WO2018098485A1

WO2018098485A1 - Method for production for press hardened steel with increased toughness

Info

Publication number: WO2018098485A1
Application number: PCT/US2017/063490
Authority: WO
Inventors: John Andrew ROUBIDAUX; Erasmus AMOATENG
Original assignee: Ak Steel Properties, Inc.
Priority date: 2016-11-28
Filing date: 2017-11-28
Publication date: 2018-05-31
Also published as: US20180147614A1; TW201829806A; WO2018098485A8

Abstract

A method for processing a press hardenable steel includes first heating a slab of the press hardenable steel. The slab is heated to a re-heat furnace temperature of approximately 2300 °F. The slab is subjected to rolling into a steel sheet having a predetermined thickness. The temperature of the slab during rolling corresponds to a rolling temperature that is greater than or equal to 1600 °F.The steel sheet is coiled. The temperature of the steel sheet during coiling corresponds to a coiling temperature of approximately 1050 °F.

Description

METHOD FOR PRODUCTION FOR PRESS HARDENED STEEL WITH INCREASED TOUGHNESS

John Andrew Roubidoux

Erasmus Amoateng

PRIORITY

[0001] This application claims priority to U. S. Provisional Application Serial

Nos. 62/426,788 filed November 28, 2016, entitled "Press Hardened Steel with Increased Toughness and Method for Production;" the disclosure of which is incorporated by reference herein.

BACKGROUND

[0002] The present application relates to an improvement in press hardened steels, hot press forming steels, hot stamping steels, or any other steel that is heated to an austenitization temperature and formed and quenched in a stamping die to achieve desired mechanical properties in the final part. These types of steels are also sometimes referred to as "heat treatable boron-containing steels." In this application, they will all be referred to as "press hardened steels."

[0003] Press hardened steels are primarily used as structural members in

automobiles where high strength, low weight, and improved intrusion resistance are desired by automobile manufacturers. A common structural member where press hardened steels are employed in the automobile structure is the B-pillar.

[0004] Current industrial processing of press hardened steel involves heating a blank (piece of steel sheet) to a temperature greater than the A3 temperature (the austenitization temperature), typically in the range 900-950°C, holding the material at that temperature for a certain duration, placing the austenitized blank into a hot stamping die, forming the blank to the desired shape, and quenching the material in the die to a low temperature such that martensite is formed. The end result is a material with a high ultimate tensile strength and a fully martensitic microstructure.

[0005] The as-quenched microstructure of prior art press hardened steel is fully martensitic. Conventional press hardened steels have ultimate tensile strengths of approximately 1500 MPa and total elongations on the order of 6%.

SUMMARY

[0006] The steels and methods of the present application improve upon

currently available press hardened steel alloys by using chemistry and processing to achieve higher residual toughness in the press hardened condition. Residual toughness refers to the toughness the material has in the press hardened condition.

[0007] The strength-ductility property of embodiments of the present steel alloys include ultimate tensile strengths greater than or equal to 1100 MPa and elongations of approximately 8%.

DESCRIPTION OF DRAWINGS

[0008] Fig. 1 shows a thermal profile and processing schematic for

embodiments of the present alloys.

[0009] Fig. 2 shows another thermal profile and processing schematic for embodiments of the present alloys.

[0010] Fig. 3 shows a plot of stress-strain curves for composition 4310, with results from a first pre-processing method shown in solid-line form and results from a second pre-processing method shown in dashed-line form.

[0011] Fig. 4 shows a plot of stress-strain curves for composition 4311, with results from the first pre-processing method shown in solid-line form and results from the second pre-processing method shown in dashed- line form.

[0012] Fig. 5 shows a plot of stress-strain curves for composition 4312, with results from the first pre-processing method shown in solid-line form and results from the second pre-processing method shown in dashed- line form.

[0013] Fig. 6 shows a plot of stress-strain curves for composition 4313, with results from the first pre-processing method shown in solid-line form and results from the second pre-processing method shown in dashed- line form.

