EP2828504A1 - Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé - Google Patents

Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé

Info

Publication number
EP2828504A1
EP2828504A1 EP13710860.1A EP13710860A EP2828504A1 EP 2828504 A1 EP2828504 A1 EP 2828504A1 EP 13710860 A EP13710860 A EP 13710860A EP 2828504 A1 EP2828504 A1 EP 2828504A1
Authority
EP
European Patent Office
Prior art keywords
gas turbine
exhaust gas
exhaust
gas
nox
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13710860.1A
Other languages
German (de)
English (en)
Inventor
Felix Guethe
Eribert Benz
Frank Graf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ansaldo Energia IP UK Ltd
Original Assignee
Alstom Technology AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alstom Technology AG filed Critical Alstom Technology AG
Priority to EP13710860.1A priority Critical patent/EP2828504A1/fr
Publication of EP2828504A1 publication Critical patent/EP2828504A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]

Definitions

  • the present invention relates to the field of gas turbines. It relates to a method for operating a gas turbine according to the preamble of claim 1. It further relates to a gas turbine for carrying out the method and a combined cycle power plant with a gas turbine.
  • combustion temperatures are further increased. Higher combustion temperatures can lead to a higher content of unwanted NOx in the exhaust gas.
  • the reduction of NOx content in the exhaust gas by improved combustion technology has limitations in terms of mixing, leakage and residence time of the fuel. Further reduction by the combustion technology does not seem possible.
  • the NO.sub.x is removed from the exhaust gases of the gas turbine by means of a selective catalytic device with the addition of NH.sub.3, wherein the NO.sub.x content of the exhaust gases is kept at a constant level by controlled recycling of part of the exhaust gases under varying operating conditions of the gas turbine and the addition of NH3 in the selective catalytic device is adjusted to the constant NOx level.
  • An embodiment of the method according to the invention is characterized in that the NOx content of the exhaust gas coming from the gas turbine is simultaneously lowered permanently by the exhaust gas recirculation.
  • Another embodiment of the method according to the invention is characterized in that the exhaust gases are passed through a cooling device with a direct-contact radiator before the selective catalytic reduction in the selective catalytic device.
  • the associated washing effect can improve the effectiveness of NOx removal by 10-30%.
  • the pH value and the addition of oxidizing agents can be regulated in order to optimize the washing effect in the cooling device.
  • Another embodiment of the gas turbine according to the invention is characterized in that a cooling device with a direct contact cooler is arranged in front of the selective catalytic device.
  • the cooling device is designed for washing the exhaust gas.
  • Another embodiment of the gas turbine according to the invention is characterized in that a control is provided which is connected to the exhaust gas recirculation and controls the exhaust gas recirculation in accordance with the NOx content in the exhaust gas.
  • gas turbine is characterized in that the gas turbine is equipped with a sequential combustion.
  • a gas turbine is derived, for example, from EP 0 620 362 B1, this document forming an integral part of the present description.
  • the invention also includes a combined cycle power plant with a gas turbine according to the invention.
  • FIG. 1 in a simplified system diagram of a combined cycle power plant with a gas turbine according to an embodiment of the invention.
  • FIG. 1 shows in a simplified system diagram a combined cycle power plant 10 with a gas turbine 1 1 according to an exemplary embodiment of the invention.
  • the combined cycle power plant 10 comprises in addition to the gas turbine 1 1 a water / steam circuit 12, the heat recovery steam generator 19 is flowed through by the exhaust gas of the gas turbine 1 1 and with the exhaust heat extracted steam for a Steam turbine arrangement with a high-pressure steam turbine 20, a medium-pressure steam turbine 21 and a low-pressure steam turbine 22 generated.
  • the steam exiting the low-pressure steam turbine 22 is condensed in a condenser 24.
  • the accumulated water is pumped by means of a pump 25 in the circuit back to the heat recovery steam generator 19.
  • the exhaust gas is divided after flowing through the heat recovery steam generator 19 in a branch 26.
  • One part is returned to the input of the gas turbine 1 1 in an exhaust gas return line 23 via a cooler 27 by means of a blower 28 and enters the compressor 15 of the gas turbine 1 1 there-together with the ambient air 18 required for combustion.
  • the other part of the exhaust gas passes via a cooling device 13 into a selective catalytic device 14 in which NOx is converted into N 2 by adding NH 3 (34) and is thus removed from the exhaust gas.
  • the resulting exhaust 35 can then be discharged to the outside.
  • the cooling device 13 comprises a direct contact cooler (DCC) 29, in which water which circulates in a closed circuit and is pumped back by means of a pump 30 through a heat exchanger 31 to the direct contact cooler 29, is sprayed into the exhaust gas flow and thus the exhaust gas flow cools. Due to the close contact between sprayed water and the exhaust gas can be generated at the same time a washing effect, which favors the removal of NOx.
  • oxidizing agents 36 such as NaOCl or O 3 or H 2 O 2 can be added to the water cycle in a controlled manner.
  • the pH can be controlled in the circulation.
  • the exhaust gas After passing through the cooling device 13, the exhaust gas enters the selective catalytic device 14, where it is brought into intensive contact with ammonia 34.
  • Essential for the invention is the combination of exhaust gas recirculation (FGR) and selective catalytic reduction (SCR), wherein the Exhaust gas recirculation is controlled so that even with changing operating conditions of the gas turbine 1 1 a constant low NOx content is achieved in the exhaust gas. If such a constant low NOx content in the exhaust gas is maintained, on the one hand NH 3 can be saved, on the other hand
  • the addition of NH 3 in the selective catalytic device 14 can be precisely tuned to the adjusted value of the NOx content, so that contamination of the exhaust gases 35 with NH 3 is greatly reduced or avoided altogether. In this way, an extremely low NOx content is realized in the exhaust gas 35 and the consumption of and contamination with NH3 is kept low.
  • a controller 32 is provided, on the one hand - controls the exhaust gas recirculation - for example via the fan 28 - and on the other hand - if necessary - the addition of NH 3 in the selective catalytic device 14 sets. Furthermore, the controller 32 can control the washing effect in the cooling device 13. Changes in the NOx content in the exhaust gas can be detected by a NOx sensor 33, which is arranged, for example, in front of the input of the selective catalytic device 14 and outputs measured values to the controller 32. It is also advantageous with respect to the NOx content if the gas turbine 1 1 is equipped with a sequential combustion and comprises two combustion chambers 16 and 16 'as well as two turbines 17 and 17'.
  • SCR selective catalytic reduction
  • FGR exhaust gas recirculation
  • the exhaust gas recirculation is controlled so that a constant NOx content in the exhaust gas is maintained even under different operating conditions of the gas turbine;
  • the addition of ammonia for selective catalytic reduction is adjusted to the constant NOx content in the exhaust gas;
  • the ratio of NO to NO 2 can be monitored for selective catalytic reduction
  • the washing effect in the direct contact cooler 29 can increase the effectiveness of the NOx removal by 10-30% with respect to the ratio NO / NO 2 and operation of the direct contact cooler with respect to pH value and oxidizing agent addition.
  • the arrangement according to FIG. 1 also includes a variant in which the direct contact cooler (DCC) 29 is arranged prior to the separation of the exhaust gases, such that it can treat the total exhaust gas mass flow.
  • DCC direct contact cooler

