  • B32B17/10467—Variable transmission
  • B32B17/10495—Variable transmission optoelectronic, i.e. optical valve
  • B32B17/10532—Suspended particle layer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10651—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments
  • B32B17/1066—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments imparting a tint in certain regions only, i.e. shade band
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10752—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polycarbonate
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
  • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
  • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
  • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
  • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
  • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
  • G02B27/0018—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 with means for preventing ghost images
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2307/00—Properties of the layers or laminate
  • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
  • B32B2307/102—Insulating
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B32—LAYERED PRODUCTS
  • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
  • B32B2605/00—Vehicles
  • B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings

Definitions

• the present invention relates to a laminated glazing, in particular a laminated glazing intended to be used as glazing for the automobile, for example as roof, windshield, rear window, side window of a vehicle.
• the invention even if the invention is first intended for application to automotive glazing, it also relates to other types of glazing and generally all glazing comprising a functional film, particularly when they present in their constitution or in their implementation, constraints including heat treatment.
• the remainder of the description refers essentially to automotive glazing and in particular to automotive glass roofs, it being understood that this does not limit the object of the invention.
• Glazed roofs are replacing an increasing part of the traditional roofs that are part of the body of vehicles.
• the choice of these roofs is the fact of the manufacturers to offer their customers this option giving the impression of opening the vehicle to the outside, like a cabriolet, without having the disadvantages of the latter, the roofs now the comfort of a traditional sedan. For this, glazed roofs must meet many requirements.
• the choice of glazed roofs aims in particular to increase the brightness in the cabin. This gain should not be contrary to other properties that ensure passenger comfort, especially thermal comfort and acoustic comfort.
• the latter is preserved or even improved by the presence of the laminated structure, in particular when it comprises interleaves selected for their vibration damping capacity, on the model of what is used in particular for the glazing of the screens. broken.
• the desire for an increase in brightness in the passenger compartment is not necessarily permanent.
• the user can, depending on the moment, prefer a lower brightness, or simply maintain the "private" character.
• glazings comprising functional films such as electro-chromium means in which the variation is obtained by modifying the state of colored ions in compositions included in these windows.
• functional films such as electro-chromium means in which the variation is obtained by modifying the state of colored ions in compositions included in these windows.
• SPD for "suspended particle devices”
• crystal-like film comprising layers of particles in suspension, which according to the application of an electric voltage are ordered or not such as the systems known as SPD (for "suspended particle devices") or a crystal-like film.
• liquid (LC) consisting of a polymer containing liquid crystals sensitive to the application of electrical voltage.
• these functional films if they allow a change in the intensity of the brightness in the passenger compartment, they have the function of modifying the privacy and the anti-glare effect.
• these functional films are switchable films between a dark state and a translucent or even transparent state or which is capable of providing a lighting function inside a vehicle in which the glazing is mounted.
• the use of liquid crystal films in glazing has been envisaged for the constitution of controlled visual isolation walls.
• the main function is the transformation of a substantially transparent glazing into a simply translucent glazing. These applications did not involve specific thermal characteristics. Similarly, light transmission was not critical.
• windows comprising an SPDs film.
• Such glazings are for example described in WO2005 / 102688 and DE 100 43 141.
• the film is switchable between a dark state (in the absence of applied voltage) and a very transparent state (when a voltage is applied).
• thermoplastic interlayer In general, whether it is a functional film of the SPD or liquid crystal (LC) type or a film comprising light-emitting diodes, the latter is laminated in a laminated glazing structure by means of at least one thermoplastic interlayer.
• This implementation is for example described in the document US2004 / 0257649.
• Such laminated glazings having variable light transmission properties due to the inclusion of a liquid crystal film (LC) or an SPD film are increasingly sought after due to improved passenger comfort. Indeed, once mounted in a vehicle, the glazing provided with such a film reduces the heat in the vehicle interior, but also allows to adjust the desired brightness inside the vehicle.
• LC liquid crystal film
• SPD film SPD film
• the zone situated at the edge of the functional film can be damaged and lead to an alteration of the film and in particular of the switching function, for example .
• Exposure to such prolonged temperatures results in particular from the application of an electric field to activate the film and / or heat conducted through the glass sheets and the enamel layer, or solar radiation.
• the functional film when integrated in a laminated glazing and positioned on a vehicle especially as a glazed roof, it must advantageously withstand high temperatures that can reach temperatures above 85 ° C. Beyond this temperature, and for prolonged exposure, the functional film deteriorates. This temperature is reached especially when the functional film is in the active position (ON position). Thus, the functional film when integrated in multiple glazing must be protected from temperature rises.