[0014] Fig. 7 shows the results of a double edge-notch tensile test for

embodiments of the present alloys after being subjected to the second pre-processing method.

[0015] Fig. 8 shows the results of a double edge-notch tensile test for

embodiments of the present alloys after being subjected to the first preprocessing method.

[0016] Fig. 9 shows the results of strain energy computations for

embodiments of the present alloys plotted as a function of niobium concentration.

[0017] Fig. 10 shows a photomicrograph of composition 4310 after being subjected to the first pre-processing method.

[0018] Fig. 11 shows a photomicrograph of composition 4310 after being subject to the second pre-processing method.

[0019] Fig. 12 shows a photomicrograph of composition 4311 after being subjected to the first pre-processing method.

[0020] Fig. 13 shows a photomicrograph of composition 4311 after being subjected to the second pre-processing method. [0021] Fig. 14 shows a photomicrograph of composition 4312 after being subjected to the first pre-processing method.

[0022] FIG. 15 shows a photomicrograph of composition 4312 after being subjected to the second pre-processing method.

[0023] Fig. 16 shows a photomicrograph of composition 4313 after being subjected to the first pre-processing method.

[0024] FIG. 17 shows a photomicrograph of composition 4313 after being subjected to the second pre-processing method.

DETAILED DESCRIPTION

[0025] Press hardened steels are generally desirable for their high strength characteristics. In practice, this permits manufacturers to produce components having greater strength and less weight relative to components produced of non-press hardened steels. These high strength characteristics are generally achieved through formation of a predominately martensitic microstructure. In particular, during a hot stamping process associated with a press hardened steel blank, the blank is first subjected to an austenitization heat treatment. During this heat treatment, the temperature of the blank is raised to greater than the A3 temperature for the particular composition of the blank to thereby transform the microstructure of the blank into predominately austenite.

[0026] Once the austenitization heat treatment is complete, the blank is

stamped into a predetermined shape using an internally cooled die set. In addition to shaping the blank, the stamping process also has the effect of rapidly cooling the blank below the martensite start temperature (M_s). As a consequence, the predominately austenitic microstructure of the blank is transformed to a microstructure of predominantly martensite. Because martensite is generally characterized as a strong and hard microstructure, the stamping process generally results in a final part having high strength and high hardness.

[0027] Although a high strength of the final hot stamped part is generally desirable for a wide variety of applications, in some circumstances additional toughness may be desirable. For instance, as described above, hot stamping generally results in a final part with high strength and high hardness. With high levels of hardness, the final part generally has relatively low ductility and thus relatively low toughness. Thus, in some circumstances it may be desirable to have a press hardened steel having the high strength characteristics of a conventional press hardened steel, but with improved residual toughness characteristics.

[0028] Prior to the hot stamping process described above, press hardened steels are subj ected to a variety of pre-processing steps. FIG. 1 shows a conventional pre-processing method (10). Pre-processing method includes subjecting a steel sheet to a plurality of pre-processing steps (20, 30, 40, 50). These steps (20, 30, 40, 50) are generally performed prior to hot stamping and prior to formation of press hardened steel blanks for the final hot stamping process. Generally, these steps (20, 30, 40, 50) are performed on sheet material in a continuous rolling mill. For instance, the press hardened steel initially begins as an as-cast slab comprising a predetermined composition. The slab then enters a re-heat furnace (20) and is subj ected to a re-heat temperature of approximately 2300° F (1260° C).

[0029] Once the slab is elevated to the re-heat temperature via the re-heat furnace (20), the slab is subjected to rough rolling (30) and then finishing rolling (40). These rolling steps progressively reduce the thickness of the slab to a final sheet thickness. During the rolling process, the temperature of the slab continuously decreases from the initial 2300° F (1260° C) re-heat temperature to a roughing temperature associated with rough rolling (30). In some examples the roughing temperature is approximately 2000° F (1093° C). During finishing rolling (40), the slab is subject to a finishing temperature of approximately 1600° F (871 ° C). As the temperature decreases, the slab is subjected to rolling operations that progressively reduce the thickness of the slab by relatively large amounts during rough rolling (30) to relatively small amounts during finishing rolling (40).

