Classifications

• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
  • C07F7/02—Silicon compounds
  • C07F7/08—Compounds having one or more C—Si linkages
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
  • C08L83/04—Polysiloxanes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
  • C08L83/04—Polysiloxanes
  • C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
  • C07F7/02—Silicon compounds
  • C07F7/08—Compounds having one or more C—Si linkages
  • C07F7/0834—Compounds having one or more O-Si linkage
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
  • C07F7/02—Silicon compounds
  • C07F7/08—Compounds having one or more C—Si linkages
  • C07F7/0834—Compounds having one or more O-Si linkage
  • C07F7/0838—Compounds with one or more Si-O-Si sequences
  • C07F7/0872—Preparation and treatment thereof
  • C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
  • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
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  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
  • C09D5/002—Priming paints
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/60—Additives non-macromolecular
  • C09D7/63—Additives non-macromolecular organic
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  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/65—Additives macromolecular
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
  • C09J11/02—Non-macromolecular additives
  • C09J11/06—Non-macromolecular additives organic
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
  • C09J11/08—Macromolecular additives
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K3/00—Materials not provided for elsewhere
  • C09K3/12—Materials for stopping leaks, e.g. in radiators, in tanks
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/045—Polysiloxanes containing less than 25 silicon atoms
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
  • C08G77/04—Polysiloxanes
  • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
  • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups

Definitions

• the present invention relates to a composition containing water and a mixture of [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomers and their ethers, wherein the proportion of epoxy groups bound in Si compounds and are in the composition, ⁇ 5 mol .-%, based on the molar fraction of Si in the composition is. Furthermore, the invention relates to a special process for the preparation of a composition according to the invention and to the use thereof.
• Organofunctional silanes are molecules that are bifunctional.
• the alkoxy groups on the silicon can be split off in the presence of water and catalysts. This results in reactive silanol groups that can undergo chemical bonding to inorganic substrates.
• the organofunctional part of the molecule is linked to the silicon by a C-Si bond and may consist of various organofunctional groups. If the organofunctional group consists only of a methyl or alkyl group, then these groups can not enter into a chemical reaction, but they can lead to a strong hydrophobic effect depending on the chain length. Therefore, alkyltrialkoxysilanes are also used for the hydrophobization of surfaces.
• Organofunctional silanes are available with different organic groups.
• Silanes are used inter alia as adhesion agents. For this function, they can be part of a primer solution or used as an additive in a paint formulation.
• the VOC discussion also does not stop at the silanes, because the hydrolysis of methoxy- or ethoxysilanes produces methanol or ethanol.
• silanes can not be fully used in aqueous paint formulations because they can further hydrolyze and condense after formulation of the paint. This results in paint formulations that have only very short application times.
• aqueous silane systems are finding increasing interest because they contain less or no organic solvents and therefore are more environmentally friendly. In addition, these systems can be used without explosion protection. Stable, aqueous silane systems can not be prepared simply by mixing silanes with water, since many silanes are insoluble in the aqueous phase and hydrolyze and condense on contact with water.
• EP0675128 teaches a process for preparing stable aqueous silane compositions.
• a water-soluble silane and a water-insoluble silane are combined in one hydrolyzed and condensed defined molar ratio.
• the hydrolysis alcohol is removed from the mixture after the reaction.
• the claimed aqueous silane compositions contain amino groups.
• EP0849332 describes a process for producing a coating.
• Example 3 shows a manufacturing scheme for a 3-glycidyloxypropyltrimethoxysilane blending system.
• the mixing system contains, as another silane, a succinic anhydride silane.
• the system is applied to the substrate as a coating and thermally cured.
• Said ligands in this case have at least one ethyl group with a terminal alpha / beta-diol group-containing alkyl groups and are bonded via a lig-Si-O bond to the surface of the solid support material; furthermore, they also have no free silanol groups.
• ligands Lig
• EP1599551 claims a process for coating a metallic surface with an aqueous composition containing at least one hydrolyzable or partially hydrolyzed silane, a metal chelate, an organic film former and a long chain alcohol.
• silane can also be used here 3-glycidylpropyltrimethoxy or ethoxysilane.
• EP1599615 teaches a method of coating a metallic surface with an aqueous composition containing at least one hydrolyzable or / and at least partially hydrolyzed silane and at least one metal chelate.
• EP1599616 a method is disclosed for coating a metallic surface with an aqueous composition, wherein the composition comprises at least one hydrolyzable or / and at least partially hydrolyzed fluorine-free silane and at least one contains hydrolysable or / and at least partially hydrolyzed fluorine-containing silane.
