EP2878657B1 - Améliorant d'indice de viscosité à base de poly(méth)acrylate, et composition d'huile lubrifiante et additif pour huile lubrifiante le contenant - Google Patents

Améliorant d'indice de viscosité à base de poly(méth)acrylate, et composition d'huile lubrifiante et additif pour huile lubrifiante le contenant Download PDF

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Publication number
EP2878657B1
EP2878657B1 EP13823599.9A EP13823599A EP2878657B1 EP 2878657 B1 EP2878657 B1 EP 2878657B1 EP 13823599 A EP13823599 A EP 13823599A EP 2878657 B1 EP2878657 B1 EP 2878657B1
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EP
European Patent Office
Prior art keywords
viscosity index
meth
index improver
acrylate
poly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP13823599.9A
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German (de)
English (en)
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EP2878657A4 (fr
EP2878657A1 (fr
Inventor
Shigeki Matsui
Hiroya Miyamoto
Hiromitsu Matsuda
Kazuo Tagawa
Akira Takagi
Ryuichi Ueno
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Eneos Corp
Original Assignee
JX Nippon Oil and Energy Corp
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Priority claimed from JP2013142014A external-priority patent/JP6018981B2/ja
Priority claimed from JP2013142036A external-priority patent/JP6018982B2/ja
Application filed by JX Nippon Oil and Energy Corp filed Critical JX Nippon Oil and Energy Corp
Publication of EP2878657A1 publication Critical patent/EP2878657A1/fr
Publication of EP2878657A4 publication Critical patent/EP2878657A4/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/68—Shear stability
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Definitions

  • the present invention relates to a poly(meth)acrylate-based viscosity index improver, a lubricating oil additive and a lubricating composition containing the viscosity index improver.
  • lubricating oils used for internal combustion engines such as a vehicle engine (also referred to as “lubricating oils for an internal combustion engine” or “engine oils”)
  • a method of increasing a viscosity index of a lubricating oil by adding a viscosity index improver to a lubricating base oil has been known.
  • lubricating oils used for transmissions of vehicles such as ATF, MTF, and CVTF (also referred to as “lubricating oils for a transmission” or “drive system oils”)
  • ATF lubricating oils for a transmission
  • CVTF also referred to as "lubricating oils for a transmission” or “drive system oils”
  • the viscosity of a lubricating oil for a transmission is lowered, other problems such as oil leak and seizure may arise.
  • a method for improving a fuel saving property there is a method involving use of a viscosity index improver.
  • This method increases the viscosity index of a lubricating oil for a transmission by using a viscosity index improver, and suppresses the viscosity increase in a low-temperature region while maintaining the viscosity in a high-temperature region.
  • a viscosity index improver the use of various viscosity index improvers has been proposed, and in particular, the use of poly(meth)acrylate-based viscosity index improvers has been often proposed (for example, refer to Patent Literatures 1 to 7).
  • WO 2007/127660 A1 relates to a lubricating composition
  • a lubricating composition comprising (a) a polymer derived from greater than 50 wt % or more of a non-diene monomer, wherein the polymer has a weight-average molecular weight of about 2000 to about 200,000, and wherein the polymer has a shear stability index of about 0 to about 25; (b) a phosphorus-containing acid, salt, or ester; (c) an extreme pressure agent, other than a phosphorus-containing acid, salt, or ester; and (d) an oil of lubricating viscosity.
  • WO 2007/127615 A2 discloses a lubricating composition
  • a lubricating composition comprising (a) about 0.1 to about 15 wt % of a polymer with (i) a weight-average molecular weight of about 100,000 to about 500,000; and (ii) a shear stability index of about 10 to about 60; (b) a phosphorus-containing acid, salt, or ester; (c) a dispersant; and (d) an oil of lubricating viscosity.
  • US 2012/046207 A1 relates to a poly(meth)acrylate-based viscosity index improver and lubricating oil compositions comprising same.
  • the index improver comprises structural units of formula 1 with R 1 being methyl and R 2 being a C12-C15 alkyl, having an average molecular weight of 69,000-82,700 g/mol.