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

L'invention concerne un procédé pour faire fonctionner une turbine à gaz (11), selon lequel les NOx sont éliminés des gaz d'échappement de la turbine à gaz (11) au moyen d'un dispositif de catalyse sélective (14) par ajout de NH3. Une teneur extrêmement faible en NOx pour une faible consommation de NH3, tout en évitant la présence de NH3 dans les gaz d'échappement, est obtenue du fait que la teneur en NOx dans les gaz d'échappement est maintenue à un niveau constant par un retour régulé d'une partie des gaz d'échappement dans des conditions de fonctionnement changeantes de la turbine à gaz (11) et que l'ajout du NH3 dans le dispositif de catalyse sélective (14) est réglé sur le niveau constant de NOx.
EP13710860.1A 2012-03-21 2013-03-21 Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé Withdrawn EP2828504A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13710860.1A EP2828504A1 (fr) 2012-03-21 2013-03-21 Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12160546.3A EP2642097A1 (fr) 2012-03-21 2012-03-21 Procédé de fonctionnement d'une turbine à gaz et turbine à gaz destinée à l'exécution du procédé
PCT/EP2013/055873 WO2013139880A1 (fr) 2012-03-21 2013-03-21 Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en œuvre le procédé
EP13710860.1A EP2828504A1 (fr) 2012-03-21 2013-03-21 Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé

Publications (1)

Publication Number Publication Date
EP2828504A1 true EP2828504A1 (fr) 2015-01-28

Family

ID=47902004

Family Applications (2)

Application Number Title Priority Date Filing Date
EP12160546.3A Withdrawn EP2642097A1 (fr) 2012-03-21 2012-03-21 Procédé de fonctionnement d'une turbine à gaz et turbine à gaz destinée à l'exécution du procédé
EP13710860.1A Withdrawn EP2828504A1 (fr) 2012-03-21 2013-03-21 Procédé pour faire fonctionner une turbine à gaz ainsi que turbine à gaz pour mettre en uvre le procédé

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP12160546.3A Withdrawn EP2642097A1 (fr) 2012-03-21 2012-03-21 Procédé de fonctionnement d'une turbine à gaz et turbine à gaz destinée à l'exécution du procédé

Country Status (6)

Country Link
US (1) US9970353B2 (fr)
EP (2) EP2642097A1 (fr)
JP (1) JP6269981B2 (fr)
CN (1) CN104204461B (fr)
CA (1) CA2867229A1 (fr)
WO (1) WO2013139880A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2581583B1 (fr) * 2011-10-14 2016-11-30 General Electric Technology GmbH Procédé d'exploitation d'une turbine à gaz et turbine à gaz
US9273612B2 (en) * 2013-01-23 2016-03-01 Siemens Aktiengesellschaft Method of operating a gas turbine for reduced ammonia slip
EP2853718B1 (fr) * 2013-09-27 2020-06-24 Ansaldo Energia IP UK Limited Procédé de traitement de gaz d'échappement pour système de turbine à gaz et ensemble de traitement de gaz d'échappement
GB2547274B (en) * 2016-02-15 2018-03-28 Siemens Ag Method and equipment for combustion of ammonia
US11193421B2 (en) * 2019-06-07 2021-12-07 Saudi Arabian Oil Company Cold recycle process for gas turbine inlet air cooling

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Also Published As

Publication number Publication date
EP2642097A1 (fr) 2013-09-25
WO2013139880A1 (fr) 2013-09-26
JP6269981B2 (ja) 2018-01-31
CA2867229A1 (fr) 2013-09-26
US20150000296A1 (en) 2015-01-01
CN104204461B (zh) 2017-03-22
JP2015514177A (ja) 2015-05-18
CN104204461A (zh) 2014-12-10
US9970353B2 (en) 2018-05-15

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