EP2987883B1 - Hochfestes heissgewalztes stahlblech und verfahren zur herstellung davon - Google Patents

Hochfestes heissgewalztes stahlblech und verfahren zur herstellung davon Download PDF

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Publication number
EP2987883B1
EP2987883B1 EP14784648.9A EP14784648A EP2987883B1 EP 2987883 B1 EP2987883 B1 EP 2987883B1 EP 14784648 A EP14784648 A EP 14784648A EP 2987883 B1 EP2987883 B1 EP 2987883B1
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European Patent Office
Prior art keywords
hot
steel sheet
rolled steel
less
rolling
Prior art date
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EP14784648.9A
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English (en)
French (fr)
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EP2987883A1 (de
EP2987883A4 (de
Inventor
Katsumi Nakajima
Kazuhiko Yamazaki
Chikara Kami
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JFE Steel Corp
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JFE Steel Corp
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Publication date
Priority claimed from JP2013084446A external-priority patent/JP5641086B2/ja
Priority claimed from JP2013084447A external-priority patent/JP5641087B2/ja
Application filed by JFE Steel Corp filed Critical JFE Steel Corp
Priority to EP18158632.2A priority Critical patent/EP3358033B1/de
Publication of EP2987883A1 publication Critical patent/EP2987883A1/de
Publication of EP2987883A4 publication Critical patent/EP2987883A4/de
Application granted granted Critical
Publication of EP2987883B1 publication Critical patent/EP2987883B1/de
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • C21D1/20—Isothermal quenching, e.g. bainitic hardening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
    • B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26—Methods of annealing
    • C21D1/28—Normalising
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/84—Controlled slow cooling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/005—Heat treatment of ferrous alloys containing Mn
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/008—Heat treatment of ferrous alloys containing Si
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
    • C21D8/0426—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
    • C21D8/0463—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment following hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C18/00—Alloys based on zinc
    • C22C18/04—Alloys based on zinc with aluminium as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
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    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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    • C23C2/36—Elongated material
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    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F17/00—Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25
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    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
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    • C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese

Definitions

  • the present invention relates to a high-strength hot-rolled steel sheet suitable for, for example, structural parts, such as members and frames, and underbody parts, such as suspensions, of automobile bodies, as well as automotive body components, such as truck frame parts.
  • the present invention relates to improvement of punchability during mass production (hereinafter also referred to as punchability in mass production).
  • high-strength steel sheets are actively utilized as automotive body components in order to reduce the weight of automobile bodies.
  • High-strength steel sheets are utilized not only in automobile structural parts but also in underbody parts and truck frame parts. In general, higher-strength steel sheets have lower workability.
  • automotive parts are formed by intense processing, steel sheets used as automotive body component materials are strongly required to have high strength and good workability.
  • Patent Literature 1 describes a high-strength hot-rolled steel sheet having a composition containing, on a mass percent basis, C: 0.05% to 0.15%, Si: 1.50% or less, Mn: 0.5% to 2.5%, P: 0.035% or less, S: 0.01% or less, Al: 0.020% to 0.15%, and Ti: 0.05% to 0.2%, wherein the high-strength hot-rolled steel sheet has a microstructure containing 60% to 95% by volume bainite and solute-strengthened or precipitation-strengthened ferrite or ferrite and martensite and has good hole expansion formability, which is shown by a fracture transition temperature of 0°C or less in a Charpy impact test.
  • Patent Literature 1 In a technique described in Patent Literature 1, after hot rolling, a steel sheet is cooled to a temperature in the range of 400°C to 550°C at an average cooling rate of 30°C/s or more, is coiled, and is cooled to a temperature of 300°C or less at a cooling rate in the range of 50°C/h to 400°C/h. Patent Literature 1 states that such a process can prevent diffusion of P in grain boundaries, decrease the fracture transition temperature to 0°C or less, improve toughness, and improve hole expansion formability.
  • truck frame parts and underbody parts are particularly frequently bored in order to join parts or reduce their weight or in order for a subsequent burring process or bore expanding process.
  • such boring is performed by punching from the perspective of productivity.
  • improved punchability is often strongly required.
  • Patent Literature 1 only prevents the intergranular segregation of P and improves hole expansion formability.
  • Patent Literature 1 does not describe stamping workability. It is difficult to believe that the prevention of segregation of P in grain boundaries can directly improve punched surface properties and contribute to improved stamping workability.