  • WO 2012/076676 A1 discloses a viscosity index improver comprising a polyalkyl(meth)acrylate polymer characterized in that the polyalkyl(meth)acrylate polymer comprises a polydispersity Mw/Mn in the range of 1.05 to 2.0.
  • US 2009/221461 A1 relates to a polymer according to Formula (I) with specific pendant groups, further to a lubricating composition containing said polymer, and to a method and use of controlling viscosity index by supplying to an oil of lubricating viscosity the polymer with pendant groups.
  • US 2011/237477 A1 relates to a hydrocarbon-based lubricating base oil comprising as an additive a viscosity index improver.
  • Said index improver is a poly(meth)acrylate-based viscosity index improver wherein the molecular weight is more than 100000 and wherein the polymer chain contains 10 mol% of units with an alkyl group of 22 carbon atoms.
  • the above-described conventional viscosity index improvers attempt to improve a viscosity property in a high-temperature region and a low-temperature region by improving the viscosity index, and they are not considered to be sufficient in terms of a friction loss decreasing effect.
  • an object of the present invention is to provide a viscosity index improver capable of achieving a fuel saving property, a lubricating oil additive and a lubricating composition containing the viscosity index improver.
  • another object of the present invention is to provide a viscosity index improver capable of sufficiently lowering a high shear viscosity at 100°C while maintaining a high shear viscosity at 150°C, a lubricating oil additive and a lubricating composition containing the viscosity index improver.
  • the present inventors made extensive research and found that a poly(meth)acrylate-based viscosity index improver which has a specific structure and in which the weight-average molecular weight, and the ratio of the weight-average molecular weight Mw to the number average molecular weight Mn, Mw/Mn satisfy specific conditions can sufficiently lower a high shear viscosity at 100°C while maintaining a high shear viscosity at 150°C, which leads to accomplish the present invention.
  • the present invention provides a poly(meth)acrylate-based viscosity index improver consisting of a polymer chain comprising a structural unit represented by the following formula (1), wherein the weight-average molecular weight Mw is 100000 or more and 500000 or less, and the ratio of the weight-average molecular weight Mw to the number average molecular weight Mn, Mw/Mn, is 1.6 or less wherein R 1 represents hydrogen or a methyl group, and R 2 represents a C1 to C36 alkyl group, and wherein the polymer chain contains 20 to 45 mass% or more of the structural unit in which R 2 is a methyl group, and wherein the polymer chain contains 20 mass% or more of the structural unit in which R 2 is an alkyl group having 18 or more carbon atoms, based on the total amount of the structural units contained in the polymer chain.
  • the weight-average molecular weight Mw is 100000 or more and 500000 or less
  • the present invention provides a lubricating oil additive comprising the above-described poly(meth)acrylate-based viscosity index improver.
  • the present invention provides a lubricating composition
  • a lubricating composition comprising a lubricating base oil, and the above-described poly(meth)acrylate-based viscosity index improver.
  • a viscosity index improver capable of achieving a fuel saving property, a lubricating oil additive and a lubricating composition containing the viscosity index improver are provided.
  • a viscosity index improver capable of sufficiently lowering a high shear viscosity at 100°C while maintaining a high shear viscosity at 150°C, a lubricating oil additive and a lubricating composition containing the viscosity index improver can be provided.
  • a poly(meth)acrylate-based viscosity index improver comprises a polymer chain containing a structural unit represented by the following formula (1).
  • the weight-average molecular weight Mw (hereinafter, just referred to as "Mw” in some cases) of the poly(meth)acrylate-based viscosity index improver is 100000 or more, and the ratio of the weight-average molecular weight Mw to the number average molecular weight Mn (hereinafter, just referred to as "Mn” in some cases), Mw/Mn (hereinafter, just referred to as "Mw/Mn” in some cases), is 1.6 or less.
  • R 1 represents hydrogen or a methyl group
  • R 2 represents a C1 to C36 alkyl group.
  • R 1 may be either hydrogen or a methyl group, and is preferably a methyl group.