• WO2005 / 090502 describes a binder consisting of an aqueous, film-forming polymeric siloxane.
• the binder may contain alkyl, alkenyl, methacrylic, epoxy, mercaptan or hydroxyalkyl groups.
• the binder is formulated with additives and fillers and used for the corrosion protection of metals.
• WO2006 / 010388 teaches the preparation of a binder from a glycidyloxypropyltrialkoxysilane, a silica sol, a catalyst and a propyl zirconate or butyl titanate or titanium acetylacetonate crosslinker.
• the binder can be used in formulations or for coating a wide variety of substrates.
• WO2005 / 108520 discloses an adhesive / sealant composition consisting of a component A and a component B.
• the component A contains at least one catalyst for the silane crosslinking and low molecular weight organofunctional silanes such as 3-glycidyloxypropyltrimethoxysilane.
• WO2006 / 079516 relates to an aqueous binder composition consisting of an epoxysilane, a formylaminopropyltrialkoxysilane and a tetraalkoxysilane.
• the silanes are acid hydrolysed and formulated with pigments and additives.
• the aqueous coating system is to be used as a shop primer.
• WO2009 / 021776 describes the preparation of an oligomeric epoxysilane and optionally another silane by hydrolysis and condensation in the presence of boric acid.
• EP0675128 teaches the preparation of stable water-based silane systems.
• Example 3 a 3-glycidyloxypropyltrimethoxysilane is reacted with diethylene glycol and butyl titanate. The resulting methanol is removed before the reacted silane is hydrolyzed by addition of water.
• CN103509188 describes the preparation of colored polysiloxane microparticles.
• silanes are hydrolyzed in water or in a water-solvent mixture between 20 and 80 ° C and a pH of 1.0 to 6.5 in the presence of an organic acid. Subsequently, the pH is adjusted to 7.1 to 13.5 with a base. After 0.1 to 24 hours, the microparticles can be separated and dried.
• WO2006 / 044340 teaches the preparation and use of an abrasion resistant coating composition.
• the composition contains at least one epoxy silane.
• JP54063176 claims a primer for transparent plastics consisting of a hydrolyzed epoxysilane and an aminoalkylsilane.
• JP2000239644 describes the composition of a primer which also contains epoxysilanes in addition to an organic solvent and water.
• EP0832911 discloses water-based organopolysiloxane-containing compositions that are substantially free of organic solvents. Investigations on a composition prepared according to Example 1 based on 3-glycidyloxypropyltrimethoxysilane show that the composition also contains opened epoxy groups in addition to a high proportion of intact epoxy groups. The result surprised.
• Aqueous silane systems are becoming increasingly important as they are environmentally friendly and easy to handle. When using these systems, no special safety precautions regarding explosion protection normally have to be observed.
• Such aqueous systems can be used as a reactive binder, co-binder, as a primer and also as a sealant.
• Silanes are very reactive and react in the presence of atmospheric moisture or water. First, hydrolysis takes place. This silanol groups are formed, which can react with inorganic or organic substrates. In addition, the silanols can also react with themselves to form Si-O-Si bonds. Under appropriate conditions, a strong crosslinking in the aqueous solution and thus gelation of the system take place.
• organofunctional silanes are to be used for aqueous silane systems, the stability of the organofunctional group must also be taken into account.
• Example 1 in EP0832911 leads to an aqueous silane system with opened and intact epoxy groups. After synthesis, about 20-30% of the epoxy groups are still intact.
• compositions of the invention are suitably acidic and can thus in addition to water and a mixture of [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomers and their ethers an acid, preferably an organic acid, particularly advantageously formic or Acetic acid as an acid.
• Such aqueous systems according to the invention are distinguished in particular by good solubility of said [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol-oligomer mixtures including their ethers and by their excellent storage stability over systems which have a significantly higher content containing epoxy-functional Si compounds. Moreover, compositions according to the invention are advantageously dilutable with water in virtually any ratio.
• coating formulations of epoxy resins containing a composition of the invention have significantly improved application properties, as systems containing a significantly higher proportion of epoxy-functional Si compounds. Reference is made to the present application studies.