  • Patent Literature 2 proposes a high-strength hot-rolled steel sheet having a composition containing, on a mass percent basis, C: 0.01% to 0.07%, N: 0.005% or less, S: 0.005% or less, Ti: 0.03% to 0.2%, and B: 0.0002% to 0.002%, having a microstructure containing ferrite or bainitic ferrite as a main phase and a hard second phase and cementite, the hard second phase and cementite having an area fraction of 3% or less, and having good stamping workability. It is stated that a technique described in Patent Literature 2 can retain B in a solid solution state and thereby prevent defects in punched surfaces. In the technologies described in Patent Literature 2, ferrite or bainitic ferrite is the largest area phase, and the hard second phase, which adversely affects hole expandability, is limited to 3% or less.
  • Patent Literature 3 proposes a high-strength hot-rolled steel sheet having a tensile strength of 780 MPa or more and good punchability.
  • the high-strength hot-rolled steel sheet has a composition containing, on a mass percent basis, C: 0.05% to 0.15%, Si: 0.1% to 1.5%, Mn: 1% to 2%, P: 0.03% or less, S: 0.003% or less, Al: 0.01% to 0.08%, Ti: 0.05% to 0.15%, and N: 0.005% or less and has a bainite phase having an area fraction of more than 95%.
  • the average particle size of the bainite microstructure at a quarter thickness in the depth direction is 5 ⁇ m or less in a vertical cross section parallel to the rolling direction and 4 ⁇ m or less in a vertical cross section perpendicular to the rolling direction.
  • a region having a thickness of 1/10 of the sheet thickness at a central position in the thickness direction contains 7 or less crystal grains having an aspect ratio of 5 or more each spreading in the rolling direction.
  • the technologies described in Patent Literature 3 is intended to improve punchability by decreasing the average particle size of bainite and by decreasing the number of spreading grains in a central region in the thickness direction.
  • WO 2012/036308 A1 discloses a high-strength hot-rolled steel sheet having superior punchability and a method for manufacturing the same, the steel sheet having a composition containing C: 0.050 to 0.15%, Si: 0.1 to 1.5%, Mn: 1.0 to 2.0%, P: 0.03% or less, S: 0.0030% or less, Al: 0.01 to 0.08%, Ti: 0.05 to 0.15%, N: 0.005% or less, and the balance being Fe and unavoidable impurities. More than 95% of the microstructure is formed of a bainite phase in terms of area fraction.
  • Average grain diameters of the bainite phase in a region having a thickness equal to 1/4 of the sheet thickness from the surface in the sheet thickness direction is 5 ⁇ m or less in an L-direction cross section and 4 ⁇ m or less in a C-direction cross section.
  • the number of crystal grains extended in the rolling direction and having an aspect ratio of 5 or more is 7 or less in a sheet thickness center portion, whereas the strength is increased to a tensile strength TS of 780 MPa or more.
  • WO 2012/127125 A1 discloses a hot-rolled steel sheet having: a yield strength greater than 690 MPa and less than or equal to 840 MPa, a strength of between 780 MPa and 950 MPa, an elongation at break greater than 10 % and a hole expansion ratio (Ac) greater than 50%.
  • the chemical composition of the sheet of the invention comprises the following, expressed by weight, namely: 0.045% ⁇ C ⁇ 0.065%, 1.6% ⁇ Mn ⁇ 1.9%, 0.1 % ⁇ Si ⁇ 0.6%, 0.095% ⁇ Ti ⁇ 0.125%, 0.025% ⁇ Nb ⁇ 0.045%, 0.01 % ⁇ Al ⁇ 0.1 %, 0.002% ⁇ N ⁇ 0.007%, S ⁇ 0.004%, the remainder comprising iron and inevitable.
  • the microstructure thereof is formed by: granular bainite, ferrite, less than 1.5 % cementite by area percentage, and carbonitrides of titanium and niobium, providing a hole expansion ratio (Ac) greater than or equal to 50%.
  • WO 2012/127125 A1 also relates to methods for producing one such sheet, regardless of whether it has a low or high level of silicon.
  • JFS T1001 Japan Iron and Steel Federation standard
  • JFS T1001 Japan Iron and Steel Federation standard
  • an approximately 100 mm ⁇ 100 mm blank sheet is taken from a steel sheet in a laboratory.
  • a 10-mm ⁇ hole is punched in the blank sheet with a cylindrical punch (10 mm ⁇ ) having no wear damage while the clearance condition of 12% ⁇ 1% of the thickness (thickness: 2 mm or more) is strictly satisfied and while the blank sheet is uniformly and firmly held.
  • the punchability of the steel sheet is evaluated by observing the fracture surface at an end face of the punched hole.
  • the present invention aims to solve such problems of the related art and to provide a high-strength hot-rolled steel sheet having high strength and excellent punchability in mass production of parts and a method for producing the high-strength hot-rolled steel sheet.
  • the present inventors studied various factors that can affect punchability in mass production of high-strength hot-rolled steel sheets.
