EP2914385B1 - Verfahren zum beschichten von objekten - Google Patents

Verfahren zum beschichten von objekten Download PDF

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Publication number
EP2914385B1
EP2914385B1 EP13829035.8A EP13829035A EP2914385B1 EP 2914385 B1 EP2914385 B1 EP 2914385B1 EP 13829035 A EP13829035 A EP 13829035A EP 2914385 B1 EP2914385 B1 EP 2914385B1
Authority
EP
European Patent Office
Prior art keywords
liquid rubber
layer
film
acrylic
diluted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13829035.8A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2914385A1 (de
Inventor
David Zbrodov
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Zbrodov David
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Individual
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Publication of EP2914385A1 publication Critical patent/EP2914385A1/de
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/57—Three layers or more the last layer being a clear coat
    • B05D7/574—Three layers or more the last layer being a clear coat at least some layers being let to dry at least partially before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/56—Three layers or more
    • B05D7/58—No clear coat specified
    • B05D7/584—No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2530/00—Rubber or the like

Definitions

  • the invention relates to a method for coating objects, in particular vehicles and vehicle parts, to a film coating which can be peeled off or sprayed over again after use, and to a vehicle provided with a film coating.
  • Coatings without spray processes are also known, in which coated films are applied to a substrate, for example to a motor vehicle body.
  • the films can be provided on one side with one or more coating layers and can have an adhesive layer on the same or the other side, so that the film can be fixed on the substrate.
  • the foils can be laminated onto the substrate so that they remain fixed on the substrate.
  • a “process for producing color coatings” is known ( DE 603 04 093 T2 ), in which a color coating layer in the form of an outer coating layer is proposed.
  • the coating layer is part of a multi-layer coating and comprises a thermosetting coating composition while avoiding the spray application. It has no separate adhesive layer and no carrier layer, such as a film.
  • the substrate in particular provided with a precoat, is coated with the additional coating layer, which is applied from a thermosetting coating composition and thermoset.
  • a sprayable coating system containing linear polymers is proposed. This is intended to provide vehicles with a weatherproof coating in order to protect them from corrosion and mechanical influences, but to be removable again after a period of time.
  • polymers are used which are used for film coating using liquid or fat-like plasticizers of the alkyd resin type. The coating system is applied to the object to be coated and then the film-forming liquid film is dried to form a film with uncrosslinked, soluble polymers. This creates peelable films.
  • the JP 2000 070839 A discloses a "temporary coating of the color change technique".
  • a releasable aqueous coating agent which forms a releasable film is formed using an emulsion coating material made of rubber, styrene, butadiene rubber, isoprene rubber, chloroprene rubber, nitrile-butadiene rubber, silicone rubber, fluororubber, urethane rubber, acrylic rubber, or a derivative thereof.
  • a top coating material which contains a color pigment and a metal pigment and has at least 50% spread rate of a formed film to form a releasable composite film.
  • the US 6 126 989 B1 shows a "urethane acrylic rubber coating and method for producing a vehicle bed interior paneling".
  • a method for forming an elastic rubber-based coating is described.
  • the first step in the process is to provide a water-curable liquid rubber and a water-based acrylic polymer.
  • the rubber and the acrylic polymer are then combined to form a hardening rubber-acrylic composite.
  • This curing rubber-acrylic composite is applied to the surface of a substrate and can be at a temperature in the range of 35 ° F. up to 110 ° F. fully cure to form a rubber-based coating.
  • the US 6,964,989 B1 shows a "peelable coating composition”.
  • This disclosure generally relates to water-resistant, peelable protective and decorative, clear or pigmented coating compositions, and more particularly to solvent and water-based polymeric coating compositions that form a protective and / or decorative coating on a variety of substrates, including automotive paints, metals , Plastics, concrete, natural and synthetic elastomers and ceramics.
  • the WO 2008/097415 A2 describes "peelable coating compositions".
  • a composition for forming a peelable coating is disclosed, the composition comprising an aqueous carrier, a water dispersible polyvinyl butyral and an acrylic latex compound.
  • This coating does not produce a color effect similar to that of the usual color coating.
  • the film has little adhesive force, so that it is only suitable for short-term use as a protective cover.
  • a method for coating objects, in particular vehicles and vehicle parts, a film coating that can be peeled off or sprayed over again after use, and a vehicle provided with the film coating are proposed.
  • the vehicle is sprayed to produce a film coating.
  • a liquid rubber is used, which is applied to the vehicle in several layers.
  • Layer by layer a "rubber film” is built up, which in the finished state is indistinguishable from normal painting and can be removed completely and without residue.
  • This process is suitable for application to the basecoat of the vehicle.