  • the number of carbon atoms of the alkyl group represented by R 2 is 1 to 36 as described above, preferably 1 to 30, more preferably 1 to 26, and further preferably 1 to 22 from the viewpoint of handleability and ease of manufacture.
  • the alkyl group represented by R 2 may be straight-chain or branched.
  • R 1 s and R 2 s may be the same or different between the respective structural units.
  • the polymer chain contains 20 to 45 mass% of the structural unit in which R 2 is a methyl group, based on the total amount of the structural units contained in the polymer chain.
  • the polymer chain contains 20 mass% or more of the structural unit in which R 2 is an alkyl group having 18 or more carbon atoms, based on the total amount of the structural units contained in the polymer chain.
  • the polymer chain may contain only the structural unit represented by the above formula (1), or may further contain a structural unit other than the structural unit represented by the above formula (1) in addition to the structural unit represented by the above formula (1).
  • terminals of the polymer chain are not particularly limited.
  • a polymer chain containing only the structural unit represented by the above formula (1), whose terminals are hydrogen atoms, that is, a polymer chain represented by the following formula (2) is preferable.
  • R 1 represents hydrogen or a methyl group
  • R 2 represents a C1 to C36 alkyl group
  • n represents an integer selected such that the Mw and the Mw/Mn satisfy the above-described conditions.
  • n is an integer of 400 to 2000.
  • the weight-average molecular weight Mw is 100000 or more, and it is preferably 125000 or more, more preferably 150000 or more, and further preferably 175000 or more from the viewpoint of a fuel saving property.
  • the upper limit of Mw is 500000 or less.
  • the number average molecular weight Mn is arbitrarily selected such that the Mw/Mn satisfies the above-described condition.
  • the Mn is preferably 75000 or more, more preferably 94000 or more, and further preferably 110000 or more from the viewpoint of lowering the HTHS viscosity at 100°C.
  • the upper limit of Mn is not particularly limited, and the Mn is, for example, 300000 or less.
  • the Mw/Mn is 1.6 or less, and it is preferably 1.5 or less, more preferably 1.4 or less, and further preferably 1.2 or less from the viewpoint of a fuel saving property. Moreover, from the viewpoint of the yield of poly(meth)acrylate, the Mw/Mn is preferably 1.0 or more, more preferably 1.01 or more, and further preferably 1.02 or more.
  • the weight-average molecular weight Mw mean Mw, Mn, and Mw/Mn (converted values with polystyrene (standard sample)) obtained by GPC analysis. Specifically, they are measured as follows, for example.
  • a solution whose sample concentration is 2 mass% is prepared by dilution using tetrahydrofuran as a solvent.
  • the sample solution is analyzed using GPC equipment (Waters Alliance2695).
  • the analysis is carried out at the flow rate of the solvent of 1 ml/min, by using a column whose analyzable molecular weight is 10000 to 256000, and a refractive index as a detector. It is to be noted that the relationship between the column retention time and the molecular weight is determined using a polystyrene standard whose molecular weight is clear and a calibration curve is separately made, and after that, the molecular weight is determined from the obtained retention time.
  • the manufacturing method of the poly(meth)acrylate-based viscosity index improver according to the present embodiment is not particularly limited, examples thereof include a method in which an initiator is added to a mixed solution containing an alkyl(meth)acrylate, a polymerization reagent, and a solvent to polymerize the alkyl(meth)acrylate at predetermined temperature.
  • alkyl(meth)acrylate an alkyl(meth)acrylate represented by the following formula (3) can be used.
  • R 1 represents hydrogen or a methyl group
  • R 2 represents a C1 to C36 alkyl group.
  • R 1 is preferably a methyl group.
  • the number of carbon atoms of the alkyl group represented by R 2 is preferably 1 to 30, more preferably 1 to 26, and further preferably 1 to 22.
  • one of the alkyl(meth)acrylate represented by the above formula (3) can be used alone, or two or more thereof can be mixed to be used, and preferably, two or more thereof are mixed to be used.