  • the present inventors first found a large difference between punchability evaluated by a method conforming to a known standard and punchability in mass production of actual parts. Also in actual mass production of parts, the punching clearance is adjusted at a timing of a die change. However, it is very difficult to completely adjust and manage the punching clearance within proper condition ranges, and therefore the clearance change generally happen caused by the circumferential position on a punched hole. Furthermore, punches have chipping and wear during mass production, and it is almost impossible to completely maintain and manage punches. This results in varying punching conditions. Furthermore, in mass production of actual parts, in addition to variations in punching clearance described above, depending on the part shape and the manufacturing process, boring by stamping is sometimes required in the middle of a mass production process.
  • stamping in mass production is punching under very severe conditions and is subjected to various process variations as described above.
  • the present inventors found that even steel sheets having good punchability as determined by punchability evaluation in laboratories in conformity with such a standard therefore often have poor boring during stamping in mass production of parts.
  • the present inventors further studied a method for evaluating punchability in mass production.
  • the present inventors first found that the punched hole diameter and the sheet clamping conditions as well as variations in punching clearance greatly influence the appearances of punched surfaces in stamping in mass production.
  • the best method for evaluating punchability in mass production includes using a 50-mm ⁇ punching punch of a flat-bottomed type, determining the hole diameter of a die such that the punching clearance is 30%, placing a spacer on the punching die, placing a blank sheet on the spacer, holding the blank sheet with a blank holder, and punching the blank sheet.
  • the present inventors intensively studied the effects of the steel sheet structure on punchability in mass production by this evaluation method. As a result, the present inventors found that size-controlling of a bainite phase for decreasing the size of the bainite phase alone is not enough to achieve the desired punchability in mass production, and additional microstructure controlling (elaboration or evolution of microstructure controlling) is required. As a result of further studies, the present inventors found that the microstructure unit that controls punchability in mass production is not only a macroscopic bainite microstructure but also the intervals of its lower microstructure, that is, bainite lath and carbide precipitation behavior.
  • the present inventors further studied and found that the punchability in mass production of a high-strength hot-rolled steel sheet is effectively and significantly improved by adjusting the rolling reduction and finishing temperature of finish rolling as well as the cooling timing and cooling rate control after the finish rolling within appropriate ranges, by forming a steel sheet microstructure composed mainly of a bainite phase, by decreasing the intervals of the lower microstructure bainite lath, and by causing iron based carbide to be precipitated in bainite lath grains, in addition to adjustment of the slab heating temperature.
  • the present invention has been accomplished on the basis of these findings after further consideration.
  • the following is the gist of the present invention.
  • a high-strength hot-rolled steel sheet that withstands severe stamping in mass production of parts and has good punchability in mass production can be easily produced as materials for automotive parts and the like.
  • the present invention has industrially significant advantages.
  • a high-strength hot-rolled steel sheet according to the present invention is suitable for truck frame parts and structural parts, such as members and frames, and underbody parts, such as suspensions, of automobile bodies in automobiles.
  • the present invention effectively contributes to weight reduction of parts.
  • compositions of a high-strength hot-rolled steel sheet according to the embodiment will be described below.
  • “%” refers to “% by mass”.
  • the term “high-strength” in the embodiment refers to a tensile strength TS of 900 MPa or more.
  • C is an element that effectively contributes to increase the strength of steel sheets and is a useful element that promotes bainite transformation and contributes to the formation of a bainite phase.
  • An adequate C content results in increased carbide in bainite lath grains and improved punchability in mass production. These effects require a C content of more than 0.07%.
  • An excessive C content of more than 0.2% results in poor workability and weldability.
  • the C content is limited to more than 0.07% and 0.2% or less, preferably 0.079% or more, more preferably 0.10% or more, and preferably 0.19% or less.
  • Si 0.05% or more and 2.0% or less
  • Si is an element that increases the strength of steel sheets by solute strengthening and contributes to improved ductility of steel sheets. It is desirable that the Si content be 0.05% or more to produce these effects. However, an excessive Si content results in an increased transformation temperature and decreased formation of a bainite phase. A Si content of more than 2.0% results in marked Si type complex oxide invasion of crystal grain boundaries of a surface layer while a steel slab is heated, and the Si type complex oxide is difficult to remove by frequent descaling during hot rolling, thus resulting in poor appearances of punched surfaces during stamping in mass production of steel sheets and poor punchability in mass production. Thus, the Si content is limited to 2.0% or more, preferably 1.5% or less, more preferably 1.0% or less.
  • Mn is an effective element that contributes to increase the strength of steel sheets by solute strengthening and transformation strengthening. Furthermore, Mn functions to decrease the transformation temperature and decrease the size of bainite lath. These effects require a Mn content of 1.0% or more. However, an excessive Mn content of more than 3.0% results in significant center segregation and very poor workability. Thus, Mn is limited to the range of 1.4% to 3.0%, preferably 1.4% to 2.6%.