  • This coating can be made transparent or combined with color pigments, so that matt or glossy transparent or colored coatings are achieved.
  • the ideal processing conditions are an air temperature of + 10 ° C or more and up to 75% relative humidity.
  • a transparent film colored by the application of water-based paint with a matt finish, is formed. All colors that can be produced on a water basis can be achieved.
  • the vehicle provided with the film coating according to the invention from the liquid rubber layers can additionally be sprayed with a single-layer paint.
  • a single-layer paint This allows the underlying film to be colored.
  • a glossy or a matt single-layer lacquer can be applied.
  • the film is applied in several layers by spraying and drying, then the single-layer lacquer is applied to the film coating, in particular sprayed on.
  • the desired color and finish are obtained.
  • This embodiment has the Advantage that the sealing is finished with the application of the one-coat lacquer, no further layer (clear lacquer) is necessary.
  • All of the exemplary embodiments can also be modified in an alternative embodiment, the application of the plastic bonding agent being omitted and a different clear lacquer being applied instead.
  • the clearcoat is designed so that it forms a connection with the film without a plastic adhesive.
  • the clear coat is preferably a scratch-resistant 2K-HS acrylic clear coat based on reflow technology. This clear coat has a high resistance to micro scratches and chemicals. It is VOC compliant.
  • the clear coat used has in particular a spray viscosity of 20 to 22 s 4 mm DIN. It can be applied with spray nozzles from 1.2 to 1.4 mm at pressures between 2 - 3 bar with an internal nozzle pressure of 0.7 bar.
  • the layer thickness of the dry film is 50 to 60 ⁇ m.
  • the drying time is between 5 min and 24 h.
  • the clear coats used are acid, base and pollutant resistant.
  • Hardeners can be added in various proportions, e.g. Clear varnish hardener Vol. 2: 1 to 3: 1.
  • the hardeners usually contain aliphatic polyisocyanates.
  • Colorless additives can be used as additives to increase the elasticity of clearcoats, e.g. Plasticizers, come. This is particularly advantageous when processing deformable plastic parts.
  • the additives are colorless and are used in a mixing ratio of 10 - 50% additions to the base coat.
  • the drying time using the additives may increase by up to 100%.
  • the coloring can be done with matt water-based lacquer or matt acrylic lacquer.
  • the clear varnish is applied over the top for sealing.
  • the coloring can also be done with a single-layer lacquer. This one-layer lacquer automatically seals the sprayed film. It can be matt or glossy.
  • the liquid rubber used is a rubber based on rubber, is elastic, resistant and easy to process.
  • the rubber can be natural or synthetic rubber and is vulcanized.
  • additives such as vulcanization accelerators or retarders, fillers, organic solvents, antioxidants and / or antiozonants are usually added to improve the durability and processability.
  • Synthetic materials such as silicones, that is to say poly (organo) siloxanes, in particular silicone rubbers, can also be used.
  • Silicone rubbers are masses which can be converted into the rubber-elastic state and contain poly (organo) siloxanes which have groups which are accessible to crosslinking reactions.
  • the process according to the invention has a further positive benefit: the film seals and protects the underlying basecoat from scratches, the effects of weather, stone chips and other signs of wear, thereby preserving the value of the vehicle. Rims or other vehicle parts treated according to the procedure are also protected against salts in winter.
  • the coloring can be designed specifically according to customer requirements. For example, colors, e.g. Acrylic-based paints or solvent-based paints can be mixed with liquid rubber and single-layer paint. Special color designs are also possible, for example phosphorescent coatings that re-emit light in the dark for hours. Furthermore, fluorescent effects can be achieved, which become visible, for example, when they are exposed to UV radiation.
  • colors e.g. Acrylic-based paints or solvent-based paints can be mixed with liquid rubber and single-layer paint.
  • Special color designs are also possible, for example phosphorescent coatings that re-emit light in the dark for hours.
  • fluorescent effects can be achieved, which become visible, for example, when they are exposed to UV radiation.
  • the film can easily be pulled off again and a new coloring of the vehicle or of the parts can be applied by means of the method according to the invention.
  • a vehicle or part already provided with a film according to the invention can be provided with another film according to the invention without pulling off the existing film.
  • the "new” film can be sprayed directly onto the existing film. For example, a car sprayed in "red” today could be sprayed with "black” tomorrow.
  • Fig. 1 represents a schematic sequence of the method.
  • the surface to be treated is cleaned and degreased beforehand. Parts that are not to be machined may be taped off.
  • the liquid rubber which is diluted for better processability.
  • the liquid rubber can be colored with color additives. At least one layer of the liquid rubber is sprayed on, an application of four to seven layers of liquid rubber has proven to be suitable for forming a film coating. There is a drying phase after each order.
  • the resulting film coating is then sealed.
  • a single-layer lacquer can be used to seal the liquid rubber layers.
  • the single-layer lacquer can achieve the desired result by adding colors or its formation (matt / clear).