  • the content of methyl(meth)acrylate in which R 2 is a methyl group is preferably 5 to 50 mass%, more preferably 10 to 50 mass%, and further preferably 20 to 45 mass% based on the total amount of the alkyl(meth)acrylate.
  • the content of an alkyl(meth)acrylate in which R 2 is an alkyl group having 18 or more carbon atoms is preferably 10 mass% or more, more preferably 15 mass% or more, and further preferably 20 mass% or more based on the total amount of the alkyl(meth)acrylate.
  • polymerization reagent for example, compounds having a thiocarbonyl group, such as cumyl dithiobenzoic acid, can be used.
  • examples of a preferred polymerization reagent include cumyl dithiobenzoic acid.
  • solvent for example, highly-refined mineral oils, anisole, and toluene can be used.
  • examples of a preferred solvent include highly-refined mineral oils.
  • azobisisobutyronitrile for example, azobisisobutyronitrile, azobismethylvaleronitrile, and azobismethylbutyronitrile can be used.
  • examples of a preferred initiator include azobisisobutyronitrile.
  • the reaction temperature when polymerizing the alkyl(meth)acrylate is preferably 70 to 120°C, more preferably 80 to 110°C, and further preferably 90 to 100°C.
  • the Mw/Mn of the obtained poly(meth)acrylate-based viscosity index improver becomes easy to be 1.6 or less.
  • the reaction temperature is 90 to 100°C
  • the Mw/Mn tends to be 1.0 to 1.2
  • the reaction temperature is 100 to 110°C
  • the Mw/Mn tends to be 1.2 to 1.4
  • the reaction temperature is 110 to 120°C
  • the Mw/Mn tends to be 1.4 to 1.6.
  • the reaction time can be arbitrarily selected in accordance with the kinds and the amounts used of the alkyl(meth)acrylate, the polymerization reagent, the solvent, and the initiator, which are raw materials, reaction conditions such as a reaction temperature, and desired Mw and Mw/Mn of the poly(meth)acrylate.
  • Examples of preferred reaction time include 10 to 14 hours.
  • the polymerization of the alkyl(meth)acrylate is preferably carried out in a nitrogen atmosphere.
  • a lubricating oil additive according to the second embodiment of the present invention contains a poly(meth)acrylate-based viscosity index improver comprising a polymer chain containing a structural unit represented by the above formula (1), wherein the weight-average molecular weight Mw is 100000 or more, and the ratio of the weight-average molecular weight Mw to the number average molecular weight Mn, Mw/Mn, is 1.6 or less.
  • the poly(meth)acrylate-based viscosity index improver in the present embodiment is the same as the viscosity index improver in the above-described first embodiment, and an overlapping explanation is omitted here.
  • the lubricating oil additive may consist of only the above-described poly(meth)acrylate-based viscosity index improver, or may be a mixture of the viscosity index improver and other additives (that is, additive composition).
  • the mixing ratio thereof is not particularly limited and can be arbitrarily selected depending on the intended use.
  • additives such as viscosity index improvers other than the above-described poly(meth)acrylate-based viscosity index improver, antioxidants, antiwear agents (or extreme pressure agents), corrosion inhibitors, rust-preventive agents, viscosity index improvers, pour-point depressants, demulsifiers, metal deactivators, antifoamers, and ashless friction modifiers.
  • additives such as viscosity index improvers other than the above-described poly(meth)acrylate-based viscosity index improver, antioxidants, antiwear agents (or extreme pressure agents), corrosion inhibitors, rust-preventive agents, viscosity index improvers, pour-point depressants, demulsifiers, metal deactivators, antifoamers, and ashless friction modifiers.
  • additives such as viscosity index improvers other than the above-described poly(meth)acrylate-based viscosity index improver, antioxidants, antiwear agents (or extreme pressure agents),
  • Examples of the viscosity index improvers other than the above-described poly(meth)acrylate-based viscosity index improver include poly(meth)acrylate-based viscosity index improvers other than the above-described poly(meth)acrylate-based viscosity index improver, polyisobutene-based viscosity index improvers, ethylene-propylene copolymer-based viscosity index improvers, and styrene-butadiene hydrogenated copolymer-based viscosity index improvers.
