EP2935631A1 - Method and apparatus for drying hides during the finishing process - Google Patents
Method and apparatus for drying hides during the finishing processInfo
- Publication number
- EP2935631A1 EP2935631A1 EP12829162.2A EP12829162A EP2935631A1 EP 2935631 A1 EP2935631 A1 EP 2935631A1 EP 12829162 A EP12829162 A EP 12829162A EP 2935631 A1 EP2935631 A1 EP 2935631A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hides
- layer
- finishing
- drying
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001035 drying Methods 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000007730 finishing process Methods 0.000 title claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 239000010985 leather Substances 0.000 claims abstract description 10
- 230000001678 irradiating effect Effects 0.000 claims abstract description 8
- 230000005672 electromagnetic field Effects 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012263 liquid product Substances 0.000 claims description 3
- 230000006641 stabilisation Effects 0.000 claims description 3
- 238000011105 stabilization Methods 0.000 claims description 3
- 239000006193 liquid solution Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 238000000151 deposition Methods 0.000 abstract description 5
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 description 14
- 239000000047 product Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 4
- 238000007761 roller coating Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 238000007766 curtain coating Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 244000126968 Kalanchoe pinnata Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 229940021722 caseins Drugs 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000010028 chemical finishing Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000000485 pigmenting effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B1/00—Manufacture of leather; Machines or devices therefor
- C14B1/58—Drying
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C11/00—Surface finishing of leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B2700/00—Mechanical treatment or processing of skins, hides or leather in general; Pelt-shearing machines; Making driving belts; Machines for splitting intestines
- C14B2700/07—Leather tensioning or stretching frames; Stretching-machines; Setting-out boards; Pasting boards; Fastening devices; Drying of leather
Definitions
- the present invention generally finds application in the field of tanning and nonwoven (imitation leather) fabrics, and particularly relates to a method of forming crust leather by drying, during the finishing process.
- the invention in another aspect, relates to an apparatus for drying hides (crust) that uses the method.
- the dried hides undergo a process typically known as finishing, whereby such defects are removed or made less visible, for better use of the hides.
- Finishing may be a mechanical or chemical process.
- chemical finishing which is the one of interest herein, the hides are coated with generally liquid products, which are designed to form a grain side layer that may have various thicknesses or be elastic or tough according to the type of finishing and leather.
- the finishing products may be selected, for instance, from the group of synthetic (acrylic, butadiene, polyurethane) resins or natural binders (caseins, albumins, protein-based film-forming agents, based on modified cellulose) possibly added with pigments, dyes, opacifiers, polishing agents, various auxiliary additives. These products are mixed with 20% to 40%, preferably 25% to 30% water, based on the total mass. The aqueous solution is deposited on the grain side of the hides and forms a film that is designed to intimately bind with the fibers, to become integral with the hide.
- the hide contacts the product-wetted roller and is supported by an opposed conveying roller. This will optimize the finishing process. A continuous, uniform and easily adjustable coating is obtained.
- a further layer of a fixing agent is typically deposited, for stabilization and preservation of the underlying finishing layer.
- This layer of fixing agent should also undergo drying in a hot air tunnel as described above.
- the drying process has been typically carried out to date using an oven or a tunnel operating with infrared rays, catalytic gas and more often with hot air.
- FIG. 1 shows a typical finishing plant R comprising two spray units R1 with two air drying tunnels T1 , T2 downstream therefrom, between the two paint and fixing agent coating stations, and upstream from a chiller C and a staker K for imparting softness to the hides again.
- Hot air is conveyed into the tunnels T1 , T2, using high-capacity compressors and blowers, with a capacity of thousands of cubic meters/hour.
- the drying temperatures in these apparatus generally range from 80 °C to 1 20 °C.
- a further drawback is that after the deposition of the finishing layer, the dried hides have a hot surface and cannot be easily handled and stacked. Therefore, completely dried hides shall be typically cooled using a cooling device, such as a cold air chiller, which has high power consumption.