  • P is an element that functions to increase the strength of steel sheets by solid solution.
  • a high P content tends to result in segregation in grain boundaries and may adversely affect workability. Thus, it is desirable to minimize the P content.
  • a P content up to 0.05% is allowable.
  • the P content is 0.03% or less.
  • S forms sulfides.
  • coarse sulfides reduce the ductility and workability of steel sheets.
  • a S content up to 0.005% is allowable.
  • the S content is limited to 0.005% or less, preferably 0.003% or less, more preferably 0.0015% or less.
  • Al 0.01% or more and 0.1% or less
  • Al is an important element that functions as a deoxidizing agent for steel. It is desirable that the Al content be 0.01% or more to produce this effect. However, an Al content of more than 0.1% results in low castability and results in low surface quality and workability due to a large amount of residual inclusions (oxide) in steel. Thus, the Al content is limited to 0.1% or less, preferably 0.06% or less.
  • N binds to a nitride-forming element and precipitates as a nitride, thereby contributing to a decreased size of crystal grains.
  • a N content of more than 0.01% is responsible for low hot ductility and very poor burring formability due to the formation of a large amount of nitride. Thus, it is desirable to minimize the N content.
  • a N content up to 0.01% is allowable. Thus, the N content is limited to 0.01% or less, preferably 0.006% or less, more preferably 0.004% or less.
  • Ti is one of the most important elements in the present invention. Ti tends to form a carbonitride and decreases the size of austenite ( ⁇ ) grains before transformation, thereby contributing to decreased lath intervals of bainite after transformation. Furthermore, Ti increases carbide (carbonitride) in fine bainite lath grains, contributes to increased strength by precipitation strengthening, increases void forming sites in stamping, and contributes to improved punchability in mass production. These effects require a Ti content of 0.05% or more. However, an excessive Ti content of more than 0.3% results in very large rolling force, thereby making rolling operation difficult, or results in excessively coarse precipitates, thereby reducing workability.
  • the Ti content is limited to the range of 0.07% to 0.3%, preferably 0.07% a strength-hole expandability balance and is one of the most important elements in the present invention.
  • V also functions to decrease the lath intervals of bainite, thereby decreasing the occurrence intervals of micro voids in punching, facilitating linking between voids, and improving punchability in mass production.
  • V also functions to decrease precipitation of coarse Fe-based carbide, thereby improving edge face properties in punching.
  • these components are basic components.
  • the following optional elements may be contained, if necessary: one or two selected from Nb: 0.005% to 0.2% and B: 0.0002% to 0.0030%, and/or one or two or more selected from Cu: 0.005% to 0.3%, Ni: 0.005% to 0.3%, and Sn: 0.005% to 0.3%, and/or one or two selected from Mo: 0.002% to 0.3% and Cr: 0.002% to 0.3%, and/or one or two selected from Ca: 0.0002% to 0.004% and REM: 0.0002% to 0.004%.
  • Nb and B are elements that contribute to improved punchability in mass production. If necessary, one or both of Nb and B may be contained.
  • Nb contributes to a finer microstructure and finely-dispersed carbide by the formation of precipitates (carbonitride), thereby decreasing the occurrence intervals of micro voids in punching and improving punchability in mass production. These effects preferably require a Nb content of 0.005% or more. However, an excessive Nb content of more than 0.2% results in coarse precipitates, poor workability, and increased production costs. Thus, if Nb is contained, the Nb content is preferably limited to the range of 0.005% to 0.2%, more preferably 0.005% to 0.15%.
  • B decreases the lath intervals of bainite and thereby contributes to improved punchability in mass production. These effects preferably require a B content of 0.0002% or more. However, an excessive B content of more than 0.0030% results in poor workability. Thus, if B is contained, the B content is preferably limited to the range of 0.0002% to 0.0030%, more preferably 0.0003% to 0.0020%.
  • Cu, Ni, and Sn are elements that contribute to increased strength by solute strengthening. If necessary, one or two or more of Cu, Ni, and Sn may be contained. It is desirable to contain Cu: 0.005% or more, Ni: 0.005% or more, and/or Sn: 0.005% or more to produce the effect. However, a Cu content of more than 0.3%, a Ni content of more than 0.3%, and/or a Sn content of more than 0.3% results in poor hot workability and may result in surface layer cracking during hot rolling. Thus, if Cu, Ni, and/or Sn are contained, each of the Cu content, the Ni content, and the Sn content is preferably limited to the range of 0.005% to 0.3%, more preferably 0.005% to 0.2%.
  • Mo and Cr are elements that tend to form carbide (precipitates) and contribute to improved punchability in mass production by the formation of the precipitates. Mo and Cr are also elements that contribute to improved hardenability. Mo and Cr are also elements that contribute to finer bainite lath by decreasing the bainite transformation temperature.
