EP3164375B1 - Pyrotechnisches anzündmittel - Google Patents
Pyrotechnisches anzündmittel Download PDFInfo
- Publication number
- EP3164375B1 EP3164375B1 EP15734332.8A EP15734332A EP3164375B1 EP 3164375 B1 EP3164375 B1 EP 3164375B1 EP 15734332 A EP15734332 A EP 15734332A EP 3164375 B1 EP3164375 B1 EP 3164375B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- additive
- pyrotechnic
- igniting agent
- alkali
- agent according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 30
- 239000011701 zinc Substances 0.000 claims description 20
- 239000000654 additive Substances 0.000 claims description 19
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 239000003513 alkali Substances 0.000 claims description 12
- -1 titanium hydride Chemical compound 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 6
- 150000002978 peroxides Chemical class 0.000 claims description 6
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 6
- QSGNKXDSTRDWKA-UHFFFAOYSA-N zirconium dihydride Chemical compound [ZrH2] QSGNKXDSTRDWKA-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 150000002823 nitrates Chemical class 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 4
- 239000011118 polyvinyl acetate Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 229910000048 titanium hydride Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910000568 zirconium hydride Inorganic materials 0.000 claims description 4
- 229910021346 calcium silicide Inorganic materials 0.000 claims description 3
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 claims description 3
- 150000004655 tetrazenes Chemical class 0.000 claims description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 1
- 229910010277 boron hydride Inorganic materials 0.000 claims 1
- 239000006063 cullet Substances 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XBDYBAVJXHJMNQ-UHFFFAOYSA-N Tetrahydroanthracene Natural products C1=CC=C2C=C(CCCC3)C3=CC2=C1 XBDYBAVJXHJMNQ-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 description 3
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- SQSPRWMERUQXNE-UHFFFAOYSA-N Guanylurea Chemical class NC(=N)NC(N)=O SQSPRWMERUQXNE-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 238000004200 deflagration Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HZLARDBKBZHHGU-UHFFFAOYSA-N 1-(tetrazol-1-yl)tetrazole Chemical group C1=NN=NN1N1N=NN=C1 HZLARDBKBZHHGU-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000028 HMX Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C7/00—Non-electric detonators; Blasting caps; Primers
Definitions
- the present invention is a pyrotechnic igniter.
- Pyrotechnic igniters in the context of the invention are substances or mixtures which can develop a pyrotechnic effect.
- the subject of the present invention is a pyrotechnic igniting agent which can be used in mechanical, electrical or opto-electric ignition systems.
- a 5,5'-azotetrazolate explosive which comprises an iron, cobalt, nickel, copper, cadmium or guanyl urea salt of a 5,5'-azotetrazole or a mixture of at least one 5,5'-azotetrazolate and at least one bistetrazolyl triazenate or at least one further metal salt or guanyl urea salt of a 5,5'-azotetrazole.
- the salts described therein are neutral, ie neither acidic nor basic.
- Zinc and chromium salts of 5,5'-azotetrazole are according to the document DE 102010025104 A1 not storable.
- tetracene-containing pyrotechnic mixtures are thermally not sufficiently stable, since tetrazene decomposes already at 120 ° C.
- DE 10 2010 036 950 A1 discloses the use of basic 5,5'-azotetrazolate salts of general formula ([ML m X n ] p + ) q (C 1 N 4 R 1 - ) r , where M is an element of the third-twelfth group of the periodic table in the range of 21-80, as initial explosive.
- the object of the present invention was to provide a further pyrotechnic igniter.
- Another object of the present invention was to provide a pyrotechnic igniter which can be used in mechanical, electrical or opto-electric ignition systems.
- this object is surprisingly achieved by the features of the main claim.
- novel basic azotetrazolate compounds according to the invention have defoaming temperatures in the range from 180 ° C to 240 ° C, friction sensitivities of 0.1 N to 1.0 N and impact sensitivity of 0.1 J to 0.5 J.
- the pyrotechnic igniter is one which contains as an additive 10 to 60 wt .-% of an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc.
- an oxidizing agent selected from one or more of the nitrates of the alkali and / or alkaline earth metals and / or ammonium, the perchlorates of the alkali and / or alkaline earth metals and / or the ammonium, the peroxides of the alkali and / or alkaline earth metals and / or zinc.
- the pyrotechnic igniting agent contains as additive 0 to 10 wt .-% of a sensitizer, preferably tetracene.