- any shrinking effect of the hot drying process will cause unevenness and some skrinkage in the hides, thereby leading to a significant reduction of the useful leather area, and to a reduction of the final inherent value of the treated hides.
- a further object of the invention is to provide a drying method that has a lower power consumption and minimizes the costs of the final product.
- Yet another object is to devise a drying method performed during finishing that does not harden hides and maintains the hand of the treated hides.
- drying and the whole finishing process will have very low running costs.
- power consumption will be about 1 electric kW per liter of extracted water.
- hides will be heated to temperatures not exceeding 30 °.
- drying process will be substantially uniform and require very little moisture extraction, thereby avoiding the infiltration of dust and other foreign matter.
- the invention relates to a plant for drying hides being finished, as defined in claim 7.
- FIG. 1 is a general view of a prior art finishing plant using hot air drying tunnels
- FIG. 2 is a perspective view of a finishing plant which incorporates drying apparatus of the invention ;
- FIG. 3 shows a side view of a detail of FIG. 2 in an enlarged scale
- FIG. 4 is a partially broken-away side view of the apparatus of FIG. 3;
- FIG. 6 shows a block diagram of the drying method of the invention.
- the drying plant of the invention is designed to be part of a plant for finishing crust hides P, generally referenced R.
- the finishing plant R comprises, as is known in the art, a first finishing unit R1 , for depositing a first layer or film S' of a liquid finishing product on a surface of the hides P, on the grain side or the flesh side.
- the finishing unit R1 may be of spray, roller or curtain coating type, as is known per se and not included in the scope of the present invention, for spraying or spreading the finishing solution on one face of the hides P being treated.
- the rate of the fixing solution will range from 2 to 1 5 g/inch 2 .
- the moving transfer surface 5 may consist of a belt conveyor or annular wires subtended by end rollers 6, 7, one of which is motorized, for automatic feeding of the hides P.
- An electromagnetic wave irradiator irradiating waves in the RF range, generally referenced 8, is placed in the shielding tunnel 2 and is designed to irradiate the surface of the hides P to be dried.
- the irradiator 8 essentially comprises a series of upper electrodes 9 and a series of lower electrodes 1 0 located on each side of the belt conveyor 5 to irradiate the opposite surfaces of the hides P.
- the upper electrodes 9 and the lower electrodes 1 0 have such a size as to ensure substantially complete drying of the first finishing layer S'.
- the irradiator 8 will be adjusted to ensure extraction of at least an amount of liquid ranging from 5 to 20 g/inch 2 .
- a second drying apparatus 1 ' substantially identical to the first 1 is located downstream from the second finishing unit R2, and is adjusted to ensure extraction of at least an amount of liquid ranging from 3 to 30 g/inch 2 .
- the finishing liquids are known to be aqueous solutions of organic and pigmenting products, representing about 20% to 40%, preferably about 25% to 30% based on the total weight of the solution.
- the organic component of the finishing layer deposited on the hide is almost instantaneously dried and cross-linked, and forms some sort of impermeable film on the grain side. Therefore, the interfibrillar water molecules cannot come out of the grain side, due to the presence of the impermeable film, and are forced to penetrate the leather fibers in the downward direction, to come out of the flesh side, where not impermeable barrier exists. Such penetration actually provides a one-way pumping effect toward the side opposite to the finishing side.
- Such one-way pumping of water molecules was surprisingly found to open out the fibers and to impart superior softness to the hide, as well as a hand that avoids crutch staking.
- the overall power consumption will be about 1 electric kW per liter of extracted water.
- the method comprises at least one step a) of substantially evenly applying a first layer S' of a finishing product solution on one surface of the hides.
- This step is followed by at least one second step c) of evenly distributing a second layer S" of a liquid fixing agent on the first layer S', for stabilizing and protecting the first layer S'.