  • Mo and Cr may be contained, if necessary. It is desirable to contain Mo: 0.002% or more and/or Cr: 0.002% or more to produce these effects. However, an excessive Mo content of more than 0.3% and/or an excessive Cr content of more than 0.3% results in increased production costs and economic disadvantages. Thus, if Mo and/or Cr is contained, each of the Mo content and the Cr content is preferably limited to the range of 0.002% to 0.3%, more preferably 0.002% to 0.2%.
  • Ca and REM are elements that effectively contribute to improved workability by morphology control of inclusions. If necessary, one or both of Ca and REM may be contained. It is desirable to contain Ca: 0.0002% or more and/or REM: 0.0002% or more to produce the effect. However, a Ca content of more than 0.004% and/or a REM content of more than 0.004% results in an increased amount of inclusions in steel and poor workability. Thus, if Ca and/or REM is contained, each of the Ca content and the REM content is preferably limited to the range of 0.0002% to 0.004%, more preferably 0.0002% to 0.003%.
  • the balance other than the components described above includes Fe and incidental impurities.
  • a high-strength hot-rolled steel sheet according to the present invention has a microstructure in which a bainite phase constitutes more than 90% by volume, the average lath interval of bainite is 0.45 ⁇ m or less, and the ratio of Fe-based carbide precipitated in bainite lath grains to all Fe-based carbide is 10% or more.
  • a bainite phase should constitute more than 90%, preferably more than 92%, more preferably more than 94%, by volume of the steel sheet structure, as described above.
  • the bainite phase is a mixed microstructure of ferrite and Fe-based carbide.
  • a microstructure composed mainly of the bainite phase alone, an interface between ferrite and Fe-based carbide acts as a starting point for the formation of micro voids during punching.
  • Such a microstructure is advantageous to both appropriate formation of micro voids and subsequent void linking.
  • the intervals of bainite lath which is the lower microstructure of the bainite phase, are 0.45 ⁇ m or less. This is based on the finding that a smaller bainite phase and a finer lower microstructure (decreased lath intervals of bainite) are important in achieving the desired punchability in mass production.
  • the lath intervals of bainite are more than 0.45 ⁇ m, the desired punchability in mass production cannot be achieved.
  • the lath intervals of bainite are limited to 0.45 ⁇ m or less, preferably 0.40 ⁇ m or less, more preferably 0.35 ⁇ m or less.
  • a second phase other than the bainite phase includes one or more of martensite, retained austenite, ferrite, and pearlite.
  • the bainite phase in the microstructure contains carbide formed therein, and the ratio of Fe-based carbide precipitated in ferrite grains to all precipitated Fe-based carbide in the microstructure is 10% or more by number.
  • the ratio of Fe-based carbide precipitated in ferrite grains to all precipitated Fe-based carbide is less than 10% by number, the desired punchability in mass production cannot be achieve.
  • the ratio of Fe-based carbide precipitated in grains to all Fe-based carbide is limited to 10% or more, preferably 15% or more, more preferably 20% or more, by number.
  • a steel slab having the composition described above is heated and is subjected to hot rolling composed of rough rolling and finish rolling to form a hot-rolled steel sheet.
  • a method for producing a steel slab is not particularly limited.
  • Molten steel having the composition described above is formed by a common melting method, for example, in a converter, an electric furnace, or an induction furnace, and, if necessary, is subjected to secondary refining in vacuum degassing equipment, and is formed into a steel slab having predetermined dimensions by a common casting method, such as by continuous casting.
  • An ingot making and blooming method may also be used without problems.
  • the steel slab may be a thin slab having a thickness of approximately 30 mm. In the case of a thin slab, rough rolling may be omitted.
  • an electro-magnetic stirrer EMS
  • IBSR intentional bulging soft reduction casting
  • Electro-magnetic stirrer treatment can form equiaxed crystals at half the thickness of a sheet and reduce segregation.
  • Intentional bulging soft reduction casting can prevent the flow of molten steel in an unsolidified portion of a continuous cast slab and reduce segregation at half the thickness of a sheet.
  • At least one of these segregation reduction treatments can be used to improve good punchability characteristic of the present invention and improve elongation among the tensile properties described below.
  • a steel slab is heated to a heating temperature of 1100°C or more and is subjected to hot rolling.
  • a steel slab is heated to a heating temperature of 1100°C or more.
  • a heating temperature of less than 1100°C results in insufficient redissolution of precipitates, and a desired precipitate distribution cannot be achieved in a subsequent process.
  • the heating temperature is preferably 1150°C or more.
  • An excessively high heating temperature results in coarse crystal grains and consequently coarse bainite lath.
  • a heated steel slab is subjected to hot rolling composed of rough rolling and finish rolling to form a hot-rolled steel sheet.