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
EP13829035.8A 2012-10-16 2013-10-16 Verfahren zum beschichten von objekten Active EP2914385B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012020197 2012-10-16
PCT/DE2013/000603 WO2014059963A1 (de) 2012-10-16 2013-10-16 Verfahren zum beschichten von objekten

Publications (2)

Publication Number Publication Date
EP2914385A1 EP2914385A1 (de) 2015-09-09
EP2914385B1 true EP2914385B1 (de) 2020-04-15

Family

ID=50097521

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13829035.8A Active EP2914385B1 (de) 2012-10-16 2013-10-16 Verfahren zum beschichten von objekten

Country Status (5)

Country Link
EP (1) EP2914385B1 (da)
DE (2) DE202013011985U1 (da)
DK (1) DK2914385T3 (da)
HU (1) HUE052296T2 (da)
WO (1) WO2014059963A1 (da)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022083522A (ja) * 2020-11-25 2022-06-06 トヨタ自動車株式会社 塗装システム

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4110135A1 (de) 1991-03-27 1992-10-01 Windmoeller & Hoelscher Verfahren und vorrichtung zur bestimmung der von einem extruder aus einem aufgabebehaelter ueber die zeit abgezogenen menge
US6126999A (en) * 1998-04-13 2000-10-03 Tomasino; Randolf R. Urethane-acrylic rubber coating and method of forming a vehicle bed liner
US6964989B1 (en) * 1998-07-08 2005-11-15 Ashland Inc. Peelable coating composition
JP2000070839A (ja) * 1998-09-02 2000-03-07 Kansai Paint Co Ltd 一時的塗色変更工法
US7351446B2 (en) 2002-10-17 2008-04-01 E.I. Du Pont De Nemours & Company Process for the production of paint coating layers
WO2008097415A2 (en) * 2007-02-08 2008-08-14 Valspar Sourcing, Inc. Peel-coat compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Also Published As

Publication number Publication date
DK2914385T3 (da) 2020-07-27
DE202013011985U1 (de) 2014-12-08
EP2914385A1 (de) 2015-09-09
DE102013017164A1 (de) 2014-04-17
WO2014059963A1 (de) 2014-04-24
HUE052296T2 (hu) 2021-05-28

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