- the pyrotechnic igniting agent according to the invention preferably contains as an additive 0 to 20 wt .-% of a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage.
- a reducing agent selected from one or more of aluminum, antimony sulfide, calcium silicide, titanium, titanium hydride, boron, borohydride, zirconium, zirconium hydride, silicon, graphite, activated carbon, carbon black or Friction agent preferably glass breakage.
- the pyrotechnic igniting agent contains as additive 0.1 to 5 wt .-% of a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.
- a binder selected from one or more of cellulose and derivatives thereof, polyvinyl butyrals, Polynitropolyphenylen, Polynitrophenylether, Plexigum, polyvinyl acetate and copolymers.
- the pyrotechnic igniting agents according to the invention are used in mechanical, electrical or opto-electric ignition systems.
- the substances are characterized by lead and barium freedom, a high ignition power, short reaction times and corresponding sensitivities. These features enable a reduction in the mass of explosives needed for safe ignition.
- Table 1 shows decomposition temperatures, friction and impact sensitivities of selected examples.
- the measurement of the friction and impact sensitivities was carried out according to methods of the Federal Institute for Materials Research (BAM) in the BAM Report 142 (1987), while the measurement of the decomposition temperatures by differential scanning calorimetry (DSC) (Mettler) at a heating rate of 10 K. per minute took place.
- BAM Federal Institute for Materials Research
- DSC differential scanning calorimetry
- Table 1 lists the compositions of 5 different basic salts of 5,5'-azotetrazole. ⁇ b> Table 1 ⁇ / b> Compositions, deflagration temperatures and friction and impact sensitivities of selected basic salts of 5,5'-azotetrazole. No. Molecular formula T Verp .
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
- Glass Compositions (AREA)
- Adhesives Or Adhesive Processes (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RS20191481A RS60020B1 (sr) | 2014-07-03 | 2015-06-29 | Pirotehničko sredstvo za paljenje |
| PL15734332T PL3164375T3 (pl) | 2014-07-03 | 2015-06-29 | Pirotechniczny środek zapłonowy |
| SI201531000T SI3164375T1 (sl) | 2014-07-03 | 2015-06-29 | Pirotehnično vžigalno sredstvo |
| HRP20192094TT HRP20192094T1 (hr) | 2014-07-03 | 2019-11-20 | Pirotehničko sredstvo za paljenje |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014009807 | 2014-07-03 | ||
| PCT/EP2015/064729 WO2016001161A1 (de) | 2014-07-03 | 2015-06-29 | Pyrotechnisches anzündmittel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP3164375A1 EP3164375A1 (de) | 2017-05-10 |
| EP3164375B1 true EP3164375B1 (de) | 2019-08-21 |
Family
ID=53514168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP15734332.8A Active EP3164375B1 (de) | 2014-07-03 | 2015-06-29 | Pyrotechnisches anzündmittel |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US20170137339A1 (lt) |
| EP (1) | EP3164375B1 (lt) |
| JP (1) | JP6559164B2 (lt) |
| CN (1) | CN107074674B (lt) |
| AU (1) | AU2015282658B2 (lt) |
| BR (1) | BR112016030839B1 (lt) |
| DK (1) | DK3164375T3 (lt) |
| ES (1) | ES2757934T3 (lt) |
| HR (1) | HRP20192094T1 (lt) |
| HU (1) | HUE046300T2 (lt) |
| LT (1) | LT3164375T (lt) |
| PL (1) | PL3164375T3 (lt) |
| PT (1) | PT3164375T (lt) |
| RS (1) | RS60020B1 (lt) |
| RU (1) | RU2695200C2 (lt) |
| SI (1) | SI3164375T1 (lt) |