  • the rough rolling may be performed under any conditions where a desired sheet bar size can be achieved.
  • the rough rolling is followed by finish rolling.
  • the conditions for the finish rolling are very important for the formation of a desired bainite lath microstructure.
  • Formation of a desired bainite lath microstructure requires bainite transformation of austenite ( ⁇ ) having sufficiently accumulated strain.
  • ⁇ austenite
  • the total rolling reduction of two final passes in finish rolling is limited.
  • the total rolling reduction of two final passes in finish rolling is less than 30%, strain is insufficiently accumulated in y, and a desired bainite lath microstructure cannot be formed after transformation.
  • the total rolling reduction of two final passes in finish rolling is limited to 30% or more, preferably 40% or more, more preferably 50% or more.
  • Finish-rolling finishing temperature control is also important for bainite transformation of austenite ( ⁇ ) having sufficiently accumulated strain.
  • the finish-rolling finishing temperature is less than the A r3 transformation temperature , it is difficult to form the desired microstructure, that is, the microstructure composed mainly of a bainite phase alone.
  • the finish-rolling finishing temperature is higher than (A r3 transformation temperature + 120°C), it is difficult to form a fine bainite phase.
  • the finish-rolling finishing temperature is limited to (A r3 transformation temperature) to (A r3 transformation temperature + 120°C), preferably (A r3 transformation temperature) to (A r3 transformation temperature + 80°C).
  • the finish-rolling finishing temperature herein refers to a surface temperature.
  • a r3 transformation temperature refers to a transformation temperature determined from a changing point in a thermal expansion curve obtained by cooling at a cooling rate of 1°C/s after processing with a Formastor testing machine (Thermecmastor-Z) .
  • cooling is performed.
  • the cooling conditions are also very important for the formation of a desired microstructure.
  • cooling In order to form a desired bainite lath microstructure by bainite transformation of ⁇ (austenite) having sufficiently accumulated strain, cooling must be started within 2 seconds after finish rolling. When cooling is started more than 2 seconds after finish rolling, recovery of ⁇ and recrystallization occur, and the number of nuclei for bainite transformation decreases. Thus, the desired bainite lath microstructure cannot be formed. Thus, cooling is started within 2 seconds, preferably 1.5 seconds, more preferably 1 second, after finish rolling.
  • the average cooling rate of cooling after finish rolling is limited to 40°C/s or more, preferably 50°C/s or more, more preferably 60°C/s or more.
  • the upper limit of the cooling rate depends on the capacity of cooling facilities and is preferably approximately 150°C/s or less in terms of the shape of steel sheets.
  • Cooling Stop Temperature 300°C to 500°C
  • the coiling temperature is the same as the cooling stop temperature.
  • the cooling stop temperature is less than 300°C or more than 500°C, the lath intervals of bainite and the Fe-based carbide distribution cannot be controlled within desired optimum ranges.
  • the cooling stop temperature is limited to the range of 300°C to 500°C, preferably 350°C to 500°C.
  • a hot-rolled steel sheet may be subjected to temper rolling.
  • a hot-rolled steel sheet may be annealed at a soaking temperature of 730°C or less and may be passed through a hot-dip galvanizing bath to form a galvanized layer on the surface thereof, thereby producing a hot-dip galvanized steel sheet.
  • the soaking temperature for annealing treatment is more than 730°C, bainite is tempered, making it difficult to form the microstructure in which a bainite phase constitutes more than 90% by volume and that has the desired lath intervals of bainite.
  • the soaking temperature for annealing treatment is 730°C or less.
  • the lower limit of the annealing temperature is not particularly limited, the soaking temperature for annealing treatment is preferably 600°C or more in terms of adhesion between a hot-dip galvanizing layer and a base steel sheet.
  • the galvanized layer may be subjected to alloying treatment to produce a galvannealed steel sheet.
  • the resulting hot-rolled steel sheet may be used to produce a coated steel sheet, such as an electrogalvanized steel sheet, as well as a hot-dip galvanized steel sheet.
  • a high-strength hot-rolled steel sheet according to the present invention will be described below with examples.
  • a steel slab having a composition listed in Table 1 was subjected to heating, finish rolling, and cooling after rolling listed in Table 2 to produce a hot-rolled steel sheet.
  • hot-rolled steel sheets other than a hot-rolled steel sheet No. 1' of steel A1 in Tables 1 to 3 described below were subjected to an electro-magnetic stirrer (EMS) to reduce segregation of components of the steel.
  • EMS electro-magnetic stirrer
  • Table 1 also lists the A r3 transformation temperature of each steel slab determined from a thermal expansion curve. After pickling, some of the hot-rolled steel sheets were passed through a continuous hot-dip galvanizing line and were subjected to annealing treatment under the conditions listed in Table 2 and hot-dip galvanizing treatment to produce hot-dip galvanized steel sheets (GI).