  • antioxidants examples include ashless antioxidants such as phenolic or amine antioxidants, and metallic antioxidants such as zinc, copper, or molybdenum antioxidants.
  • phenolic antioxidants examples include 4,4'-methylenebis(2,6-di-tert-butylphenol), 4,4'-bis(2,6-di-tert-butylphenol), 4,4'-bis(2-methyl-6-tert-butylphenol), 2,2'-methylenebis(4-ethyl-6-tert-butylphenol), 2,2'-methylenebis(4-methyl-6-tert-butylphenol), 4,4'-butylidenebis(3-methyl-6-tert-butylphenol), 4,4'-isopropylidenebis(2,6-di-tert-butylphenol), 2,2'-methylenebis(4-methyl-6-nonyl phenol), 2,2'-isobutylidenebis(4,6-dimethylphenol), 2,2'-methylenebis(4-methyl-6-cyclohexylphenol), 2,6-di-tert-butyl-4-methylphenol, 2,6-di-tert-butyl
  • amine antioxidants examples include known amine antioxidants generally used for lubricating oils, such as aromatic amine compounds, alkyldiphenylamines, alkylnaphthylamines, phenyl- ⁇ -naphthylamine, and alkylphenyl- ⁇ -naphthylamines.
  • corrosion inhibitors examples include benzotriazole, tolyltriazole, thiadiazole, and imidazole compounds.
  • rust-preventive agents examples include petroleum sulfonates, alkylbenzene sulfonates, dinonylnaphthalene sulfonates, alkenylsuccinic acid esters, and polyhydric alcohol esters.
  • metal deactivators examples include imidazoline, pyrimidine derivatives, alkylthiadiazoles, mercaptobenzothiazole, benzotriazole or derivatives thereof, 1,3,4-thiadiazole polysulfide, 1,3,4-thiadiazolyl-2,5-bisdialkyldithiocarbamate, 2-(alkyldithio)benzimidazole, and ⁇ -(o-carboxybenzylthio)propionitrile.
  • antifoamers examples include silicone oil whose kinematic viscosity at 25°C is 1000 to 100000 mm 2 /s, alkenylsuccinic acid derivatives, esters of polyhydroxy aliphatic alcohols and long-chain fatty acids, methylsalicylate, and o-hydroxybenzyl alcohol.
  • ashless friction modifiers arbitrary compounds generally used as ashless friction modifiers for lubricating oils can be used, and examples thereof include ashless friction modifiers such as amine compounds, fatty acid esters, fatty acid amides, fatty acids, aliphatic alcohols, and aliphatic ethers, each of which has at least one alkyl group or alkenyl group having 6 to 30 carbon atoms, in particular straight-chain alkyl group or straight-chain alkenyl group having 6 to 30 carbon atoms in a molecule.
  • nitrogen-containing compounds and acid-modified derivatives thereof and the like described in Japanese Patent Application Laid-Open No. 2009-286831 and various ashless friction modifiers exemplified in International Publication No. WO 2005/037967 Pamphlet can also be used.
  • the lubricating oil additive according to the present embodiment may further contain a solvent.
  • a solvent highly-refined mineral oils, anisole, and toluene can be used. Among them, it is preferable to use highly-refined mineral oils.
  • the content of the solvent is preferably 5 to 75 mass%, and more preferably 30 to 60 mass% based on the total amount of the lubricating oil additive from the viewpoint of handling as an additive.
  • a lubricating composition according to the third embodiment contains a lubricating base oil, and the above poly(meth)acrylate-based viscosity index improver comprising a polymer chain containing a structural unit represented by the above formula (1), wherein the weight-average molecular weight Mw is 100000 or more and 500000 or less, and the ratio of the weight-average molecular weight Mw to the number average molecular weight Mn, Mw/Mn, is 1.6 or less.
  • the lubricating composition according to the present embodiment includes an aspect containing a lubricating base oil and the lubricating oil additive according to the above-described second embodiment.