• the numbering of the sheets of glass in the following description refers to the numbering nomenclature conventionally used for glazing.
• face 1 the face of the laminate which is in contact with the environment outside the vehicle
• face 4 the surface in contact with the internal medium, that is to say the passenger compartment of the vehicle
• the terms "external” and “internal” refer to the orientation of the glazing when installed as glazing in a vehicle.
• the automotive laminated glazings are printed on the entire periphery of the edges of the glazing on the face 2, to form an occultation band, in order to protect UV radiation, the glue for adhering all the busbars and the electrical connectors between the functional film and the wiring harness of the vehicle, and on the other hand to hide these elements.
• the purpose of the band is twofold, on the one hand the aesthetics, because from the outside all these elements are not visible from the outside, and on the other hand, to avoid the damage of glue or other components of UV exposure.
• the occultation band can also be used to mask the edges of the functional film.
• the impression used is the screen printing of the enamel.
• the enamel provides the optical qualities required and sufficient masking elements such as those mentioned above.
• the enamel is screen printed on the inside face of the glass sheet intended for the outer position, that is to say in contact with the atmosphere, called face 2, and / or on the outside face of the sheet glass for the inner position, called the face 4, which is in contact with the interior atmosphere, including the passenger compartment of a vehicle.
• the invention consists in substituting the screen printing usually used on at least the face 2 to generally hide the edge of the glazing by a thermoplastic interlayer film comprising an area opaque to the visible wavelength radiation.
• thermoplastic interlayer opaque to visible wavelength radiation can also be positioned on the face 4 or any other position.
• Opaque zone is defined as the radiation of visible wavelengths, an area whose light transmission is less than 5% and preferably equal to 0% of the incident light.
• This opaque zone unlike enamel, allows both masking elements as connectors (busbars ...), glue ... as enamel but especially prevents the absorption of infrared radiation and therefore allow to protect the functional film from heat (ie high temperatures).
• opaque zone will refer to the area opaque to visible wavelength radiation.
• the invention therefore aims to provide a means for protecting a functional film against heat, when it is integrated in a laminated glazing, while allowing to hide elements such as busbars, connectors. .. as does the email conventionally used in automotive glasses.
• a functional film powered electrically vs. means for reflecting the infrared radiation disposed between the first glass sheet and the electrically powered functional film, d. at least a first thermoplastic interlayer disposed between the means for reflecting infrared radiation and the functional film,
• the laminated glazing comprises at least a first spacer comprising an area opaque to the radiation of the wavelengths of the visible.
• said opaque zone extends over the entire periphery of the glass sheet on which it is applied, just like the enamel layer. This opaque zone thus replaces the enamel conventionally used.
• the opaque zone may extend over a large portion of the laminated glazing.
• said opaque zone extends over the entire periphery of the internal face of the outer glass sheet, that is to say, face 2.
• the functional film between at least two sheets of glass is protected against heat from, in particular, the absorption of infra-red by the glass sheets which during the heating step during the lamination process and / or applying an electric field to activate the film and / or heat conducted through the glass sheets or solar radiation.
• Functional films such as PDLCs and SPDs are sensitive to both temperature and humidity, so the performance of these films can be affected. For example, the life of the functional film can be significantly reduced if it is subjected to high temperatures for an extended period of time.
• the functional film is alterable at an elevated temperature.
• such a film comprises liquid crystals dispersed in a polymer (PDLC) or dispersed particles suspended in a polymer (SPD). Thanks to the invention, the duration of the half-life of the electroluminescent device can be increased.
• High temperature means temperatures above 60 ° C and preferably temperatures above 80 ° C.
• the functional film subjected to such prolonged temperatures deteriorates. It is therefore necessary to greatly reduce or eliminate the infrared absorption by the glass sheet which will be placed on the outside of the vehicle because the infrared are then led to the functional film.
• the functional film is not sufficiently protected from infrared radiation at the edges of the laminated glazing in which it is integrated because usually an enamel layer is present to hide the edges but this enamel layer is present in the glazing laminated before the reflective layer infrared radiation.
• the edge of the glazing can reach temperatures above 100 ° C which ultimately damage the functional film.
• the temperatures measured at the edges of the glazing, at the opaque zone are less than 100 ° C and preferably less than 90 ° C and even more preferably less than 85 ° C.
• the functional film is no longer subjected to high temperatures which eventually lead to degradation of the functional film.