- the drying method comprises, after each of the steps a) of applying the first layer S' and b) of distributing the second layer S", a first step b) and a second step d) of irradiating the wet portion of the hides P with an alternating electromagnetic field whose frequency is within the RF range, for substantially complete drying of said first and said second layers.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Drying Of Solid Materials (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Coloring (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000338A ITVI20120338A1 (en) | 2012-12-19 | 2012-12-19 | METHOD AND EQUIPMENT FOR SKIN DRYING DURING THE FINISHING PROCESS |
PCT/IB2012/057798 WO2014096910A1 (en) | 2012-12-19 | 2012-12-28 | Method and apparatus for drying hides during the finishing process |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2935631A1 true EP2935631A1 (en) | 2015-10-28 |
EP2935631B1 EP2935631B1 (en) | 2016-11-16 |
Family
ID=47633498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12829162.2A Active EP2935631B1 (en) | 2012-12-19 | 2012-12-28 | Method and apparatus for drying hides during the finishing process |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP2935631B1 (en) |
KR (1) | KR101940852B1 (en) |
CN (1) | CN105008552B (en) |
BR (1) | BR112015014689B1 (en) |
ES (1) | ES2613762T3 (en) |
IT (1) | ITVI20120338A1 (en) |
MX (1) | MX364843B (en) |
PT (1) | PT2935631T (en) |
WO (1) | WO2014096910A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200094158A (en) * | 2017-11-30 | 2020-08-06 | 오피시네 디 카르티글리아노 에스.피.에이. | Plant for drying pre-treated flexible sheet products |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT201700037050A1 (en) * | 2017-04-04 | 2018-10-04 | Ge Ma Ta Spa | APPARATUS FOR THE CONTINUOUS DEPOSITION OF TWO DIFFERENT CHEMICAL SUBSTANCES ON A SKIN AND A CONTINUOUS DEPOSITION METHOD |
RU2655770C1 (en) * | 2017-04-24 | 2018-05-29 | Государственное бюджетное образовательное учреждение высшего образования Нижегородский государственный инженерно-экономический университет (НГИЭУ) | Super high frequency installation with portable cylindrical resonators for drying down and fur material continuously |
RU2651593C1 (en) * | 2017-04-24 | 2018-04-23 | Государственное бюджетное образовательное учреждение высшего образования Нижегородский государственный инженерно-экономический университет (НГИЭУ) | Aerodynamic dryer of down and fur raw material with the influence of electromagnetic field of super high frequency |
RU2651594C1 (en) * | 2017-04-25 | 2018-04-23 | Государственное бюджетное образовательное учреждение высшего образования Нижегородский государственный инженерно-экономический университет (НГИЭУ) | Microwave drier of down and fur raw materials of the rotor type |
RU2655748C1 (en) * | 2017-07-03 | 2018-05-29 | Государственное бюджетное образовательное учреждение высшего образования Нижегородский государственный инженерно-экономический университет (НГИЭУ) | Microwave installation providing fur separation from the skin of rabbit hides |
IT201900025135A1 (en) * | 2019-12-20 | 2021-06-20 | Ge Ma Ta Spa | DRYING TUNNEL OF THE CHEMICAL FILM DEPOSITED ON THE SKIN SURFACE IN THE PHASE OF FINISHING THE SKIN ITSELF AND A LEATHER FINISHING LINE THAT INCLUDES SAID DRYING TUNNEL |
