EP3024917B1 - Détergent contenant de l'oxyde d'amine - Google Patents

Détergent contenant de l'oxyde d'amine Download PDF

Info

Publication number
EP3024917B1
EP3024917B1 EP14742492.3A EP14742492A EP3024917B1 EP 3024917 B1 EP3024917 B1 EP 3024917B1 EP 14742492 A EP14742492 A EP 14742492A EP 3024917 B1 EP3024917 B1 EP 3024917B1
Authority
EP
European Patent Office
Prior art keywords
washing agent
amine oxide
fatty alcohol
detergent
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP14742492.3A
Other languages
German (de)
English (en)
Other versions
EP3024917A1 (fr
Inventor
Inga Kerstin Vockenroth
Eva-Maria Wikker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL14742492T priority Critical patent/PL3024917T3/pl
Publication of EP3024917A1 publication Critical patent/EP3024917A1/fr
Application granted granted Critical
Publication of EP3024917B1 publication Critical patent/EP3024917B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Definitions

  • the use of at least one amine oxide to improve the cleaning performance, in particular the cleaning performance of greasy soils, a detergent, in particular a liquid detergent comprising at least one alkylbenzenesulfonate, at least one alkyl ether sulfate and at least one fatty alcohol alkoxylate, subject of the present invention may contain the individual surfactant ingredients in the amounts and ratios disclosed above in connection with the detergent.
  • the total amount of nonionic surfactants based on the weight of the detergent is 1 to 20 wt%, preferably 2 to 15 wt%, more preferably 2.5 to 12.5 wt%, still more preferably 3 to 11 wt .-% and in particular 4 to 10 wt .-%.
  • Nonionic surfactants within the meaning of the present invention include, but are not limited to, alkyl glycosides, alkoxylated fatty acid alkyl esters, amine oxides, fatty acid alkanolamides, hydroxy mixed ethers, sorbitan fatty acid esters, polyhydroxy fatty acid amides, and alkoxylated alcohols.
  • Suitable water-soluble films for producing the water-soluble coating are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 gmol -1 , preferably 20,000 to 500,000 gmol -1 , more preferably 30,000 to 100,000 gmol -1 and especially from 40,000 to 80,000 gmol -1 .
  • polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
  • Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Produit de lavage, de préférence liquide, contenant un mélange de tensioactifs en une quantité allant de 2 à 30 % en poids, rapportée à la quantité totale de produit de lavage, dans lequel le mélange de tensioactifs comprend :
    a) de 5 % en poids à 20 % en poids d'oxyde d'amine,
    b) de 10 % en poids à 60 % en poids d'alkylbenzènesulfonate,
    c) de 12,5 % en poids à 70 % en poids d'alkyléthersulfate, et
    d) de 10 % en poids à 60 % en poids d'alcoxylate d'alcool gras,
    dans chaque cas, rapporté au mélange de tensioactifs,
    dans lequel
    i) le rapport en masse de l'oxyde d'amine à l'alkylbenzènesulfonate se situe dans la plage allant de 1:2 à 1:3, de préférence de 1:2,1 à 1:2,5,
    ii) le rapport en masse de l'oxyde d'amine à l'alkyléthersulfate se situe dans la plage allant de 1:2,5 à 1:3,5, de préférence de 1:2,8 à 1:3,2, et
    iii) le rapport en masse de l'oxyde d'amine à l'alcoxylate d'alcool gras se situe dans la plage allant de 1:2 à 1:3, de préférence de 1:2,1 à 1:2,5.
  2. Produit de lavage selon la revendication 1, caractérisé en ce que le mélange de tensioactifs comprend :
    a) de 7,5 % en poids à 17 % en poids, de préférence de 10 % en poids à 15 % en poids, et de façon plus préférée de 11 % en poids à 12 % en poids d'oxyde d'amine ;
    b) de 15 % en poids à 50 % en poids, de préférence de 19 % en poids à 35 % en poids, de façon plus préférée de 20 % en poids à 30 % en poids, et de façon tout à fait préférée de 26 % en poids à 27 % en poids d'alkylbenzènesulfonate ;
    c) de 20 % en poids à 50 % en poids, de préférence de 26 % en poids à 42 % en poids, de façon plus préférée de 30 % en poids à 40 % en poids, et de façon tout à fait préférée de 34 % en poids à 35 % en poids d'alkyléthersulfate ; et