  • the poly(meth)acrylate-based viscosity index improver in the present embodiment is the same as the poly(meth)acrylate-based viscosity index improvers in the above-described first embodiment and second embodiment, and furthermore, other additives and a solvent which can be contained in the lubricating composition are the same as the other additives and the solvent in the second embodiment, and an overlapping explanation is omitted here.
  • the lubricating base oil is not particularly limited, and lubricating base oils used for general lubricating oils can be used. Specifically, mineral lubricating base oils, synthetic lubricating base oils, a mixture in which two or more lubricating base oils selected therefrom are mixed at an arbitrary ratio and the like can be used.
  • mineral lubricating base oils examples include those obtained by refining a lubricating oil fraction obtained by reduced-pressure distillation of an atmospheric residue obtained by atmospheric distillation of a crude oil by carrying out one or more treatment, such as solvent deasphalting, solvent extraction, hydrocracking, solvent dewaxing, and hydrorefining, and base oils manufactured by a method of isomerizing wax-isomerized mineral oils and GTL waxes (gas-to-liquid waxes).
  • Examples of the synthetic lubricating oils include polybutene or hydrides thereof; poly- ⁇ -olefins such as 1-octene oligomer and 1-decene oligomer, or hydrides thereof; diesters such as ditridecyl glutarate, di-2-ethylhexyl adipate, diisodecyl adipate, ditridecyl adipate, and di-2-ethylhexyl sebacate; polyol esters such as trimethylolpropane caprylate, trimethylolpropane pelargonate, pentaerythritol-2-ethylhexanoate, and pentaerythritol pelargonate; aromatic synthetic oils such as alkylnaphthalenes and alkylbenzenes, and mixtures thereof.
  • the kinematic viscosity at 100°C of the lubricating base oil is preferably 2.5 to 10.0 mm 2 /s, more preferably 3.0 to 8.0 mm 2 /s, and further preferably 3.5 to 6.0 mm 2 /s.
  • the viscosity index of the lubricating base oil is preferably 90 to 165, more preferably 100 to 155, and further preferably 120 to 150.
  • the saturated component of the lubricating base oil by chromatography analysis is preferably 80% or more, more preferably 85% or more, further preferably 90% or more, and most preferably 95% or more so as to make it easy to exert an effect of additives such as the poly(meth)acrylate-based viscosity index improver according to the first embodiment.
  • the content of the poly(meth)acrylate-based viscosity index improver according to the first embodiment is preferably 0.1 to 20.0 mass%, more preferably 0.5 to 15.0 mass%, and further preferably 1.0 to 10.0 mass% based on the total amount of the lubricating composition.
  • the content is the above-described lower limit or more, a sufficient effect of addition becomes easy to be obtained, and on the other hand, when the content is the above-described upper limit or less, shear stability increases and fuel consumption sustainability is improved.
  • the kinematic viscosity at 100°C of the lubricating composition is preferably 3.0 to 16.3 mm 2 /s, more preferably 3.5 to 12.5 mm 2 /s, and further preferably 4.0 to 9.3 mm 2 /s.
  • a lubricating property becomes easy to be ensured
  • the kinematic viscosity at 100°C is the above-described upper limit or less
  • a fuel saving property is further improved.
  • the kinematic viscosity at 100°C in the present invention means a kinematic viscosity at 100°C defined by JIS K-2283-1993.
  • the viscosity index of the lubricating composition is preferably 150 to 250, more preferably 160 to 240, and further preferably 170 to 230.
  • the viscosity index is the above-described lower limit or more, a fuel saving property can be further improved, and moreover, the low-temperature viscosity becomes easy to be lowered while maintaining the HTHS viscosity.
  • the viscosity index is the above-described upper limit or less, low-temperature fluidity, solubility of additives, and compatibility with a sealing material can be ensured.
  • the viscosity index in the present invention means a viscosity index defined by JIS K 2283-1993.
  • the HTHS viscosity at 150°C of the lubricating composition is preferably 1.7 mPa ⁇ s or more, more preferably 2.0 mPa ⁇ s or more, further preferably 2.3 mPa ⁇ s or more, and most preferably 2.6 mPa ⁇ s or more.