• thermoplastic interlayer comprising an opaque zone is formed from an opaque frame disposed around the non-opaque zone.
• a thermoplastic interlayer in its entirety and size allowing the lamination of the glass sheets together can be hollowed out of its central portion to form a frame.
• the central part is then replaced by a non-opaque or transparent thermoplastic interlayer.
• the frame is formed of strips of opaque interlayer, for example a PVB or EVA stained black in the juxtaposed mass, the strips being arranged around a central part of a thermoplastic interlayer, the pieces will be fused together. to form the thermoplastic interlayer which will extend over the entire periphery of the glass sheets.
• thermoplastic interlayer according to the invention comprises an opaque zone for protecting the functional film from infrared radiation, this opaque zone surrounding an opaque zone.
• the at least one thermoplastic interlayer may be of any material known in the art capable of forming a laminate. It can be an ethylene-vinyl acetate, polyurethane, polycarbonate, polyvinyl butyral copolymer, polyvinyl chloride or a copolymer of ethylene and methacrylic acid. According to a preferred embodiment of the invention, the thermoplastic interlayer comprising an area opaque to the radiation of the visible lengths is a sheet of polyvinyl butyral (PVB) or ethylene-vinyl acetate (EVA).
• PVB polyvinyl butyral
• EVA ethylene-vinyl acetate
• thermoplastic interlayer comprising an opaque zone is obtained by mass staining of the periphery of the interlayer.
• the thermoplastic interlayer comprising an opaque zone is obtained by juxtaposing an opaque colored thermoplastic interlayer frame and a central part formed of a transparent interlayer, the opaque frame and the central part of the interlayer thermoplastic may be in the same or different thermoplastic material, one being colored and the other not.
• the dimensions of the opaque zone are similar to those usually used for an enamel layer. It is understood that they may be greater or smaller than those of the enamel layer, the aim being that the opaque zone is wide enough to hide the elements glued to the glazing such as busbars, connectors ....
• thermoplastic interlayer comprising an area opaque to the radiation of the lengths of the visible, according to the invention is disposed substantially on the surface of the glazing.
• the laminated glazing further comprises a second thermoplastic interlayer flanking the functional film.
• the second thermoplastic interlayer is preferably a polyvinyl butyral (PVB) sheet.
• the functional film is then smaller than the glass sheets between which the film will be laminated.
• the functional film is then placed in a pre-cut region of the second thermoplastic interlayer so as to promote its lamination between the two glass sheets and prevent the formation of bubbles in the laminated glazing.
• the first and second sheets of glass are laminated by means of at least three thermoplastic interleaves.
• the first thermoplastic interlayer is the thermoplastic interlayer comprising an opaque zone, and disposed on the face 2 of the laminated glazing according to the invention
• the second interlayer is a thermoplastic interlayer flanking the functional film
• the third thermoplastic interlayer is disposed on the face 3 of the laminated glazing according to the invention.
• at least one of the three thermoplastic spacers is chosen from a copolymer of polyvinyl butyral or ethylene-vinyl acetate, or polyurethane, or polycarbonate.
• thermoplastic spacers may be disposed between the functional film and the glass sheets.
• Such a design using at least three thermoplastic spacers including a flanking the functional film, may be particularly advantageous for laminating an electrically powered functional film, whose thickness is greater than fifty microns.
• thermoplastic interleaves are positioned between the functional film and the second glass sheet.
• the control of the functional film may comprise simple switches or else sensors placed between the functional film and the second glass sheet or on the face 4 of the laminated glazing unit. If it is desired to have a switch on the glass roof itself, it is desirable that it does not hinder the transparency at the origin of the choice of glazed roofs.
• the invention proposes to use control means of the functional film which are also essentially transparent.
• the invention proposes to use switches whose implementation is triggered by means of relays actuated by a pulse linked to an electrical quantity.
• the switch used is of the capacitive type. This mode is the one that allows to use the best structure of the elements included in the roof.
• a capacitive sensor may be direct contact type.
• the sensitive element is for example a zone defined in a low-e layer located on the side facing the passenger compartment.
• the low-e layers being conductive can serve as a sensor for the control of the interrupt relay.
• the advantage of the direct contact is that the contact induced capacitance change can be relatively large so that the threshold controlling the switch can be high enough to rule out any parasitic triggering.
• the means for reflecting the infrared radiation provided in the laminated glazing is preferably an infrared reflective layer.
• the glazing according to the invention comprises thin layers reflecting infrared.