[0030] From the initial re-heat temperature associated with the re-heat furnace

(20) to the temperature associated with finishing rolling (40), the temperature of the slab decreases at a relatively constant rolling cooling rate (12).

[0031] After completion of rolling, the press hardened steel material is in a steel sheet form. In the steel sheet form, the steel sheet is subj ect to coiling (50). Coiling (50) can be performed at a coiling temperature of approximately 1200° F (649° C). In some examples, coiling (50) can begin immediately after finishing (40). Thus, in some examples coiling (50) may begin at temperatures above 1600° F (871 ° C) and decrease to the coiling temperature of approximately 1200° F (649° C).

[0032] Prior to coiling (50), the steel sheet can be cooled to the coiling

temperature at one or more different cooling rates (14, 16) as shown in FIG. 1. For instance, at a first cooling rate (14) or second cooling rates (16), the steel sheet is cooled relatively slowly at between about 18° F/second and about 20° F/second.

[0033] At the conclusion of coiling (50), the coiled steel sheet is permitted to cool to ambient or room temperature. The coiled steel sheet is then subsequently formed into blanks of steel material for press hardening. The blanks can then be subjected to the hot stamping process described above. [0034] As described above, in some circumstances it may be desirable to increase the toughness of press hardened steel parts. In some circumstances, toughness can be improved by refining the grain size of the press hardened steel material by modifying certain parameters of the pre-processing steps described above.

[0035] FIG. 2 shows modified pre-processing method (100). As with preprocessing method (10) described above, pre-processing method (100) of the present example includes a series of pre-processing steps (120, 130, 140, 150). As similarly described above, these steps (120, 130, 140, 150) are generally performed prior to hot stamping and prior to formation of press hardened steel blanks for the final hot stamping process. Generally, these steps (120, 130, 140, 150) are performed on sheet material in a continuous rolling mill. For instance, the press hardened steel initially begins as an as-cast slab comprising a predetermined composition. The slab then enters a re-heat furnace (120), where the slab is subjected to a re-heat temperature. Like with the reheat temperature described above with respect to re-heat furnace (20), the reheat temperature in the present example is approximately 2300° F (1260° C).

[0036] Once the slab is elevated to the re-heat temperature of re-heat furnace

(120), the slab is subjected to rough rolling (130) and then finishing rolling (140). This progressively reduces the thickness of the slab to a final sheet thickness. As an example, during the rolling process, the temperature of the slab continuously decreases from the initial 2300° F (1260° C) re-heat temperature of the re-heat furnace (120) to a roughing temperature of approximately 2000° F (1093° C) associated with rough rolling (130). Next, the slab is further reduced to a finishing temperature of approximately 1600° F (871 ° C) associated with finishing rolling (140). Unlike finishing rolling (40) in the conventional pre-processing method (10) described above, finishing rolling (140) in the present example is performed at a relatively lower temperature. As will be described in greater detail below, this relatively lower temperature can lead to increased grain refinement when performed in connection with a modified coiling temperature. As the temperature decreases, the slab is subjected to rolling operations that reduce the thickness of the slab by relatively large amounts during rough rolling (130) to relatively small amounts during finishing rolling (140).

[0037] From the initial re-heat temperature associated with the re-heat furnace

(120) to the temperature associated with finishing rolling (140), the temperature of the slab decreases at a relatively constant rolling cooling rate (112). This cooling rate is similar to the rolling cooling rate (12) of the prior process.