  • the HTHS viscosity at 150°C is the above-described lower limit or more, evaporation of the lubricating composition can be suppressed, and a lubricating property can be ensured.
  • the HTHS viscosity at 100°C of the lubricating composition is preferably 5.2 mPa ⁇ s or less, more preferably 5.1 mPa ⁇ s or less, and further preferably 5.0 mPa ⁇ s or less.
  • the HTHS viscosity at 100°C is the above-described upper limit or less, a higher fuel saving property can be obtained.
  • the HTHS viscosity at 150°C or 100°C in the present invention means a high temperature high shear viscosity at 150°C or 100°C defined by ASTM D-4683.
  • the viscosity index improver according to the first embodiment, the lubricating oil additive according to the second embodiment, and the lubricating composition according to the third embodiment, which are described above, can be used in a wide range of fields such as lubricating oils for an internal combustion engine and drive system lubricating oils, and in particular, are useful in the field of lubricating oils for an internal combustion engine.
  • Fuel of the internal combustion engine in this case may be either gasoline or diesel fuel.
  • a poly(meth)acrylate-based viscosity index improver was synthesized in the following condition (designated as "Synthesis Condition 1-1").
  • the solution was cooled to 0°C on an ice bath, and vacuum deaeration/nitrogen purge of a reaction system was carried out 5 times using a diaphragm pump. Furthermore, from the sample inlet, as a radical initiator, 0.052 g of azobisisobutyronitrile (AIBN) was charged under nitrogen flow, and then, polymerization was carried out for 12 hours at the solution temperature of 110°C under a nitrogen atmosphere to obtain a solution containing a poly(meth)acrylate-based viscosity index improver.
  • AIBN azobisisobutyronitrile
  • the weight-average molecular weight Mw and the number average molecular weight Mn were measured by GPC analysis.
  • the weight-average molecular weight Mw was 230000
  • the number average molecular weight Mn was 152000
  • the Mw/Mn was 1.51.
  • the procedure of the GPC analysis is as follows.
  • a solution whose sample concentration is 2 mass% was prepared by dilution using tetrahydrofuran as a solvent.
  • the sample solution was analyzed using GPC equipment (Waters Alliance2695). The analysis was carried out at the flow rate of the solvent of 1 ml/min, by using a column whose analyzable molecular weight is 10000 to 256000, and a refractive index as a detector. It is to be noted that the relationship between the column retention time and the molecular weight was determined using a polystyrene standard whose molecular weight is definite and the molecular weight was determined from the obtained retention time based on the calibration curve which was separately made.
  • a poly(meth)acrylate-based viscosity index improver was synthesized in the following condition (designated as "Synthesis Condition 1-2").
  • the solution was cooled to 0°C with an ice bath, and vacuum deaeration/nitrogen purge of a reaction system was carried out 5 times using a diaphragm pump. Furthermore, from the sample inlet, as a radical initiator, 0.051 g of azobisisobutyronitrile (AIBN) was charged under nitrogen flow, and then, polymerization was carried out for 12 hours at the solution temperature of 100°C under a nitrogen atmosphere to obtain a solution containing a poly(meth)acrylate-based viscosity index improver.
  • AIBN azobisisobutyronitrile
  • Example 1-1 For the obtained poly(meth)acrylate-based viscosity index improver, GPC analysis was carried out in the same manner as Example 1-1, and as a result, the weight-average molecular weight Mw was 220000, the number average molecular weight Mn was 167000, and the Mw/Mn was 1.32.
  • a poly(meth)acrylate-based viscosity index improver was synthesized in the following condition (designated as "Synthesis Condition 1-3").
  • the solution was cooled to 0°C on an ice bath, and vacuum deaeration/nitrogen purge of a reaction system was carried out 5 times using a diaphragm pump. Furthermore, from the sample inlet, as a radical initiator, 0.055 g of azobisisobutyronitrile (AIBN) was charged under nitrogen flow, and then, polymerization was carried out for 12 hours at the solution temperature of 90°C under a nitrogen atmosphere to obtain a solution containing a poly(meth)acrylate-based viscosity index improver.