• Such layers are in particular those comprising one or more metallic thin layers, in particular based on silver, associated with thin dielectric layers which contribute in particular to the selectivity of the filter.
• These sets of layers are arranged either on a support sheet, in particular PET, inserted into the laminate, or not directly applied to the glass sheet. In both cases, this means for reflecting the infrared is located in the laminate above the functional film, improving the protection of this film.
• Such infrared reflective layers are used in many applications in sunscreen glazing or low-emissivity glazing. They generally consist of thin layers of conductive oxides, or better, because much more efficient metal layers thin enough to be virtually transparent. In these means for reflecting the infrared are associated with dielectric layers also thin and transparent which give the set the necessary selectivity. Most often to improve this selectivity, which is accompanied by reflection that is striven to make as neutral as possible, the filters comprise a plurality of metal layers which are usually based on silver.
• the choice of the layer system is advantageously that of multi-layered silver systems to obtain a means for reflecting infrared effective and allows the control of the color including reflection.
• a particularly effective set of layers is as described in WO2011 / 147875.
• the recommended system comprises three layers of silver and dielectric layers, the assembly being chosen, in particular the thicknesses of the silver layers, such that the coloration in reflection is satisfactory even under low observation angles.
• the means for reflecting the infrared radiation is provided on the face 2 of the laminated glazing between the outer glass sheet and the functional film, that is to say the inner face of the first glass sheet.
• it can also be provided on one side of the second glass sheet included in the laminated glazing.
• the one or more layers from which the infrared reflecting film is formed are of the order of a few tens of nanometers in thickness.
• the layer does not extend to the ends of the glass sheet, the area separating the edge of the glazing from the beginning of the infrared reflecting layer is commonly called Edge delition.
• the functional film is placed at a distance from the edge of the leaf glazing and in particular from the so-called "Edge delition” zone. This minimal distance, which is a function of the length of the "edge delition” zone, dissipates the calories and thus protects the functional film.
• the infrared reflective layer may comprise a plurality of non-metallic layers, such that it functions as a band-pass filter (the band being centered on the region of the near infrared of the electromagnetic spectrum).
• the laminated glazing according to the invention when used as automotive glazing, can be described as comprising an outer glass sheet and an inner glass sheet, a means for reflecting infrared provided between the glass sheet external of the laminated glazing and the functional film, which reduces the amount of infrared radiation that could otherwise be incident on the functional film and therefore deteriorate.
• laminated glazing units of the prior art comprising a functional film and a means for reflecting the infrared and in particular when this means is a metal layer, it is applied on the face 2 after the enamel layer.
• the amount of infrared that can be conducted to the functional film is greater in comparison with the invention.
• the infrared reflecting layer is according to the invention in direct contact with the glass sheet and is provided before the interlayer comprising an opaque zone.
• the infrared reflecting layer plays its role fully and uniformly.
• the amount of infrared penetrating in particular at the edges of the glazing and consequently transmitted by conduction to the functional film, which are masked by the opaque zone of the thermoplastic interlayer is thus reduced.
• opto-energetic characteristics in the opaque zone at the edges of the glazing seen from outside the vehicle are improved.
• the energy reflection is less than 60%, less than 55% preferably, and more preferably less than 50%.
• the reflection in the infrared is greater than 70%, preferably greater than 80% and even more preferably greater than 85%.
• the light transmission in this opaque zone is preferably less than 5% and preferably 0%.
• These properties make it possible to guarantee a good aesthetics of the outside of the vehicle (connector cover, ...) and at the same time to prevent overheating of the roof due to solar radiation in this area.
• the components of the functional films can be degraded by excessive UV exposure. The choice of inserts limits this exposure considerably. This is particularly the case for the use of PVB interleaves, which by nature are UV-shielded, allowing only a very small proportion of them to pass through. For PVB films 0.38mm thick more than 95% UV is removed. This proportion may exceed 99%.
• Ethylene vinyl acetate (EVA) -based polymers are also provided which contain components which impart a very low UV transmission.
• the at least one thermoplastic interlayer and in particular the non-opaque area is a thermoplastic interlayer that forms a UV screen, also called "UV-cut".
• a glazed roof modifies the conditions of thermal comfort for the occupants of the vehicle. If warming when the vehicle is exposed to the sun leads to the conditions stated above, for the passengers the presence of glazed roofs can also lead to what is termed a "cold shoulder" sensation when the outside temperature is lower than the ambient temperatures. of comfort. This sensation is caused by a loss of heat from the cabin, by the emission of far infrared.