[0038] After completion of rolling, the press hardened steel material is in a steel sheet form. In the steel sheet form, the steel sheet is subject to coiling (150). Coiling (150) can be performed at a coiling temperature of approximately 1050° F (566° C). In some examples, coiling (150) can begin immediately after finishing (140). Thus, in some examples coiling (150) may begin at approximately 1600° F (871° C) and decrease to the coiling temperature of approximately 1050° F (566° C). Alternatively, in some examples coiling (150) can be delayed until the steel sheet reaches the coiling temperature of approximately 1050° F (566° C). Once the coiling temperature is reached (150), the steel sheet may be held isothermally for the entirety of coiling (150). Preferably, the finishing (140) is performed at the finishing temperature of about 1600° F (871° C), the steel sheet is lowered to the coiling temperature of 1050° F (566° C), and coiling (150) is performed while the steel sheet is held at the coiling temperature.

[0039] Regardless of how the coiling temperature is reached, it should be understood that the coiling temperature of approximately 1050° F (566° C) is generally low relative to the coiling temperatures described above with respect to conventional pre-processing method (10). As will be understood, this reduced coiling temperature can generally result in improved grain refinement of the steel sheet that can lead to increased residual toughness in a final work product after hot stamping.

[0040] Prior to coiling (150), the steel sheet can be cooled to the coiling

temperature at a cooling rate (114) as shown in FIG. 2. In the present example, the cooling rate (114) is between about 35 °F/second and about 50° F/second.

[0041] Unlike cooling rates (14, 16) described above, cooling rate (114) in the present example is generally relatively fast. This relatively fast cooling rate can be achieved using a run-out-table accelerated cooling method. As will be understood, this relatively fast cooling rate (114) can generally lead to increased grain refinement and associated improved residual toughness in a final work product after hot stamping.

[0042] At the conclusion of coiling (150), the coiled steel sheet is permitted to cool to ambient or room temperature. The coiled steel sheet is then subsequently formed into blanks of steel material for press hardening. The blanks can then be subjected to the hot stamping process described above.

[0043] As described above, the pre-processing methods (10, 100) can be performed using an as-cast slab comprising a predetermined composition. It should be understood that the particular composition of the slab can be varied such that a variety of compositions can be used with the methods (10, 100) described above. As will be described in greater detail below, various elements can be added to the slab to influence numerous metallurgical properties of the final work product. [0044] Carbon is added to reduce the martensite start temperature, provide solid solution strengthening, and to increase the hardenability of the steel. Carbon is an austenite stabilizer. In certain embodiments, carbon can be present in concentrations of 0.1 - 0.5 mass %; in other embodiments, carbon can be present in concentrations of 0.2 - 0.30 mass %.

[0045] Manganese is added to reduce the martensite start temperature, provide solid solution strengthening, and to increase the hardenability of the steel. Manganese is an austenite stabilizer. In certain embodiments, manganese can be present in concentrations of 0.75 - 3.0 mass %; in other embodiments, manganese can be present in concentrations of 1.15 - 1.25 mass %.

[0046] Silicon is added to provide solid solution strengthening. Silicon is a ferrite stabilizer. In certain embodiments, silicon can be present in concentrations of 0.02 - 1.5 mass %; in other embodiments, silicon can be present in concentrations of 0.15 - 0.30 mass %.

[0047] Aluminum is added for deoxidation during steelmaking and to provide solid solution strengthening. Aluminum is a ferrite stabilizer. In certain embodiments, aluminum can be present in concentrations of 0.0 - 0.8 mass %; in other embodiments, aluminum can be present in concentrations of 0.02 - 0.15 mass %. In other embodiments, aluminum is entirely optional and can be therefore omitted or limited to an impurity element in some embodiments.

[0048] Titanium is added to getter nitrogen. In certain embodiments, titanium can be present in concentrations of 0.0-0.060 mass %; in other embodiments, titanium can be present in concentrations of a maximum of 0.045 mass %. In other embodiments, titanium is entirely optional and can be therefore omitted or limited to an impurity element in some embodiments. [0049] Molybdenum is added to provide solid solution strengthening and to increase the hardenability of the steel. In certain embodiments, molybdenum can be present in concentrations of 0-0.5 mass %; in other embodiments, molybdenum can be present in concentrations of 0-0.3 mass %. In other embodiments, molybdenum is entirely optional and can be therefore omitted or limited to an impurity element in some embodiments.