  • GI hot-dip galvanized steel sheets
  • each of the hot-rolled steel sheets subjected to the annealing treatment was immersed in a galvanizing bath (0.1% by mass Al-Zn) at 480°C, and 45 g/m 2 of a hot-dip galvanized layer was formed on each side of the steel sheet.
  • a galvanizing bath (0.1% by mass Al-Zn) at 480°C, and 45 g/m 2 of a hot-dip galvanized layer was formed on each side of the steel sheet.
  • some of the hot-rolled steel sheets were subjected to alloying treatment to produce galvannealed steel sheets (GA).
  • the alloying treatment temperature was 520°C.
  • Test specimens were taken from the hot-rolled steel sheets (including coated steel sheets) and were subjected to microstructure observation, a tensile test, and a punchability-in-mass-production test.
  • the test methods were as follows:
  • Test specimens for microstructure observation were taken from the hot-rolled steel sheets (coated steel sheets).
  • a vertical cross section (L cross section) of each test specimen parallel to the rolling direction was polished and was etched with a 3% nital solution to expose a microstructure.
  • the microstructure in the L cross section at a quarter thickness in the depth direction was observed with a scanning electron microscope (magnification: 3000 times).
  • Ten visual fields of the microstructure were photographed. Phases other than a bainite phase were separated by image analysis to determine the percentage of the phases other than bainite and calculate the area percentage of the bainite phase. The area percentage calculated in this manner was considered to be the volume percentage of the bainite phase.
  • Samples for a thin film were taken from the hot-rolled steel sheets (coated steel sheets) at a quarter thickness in the depth direction and were subjected to mechanical polishing and electropolishing to prepare thin film specimens.
  • the microstructure of each thin film specimen was observed with a transmission electron microscope (magnification: approximately 30000). Ten visual fields of the microstructure were photographed. The lath intervals of bainite were measured and were averaged to determine the lath intervals of bainite of each hot-rolled steel sheet.
  • Test specimens for microstructure observation were taken from the hot-rolled steel sheets (coated steel sheets).
  • a vertical cross section (L cross section) of each test specimen parallel to the rolling direction was polished and was etched with a 3% nital solution to expose a microstructure.
  • a replica sample at a quarter thickness in the depth direction was prepared.
  • the microstructure of the replica sample was observed a transmission electron microscope (magnification: approximately 30000 times).
  • Ten visual fields of the microstructure were photographed.
  • the number of Fe precipitates was measured in each precipitation site (at a grain boundary and within a grain) in the microstructure photographs, thereby calculating the ratio of the number of Fe precipitates in bainite lath grains to the number of all Fe precipitates.
  • Fe precipitates were identified by the shape of the precipitates and by energy dispersive X-ray (EDX) analysis.
  • test pieces Three JIS No. 5 tensile test pieces were taken from each of the hot-rolled steel sheets (coated steel sheets) such that the tensile direction was perpendicular to the rolling direction.
  • the test pieces were subjected to a tensile test according to JIS Z 2241.
  • the cross head speed was 10 mm/min.
  • the averages of tensile properties (tensile strength TS and elongation El) were considered to be the tensile properties of the steel sheets.
  • a blank sheet (size: 150 ⁇ 150 mm) was taken from each of the hot-rolled steel sheets (coated steel sheets).
  • a 50-mm ⁇ punching punch of a flat-bottomed type was used. The hole diameter of a die was determined such that the punching clearance was 30%.
  • a spacer was placed on the punching die.
  • a blank sheet was placed on the spacer and was held with a blank holder.
  • a hole was then punched in the blank sheet. After punching, the fracture surface condition of the punched surface was observed around the entire perimeter of the punched hole with a scanning electron microscope (magnification: 100 times) and was checked for cracking, chipping, a brittle fracture surface, a secondary shear surface, and cross section roughness.
  • Punchability in mass production was rated as follows: fracture surfaces free of cracking, chipping, a brittle fracture surface, a secondary shear surface, and cross section roughness were rated as good (circle) ; fracture surfaces having cross section roughness were rated as fair (triangle); and the other fracture surfaces were rated as poor (x).
  • Hot-dip galvanizing treatment Remarks Heating temperature (°C) Finish-rolling finishing temperature (°C) Total rolling reduction of two final passes (%) Cooling start time (s) Average cooling rate* (°C/s) Coiling temperature (°C) Annealing temperature (°C) Alloying treatment 1 A1 2.9 1180 905 35 1.3 65 425 - - Example 1' A1 2.9 1180 900 35 1.4 60 425 - - Example 2 B1 2.6 1290 950 40 0.9 80 450 - - Example 3 B1 2.0 1290 915 45 0.8 90 440 605 - Example 4 B1 2.6 1290 920 45 1.3 80 480 785 - Comparative example 5 B1 2.6 1290 915 50 2.5 55 385 - - Comparative example 6 C1 4.0 1220 890 35 1.4 60 430 - - Example 7 D1 2.6 1250 920 60 0.8 100 400 - - Example 8 D
  • the hot-rolled steel sheets (coated steel sheets) according to the examples had a high tensile strength TS of 900 MPa or more and good punchability in mass production.