IT202000010873A1 (en) * | 2020-05-13 | 2021-11-13 | Todesco S R L | METHOD, PLANT AND STATION FOR THE PROCESSING OF ANIMAL SKINS |
CN116287483B (en) * | 2023-03-23 | 2024-02-13 | 重庆能源职业学院 | Drying equipment with reciprocating motion structure |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3521061A1 (en) * | 1985-06-12 | 1986-12-18 | Dokoupil, Jiří, Dipl-Ing., 6251 Gückingen | METHOD AND DEVICE FOR CONDITIONING LEATHER, FURS, FURS AND THE LIKE. |
FR2617064B1 (en) * | 1987-06-23 | 1991-06-14 | Centre Tech Cuir Chaussure | PROCESS AND INSTALLATION FOR AUTOMATIC FINISHING OF FLEXIBLE MATERIALS, IN PARTICULAR LEATHERS OR SKINS, WHOLE OR CUT |
DE3838370C2 (en) * | 1988-11-11 | 1993-10-07 | Joachim Spahrmann | Device for drying leather or the like |
DE3915042A1 (en) * | 1989-05-08 | 1990-11-15 | Dokoupil Jiri | METHOD AND DEVICE FOR MACHINING SOFT-FLEXIBLE FLAT MATERIAL PIECES |
IT1278907B1 (en) * | 1995-04-27 | 1997-11-28 | Gidue Srl | METHOD FOR THE MOBILIZATION OF SKINS AND IMPLANT SUITABLE TO REALIZE THIS METHOD OF ENABLING |
DK1321731T3 (en) * | 2001-12-22 | 2006-11-13 | Moletherm Holding Ag | Energy transmitter as a component of a coating and / or drying plant, especially for a lacquer coating |
DE10211293A1 (en) * | 2002-03-14 | 2003-09-25 | Basf Ag | Process for automated surface control and surface correction |
WO2006015978A1 (en) * | 2004-08-10 | 2006-02-16 | Tfl Ledertechnik Gmbh | Water-repellent and self-cleaning leather |
DE102005001683B4 (en) * | 2005-01-13 | 2010-01-14 | Venjakob Maschinenbau Gmbh & Co. Kg | Method and device for drying lacquer layers |
ITVI20050081A1 (en) * | 2005-03-23 | 2006-09-24 | Cos T A Srl | METHOD FOR FINISHING A SKIN OR A LAMINAR ELEMENT AND ITS PLANT |
ITVI20090251A1 (en) * | 2009-10-16 | 2011-04-17 | Feltre Srl | PERFECT DRYING SYSTEM |
-
2012
- 2012-12-19 IT IT000338A patent/ITVI20120338A1/en unknown
- 2012-12-28 EP EP12829162.2A patent/EP2935631B1/en active Active
- 2012-12-28 PT PT128291622T patent/PT2935631T/en unknown
- 2012-12-28 MX MX2015007924A patent/MX364843B/en active IP Right Grant
- 2012-12-28 CN CN201280078219.2A patent/CN105008552B/en active Active
- 2012-12-28 ES ES12829162.2T patent/ES2613762T3/en active Active
- 2012-12-28 WO PCT/IB2012/057798 patent/WO2014096910A1/en active Application Filing
- 2012-12-28 KR KR1020157019373A patent/KR101940852B1/en active IP Right Grant
- 2012-12-28 BR BR112015014689-9A patent/BR112015014689B1/en active IP Right Grant
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20200094158A (en) * | 2017-11-30 | 2020-08-06 | 오피시네 디 카르티글리아노 에스.피.에이. | Plant for drying pre-treated flexible sheet products |
Also Published As
Publication number | Publication date |
---|---|
PT2935631T (en) | 2017-02-03 |
BR112015014689B1 (en) | 2021-03-30 |
CN105008552A (en) | 2015-10-28 |
MX364843B (en) | 2019-05-08 |
ES2613762T3 (en) | 2017-05-25 |
MX2015007924A (en) | 2016-02-05 |
KR20150096512A (en) | 2015-08-24 |
CN105008552B (en) | 2017-08-22 |
EP2935631B1 (en) | 2016-11-16 |
WO2014096910A1 (en) | 2014-06-26 |
ITVI20120338A1 (en) | 2014-06-20 |
KR101940852B1 (en) | 2019-01-21 |
BR112015014689A2 (en) | 2017-07-11 |
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