[0050] Chromium is added to reduce the martensite start temperature, provide solid solution strengthening, and increase the hardenability of the steel. Chromium is a ferrite stabilizer. In certain embodiments, chromium can be present in concentrations of 0-0.5 mass %; in other embodiments, chromium can be present in concentrations of 0.15-0.25 mass %.

[0051] Boron is added to increase the hardenability of the steel. In certain embodiments, boron can be present in concentrations of 0-0.005 mass%; in other embodiments, boron can be present in concentrations of 0.003-0.005 mass %.

[0052] Nickel is added to provide solid solution strengthening and reduce the martensite start temperature. Nickel is an austenite stabilizer. In certain embodiments, nickel can be present in concentrations of 0.0-0.6 mass %; in other embodiments, nickel can be present in concentrations of 0.02-0.3 mass %. In still other embodiments, nickel is entirely optional and can be therefore omitted or limited to an impurity element in some embodiments.

[0053] Niobium is added to provide improved grain refinement. Niobium can also increase hardness and strength. In certain embodiments, niobium can be present in concentrations of 0-0.090 mass%.

[0054] Example 1 [0055] A plurality of alloy compositions shown in Table 1 were prepared using standard steel making processes, except as noted below.

[0056] Table 1: Composition range. Compositions are in mass pet.

C B Cr Mn Nb Si

4310 0.21 0.003 0.21 1.18 0.000 0.24

4311 0.21 0.0029 0.19 1.19 0.029 0.24

4312 0.21 0.0029 0.20 1.20 0.043 0.24

4313 0.22 0.003 0.19 1.20 0.052 0.25

[0057] Example 2

[0058] Composition 4310 of Table 1 in Example 1 was subjected to both preprocessing methods (10, 100) described above. The steel underwent simulated hot stamping. The steel was heated to approximately 930 °C for 5 min and then quenched in water-cooled copper dies. Samples subjected to each pre-processing method (10, 100) plus simulated hot stamping were then subjected to tensile testing to generate stress-strain curves. The resulting stress-strain curves are shown in FIG. 3 with preprocessing method (10) shown in solid-line form and pre-processing method (100) shown in dashed-line form.

[0059] As can be seen in FIG. 3, the samples subjected to pre-processing method (100) generally resulted in improved residual toughness relative to samples subjected to pre-processing method (10).

Photomicrographs were prepared for each sample in the hot-rolled condition prior to the simulated hot stamping and are shown in FIGS. 10 and 11, with FIG. 10 corresponding to pre-processing method (10) and FIG. 11 corresponding to pre-processing method (100). As can be seen, pre-processing method (100) generally resulted in a more refined grain structure relative to the grain structure produced from preprocessing method (10). As a consequence of this, improved residual toughness was observed in FIG. 3. [0060] Example 3

[0061] Composition 4311 of Table 1 in Example 1 was subjected to both preprocessing methods (10, 100) described above. The steel underwent simulated hot stamping. The steel was heated to approximately 930 °C for 5 min and then quenched in water-cooled copper dies. Samples subjected to each pre-processing method (10, 100) plus simulated hot stamping were then subjected to tensile testing to generate stress-strain curves. The resulting stress-strain curves are shown in FIG. 4 with preprocessing method (10) shown in solid-line form and pre-processing method (100) shown in dashed-line form.

[0062] As can be seen in FIG. 4, the samples subjected to pre-processing method (100) generally resulted in improved residual toughness relative to samples subjected to pre-processing method (10).

Photomicrographs were prepared for each sample in the hot-rolled condition prior to the simulated hot stamping and are shown in FIGS. 12 and 13, with FIG. 12 corresponding to pre-processing method (10) and FIG. 13 corresponding to pre-processing method (100). As can be seen, pre-processing method (100) generally resulted in a more refined grain structure relative to the grain structure produced from preprocessing method (10). As a consequence of this, improved residual toughness was observed in FIG. 4.