  • the comparative examples outside the scope of the present invention had poor punchability in mass production.

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Claims (4)

  1. Hochfestes warmgewalztes Stahlblech, das eine Zugfestigkeit TS von 900 MPa oder mehr hat und eine Zusammensetzung sowie eine Mikrostruktur hat,
    wobei die Zusammensetzung in Masse-% aus
    mehr als 0,07% und 0,2% oder weniger C,
    0,05% oder mehr und 2,0% oder weniger Si,
    1,4% bis 3,0% Mn,
    0,05% oder weniger P,
    0,005% oder weniger S,
    0,01% oder mehr und 0,1% oder weniger Al,
    0,01% oder weniger N,
    0,07% bis 0,3% Ti,
    0,05% bis 0,3% V,
    optional wenigstens einem Bestandteil, der ausgewählt wird aus 0,005% bis 0,2% Nb, 0,0002% bis 0,0030% B, 0,005% bis 0,3% Cu, 0,005% bis 0,3% Ni, 0,005% bis 0,3% Sn, 0,002% bis 0,3% Mo, 0,002% bis 0,3% Cr,
    0,0002% bis 0,004% Ca, sowie 0,0002% bis 0,004% REM besteht, und
    der Rest Fe sowie zufällige Verunreinigungen sind,
    die Mikrostruktur mehr als 90 Vol.-% eines Bainits umfasst, wobei der Bainit einen durchschnittlichen Lanzett-Abstand von 0,45 µm hat und in Bainit-Lanzett-Körnern ausgefälltes Karbid auf Fe-Basis einen numerischen Anteil von 10 % oder mehr an dem gesamten Karbid auf Fe-Basis hat.
  2. Feuerverzinktes Stahlblech, das eine Feuerverzinkungs-Schicht oder eine legierte Feuerverzinkungs-Schicht an einer Oberfläche des hochfesten warmgewalzten Stahlblechs nach Anspruch 1 aufweist.
  3. Verfahren zum Herstellen des hochfesten warmgewalzten Stahlblechs nach Anspruch 1, das umfasst:
    Erhitzen einer Stahlbramme mit der Zusammensetzung nach Anspruch 1 und Durchführen von Warmwalzen der Stahlbramme, das aus Vorwalzen und Fertigwalzen besteht, um ein warmgewalztes Stahlblech auszubilden,
    wobei das Warmwalzen einschließt, dass die Stahlbramme auf 1100 °C oder mehr erhitzt wird, eine Gesamt-Walzreduktion zweier abschließender Durchläufe bei dem Fertigwalzen 30 % oder mehr beträgt, eine Fertigwalz-Abschlusstemperatur in einem Bereich von (Ar3-Umwandlungstemperatur) bis (Ar3-Umwandlungstemperatur + 120 °C) liegt, Kühlen innerhalb von 2 Sekunden nach dem Fertigwalzen begonnen wird, das warmgewalzte Stahlblech mit einer durchschnittlichen Abkühlgeschwindigkeit von 40 °C/s oder mehr auf eine Wickeltemperatur abgekühlt wird und das warmgewalzte Stahlblech bei einer Wickeltemperatur von 300 °C bis 500 °C gewickelt wird.
  4. Verfahren zum Herstellen eines feuerverzinkten Stahlblechs nach Anspruch 2, das umfasst:
    Beizen eines mit dem Verfahren zum Herstellen eines hochfesten warmgewalzten Stahlblechs nach Anspruch 3 hergestellten hochfesten warmgewalzten Stahlblechs und Durchführen von Glüh-und-Beschichtungs-Behandlung des hochfesten warmgewalzten Stahlblechs, um ein beschichtetes Stahlblech auszubilden,
    wobei das Glühen bei einer Durchwärm-Temperatur von 730 °C oder weniger durchgeführt wird und die Beschichtungs-Behandlung nach dem Glühen einschließt, dass das hochfeste warmgewalzte Stahlblech durch ein Feuerverzinkungs-Bad geführt wird, um eine Feuerverzinkungs-Schicht an einer Oberfläche des hochfesten warmgewalzten Stahlblechs auszubilden, und optional Legierungs-Behandlung des hochfesten warmgewalzten Stahlblechs durchgeführt wird, um die Feuerverzinkungs-Schicht zu legieren.
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