    d) de 15 % en poids à 50 % en poids, de préférence de 19 % en poids à 35 % en poids, de façon plus préférée de 20 % en poids à 30 % en poids, et de façon tout à fait préférée de 26 % en poids à 27 % en poids d'alcoxylate d'alcool gras.
  3. Produit de lavage selon la revendication 1 ou 2, caractérisé en ce que
    (1) l'oxyde d'amine est un oxyde d'alkyle en C12-C18-di(alkyl en C1-C4)amine, de préférence un oxyde d'alkyldiméthylamine en C12-18 ; et/ou
    (2) l'alkylbenzènesulfonate est un alkylbenzènesulfonate en C9-19 linéaire ou ramifié, de préférence un alkylsulfonate en C9-13 linéaire ; et/ou
    (3) l'alkyléthersulfate est un éthersulfate d'alcool gras en C12-20 ayant de 2 à 8 OE, de préférence un éthersulfate d'alcool gras en C12-14 ayant 2 OE ; et/ou
    (4) l'alcoxylate d'alcool gras est un éther d'alcool gras en C12-C20 ayant de 2 à 8 OE, de préférence un éther d'alcool gras en C12-18 ayant 7 OE.
  4. Produit de lavage selon l'une quelconque des revendications 1 à 3, caractérisé en ce que le produit de lavage contient, rapporté à la quantité totale de produit de lavage, le mélange de tensioactifs en une quantité allant de 5 à 25 % en poids, de façon plus préférée de 10 à 20 % en poids, et de façon tout à fait préférée de 14 à 18 % en poids.
  5. Produit de lavage selon l'une quelconque des revendications 1 à 4, caractérisé en ce que le produit de lavage contient en outre des savons, de préférence des savons d'acides gras en C12-18.
  6. Produit de lavage selon la revendication 5, caractérisé en ce que le produit de lavage contient de 0,25 à 15 % en poids, de préférence de 0,5 à 12,5 % en poids, de façon plus préférée de 1 à 10 % en poids, de façon encore plus préféree de 1,5 à 7,5 % en poids et en particulier de 2 à 6 % en poids de savon(s).
  7. Produit de lavage selon l'une quelconque des revendications 1 à 6, caractérisé en ce que le produit de lavage se présente sous forme liquide dans une enveloppe hydrosoluble, en particulier une enveloppe hydrosoluble constituée d'un film hydrosoluble, dans lequel le film hydrosoluble contient de préférence de l'alcool polyvinylique ou un copolymère d'alcool polyvinylique.
  8. Utilisation d'un produit de lavage selon l'une quelconque des revendications 1 à 7 en tant que produit de lavage pour textile.
  9. Procédé de lavage comprenant les étapes de procédé consistant à :
    i) fournir une solution de lavage comprenant un produit de lavage selon l'une quelconque des revendications 1 à 7.
    ii) mettre en contact un textile avec la solution de lavage selon le point (i).
  10. Utilisation d'oxyde d'amine pour améliorer les performances de nettoyage, en particulier sur les taches grasses, d'un produit de lavage, en particulier d'un produit de lavage liquide, dans laquelle le produit de lavage contient de 2 à 30 % en poids d'un mélange de tensioactifs qui comprend :
    a) de 5 % en poids à 20 % en poids d'oxyde d'amine,
    b) de 10 % en poids à 60 % en poids d'alkylbenzènesulfonate,
    c) de 12,5 % à 70 % en poids d'alkyléthersulfate, et
    d) de 10 % à 60 % en poids d'alcoxylate d'alcool gras,
    dans chaque cas, rapporté au mélange de tensioactifs,
    dans lequel
    i) le rapport en masse de l'oxyde d'amine à l'alkylbenzènesulfonate se situe dans la plage allant de 1:2 à 1:3, de préférence de 1:2,1 à 1:2,5.
    ii) le rapport en masse de l'oxyde d'amine à l'alkyléthersulfate se situe dans la plage allant de 1:2,5 à 1:3,5, de préférence de 1:2,8 à 1:3,2, et
    iii) le rapport en masse de l'oxyde d'amine à l'alcoxylate d'alcool gras se situe dans la plage allant de 1:2 à 1:3, de préférence de 1:2,1 à 1:2,5.
EP14742492.3A 2013-07-24 2014-07-18 Détergent contenant de l'oxyde d'amine Not-in-force EP3024917B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL14742492T PL3024917T3 (pl) 2013-07-24 2014-07-18 Środek piorący zawierający tlenek aminy