[0063] Example 4

[0064] Composition 4312 of Table 1 in Example 1 was subjected to both preprocessing methods (10, 100) described above. The steel underwent simulated hot stamping. The steel was heated to approximately 930 °C for 5 min and then quenched in water-cooled copper dies. Samples subjected to each pre-processing method (10, 100) plus simulated hot stamping were then subjected to tensile testing to generate stress-strain curves. The resulting stress-strain curves are shown in FIG. 5 with pre- processing method (10) shown in solid-line form and pre-processing method (100) shown in dashed-line form.

[0065] As can be seen in FIG. 5, the samples subjected to pre-processing method (100) generally resulted in improved residual toughness relative to samples subjected to pre-processing method (10).

Photomicrographs were prepared for each sample in the hot-rolled condition prior to the simulated hot stamping and are shown in FIGS. 14 and 15, with FIG. 14 corresponding to pre-processing method (10) and FIG. 15 corresponding to pre-processing method (100). As can be seen, pre-processing method (100) generally resulted in a more refined grain structure relative to the grain structure produced from preprocessing method (10). As a consequence of this, improved residual toughness was observed in FIG. 5.

[0066] Example 5

[0067] Composition 4313 of Table 1 in Example 1 was subjected to both preprocessing methods (10, 100) described above. The steel underwent simulated hot stamping. The steel was heated to approximately 930 °C for 5 min and then quenched in water-cooled copper dies. Samples subjected to each pre-processing method (10, 100) plus simulated hot stamping were then subjected to tensile testing to generate stress-strain curves. The resulting stress-strain curves are shown in FIG. 6 with preprocessing method (10) shown in solid-line form and pre-processing method (100) shown in dashed-line form.

[0068] As can be seen in FIG. 6, the samples subjected to pre-processing method (100) generally resulted in improved residual toughness relative to samples subjected to pre-processing method (10).

Photomicrographs were prepared for each sample in the hot-rolled condition prior to the simulated hot stamping and are shown in FIGS. 16 and 17, with FIG. 16 corresponding to pre-processing method (10) and FIG. 17 corresponding to pre-processing method (100). As can be seen, pre-processing method (100) generally resulted in a more refined grain structure relative to the grain structure produced from preprocessing method (10). As a consequence of this, improved residual toughness or retained ductility was observed in FIG. 6.

[0069] Example 6:

[0070] Toughness for samples having each composition identified in Table 1 of Example 1, above, was evaluated further using double-edge-notch tensile tests. A sample for each composition (e.g., 4310, 4311, 4312, 4313) was subject to each pre-processing method (10, 100) described above. Steels then underwent a simulated press hardening procedure in which they were austenitized at approximately 930 °C for 300 s and then quenched in flat, water-cooled dies. Double-edge notched tensile tests were then performed. Plots were then prepared of the resulting data for each composition as shown in FIGS. 7 and 8. For instance, FIG. 7 shows the results for each sample subjected to pre-processing method (100). FIG. 8 shows the results for each sample subjected to pre-processing method (10). For both FIGS. 7 and 8, the data for each composition is identifiable by symbols. For instance, circles correspond to composition 4310, triangles correspond to composition 4311, stars correspond to composition 4312, and crosses correspond to composition 4313.

[0071] As can be seen in FIGS. 7 and 8, materials subjected to pre-processing method (100) exhibited a higher peak load/force prior to fracture in compassion to the materials subject to pre-processing method (10). Thus, FIGS. 7 and 8 are indicative of pre-processing method (100) resulting in increased toughness or retained ductility.

[0072] Example 7 [0073] The data discussed above with respect to Example 6 was analyzed further. In particular, integration of the area under the force- displacement curves shown in FIGS. 7 and 8 can be used to obtain a value of strain energy. Strain energy is considered a measure of material toughness. Accordingly, a measure of material toughness for each sample discussed above with respect to Example 6 was generated.