• the composition according to the invention is advantageously obtainable by using 3-glycidyloxypropyltrimethoxysilane or 3-glycidyloxypropyltriethoxysilane or a mixture of 3-glycidyloxypropyltrimethoxysilane and 3-glycidyloxypropyltriethoxysilane in the preparation in step 1 and a defined amount in the presence of an acid Water that is distilled, desalted or deionized, for example, so-called “deionized water” or so-called “distilled water”, brings together and mix within 10 to 30 minutes, the pH in the reaction mixture preferably in Range of 2 to 4, in step 2, the reaction mixture is heated and stirred at 55 to 70 ° C for 1.5 to 5 hours, then in step 3 for at least 10 hours, preferably within 10 to 16 hours, including the
• An aqueous composition thus prepared advantageously contains substantially as active ingredient said [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomer mixtures, i. Hydroxy, ether and silanol groups, however, virtually no epoxy groups, and can be used as a coupling reagent in primer solutions, as sealants on inorganic substrates, as a reactive binder, as a co-binder for aqueous formulations in a variety of areas, but in particular for the formulation more stable , application-friendly 2-component epoxy resin coatings are used with great success.
• said [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomer mixtures i. Hydroxy, ether and silanol groups, however, virtually no epoxy groups, and can be used as a coupling reagent in primer solutions, as sealants on inorganic substrates, as a reactive binder, as a co-binder for aqueous formulations in a variety of
• compositions of the invention are pourable liquids, excellent shelf life, miscible with water in virtually any ratio, and substantially free of sodium or potassium ions, i. apart from traces of how ubiquitous they are.
• the present invention thus relates to a composition
• a composition comprising water and a mixture of [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomers and their ethers, wherein the proportion of epoxy groups which are bonded in Si compounds and may be less than or equal to 0.05 mole of epoxy groups per mole of Si in the composition.
• aqueous compositions according to the invention wherein the proportion of epoxy groups which can be bound in Si compounds and be present in the composition is 0 to less than 0.04 mol of epoxy groups per mol of Si in the composition, in particular 0.001 to 0.03 mole of epoxy functionality per mole of Si in the composition.
• a composition of the invention advantageously contains a content of formic acid or acetic acid.
• aqueous compositions according to the invention have a pH of from 2 to 4.
• the pH in a composition according to the invention can be determined, for example, by means of a glass electrode or by means of pH paper or pH measuring sticks from Merck in a manner known to the person skilled in the art.
• a composition of the invention comprises [3- (2,3-dihydroxyprop-1-oxy) propyl] silanol oligomers or their ethers according to the general formula Y-Si (OH) 2 O 1/2 [Y-Si (OH) O 2/2 ] n [Y-SiO 3/2 ] m (Y-) Si (OH) 2 O 1/2 (I), where n ⁇ 0 and m ⁇ 0, groups Y stand for R "O-CH 2 -CH (OR ') - CH-OC 3 H 6 - and the groups R' and R "are the same or different and may stand for H, methyl and ethyl.
• composition according to the invention may suitably also contain silanols of the general formula II Y-Si (OH) (OR) 2 (II), where group Y is R "O-CH 2 -CH (OR ') - CH-OC 3 H 6 - and the groups R, R' and R" are identical or different and represent H, methyl (Me) and ethyl ( Et) can stand.
• compositions according to the invention are characterized as VOC-free, VOC-free in the present application is understood to mean that a composition according to the invention contains, in particular, less than or equal to 1% by weight of free alcohol, the percentage by weight referring to the composition and the alcohol is selected from the series methanol and ethanol.
• compositions according to the invention may also contain organofunctional silanols, as can be seen from the above-mentioned formula II, in a comparatively small proportion These Si compounds are seen in total as the active ingredient in a composition according to the invention.
• aqueous compositions according to the invention suitably have an active ingredient content of up to 80% by weight, based on the total composition, of preferably 5 to 80% by weight, particularly preferably 10 to 70% by weight, very particularly preferably 20 to 60 Wt .-%, in particular 30 to 50 and 40 to 50 wt .-%.
• a composition according to the invention thus advantageously has an active substance content of compounds of the formula I including compounds of the formula II to 80% by weight, ie in total and based on the total composition, ie compounds of the formula II can, in addition to those of the formula I, optionally as the active ingredient in a composition according to the invention.
• subject of the present invention is a process for the preparation of a composition according to the invention by in step 1 as 3-glycidyloxypropyltrialkoxysilane 3-glycidyloxypropyltrimethoxysilane or 3-glycidyloxypropyltriethoxysilane or a mixture of 3-glycidyloxypropyltrimethoxysilane and 3-glycidyloxypropyltriethoxysilane and in the presence of an acid with a defined amount of water which is distilled, desalted or deionized within 10 to Brings together and mixes 30 minutes, in step 2, the reaction mixture is heated and stirred at 55 to 70 ° C for 1.5 to 5 hours, then distilled in step 3 for at least 10 hours under reduced pressure at a temperature in the range of 40 to 55 ° C, an alcohol / water mixture and at the same time weight-based by water, which is distilled, desalted or deionized, replaced and the distillation operates at least 10 hours and until the top
• step 1 the 3-glycidyloxypropyltrialkoxysilane and water are used in a molar ratio of 1 to 3 to 60, all of the molar feed ratios derivable therefrom for the person skilled in the art are included.