• low-e layers low-emissive layer
• the layers in question act as a filter selectively reflecting the far infrared rays emitted from the passenger compartment, without constituting an important obstacle to the transmission of the rays of the domain. visible from the outside to the inside.
• so-called "hard” layers such as those produced by pyrolytic, CVD or PECVD type techniques, are chosen.
• low-e systems can also be prepared by vacuum cathodic sputtering techniques, provided that these systems are protected by sufficiently strong layers.
• a system of low-emissivity layers whose emissivity is less than 0.3 and preferably less than 0.2, and particularly preferably less than 0.1.
• the most common "low-e" (low-emissive) pyrolytic systems comprise a layer of doped tin oxide deposited on a first layer whose function is to neutralize the color in reflection.
• the layer in contact with the glass is usually a layer of silica or silicon oxy-carbide, optionally modified with additives.
• the tin oxide layers compared to the layers of the systems deposited by cathodic sputtering, are relatively thick, more than 200 nm, and for some more than 450 nm. These thick layers are strong enough to withstand being exposed to mechanical and / or chemical tests.
• the functional film according to the invention is electrically powered. Its connection to the general power system of the vehicle is necessarily from the edges of the glazing.
• the electrical connection leads are normally not transparent.
• efforts are made to conceal these pipes in the peripheral zones of the glazing, which comprise, according to one embodiment of the invention, an opaque zone formed by a thermoplastic interlayer intended, in particular for mask the irregular gluing marks of the glazing on the bodywork and protect the functional film against heat.
• thermoplastic interlayer comprising an opaque zone may have infrared reflection properties and / or acoustic insulation properties (commonly known as an "acoustic interlayer" material).
• the functional film makes it possible to vary the light transmission of the glazing unit incorporating the film.
• the diffusion ratio in known manner, is adjustable according to the applied electric field.
• the orientation of the crystals is directly dependent on this field.
• the increase of the field remains limited to what the films can support without risk of breakdown, corresponding to a short circuit between the electrodes which cover the functional material consisting essentially of polymer containing the liquid crystals.
• the supportable voltage may depend in part on the thickness of the film. For the reasons indicated above, this thickness is limited. Under these conditions the supportable voltage for the usual films is of the order of 220V.
• the glazings according to the invention are composed in such a way that the penetrating light by transmission and diffusion in the activated state of the film LC is not greater than 50% of the incident light and preferably less than 40% or even 30% . This proportion can be much smaller. Nevertheless, the glazings according to the invention advantageously have a global rate of transmission and diffusion in the activated state of the LC film, which is not less than 5% and preferably not less than 10%.
• the presence of the LC film makes it possible to modulate the diffusion transmission assembly according to the activated state or not of the electric field.
• glazings comprising an LC film
• the most important is the fact that we go from a fully diffusing, and therefore essentially translucent, set to a state in which the transmitted light has only a small diffusion fraction. as indicated above. Nevertheless the transition from one state to another is also accompanied by a variation in the luminous flux entering the passenger compartment.
• the ratio of light penetrating to the activated state in the non-activated state is advantageously at least 1 , 5 and preferably at least 2. This ratio is found almost also in that of energetic transmissions.
• At least one of the glass sheets used in the glazing is colored.
• the two glass sheets are colored.
• the glazing may also include colored dividers which contribute to the establishment of the desired optical conditions.
• a colored sheet is chosen so that under a thickness of 4 mm its transmission is not greater than 50%.
• thermoplastic interleaves can be superimposed to obtain a particular color or optical conditions.
• LC films tend to have a slightly yellow coloring especially in reflection. It is desirable, in order to avoid this appearance perceived by the passengers of the vehicle, to ensure that the glass sheet, and / or an interlayer arranged between the film LC and this sheet of glass turned towards the passenger compartment, is colored so as to hide this yellow shade. Most often one chooses a glass sheet and / or an insert of neutral coloring, preferably gray or bluish gray.
• a SPD can also be chosen to satisfy the need for privacy and the absence of glare.
• a SPD is a film comprising a plurality of particles suspended in a liquid suspension medium, which are held in a polymer medium.
• the film is switchable between a dark state (in the absence of voltage is applied), and a very transparent state (when a voltage is applied).
• the degree of relative alignment between the particles is determined by the applied AC voltage, so that an SPD-based device has a variable optical transmission when a variable voltage is applied.
• the SPD film in a laminated glazing structure may represent all or part of an intermediate layer between the two sheets of glass.