[0074] The resulting strain energy for each sample was then plotted as a

function of niobium concentration in the corresponding composition for each sample. The resulting plot is shown in FIG. 9. Unlike FIGS. 7 and 8 discussed above, FIG. 9 utilizes a different symbolic scheme to identify the correspondence between specific data points and composition. For instance, in FIG. 9, circles correspond to composition 4310, crosses correspond to composition 4311, triangles correspond to composition 4312, and squares correspond to composition 4313. In addition, because the results for samples subjected to each preprocessing method (10, 100) are included in a single plot, FIG. 9 depicts a comparison of samples subjected to pre-processing method (10) and samples subjected to pre-processing method (100). In each case, the steels underwent simulated hot stamping prior to testing. In FIG. 9, solid symbols represent processing method (10) and open symbols represent processing method (100).

[0075] As can be seen in FIG. 9, samples subjected to pre-processing method

(100) generally resulted in increased strain energy and therefore increased toughness. In addition, some increase in toughness was observed in response to a composition with increased niobium. For instance, composition 4313 included the highest niobium concentrations and also included the highest strain energy or toughness measurements.

[0076] Example 8 A press hardenable steel comprising by total mass percentage of the steel : wherein said steel is subject to the following processing: heating a slab of the press hardenable steel to a re-heat furnace temperature of approximately 2300 °F;

rolling the slab into a steel sheet having a predetermined thickness, wherein the temperature of the slab during rolling corresponds to a rolling temperature that is greater than or equal to about 1600° F (871° C); and

coiling the steel sheet, wherein the temperature of the steel sheet during coiling corresponds to a coiling temperature of approximately 1050 °F.

Example 9

A press hardenable steel of Example 8 or any one of the following Examples, comprising by total mass percentage of the steel:

0.10 to 0.50% Carbon;

0.00 to 0.005% Boron;

0.0 to 0.50% Chromium;

0.75 to 3.0% Manganese;

0.090% or less Niobium;

0.02 to 1.50% Silicon;

0.0 to 0.8% Aluminum;

0.0 to 0.060% Titanium;

0.0 to 0.50% Molybdenum;

0.0 to 0.6% Nickel; and [0091] the balance including iron and impurities,

[0092] Example 10

[0093] A press hardenable steel of Example 8 or 9 or any one of the following

Examples, comprising 0.2 - 0.3 mass % carbon.

[0094] Example 11

[0095] A press hardenable steel of any one of Examples 8 through 10 or any one of the following Examples, comprising 1.15-1.25 mass % manganese.

[0096] Example 12

[0097] A press hardenable steel of any one of Examples 8 through 11 or any one of the following Examples, comprising 0.15-0.30 mass% silicon.

[0098] Example 13

[0099] A press hardenable steel of any one of Examples 8 through 12 or any one of the following Examples, comprising 0.02 - 0.15 mass% aluminum.

[00100] Example 14

[00101] A press hardenable steel of any one of Examples 8 through 13 or any one of the following Examples, comprising a maximum of 0.045 mass% titanium.

[00102] Example 15

[00103] A press hardenable steel of any one of Examples 8 through 14 or any one of the following Examples, comprising 0 - 0.30 mass% molybdenum.

[00104] Example 16 [00105] A press hardenable steel of any one of Examples 8 through 15 or any one of the following Examples, comprising 0.15-0.25 mass% chromium.

[00106] Example 17

[00107] A press hardenable steel of any one of Examples 8 through 16 or any one of the following Examples, comprising 0.003 - 0.005 mass% boron.

[00108] Example 18

[00109] A press hardenable steel of any one of Examples 8 through 17 or any one of the following Examples, comprising 0.02 - 0.3 mass% nickel.

[00110] Example 19

[00111] A press hardenable steel of any one of Examples 8 through 18 or any one of the following Examples, comprising 0 - 1.0 mass% molybdenum.