• the acid used is preferably formic acid or acetic acid, preferably in a molar ratio of acid to 3-glycidyloxypropyltrialkoxysilane of from 0.03 to 0.06 to 1, all of which are deducible from those skilled in the art including molar feed ratios.
• compositions prepared according to the invention clearly differ from compositions known from the prior art; compositions according to the invention and those produced by the process according to the invention are essentially free of epoxy-functional silicon compounds, they are stable on storage and in particular also have very good properties ie once again improved performance properties in epoxy resin formulations.
• the subject matter of the present invention is also an aqueous composition obtainable by the process according to the invention.
• the present invention further provides the use of a composition according to the invention or a composition prepared or obtainable by the process according to the invention as a component in epoxy resin formulations, as a coupling reagent in primer solutions, as a sealant on inorganic substrates, as a reactive binder and as a co-binder.
• Dynasylan® GLYMO (3-glycidyloxypropyltrimethoxysilane), Evonik Industries Formic acid 85%, BCD chemistry Araldur 3986, BBC00235V1 Huntsman Araldite PZ 3961-1, AAC0250900 Huntsman
• the viscosity was determined at 25 ° C according to DIN 53019.
• the layer thickness of the cured coatings was measured with a Dualscope MP4C Coating Thickness Gauge from Fischer with the measuring probe EGAB 1.3.
• the signal at 0.49 (see Figure 1 positions 2 a and 2 b) is used as a reference for the sum of all epoxysilanes used (correction by a factor of 0.5, since there are 2 protons on the carbon atom).
• the signal at 2.73 shift (see Figure 1, position 7b) corresponded to one of the two protons on the epoxy group.
• the integral of this shift must be divided by the corrected integral at 0.49 (see Figure 1, position 2 a) and multiplied by 100.
• the value obtained corresponded to the number of intact epoxy groups in mol% in the silane or the hydrolysis product.
• Example 3 (Comparative Example from WO91 / 19656):
• the respective aqueous epoxy resin formulation (see Table 1) was applied to the cleaned steel sheets (substrate) using a 40 ⁇ m spiral doctor blade and cured at 80 ° C. for 20 minutes.
• the dry film thicknesses of the coatings were 14-18 ⁇ m.
• the coated steel sheets were tested in the neutral salt spray test according to DIN EN ISO 9227.
• Formulation 2 with the aqueous composition of Example 4 according to the invention shows a detachment of 5 mm from the scratch.
• the formulation 3 with the aqueous composition of Comparative Example 1 shows a detachment of 10 mm and the formulation 1 without the addition of a silane system a detachment of 15 mm.
• the tested formulations could consist of 3 components: the epoxy resin (Araldite PZ 3961-1), the amine hardener (Aradur 3986) and the aqueous silane system. However, a simpler system of 2 components would be much easier for the end user to handle.
• the durabilities of Formulations 1 to 3 were examined.
• the amine hardener (Aradur 3986) was mixed in each case with the aqueous silane system from (Comparative) Example 1 and from Inventive Example 4 in the amounts shown in Table 1 and the viscosity of the formulations was measured at intervals. The results are summarized in Table 3.
• Table 3 Viscosity Measurement after Viscosity of a formulation of 38.4 g of Aradur 3986 + 1.44 g composition of (Comparative) Example 1 Viscosity of a formulation of 38.4 g of Aradur 3986 + 1.44 g of the composition of Example 4 Viscosity of Aradur 3986 [Minutes] [mPa s] [mPa s] [mPa s] 0 4.96 4.96 17.70 51 5.38 4.96 17.70 81 13.77 4.96 17.70 119 31.92 4.91 17.70 158 93.82 4.89 17.70 192 266.33 4.88 17.70 226 775.33 4.88 17.70

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• Compositions Of Macromolecular Compounds (AREA)
• Sealing Material Composition (AREA)
• Epoxy Resins (AREA)

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• 2015
  • 2015-12-08 EP EP15198353.3A patent/EP3178884B1/de active Active
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  • 2016-12-07 CN CN201611114869.4A patent/CN107011763B/zh active Active
  • 2016-12-07 DE DE102016224343.8A patent/DE102016224343A1/de not_active Withdrawn
  • 2016-12-07 KR KR1020160165533A patent/KR102539519B1/ko active Active
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