• the functional film according to the invention may comprise light-emitting diodes. There are many light-emitting diodes known in the state of the art that can be used in accordance with the present invention.
• the invention further relates to a method for manufacturing a laminated glazing as described above.
• the invention also relates to the use of at least one thermoplastic interlayer comprising an area opaque to visible wavelength radiation, for protecting an alterable functional film from heat at high temperatures, said film being between at least two sheets of glass.
• Figure 1 shows a schematic plan view of prior art glazing 10 comprising a PDLC film laminated between 2 sheets of glass.
• FIG. 2 shows a schematic plan view of a thermoplastic spacer 20 comprising an opaque zone 21 at the visible wavelength radiation. Said opaque zone framing a non-opaque zone 22.
• FIG. 3 shows a schematic plan view of a glazing unit 10 according to the invention comprising a PDLC film laminated between 2 glass sheets and a thermoplastic interlayer comprising an area opaque to areas opaque to visible wavelength radiation.
• FIG. 1 shows a laminated glazing unit known from the prior art, in the form of an automotive glazed roof 10, comprising a functional film in the form of a dispersed liquid crystal polymer film 12 mounted inside the laminated structure. The Figure 1 does not show the curvatures of the leaves for the sake of clarity.
• the roofs, glazed or not have curvatures which are usually more accentuated on the edges at the location of attachment to the bodywork for a docking chosen for its "design”, aerodynamics and appearance "flush Corresponding to a good surface continuity between the contiguous elements.
• the functional film is an LC type film made of a polymer containing liquid crystals sensitive to the application of electrical voltage.
• the film is of the PDLC (polymer dispersed liquid crystal) type.
• This laminated structure further comprises a sensor sensitive to the application of the electrical voltage so as to activate the PDLC film (not shown), such a sensor being able to be placed between the PDLC and the second glass sheet
• the dispersed liquid crystal polymer (PDLC) film 12 is shown to be positioned near the edges of the glass sheets 11 and 16 of the glazing 10, but could be positioned anywhere inside the glazing, for example In the center. However, in order to protect the PDLC film inside the laminated glazing, it is preferable that the edges of the film do not reach the edges of the glass sheets 11 and 16.
• the PDLC film is "framed" by a PVB frame 17 (corresponding to the second thermoplastic spacer described above) and is laminated between two thermoplastic interleaves 17 and 18 (respectively corresponding to the first and third thermoplastic spacers), this assembly is itself same laminated between an outer glass sheet 11 and an outer glass sheet 16.
• the thermoplastic interlayer 18 is added so as to ensure sufficient adhesion between the PDLC film 12 and the outer glass sheet glass 16. It is known to use a "frame” design framing the functional film, itself laminated between two thermoplastic spacers, for laminating a functional film within a glazing unit. According to a particular embodiment of the invention and as illustrated by FIGS.
• thermoplastic interlocks 17 and 18 are made of PVB, but of course they may be in a completely different material capable of lamination of the functional film. Between two sheets of glass. Thermoplastic interleaves 17 and 18 are co- extensive with glass sheets 11 and 16.
• the PDLC film has a thickness of 0.38mm.
• an obscuration band 101 and 102 More precisely an enamel layer which has the role of on the one hand to hide and protect the sealing material (not shown) which is used to fix the glass in a vehicle (not shown), and on the other hand to mask the electrical connections (busbars, etc.) that provide electrical energy to the dispersed liquid crystal polymer film 12
• the infrared reflecting layer 13 of the silver metal layer type makes it possible to reflect the infrared radiation 104 originating from the PDLC film.
• the means for reflecting the infrared radiation 13 may consist of multiple alternating layers of silver and indium oxide.
• the infrared reflective film 13 may be a non-metallic film, composed of several layers.
• the infrared radiation coming from outside the glazing for example from the lamination process or solar radiation, are absorbed by the outer glass sheet 11.
• the heat is then conducted 106 through the outer glass sheet 12, the first thermoplastic spacer 16, the thermoplastic spacer frame 17 and finally to be captured by the PDLC film, then leading to its deterioration .
• the temperature of the PDLC can then reach a temperature higher than 100 ° C., a high temperature which in the long term damages the PDLC film.
• thermoplastic interleaves can be placed between the PDLC film and the second glass sheet 16 so as to assemble the laminate.
• the glass sheets 11 and 16 as illustrated in FIGS. 1 and 3 are glasses of silico-soda-lime type.
• One or both sheets of glass may be sheets of clear glass of the silico-sodo-calcium type of the following composition (by weight): SiO2 68-75%; A12O3 at 0-5%; Na2O 10 - 18%; K2O at 0 - 5%; MgO 0 - 10%; CaO 5 to 15%; SO3 O - 2%.