[00112] Example 20

[00113] A press hardenable steel of any one of Examples 8 through 19 or any one of the following Examples, wherein the rolling step includes a rough rolling operation and a finish rolling operation.

[00114] Example 21

[00115] A press hardenable steel of any one of Examples 8 through 20 or any one of the following Examples, wherein the temperature of the slab during the rough rolling operation is greater than or equal to 2000 °F.

[00116] Example 22

[00117] A press hardenable steel of any one of Examples 8 through 21 or any one of the following Examples, wherein the temperature of the slab during the finish rolling operation is greater than or equal to about 1600° F (871° C).

[00118] Example 23

[00119] A press hardenable steel of any one of Examples 8 through 22 or any one of the following Examples, further comprising the step of hot stamping at least a portion of the steel sheet after coiling the steel sheet.

[00120] Example 24

[00121] A press hardenable steel of any one of Examples 8 through 23 or any one of the following Examples, further comprising the step of cooling the press hardenable steel from the re-heat furnace temperature to the rolling temperature at a first cooling rate, and cooling the press hardenable steel from the rolling temperature to the coiling temperature at a second cooling rate, wherein the second cooling rate is greater than the first cooling rate.

[00122] Example 25

[00123] A press hardenable steel of any one of Examples 8 through 24 or any of the following Examples, wherein the step of cooling the press hardenable steel from the rolling temperature to the coiling temperature is performed using a run-out table accelerated cooling method.

[00124] Example 26

[00125] A press hardenable steel of any one of Examples 8 through 25 or the following Example, wherein the temperature of the slab during the rough rolling operation is approximately 2000 °F.

[00126] Example 27 A press hardenable steel of any one of Examples 8 through 26, wherein the temperature of the slab during the finish rolling operation is approximately 1600° F to 1700°F.

Claims

What is Claimed is:

1. A method for processing a press hardenable steel, the method comprising:

(a) heating a slab of the press hardenable steel to a re-heat furnace

temperature of approximately 2300 °F;

(b) rolling the slab into a steel sheet having a predetermined thickness, wherein the temperature of the slab during rolling corresponds to a rolling temperature that is greater than or equal to about 1600° F (871° C); and

(c) coiling the steel sheet, wherein the temperature of the steel sheet during coiling corresponds to a coiling temperature of approximately 1050 °F.

2. The method of claim 1, wherein the rolling step includes a rough rolling operation and a finish rolling operation.

3. The method of claim 2, wherein the temperature of the slab during the rough rolling operation is greater than or equal to 2000 °F.

4. The method of claim 2, wherein the temperature of the slab during the finish rolling operation is greater than or equal to about 1600° F (871° C) .

5. The method of claim 2, wherein the temperature of the slab during the rough rolling operation is approximately 2000 °F.

6. The method of claim 2, wherein the temperature of the slab during the finish rolling operation is approximately 1600°F to 1700 °F.

7. The method of claim 1, further comprising hot stamping at least a portion of the steel sheet after coiling the steel sheet.

8. The method of claim 1, further comprising cooling the press hardenable steel from the re-heat furnace temperature to the rolling temperature at a first cooling rate, and cooling the press hardenable steel from the rolling temperature to the coiling temperature at a second cooling rate, wherein the second cooling rate is greater than the first cooling rate.

9. The method of claim 1, wherein the step of cooling the press hardenable steel from the rolling temperature to the coiling temperature is performed using a run-out table accelerated cooling method.

10. The method of claim 1 , wherein the press hardenable steel has a composition comprising:

0.10 to 0.50% Carbon;

0.00 to 0.005% Boron;

0.0 to 0.50% Chromium;

0.75 to 3.0%) Manganese;

0.090% or less Niobium;

0.02 to 1.50% Silicon;

0.0 to 0.80% Aluminum;

0.0 to 0.060%) Titanium;

0.0 to 0.50% Molybdenum;

0.0 to 0.60% Nickel; and

the balance including iron and impurities.