  • AIBN azobisisobutyronitrile
  • a poly(meth)acrylate-based viscosity index improver was synthesized in the following condition (designated as "Synthesis Condition 1-4").
  • a raw material in which 12 g of methyl methacrylate (C1-MA) and 18 g of stearyl methacrylate (C18-MA) as raw material monomers, and 0.12 g of azobisisobutyronitrile (AIBN) as a radical initiator are mixed was charged into the dropping funnel for introducing a sample, and the raw material was dropped in the reaction flask for 70 minutes. After that, polymerization was carried out for 8 hours at 85°C under nitrogen flow while maintaining stirring to obtain a solution containing a poly(meth)acrylate-based viscosity index improver. After that, unreacted monomers were removed from the above-described solution by carrying out vacuum distillation for 3 hours at 130°C and 1 mmHg.
  • AIBN azobisisobutyronitrile
  • Example 1-1 For the obtained poly(meth)acrylate-based viscosity index improver, GPC analysis was carried out in the same manner as Example 1-1, and as a result, the weight-average molecular weight Mw was 260000, the number average molecular weight Mn was 158000, and the Mw/Mn was 1.65.
  • a poly(meth)acrylate-based viscosity index improver was synthesized in the same manner as any of the above-described Synthesis Conditions 1-1 to 1-4 other than changing the amount of the raw material blended as shown in Tables 1, 3, 5, and 7.
  • C12-MA represents a compound in which R 1 and R 2 in the formula (3) are a methyl group and a dodecyl group (straight-chain alkyl group having 12 carbon atoms), respectively
  • C22-MA represents a compound in which R 1 and R 2 in the formula (3) are a methyl group and a docosanyl group (straight-chain alkyl group having 22 carbon atoms), respectively.
  • Mw, Mn, and Mw/Mn of the obtained poly(meth)acrylate-based viscosity index improver are shown in Tables 2, 4, 6, and 8.
  • a metallic (calcium sulfonate) cleaner an ashless dispersant (succinimide), a friction modifier (glycerin monooleate), and a wear inhibitor (zinc dithiophosphate)
  • a highly-refined mineral oil Group III base oil, kinematic viscosity at 100°C: 4.2

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Claims (3)

  1. Agent améliorant l'indice de viscosité à base de poly(méth)acrylate constitué d'une chaîne polymère comprenant un motif structural représenté par la formule (1) suivante,
    où une masse moléculaire moyenne en poids Mw est de 100 000 ou plus et 500 000 ou moins, et un rapport de la masse moléculaire moyenne en poids Mw sur une masse moléculaire moyenne en nombre Mn, Mw/Mn, est de 1,6 ou moins
    Figure imgb0008
     où R1 représente l'hydrogène ou un groupe méthyle et R2 représente un groupe alkyle en C1 à C36, et
    où la chaîne polymère contient de 20 à 45 % en masse ou plus du motif structural dans lequel R2 est un groupe méthyle, et où la chaîne polymère contient 20 % en masse ou plus du motif structural dans lequel R2 est un groupe alkyle ayant 18 atomes de carbone ou plus, sur la base de la quantité totale des motifs structuraux présents dans la chaîne polymère.
  2. Additif pour huile lubrifiante comprenant l'agent améliorant l'indice de viscosité à base de poly(méth)acrylate selon la revendication 1.
  3. Composition lubrifiante comprenant :
    une huile de base lubrifiante ; et
    l'agent améliorant l'indice de viscosité à base de poly(méth)acrylate selon la revendication 1.
EP13823599.9A 2012-07-24 2013-07-24 Améliorant d'indice de viscosité à base de poly(méth)acrylate, et composition d'huile lubrifiante et additif pour huile lubrifiante le contenant Not-in-force EP2878657B1 (fr)

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PCT/JP2013/070100 WO2014017558A1 (fr) 2012-07-24 2013-07-24 Améliorant d'indice de viscosité à base de poly(méth)acrylate, et composition d'huile lubrifiante et additif pour huile lubrifiante le contenant

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