• the glass may also contain other additives, such as, for example, ripening aids up to 2%.
• one or both glass sheets 11, 16 may be highly absorbent colored glass sheets, so that the light transmission is limited by the sole effect of these two sheets. for example less than 50%, and in a configuration of this type preferably less than 30%.
• Glasses used for these sheets are, for example, gray glasses as described in patent FR2738238 or in patent EP1680371, or gray glasses with a green shade as described in EP 887320, or in blue shade as in EPI 140718.
• the glass sheets 11 and 16 are, in one example, respectively 1.6 mm and 2.6 mm thick.
• the internal glass sheet of the laminated glazing can be stained glass in the mass, the composition of which may comprise one or more of the following colorants: iron oxide, cobalt oxide, selenium, chromium oxide, titanium oxide, manganese oxide, oxide copper, vanadium oxide, nickel oxide. It is understood that the two sheets of glass can be clear glass.
• One or the glass sheets may be tempered glass.
• the glass sheets can be flat or curved. Each glass sheet may have a thickness between 0.5 and 25 mm thick, preferably between 1 and 5 mm.
• the total thickness of the automotive glazing may therefore be between 1.5 and 100 mm, preferably between 2 and 50 mm, and more preferably between 2.5 and 20 mm.
• the glazing has a transmission of visible light (measured with illuminant CIE A) greater than 70% and even more preferably greater than 75% when the two glass sheets and the thermoplastic interlayer film layers are substantially clear.
• the glazing generally has a tint (because either the inner glass sheet of the glazing is body-tinted or one or more plies of the interlayer material is tinted), it preferably has a visible light transmission (measured by the CIE Illuminant A) less than 40%, more preferably less than 30% and preferably less than 25%, and a transmission total energy (Parry Moon, Air Mass 1.5) of less than 30%, more preferably less than 25% and preferably less than 20%.
• FIG. 2 shows the at least first thermoplastic film according to a particular embodiment of the invention.
• the thermoplastic interlayer 20 comprising an opaque zone 21 is at the periphery of the thermoplastic interlayer 20.
• the interlayer film 20 is of slightly greater dimension than that of the glass sheets 11 and 16 so that it is extends over the entire surface of the glass sheets.
• the opaque zone 21 according to this particular embodiment takes the form of a frame made from a colored thermoplastic interlayer whose light transmission is 0%.
• the frame is made from a black PVB surrounding the non-opaque zone 22 which consists of a transparent UV-screening PVB which allows only a very small proportion of these to pass through.
• PVB films 0.38mm thick more than 95% UV is removed. This proportion may exceed 99%.
• Ethylene vinyl acetate (EVA) -based polymers are also provided which contain components which impart a very low UV transmission. It is understood that any thermoplastic interlayer having these characteristics, namely a transmission less than 5% and preferably equal to 0% can be used to form this opaque zone. The dimensions of the opaque zone are generally equivalent to those usually used for the occultation band. These dimensions will depend in particular on the area to be masked.
• the at least first thermoplastic interlayer as represented by FIG. 2 is formed of a colored-colored PVB frame disposed on the periphery / periphery of a transparent PVB so as to form the thermoplastic interlayer according to the invention .
• this frame may be formed by different strips arranged so as to form said frame, these strips merging during baking so as to form a single piece. However, it can be composed and applied using any other known means.
• the interlayer is then provided on at least the 2-lla-side of the outer glass sheet. It can of course also be provided on the face 4.
• Figure 3 shows a glazing according to the invention in the form of a glass roof for automobile 10, comprising a functional film in the form of a liquid crystal polymer film dispersed 12 mounted within the laminated structure.
• the description of FIG. 1 generally applies to that shown in FIG. 3, except that, in FIG. 3, a thermoplastic interlayer comprising an area that is opaque to visible wavelength radiation is provided on FIG. face 2- 11a- of the glass sheet 11 (that is to say on the inner surface of the outer pane 11) between the means for reflecting the infrared radiation and the PDLC film.
• the dispersed liquid crystal polymer (PDLC) film 12 is shown to be positioned near the edges of the glass sheets 11 and 16 of the glazing 10.
• the PDLC film does not cover the entire glazing so that the edges of the LC film do not enter contact with the outside atmosphere, especially to protect the crystals from moisture.
• the PDLC film 12 is entirely wrapped in the various thermoplastic interleaves.