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013214472.5A DE102013214472A1 (de) 2013-07-24 2013-07-24 Waschmittel enthaltend Aminoxid
PCT/EP2014/065553 WO2015011062A1 (fr) 2013-07-24 2014-07-18 Détergent contenant de l'oxyde d'amine

Publications (2)

Publication Number Publication Date
EP3024917A1 EP3024917A1 (fr) 2016-06-01
EP3024917B1 true EP3024917B1 (fr) 2018-09-05

Family

ID=51224924

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14742492.3A Not-in-force EP3024917B1 (fr) 2013-07-24 2014-07-18 Détergent contenant de l'oxyde d'amine

Country Status (6)

Country Link
US (1) US10323213B2 (fr)
EP (1) EP3024917B1 (fr)
KR (1) KR102294794B1 (fr)
DE (1) DE102013214472A1 (fr)
PL (1) PL3024917T3 (fr)
WO (1) WO2015011062A1 (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015214056A1 (de) * 2015-07-24 2017-01-26 Henkel Ag & Co. Kgaa Waschkraftverstärkende Hydroxyaminoxide
EP3184621B1 (fr) 2015-12-22 2023-09-06 The Procter & Gamble Company Nettoyants de surfaces dures antimicrobiens épaissis
EP3184618B1 (fr) * 2015-12-22 2020-04-29 The Procter & Gamble Company Compositions de nettoyage de surface dure antimicrobienne assurant une meilleure élimination de graisse
US9796948B2 (en) 2016-01-13 2017-10-24 The Procter & Gamble Company Laundry detergent compositions comprising renewable components
DE102016204062A1 (de) * 2016-03-11 2017-09-14 Henkel Ag & Co. Kgaa Aminoxid-haltige Reinigungsmittel
EP3279303B2 (fr) 2016-08-04 2022-03-23 The Procter & Gamble Company Article de dose unitaire soluble dans l'eau comprenant un tensioactif amphotère
US10385291B2 (en) * 2016-12-22 2019-08-20 Henkel Ag & Co. Kgaa Liquid surfactant compositions and associated methods
US10047321B2 (en) * 2016-12-22 2018-08-14 Henkel Ag & Co. Kgaa Liquid surfactant compositions having a modified oxo-alcohol derivative
US20190233785A1 (en) 2018-01-26 2019-08-01 The Procter & Gamble Company Water-soluble unit dose articles comprising perfume
CA3086689C (fr) 2018-01-26 2023-05-09 The Procter & Gamble Company Procede de fabrication d'articles hydrosolubles en coupant une toile fibreuse en motif carrele
WO2019147532A1 (fr) 2018-01-26 2019-08-01 The Procter & Gamble Company Articles en dose unitaire soluble dans l'eau comprenant un parfum
CA3087284C (fr) 2018-01-26 2023-05-02 The Procter & Gamble Company Articles en dose unitaire soluble dans l'eau comprenant une enzyme
WO2019168829A1 (fr) 2018-02-27 2019-09-06 The Procter & Gamble Company Produit de consommation comprenant un conditionnement plat contenant des articles de dose unitaire
US10982176B2 (en) 2018-07-27 2021-04-20 The Procter & Gamble Company Process of laundering fabrics using a water-soluble unit dose article
WO2018224699A1 (fr) * 2018-09-18 2018-12-13 Henkel Ag & Co. Kgaa Composition détergente liquide comprenant un mélange tensioactif et au moins deux enzymes
WO2020097297A1 (fr) * 2018-11-07 2020-05-14 The Procter & Gamble Company Composition détergente à faible ph
WO2020159860A1 (fr) 2019-01-28 2020-08-06 The Procter & Gamble Company Emballage recyclable, renouvelable ou biodégradable
EP3712237A1 (fr) 2019-03-19 2020-09-23 The Procter & Gamble Company Articles fibreux de dose unitaire soluble dans l'eau comprenant des structures fibreuses solubles dans l'eau
EP3942008A1 (fr) 2019-03-19 2022-01-26 The Procter & Gamble Company Procédé de réduction des mauvaises odeurs sur des tissus
US11667871B2 (en) * 2020-09-18 2023-06-06 Henkel Ag & Co. Kgaa Use of alkyl dialkylamine oxide and surfactant blend to increase mildness of unit dose or liquid laundry detergent
CN112206716A (zh) * 2020-10-26 2021-01-12 蒲城驭腾新材料科技有限公司 一种低表面张力的碳氢类表面活性剂及其制备方法
EP4001391A1 (fr) * 2020-11-20 2022-05-25 The Procter & Gamble Company Article de dose unitaire soluble dans l'eau comprenant un agent tensioactif non ionique à base d'alcoxylate d'ester d'alkyle gras et un agent tensioactif non ionique alcoolique alcoxylé

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2241884A1 (fr) * 1996-01-05 1997-07-17 Kirsten Louise Mckillop Compositions detergentes liquides ou en gel pour la vaisselle et a usage domestique qui possedent des qualites de revitalisation de la peau, de sensation agreable au toucher, et de rincage
EP1326787B2 (fr) * 2000-10-18 2008-10-22 Reckitt Benckiser N.V. Compositions de nettoyage conditionnees dans des matieres a base d'alcool polyvinylique ethoxyle
US20050020467A1 (en) * 2003-07-22 2005-01-27 Colgate-Palmolive Company Gelled light duty liquid cleaning composition
DE102006034902A1 (de) * 2006-07-25 2008-01-31 Henkel Kgaa Wasch- oder Reinigungsmittel mit verbessertem Dispergievermögen
CA2769440C (fr) * 2009-09-14 2014-05-13 The Procter & Gamble Company Composition detergente pour le linge, fluide et compacte

Also Published As

Publication number Publication date
PL3024917T3 (pl) 2019-01-31
US20160186095A1 (en) 2016-06-30
KR20160034969A (ko) 2016-03-30
WO2015011062A1 (fr) 2015-01-29
KR102294794B1 (ko) 2021-08-26
DE102013214472A1 (de) 2015-01-29
US10323213B2 (en) 2019-06-18
EP3024917A1 (fr) 2016-06-01

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