| WO (1) | WO2016001161A1 (lt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108456126B (zh) * | 2017-02-20 | 2020-02-21 | 比亚迪股份有限公司 | 一种气体发生器的传火药及其制备方法和一种汽车安全气囊用气体发生器 |
| CN110937962A (zh) * | 2019-12-03 | 2020-03-31 | 北京理工大学 | 一种合金型洋红色冷烟花药剂及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH103654A (de) * | 1922-03-27 | 1924-03-01 | Hans Dr Rathsburg | Verfahren zur Herstellung von Zündsätzen. |
| FR2228043B1 (lt) * | 1972-10-17 | 1977-03-04 | Poudres & Explosifs Ste Nale | |
| US4566921A (en) * | 1985-02-08 | 1986-01-28 | L'etat Francais Represente Par Le Delegue Ministeriel Pour L'armement | Priming composition which is sensitive to percussion and a method for preparing it |
| DE19505568A1 (de) * | 1995-02-18 | 1996-08-22 | Dynamit Nobel Ag | Gaserzeugende Mischungen |
| JP5388573B2 (ja) * | 2005-06-02 | 2014-01-15 | ルアグ アモテック ゲゼルシャフト ミット ベシュレンクテル ハフツング | パイロ技術的な作用物質 |
| CN101434617A (zh) * | 2008-08-20 | 2009-05-20 | 西北大学 | 基于偶氮四唑的含能配合物及其应用 |
| DE102010025104B4 (de) | 2010-04-14 | 2015-06-11 | Diehl Bgt Defence Gmbh & Co. Kg | Initialsprengstoff |
| DE102010036950B4 (de) * | 2010-08-11 | 2014-04-03 | Nammo Germany Gmbh | Explosive Metallkomplexe, deren Herstellung und Verwendung, sowie Zündmittel |
| CN102731425A (zh) * | 2011-04-12 | 2012-10-17 | 南京理工大学 | 5,5’-偶氮四唑锌的制备方法 |
| CZ2013858A3 (cs) * | 2013-11-07 | 2015-09-02 | Sellier & Bellot | Energetické materiály na bázi bismutu |
-
2015
- 2015-06-29 ES ES15734332T patent/ES2757934T3/es active Active
- 2015-06-29 DK DK15734332T patent/DK3164375T3/da active
- 2015-06-29 LT LT15734332T patent/LT3164375T/lt unknown
- 2015-06-29 WO PCT/EP2015/064729 patent/WO2016001161A1/de active Application Filing
- 2015-06-29 PL PL15734332T patent/PL3164375T3/pl unknown
- 2015-06-29 RU RU2017103493A patent/RU2695200C2/ru active
- 2015-06-29 CN CN201580034915.7A patent/CN107074674B/zh active Active
- 2015-06-29 US US15/323,359 patent/US20170137339A1/en not_active Abandoned
- 2015-06-29 RS RS20191481A patent/RS60020B1/sr unknown
- 2015-06-29 SI SI201531000T patent/SI3164375T1/sl unknown
- 2015-06-29 HU HUE15734332A patent/HUE046300T2/hu unknown
- 2015-06-29 EP EP15734332.8A patent/EP3164375B1/de active Active
- 2015-06-29 JP JP2016575851A patent/JP6559164B2/ja active Active
- 2015-06-29 PT PT157343328T patent/PT3164375T/pt unknown
- 2015-06-29 AU AU2015282658A patent/AU2015282658B2/en active Active
- 2015-06-29 BR BR112016030839-5A patent/BR112016030839B1/pt active IP Right Grant
-
2019
- 2019-11-20 HR HRP20192094TT patent/HRP20192094T1/hr unknown
Non-Patent Citations (1)
| Title |
|---|
| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3164375A1 (de) | 2017-05-10 |
| DK3164375T3 (da) | 2019-11-25 |
| HRP20192094T1 (hr) | 2020-02-21 |
| WO2016001161A1 (de) | 2016-01-07 |
| RU2017103493A3 (lt) | 2019-02-08 |
| JP6559164B2 (ja) | 2019-08-14 |
| RU2695200C2 (ru) | 2019-07-22 |
| RU2017103493A (ru) | 2018-08-03 |
| AU2015282658B2 (en) | 2019-10-10 |
| SI3164375T1 (sl) | 2020-07-31 |
| PL3164375T3 (pl) | 2020-06-01 |
| PT3164375T (pt) | 2019-12-02 |
| CN107074674B (zh) | 2020-12-08 |
| BR112016030839A2 (lt) | 2017-08-22 |
| ES2757934T3 (es) | 2020-04-30 |
| BR112016030839B1 (pt) | 2022-04-19 |
| LT3164375T (lt) | 2019-12-10 |
| US20170137339A1 (en) | 2017-05-18 |
| RS60020B1 (sr) | 2020-04-30 |
| AU2015282658A1 (en) | 2017-02-02 |
| JP2017524638A (ja) | 2017-08-31 |
| HUE046300T2 (hu) | 2020-02-28 |
| CN107074674A (zh) | 2017-08-18 |
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