• the PDLC film is wrapped at its periphery with a PVB film 17 of a thickness close to that of the PDLC film which has a suitable cut in which is housed the PDLC film (corresponding to the second thermoplastic spacer described above) and is laminated between a first thermoplastic interlayer 20 and a third thermoplastic interlayer 18.
• thermoplastic interleaves can be placed between the PDLC film and the second glass sheet 16 so as to ensure the assembly of the laminate.
• the spacers are PVB 0.38 mm thick each.
• the first thermoplastic interlayer 20 is positioned between the means for reflecting the infrared radiation 13, itself deposited on the face 2-1 la of the outer glass sheet 11, and the PDLC film 12.
• the thermoplastic interlayer 20 such as represented by FIG. 2 comprises an opaque zone 21 at the visible wavelength radiation and a non-opaque zone 22.
• the non-opaque zone 22 is formed of a 0.76 mm transparent UV-screening PVB film. .
• the zone opaque to the visible wavelength radiation 21 is itself formed by a "frame" of black corridor PVB film (PVB tinted in the mass) which surrounds the non-opaque zone.
• the thermoplastic interlayer 20 is formed by a black PVB frame surrounding the non-opaque area of conventional transparent PVB, so as to form an integral PVB sheet which extends over the entire surface of the outer glass sheet 11
• the dimensions of the area opaque are generally equivalent to those usually used for the occultation band. These dimensions will depend in particular on the area to be masked.
• the face 2 -11a of the outer glass sheet is devoid of an enamel layer.
• the components of the PDLC films may be susceptible to aging.
• the film is normally protected by an infrared reflective means, especially from solar radiation.
• Such a means is disposed between the glass sheet 11 and the PDLC film 12.
• the infrared radiation reflecting means plays its role well by reflecting outside the infrared (104) glazing thus protecting the PDLC. of internal warming
• the infrared radiation coming from the outside of the glazing are then very little or not absorbed by the opaque zone 21 of the first thermoplastic interlayer 20 thus avoiding that the PDLC film is subjected to high temperatures.
• the heat conducted 106 by the glass sheet then the opaque zone 21 of the thermoplastic interlayer 20 and finally the thermoplastic film 17 to be captured by the PDLC film is greatly reduced compared to the glazing of the prior art as shown in FIG. figure 1.
• an enamel layer may be present on the face 4 of the glazing so as to mask the connectors such as the busbars and the connectors that supply electrical energy to the crystal polymer film. dispersed liquids 11 or the glue for sticking these elements ...
• the means for reflecting infrared radiation 13 is identical to that shown in FIG. 2, namely a metallic silver layer.
• the infrared reflecting film 13 may consist of multiple alternating layers of silver and indium oxide.
• the infrared reflective film 13 may be a non-metallic film, composed of several layers.
• a glazing unit according to the invention has the following structure of the outside inside - clear glass sheet (even extra-clear) 2.1 mm thick a layer of silver as infrared reflective medium
• thermoplastic interleaves including in particular the activation means of the film PDLC
• the PDLC film is supplied with AC current at 50 Hz, and under a potential difference of HOv.
• a laminated glazing unit according to the invention can be mounted in any window of a vehicle. It can be particularly and preferentially used as a glazed car roof.
• a laminated glazing unit according to the invention may be provided with additional functionality, by the inclusion of appropriate elements, such as a hydrophilic or hydrophobic coating on the faces 1 or 4.
• laminated glazing as used as a windshield or rear window of a motor vehicle have many features such as: a layer reflecting the solar radiation, thereby lowering the temperature of the dashboard and the ambient temperature in the passenger compartment, the support of interior rear-view mirror, bus-bars for bringing an electric current, a heating wire network, an upper band filtering solar radiation, with possibly degraded coloration, a rain detector, etc.

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• Chemical & Material Sciences (AREA)
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• Physics & Mathematics (AREA)
• General Physics & Mathematics (AREA)
• Optics & Photonics (AREA)
• Joining Of Glass To Other Materials (AREA)
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• Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)

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• 2014
  • 2014-12-19 EP EP14199140.6A patent/EP3034297A1/de not_active Withdrawn
• 2015
  • 2015-12-16 EP EP15813370.2A patent/EP3233478A1/de active Pending
  • 2015-12-16 JP JP2017532901A patent/JP7226916B2/ja active Active
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  • 2015-12-16 CN CN201580068809.0A patent/CN107107566A/zh active Pending
  • 2015-12-16 US US15/537,242 patent/US10786975B2/en active Active
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